Including Polyene Monomers Patents (Class 428/519)
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Publication number: 20100151180Abstract: The invention describes a carbon black particulate filled film, useful as a backsheet for a photovoltaic construct.Type: ApplicationFiled: October 9, 2009Publication date: June 17, 2010Inventors: David J. Bravet, Paul W. Ortiz
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Publication number: 20100143627Abstract: To provide a multilayer film and a container formed of the multilayer film which are excellent in unsealability, transparency, mechanical strength and sterilization heat resistance and are capable of preventing exudation of additives from the film into a liquid contained in the container. In a multilayer film including a first layer (1), a second layer (2), a third layer (3), a fourth layer (4) and a fifth layer (5) stacked in this order, the first layer (1) is composed of a propylene-ethylene random copolymer and/or a polypropylene homopolymer, and the second layer (2) and the fourth layer (4) are each composed of a mixture of a propylene-ethylene random copolymer and an ?-olefin elastomer. The third layer (3) is composed of a mixture of a polycycloolefin and a polyethylene, and the fifth layer (5) is composed of a mixture containing a polypropylene homopolymer and a propylene-ethylene random copolymer in a weight ratio of 90:10 to 10:90.Type: ApplicationFiled: February 18, 2008Publication date: June 10, 2010Inventors: Fujio Inoue, Isamu Tateishi, Yasushi Morimoto
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Publication number: 20100112365Abstract: The present invention relates to layered-structure vulcanizates, where at least one of the layers is composed of a hydrogenated vinylpolybutadiene and the other layers are preferably composed of rubbers double bonds.Type: ApplicationFiled: June 25, 2007Publication date: May 6, 2010Applicant: LANXESS DEUTSCHLAND GMBHInventors: Werner Obrecht, Andreas Bischoff, Alexander Lissy
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Publication number: 20100112366Abstract: The present invention provides a composite molded article and a method for producing the same. The composite molded article comprises a molded article of an olefin thermoplastic elastomer (A) and a molded article of an olefin thermoplastic elastomer (B) fused to each other, wherein the olefin thermoplastic elastomer molded article (A) contains an olefin thermoplastic elastomer composition (A?) having less than 5% by weight of a cyclohexane-soluble(s) and less than 35% of a compression set (JIS K6262, 70° C., 22 hours), and the olefin thermoplastic elastomer molded article (B) contains an olefin thermoplastic elastomer composition (B?) obtained by blending 100 parts by weight of an ethylene/?-olefin/non-conjugated diene copolymer rubber (b-1) containing 6 to 15 wt % of a non-conjugated diene unit, with 40 to 150 parts by weight of a mineral oil softener (b-2), 5 to 150 parts by weight of an olefin resin (b-3), and 0.Type: ApplicationFiled: March 21, 2008Publication date: May 6, 2010Applicant: Sumitomo Chemical Company LimitedInventors: Nobuhiro Natsuyama, Hironobu Shigematsu
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Publication number: 20100075165Abstract: The present invention relates to a low surface gloss styrene resin composition. The composition of the present invention is composed of (A) 80-99.9 weight % of the basic resin comprising rubber-modified styrene resin and (B) 0.1-20 weight % of syndiotactic polystyrene, the matting agent. The composition also includes (C) hydrogenated styrene block copolymer comprising styrene block and butadiene rubber block as a compatibilizer by 0.1-20 weight % for the total weight of the low surface gloss styrene resin composed of (A) the basic resin and (B) the matting agent and additionally includes (D) a plasticizer by 0.1-30 weight %. The composition of the present invention has excellent weatherability and impact-resistance in addition to the low surface gloss properties, so that it can be applied in various products, particularly exterior products for structures such as sidings and window frames, etc.Type: ApplicationFiled: January 30, 2008Publication date: March 25, 2010Applicant: LG CHEM, LTD.Inventors: Yun-kyoung Cho, Seon-mo Son, Bong-keun Lee, Tae-bin Ahn, Han-jong You, Sung-tae Ahn
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Patent number: 7674514Abstract: A multi-layer membrane includes a fluorine containing layer and a substrate which are joined through spray coating and heat treatment in a multi-step technique.Type: GrantFiled: December 2, 2005Date of Patent: March 9, 2010Inventors: Thomas E Frankel, Seoungil Kang, Todd D Ritter, Hong-suk Kim
