Of Cross-linked Polyester Patents (Class 428/482)
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Patent number: 6068935Abstract: A thermoplastic polyester resin represented by general formula (1) or (2) which has a melt index of from 1 to 50. The polyester resin is excellent in flexibility, flame retardancy, and thermal aging resistance. The electric wire, insulated cable, and heat-shrinkable tube obtained with the resin are excellent also in abrasion resistance: ##STR1## whereinRa1 is an aromatic and/or aliphatic hydrocarbon group;Ra2 is a hydrocarbon group;Ra3 is an aliphatic hydrocarbon group having a C.dbd.C bond;Rb is a hydrocarbon group; andl, m, n, p and q each is a positive integer.Type: GrantFiled: September 23, 1999Date of Patent: May 30, 2000Assignees: Sumitomo Electric Industries, Ltd., The Nippon Synthetic Chemical IndustryInventors: Hiroshi Hayami, Harumi Kanke, Akira Yamabayashi
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Patent number: 6037034Abstract: A foil for forming a surface protection layer on a profiled body is produced by a method including forming a carrier foil impregnated with an impregnating resin which is an aqueous condensation resin having a higher volatile component content during coating and a lower volatile component content during lacquering, and applying a lacquer layer of a lacquer which is an aqueous system of a polymerisate containing an OH-group, wherein the foil prior to its application on the profile body has a relatively low end moisture.Type: GrantFiled: December 10, 1996Date of Patent: March 14, 2000Assignee: Werzalit AG & Co.Inventors: Bernd Asseier, Martin Dietz, Jorg Golombek
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Patent number: 6033737Abstract: A compounded and plasticized vinyl chloride polymer layer, optionally supported with a fabric, contains an outer adherent, stain resistant layer having durability and flexibility. The adherent, stain resistant layer is derived from a water-based polyester-amino resin composition. The stain resistant layer comprises the reaction product of said polyester, an acid catalyst, and an amino resin. The vinyl chloride layer may be printed or embossed or both printed and embossed, optionally printed again, before the outer layer is applied. A laminate formed from the polyvinyl chloride polymer layer and the stain resistant layer can also be embossed.Type: GrantFiled: February 13, 1998Date of Patent: March 7, 2000Assignee: OMNOVA Solutions Inc.Inventors: Jay A. Johnson, Marten S. Callicott, Richard W. Davis, Daniel C. Gottschalk, Joseph L. Pate, Joe A. Wright
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Patent number: 6033747Abstract: A laminate including a base material and a copolymer consisting essentially of 3-hydroxybutyrate and 3-hydroxyhexanoate, the copolymer being laminated on at least one side of the base material. A wrapping material including the above laminate. A container made of the above laminate.Type: GrantFiled: October 28, 1997Date of Patent: March 7, 2000Assignee: Kaneka CorporationInventor: Takeshi Shiotani
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Patent number: 6017640Abstract: Opaquely pigmented or thick filmed powder coatings for heat sensitive substrates, such as wood, wood composites, for example, medium density fiber board, and plastics, that can be fully cured, especially near the substrate, through the incorporation of a dual cure system in the powder comprising a thermal initiator, such as a peroxide, along with a UV initiator. The UV initiator cures the surface, while the thermal initiator cures at the substrate. Surprisingly, virtually no pregelation occurs during the heated melt and flow out step prior to UV curing. Consequently, the hardened film finish formed on the surface exhibits exceptional smoothness which is comparable to that of traditional UV curable powders. The hardened film finish is also fully cured throughout and exhibits exceptional adhesion to the substrate which cannot be achieved with traditional UV curable powders that have been pigmented.Type: GrantFiled: April 23, 1999Date of Patent: January 25, 2000Assignee: Morton International, Inc.Inventors: Jeno Muthiah, Andrew T. Daly, Richard P. Haley, Joseph J. Kozlowski
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Patent number: 5998038Abstract: A liquid electrophotographic development sheet wherein a polyethylene resin or a resin including polyethylene such as a polyethylene ionomer as a main component is present on at least one of the surfaces of a substrate sheet is provided. The development sheet can find wide application such as a newspaper, a magazine, a commercial publication, various publications, a poster, a postcard and an envelope, due to its excellent transfer-fixing property.Type: GrantFiled: April 7, 1997Date of Patent: December 7, 1999Assignee: Tokushu Paper Mfg. Co., Ltd.Inventors: Masaya Shibatani, Toyohisa Mouri, Yutaka Hattori
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Patent number: 5985416Abstract: A process for coating and transfer printing sheet metal which is especially suited for manufacture into three-dimensional articles such as appliance panels and one-piece pictures and frames. The coatings may include a thin pigmented base coat and a clear, thin top coat. A decorative image is transfer printed in the clear top coat.Type: GrantFiled: May 26, 1995Date of Patent: November 16, 1999Assignee: American Trim, LLCInventors: Louis R. Sherman, Thomas R. Dunnavant
