Phenol-aldehyde Patents (Class 428/506)
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Patent number: 4480012Abstract: An adhesive composition for bonding cured layers of EPDM together is provided which comprises a neutralized sulfonated EPDM elastomeric terpolymer, an organic hydrocarbon solvent or mixture of an organic hydrocarbon solvent and an aliphatic alcohol, a para-alkylated phenol formaldehyde tackifying resin and an alkylphenol or ethoxylated alkylphenol. A method for bonding the cured layers of EPDM together utilizing the adhesive composition is also provided.Type: GrantFiled: March 12, 1984Date of Patent: October 30, 1984Assignee: The Firestone Tire & Rubber CompanyInventor: John W. Fieldhouse
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Patent number: 4450252Abstract: An adhesive composition for bonding cured layers of EPDM together is provided which comprises a neutralized sulfonated EPDM elastomeric terpolymer, an organic hydrocarbon solvent or mixture of an organic hydrocarbon solvent and an aliphatic alcohol, a para-alkylated phenol formaldehyde tackifying resin and an alkylphenol or ethoxylated alkylphenol. A method for bonding the cured layers of EPDM together utilizing the adhesive composition is also provided.Type: GrantFiled: September 30, 1982Date of Patent: May 22, 1984Assignee: The Firestone Tire & Rubber CompanyInventor: John W. Fieldhouse
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Patent number: 4435472Abstract: Acid cured, polymer protective layers are bonded to metal or cement surfaces using a primer coating of an acid stable, thermoplastic elastomer such as a block copolymer of styrene-butadiene.Type: GrantFiled: August 27, 1982Date of Patent: March 6, 1984Assignee: Pennwalt CorporationInventor: George R. Leah
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Patent number: 4409290Abstract: An aqueous alkaline dispersion of a rubbery graft or over polymerized copolymer of a diene and a vinyl pyridine on a polyacrylate seed (core or substrate), said acrylate polymer having a Tg of not above about -20.degree. C., desirably also containing a polybutadiene, and a water soluble, heat reactable phenolic resin, in certain amounts is useful in forming an adhesive for bonding glass fiber reinforcing elements or cords to rubber compounds or stocks. After dipping the glass fiber cord in the one-step adhesive dip, the coated cord is heated to dry it and heat cure or heat set the adhesive on the cord. Thereafter, the adhesive containing glass fiber cord is combined or laminated (calendered) with a curable rubber compound and the resulting assembly is cured to form a composite in which the glass fiber cord is bonded to the rubber by means of said adhesive.Type: GrantFiled: July 22, 1982Date of Patent: October 11, 1983Assignee: The General Tire & Rubber CompanyInventor: Richard M. Wise
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Patent number: 4404252Abstract: A waferboard having at least one surface rendered water resistant and stabilized against wafer loss is disclosed. In the past heavy paper overlays have been used on panel surfaces. However, these paper overlays are specially treated non-porous paper and generally have to be specially applied by the addition of a glue. The waferboard of the present invention is formed of wood wafers bonded together in a hot press with adhesive resin and wax, and having a layer of porous paper bonded in the hot press to at least one surface of the waferboard. In one embodiment, the contours of the wood wafers on the surface of the waferboard are transmitted through the layer of porous paper.Type: GrantFiled: September 16, 1981Date of Patent: September 13, 1983Assignee: MacMillan Bloedel LimitedInventors: Bernard H. Hetzler, Hugh V. Martin
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Patent number: 4396680Abstract: A substrate of either metal or plastic which is coated with a crater resistant enamel coating composition is used for the exterior of trucks and automobiles; the binder of the coating composition is a blend of(A) an acrylic polymer having hydroxy groups and contains about 0.1-10% by weight of a polymerized perfluoro carbon constituent of the formula ##STR1## where R is H or CH.sub.3, R.sup.1 is alkyl, R.sup.2 is perfluoro alkyl and n is 0 or 1 and(B) an aminoplast crosslinking agent such as an alkylated melamine formaldehyde resin;The composition is applied and baked by conventional techniques, to form a finish on the substrate that has an excellent appearance.Type: GrantFiled: November 18, 1981Date of Patent: August 2, 1983Assignee: E. I. Du Pont de Nemours and Co.Inventor: David C. Chang