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Publication number: 20100024941Abstract: An article having a fluid permeation prevention layer, such as a pneumatic tire or hose. A tire for example includes an outer tread layer, intermediate sidewall and carcass layers and an innermost air permeation prevention layer: (i) the air permeation prevention (APP) layer having an upper and a lower surface, the layer having a polymer composition exhibiting an air permeation coefficient (APC) of about 25×1O?12 cc cm/cm2 sec cmHg (at 30* C) or less and a Young's modulus of about 1 MPa to about 500 MPa, the polymer composition comprising: (A) at least 10 wt % of at least one. thermoplastic resin component having an APC of about 25×1O?12 cc cm/cm2 sec cmHg (at 30° C.) or less and a Young's modulus of more than 500 MPa, which is preferably a polyamide resin or mixture, and (B) at least 10 wt % of at least one elastomer component having an APC of more than about 25×10?12 cc cm/cm2 sec cmHg (at 30° C.Type: ApplicationFiled: October 26, 2006Publication date: February 4, 2010Inventors: Yuichi Hara, Shusaku Tomoi, Andy Haishung Tsou, Stephan Bertil, Yoshihiro Soeda
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Patent number: 7638205Abstract: An optical laminate film comprising a layer (A) comprising a material having a negative intrinsic birefringence value as a primary component; and a layer (B) comprising a transparent resin as a primary component which is laminated to at least one side of the layer (A). The optical laminate film satisfies the following conditions: (a) nz>(nx+ny)/2 (b) 0? dispersion of retardation Re?+10 nm, wherein retardation Re is represented by the formula [|nx?ny|×D] where D represents thickness (?m) of the laminated film, nz represents a refractive index in the thickness direction, and nx and ny each represent a refractive index, respectively in two directions orthogonal to each other and both of which are perpendicular to the thickness direction, all of the refractive indices being measured using light with wavelength of 550 nm.Type: GrantFiled: August 18, 2004Date of Patent: December 29, 2009Assignee: Zeon CorporationInventors: Kohei Arakawa, Katsuhiro Kurosaki, Toshihide Murakami
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Publication number: 20090275111Abstract: Compostable hydrocarbon polymers, composites, and articles anaerobically biodegrade in landfills in a relatively short time. Composite polymeric articles and sheets such as indoor or outdoor signs, billboards, banners, images, protective barriers, backdrops and wall coverings have very useful service durations and yet are landfill biodegradable.Type: ApplicationFiled: July 10, 2009Publication date: November 5, 2009Applicant: BIOTech Products, LLCInventor: Richard F. Grossman
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Publication number: 20090220757Abstract: The present invention relates to a multi-layer oriented shrink film comprising at least one skin layer comprising a polystyrene material and at least one core layer comprising a polyolefin layer. The films are preferably primarily oriented in either the machine or the cross direction. These films are ideally suited for use as a shrink label which can be applied either as a CD shrink sleeve or applied using a continuous roll process. The films ideally have an overall density of less than 1.0 g/cm3, to facilitate recycling efforts.Type: ApplicationFiled: November 2, 2006Publication date: September 3, 2009Inventors: Rajen M. Patel, Debra H. Niemann, Pak-Wing S. Chum, Morris Amon, Evgueni Rozenbaoum, Chia-Hsi Chu
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Patent number: 7514152Abstract: An oxygen scavenger film includes a layer including a blend of an oxygen scavenger and a polymer selected from high density polyethylene, polypropylene or a propylene copolymer, and a sealant layer. Alternatively, both the oxygen scavenging layer and the sealant layer include a polymer selected from high density polyethylene, polypropylene or a propylene copolymer. The hot tack strength of these films is at least 2.0 Newtons/inch at 135° C., according to ASTM F 1921-98, measured with DTC instrumentation.Type: GrantFiled: January 25, 2006Date of Patent: April 7, 2009Assignee: Cryovac, Inc.Inventors: Janet Rivett, Drew V. Speer
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Publication number: 20090053949Abstract: The invention relates to low-viscosity, low-monomer aqueous polymer dispersions based on polychloroprene, and a process for the preparation thereof and the use thereof as a contact adhesive.Type: ApplicationFiled: August 19, 2008Publication date: February 26, 2009Applicant: Bayer MaterialScience AGInventors: Dirk Achten, Peter Kueker, Juergen Kempkes, Bianka Lorenz, Peter Reichert, Winfried Jeske, Jose Colinas-Martinez
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Patent number: 7473472Abstract: A sulfur-crosslinkable adhesive composition of the non-aqueous type, that is to say not requiring the presence of water, usable for direct bonding of a pregelled polyester or vinyl ester composite to rubber in the uncured state. The composition comprises polyvinylpyridine-styrene-butadiene elastomer (“p-VSBR”) in combination with a polyester or vinyl ester resin. Preferably, the resin used is a novolak and/or bisphenol based resin of the epoxy vinyl ester type. This composition, unlike conventional RFL adhesives, does not require any activation treatment, such as intermediate drying, at the time of use. A process for preparing such an adhesive composition, use of said composition for the manufacture of laminated composite parts.Type: GrantFiled: June 27, 2005Date of Patent: January 6, 2009Assignee: Conception et Developpment Michelin S.A.Inventors: Philippe Chenaux, Antonio Delfino
