Next To Polyene Polymer Patents (Class 428/517)
  • Patent number: 5346736
    Abstract: A magnetic tape cassette in which critical parts subject to wear are coated with a hard coating such as an ultraviolet-cured resin. Among other effects, the generation of rubbed-off powder is reduced, thereby reducing the amount of data drop-out. Also, the case of the cassette is protected from damage.
    Type: Grant
    Filed: December 15, 1992
    Date of Patent: September 13, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masato Mizuno, Kengo Oishi
  • Patent number: 5346759
    Abstract: A decking structure 30 includes a bottom layer 16 of UHMWP, an elastomeric layer 18 disposed on the bottom layer, an intermediate UHMWP layer 22 disposed on the elastomeric layer, and a top UHMWP layer 24 abrasive particles and having a pattern 32 provided therein by increasing the traction thereof. A pattern of cavities is provided in the elastomeric layer 18 and the bottom layer 16 for improving the shock absorption capabilities of the decking structure 30.
    Type: Grant
    Filed: May 26, 1992
    Date of Patent: September 13, 1994
    Assignee: The B. F. Goodrich Company
    Inventor: Robert J. Will
  • Patent number: 5346760
    Abstract: A composite material comprising at least two elastomer layers, the first layer having a first composition comprising from 40 to 80 percent by weight of silicone rubber, the second layer having a second composition comprising from 50 to 100 percent by weight of rubber of the ethylene-propylene copolymer and/or terpolymer type, wherein the first composition further contains from 20 to 60 percent by weight of rubber of the ethylene-propylene copolymer and/or terpolymer type, and each of the two compositions contains more than 5 percent, and preferably from 5 to 60 percent, by weight of silica.
    Type: Grant
    Filed: January 23, 1992
    Date of Patent: September 13, 1994
    Assignee: Total Ruffinage Distribution S.A.
    Inventors: Guy Lemoine, Etienne Benard, Christian Exandier
  • Patent number: 5340208
    Abstract: A refrigerator cabinet is provided with a plastic liner, the inside wall of the refrigerator, which is resistant to chemical degradation by fluorocarbons. Freon and Freon substitutes used as blowing agents for foaming the insulation contained between an outer metal cabinet and on the inside wall of the refrigerator can cause blistering, cracking, and sometimes dissolution of materials used to form the plastic liner which is the inside wall of the refrigerator. There is provided a plastic liner which is resistant to those blowing agents and particularly to those blowing agents which are partially halogenated and tend to be more aggressive than Freon. The plastic liner wall maintains impact strength and toughness after exposure to fluorohydrocarbons conventionally employed in refrigerator units for in situ polyurethane foam production.
    Type: Grant
    Filed: June 16, 1993
    Date of Patent: August 23, 1994
    Assignee: BASF Corporation
    Inventors: Steven M. Hauck, Jeffrey P. Viola
  • Patent number: 5334458
    Abstract: The present invention provides a non-rusting unitary co-extruded article, which may be used for a variety of purposes, including a seal. The co-extruded article is comprised of at least two dissimilar discrete parts such as a rubber component, referred to herein as the "rubber extrudate," and a thermoplastic component, referred to herein as the "plastic extrudate." A particular advantage of the invention is that the rubber extrudate and thermoplastic extrudate are cohesively joined at their interface. By cohesively joined, it is meant that the two extrudates stick together tightly without the necessity of a separate adhesive. Where hardness is desired of the thermoplastic extrudate, ethylene vinyl acetate is generally preferred. Where a seal is desired, the rubber extrudate comprises ethylene propylene diene rubber, which provides a suitable seal. The invention also relates to a method for making the same.
    Type: Grant
    Filed: April 23, 1992
    Date of Patent: August 2, 1994
    Assignee: Geauga Company
    Inventors: Thomas O. Powers, Timothy T. Hertrick, Mary A. Peak
  • Patent number: 5330832
    Abstract: A water soluble pressure sensitive adhesive composition is disclosed wherein polyvinyl methyl ether is the major component and a styrenic block copolymer is the second component, the polyvinyl methyl ether and styrenic block copolymer present in a weight ratio of from about 95:5 to about 88:12, said styrenic block copolymer in said composition comprising less than about 14 percent by weight of the weight of the polyvinyl methyl ether. The pressure sensitive adhesive is useful for bonding polyethylene, polypropylene, ethylene-propylene copolymers, and paper.
    Type: Grant
    Filed: March 22, 1993
    Date of Patent: July 19, 1994
    Assignee: Amoco Corporation
    Inventor: Wen-Feng Liu
  • Patent number: 5330812
    Abstract: A composite material comprising a base liner with a release layer on at least one surface thereof, and a releasable face layer releasably adhered to the base liner through the release layer by a pressure sensitive adhesive, wherein the base liner has a skin layer on its surface proximate to the release layer which is more difficult to cut than the remainder of the base liner material, such that when the composite is subjected to die cutting or perforating to allow portions of the face layer to be selectively removed, the cutter will not penetrate into or through the base liner to any substantial extent.
