Of Cross-linked Polyester Patents (Class 428/482)
-
Patent number: 11479679Abstract: A thermosetting powder coating composition C (PCC C) includes a physical mixture of a thermosetting powder coating composition A (PCC A) with a separate, distinct thermosetting powder coating composition B (PCC B). Also provided are processes for making the thermosetting powder coating composition C and for coating an article with the thermosetting powder coating composition C. A cured thermosetting powder coating composition C (c-PCC C) is also provided so as to obtain articles having coated and cured thereon the thermosetting powder coating composition C. Heat-curing can occur at low temperatures. The cured c-PCC C is a powder coating having at least one desirable property such as excellent resistance to swelling, good smoothness, good chemical resistance, low gloss, and/or low yellowness.Type: GrantFiled: April 8, 2015Date of Patent: October 25, 2022Assignee: COVESTRO (NETHERLANDS) B.V.Inventors: Johannes Gertrudis Christianus Bongaerts, Petrus Henricus Marinus Wellenberg, Johan Franz Gradus Antonius Jansen
-
Patent number: 10703931Abstract: A coating composition comprising a polyester resin binder and a phosphatized polyester. The compositions are useful for coating containers such as food and beverage containers. The compositions have excellent hydrolytic stability upon storage at high temperature. The compositions are formulated to be substantially free of bisphenol A (BPA) and bisphenol A diglycidyl ether (BADGE).Type: GrantFiled: February 9, 2016Date of Patent: July 7, 2020Assignee: PPG Industries Ohio, Inc.Inventors: Carl Seneker, Jessica Williamson, Claudia Knotts, Youssef Moussa
-
Patent number: 10329431Abstract: The invention relates to a one component heat curable powder coating composition comprising a resin containing reactive unsaturations and wherein all said reactive unsaturations are carbon carbon double bonds connected directly to an electron withdrawing group, a thermal initiation system comprising a peroxide chosen from the group of compounds represented by formula (1) wherein R1 and R2 each independently stand for an optionally substituted alkyl of 1 to 30 C-atoms, wherein the 1 to 30 C-atoms do not include the C-atoms of the substituents or for an optionally substituted aryl of 6 to 18 C-atoms, wherein the 6 to 18 C-atoms do not include the C-atoms of the substituents, and a co-crosslinker chosen from the group of vinylethers, vinyletherurethanes, vinylesters, vinylamides, itaconates, enamines, vinylureas and mixtures thereof.Type: GrantFiled: September 25, 2015Date of Patent: June 25, 2019Assignee: DSM IP ASSETS B.V.Inventors: Johan F.G.A. Jansen, Jan Pieter Drijfhout
-
Patent number: 10328455Abstract: The invention relates to a one component heat-curable powder coating composition comprising a resin containing reactive unsaturations and wherein all said reactive unsaturations are carbon carbon double bonds connected directly to an electron withdrawing group, a thermal initiation system comprising a transition metal catalyst and a peroxide, wherein the peroxide is chosen from the group of peroxyesters, mono-peroxycarbonates and mixtures thereof and a co-crosslinker chosen from the group of vinylethers, vinylesters, vinylamides, itaconates, enamines and mixtures thereof.Type: GrantFiled: September 18, 2015Date of Patent: June 25, 2019Assignee: DSM IP ASSETS B.V.Inventors: Johan F. G. A. Jansen, Jan Pieter Drijfhout
-
Patent number: 10280332Abstract: A coating composition comprising a resinous binder and up to 10 percent by weight of a phosphatized polyester. The compositions are useful for coating containers of all sorts such as food and beverage containers, and the phosphatized polyester provides enhanced adhesion of the coating to the container substrate. The compositions can be formulated to be substantially free of bisphenol A (BPA) and bisphenol A diglycidyl ether (BADGE).Type: GrantFiled: December 8, 2016Date of Patent: May 7, 2019Assignee: PPG Industries Ohio, Inc.Inventors: Youssef Moussa, Claudia Knotts
-
Patent number: 10005264Abstract: A display film includes a transparent polymeric substrate layer having a 0.2% offset yield stress greater than 110 MPa and a transparent aliphatic cross-linked polyurethane layer having a thickness of 100 micrometers or less disposed on the transparent polymeric substrate layer. The transparent aliphatic cross-linked polyurethane layer has a glass transition temperature in a range from 11 to 27 degrees Celsius and a Tan Delta peak value in a range from 0.5 to 2.5. The display film has a haze value of 2% or less.Type: GrantFiled: December 15, 2015Date of Patent: June 26, 2018Assignee: 3M INNOVATIVE PROPERTIES COMPANYInventors: Catherine A. Leatherdale, David Scott Thompson, Michael A. Johnson, John J. Stradinger, Evan L. Breedlove, Steven D. Solomonson, Joseph D. Rule