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Patent number: 7473473Abstract: A shrink film includes an internal layer including a styrene/butadiene/styrene block copolymer; and first and second outer layers including an olefinic polymer. First and second intermediate layers including an ethylene copolymer having a melt index less than 4.0 can be optionally included. Alternatively, a shrink film includes an internal layer including an ethylene copolymer having a melt index less than 4.0; a first and second intermediate layer each including a styrene/butadiene/styrene block copolymer; and a first and second outer layer each including an olefinic polymer. Film of the invention has a free shrink of from 40% to 80% at 240° F., and an Elmendorf tear of from 70 grams/mil to 300 grams/mil, in at least one of the longitudinal and transverse directions.Type: GrantFiled: March 4, 2005Date of Patent: January 6, 2009Assignee: Cryovac, Inc.Inventor: Anthony Verrocchi
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Publication number: 20080311261Abstract: Packaging materials comprising a sealant film having at least a skin layer comprising LDPE, a core layer comprising LDPE, MDPE, HDPE, or a blend of any two or all three of these, and a sealant layer comprising EVA copolymer are disclosed. At least one of the layers additionally comprises a stiffening agent such as calcium carbonate. The packaging material is especially useful in applications where good pouch formation and sealing characteristics are needed, such as in the packaging of process cheese products (e.g., loaf).Type: ApplicationFiled: June 13, 2008Publication date: December 18, 2008Applicant: ALCAN PACKAGING FLEXIBLE FRANCEInventor: George T. GULLICK
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Publication number: 20080299397Abstract: Provided is a composition thermoplastic elastomer structure comprising (1) a first component comprising a first elastomeric component comprising an at least partially vulcanized rubber and a thermoplastic resin, (2) an adhesive later comprising a grafted random propylene copolymer and (3) a third component comprising a polyamide or polyester. The third component is at least partially adhered to the adhesive component, which is in turn, partially adhered to the first component. The structure has superior adhesive properties between structures. Also provided are articles made from the structures, particularly automotive weather seals, glass run channels, a noise attenuating device, automotive interior part, automotive belt, automotive hose, industrial belt, industrial hose, packaging material, construction material, decorative building material, and other consumer goods.Type: ApplicationFiled: June 4, 2007Publication date: December 4, 2008Inventors: Leander Michiel Kenens, Eric Paul Jourdain, Jean-Roch Schauder
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Patent number: 7445846Abstract: A thermoplastic vulcanizate comprising a) a dynamically vulcanized rubber, b) a thermoplastic resin, and c) optionally a synthetic oil, where the thermoplastic vulcanizate is substantially devoid of mineral oils.Type: GrantFiled: April 1, 2005Date of Patent: November 4, 2008Assignee: Advanced Elastomer Systems, L.P.Inventors: Sunny Jacob, William Gary Stevenson
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Patent number: 7425372Abstract: The coating agent composition comprises an emulsion containing (A) polydiorganosiloxane having a viscosity of 50 to 10,000,000 mPa·s at 25° C. and having both terminal ends blocked by hydroxyl groups, (B) polyorganohydrogensiloxane having at least three hydrogen atoms bonded to silicon atoms in one molecule, (C) a curing catalyst, and (D) chlorinated polyolefine and/or acryl-modified polyolefine, with which (E) fine spherical particles comprised of a rubber-like elastomer having hardness of less than 90 are mixed to disperse into it. The coating agent composition having good uniform applying property, non tackness, water repellency and lubricating properties and outstanding adhesiveness to a rubber or plastic substrate can be obtained.Type: GrantFiled: June 4, 2004Date of Patent: September 16, 2008Assignee: GE Toshiba Silicones Co., Ltd.Inventors: Toshio Yamato, Hiroyoshi Shimotsu
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Patent number: 7422782Abstract: The present invention describes a multilayer film suitable for use in packaging applications comprising at least a polymeric first layer having a first surface and an opposing second surface wherein the polymeric first layer comprises a heat-sealable, water-insoluble polyester; a polymeric second layer having a first surface and an opposing second surface and comprising a pressure-sensitive adhesive, wherein the second surface of the polymeric second layer is in contact with the first surface of the polymeric first layer and forms a peelable/resealable bond therebetween; and a third layer in contact with the first surface of the polymeric second layer.Type: GrantFiled: February 1, 2005Date of Patent: September 9, 2008Assignee: Curwood, Inc.Inventors: Edward L. Haedt, Paul J. Sheridan, Joseph J. Michels, Lynn M. Nett
