Abstract: A modified polytetrafluoroethylene which can be formed under a low extrusion pressure and with which changes of the extrusion pressure are suppressed, even in paste extrusion at a high RR ratio, and its production method. The modified polytetrafluoroethylene having units based on tetrafluoroethylene, 0.020 to 0.040 mass % of units based on a monomer represented by the following formula (1), and 0.003 to 0.080 mass % of units based on a monomer represented by the following formula (2), each based on all units of the modified polytetrafluoroethylene. The monomers of formulae (1) and (2) are represented by: CH2?CH—CnF2n+1 (1), wherein n is from 2 to 6; and CF2?CFO(LO)mRf (2), wherein L is a perfluoroalkylene group, Rf is a perfluoroalkyl group, and m is an integer of from 0 to 4.

Abstract: Waterproof engineered floor and wall planks have a wear layer, an underlayer about an extruded dust and plastic composite core and a click-lock edge fastening system.

Abstract: A method is disclosed herein for treating a polymeric surface to resist non-specific binding of biomolecules and attachment of cells. The method includes the steps of: imparting a charge to the polymeric surface to produce a charged surface; exposing the charged surface to a nitrogen-rich polymer to form a polymerized surface; exposing the polymerized surface to an oxidized polysaccharide to form an aldehyde surface; and exposing the aldehyde surface to a reducing agent. Advantageously, a method is provided which produces surfaces that resist non-specific protein binding and cell attachment and that avoids the use of photochemical reactions or prior art specially designed compounds.

Abstract: Waterproof engineered floor and wall planks have a wear layer and an underlayer about an extruded dust and plastic composite core.

Abstract: A film for a backlight unit including a semiconductor nanocrystal-polymer composite film including a semiconductor nanocrystal and a matrix polymer in which the semiconductor nanocrystal is dispersed, wherein the matrix polymer is a polymer produced by a polymerization of a multifunctional photo-curable oligomer, a mono-functional photo-curable monomer, and a multifunctional photo-curable cross-linking agent, the multifunctional photo-curable oligomer has an acid value of less than or equal to about 0.1 mg of KOH/g, and a content (A1) of a first structural unit derived from the multifunctional photo-curable oligomer, a content (A2) of a second structural unit derived from the mono-functional photo-curable monomer, and a content (A3) of a third structural unit derived from the multifunctional photo-curable cross-linking agent satisfy Equation 1: A1<(A2+A3).

Abstract: Stable, high performance polymer compositions including polybenzimidazole (PBI) and a melamine-formaldehyde polymer, such as methylated, poly(melamine-co-formaldehyde), for forming structures such as films, fibers and bulky structures. The polymer compositions may be formed by combining polybenzimidazole with the melamine-formaldehyde polymer to form a precursor. The polybenzimidazole may be reacted and/or intertwined with the melamine-formaldehyde polymer to form the polymer composition. For example, a stable, free-standing film having a thickness of, for example, between about 5 ?m and about 30 ?m may be formed from the polymer composition. Such films may be used as gas separation membranes and may be submerged into water for extended periods without crazing and cracking. The polymer composition may also be used as a coating on substrates, such as metal and ceramics, or may be used for spinning fibers. Precursors for forming such polymer compositions are also disclosed.

Abstract: This invention provides an embossed release paper that has high heat resistance and embossing properties. The embossed release paper comprises a paper base material, an ionizing radiation-cured resin layer, and a heat-cured silicone layer stacked in that order, the embossed release paper having embosses. The embossed release paper has high heat resistance and thus is suitable for use in synthetic leather production and melamine decorative sheet production that involve surface emboss pattern formation.

Abstract: A corrosive gas resistant laminate comprises an outer polymer layer desirably containing a volatile corrosion inhibitor therein, a corrosion gas resistant barrier layer that can be a hydrophilic polymer, and a tie layer located between said outer and said barrier layers. The various laminates have improved transmission resistance with regard to corrosive gases such as oxygen, hydrogen sulfide, and halogen gases such as chlorine. The laminates can be used to protect metal during storage and transit.