-
Patent number: 9835947Abstract: A self-organization material according to an embodiment includes a block copolymer and a top coat material. The block copolymer contains a first block and a second block. The second block has a surface free energy higher than that of the first block. The top coat material contains a first portion having a surface free energy higher than that of the first block and lower than that of the second block, and a second portion having a surface free energy lower than that of the first block. The first portion is one of a homopolymer miscible with both the first block and the second block, and a random copolymer having a repeating unit of the first block and a repeating unit of the second block. The second portion is one of an organic siloxane-containing polymer and a fluorine-containing polymer.Type: GrantFiled: September 6, 2016Date of Patent: December 5, 2017Assignee: Kabushiki Kaisha ToshibaInventors: Yuriko Seino, Naoko Kihara
-
Patent number: 9764884Abstract: The invention features a packaging material including a film having a barrier layer formed from an admixture containing a base polymer and a surface-modifying macromolecule. The invention also features containers made from the packaging materials and methods of storing a good.Type: GrantFiled: October 6, 2015Date of Patent: September 19, 2017Assignee: Interface Biologics, Inc.Inventors: Jamie Robert Swenor, Mark A. Steedman, Sanjoy Mullick
-
Patent number: 9708504Abstract: A polyester prepared by free radical polymerization of an unsaturated polyester prepolymer, wherein the polymerization occurs primarily by reaction of the unsaturation is disclosed. Coatings comprising the same are also disclosed, as are substrates coated at least in part with such coatings.Type: GrantFiled: April 1, 2010Date of Patent: July 18, 2017Assignee: PPG Industries Ohio, Inc.Inventors: Debra L. Singer, Dennis A. Simpson, John M. Dudik, Anthony M. Chasser, Kam Lun Lock, Richard Woods, Nigel Francis Masters
-
Patent number: 9394401Abstract: Polyol acrylates are disclosed that are the reaction products of a modified polyol and a (meth)acrylic acid or derivative thereof. The modified polyols used in preparing the polyol acrylates are the reaction product of a natural oil or fatty carboxylic acid or derivative thereof with a polyol selected from the group consisting of polyester polyols, polyether polyols, polyester ether polyols and polyalcohols such that the natural oil or fatty carboxylic acid or derivative thereof is incorporated into the backbone of the polyol. The polyol acrylates are used to prepare pigment dispersions that are useful in formulating energy curable ink compositions.Type: GrantFiled: May 23, 2012Date of Patent: July 19, 2016Assignee: Stepan CompanyInventors: Scott Yin, Michael E. O'Brien, Mingzhe Wang
-
Publication number: 20150125710Abstract: The purpose of the present invention is to provide a two-component curable oxygen-absorbing resin composition that has both oxygen-absorbing and adhesive properties and cohesive power. The resin for an oxygen-absorbing adhesive is a polyester comprising structural units derived from an acid component (A) and an acid component (B), wherein the ratio of the acid component (A) to total acid components is 70% to 95 mol %, the ratio of the acid component (B) to total acid components is 0% to 15 mol %, the polyester has a glass transition temperature of ?20° C. to 2° C., the resin is cured using a hardening agent, the acid component (A) is tetrahydrophthalic acid or a derivative thereof, or tetrahydrophthalic acid anhydride or a derivative thereof, and the acid component (B) is phthalic acid.Type: ApplicationFiled: January 12, 2015Publication date: May 7, 2015Inventors: Yoshihiro Ohta, Yoichi Ishizaki, Yui Asano
-
Patent number: 8940401Abstract: The presently disclosed and claimed inventive concept(s) relates generally to liquid-based coatings for writable-erasable surfaces, products that include such coatings, and methods for making and using the same.Type: GrantFiled: June 10, 2012Date of Patent: January 27, 2015Assignee: Resinate Technologies, Inc.Inventors: Kristopher M. Felice, Adam W. Emerson
-
Publication number: 20140322470Abstract: The invention relates to processes for coating a surface with a crosslinked polyelectrolytes multilayer film incorporating a protein, preferably a growth factor type protein. The invention also relates to crosslinked polyelectrolytes multilayer films obtained by this process, and a coated surface obtained therefrom.Type: ApplicationFiled: June 20, 2014Publication date: October 30, 2014Inventors: CATHERINE PICART, THOMAS CROUZIER