    Type: Grant
    Filed: April 13, 1992
    Date of Patent: July 19, 1994
    Assignee: Mobil Oil Corp.
    Inventors: Anthony R. Knoerzer, Pang-Chia Lu, Conway F. Shields, Donald G. Whyman
  • Patent number: 5318839
    Abstract: There is disclosed a laminate comprising (a) a layer of a styrenic polymer having a higher degree of syndiotactic configuration and a crystallinity of at least 25%, preferably 35%, (b) a layer of paper and optionally (c) an adhesive layer and (d) a barrier layer. The above laminate is excellent in heat resistance, hydrolytic resistance, tearability, dead foldability and gloss and can find a wide range of effective application.
    Type: Grant
    Filed: February 6, 1992
    Date of Patent: June 7, 1994
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Yosuke Arai, Yuichi Oki, Eiji Maemura, Keisuke Funaki
  • Patent number: 5316861
    Abstract: The invention relates to a method for fabricating coverings for floors or walls and to such coverings comprising at least an upper sheet (21), a lower sheet (23) charged and made flexible, and a decoration interleaved between said sheets, substantially comprised of a material derived from propylene polymer.
    Type: Grant
    Filed: June 6, 1991
    Date of Patent: May 31, 1994
    Assignee: Sommer S.A.
    Inventors: Daniel Marchal, Dung V. Dao
  • Patent number: 5316835
    Abstract: A multi-layer insulation product which achieves low emissivity values by using at least one layer of metallic foil. The metallic foil (25, 29) is used at exterior locations of the insulation product by way of novel strengthening means positioned below said metallic foil. A central layer of foamed material (21) adds to the insulative effect. The strengthening features of the invention allow use of the insulation product on exterior locations which has not heretofore been possible in the art.
    Type: Grant
    Filed: November 16, 1992
    Date of Patent: May 31, 1994
    Inventors: Cory L. Groft, Thomas W. Dauber
  • Patent number: 5316848
    Abstract: The present invention relates to a waterproofing membrane comprising a carrier, a synthetic adhesive coated on one face of the carrier substrate, and a protective layer coated on the synthetic adhesive. The present invention also relates to a method of waterproofing post cast concrete structures comprised of affixing a carrier to the inside of a concrete form and post casting concrete, wherein the carrier further comprises a synthetic adhesive coated with a protective coating. Furthermore, the present invention relates to post cast concrete structures comprising a waterproofing membrane adhered to all or part of the exposed surface of said structure, wherein said membrane comprises a carrier, a synthetic adhesive coated on one face of the carrier substrate, and a protective coating on the synthetic adhesive and wherein the protective coating face contacts said structure.
    Type: Grant
    Filed: August 17, 1992
    Date of Patent: May 31, 1994
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Keith R. Bartlett, Robert F. Jenkins
  • Patent number: 5312669
    Abstract: A thermoplastic composite reinforcing sheet material useful for reinforcing orthotic devices and other articles, such as a prosthetic socket or a ski boot. The composite sheet material consists of a plurality of layers. Two layers form outer opposed sides of the sheet and are made from a thermoplastic material. The core of the sheet consists of a plurality of fiber-containing layers. Each layer is impregnated with a thermoplastic resin which will bond with the outer thermoplastic layers when the final shape is vacuum thermoformed. The orientation of the fibers in the core may be varied to change the strength and rigidity of the composite thermoplastic reinforcing sheet. An orthotic device can be built using a thermoplastic host material and the disclosed thermoplastic composite reinforcing sheet material. The host material defines the overall shape of the orthotic device and is any thermoformable thermoplastic. The reinforcing sheet is used to reinforce desired sections of the final orthotic device.
    Type: Grant
    Filed: January 3, 1992
    Date of Patent: May 17, 1994
    Assignee: Becker Orthopedic Appliance Company
    Inventor: Gary Bedard
  • Patent number: 5306548
    Abstract: A coextruded weatherable film for lamination to an underlying nonweatherable substrate, including, for example, a two-layer film structure including an outer layer of a weatherable polymer that provides weather resistance such as ethylene/propylene/nonconjugated diene-reinforced styrene/acrylonitrile copolymer (AES) or butyl acrylate-reinforced styrene/acrylonitrile copolymer (ASA), coextruded over a thermoplastic underlying layer, for example, of a carbon black pigmented, UV stabilized polymer such as chlorinated polyethylene that provides UV protection for an underlying substrate such as vinyl siding or polymer layers.