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Patent number: 7355089Abstract: This invention relates to polyolefin compositions. In particular, the invention pertains to elastic polymer compositions that can be more easily processed on cast film lines, extrusion lamination or coating lines due to improved resistance to draw resonance. The compositions of the present invention preferably comprise an elastomeric polyolefin resin and a high pressure low density type resin.Type: GrantFiled: March 15, 2006Date of Patent: April 8, 2008Assignee: Dow Global Technologies Inc.Inventors: Andy C. Chang, Ronald J. Weeks, Hong Peng, Antonios K. Doufas, Yunwa W. Cheung
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Publication number: 20080075901Abstract: A packaging film or sheet having a styrene-butadiene block copolymer directly melt-bonded to at least one layer of a cyclo-olefin copolymer is disclosed. The films may be made by means of co-extrusion. The packaging film is amenable to thermoforming processes and is particularly suitable for forming blister packaging used in pharmaceutical applications.Type: ApplicationFiled: February 22, 2006Publication date: March 27, 2008Inventors: S. Thomas Lee, P. Michael Bost, Jeffrey P. Viola, Jennifer R. Stewart
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Patent number: 7348066Abstract: A norbornene-based cyclic olefin layer with a curable layer disposed thereon is described. The curable layer may additionally be imparted with a texture. The norbornene-based cyclic olefin films with curable layers can be incorporated into optical bodies which include an optical film, such as an oriented multilayer optical film. In addition, the invention includes a method of coating a curable layer onto a norbornene-based polymer layer or film without requiring a primer layer. Methods of making the norbornene-based cyclic olefin layer containing films are also disclosed.Type: GrantFiled: October 14, 2005Date of Patent: March 25, 2008Assignee: 3M Innovative Properties CompanyInventors: Bert T. Chien, Joan M. Strobel, Mark A. Strobel, Clinton L. Jones, Joel A. Getschel, Ellen R. Bosl
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Patent number: 7329465Abstract: A norbomene-based cyclic olefin layer with a curable layer disposed thereon is described. The curable layer may additionally be imparted with a texture. The norbomene-based cyclic olefin films with curable layers can be incorporated into optical bodies which include an optical film, such as an oriented multilayer optical film. In addition, the invention includes a method of coating a curable layer onto a norbomene-based polymer layer or film without requiring a primer layer. Methods of making the norbomene-based cyclic olefin layer containing films are also disclosed.Type: GrantFiled: October 29, 2004Date of Patent: February 12, 2008Assignee: 3M Innovative Properties CompanyInventors: Bert T. Chien, Joan M. Strobel, Mark A. Strobel, Clinton L. Jones, Joel A. Getschel, Ellen R. Bosl
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Patent number: 7329445Abstract: The present invention provides a multiple layered non-PVC containing tubing structure. The tubing structure has a first and a second layer. The first layer is of a polymer blend of (a) from about 30% to about 50% by weight of the first layer a first polyolefin selected from the group consisting of a first propylene containing polymer, (b) from about 0 to about 50% by weight of the first layer a second polyolefin of an ?-olefin containing polymer; (c) from about 0% to about 40% by weight of the first layer a radio frequency susceptible polymer and (d) from about 5% to about 40% of a first thermoplastic elastomer. The second layer is attached to the first layer and includes a non-PVC containing material.Type: GrantFiled: October 17, 2003Date of Patent: February 12, 2008Assignees: Baxter International Inc., Baxter Healthcare S.A.Inventors: Michael T. K. Ling, Ketan Shah, Bill Hurst, Samuel Ding
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Patent number: 7326471Abstract: An automotive sealant composite structure is provided. The composite structure includes a first piece comprising a first elastomeric component that includes an at least partially crosslinked rubber, a first olefinic thermoplastic resin component, and a second olefinic thermoplastic resin component. The second olefinic thermoplastic resin component includes a propylene copolymer that has (i) 60 wt % or more units derived from propylene, (ii) isotactically arranged propylene derived sequences and (iii) a heat of fusion less than 45 J/g. The composite structure also includes a second piece at least partially adhered to the first piece. Preferably, the second piece includes one or more thermoset ethylene copolymer rubbers. Preferably, the first piece is a corner piece and the second piece is a straight piece at least partially adhered to the corner piece, together constituting a vehicular window seal structure.Type: GrantFiled: October 15, 2004Date of Patent: February 5, 2008Assignee: Advanced Elastomer Systems, L.P.Inventor: Karla Drew Shaw