-
Publication number: 20140183089Abstract: Disclosed are Bisphenol A (BPA), Bisphenol F, Bisphenol A diglycidyl ether (BADGE), and Bisphenol F diglycidyl ether (BFDGE)-free coating compositions for metal substrates including an under-coat composition containing a polyester (co)polymer, and an under-coat cross-linker; and an over-coat composition containing a poly(vinyl chloride) (co)polymer dispersed in a substantially nonaqueous carrier liquid, an over-coat cross-linker, and a functional (meth)acrylic (co)polymer. Also provided is a method of coating a metal substrate using the BPA, BPF, BADGE and BFDGE-free coating system to produce a hardened protective coating useful in fabricating metal storage containers. The coated substrate is particularly useful in fabricating multi-part foodstuffs storage containers with “easy-open” end closures.Type: ApplicationFiled: March 7, 2014Publication date: July 3, 2014Applicant: VALSPAR SOURCING, INC.Inventors: Peter Mayr, Paul Cooke, Trevor Fielding, Ronald L. Goodwin, Greg Paulson, James Robinson, Anthony Violleau
-
Publication number: 20140134441Abstract: The invention relates to a polymer material comprising a mixture of: a base polylactic acid (PLA) polymer formed by between 60 wt.-% and 85 wt.-% L units and between 15 wt.-% and 40 wt.-% D units or between 60 wt.-% and 85 wt.-% D units and between 15 wt.-% and 40 wt.-% L units; and a plasticiser selected from the group containing citric acid esters, glycerin esters and derivatives, poly(alkylene ethers), oligomers of lactide or derivatives of lactic acid, fatty acid esters and epoxidised oils, representing between 10 wt.-% and 40 wt.-% in relation to the total weight of the polymer material.Type: ApplicationFiled: June 6, 2012Publication date: May 15, 2014Applicant: AGC Glass EuropeInventors: Sophie Dropsit, Philippe Dubois, Laurent Paternostre, Francois Rase, Olivier Talon
-
Patent number: 8686092Abstract: A series of resins were synthesized using a range of bio-based materials to control the molecular architecture, and therefore the properties, of the inventive resins. The utility of these resins was demonstrated in the formulation of powder coatings, such as ?-hydroxy amide crosslinked and hybrid types. Generally, the bio-based resins flowed out on heating faster than conventional petrochemically-based resins, allowing the use of lower temperatures in the curing oven than is typically possible and a more active catalyst system, especially in the carboxylic acid-epoxy crosslinked hybrid coating formulations.Type: GrantFiled: January 26, 2012Date of Patent: April 1, 2014Assignee: Battelle Memorial InstituteInventors: Bhima R. Vijayendran, Jerry L. King, II, Katherine P. Mitchell, Michael C. Clingerman, Jeffrey T. Cafmeyer
-
Publication number: 20130323502Abstract: A method of manufacturing a polyester film, including: preparing a polyester film substrate having an amount of a terminal carboxylic acid group (AV) of from 3 eq/ton to 20 eq/ton, by using a polyester resin having a temperature distribution of a pre-melting peak (Tm?) of from 1° C. to 10° C.; providing a coating layer on at least one surface of the polyester film substrate; and stretching the polyester film substrate provided with the coating layer at least once.Type: ApplicationFiled: August 14, 2013Publication date: December 5, 2013Applicant: FUJIFILM CorporationInventor: Kiyokazu HASHIMOTO
-
Publication number: 20130302582Abstract: A layered polyester film includes a substrate polyester film with at least one surface laminated with a lamination layer including a polyester resin as a primary component, the surface of the lamination layer having a wetting tension of 35-45 mN/m and the polyester resin contained in the lamination layer meeting (a) to (c): (a) the lamination layer contains polyesters (A) having a glass transition temperature (Tg) of 110-140° C. and polyesters (B) having a glass transition temperature (Tg) of 40-90° C., (b) at least either polyesters (A) or polyesters (B) contains both a monomer having a sulfonic acid component and a monomer having a tri or higher-valent, carboxylic acid component, and (c) the mixing ratio between polyesters (A) and polyesters (B) is 10/90 to 60/40.Type: ApplicationFiled: January 11, 2012Publication date: November 14, 2013Applicant: Toray Industries, Inc.Inventors: Atsushi Matsunaga, Tsutomu Kurihara, Motohiro Okochi
-