    Type: Grant
    Filed: May 20, 1992
    Date of Patent: April 26, 1994
    Assignee: The Dow Chemical Company
    Inventors: Vincent S. Zabrocki, Robert H. Kelch
  • Patent number: 5306537
    Abstract: A low friction wear resistant coating for the base of a glass run channel and method. A thermoplastic powder is applied to a thermoset rubber substrate. The combination is heated to form free form shaped domains of thermoplastic on the thermoset rubber.
    Type: Grant
    Filed: December 20, 1991
    Date of Patent: April 26, 1994
    Assignee: The Standard Products Company
    Inventors: Thomas L. Gustafson, Lou Citarel
  • Patent number: 5302463
    Abstract: According to the present invention, there is provided a thermoplastic elastomer laminate which comprisesa layer comprising a thermoplastic elastomer (A) composed of a crystalline polyolefin and a rubber, anda layer comprising an ultra-high molecular weight polyolefin (B) or an ultra-high molecular weight polyolefin composition.In addition, a glass run channel composed of the thermoplastic elastomer laminate is also provided in the invention.
    Type: Grant
    Filed: April 22, 1992
    Date of Patent: April 12, 1994
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Kazuhiko Murata, Norishige Murakami, Kyooji Muraoka, Noboru Sakamaki
  • Patent number: 5300363
    Abstract: A water-based coating composition and methods of making and using the same are disclosed. The composition includes a halogenated resin, a polyol, a surfactant, and an amine. It is suitable for coating a variety of substrates including polyolefinic substrates such as polypropylene, and operates without aromatic organic solvents.
    Type: Grant
    Filed: February 22, 1993
    Date of Patent: April 5, 1994
    Assignee: A-Line Products Corporation
    Inventors: Alger E. Laura, Ronald J. Easton, Kurt C. Frisch, Han X. Xiao
  • Patent number: 5296304
    Abstract: A laminate film for stretch-wrapping is disclosed, comprising an intermediate layer containing from 50 to 95% by weight of an ethylene-.alpha.-olefin copolymer, a propylene-ethylene-.alpha.-olefin random copolymer, a propylene-.alpha.-olefin random copolymer, a butene-1 homopolymer, or a butene-1-ethylene copolymer and from 5 to 50% by weight of a hydrogenated block copolymer elastomer having laminated on both sides thereof a surface layer comprising from 75 to 95% by weight of ethylene and from 5 to 25% by weight of vinyl acetate. The film is excellent in stretchability, softness, tear strength, and in particular deformation recovery properties.
    Type: Grant
    Filed: February 5, 1992
    Date of Patent: March 22, 1994
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Takao Yazaki, Masataka Noro, Takashi Matsui
  • Patent number: 5292560
    Abstract: A thermoplastic film is provided which is especially suitable for use in stretch/.cling applications such as, for example, the bundling, packaging and unitizing of foods and other goods. The film comprises a cling layer comprising a polymer of at least ethylene and acrylate, preferably without a tackifying additive. The film further comprises a slip layer comprising a polyolefin preferably including an anticling (slip and/or antiblock) additive. Preferred polyolefins include linear low density polyethylene and polypropylene.
    Type: Grant
    Filed: December 6, 1990
    Date of Patent: March 8, 1994
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Paul M. German
  • Patent number: 5286576
    Abstract: Impact resistant and flame retardant polymer composition, slab-like rectangular solid made of said composition, and composite laminate article having at least one layer of said composition. The polymer composition comprises a maximum of 86 volume percent of ultra high molecular weight polyethylene (UHMWPE), a minimum of 4.40 volume percent of a flame retardant additive or mixture thereof, and a minimum of 6 volume percent of chopped reinforcing fibers, all volumes referring to the densified (molded) state. In addition the bulk volume of the chopped reinforcing fibers, as measured by a tapped density test, must be a minimum of 27 percent of the final molded volume of the composition. The maximum volume % loading of the additives is limited by the requirement that the notched Izod impact strength is a minimum of 7 ft.-lb per inch width.
    Type: Grant
    Filed: September 12, 1991
    Date of Patent: February 15, 1994
    Assignee: The B. F. Goodrich Company
    Inventors: Raymond C. Srail, Richard A. Glover, Roy L. Orndorff, Jr.
  • Patent number: 5284694
    Abstract: An embossable sheet, having at least one stress-whitening layer comprising a blend of:a) at least one heat-stable polymer selected from the group consisting of polypropylene and a polymethyl alkene, said alkene having from about 3 to about 7 carbon atoms,b) at least one other polymeric material immiscible therewith, andc) an effective amount of an antioxidant, said sheet exhibiting stress-whitening which is stable at 136.degree. C. for at least about 7 days.