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Patent number: 5981077Abstract: An image transfer sheet in which a releasing layer is formed on at least one side of a substrate and an image transfer layer including a self-crosslinkable polymer is formed on the releasing layer. An image is formed on the image transfer layer by an electrophotography method, a thermal transfer recording method or the like, and then transferred onto an image receiving material. The transferred image on the image receiving material has good image qualities and good resistance to heat of iron and washing.Type: GrantFiled: May 22, 1997Date of Patent: November 9, 1999Assignee: Ricoh Company, Ltd.Inventor: Keishi Taniguchi
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Patent number: 5976706Abstract: Polyesterdiols having low viscosities of less than 3500 cps, high content of non-volatile matter in excess of 96 wt %, and narrow molecular weight distribution of less than about 1.4 are prepared by esterification of one or more aliphatic dicarboxylic acids or ester derivatives thereof using at least a 1.5 molar excess of one or more aliphatic diols until an acid number of less than 20 is achieved, and stripping excess diol from the polyesterdiol reaction product. Where esterification catalyst is used, catalyst is substantially removed prior to stripping excess unreacted diol from polyesterdiol reaction product. The polyesterdiols so produced are useful as (i) curable components in thermosettable resin compositions, particularly compositions essentially free of volatile organic solvent and also containing a crosslinking agent and a reactive hardening agent: and/or (ii) useful as coatings, paints and adhesives, providing coatings with very low content of volatile organic compounds.Type: GrantFiled: July 27, 1998Date of Patent: November 2, 1999Assignee: Exxon Chemical Patents Inc.Inventors: Albert Ilya Yezrielev, Konstantinos R. Rigopoulos, Richard William Ryan, Karen K. Kuo, George Andrew Knudsen
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Patent number: 5976701Abstract: A flexible, aminoplast-curable film-forming composition can serve as a transparent coating composition for a multi-component composite coating composition having the transparent coating on a pigmented or colored base coat. The film-forming composition comprises at least two polymeric components. One is a polyether polymer containing a plurality of terminal and/or pendant carbamate groups of the structure: ##STR1## Another is at least one additional carbamate functional polymer along with urethane oligomer or is a polyurethane polyol. The former include carbamate functional polyester, acrylic polymer, and polyurethane, where each contains a plurality of terminal and/or pendant carbamate groups of the Structure I depicted above. Also the urethane oligomers has a plurality of carbamate groups of Structure I that are pendant and/or terminal.Type: GrantFiled: December 19, 1996Date of Patent: November 2, 1999Assignee: PPG Industries Ohio, Inc.Inventors: Steven V. Barancyk, Christopher A. Verardi, Gina M. Terrago
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Patent number: 5968662Abstract: A coated metal sheet has undercoat and topcoat paint films formed on the metal substrate. The undercoat film is composed of polyester paint, which is preferably prepared by adding methylated or butylated melamine resin as a curing agent to hydroxyl group-containing macromolecular polyester resin having a glass-transition temperature of 10.degree. C. or higher. The topcoat film is composed of the polyester paint which is preferably prepared by adding an isocyanate curing agent in an amount of 10 wt. % or more to hydrocyl group-containing macromolecular polyester resin. The substrate metal may be a chemically converted steel sheet, galvarnized steel sheet, stainless steel sheet or aluminum sheet. Since the coated steel sheet is bonded with excellent shear strength and durability, it is useful as the casing of electric home appliance or business machine, or a structural member or part for building or furniture.Type: GrantFiled: October 20, 1997Date of Patent: October 19, 1999Assignees: Nisshin Steel Co., Ltd., Dainippon Ink & Chemicals, Inc.Inventors: Michiharu Morishige, Keiichi Sawaya, Hidetoshi Yamabe, Tetsuo Sakai, Toshio Nagatomo, Hideyasu Kamikawa, Akihiro Sawaguchi, Hiroshi Matsuo
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Patent number: 5948526Abstract: A method for protecting a substrate sheet such as a conductive foil suitable for use in the manufacture of printed circuit boards involving applying a lamination mold-release layer to one side of a protective film, and applying a preferably electron beam curable adhesive pressure-sensitive coating to the other side of the film, curing the adhesive coating, and laminating the protective film to the foil or other substrate sheet, which, in turn, may be laminated to other substrates such as dielectric sheets, and in which the laminate product is a protected substrate sheet having a protective film laminated to one side of the sheet (or both), the film having a lamination mold-release layer on one side thereof and an electron beam cured pressure-sensitive adhesive coating on the other side thereof, said other side contacting but being releasably detachable from said substrate sheet, and further wherein the substrate sheet is a foil or similar surface, protection is thus provided during handling and storage as welType: GrantFiled: July 29, 1997Date of Patent: September 7, 1999Assignee: Metallized Products, Inc.Inventors: Martin J. Wilheim, Allen H. Keough