Abstract: A flooring system comprising a carrying panel with edges, said edges being provided with means for joining. The carrying panel is further being provided with an upper side and a lower side. The flooring system comprises a plurality of panels where each panel is provided with an upper decorative surface. The flooring system comprises panels with at least two of decorative surfaces selected from the group consisting of: a thermosetting composite, a thermoplastic composite. an elastomeric foil, a thermoplastic foil, a metal sheet, a fabric, a mineral and a mineral composite.

Abstract: A flooring system comprising a carrying panel with edges, said edges being provided with means for joining. The carrying panel is further being provided with an upper side and a lower side. The flooring system comprises a plurality of panels where each panel is provided with an upper decorative surface. The flooring system comprises panels with at least two of decorative surface selected from the group consisting of a thermosetting composite, a thermoplastic composite, an elastomeric foil, a thermoplastic foil, a metal sheet, a fabric, a mineral and a mineral composite.

Abstract: A polymerization process for producing a tetra-fluoroethylene copolymer, and the copolymer produced thereby, are provided. The copolymer is of the dispersion/fine powder type and contains polymerized tetrafluoroethylene monomer units and co-polymerized higher homologous comonomer units having the formula (CnF(2n+1))CH?CH2, wherein 6?n<10, in which the primary particles are believed to have a core and shell structure and the polymerized comonomer units are present in an amount from 0.01 mol % to 0.3 mol %, based upon total copolymer composition. The copolymer has a raw dispersion primary particle size (RDPS) of less than 0.210 microns coupled with a standard specific gravity (SSG) of less than 2.143. Preferably the copolymer has comonomer units present in an amount from 0.05 mol % and 0.25 mol % and the RDPS is within the range between 0.178 microns and 0.200 microns, coupled with a SSG of less than 2.140.

Abstract: A flooring system comprising a carrying panel with edges, said edges being provided with means for joining. The carrying panel is further being provided with an upper side and a lower side. The flooring system comprises a plurality of panels where each panel is provided with an upper decorative surface. The flooring system comprises panels with at least two of decorative surface selected from the group consisting of a thermosetting composite, a thermoplastic composite, an elastomeric foil, a thermoplastic foil, a metal sheet, a fabric, a mineral and a mineral composite.

Abstract: A sheet material includes a polycarbonate substrate and a protective coating containing the reaction products of an aminoplast resin, a polyol compound, and a UV-absorbing amount of a triazine compound. The sheet material exhibits an improved balance of abrasion resistance, solvent resistance, weatherability, and formability.

Abstract: A polymerization process for producing a tetrafluoroethylene copolymer, and the copolymer produced thereby, are provided. The copolymer is of the dispersion/fine powder type and contains polymerized tetrafluoroethylene monomer units and co-polymerized higher homologous comonomer units having the formula (CnF(2n+1))CH?CH2, wherein 6?n<10, in which the primary particles are believed to have a core and shell structure and the polymerized comonomer units are present in an amount from 0.01 mol % to 0.3 mol %, based upon total copolymer composition. The copolymer has a raw dispersion primary particle size (RDPS) of less than 0.210 microns coupled with a standard specific gravity (SSG) of less than 2.143. Preferably the copolymer has comonomer units present in an amount from 0.05 mol % and 0.25 mol % and the RDPS is within the range between 0.178 microns and 0.200 microns, coupled with a SSG of less than 2.140.

Abstract: Resin compositions, methods of forming such resin compositions, methods of using such resin compositions and substrates treated with such resin compositions are disclosed. One of such resin compositions contains no formaldehyde and is useful as a binder. Such resin composition comprises the reaction product of: a—melamine, b—at least one aldehyde of formula (1) as defined in the specification, c—a cross linking agent, wherein the cross linking agent is glyoxylic acid, and d—at least one polyol having 2 or more than 2 hydroxyl groups. The resin composition of the present invention can provide performance characteristics to which they are applied.

Abstract: Low density microspheres, methods for preparing same, and use of same as contrast agents are described. The microspheres have a void which contains a gas or the vapor of a volatile liquid selected from the group consisting of aliphatic hydrocarbons, chlorofluorocarbons, tetraalkyl silanes and perfluorocarbons.