    Type: Grant
    Filed: August 25, 1992
    Date of Patent: February 8, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Rochelle L. Lockridge, Dennis L. Krueger, Philip G. Martin, Gary W. Schlaeger
  • Patent number: 5283127
    Abstract: Multilayer, sealable plastics films essentially consist ofA: a top layer A of a polymer which is dimensionally stable at elevated temperatures and has a melting point above 200.degree. C.,B: an adhesion promoter B of from 30 to 95% by weight of a styrene/butadiene block copolymer, up to 95% by weight of polystyrene and/or high impact polystyrene and from 5 to 70% by weight of a polymer which is incompatible with polystyrene and contains polar groups, the percentages being based on B,C: a substrate layer C of from 5 to 100% by weight of a styrene/butadiene block copolymer and up to 95% by weight of polystyrene and/or high impact polystyrene,D: if required, a barrier layer D which may correspond to the top layer A andE: a sealing layer E whose composition essentially corresponds to that of the adhesion promoter B.
    Type: Grant
    Filed: July 17, 1992
    Date of Patent: February 1, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Uwe Blumenstein, Dietmar Bender, Helmut Jenne
  • Patent number: 5277971
    Abstract: A film useful in tamper-evident pressure sensitive label applications comprises a blend of incompatible polymers wherein the film is melt extrusion cast and has a cohesive strength less than the adhesive strength of an adhesive material bonded to one surface of the film. The adhesive material has an adhesive strength greater than the cohesive strength of the film so that when the tamper-evident pressure sensitive label has been adhered to a substrate attempted tampering or removal of the label causes at least partial destruction of the film.
    Type: Grant
    Filed: May 22, 1992
    Date of Patent: January 11, 1994
    Assignee: Tredegar Industries, Inc.
    Inventors: Tung Y. Weng, Carl D. Ray
  • Patent number: 5273797
    Abstract: A seal layer for use in heat sealed containers, especially retortable polymer containers. A semirigid or rigid packaging container with a multilayer laminate heat sealed to a tray flange, the laminate having a barrier layer and the lidding being easily opened by cohesive failure of a layer containing as elastomer. The elastomer is preferably PIB in a heat seal film layer on a polypropylene tray.
    Type: Grant
    Filed: January 16, 1990
    Date of Patent: December 28, 1993
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Donald R. Hazelton, Lawrence K. Locke
  • Patent number: 5271976
    Abstract: A tubular multilayer film including at least two, biaxially stretched tubular layers each formed of a polypropylene resin, wherein the innermost layer contains spherical antiblocking agent particles having an average particle size of 0.2 to 5 .mu.m in an amount of 0.1 to 0.7% by weight, and the outermost layer is free of the spherical antiblocking agent particles is disclosed. The multilayer film may be prepared by biaxially stretching a multilayer tubular raw sheet having an innermost polypropylene layer containing spherical antiblocking agent particles and an outermost polypropylene layer free of such antiblocking agent particles.
    Type: Grant
    Filed: April 19, 1991
    Date of Patent: December 21, 1993
    Assignees: Okura Industrial Co., Ltd., Sumitomo Chemical Company, Limited
    Inventors: Kazuo Kondo, Nobuya Ishiguro, Toyoki Wano, Teruo Tada, Teruaki Yoshida
  • Patent number: 5268203
    Abstract: The invention relates to a process of thermoforming thermoplastic substrates. More particularly the method of the invention relates to a method of thermoforming thermoplastic substrates wherein an integral coating is formed on the thermoplastic substrate that is resistant to removal of the coating. The novel coating method of the invention produces coated thermoplastic substrates wherein the coating is intimately bonded to the substrate. The coated substrates are hard, abrasion resistant, mold resistant, chemically resistant, and solvent resistant. The coating composition employs in a solvent base a pigment and a thermoplastic material compatible with the to be coated thermoplastic substrate. The thermoplastic material in cooperation with the pigment, solvent and other components of the coating composition after coating on the thermoplastic substrate, are heated to a thermoforming temperature and the thermoplastic material is intimately fused to the thermoplastic substrate surface.
    Type: Grant
    Filed: September 18, 1992
    Date of Patent: December 7, 1993
    Assignee: H. B. Fuller Company
    Inventor: Vernon H. Batdorf
  • Patent number: 5266399
    Abstract: A pressure-sensitive adhesive that can adhere aggressively to both polar and nonpolar substrates and has good internal strength at high temperatures is provided by heat or radiation curing a blend of an ethylenically-unsaturated .alpha.-olefin polymer, a crosslinker having at least 2 hydrosilyl groups, and a hydrosilation catalyst. A preferred hydrosilane crosslinker has the formula ##STR1## wherein R is an alkyl group having 1-6 carbon atoms, and n' is a number in the range of 2 to 35.