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Patent number: 5932344Abstract: A cement retarder which comprises a saturated or unsaturated polyester obtained by a reaction of a polycarboxylic acid component comprising a polycarboxylic acid having 2 to 6 carbon atoms in the main chain or its derivative, and a polyol component containing a polyhydric alcohol having 2 to 4 carbon atoms or its condensate, wherein:(a) the saturated polyester has a weight average molecular weight of about 300 to about 50,000; or(b) the unsaturated polyester has a weight average molecular weight of about 500 to about 25,000; or(c) the polyhydric alcohol used to obtain the saturated or unsaturated polyester is a condensate of a C.sub.2-4 alkylene glycol; or(d) the saturated polyester is a polyester obtained by the use of a condensate of a C.sub.2-4 alkylene glycol and has a weight average molecular weight of about 300 to about 50,000; or(e) the unsaturated polyester is a polyester obtained by the use of a condensate of a C.sub.Type: GrantFiled: October 7, 1996Date of Patent: August 3, 1999Assignee: Daicel-Huels Ltd.Inventors: Yoshiyuki Ikemoto, Toru Ikuta
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Patent number: 5922473Abstract: Opaquely pigmented or thick filmed powder coatings for heat sensitive substrates, such as wood, wood composites, for example, medium density fiber board, and plastics, that can be fully cured, especially near the substrate, through the incorporation of a dual cure system in the powder comprising a thermal initiator, such as a peroxide, along with a UV initiator. The UV initiator cures the surface, while the thermal initiator cures at the substrate. Surprisingly, virtually no pregelation occurs during the heated melt and flow out step prior to UV curing. Consequently, the hardened film finish formed on the surface exhibits exceptional smoothness which is comparable to that of traditional UV curable powders. The hardened film finish is also fully cured throughout and exhibits exceptional adhesion to the substrate which cannot be achieved with traditional UV curable powders that have been pigmented.Type: GrantFiled: December 26, 1996Date of Patent: July 13, 1999Assignee: Morton International, Inc.Inventors: Jeno Muthiah, Andrew T. Daly, Richard P. Haley, Joseph J. Kozlowski
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Patent number: 5922475Abstract: A curable film-forming composition is provided comprising: (i) a polyester polymer or oligomer containing a plurality of carbamate groups of the structure: ##STR1## (ii) an alkylolated and optionally etherified carbamate functional acrylic polymer; and (iii) an aminoplast crosslinking agent.A multi-component composite coating composition is also provided. The coating composition comprises a pigmented film-forming composition serving as a base coat and a clear film-forming composition serving as a transparent coat over the base coat. The transparent coat, or clear coat, is derived from the curable film-forming composition described above.Type: GrantFiled: April 29, 1997Date of Patent: July 13, 1999Assignee: PPG Industries Ohio, Inc.Inventors: Steven V. Barancyk, Leigh-Ann Humbert
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Patent number: 5922808Abstract: A PVA-base copolymer is obtained by subjecting a lactone, whose ring is formed of 3 to 10 carbon atoms, to ring-opening polymerization in the presence of polyvinyl alcohol (PVA). The copolymer comprises a PVA chain and an aliphatic polyester grafted as a ring-opened polymer of the lactone on the PVA chain. Further, the copolymer has a PVA content of 2 to 98 wt. %, a polyester content of 98 to 2 wt. %, and a number average molecular weight of 10,000 to 500,000.Type: GrantFiled: June 25, 1997Date of Patent: July 13, 1999Assignees: Dainichiseika Color&Chemicals Mfg. Co., Ltd, Ukima Colour&Chemicals Mfg. Co., LtdInventors: Kazuyuki Hanada, Katsumi Kuriyama
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Patent number: 5919873Abstract: Disclosed are novel crosslinked polymers derived from methylol phenols and maleic acid species, and methods of synthesizing these macromolecules. Polyesters and chromandicarboxylic groups are the dominant linkages in the structure of general formula: ##STR1## R is H or a spacing group between aromatics, R.sub.1 is an aldehyde substituent, R.sub.2 a spacing group belonging to multihidric alcohols, a maleyl grouping, and n a whole number either 0 or 1.Type: GrantFiled: July 24, 1998Date of Patent: July 6, 1999Assignee: Rio Oeste, S.A.Inventor: Nicholas M. Irving
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Patent number: 5912063Abstract: A biaxially oriented laminate film comprising a thermoplastic resin layer A and a thermoplastic resin layer B which is laminated on one side of the thermoplastic resin layer A. The surface of the thermoplastic resin layer A has protrusions having an average height of 2 to 85 nm and an average width of 20 to 500 .mu.m, at a density of 4 to 2,500/mm.sup.2. The thermoplastic resin layer B contains inert fine particles, and the surface of the thermoplastic resin layer B is rougher than the surface of the thermoplastic resin layer A. The laminate film can have furher a layer C on the thermoplastic resin layer A. The surface of the thermoplastic resin layer C has protrusions having an average height of 2 to 85 nm and an average width of 20 to 500 .mu.m, at a density of 4 to 2,500/mm.sup.2. These laminate film are useful as a base film for magnetic recording medium.Type: GrantFiled: February 3, 1997Date of Patent: June 15, 1999Assignee: Teijin LimitedInventors: Toshifumi Osawa, Makoto Handa, Mitsuio Tojo, Hideaki Watanabe
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Patent number: 5910356Abstract: An adherent polyester film laminate (A) having a coating layer of a composition formed on one side or both sides of a polyester film, the composition comprising, as main components, (i) an aqueous polyester having a secondary transition point of 40 to 85.degree. C. and (ii) a fatty acid bisamide; a polyester film laminate (B) having a hard coat layer formed on the coating layer of the laminate (A); and a polyester film laminate (C) having an anti-reflection layer formed on the hard coat layer of the laminate (B). Since these laminates are excellent in adhesive force, transparency and slipperiness and has an anti-reflection property, they are useful as a face surface protective material for glass and displays.Type: GrantFiled: February 5, 1997Date of Patent: June 8, 1999Assignee: Teijin LimitedInventors: Toshifumi Ishikawa, Shinichiro Okada, Masayuki Fukuda, Hiroshi Tomita