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Patent number: 4365001Abstract: There are obtained laminates of improved fire resistance comprising a substrate of reinforced phenolic resin, directly coated on at least one side thereof with a surface layer of a furan resin, and bonded to the outer surface of the furan resin a "gel-coat" of an unsaturated polyester resin, wherein the furan resin contains boron in sufficient amounts to impart an improved fire resistance to the laminates as compared to the fire resistance of the outer surface gel-coat. The boron is introduced as boric anhydride by use of a substantially anhydrous boric anhydride hardener solution to harden the furan resin.Type: GrantFiled: April 22, 1981Date of Patent: December 21, 1982Assignee: Societe Chimique Des CharbonnagesInventors: Nicolas Meyer, Michel Cousin
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Patent number: 4360560Abstract: A base material for the production of printed circuits according to the additive method includes a laminate base made up of laminated-together core sheets impregnated with hardenable resin, and a cover layer made up of a substrate sheet preimpregnated with phenolic resol resin and provided with an adhesive layer of an elastomeric polymer. The preimpregnated substrate sheet is also provided with a further resin impregnation containing a self-crosslinking copolymer of acrylic monomers and up to 30% by weight of a hardenable phenolic resol resin.Type: GrantFiled: March 8, 1979Date of Patent: November 23, 1982Assignee: Dynamit Nobel AktiengesellschaftInventors: Siegfried Kopnick, Dirk Huthwelker, Arnold Franz, Lothar Jacob
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Patent number: 4308367Abstract: Polymerizable compositions comprise(a) a compound containing in the same molecule both at least one phenolic hydroxyl group and at least two groups chosen from allyl, methallyl, and 1-propenyl groups, e.g., 2,2-bis(3-allyl-4-hydroxyphenyl)propane or bis(3-(1-propenyl)-4-hydroxyphenyl)methane,(b) a compound containing at least two mercaptan groups per molecule, e.g., pentaerythritol tetrathioglycollate, and(c) a heat-activated crosslinking agent for phenol-aldehyde novolac resins.The compositions are caused to polymerize by the action of irradiation of free-radical catalysts. The polymers so obtained, containing more than one phenolic hydroxyl group, can be subsequently crosslinked in situ by heating. The compositions are useful in various two-stage operations, such as the production of multilayer printed circuits.Polymerizable compositions may also comprise(d) a compound as (a) but containing at least two phenolic hydroxyl groups,(e) a compound containing more than two mercaptan groups per molecule.Type: GrantFiled: January 19, 1979Date of Patent: December 29, 1981Assignee: Ciba-Geigy CorporationInventors: George E. Green, Abdul-Cader Zahir
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Patent number: 4283462Abstract: In reinforced phenolic resin laminates coated with a surface layer on at least one side, the improvement wherein said surface layer consists essentially of a furan resin coating which is directly bonded to the reinforced phenolic resin laminate, thereby removing surface irregularities in the resultant laminate.Type: GrantFiled: January 24, 1980Date of Patent: August 11, 1981Assignee: Societe Chimiques des CharbonnagesInventors: Nicolas Meyer, Leon Schuller
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Patent number: 4275108Abstract: The present invention relates to a leader or trailer tape for a magnetic tape, which comprises a plastic support member and, on one side thereof, a laminated coating consisting of at least (1) an electrically conductive layer as a first layer and (2) a layer containing mainly a pigment and a binder as a second layer.Type: GrantFiled: October 9, 1979Date of Patent: June 23, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobutana Yamaguchi, Satoru Takayama, Masahiro Utumi, Masaaki Fujiyama
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Patent number: 4272581Abstract: A low pressure heat resistant decorative laminate material comprises a wood base member directly secured to a decorative plastic film by an adhesive having aluminum powder dispersed therein.Type: GrantFiled: August 27, 1979Date of Patent: June 9, 1981Inventors: James Cooley, Ozzie Fogle