    Type: Grant
    Filed: January 26, 1993
    Date of Patent: November 30, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Gaddam N. Babu, Larry D. Boardman
  • Patent number: 5264280
    Abstract: This invention relates to a multilayer thermoformable structure comprising (A) at least one cap layer and (B) at least one core layer, and polymer compositions for making the same. The multilayer structures and polymer compositions of the invention are useful in preparing thermoformed articles and are particularly useful in preparing liners for refrigerators and freezers. The multilayer structures and the polymer composition have good thermoformability and chemical resistance. The multilayer structures and the polymer composition have good surface properties including a glossy finish. Further these materials are compatible with new blowing agents, such as the hydrochlorofluorocarbons and hydrofluorocarbon blowing agents, which are more environmentally friendly. The layers of the multilayer structure do not require a glue layer.
    Type: Grant
    Filed: September 21, 1992
    Date of Patent: November 23, 1993
    Assignee: Ferro Corporation
    Inventors: Deenadayalu Chundury, Anthony S. Scheibelhoffer, Berdine L. Leonard, Ronald E. Thompson, Randall S. McAllister, Surachai Wimolkiatisak, Anthony F. Dean, Jr.
  • Patent number: 5261536
    Abstract: The present invention relates to novel multi-layer coextruded thermoplastic stretch wrap films useful for the packaging or palletizing of goods. More particularly the films of this invention comprise at least three layers having two outer layers and at least one intermediate layer placed between the outer layers. The intermediate layer is formed from a high pressure low density polyethylene resin and the outer layers are formed from a linear low density polyethylene copolymer such as ethylene copolymerized with a minor amount of at least one C.sub.4 to C.sub.10 alpha-olefin, such as hexane-1, octene-1, decene-1, 4-methyl-pentene-1 and butene-1. The force required to stretch the novel films of this invention may be controlled by the thickness of the intermediate layer relative to overall film thickness, the melt index of the intermediate layer resin, the molecular weight of the intermediate layer resin or a combination thereof.
    Type: Grant
    Filed: December 17, 1992
    Date of Patent: November 16, 1993
    Assignee: Mobil Oil Corporation
    Inventor: Gregory M. Wilson
  • Patent number: 5260111
    Abstract: A laminate seam of flat rubber sheet material for roofing comprising two layers (10, 11) of the sheet material, at least one layer of which is uncured or cured, and one layer of a thermoplastic film (14) interposed between the overlapped edges (12, 13) of the two layers of sheeting material to form a seam without the use of an adhesive. A method for covering a roof comprises the steps of applying a thermoplastic film (14) to the edge (12) of at least one layer of a flat rubber sheet material (10); applying a second layer of flat rubber sheet material (11) overlapping the thermoplastic film and the edge of the first flat rubber sheet material; heating the overlapped area to a temperature slightly above the peak melt temperature of the thermoplastic film; and, seaming the overlapped area under sufficient heat and pressure to provide an acceptable seam without the use of an adhesive.
    Type: Grant
    Filed: August 8, 1991
    Date of Patent: November 9, 1993
    Assignee: Bridgestone Corporation
    Inventors: Joseph K. Valaitis, James A. Davis, D. Frederick Lohr
  • Patent number: 5252379
    Abstract: An embossed process paper for transfer, adapted to be used for forming a dry type of synthetic leather, includes a backing paper (1), a mixed resin (2) of polypropylene with polyethylene laminated on the surface of the backing paper (1) and a homopolypropylene resin (3) laminated on the surface of the mixed resin (2). Both the resins are laminated together at a total resin coat thickness of 30 to 120 .mu.m, the thickness of the mixed resin (2) accounting for 50 to 20% of the total resin coat thickness and the thickness of the resin (3) accounting for 50 to 80% of the total resin coat thickness, both the resins having thereon a given embossed pattern having a depth of 20 to 150 .mu.m, and the backing paper (1) having a smooth back side.
    Type: Grant
    Filed: November 21, 1991
    Date of Patent: October 12, 1993
    Assignees: Sanyo Kakoshi Kabushiki Kaisha, Showa Denko Kabushiki Kaisha
    Inventors: Takeshi Kuribayashi, Haruo Yoshikawa, Yoshio Matsumoto
  • Patent number: 5248532
    Abstract: An air bag-containing cover comprising:a soft surface skin layer made of a thermoplastic polymer containing the following ingredients A, B, C and D:ingredient A: a hydrogenated derivative of a block copolymer comprising styrene an conjugated diene,ingredient B: an olefinic resin,ingredient C: polyisobutylene with a viscosity average molecular weight of not greater than 70,000, andingredient D: a hydrocarbon series rubber softening agent with a kinetic viscosity at 40.degree. C. of not greater than 500 cSt and/or polybutene with a number average molecular weight of not greater than 2500, in which blending ratio is:ingredient A=40 to 80% by weight,ingredient B=5 to 30% by weightingredient C=2 to 30% by weightingredient D=0 to 20% by weight, and having a JIS-A hardness according to JIS-K6301 of from 20 to 90, anda rigid core layer comprising an olefinic resin having a modulus in flexure according to JIS-K7203 of from 1000 to 7000 kg/cm.sup.