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Patent number: 5900311Abstract: Fiber-reinforced thermosetting polyester composites containing in excess of 30 wt %, based on the weight of the composite, reinforcing fiber, are made by a vacuum-assisted transfer molding technique from a 1-phase composite matrix precursor comprising a polyester, a reactive monomer, and a low-profile additive. The polyester has a molecular weight/double bond factor of between about 150 and 190, styrene is a preferred reactive monomer, and a preferred low-profile additive is a thermoplastic polymer with a weight average molecular weight in excess of 3,000 and which is miscible in the polyester and reactive monomer. The polyester composite is formed by coating the surface of a mold with a gel coat; applying a skin laminate over the partially cured gel coat; applying a fiber reinforcement to the skin laminate; closing the mold; and injecting the 1-phase matrix precursor while the mold is under vacuum.Type: GrantFiled: March 23, 1994Date of Patent: May 4, 1999Assignee: Cook Composites and Polymers Co.Inventors: David A. Campanella, Chih-Pin G. Hsu
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Patent number: 5891582Abstract: A resin composition comprises an acrylated polyester, the polyester being the reaction product of an equivalent excess of 1,6-hexanediol and an aromatic polycarboxylic acid or anhydride, preferably trimellitic anhydride. In the preferred embodiment, the reaction product includes a highly ethoxylated triacrylate. Upon UV initiated polymerization or copolymerization, improved clear coatings for "no-wax" resilient floors are obtained. These coatings have better resistance to household and other stains than commercial urethane/acrylate floor coverings.Type: GrantFiled: June 30, 1997Date of Patent: April 6, 1999Assignee: Armstrong World Industries, Inc.Inventors: Wendell A. Ehrhart, Songvit Setthachayanon
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Patent number: 5888645Abstract: A fiber-reinforced composite material and articles of manufacture formed thereof are formed by the method comprising: forming a compound material comprising a mixture of curable matrix-forming binder, heat resistant reinforcing fibers, and at least one particulate material, wherein the curable matrix-forming binder is 5 to 50% by volume of the compound material; curing the curable binder under simultaneous application of externally applied pressure and ultrasonic energy. Articles according to the invention are useful in a multitude of applications, particularly in applications where the article must retain its shape and properties when subjected to temperatures above the melting point of usual thermoplastic materials, e.g. above 1000.degree. C. The method provides dense, thermally stable, coherent composite materials having a desired high density. Forming and curing times are typically 10 times shorter than conventional methods, e.g. for brake pads in about 3-5 seconds.Type: GrantFiled: May 10, 1993Date of Patent: March 30, 1999Assignee: Obtec A/SInventors: Torben Lindgaard, David Morgan Thomas
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Patent number: 5869191Abstract: Linear, tertiary carboxyl functional polyester resins obtainable by reaction ofa) at least one compound A.sub.1, comprising the reaction product of(i) a glycidylester of a mixture of certain highly branched saturated monocarboxylic acids isomers, and(ii) a mixture of said highly branched saturated monocarboxylic acids;b) at least one aromatic or cycloaliphatic dicarboxylic acid compound B;c) optionally at least one dihydroxymonocarboxylic acid compound C; andd) optionally at least one diol compound D; in a certain molar ratio of compounds A.sub.1 :B:C:D, at a temperature of from 100.degree. to 225.degree. C., until essentially all the non-tertiary carboxyl groups as initially present in the reaction mixture have been reacted.Type: GrantFiled: November 24, 1997Date of Patent: February 9, 1999Assignee: Shell Oil CompanyInventors: Ronald Petrus Clemons Van Gaalen, Petrus Gerardus Kooijmans, Eric Johannes Vos
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Patent number: 5866264Abstract: A process is descripted in which an article of manufacture may be produced which includes a renewable surface on a synthetic wood composite substrate.Type: GrantFiled: October 22, 1996Date of Patent: February 2, 1999Assignee: Crane Plastics Company Limited PartnershipInventors: Burch E. Zehner, Jeffrey R. Brandt
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Patent number: 5863641Abstract: A biaxially orientated polyester film for sublimitation type thermal transfer printing having a coating layer and a sublimation type ink layer formed on the coating layer. The coating layer comprises an aqueous acrylic resin (A), an aqueous polyester (B) and an aqueous epoxy compound (C), weights of which satisfy the relationships: (1) 0.30.ltoreq.W.sub.A .ltoreq.0.90, (2) 0.10.ltoreq.W.sub.B .ltoreq.0.50, (3) 0.05.ltoreq.W.sub.C .ltoreq.0.30, and (4) 0.25.ltoreq.W.sub.C /W.sub.B .ltoreq.2 in which W.sub.A, W.sub.B and W.sub.C are weight ratios of the aqueous acrylic resin (A), the aqueous polyester (B), and the aqueous epoxy compound (C), respectively based the whole weight of the coating layer.Type: GrantFiled: March 28, 1997Date of Patent: January 26, 1999Assignee: Diafoil Hoechst Company, Ltd.Inventors: Seiji Sakamoto, Jun Takahashi