Abstract: The invention relates to phenol-free decorative laminates, in the form of sheets, such as HPL, CPL and LPL, using multilayer carrier materials in which no phenol resins are used for impregnation and which are therefore toxicologically safe, have a neutral odor and are more economical in their production. The impregnating resin system used is a urea/melamine/formaldehyde resin which was processed exclusively in an aqueous reaction medium and to which a polymer dispersion was added, the impregnating resin having been prepared in a first stage in the pH range from 7.0 to 8.5 and in a second stage in the pH range from 4.0 to 6.0. Finally, this resin batch is neutralized, added to the carrier material and pressed with the latter.

Abstract: The invention relates to phenol-free decorative laminates, in the form of sheets, such as HPL, CPL and LPL, using multilayer carrier materials in which no phenol resins are used for impregnation and which are therefore toxicologically safe, have a neutral odor and are more economical in their production. The impregnating resin system used is a urea/melamine/formaldehyde resin which was processed exclusively in an aqueous reaction medium and to which a polymer dispersion was added, the impregnating resin having been prepared in a first stage in the pH range from 7.0 to 8.5 and in a second stage in the pH range from 4.0 to 6.0. Finally, this resin batch is neutralized, added to the carrier material and pressed with the latter.

Abstract: A composite of a resin member bonded to a vulcanized rubber member is obtained with using a rubber member vulcanized with a radical-generating agent (e.g., an organic peroxide) and a thermoplastic resin having at least 2 atoms, on average, selected from H and S atom per molecule, each atom having not less than 0.006 of an orbital interaction energy coefficient S represented by the following formula (1): S=(CHOMO,n)2/|Ec?EHOMO,n|+(CLUMO,n)2/|Ec?ELUMO,n| ??(1) wherein Ec: an orbital energy (eV) of a radical, CHOMO,n: a molecular-orbital coefficient of a highest occupied molecular orbital (HOMO) of an n-th H or S atom constituting a basic unit of the resin, EHOMO,n: an orbital energy (eV) of the HOMO, CLUMO,n: a molecular-orbital coefficient of a lowest unoccupied molecular orbital (LUMO) of the n-th H or S atom constituting the basic unit of the resin, ELUMO,n: an orbital energy (eV) of the LUMO, and above all represent a value calculated by a semiempirical molecular orbital method MOPACPM3.

Abstract: A polymerization process for producing a copolymer of tetrafluoroethylene and (perfluorobutyl)ethylene, prepared by an aqueous dispersion polymerization technique, and the resin produced thereby, are provided. This copolymer contains a relatively small amount, between about 0.02 weight percent and about 0.6 weight percent, of comonomer polymerization units. The copolymer is believed to be comprised of a core-shell structure wherein the polymerized comonomer units reside primarily within the core. The primary particle size of the copolymer ranges from 0.175 microns to and including 0.203 microns and the standard specific gravity is less than 2.143. This copolymer possesses a unique combination of very small particle size coupled with high molecular weight, a combination not heretofore achieved in tetra-fluoroethylene polymers of the dispersion or fine powder type.

Abstract: Adhesive composition consisting of an aminoplast resin with a free formaldehyde-like compound being present. In particular an adhesive composition consisting of a melamine-urea-formaldehyde resin to which a free formaldehyde-like compound has been added so that F/(NH2)2 is equal to 0.8-1.6. The adhesive is in particular suitable for the preparation of board material by combining in a press cellulose-containing materials with the adhesive according to the invention and in this press manufacturing board material at elevated temperature and pressure.

Abstract: A water-based coating composition suitable for preparing hydrophilic surfaces on various articles is provided which includes a supporting polymer having functional moieties capable of undergoing crosslinking reactions, said supporting polymer soluble in or emulsified in an aqueous based medium; and a hydrophilic polymer, said hydrophilic polymer associated with the supporting polymer. The composition is characterized in that, when crosslinked at the functional moieties, the supporting polymer forms a three-dimensional network which substantially minimizes disassociation of the hydrophilic polymer.

Abstract: A decorative base paper or a preimpregnated decorative base paper is finished with an ink absorbing layer for printing by the ink-jet method.

Abstract: An incombustible resin composition in which a silicone oligomer, a metal hydrate and a resin material are contained as essential components, the metal hydrate is 20% by weight or more in the total solids of the resin composition is provided.