    Type: Grant
    Filed: December 7, 1990
    Date of Patent: September 28, 1993
    Assignee: Takata Corporation
    Inventors: Masami Sawada, Takayasu Zushi, Mitsuo Yoshiyasu
  • Patent number: 5234732
    Abstract: Tamper-indicating, laminated wrappers wherein a visible change between layers of the wrapper indicate that the wrapper has been punctured or that there has been tampering with the wrapper or its contents. The wrapper may be composed of two or more plies of packaging material such as films made from ethylene vinyl alcohol copolymer or from polyolefins such as polypropylene. In one construction, a transparent or translucent laminated wrapper becomes opaque upon rupture or puncture. In other constructions, a transparent or translucent wrapper becomes colored at the site of the rupture or puncture.
    Type: Grant
    Filed: March 18, 1991
    Date of Patent: August 10, 1993
    Assignee: Philip Morris Inc.
    Inventors: Ronald J. Versic, Donald D. Emrick
  • Patent number: 5221136
    Abstract: A refrigerator cabinet is provided with a plastic liner, the inside wall of the refrigerator, which is resistant to chemical degradation by fluorocarbons. Freon and Freon substitutes used as blowing agents for foaming the insulation contained between the outer metal cabinet and the inside wall of the refrigerator can cause blistering, cracking, and sometimes dissolution of materials used to form the plastic liner, which is the inside wall of the refrigerator. There is now provided a plastic liner which is resistant to those blowing agents and particularly to those blowing agents which are partially halogenated and tend to be more aggressive than Freon. The plastic liner wall maintains impact strength and toughness after exposure to fluorohydrocarbons conventionally employed in refrigerator units for in situ polyurethane foam production.
    Type: Grant
    Filed: September 12, 1991
    Date of Patent: June 22, 1993
    Assignee: BASF Corporation
    Inventors: Steven M. Hauck, Jeffrey P. Viola
  • Patent number: 5204183
    Abstract: An encapsulated breaker chemical composition used in a fracturing process in an oil or gas stimulation operation which comprises: (a) a breaker chemical; (b) a water soluble sealing layer, such as urea, having a thickness within the range of about 1 to about 30 microns deposited on the surface of said breaker chemical and encapsulating said breaker chemical; and (c) a pinhole free coating of a neutralized sulfonated elastomeric polymer of about 2 to about 80 microns thick deposited onto the surface of the coated breaker chemical, wherein said neutralized sulfonated polymer encapsulates the breaker chemical and is permeable to the breaker chemical.
    Type: Grant
    Filed: January 3, 1992
    Date of Patent: April 20, 1993
    Assignee: Exxon Research and Engineering Company
    Inventors: Lee A. McDougall, John C. Newlove, Pacifico V. Manalastas, Evelyn N. Drake
  • Patent number: 5202188
    Abstract: A film with properties such as good thermal stability, enhanced extrudability, improved oxygen barrier properties, and reduced stickiness to metal surfaces is made by the use of a vinylidene chloride composition with small amounts of a plasticizer (such as epoxidized oil or epoxidized alpha olefin), and acrylate/styrene polymer (such as methyl methacrylate/butyl acrylate/styrene polymer) or poly(alpha-methylstyrene).
    Type: Grant
    Filed: August 23, 1991
    Date of Patent: April 13, 1993
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Solomon Bekele
  • Patent number: 5196262
    Abstract: Microporous material comprises: (1) a matrix comprising a mixture of substantially linear ultrahigh molecular weight polyethylene having an intrinsic viscosity of at least about 10 deciliters/gram and lower molecular weight polyethylene having an ASTM D 1238-86 Condition E melt index of less than about 50 grams/10 minutes and an ASTM D 1238-86 Condition F melt index of at least 0.1 gram/10 minutes, (2) a large proportion of finely divided water-insoluble siliceous filler, and (3) interconnecting pores wherein the weight percent of the ultrahigh molecular weight polyethylene in the total polyethylene of the matrix and the filler/matrix weight ratio are within the polygon ABCDEF of FIG. 6 of the drawings.
    Type: Grant
    Filed: October 10, 1990
    Date of Patent: March 23, 1993
    Assignee: PPG Industries, Inc.