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Patent number: 5858549Abstract: (Hydroxyalkyl)urea crosslinking agents and compositions which utilize such crosslinking agents are disclosed. The crosslinking agents contain a single urea group, at least two hydroxyl groups, and have at least two carbon atoms disposed between the urea group and each of the hydroxyl groups. The compositions contain a poly-functional molecule which contains at least two functional groups selected from the group consisting of carboxyl, anhydride and amine.Type: GrantFiled: January 7, 1997Date of Patent: January 12, 1999Assignee: National Starch and Chemical Investment Holding CorporationInventors: Andrew J. Kielbania, Jr., Pravin Kukkala, Sharon Lee, John C. Leighton
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Patent number: 5856017Abstract: The present invention provides a gas barrier film including a plastic film and a thin film which is made of a composition containing an oxide as a main component and is formed on at least one surface of the plastic film. A specific gravity of the thin film is 55% or more and 100% or less of a specific gravity of the oxide in the form of a crystal generally present at room temperature and under atmospheric pressure. Thus, the invention provides a gas barrier film having an excellent gas barrier and retort properties and bending resistance; a gas barrier film suitably used in a wrapping material for dried food, liquid food or food containing liquids, frozen food and retort food; a gas barrier film that can be used in an electronic oven, can be sterilized by micro waves and can contain a free-oxygen absorber; a gas barrier film suitably used in a paper carton, a tube, a lid and the like; and a gas barrier film suitably used for cutting off gas for industrial use.Type: GrantFiled: July 18, 1997Date of Patent: January 5, 1999Assignee: Toyo Boseki Kabushiki KaishaInventors: Shusei Matsuda, Kiyoshi Iseki, Yoshiharu Morihara, Toru Kotani, Toshiyuki Oya, Toshio Uno, Teizo Harima, Hideomi Kobe, Yozo Yamada
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Patent number: 5844017Abstract: The present invention describes a prepolymer of aliphatic polyoxaesters containing amines and/or amido groups having polymerizable end groups that may be used to produce surgical devices such as sutures, sutures with attached needles, molded devices, and the like.Type: GrantFiled: November 17, 1997Date of Patent: December 1, 1998Assignee: Ethicon, Inc.Inventors: Dennis D. Jamiolkowski, Rao S. Bezwada
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Patent number: 5834118Abstract: Hyperbranched polyester of a polyol with 3 to 10 reactive hydroxyl groups, preferably of equivalent reactivity, and an aromatic polycarboxylic anhydride with 2 to 4 carboxyl groups, preferably 3 carboxyl groups, each hydroxyl group of the polyol forming an ester linkage with one anhydride group of the polycarboxylic anhydride, and further glycidyl (meth)acrylate or allyl glycidyl ether forming ester linkages with the remaining carboxyl groups of the anhydride and free hydroxyl groups. Further in the hyperbranched polyester (meth)acrylic anhydride and/or an aliphatic carboxylic anhydride form ester linkages with the free hydroxyl groups. The invention also comprises a process for the production of hyperbranched polyesters and such polyesters obtainable by the process. The hyperbranched polyesters can be used as resins, curable by UV irradiation, for the production of coatings, adhesives, laminates, foils and thin films and fibre-reinforced composites.Type: GrantFiled: May 9, 1997Date of Patent: November 10, 1998Assignee: Neste Oy of KeilaniemiInventors: Bengt R.ang.nby, Shi Wenfang
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Patent number: 5814410Abstract: A color-plus-clear coating system is disclosed. A pigmented or colored basecoat is first applied to a substrate followed by the application of a transparent topcoat to the basecoat. The transparent topcoat composition is a crosslinkable composition comprising (1) a material containing a plurality of carbamate and/or urea functional groups and (2) an aminoplast crosslinking agent. The topcoat composition provides a composite coating with improved acid etch resistance, making the composite coating particularly useful as an automotive topcoat.Type: GrantFiled: February 22, 1996Date of Patent: September 29, 1998Assignee: PPG Industries, Inc.Inventors: Debra L. Singer, Shanti Swarup, Michael A. Mayo
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Patent number: 5811198Abstract: Linear, tertiary carboxyl functional polyester resins suitable for the production of coatings having excellent outdoor durable properties, the polyester resins obtainable by reaction ofa) at least one aromatic and/or cycloaliphatic carboxylic acid compound A comprising two aromatic- and/or secondary aliphatic carboxyl groups or the anhydride thereof,b) at least one hydroxyl compound B comprising two aliphatic hydroxyl groups, which groups each independently may be primary or secondary hydroxyl groups,c) at least one hydroxyl substituted carboxylic acid compound C comprising at least one tertiary aliphatic carboxyl group and two aliphatic hydroxyl groups, which groups each independently may be primary or secondary hydroxyl groups, andd) optionally one carboxylic acid compound D comprising one carboxyl group, the molar ratio of compounds A:B:C:D being (X+Y-1):X:Y:Z,wherein X ranges from 2 to 8, Y ranges from 2 to 8, and Z ranges from 0 to 2.Type: GrantFiled: October 27, 1997Date of Patent: September 22, 1998Assignee: Shell Oil CompanyInventors: Jan Freriks, Petrus Gerardus Kooijmans, Gerrit Gerardus Rosenbrand, Marianne Angele Walravens