Publication number: 20130295355Abstract: A multilayered biodegradable film comprising at least one first resin layer and at least one second resin layer, wherein the first and second resin layers are alternately layered; the first resin layer comprises a polylactic acid-based polymer; the second resin layer comprises an aliphatic polyester-based resin or an aliphatic-aromatic copolymerized polyester-based resin; and the film has a coloring peak value of 0.3 or less, a haze of 10% or less, and an elastic modulus of 300 kgf/mm2 or less, exhibits improved flexibility and transparency, which is useful for environmentally friendly packaging.Type: ApplicationFiled: October 19, 2011Publication date: November 7, 2013Applicant: SKC CO., LTDInventors: Deuk-Young Lee, Sang Il Kim
-
Patent number: 8541542Abstract: The present invention relates to a process for reducing residuals content in a vinyl aromatic polymer, said residuals comprising essentially unpolymerized vinyl aromatic monomer, wherein the vinyl aromatic polymer in the molten state is brought in contact with a solid in powder capable to catalyze the alkylation of said residual vinyl aromatic monomer on the vinyl aromatic polymer. Advantage of the present invention is a sharp reduction of the unpolymerized vinyl aromatic monomer in the vinyl aromatic polymer without generating a new residual and without inducing a colored vinyl aromatic polymer. The present invention also relates to said vinyl aromatic polymer having a low residuals content.Type: GrantFiled: July 13, 2007Date of Patent: September 24, 2013Assignee: Total Research & Technology FeluyInventors: Thomas-Maurice Roussel, Bruno Vuillemin, Francois Fajula
-
Patent number: 8501281Abstract: There are provided: a method for forming a shining coating film which can form a coating film extremely excellent in a leveling property and a brightness with good workability and can also realize the reduction of environmental burden; and a coated article excellent in a design property obtained by this method. In a method comprising the steps of sequentially coating a shining material-containing solvent type first base coat coating, a shining material-containing solvent type second base coat coating and a top clear coating onto a base material and baking a formed multilayered coating film at the same time, an improvement is made so that the resin composition and coating nonvolatile concentration of the first and second base coat coatings and the amount of nonvolatiles in the first and second base coating films will have specific conditions.Type: GrantFiled: February 24, 2009Date of Patent: August 6, 2013Assignees: Honda Motor Co., Ltd., Nippon Paint Co., Ltd., Nippon Bee Chemical Co., Ltd.Inventors: Emi Nomi, Takeshi Ogawa, Atsuo Magoshi, Koji Nakajima, Masanobu Inoue, Yoshiki Takaira
-
Publication number: 20130143053Abstract: A moisture vapor and oxygen transmission resistant flexible film has a polymeric base layer and a barrier layer of discrete particles of a first organic polymer dispersed throughout a matrix of a second organic polymer. Preferably, the first and second polymers are water insoluble and water soluble, respectively. The barrier layer is formed by depositing onto the base layer a coating composition of finely divided insoluble organic polymer particles suspended in an aqueous solution of the water soluble organic polymer, a crosslinking agent and surfactant. The coating composition is heated to crosslink the barrier layer polymers and evaporate solvent to provide a barrier film suitable for packaging applications. Optionally, the film can be metalized to increase barrier properties.Type: ApplicationFiled: January 31, 2013Publication date: June 6, 2013Applicant: TORAY PLASTICS (AMERICA) INC.Inventors: Tracy Paolilli, John Fitch
-
Publication number: 20130122285Abstract: The present invention provides a laminated polyester film which can be suitably used in the applications requiring a good visibility and a good adhesion property to a hard coat layer, etc., for example, such as various kinds of optical films as members of liquid crystal displays as well as molding films. The laminated polyester film of the present invention comprises a polyester film and a coating layer formed on at least one surface of the polyester film which is produced by applying a coating solution comprising a polyester resin having a naphthalene skeleton, a metal oxide, and an acrylic resin and/or a urethane resin, thereonto.Type: ApplicationFiled: May 9, 2011Publication date: May 16, 2013Applicant: Mitsubishi Plastics Inc.Inventors: Taishi Kawasaki, Masato Fujita
-