Abstract: Sandwich type board, for application in the construction field, of the type comprised of side and counterside, which has the following successive layers, from the center to the outside: a cellulose core impregnated in phenolic resin, a cellulose film impregnated in melamine, a laminated wood panel treated with phenolic resin, a tone package of one to three translucent and/or transparent films of cellulose, each of them impregnated in a resin to be chosen between melamine, melamine-acrylic, phenolic, melamine-phenolic, a multi-layer transparent/translucent acrylic film and a surface finish obtained by means of a demoulding film in the board press process.

Abstract: The present invention relates to a multilayer coating comprising at least one basecoat layer and one topcoat layer, the coating being preparable by A. applying a component (I), if desired radiation-curable component, based on polyurethane resins, polyacrylate resins, polyester resins and/or amino resins and also mixtures thereof to a substrate and subjecting it to thermal partial crosslinking or drying at temperatures of less than 100° C., preferably 60-80° C., and B. applying a topcoat to this coating layer, and subsequently carrying out radiation curing.

Abstract: The present invention is directed toward compositions that are chemically different after application to a substrate as compared to the composition prior to its application. A method of the invention comprises a method of transitioning a crosslinked polymer composition from a first chemical state to a second chemical state. Advantageously, compositions of the invention are relatively stable after transformation to their altered, or second, chemical state.

Abstract: A process for producing fiberboard panels includes I. gluing cellulosic fibers with an aqueous glue solution and adjusting the moisture content of the cellulosic fibers and/or the water content of the glue such that the moisture content of the glued cellulosic fibers is not more than 150%; and II. compressing the glued cellulosic fibers produced in step (I) at elevated temperature to fiberboard panels.

Abstract: A melamine-urea-formaldehyde resin modified with a cyclic urea prepolymer and sodium metabisulfite. Products prepared with the binder include wood composites such as particleboard and medium density fiberboard.

Abstract: An inorganic porous material, having uniform pores defined by pore walls of crystalline titanium oxide. The inorganic porous material may be produced by heating an organic inorganic mesostructured material containing titanium and having a hexagonal crystal phase at a temperature and for a period of time sufficient to form a porous material having a multiplicity of pores defined by pore walls containing crystalline titanium oxide.

Abstract: Described are articles having an aminoplast resin photochromic coating prepared from an aminoplast resin, components(s) having hydroxyl functional groups and photochromic substances. The coatings exhibit a Fischer microhardness of from 45 to 180 Newtons per mm2 and desirable photochromic properties, i.e., the formation of darker activated colors and faster rates of photochromic activation and fade when irradiated with ultraviolet light. Also described are photochromic aminoplast resin articles.

Abstract: An improved PVOH-based coating solution for application to a polymeric substrate. The coating solution includes poly(vinyl alcohol), a formaldehyde-containing crosslinking agent and a crosslinking-promoting acid catalyst which lowers the pH of the solution to about 3.5 or less and, preferably, to about 3 or less. The coating solution exhibits improved viscosity stability, particularly with the addition of a second acid catalyst. The coating solution also provides improved crosslinking and oxygen barrier characteristics upon drying.

Abstract: The present invention provides a crosslinking agent which may have reactive benzoxazine groups prepared from (a) at least one aromatic compound, (b) at least one aminotriazine compound, and (c) at least one other compound having active hydrogen groups reactive with aminoplast compound (b). The crosslinking agent is essentially free of hydroxyl functionality and has a glass transition temperature of at least 25° C. The present invention is further directed to a method for preparing the above-described crosslinking agent, and a curable powder coating composition comprising a mixture of (A) a polymer having functional groups reactive with aminotriazine and/or benzoxazine groups having a glass transition temperature of at least 30° C.; and (B) the above crosslinking agent. Multilayer composite coating compositions are also provided including a basecoat deposited from a film-forming composition and a topcoat over the basecoat, deposited from the curable powder coating composition described above.