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Patent number: 5761809Abstract: Disclosed is a process which comprises reacting a haloalkylated aromatic polymer with a material selected from the group consisting of unsaturated ester salts, alkoxide salts, alkylcarboxylate salts, and mixtures thereof, thereby forming a curable polymer having functional groups corresponding to the selected salt. Another embodiment of the present invention is directed to a process for preparing an ink jet printhead with the curable polymer thus prepared.Type: GrantFiled: August 29, 1996Date of Patent: June 9, 1998Assignee: Xerox CorporationInventors: Timothy J. Fuller, Ram S. Narang, Thomas W. Smith, David J. Luca, Raymond K. Crandall
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Patent number: 5763099Abstract: The invention relates to a binder composition for powder coatings. The binder composition is substantially based on a mixture of an unsaturated polyester and an oligomer having a plurality of allyl groups and further having at least either ether and ester groups or urethane and optionally ether groups.The oligmer is preferably an allyl ether ester being more preferably the ester of trimethylolpropane diallyl ether or pentaerythritol triallyl ether and a polycarboxylic acid (anhydride).Type: GrantFiled: May 7, 1996Date of Patent: June 9, 1998Assignee: DSM N.V.Inventors: Tosko A. Misev, Eimbert G. Belder, Fokeltje A. Koldijk
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Patent number: 5763096Abstract: Disclosed is a film having a good adhesive property comprising a base film and a coated layer formed on at least one surface of the base film. The coated layer comprises a mixture whose main constituents are a polyester resin and a melamine compound, and not less than 60% by weight of constituents forming the coated layer is the polyester resin. Or the concentration of a carboxylic acid of the surface of the coated layer is not less than 0.005 and the concentration of a primary amine of the surface of the coated layer is not less than 0.0015. The film having such a coated layer can indicate an excellent adhesive property for a deposited layer under a high-moisture condition, particularly, in water, and an excellent adhesive property for a printing ink.Type: GrantFiled: March 5, 1996Date of Patent: June 9, 1998Assignee: Toray Industries, Inc.Inventors: Kohzo Takahashi, Masahiro Kimura, Takashi Mimura
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Patent number: 5744248Abstract: The present invention relates to coating compositions, which are curable by radiation and containI) 0 to 95 parts by weight of at least one binder curable by radiation and containing maleate, fumarate and/or acryloyl groups other than those of component II),II) 5 to 100 parts by weight of a mixture ofA) 20 to 80 parts by weight of at least one polyester resin prepared from fatty acids, provided that at least 20 wt. % of component A) is a fatty acid having a number average molecular weight of 112 to 400 andB) 20 to 80 parts by weight of compounds containing (meth)acryloyl groups, having a viscosity at 23.degree. C. of 10 to 1,000 mPa.s and having a number average molecular weight of 170 to 1,000,wherein the sum of the parts by weight of components I) and II) adds up to 100, based on the weight of components I) and II), and the sum of the parts by weight of components A) and B) adds up to 100, based on the weight of components A) and B).Type: GrantFiled: January 28, 1997Date of Patent: April 28, 1998Assignee: Bayer AktiengesellschaftInventors: Jurgen Meixner, Wolfgang Fischer, Manfred Muller, Gunter Ruf
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Patent number: 5741602Abstract: A heat-curable, epoxy-free coating composition comprises a dry blend of at least two different binder resins, each binder resin comprising of (a) a carboxyl-terminated polyester resin having an acid value from 20 to 200 mg KOH/g and a glass transition temperature of at least 40.degree. C., and (b) a .beta.-hydroxylalkylamide with at least two .beta.-hydroxylalkylamide groups per molecule; the at least two different binder resins differing in functionality, or in other words in the number of carboxyl and/or .beta.-hydroxylalkylamide groups per binder resin molecule. Along with the binder resins, the coating composition optionally includes further additives that are typical for the processing and use of powder coatings.Type: GrantFiled: August 23, 1995Date of Patent: April 21, 1998Assignee: EMS-Inventa AGInventors: Manfred Hoppe, Andreas Kaplan, Rene Gisler
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Patent number: 5739256Abstract: High performance polyester sulfone oligomers are prepared for aerospace applications by condensing mono- or difunctional crosslinkable end caps (i.e. unsaturated hydrocarbons having one or two crosslinking sites) with dicarboxylic acid halides and dialcohols (i.e. diols). Multidimensional oligomers have an aromatic hub from which the polyester chains radiate. Blends of the linear and multidimensional oligomers can be made using compatible, non-crosslinking polymers. Prepregs and composites are formed from the oligomers or blends.Type: GrantFiled: June 5, 1995Date of Patent: April 14, 1998Assignee: The Boeing CompanyInventors: Hyman R. Lubowitz, Clyde H. Sheppard
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Patent number: 5736249Abstract: Articles of manufacture are provided with a low surface energy, permanently non-stick, non-fouling and ice-phobic surface by a system of coating comprising applying a primary coating having a surface energy of 22-28 dynes/cm.sup.2 comprising a novel polymeric material having non-stick and hardness properties and then applying a top coating having lower surface energy of from about 18-21 dynes/cm.sup.2 comprising a siliconic polymer and interdigitating means to make the top coating permanent, the means preferably comprising a bi- or polyfunctional organic compound adapted to wet the surface of the primary coating and chemically or physically bond thereto and to couple to the siliconic polymeric substance in the top coating. The coated substrates are resistant to marking by graffiti, to adherence by marine fouling organisms, and frozen ice on the surface is easily removed.Type: GrantFiled: August 16, 1994Date of Patent: April 7, 1998Assignee: Decora, IncorporatedInventors: John Ralph Smith, Nissim N. Garti