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Patent number: 7312277Abstract: Disclosed is a mass polymerized rubber-modified monovinylidene aromatic copolymer composition with an excellent balance of physical and mechanical properties especially low temperature impact, and methods for preparing such a composition.Type: GrantFiled: April 4, 2005Date of Patent: December 25, 2007Assignee: Dow Global Technologies Inc.Inventors: Doninique Maes, Adrianus Ruiter, Gilbert Bouquet, Tim Pope, Rony Vanspeybroeck, Kees-Jeen Van Duin
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Patent number: 7267885Abstract: The present invention provides a flowable materials container. The container has a first sidewall and a second sidewall sealed together along a peripheral seam to define a fluid chamber. At least one sidewall is a film having at least one layer of blend of a first component selected from the group of: (1) ethylene and ?-olefin copolymers having a density of less than about 0.Type: GrantFiled: March 16, 2000Date of Patent: September 11, 2007Assignee: Baxter International Inc.Inventors: Lecon Woo, Sherwin Shang, Michael T. K. Ling, Yuan-pang Samuel Ding, Tahua Yang, Craig Sanford
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Patent number: 7247674Abstract: The present invention concerns a polymer composition comprising: a block copolymer (a) including a polymer block A, which is composed mainly of an ?-methylstyrene, and a hydrogenated or unhydrogenated polymer block B, which is composed of a conjugated diene or isobutylene and has a weight average molecular weight of 30,000 to 200,000; an acrylic resin (b); and a softener (c), wherein proportions (by mass) of the respective components in the polymer composition are such that each of the following relationships (1) and (2) holds: 0.05?Wb/Wa?2 and??(1) Wc/(Wa+Wb+Wc)?0.5??(2) wherein Wa, Wb, and Wc represent amounts (by mass) of the block copolymer (a), the acrylic resin (b) and the softener (c), respectively.Type: GrantFiled: April 21, 2003Date of Patent: July 24, 2007Assignee: Kuraray Co., Ltd.Inventors: Hajime Kitano, Kenji Shachi, Noboru Higashida, Koichi Wada, Mizuho Maeda
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Publication number: 20070160860Abstract: Inelastic film structures including at least one layer incorporating a combination of a first polymeric component that is at least one polymer incorporating propylene-derived units and a second polymeric component that is a thermoplastic polymer, for example, a polymer incorporating a polyolefin, are provided. The combination of the first polymeric component and the second polymeric component incorporates from about 40 wt. % to about 98 wt. % of the at least one polymer incorporating propylene-derived units and from about 2 wt. % to about 60 wt. % of the at least one polymer incorporating a polyolefin. The film structures are found to have properties making the structures useful for inclusion in a variety of applications. In certain embodiments, the film structures may exhibit optical clarity, tack, sealability, toughness, softness, and machinability properties superior to conventional polypropylene films and other conventional polyolefin films.Type: ApplicationFiled: December 15, 2006Publication date: July 12, 2007Inventors: David Michael Fiscus, Narayanaswami Raja Dharmarajan, Michael Charles Bulawa
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Patent number: 7211308Abstract: Multilayer sheets and films are provided that include a layer of a fluoropolymer material and a layer of a thermoplastic polymer material. More particularly, an adhesive material and multilayered structures formed therewith are provided in which a layer of a fluoropolymer material is attached to a layer of another thermoplastic polymer. The adhesive material is useful to adhere layers of dissimilar polymeric materials that are otherwise incompatible, and achieves a significantly improved interlayer bond strength between fluoropolymer and thermoplastic polymer layers as compared to the art.Type: GrantFiled: February 20, 2004Date of Patent: May 1, 2007Assignee: Honeywell International Inc.Inventors: Sangkeun Rhee, Michael P. Della Vecchia
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Patent number: 7192636Abstract: A multilayer shrink film and methods of making same comprising one or more polyethylenic layers, one or more polystyrenic layer and polystyrene compatibilizing layers situate between each polyethylenic layer and polystyrenic layer wherein the polystyrene compatibilizing layers comprise less than 1% by weight substantially random interpolymer. The multilayer shrink films of the invention are produced using film biaxial orienting means.Type: GrantFiled: December 9, 2003Date of Patent: March 20, 2007Assignee: Intertape Polymer Corp.Inventor: Shane Taghavi