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Patent number: 4269321Abstract: A peelable bonded structure having a peel strength of 0.05 to 5 kg/cm comprises a plurality of articles, at least one of which is made of metal, bonded together through a composite coating layer. The composite coating layer is composed of adjacent first and second coating layers at least one of which comprises (A) a modified olefin resin having a carbonyl group concentration of 0.01 to 200 milliequivalents per 100 g of the olefin resin and (B) a coating film-forming base resin at an (A)/(B) weight ratio of from 0.2/99.8 to 40/60 and has a multi-layer distribution structure having resin concentration gradients in the thickness direction such that the modified olefin resin (A) is distributed predominantly in the portion contiguous to the interface between the two coating layers and the base resin (B) is distributed predominantly in the opposite portion.Type: GrantFiled: November 28, 1978Date of Patent: May 26, 1981Assignee: Toyo Seikan Kaisha, Ltd.Inventors: Isao Ichinose, Fumio Mori, Noboru Suzuki
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Patent number: 4255486Abstract: The strength of the bond obtained between substates with the aid of phenoplasts, modified phenoplasts and/or epoxy resins, e.g. between fibrous material and an elastomer on vulcanization thereof, is improved by applying, to at least one of the substrates, in addition to a preformed phenoplast, modified preformed phenoplast, and/or preformed epoxy resin, and drying thereon before the assembly thereof with the other substrate, as an adhesion promoter, a quantity of m-aminophenol, which may be blended in a phenoplast adhesive, such as an RF dip or an RFL dip, or may be blended in the elastomer latex used for forming an RFL dip. Adhesive/promoter blends and latex/promoter blends for forming the same are also disclosed.This is a divison of application Ser. No. 951,040, filed October 13, 1978, now abandoned, which in turn is a division of Ser. No. 754,182, filed December 29, 1976, now U.S. Pat. No. 4,131,584 which in turn is a division of Ser. No. 422,777, filed December 7, 1973, now U.S. Pat. No.Type: GrantFiled: October 11, 1979Date of Patent: March 10, 1981Assignees: Marion Darrah, Joseph Y. HoughtonInventors: Oliver W. Burke, Jr., Barbara P. Hunt
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Patent number: 4244845Abstract: A pre-mixed adhesive composition comprised of a vinyl acetate co-polymer emulsion including a cross-linking catalyst and a cross-linking inhibitor providing a good cured water resistant Type II bond and extended shelf life so that the adhesive composition will not gel over an extended period of time and will therefore be usable for direct gluing application to semi-porous and porous substrates.Type: GrantFiled: February 13, 1978Date of Patent: January 13, 1981Assignee: National Casein of New JerseyInventor: Ming C. Woo
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Patent number: 4241139Abstract: A magnetic recording medium which has a protective layer on a magnetic recording layer coated on a substrate and said protective layer comprises polyurethane and nitrocellulose in which isopropyl alcohol originally present has been replaced by a resin selected from the group consisting of polyurethane resins, polybutadiene resins, butadiene-acrylonitrile copolymers, vinyl chloride-vinyl acetate-vinyl alcohol copolymers, vinyl chloride-vinyl acetate copolymers, vinyl chloride-vinylidene chloride copolymers, vinylidene chloride-acrylonitrile-copolymers, vinyl acetate resins, epoxy resins, phenoxy resins, polyvinylbutyral resins, polyvinyl formal resins and polyester resins.Type: GrantFiled: April 5, 1979Date of Patent: December 23, 1980Assignees: TDK Electronics Co., Ltd., Tokyo Magnetic Printing Co., Ltd.Inventors: Yuichi Kubota, Tsunayoshi Saito, Yoshiaki Makino
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Patent number: 4238341Abstract: A composition of magnetic recording media consisting of a ferromagnetic powder such as .gamma.-Fe.sub.2 O.sub.3, a binder and single crystal alumina as a reinforcing agent. Single crystal .alpha.-alumina is preferably used as said single crystal alumina and its amount is preferably from 1 to 20% by weight based on the magnetic powder.Type: GrantFiled: October 12, 1979Date of Patent: December 9, 1980Assignee: Hitachi, Ltd.Inventors: Yoshiki Kato, Heigo Ishihara, Hajime Fukke, Katsuyoshi Chiba, Waichi Nagashiro, Teruo Tsunoda, Munehisa Mitsuya
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Patent number: 4182791Abstract: A composite body having a portion of a thermosetting material and a portion of a thermoplastics material is formed by including a layer of fabric having a serrated surface between the two portions as a connecting means. The fabric with its serrated surface facing outwards is applied to an area of a thermosetting material after which a thermoplastics material in particulate form is intimately mixed into the serrations of the fabric. The composite body, such as a weaving shuttle, is then pressed, fused and cured.Type: GrantFiled: March 24, 1978Date of Patent: January 8, 1980Inventors: Otto Meyering, Wilhelm Schmidt