Patent number: 8440306Abstract: A conductive film which is excellent in moist heat resistance, conductivity, transparency and coating film strength. The conductive film comprises a base film and a coating layer formed on the base film by curing a composition comprising: (i) a conducting polymer containing a polycationic polythiophene having a recurring unit represented by the following formula (1) as the main constituent and a polyanion (component A): wherein R1 and R2 are each independently a hydrogen atom or alkyl group having 1 to 4 carbon atoms or bonded together to form an alkylene group having 1 to 12 carbon atoms which may be substituted arbitrarily; (ii) a water-soluble compound having at least one hydrophilic group selected from the group consisting of oxyethylene group and sulfonate group (component B); and (iii) a crosslinking agent having a glycidyl group (component C), and which has a surface resistance change rate after it is treated at a temperature of 60° C. and a humidity of 90% for 240 hours of 160% or less.Type: GrantFiled: September 3, 2007Date of Patent: May 14, 2013Assignee: Teijin Dupont Films Japan LimitedInventors: Masato Asai, Ai Koganemaru
-
Publication number: 20130089730Abstract: The present invention provides a laminated polyester film which can be suitably used in the applications requiring a good visibility and a good adhesion property to a hard coat layer, etc., for example, such as various kinds of optical films as members of liquid crystal displays as well as molding films. The laminated polyester film of the present invention comprises a polyester film and a coating layer formed on at least one surface of the polyester film which is produced by applying a coating solution comprising a polyester resin having a naphthalene skeleton, a metal oxide and an aromatic isocyanate compound thereonto.Type: ApplicationFiled: April 7, 2011Publication date: April 11, 2013Applicant: MITSUBISHI PLASTICS, INC.Inventors: Taishi Kawasaki, Masato Fujita
-
Publication number: 20120315499Abstract: The object of the present invention is to provide a release film in which the oligomer precipitation from the film surfaces constituting the release film in the respective film processing steps such as an adhesive-applying step of, drying step and sticking step is reduced as possible and it can be attained to improve the continuous production of film. The above object is attained by a release film comprising: a polyester film, coating layers which is formed on both surfaces of said polyester film and comprises a polymer containing ammonium base, a polymer containing polyethylene glycol and a crosslinking agent, and at least one release layer formed on at least one surface of said coating layers.Type: ApplicationFiled: September 16, 2010Publication date: December 13, 2012Inventors: Kimihiro Isaki, Kenji Yoshihara, Masato Fujita
-
Patent number: 8309229Abstract: The invention discloses specific polyester resins which are obtained by the technique of reacting polyesterpolyol oligomer of specific monomeric composition further with polyvalent carboxylic acid (anhydride) and the like; thermosetting water-borne coating compositions using the polyester resins, and coating film-forming methods using the thermosetting water-borne coating compositions.Type: GrantFiled: June 9, 2005Date of Patent: November 13, 2012Assignee: Kansai Paint Co., Ltd.Inventors: Shuichi Nakahara, Hiromi Harakawa
-
Patent number: 8231951Abstract: The present invention provides novel packaging articles, e.g., food and beverage cans. Preferred cans typically comprise a body portion and an end portion, wherein at least one of the body and end portions are aluminum and are coated on at least one major surface with a coating composition of the present invention. Suitable coating compositions of the present invention comprise: one or more polyester resins, wherein at least on the polyester resins has a glass transition temperature (“Tg”) less than about 50° C., and wherein the polyester resin is formed by the reaction of one or more polyacid molecules and one or more polyol molecules; and a crosslinker. The present invention also provides a method of making such cans.Type: GrantFiled: January 25, 2012Date of Patent: July 31, 2012Assignee: Valspar Sourcing, Inc.Inventors: Girish G. Parekh, George K. Bartley, III, Greg M. Paulson, Paul E. Fuchs, Daniel E. Rardon, Robert M. O'Brien
-
Publication number: 20120113361Abstract: The present invention is directed to an optical level composite pressure-sensitive adhesive (PSA), which includes a first portion and a second portion, which have different crosslinked densities and together form a mono-composite structure. The first portion and the second portion may be respectively bonded to a first lamination layer and a second lamination layer that are heterogeneous to each other. Accordingly, different interfacial adhesion and bulk rheology are generated at the interface of the first portion/first, lamination layer and the interface of the second portion/second lamination layer.Type: ApplicationFiled: November 10, 2010Publication date: May 10, 2012Inventors: Jun-Yao Huang, Po-Pin Hung
-