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Patent number: 7192640Abstract: A packaging laminate comprising a paperboard substrate for providing a base layer, a tear-resistant polymer layer applied to said substrate, and a heat seal polymer layer applied to said tear-resistant polymer. This laminate structure is particularly useful for blister pack packaging.Type: GrantFiled: January 31, 2003Date of Patent: March 20, 2007Assignee: International Paper CompanyInventors: Victor P. Holbert, David Reed
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Patent number: 7183006Abstract: A multilayer film has a first layer and a second layer. The first layer comprises an additive, a binder, and a crosslinking agent. The additive is a flavor, fragrance, colorant, antimicrobial agent, antioxidant, chelating agent, and/or odor absorbent. The binder is a polysaccharide and/or a protein. The crosslinking agent comprises a compound with at least two carbonyl groups. The second layer comprises a non-water-soluble thermoplastic polymer comprising at least one member selected from the group consisting of polyolefin, polyamide, polyester, polyvinylidene chloride, polyvinyl chloride, and polystyrene. Each of the additive, binder, and crosslinking agent are present throughout a thickness of the first layer. Preferably, the first layer is coated onto the second layer, which is preferably a non-water-soluble thermoplastic polymer, e.g., polyolefin, polyamide, and/or polyester.Type: GrantFiled: September 5, 2003Date of Patent: February 27, 2007Assignee: Cryovac, Inc.Inventors: Charles R. Bamore, Narender P. Luthra, Walter B. Mueller, Woodrow W. Pressley, Scott W. Beckwith
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Patent number: 7183354Abstract: The coating for substrates or materials, preferably elastomers or elastomers bonded to metal. The coating composition comprises (a) a functionalized hydrogenated copolymer comprising at least one repeat unit derived from a conjugated diene monomer; preferably including an unsaturated nitrile monomer; and a functional group containing monomer or graft linked compound or combinations thereof; (b) a curing component comprising at least one isocyanate group, or a carbodiimide compound, or an amino resin, or combinations thereof, and (c) a solvent. The coating compounds can be applied to an substrate either before or after the substrate has been vulcanized. The coatings can be cured at ambient temperatures.Type: GrantFiled: March 8, 2002Date of Patent: February 27, 2007Assignee: Lord CorporationInventors: James R. Halladay, Frank J. Krakowski, Ernest Barritt Troughton, Jr.
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Patent number: 7160593Abstract: A multi-layered pipe of arbitrary length and cross-section is produced by co-extrusion of a lower polyolefin (C2–C4) outer body over the exterior surface of a tubular core of randomly, partially randomly, or blocky chlorinated lower polyolefin, the core having a wall thickness, measured in the radial direction, in the range from about 0.025 mm to 5 mm. The tubular core is coextensive with essentially the entire length of the pipe. The tubular core comprises a major proportion by weight of the randomly chlorinated polyolefin (r-CPO), or, partially randomly chlorinated polyolefin (pr-CPO), or, a blocky chlorinated polyolefin (b-CPO), any of which may be blended with a minor proportion by weight of a blending ingredient. The r-CPO, pr-CPO or b-CPO, or a blend thereof, each has an extrusion temperature in the same range as that for the corresponding non-halogenated polyolefin, namely in the range from about 150° C. to 250° C.Type: GrantFiled: July 9, 2003Date of Patent: January 9, 2007Assignee: Noveon, Inc.Inventors: Girish T. Dalal, Arthur L. Backman, Andrew M. Olah, Theodore J. Schmitz, Andrew L. Auvil, Michael D. Vaughn, James J. Dedrick
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Patent number: 7135233Abstract: Multi-layer composite structures offer improved weatherability and adhesion to fiber-reinforced plastic substrates when compared to structures now available. These composites have an outer layer made from a polyacrylate, a second layer made from an acrylonitrile-styrene-acrylate rubber terpolymer; a third layer made from an ABS polymer; and optionally a fourth layer made from a polyacrylate. The layers include one or more layers having an improvement selected from among: (a) the improvement wherein the second layer is made from an acrylate-modified acrylonitrile-styrene-acrylate rubber terpolymer; (b) the improvement wherein the third layer is a modified ABS that further includes a polymer modifier that decreases the softening of the ABS on contact with styrene, and an acrylonitrile-styrene-acrylate rubber terpolymer; and (c) the improvement wherein the fourth layer is present and is a polyacrylate. This composite can be applied to a fiber-reinforced plastic substrate such as fiberglass as a coating.Type: GrantFiled: October 20, 2003Date of Patent: November 14, 2006Assignee: General Electric CompanyInventors: Satish K. Gaggar, Ke Feng, Donald M. Kulich, Christopher D. Willis, Craig Williams