Abstract: Improved anti-reflective coating compositions for use in integrated circuit manufacturing processes and methods of forming these compositions are provided. Broadly, the compositions are formed by heating a solution comprising a compound including specific compounds (e.g., alkoxy alkyl melamines, alkoxy alkyl benzoguanamines) under acidic conditions so as to polymerize the compounds and form polymers having an average molecular weight of at least about 1,000 Daltons. The monomers of the resulting polymers are joined to one another via linkage groups (e.g., —CH2—, —CH2—O—CH2—) which are bonded to nitrogen atoms on the respective monomers. The polymerized compound is mixed with a solvent and applied to a substrate surface after which it is baked to form an anti-reflective layer. The resulting layer has high k values, improved etch rates, and can be formulated for both conformal and planar applications.

Abstract: The present invention is a cellulosic, inorganic-filled plastic composite. The composite includes about 30% to about 70% by weight of the composite of cellulosic material, about 1% to about 20% by weight of the composite of talc, and about 25% to about 40% by weight of the composite of polyethylene. An extruded article and a method of making the cellulosic, inorganic-filled plastic composite are also disclosed.

Abstract: The invention relates to a process for applying a multicoat finish to a substrate surface, comprising the following steps: (1): applying an aqueous basecoat A to the substrate surface, (2): forming a polymer film from the aqueous basecoat A applied in stage (1), (3): applying an aqueous transparent topcoat B to the basecoat film obtained in stage (2), and finally (4); baking the basecoat film and the topcoat film together, wherein the basecoat A comprises at least one hydroxyl-containing binder in aqueous solution or dispersion and a stable aqueous dispersion, prepared with a hydroxyl-containing emulsifier, of a hydrophobicized amino resin, and to substrates coated in accordance with the process of the invention.

Abstract: A composition and adhesive film of a thermosetting resin and a terpolymer of an &agr;-olefin, carbon monoxide and an ethylenically unsaturated carboxylic ester monomer, wherein the melt temperature of the terpolymer is less than the set temperature of the thermosetting resin. The film may be applied to a substrate to provide for an adhesive backing. The film may also be utilized to adhesively bond first and second substrates together.

Abstract: The invention provides a resin composition for a fiber reinforced composite which can be used to produce a prepreg excellent in tackiness, drapability and windability around a mandrel, and also provides a prepreg in which reinforcing fibers are impregnated with a resin composition, and a fiber reinforced composite obtained from them. The resin composition includes a thermosetting resin and a thermoplastic resin with a weight average molecular weight of 200,000 to 5,000,000.

Abstract: An automobile exterior component, having good balance between impact resistance and fluidity and being excellent in coating heat resistance and rigidity, which is prepared by performing urethane coating or melamine coating on a molded article obtained by molding a resin composition which comprises a polyamide resin (A); a grafted polymer (B) prepared by graft polymerizing an aromatic vinyl monomer and a vinyl cyanide monomer in the presence of a diene rubber; an unsaturated carboxylic acid-modified copolymer (C) which has a reduced viscosity of 0.2 to 0.5 dl/g and is prepared by polymerizing an unsaturated carboxylic acid monomer, an aromatic vinyl monomer and a vinyl cyanide monomer; a copolymer (D) prepared by polymerizing an aromatic vinyl monomer and a vinyl cyanide monomer; and talc, wherein the amount ratio of (A), (B), (C) and (D) is in a specific range.

Abstract: The preparation of phenol-formaldehyde and melamine-formaldehyde resin-based binders extended with a cyclic urea-formaldehyde prepolymer and to products prepared using the binders. More particularly, the invention relates to a cyclic urea prepolymer comprising urea, formaldehyde, and ammonia or a primary amine which, when added to a phenol-formaldehyde or melamine-formaldehyde based resin, results in a useful binder for the manufacturer numerous articles.

Abstract: A process is described for preparing a dialkoxyethanal-amine derivative resin low in color by adding low amounts of formaldehyde to the reactants before acidification and heating. The reaction product is also claimed. The composition is useful in a variety of coating and overcoating applications where a brown, yellow or amber color would be aesthetically undesirable.

Abstract: The present invention relates to a modified crosslinkable resin and a composite coating composition or system employing the resin. More particularly, the resin comprises an ethylenically unsaturated monomer or copolymer and para-hydroxybenzoic acid or substituted para-hydroxybenzoic acid, the reaction product thereof subsequently being reacted with a crosslinking agent gives rise to a composition including an ether linkage with a carbon-carbon site ortho to the phenolic hydroxy group.