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Patent number: 4173594Abstract: A thermosetting coating composition comprising the organic solvent-soluble reaction product formed by contacting at an elevated temperature at least one blocked isocyanate-functional urethane and at least one organic solvent-soluble phenolic resin, and, optionally, at least one blocked isocyanate-functional urethane. The compositions are storage-stable for extended periods and cure to a thermoset state to afford tough, durable, flexible finishes which are resistant to cracking, staining, and marring.Type: GrantFiled: February 24, 1975Date of Patent: November 6, 1979Assignee: Lord CorporationInventor: Zygmunt D. Dyszlewski
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Patent number: 4139671Abstract: In a bowling lane having a decorative laminate surface, an internal lubricant in the resin for the laminate surface obviates the need for oil treatment or conditioning of the surface.Type: GrantFiled: September 16, 1977Date of Patent: February 13, 1979Assignee: General Electric CompanyInventors: Peter B. Kelly, Donald G. Pucci
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Patent number: 4136228Abstract: This invention relates to industrial laminates which can be cold punchable and are flame resistant. The laminates are prepared from paper impregnated with a composition comprising a phenol-formaldehyde resole resin and a vinyl chloride interpolymer.Type: GrantFiled: August 8, 1977Date of Patent: January 23, 1979Assignee: Monsanto CompanyInventor: Ronald H. Dahms
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Patent number: 4074014Abstract: The specification discloses noncracking permanent adhesives which utilize mixtures of phenolic resins and methacrylate resins having a Mw greater than about 100,000 and preferably about 400,000 bonding plasticized vinyl resin coverings, e.g., PVC, to hard polymeric substrate surfaces such as ABS, etc. Also, it is preferable that the vinyl resin covering contain plasticizers which are no more than limited in compatibility with the adhesive. It is theorized that the adhesive mixture prevents migration of plasticizer from the plasticizer-containing vinyl resin covering into the adhesive and eventually into the polymeric substrate.Type: GrantFiled: January 6, 1976Date of Patent: February 14, 1978Assignee: Leon Chemical & Plastics, Division of U.S. Industries, Inc.Inventor: Carl H. Wollen
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Patent number: 4064299Abstract: Disclosed are heat-transmitting, anti-friction composites useful for example to reduce sliding friction between the stationary platens and moving belts of continuous hot presses used in the manufacture of consolidated board-like products such as fiberboard. In the disclosed embodiment, the composite comprises a brass sheet perforated in such a manner as to form a multiplicity of rigid prongs projecting transversely from one of its faces. An overlay sheet comprised of polytetrafluoroethylene or other solid lubricant is impaled on the prongs and adhesively bonded to the face of the brass sheet from which the prongs project. The prongs serve to inhibit the tendency of the overlay sheet to undergo plastic flow when subjected to stresses such as are caused by a belt sliding over it. The prongs also serve as paths for efficiently conducting heat through the overlay sheet.Type: GrantFiled: October 2, 1975Date of Patent: December 20, 1977Assignee: Formac International, Inc.Inventor: Ronald T. Martin
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Patent number: 4045595Abstract: Panels are provided with a glossy, tough coating by a method comprising the steps of applying on the panel surface a conventional resin adhesive; spreading thereon vinyl-modified lignocellulosic particles made by polymerization of vinyl monomers on substrate lignocellulosic particles; and subjecting the assembly to heat and pressure. Over a wide range of add-on ratio of vinyl polymer to lignocellulosic particles, coatings can be produced which have neither the solvent sensitivity of the polymer nor the water sensitivity of the cellulose. The novel, esthetically pleasing marbleized appearance is heightened by the use of dyed particles.Type: GrantFiled: January 20, 1976Date of Patent: August 30, 1977Assignee: The Borden Chemical Company (Canada) LimitedInventors: Shui-Tung Chiu, William Melvin Turko