    Inventors: Richard A. Schwarz, William Keim
  • Patent number: 5192615
    Abstract: An encapsulated breaker chemical composition used in a fracturing process in the protection of an oil or gas stimulation operation which comprises: a breaker chemical; and a pinhole free coating of a neutralized sulfonated elastomeric polymer of about 2 to about 80 microns thick deposited onto the surface of the breaker chemical, wherein said neutralized sulfonated polymer encapsulates the breaker chemical, wherein the neutralized sulfonated polymer is permeable to the breaker chemical and the neutralized sulfonated polymer is non-reactive to the breaker chemical.
    Type: Grant
    Filed: January 3, 1992
    Date of Patent: March 9, 1993
    Assignee: Exxon Research & Engineering Company
    Inventors: Lee A. McDougall, John C. Newlove, Pacifico V. Manalastas, Evelyn N. Drake
  • Patent number: 5187011
    Abstract: An encapsulated breaker chemical composition used in an oil or gas stimulation operation which comprises: a breaker chemical; and a pinhole free coating of an ionically and covalently crosslinked neutralized sulfonated elastomeric polymer of about 2 to about 80 microns thick deposited onto the surface of the breaker chemical, wherein said polymer encapsulates the breaker chemical, wherein the polymer is permeable to the breaker chemical and the polymer is non-reactive to the breaker chemical.
    Type: Grant
    Filed: January 9, 1992
    Date of Patent: February 16, 1993
    Assignee: Exxon Research and Engineering Company
    Inventors: Pacifico V. Manalastas, Evelyn N. Drake, Edward N. Kresge, Warren A. Thaler, Lee A. McDougall, John C. Newlove, Vijay Swarup, Albert J. Geiger
  • Patent number: 5174848
    Abstract: A process for producing a propylene resin formed article with a hard coat is disclosed, comprising forming an ultraviolet-curing acrylic resin coating film on the surface of a propylene resin film or sheet, subjecting the film or sheet with the coating film to thermoforming, and irradiating the coating film to ultraviolet rays to cure said ultraviolet-curing resin, wherein said propylene resin film or sheet is composed of at least a propylene resin surface layer containing substantially no nucleating agent on which surface is coated said acrylic resin film and a thermoplastic resin base layer containing a nucleating agent which is laminated on the other side of said propylene resin surface layer prior to the thermoforming. The hard coat on the propylene resin formed article has high gloss.
    Type: Grant
    Filed: April 1, 1991
    Date of Patent: December 29, 1992
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Takao Yazaki, Masataka Noro, Takashi Matsui, Kazuhide Hayama, Noritaka Hosokawa
  • Patent number: 5171640
    Abstract: Multilayer polymer material with barrier properties containing a layer (a) of a polymer with barrier properties and a layer (b) of copolymer of styrene and maleic anhydride.The polymer of layer (a) is a copolymer of ethylene and vinyl alcohol and the said material also has a lyer (c) of a copolymer of ethylene containing units derived from an unsatured dicarboxylic acid anhydride and layer (c) is in contact with layer (a).
    Type: Grant
    Filed: November 26, 1990
    Date of Patent: December 15, 1992
    Assignee: Atochem
    Inventor: Rene Wirth
  • Patent number: 5165919
    Abstract: A medical material comprising a high-molecular weight material and a heparin derivative is provided, which high-molecular weight material comprises a high-molecular weight compound having functional groups capable of binding with epoxy groups, a compound having at least two amino groups and a polymer having a number of epoxy groups, said functional groups and some of said amino groups being bound to said epoxy groups, and which heparin derivative comprises heparin and an epoxy compound having at least two epoxy groups part of which is bound to amino groups in the heparin, the amino groups not bound to the epoxy groups in said high-molecular weight material being bound to the epoxy groups not bound to the amino groups in the heparin derivative. Also provided are an intermediate (high-molecular weight material) to be used for said medical material, as well as processes for producing said medical material and said intermediate.
    Type: Grant
    Filed: September 26, 1990
    Date of Patent: November 24, 1992
    Assignee: Terumo Kabushiki Kaisha
    Inventors: Masatomi Sasaki, Shinichi Kaneda, Nobuyoshi Kashiwagi
  • Patent number: 5158836
    Abstract: Polymeric, oriented films can be made by the use of a combination of a hot blown process and a blown bubble process. Styrene butadiene copolymer (SBC) forms two outer layers of the preferred embodiment, with a core layer of very low density polyethylene (VLDPE) or blends thereof, and intermediate polymeric adhesive layers such as ethylene vinyl acetate copolymer (EVA) bonding the core layer to the outer layers. A monoaxially or biaxially oriented film is produced with excellent optics.