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Patent number: 5733956Abstract: A light stabilizer package is disclosed. The light stabilizer package comprises a monomeric HALS having a pKa of no greater than 7, an ultraviolet light absorber and, optionally, a polymeric HALS having a pKa of less than 7. The light stabilizer package may be blended with a thermoplastic olefin to form a moldable light stable composition. An article comprising the moldable light stable composition may have an exterior surface that is at least partially coated.Type: GrantFiled: June 5, 1995Date of Patent: March 31, 1998Assignee: Solvay Engineered PolymersInventors: Edmund Kwok-Leung Lau, David K. Edge
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Patent number: 5731095Abstract: A water-soluble or water-dispersible fluorine-containing dendritic polymer surfactant having at least one terminal fluorocarbon moiety and at least one terminal anionic moiety, and which is suitable for use in preparing protective coating compositions is disclosed. The water-soluble or water-dispersible fluorine-containing dendritic polymer surfactants are represented by the general formula: ##STR1## where D represents a dendritic polymer, R.sub.F represents a fluorocarbon containing moiety, A.sup.- represents an anionic containing moiety, C.sup.+ represents a cation, T represents a terminal group of the dendritic polymer which has not been functionalized with a fluorocarbon or anionic moiety, n and m are at least each at least one, and the sum of n+m+q is the total number of terminal groups on the dendritic polymer. Also disclosed is a coating composition capable of forming a highly crosslinked, non-stick, protective coating.Type: GrantFiled: October 23, 1996Date of Patent: March 24, 1998Assignee: Oxazogen, Inc.Inventors: Larry A. Milco, Donald A. Tomalia
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Patent number: 5725958Abstract: The present invention provides a gas barrier film including a plastic film and a thin film which is made of a composition containing an oxide as a main component and is formed on at least one surface of the plastic film. A specific gravity of the thin film is 55% or more and 100% or less of a specific gravity of the oxide in the form of a crystal generally present at room temperature and under atmospheric pressure. Thus, the invention provides a gas barrier film having an excellent gas barrier and retort properties and bending resistance; a gas barrier film suitably used in a wrapping material for dried food, liquid food or food containing liquids, frozen food and retort food; a gas barrier film that can be used in an electronic oven, can be sterilized by micro waves end can contain a free-oxygen absorber; a gas barrier film suitably used in a paper carton, a tube, a lid and the like; and a gas barrier film suitably used for cutting off gas for industrial use.Type: GrantFiled: February 2, 1996Date of Patent: March 10, 1998Assignee: Toyo Boseki Kabushiki KaishaInventors: Shusei Matsuda, Kiyoshi Iseki, Yoshiharu Morihara, Toru Kotani, Toshiyuki Oya, Toshio Uno, Teizo Harima, Hideomi Kobe, Yozo Yamada
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Patent number: 5709950Abstract: Flexible, aminoplast-curable film-forming compositions and multi-component composite coating compositions comprising at least one pigmented or colored base coat and at least one transparent clear coat are disclosed. A pigmented or colored base coat is first applied to a substrate followed by the application of a clear coat to the base coat. Both the colored base coat and the clear coat are flexible, curable film-forming compositions having an aminoplast crosslinking agent, and the base coat and optionally the clear coat has carbamate functional polymers. The flexible, multi-component composite coating compositions provide improved durability, water spotting resistance, and/or acid etch resistance, making the composite coatings particularly useful for plastic automotive parts.Type: GrantFiled: December 19, 1996Date of Patent: January 20, 1998Assignee: PPG Industries, Inc.Inventors: John W. Burgman, Gina M. Terrago, Christopher A. Verardi
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Patent number: 5705275Abstract: Disclosed is a novel thermosetting resin composition suitable for the preparation of an integrally molded two-parts composite body consisting of a first part of a cured silicone rubber and a second part of a cured thermosetting resin without intervention of an adhesive layer at the interface. The thermosetting resin composition comprises:(a) 100 parts by weight of an unsaturated polyester resin;(b) from 20 to 50 parts by weight of an ethylenically unsaturated polymerizable compound such as diallyl phthalate;(c) from 5 to 30 parts by weight of an epoxy resin;(d) from 2 to 20 parts by weight of a melamine resin;(e) from 0.1 to 2 parts by weight of a radical-reactive curing agent which is an organic peroxide; and(f) from 0.1 to 2 parts by weight of an acidic catalyst such as aromatic sulfonic acid derivatives.Type: GrantFiled: November 29, 1996Date of Patent: January 6, 1998Assignee: Shin-Etsu Polymer Co., Ltd.Inventors: Sadao Nakano, Susumu Iwama, Mikio Kiyosawa