Abstract: The present invention provides a coating composition capable of forming, on a zinc or zinc alloy plated steel plate subjected to a chromate chemical treatment, a coating film superior in processability, corrosion resistance, adhesive property, impact resistance, scratch resistance, etc. This composition comprises:(A) a polyester resin having a glass transition temperature of -25.degree. C. to 35.degree. C., a number-average molecular weight of 1,000-35,000 and a hydroxyl value of 3-80 mgKOH/g,(B) a melamine resin curing agent which is a methyl-etherified melamine resin, or a mixture of a methyl-etherified mel amine resin and a butyl-etherified melamine resin,(C) a rust preventive pigment, and(D) organic polymer fine particles,wherein the proportions of the individual components are:(A) 60-95 parts by weight,(B) 5-40 parts by weight,(C) 1-50 parts by weight per 100 parts by weight of the total of (A) and (B), and(D) 2-40 parts by weight per 100 parts by weight of the total of (A) and (B).

Abstract: A transparent electrically conductive plate contains a transparent substrate, a transparent electrically conductive layer, an ultraviolet absorbing layer disposed between the transparent substrate and the transparent electrically conductive layer and containing an organic ultraviolet absorber, and an overcoating layer disposed between the transparent electrically conductive layer and the ultraviolet absorbing layer for protecting the ultraviolet absorbing layer.

Abstract: An aqueous composition containing an acid-hardenable melamine-formaldehyde resin and a nitrogen-containing acidic phosphorus curing agent made from either phosphoric acid or phosphorous acid which is curable to an intumescent composition.

Abstract: The present invention provides a retroreflective sheeting including: optical elements arranged in substantially a monolayer; a spacing layer in which the optical elements are at least partially embedded; a specularly reflecting layer underlying the spacing layer; and a bead bond layer in which the optical elements are at least partially embedded. The bead bond layer includes an aminoplast-crosslinked polymer comprising urethane groups, wherein prior to crosslinking the polymer has a glass transition temperature (Tg) of less than about 0.degree. C.

Abstract: Disclosed are coating compositions, wearlayer compositions and surface covering products which utilize wearlayer compositions. The wearlayer compositions of the present invention are capable of at once exhibiting high initial gloss values and excellent resistance to scuff, stain and gloss loss. Such wearlayer compositions are produced utilizing curable coating compositions which comprise thermoplastic polymer, from about 3% by weight to about 25% by weight of plasticizer for the thermoplastic polymer and at least about 30% by weight of reactive crosslinking agent. The weight ratio of the thermoplastic polymer to the crosslinking agent is preferably no greater than about 2:1.

Abstract: A friction material comprises: a thermosetting resin binder; an organic fiber; a non-asbestos inorganic fiber; a filler; and an organic resin coating formed on a scorched surface of the friction material.

Abstract: A receiver sheet for diffusion transfer printing comprising a substrate having thereon a dye receiver layer comprising a dye receptive polymer and the reaction product of a first compound, which is a resin, having at least two reactive functional groups and a second, fluorine containing compound having a single reactive functional group.

Abstract: The present invention relates to a coating composition which is excellent in handling and safety, enables the curing of the resultant coating composition at low temperature, and provides an excellent adhesion to polyolefin resin moldings. The coating composition comprises (1) 40-90 wt. % of a grafted and chlorinated polyolefin oligomer obtained by graft polymerizing a vinyl polymerizable monomer to a chlorinated polyolefin, the grafted and chlorinated polyolefin oligomer having a primary or blocked primary hydroxyl group at a position of 15 to 40 atoms away from the vinyl graft polymer chain grafted to the chlorinated polyolefin, a number average molecular weight of 5,000 to 50,000, 0.4 to 2.5 mole/kg-resin of a primary or blocked primary hydroxyl group, 50 to 95 wt. % of said vinyl graft polymer chain, and 5 to 50 wt. % of the chlorinated polyolefin used as a starting material, and (2) 60 to 10 wt. % of an imino-type, methylol-type or complete alkoxy-type melamine resin.