    Type: Grant
    Filed: February 21, 1991
    Date of Patent: October 27, 1992
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Henry G. Schirmer, Stephen F. Compton, Martin Nelson
  • Patent number: 5156920
    Abstract: The adherence of protective and/or decorative paints to polyphenylene ether resins, alone, or combined with high impact strength polystyrene resins, is markedly improved by adding a high impact rubber modified terpolymer resin comprising units of a non-polar aromatic monovinyl compound, e.g., styrene, a polar monovinyl compound, e.g., acrylonitrile, acrylic acid, methacrylic acid, maleic anhydride, etc., and a diene rubber, e.g., butadiene.
    Type: Grant
    Filed: September 5, 1986
    Date of Patent: October 20, 1992
    Assignee: General Electric Company
    Inventors: David F. Aycock, Peter H. Shu
  • Patent number: 5153072
    Type: Grant
    Filed: March 25, 1991
    Date of Patent: October 6, 1992
    Assignee: The Board of Regents of the University of Washington
    Inventors: Buddy D. Ratner, Gabriel P. Lopez
  • Patent number: 5143788
    Abstract: A coating composition particularly useful in for forming exterior finishes on the exterior of vehicle parts, the binder of the composition which is in an organic liquid carrier is a polyesterurethane and a multifunctional epoxy compound; whereinthe polyesterurethane is formed by reacting a hydroxy functional polyester with a hydroxy containing carboxylic acid and an organic polyisocyanate andthe multifunctional epoxy resin is an aliphatic, cycloaliphatic or aromatic epoxy resin; coated parts, laminates and composite structures made with the coating composition are also part of the invention.
    Type: Grant
    Filed: November 20, 1991
    Date of Patent: September 1, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Jeffery W. Johnson
  • Patent number: 5137785
    Abstract: The invention herein is directed to article and process for making it. The article is characterized by a substrate composed of a ring-opened polymer of a norbornene-type monomer having tricyclic or higher cyclic structure and a polymer sheet tenaciously adhering to the substrate. The process includes the steps of positioning the polymer sheet in a mold, flowing the monomer in a liquid state in a plurality of streams into the mold, polymerizing the monomer in the mold by ring-opening of the monomer, and removing the article from the mold with the polymer sheet on at least one outer surface thereof.
    Type: Grant
    Filed: March 20, 1989
    Date of Patent: August 11, 1992
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Shoji Suzuki, Tokio Kaneki, Masayoshi Matsui, Motoyuki Yamato
  • Patent number: 5135797
    Abstract: A decorative film which is capable of being fused to an ethylene-propylene diene monomer. The film comprises a substrate formed from an ethylene/acrylic acid copolymer or an ethylene/ethyl acrylate copolymer and a synthetic resin elastomer film decoratable layer which is bonded to the substrate by an adhesive.
    Type: Grant
    Filed: May 15, 1991
    Date of Patent: August 4, 1992
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Makoto Sasaki
  • Patent number: 5130182
    Abstract: A fusion bonded waterproof sheet having a first ethylene-.alpha.-olefin rubber layer which has a high crosslinking rate and is changed to a crosslinked layer and a second ethylene-.alpha.-olefin rubber layer which has a low crosslinking rate and is changed to a partially crosslinked layer, the crosslinking of both sheets being carried after compositing and integrating them, which sheet has good fusion bondability and good bond strength at high temperature.
    Type: Grant
    Filed: September 6, 1991
    Date of Patent: July 14, 1992
    Assignee: Sumitomo Chemical Co., Ltd.
    Inventors: Masashi Aoshima, Hironobu Shigematsu, Tatsuo Sassa
  • Patent number: 5114795
    Abstract: Multilayered high barrier film products providing gas and moisture barrier properties. The film products comprise at least a first polymer film having low permeability to moisture and a polymer blend film containing a gas barrier polymer and a second polymer functionalized for compatibility with the gas barrier polymer and so as to allow the polymer blend film to adhere to the first polymer film. A method for the preparation of multilayered high barrier film products includes the steps of forming a gas barrier polymer film from a polymer blend containing a gas barrier polymer and a second polymer and, bonding a moisture barrier polymer film to at least one side of the gas barrier film.
    Type: Grant
    Filed: October 17, 1988
    Date of Patent: May 19, 1992
    Assignee: The Standard Oil Company
    Inventors: Elena S. Percec, Lucy Melamud, Gerald P. Coffey
  • Patent number: 5114790
    Abstract: A conductive resilient pad for keyboards, such as computer keyboards, is disclosed. The pad is composed of EPDM blended with a copolymer of propylene oxide and allyl glycidyl ether and Ketjen Black. Each of the polymers is present in the amount of about 25 to about 75 parts and the Ketjen Black is present in an amount of about 1 to about 30 parts.
    Type: Grant
    Filed: November 10, 1988
    Date of Patent: May 19, 1992
    Assignee: Acushnet Company
    Inventor: Daniel P. Corbett