Publication number: 20120107630Abstract: Compositions of PHAs with aromatic/aliphatic polyester are described and methods of making the same.Type: ApplicationFiled: June 25, 2010Publication date: May 3, 2012Inventors: Rajendra K. Krishnaswamy, Xiudong Sun
-
Patent number: 8168276Abstract: Food and beverage containers and methods of coating are provided. The food and beverage containers include a metal substrate that is at least partially coated with a coating prepared from a composition that includes a resin system, a crosslinker, and a catalyst. Preferably, the coating composition is substantially Bisphenol A-free.Type: GrantFiled: September 18, 2007Date of Patent: May 1, 2012Assignee: Valspar Sourcing, Inc.Inventors: Michael Cleaver, Sebastien Gibanel, Georges Sion, Benoit Prouvost, Dave Pape, Paul Stenson
-
Patent number: 8133592Abstract: A laminated adhesive thermoplastic resin film includes a laminated layer containing a polyester resin (A) and a polyester resin (B) different from each other in glass transition temperature and a melamine-based crosslinking agent (C) as components and having a surface energy of 48 to 55 mN/m, formed at least on one surface of the thermoplastic resin film, wherein the glass transition temperature of the polyester resin (A) is 110° C. or higher; the glass transition temperature of the polyester resin (B) is 60° C. to lower than 110° C.; and the amount of the melamine-based crosslinking agent (C) is 75 to 200 parts by weight per 100 parts by weight based on the weight of the polyester resin (A) and the polyester resin (B).Type: GrantFiled: February 14, 2008Date of Patent: March 13, 2012Assignee: Toray Industries, Inc.Inventors: Yasushi Takada, Mitsuhiro Horiuchi, Masato Yanagibashi
-
Patent number: 8133557Abstract: The present invention provides novel packaging articles, e.g., food and beverage cans. Preferred cans typically comprise a body portion and an end portion, wherein at least one of the body and end portions are aluminum and are coated on at least one major surface with a coating composition of the present invention. Suitable coating compositions of the present invention comprise: one or more polyester resins, wherein at least one of the polyester resins has a glass transition temperature (“Tg”) less than about 50° C., and wherein the polyester resin is formed by the reaction of one or more polyacid molecules and one or more polyol molecules; and a crosslinker. Preferred compositions are substantially free of mobile BPA and aromatic glycidyl ether compounds, e.g., BADGE, BFDGE and epoxy novalacs (e.g., NOGE) and more preferred compositions are also substantially free of bound BPA and aromatic glycidyl ether compounds. In more preferred embodiments (e.g.Type: GrantFiled: August 1, 2003Date of Patent: March 13, 2012Assignee: Valspar Sourcing, Inc.Inventors: Girish G. Parekh, George K. Bartley, III, Greg M. Paulson, Paul E. Fuchs, Daniel E. Rardon, Robert M. O'Brian
-
Patent number: 8124221Abstract: The invention provides a fluoropolymer coated film comprising: a polymeric substrate film; and a fluoropolymer coating on the polymeric substrate film, the fluoropolymer coating comprising a vinyl fluoride copolymer comprised of about 40 to about 90 mole % of repeat units derived from vinyl fluoride and about 10 to about 60 mole % of repeat units derived from monomer selected from the group consisting of (a) and (b) below and mixtures thereof, with the proviso that about 0.Type: GrantFiled: December 21, 2007Date of Patent: February 28, 2012Assignees: E. I. du Pont de Nemours and Company, Dupont-Mitsui Flourochemicals Co LtdInventors: Ronald Earl Uschold, Jian Wang, Masahiro Yamamoto
-
Patent number: 8124242Abstract: The present invention provides a coating composition, and coated substrates and articles. The coating composition includes a binder containing a polyester resin that is formed using at least one aromatic, dicarboxylic acid and at least one asymmetric diol. The present invention also provides coating compositions that may be used on articles where excellent outdoor durability is desired. A method of coating and fabricating a substrate is also included.Type: GrantFiled: May 21, 2008Date of Patent: February 28, 2012Assignee: Valspar Sourcing, Inc.Inventors: Larry B. Brandenburger, Abdel Hamid Yassin, Ted Robert Best
-
Patent number: 8080363Abstract: A resin to be added to a resist composition and locally distributed on a resist film surface to hydrophobitize the resist film surface includes a residual monomer in an amount of 1 mass % or less to the resin as a whole in terms of solid content.Type: GrantFiled: September 9, 2008Date of Patent: December 20, 2011Assignee: Fujifilm CorporationInventor: Hiromi Kanda
-