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Patent number: 5700583Abstract: The present invention describes a crosslinked aliphatic polyoxaesters containing amines and/or amido groups and blends thereof with other polymers that may be used to produce surgical devices such as sutures, sutures with attached needles, molded devices, and the like. The crosslinked aliphatic polyoxaesters of the present invention is formed from an aliphatic polyoxaester having a first divalent repeating unit of formula I:?O--C(O)--C(R.sub.1)(R.sub.2)--O--(R.sub.3)--O--C(R.sub.1)(R.sub.2)--C(O)-- !Iand a second repeating unit of the formula:?--O--R.sub.12 --!.sub.U, XVIand optionally a third repeating unit with a formula selected from the group consisting of:?--O--R.sub.4 --!.sub.A, II?--O--R.sub.5 --C(O)--!.sub.B, III(?--O--R.sub.5 --C(O)!.sub.P --O--).sub.L G XIand combinations thereof wherein R.sub.12 contains an internal amine or internal amide group wherein the aliphatic polyoxaester has been crosslinked.Type: GrantFiled: November 6, 1996Date of Patent: December 23, 1997Assignee: Ethicon, Inc.Inventors: Dennis D. Jamiolkowski, Rao S. Bezwada
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Patent number: 5698329Abstract: A coated film having a polymeric film substrate with a subbing layer containing an organic acid and a polymer which has a repeating unit(s) containing a pendant nitrogen atom(s). The ratio of organic acid to polymer in the subbing layer is in the range from 1:0.1 to 20 by weight. The coated film exhibits excellent adhesion to photographic emulsion layers, even when applied prior to completion of any film stretching operation.Type: GrantFiled: June 5, 1995Date of Patent: December 16, 1997Assignee: Imperial Chemical Industries PLCInventor: Julian Neal Robinson
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Patent number: 5690994Abstract: A coated film having a polymeric film substrate with a subbing layer containing an organic acid and a polymer which has a repeating unit(s) containing a pendant nitrogen atom(s). The ratio of organic acid to polymer in the subbing layer is in the range from 1:0.1 to 20 by weight. The coated film exhibits excellent adhesion to photographic emulsion layers, even when applied prior to completion of any film stretching operation.Type: GrantFiled: June 5, 1995Date of Patent: November 25, 1997Assignee: Imperial Chemical Industries PLCInventor: Julian Neal Robinson
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Patent number: 5688598Abstract: A thermosetting, organic solvent-based, primer coating composition for protecting metal surfaces which includes a solvent solution of: (a) a hydroxy-functional polyester resin; (b) a thermosetting acrylic resin; (c) a hydroxy-terminal polybutadiene resin, a hydroxy-terminal epoxidized polybutadiene resin, or mixtures thereof; (d) a blocked isocyanate crosslinker including at least one dimethyl pyrazole blocked isocyanate; (e) an aminoplast crosslinker including at least one melamine-formaldehyde condensate; (f) a catalyst; and, (g) a pigment. The primer exhibits excellent flexibility after curing to allow the primer to be coil coated onto metals as a thicker film and to have the metal subsequently formed without film fracture or loss of adhesion.Type: GrantFiled: June 28, 1996Date of Patent: November 18, 1997Assignee: Morton International, Inc.Inventors: Mitchell T. Keck, Ronald J. Lewarchik, Jack C. Allman
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Patent number: 5679450Abstract: A composite material is disclosed which comprises a shaped, expanded body having a closed cellular structure, and a layer of a thermosetting resin directly bonded to a surface of the shaped body, wherein the shaped body is formed of a mixed thermoplastic resin having a xylene-insoluble content of not greater than 1% by weight and containing at least 50% by weight of a polyolefin resin and at least 2% by weight of a polyene polymer having vinyl group-containing side chains.Type: GrantFiled: July 5, 1995Date of Patent: October 21, 1997Assignee: JSP CorporationInventors: Hisao Tokoro, Hidehiro Sasaki, Masakazu Sakaguchi
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Patent number: 5674608Abstract: Polymeric, thin oriented films can be made by use of a combination of a hot blown process and a blown bubble process, i.e. a double bubble process. The resulting film has use in replacing PVC for in store stretch wrap applications. Very low density polyethylene, VLDPE, is an especially preferred material for this process. It may be used as a monolayer, or as one layer of a multilayer structure. In practicing the invention, the polymer is extruded and hot blown, and heated to a temperature above its orientation temperature. This heating can be accomplished by the use of a heated liquid reservoir or sock disposed at the lower end of the primary bubble, inside the bubble. The hot blown heated film is then passed through a first set of pinch rolls, re-inflated into a blown bubble, and collapsed at a second set of pinch rolls. Thin, tough and elastic packaging materials are obtained by this process.Type: GrantFiled: March 23, 1995Date of Patent: October 7, 1997Assignee: W. R. Grace & Co.-Conn.Inventor: Henry G. Schirmer
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Patent number: 5667901Abstract: Provided are various 2-acetylglutarate esters of polyols which are useful as poller crosslinkers for use in thermosetting coating compositions, as well as methods of preparation of these materials. In particular, the invention provides crosslinkers of the formula ##STR1## wherein R and R' are independently t-butyl, t-amyl, or phenyl, and x is an integer of from 2 to 5.Type: GrantFiled: February 20, 1996Date of Patent: September 16, 1997Assignee: Eastman Chemical CompanyInventors: Philip C. Heidt, Charles H. Foster, J. Stewart Witzeman