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Patent number: 4029845Abstract: A base board for printed circuits prepared by the additive process, obtained by heating under pressure a layer comprising at least one sheet of prepreg comprising a thermosetting resin as impregnant and a layer of composition comprising a semi-cured thermosetting resin and a nitrile rubber, said layer of composition being placed on one or both sides of said prepreg layer to integrate said layers as a finished laminate. This base board is used in the additive process for manufacturing a printed circuit board having favorable properties with strong adhesion between the circuit and the base board without showing any warp or twist.Type: GrantFiled: August 12, 1975Date of Patent: June 14, 1977Assignees: Sumitomo Bakelite Company, Limited, Nomura Electroplating Company, Ltd.Inventor: Hirotoshi Nomura
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Patent number: 3991027Abstract: An aqueous alkaline dispersion of a rubbery vinyl pyridine copolymer, trimethylol phenol, and a resorcinol compound, in certain amounts is useful in forming an adhesive for bonding polyamide or nylon cords to rubber compounds or stocks. After dipping the cord in the adhesive dip, the coated cord is heated to dry it and heat cure or heat set the adhesive on the cord. Thereafter, the adhesive containing cord is combined or laminated (calendered) with a curable rubber compound and the resulting assembly is cured. High H-adhesions are obtained with this one-step or single treatment coating dip. It is particularly useful for bonding crystalline polyamides having a large number of aromatic groups in the polymeric structure, e.g., "Fiber B.Type: GrantFiled: December 9, 1974Date of Patent: November 9, 1976Assignee: The General Tire & Rubber CompanyInventors: Gerard E. van Gils, Edward F. Kalafus
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Patent number: 3955036Abstract: Adhesion of thermoplastic elastomers, such as unvulcanized styrene-butadiene rubber, to a solid substrate is obtained by using a primer containing a tackifier component, such as hydrogenated rosin or a coumarone-indene resin, and an amino-functional trihydrolyzable silane, partial condensates and hydrochloride salts thereof in which the amino-functionality is in the form of a primary or secondary amine.Type: GrantFiled: November 19, 1973Date of Patent: May 4, 1976Assignee: Dow Corning CorporationInventor: Edwin P. Plueddemann
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Patent number: 3932559Abstract: Halogenated olefin copolymer rubber, particularly halogenated EPDM (prepared by heating the rubber in admixture with an N-haloamide [e.g., 1,3-dichloro-5,5-dimethyl hydantoin or N,N'-dichloro-p-toluene sulfonamide]) is blended with curatives (sulfur, accelerator) and a resorcinol-aldehyde condensation product in which the aldehyde has 2-4 carbon atoms (e.g., acetaldehyde) to make a vulcanizable adhesive for nylon textile. Nylon fabric coated with the composition is useful for making air bags (passive restraints for automotive vehicles). The adhesive is also useful for making nylon-reinforced tires, hose, etc.Type: GrantFiled: January 25, 1974Date of Patent: January 13, 1976Assignee: Uniroyal Inc.Inventors: Stephen E. Cantor, Arthur A. Blaskiewicz
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Patent number: RE30573Abstract: A crown closure having a polyolefin liner that can be readily removed, said crown closure comprising a crown shell having a primer layer on its inner surface and a polyolefin liner applied to the inside of said crown shell, characterized in that said primer layer is a two-component priming consisting of an undercoat layer containing .[.a polyethylene oxide.]. .Iadd.an oxidized polyethylene .Iaddend.and a topcoat layer containing .[.a polyethylene oxide.]. .Iadd.an oxidized polyethylene .Iaddend.and at least one other compatible resin, with the provision of a printing layer of indicia at the interface between said undercoat and topcoat layers or atop said topcoat layer. Aforesaid crown closure can be prepared by providing at one face of a metal stock sheet a primer undercoat layer containing .[.a polyethylene oxide.]. .Iadd.an oxidized polyethylene.Iaddend., printing indicia thereon, providing atop said undercoat layer a primer topcoat layer containing .[.a polyethylene oxide.]. .Iadd.Type: GrantFiled: September 18, 1979Date of Patent: April 14, 1981Assignee: Japan Crown Cork Co., Ltd.Inventors: Isao Ichinose, Mitsuhiro Sakemoto, Noboru Suzuki