Patent number: 8034446Abstract: A composite solid surface article includes a surface layer with at least one first polymeric resin and a filler, and a backing layer on the surface layer with at least one second polymeric resin and wood particles.Type: GrantFiled: June 15, 2007Date of Patent: October 11, 2011Assignee: Cheil Industries, Inc.Inventors: Jae Wook Juen, Eung Seo Park, Do Choon Rha
-
Patent number: 8029894Abstract: Thermosetting compositions comprising an adhesion-promoting agent are disclosed. The adhesion-promoting agent is derived from boric acid or an equivalent and an ester having two or more functional groups that are derived at least in part from a 1,3-polyol.Type: GrantFiled: August 18, 2006Date of Patent: October 4, 2011Assignee: PPG Industries Ohio, Inc.Inventors: Karen A. Morow, Jane N. Valenta, Shanti Swarup, Lawrence G. Anderson
-
Patent number: 8008394Abstract: The invention is directed to coating compositions for direct coating of plastic substrates, comprising the following components: A) a hydroxy-functional binder component, comprising at least one branched hydroxy-functional polyester having a hydroxyl value of 50-300 mg KOH/g solid, a polydispersity of <2 and a number average molecular weight (Mn) of 300 to 4000, having at least three branches, and having at least one hydroxyl group on each of the at least three branches, B) a crosslinking component for the hydroxyfunctional binder component A), C) at least one adhesion promoting component and optionally, D) organic solvents, additives conventionally found in paints as well as pigments and/or fillers.Type: GrantFiled: July 13, 2005Date of Patent: August 30, 2011Assignee: E.I. du Pont de Nemours & CompanyInventors: Wolfgang Stricker, Udo Hellmann, Yvonne Seulen, Rolf Lackmann
-
Patent number: 7985472Abstract: An EB (electron beam) or UV (ultra violet) curable, low-gloss, dry-erase coating formulation for static and electronic whiteboards is disclosed. The coating contains an acrylate silica blend, an aliphatic urethane acrylate or a polyester acrylate, a polyfunctional reactive diluent and at least one photoinitiator.Type: GrantFiled: June 22, 2007Date of Patent: July 26, 2011Assignee: Exopack-Technology, LLCInventors: Mark O'Neil Outlaw, Michael Ray Carter
-
Publication number: 20110177352Abstract: Disclosed are coating compositions that can be one-component, ambient curable, and waterborne. The coating compositions comprise acrylic copolymer resin particles comprising carbonyl functional groups and a crosslinking agent comprising functional groups, such as hydrazide groups, that are reactive with carbonyl groups.Type: ApplicationFiled: January 15, 2010Publication date: July 21, 2011Applicant: PPG Industries Ohio, Inc.Inventors: Ronald R. Ambrose, Mark S. Gaston, Brian K. Rearick, Irina G. Schwendeman, Venkateshwarlu Kalsani, Hongying Zhou, Michael J. Ziegler
-
Publication number: 20110111242Abstract: The invention offers methods for forming multilayer coating film excelling in smoothness, distinctness of image, water resistance and chipping resistance, the methods comprising successively applying onto a coating object a water-based first coloring paint and a water-based second coloring paint, and simultaneously heating and curing the resultant first colored coating film and second colored coating film, in which the water-based first coloring paint comprises hydroxy-containing polyester resin, curing agent, and water-dispersible acrylic resin which is obtained by polymerization of a monomer component comprising 30-100 mass % of C5-22 alkyl-containing polymerizable unsaturated monomer and 0-70 mass % of polymerizable unsaturated monomer other than the C5-22 alkyl-containing polymerizable unsaturated monomer.Type: ApplicationFiled: June 24, 2009Publication date: May 12, 2011Inventors: Yasuhiro Tomizaki, Takuya Kawachi, Takahisa Ooya
-
Patent number: 7919158Abstract: An insulated glazing unit is described and includes a first transparent substrate spaced apart from a parallel second transparent substrate, a sealed void space defined between the first transparent substrate, second transparent substrate, and the window mounting member, and an infrared radiation reflecting multilayer polymeric film disposed between the first transparent substrate and the second transparent substrate. The infrared radiation reflecting multilayer polymeric film includes a plurality of alternating polymeric layers of a first polymer material and a second polymer material. At least one of the alternating polymer layers is birefringent and oriented. The alternating, polymeric layers cooperate to reflect infrared radiation.Type: GrantFiled: May 31, 2007Date of Patent: April 5, 2011Assignee: 3M Innovative Properties CompanyInventors: Jayshree Seth, Raghunath Padiyath
-