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Patent number: 7135234Abstract: A multilayer thermoplastic extruded structure comprises at least one thermoplastic polyolefin layer; at least one thermoplastic vinyl aromatic polymer layer; and a multicomponent tie layer. The multicomponent tie layer comprises at least one thermoplastic polyolefin; at least one thermoplastic vinyl aromatic polymer; and at least one styrenic block copolymer. Preferred structures are multilayer films used for packaging or multilayer sheets for thermoformed containers.Type: GrantFiled: May 21, 2004Date of Patent: November 14, 2006Assignee: Nova Chemicals (International) S.A.Inventors: Karen D. Donnelly, Robert Dorville Roberts, John Chi Hee Kwok, Chris K. Hung, Trevor Dean Pacholok
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Patent number: 7101628Abstract: Broadly, the present invention provides a thermoplastic vulcanizate which can be readily processed into sheeting material for covering a roof that is both flexible and highly elastic. Where other thermoplastic elastomeric compositions have either been too stiff to act as roofing membranes or not processable due to their melt flow characteristics, the present thermoplastic vulcanizate employs a polypropylene random copolymer resin and a polyethylene random copolymer resin having about 10 to about 35 percent by weight ?-olefin co-monomer units; together with a compatibilizing rubber and a peroxide-based cross-linking agent, to provide an effective membrane for covering roofs.Type: GrantFiled: March 20, 2003Date of Patent: September 5, 2006Assignee: BFS Diversified Products, LLCInventor: Lichih Richard Peng
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Patent number: 7074492Abstract: The present invention relates to a coextrusion tie comprising 10 to 35 weight % of a polymer (A) itself composed of a blend of 80 to 20 weight % of a metallocene polyethylene (A1) with a density of between 0.865 and 0.915 and of 20 to 80 weight % of a non-metallocene LLDPE polyethylene (A2), the blend of polymers (A1) and (A2) being cografted by an unsaturated carboxylic acid or its derivative, the content of which in the said blend is between 30 and 100 000 ppm; 40 to 60 weight % of a styrene/butadiene/styrene block copolymer (B) with 50 to 90 mol % of styrene; and 20 to 35 weight % of PE (C); the total making 100%, the blend of (A), (B) and (C) being such that the MFI or melt flow index (ASTM D 1238, 190° C., 2.16 kg) is between 0.1 and 10 g/10 min. The present invention also relates to a multilayer structure comprising a layer of tie according to the invention and to the objects comprising such a structure.Type: GrantFiled: September 12, 2003Date of Patent: July 11, 2006Assignee: ArkemaInventors: Jean-Laurent Pradel, Jérome Pascal, Patrice Robert
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Patent number: 7051493Abstract: A multilayer film, which is particularly suited to packaging of cheese on a Hayssen® RT packaging machine, has a first layer comprising cyclic olefin copolymer having a glass transition temperature of at least 125° C., and a second layer comprising at least one member selected from the group consisting of cyclic olefin copolymer having a glass transition temperature of at least 125° C., polyamide, polyester, and polystyrene. The first and second layers are on opposite sides of a tensile axis of symmetry of the film. The film exhibits from 0 to 45 degrees of transverse edge curl, a yield point of at least 1200 psi at a temperature of 85° C., and an elongation at break of from 0 to 300 percent at 85° C.Type: GrantFiled: August 21, 2002Date of Patent: May 30, 2006Assignee: Cryovac, Inc.Inventors: Hubert J. Cook, Janet W. Rivett, Gautam P. Shah, Richard M. Dayrit, Kelly R. Ahlgren
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Patent number: 7048977Abstract: The invention relates to a method of enhancing the tear resistance, tensile strength, and the aging properties of a latex product by adding an antioxidant synergist with an antioxidant to a latex compound comprising of a polymer and a curing system comprised of an activator, crosslinker and accelerator and to the latex products formed therefrom. Antioxidant synergists which can be used with the present invention include 2-mercaptobenzimidazole (MBI), 2-mercaptotoluimidazole (MTI), zinc 2-mercaptobenzimidazole (ZMBI) and zinc 2-mercaptotoluimidazole (ZMTI). The latex products formed may be gloves but can also include threads, balloons and other latex-related products.Type: GrantFiled: September 24, 2003Date of Patent: May 23, 2006Assignee: R.T. Vanderbilt Company, Inc.Inventor: Robert Thomas Dzikowicz