Publication number: 20110070416Abstract: A laminated polyester film includes a layer (S) of polyester and a layer (C) including a polyester resin (A) having a fluorene backbone, wherein a surface of the layer (C) has an adhesive index after a heat and wet test of 3 to 5.Type: ApplicationFiled: May 18, 2009Publication date: March 24, 2011Applicant: TORAY INDUSTRIES, INC.Inventors: Masami Nemoto, Mitsuhiro Horiuchi, Yasushi Takada
-
Patent number: 7907346Abstract: Photochromic materials and photochromic compositions and articles including the photochromic materials are disclosed. The photochromic materials may be the reaction product of a hyperbranched polyester polyol having, on average, at least two reactive hydroxyl groups, and at least one photochromic indeno-fused naphthopyran.Type: GrantFiled: March 16, 2007Date of Patent: March 15, 2011Assignee: Transitions Optical, Inc.Inventors: Shanti Swarup, Carol L. Knox, Feng Wang
-
Patent number: 7820261Abstract: The present invention provides a resin composition having an oxygen scavenging function. The resin composition comprises 70 to 99.9 wt % of a polyvinyl alcohol resin (A) and 0.1 to 30 wt % of a thermoplastic resin (B) other than the polyvinyl alcohol resin (A), wherein the thermoplastic resin (B) has a carbon-carbon double bond and a functional group including a hetero atom, and an oxygen absorption rate of the resin composition is 0.001 ml/m2·day or more.Type: GrantFiled: June 26, 2007Date of Patent: October 26, 2010Assignee: Kuraray Co., Ltd.Inventors: Shinji Tai, Hiroyuki Shimo, Masakazu Nakaya, Mizuho Maeda
-
Publication number: 20100189994Abstract: Aqueous dispersions of crosslinked emulsion polymers comprising tertiary ester groups, comprising (a) at least 50% by weight of an ester derived from a tertiary alcohol and an ethylenically unsaturated C3 to C5 carboxylic acid, (b) 0.001% to 5.0% by weight of at least one compound having at least two ethylenically unsaturated double bonds, and (c) 0% to 49.999% by weight of at least one other monoethylenically unsaturated compound in interpolymerized form and having an average particle size of not more than 1000 nm, and water-absorbing materials obtainable by coating a backing material with the aqueous dispersion described of crosslinked emulsion polymers comprising tertiary ester groups, drying and heating the thus treated backing material to a temperature of at least 140° C. to form carboxyl groups from the tertiary ester groups of the emulsion polymer and at least partly neutralizing the carboxyl groups, and also the use of the water-absorbing materials as an absorbent for water and aqueous fluids.Type: ApplicationFiled: August 6, 2007Publication date: July 29, 2010Applicant: BASF SEInventors: Marc Bothe, Hermann Seyffer, Mirjam Herrlich-Loos, Robert Heger, Matthias Weismantel
-
Publication number: 20100143629Abstract: The invention relates to a methacrylic composition comprising (100-x-y) parts of at least one methacrylic polymer that is a homopolymer or copolymer of MMA, dispersed in which are: x parts of particles of a thermoplastic polymer A comprising MMA as the main monomer that is either crosslinked or that has a weight-average molecular weight Mw>300 000 g/mol, advantageously >400 000 g/mol (relative to a PMMA standard), with a weight-average diameter (ASTM D1921)>100 ?m, advantageously >250 ?m and <500 ?m, advantageously <400 ?m; y parts of particles of a crosslinked thermoplastic polymer B comprising MMA as the main monomer, with a weight-average diameter (ASTM D1921) ranging from 15 to 70 ?m; such that x varies from 2 to 20 and y varies from 10 to 25. Preferably, x+y<33.Type: ApplicationFiled: November 8, 2007Publication date: June 10, 2010Applicant: Arkema FranceInventors: Patrick Delprat, Jerome Berge
-
Publication number: 20100055480Abstract: The present invention is a process for preparing coating compositions comprising a tricure acrylic resin which comprises functionality having different rates of reactivity to crosslinking compounds such as, for example, diisocyantes and polyisocyanates.Type: ApplicationFiled: August 29, 2008Publication date: March 4, 2010Inventors: PATRICIA MARY ELLEN SORMANI, JAMES WILLIAM O'NEIL
-
Publication number: 20100009108Abstract: A composition that is configured for use in creating a film. The composition includes a vinyl acetate containing polymer, such as a vinyl acetate ethylene (VAE) copolymer, and at least one additive that is a pigment, a surfactant, a dispersant, a wetting agent, a plasticizer, a defoamer, a coupling agent, a solvent, a UV absorber, a fire retardant, or a light stabilizer.Type: ApplicationFiled: November 26, 2008Publication date: January 14, 2010Applicant: AVERY DENNISON CORPORATIONInventor: Frank Y. SHIH