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Patent number: 7041379Abstract: Elastomer coating composition are disclosed which cure at room temperature, and form highly flex-resistant, durable, and flexible protective layer on elastomers and provides excellent adhesion to elastomeric and metal substrates. The coating is a solvent solution of (A) a carboxylated hydrogenated acrylonitrile-butadiene copolymer, and (B) a room temperature isocyanate curing component. Coated bonded elastomer-metal composites are obtained without an additional application of heat to cure the coating.Type: GrantFiled: September 4, 2003Date of Patent: May 9, 2006Assignee: Lord CorporationInventors: James R. Halladay, Frank J. Krakowski
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Patent number: 7041739Abstract: A thermoplastic elastomer composition characterized in that the composition comprises a resin component and at least two kinds of rubber components, wherein at least one kind of the rubber components makes a continuous phase and/or a network-like phase, and the remaining at least one kind of the rubber components makes an isolated phase; and a process for producing the same.Type: GrantFiled: March 20, 2002Date of Patent: May 9, 2006Assignee: Sumitomo Chemical Company, LimitedInventors: Hiroshi Toyoda, Nobuo Oi, Eiji Nakaishi
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Patent number: 7041367Abstract: An elastomeric article includes a substrate body formed from an elastomeric material. The substrate body has a first surface, and a donning layer overlying at least a portion of the first surface. The donning layer is formed from a modified vinyl acetate polymer.Type: GrantFiled: June 3, 2003Date of Patent: May 9, 2006Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Robert A. Janssen, Martin S. Shamis, William E. Conley, Maris Vistins, Sanford E. White, Kermit R. Littleton
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Patent number: 7008699Abstract: Composite structures are described that include (a) a first polymer structure (e.g., a film or solid component) made of EPDM adhered to (b) a second polymer structure (film or solid component) that is made of a blend of dynamically vulcanized EPDM dispersed in a matrix of a thermoplastic polyolefin polymer. Either the first polymer structure, or both the first and second polymer structures are blended with an effective amount of a semicrystalline random adhesive copolymer.Type: GrantFiled: December 21, 2001Date of Patent: March 7, 2006Assignee: Advanced Elastomer Systems, L.P.Inventors: Eric P. Jourdian, Jean-Roch H. Schauder, Leander Kenens
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Patent number: 6998179Abstract: A process for preparing a polarizer is described whereby an article comprising an oriented, vinylalcohol polymer film layer, and an acid donor layer comprising a photoacid generator, is exposed to radiant energy at a temperature sufficient to effect a partial dehydration of the vinylalcohol polymer to a vinylalcohol/poly(acetylene) copolymer.Type: GrantFiled: June 21, 2004Date of Patent: February 14, 2006Assignee: 3M Innovative Properties CompanyInventors: Duane D. Fansler, Todd D. Jones, Babu N. Gaddam, Robert T. Fitzsimons, Steven M. Heilmann, John J. Cael
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Patent number: 6964798Abstract: A multiple layer structure comprising a first and a second skin layer, each skin layer composed of a polypropylene containing polymer, and a radio frequency (“RF”) susceptible layer adhered to and between the first and second skin layers. The RF layer has a first component of a propylene based polymer, a second component of a non-propylene polyolefin, a third component of a radio frequency susceptible polymer, and a fourth component of a polymeric compatibilizing agent.Type: GrantFiled: March 21, 2002Date of Patent: November 15, 2005Assignee: Baxter International Inc.Inventors: Gregg Nebgen, Keith Anderson, Mike Scharf
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Patent number: 6958185Abstract: A multilayer synthetic wood component comprised of a layer of a first synthetic wood composition that is secured to a layer of a second synthetic wood composition. As a result, the present invention may provide a component that utilizes the beneficial characteristics of each of the compositions. For instance, the component can have an improved combination of appearance, strength, durability, weight, weatherability, and other characteristics. Moreover, the present invention enables the ingredients of each layer to be tailored to the particular application. Consequently, certain ingredients can be conserved, thereby reducing the cost and/or the weight of the component.Type: GrantFiled: April 23, 2003Date of Patent: October 25, 2005Assignee: Crane Plastics Company LLCInventor: Burch E. Zehner
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Patent number: 6926958Abstract: A base film for medical adhesive tape is described, which is obtained by laminating, over one side or both sides of layer A composed of amorphous polyolefin, layer B composed of a polypropylene-based resin. A medical adhesive tape equipped with a pressure-sensitive adhesive layer on at least one side of the base film for medical adhesive tape; an adhesive plaster obtained by rolling the medical adhesive tape having the base film equipped with the pressure-sensitive adhesive layer; and a first-aid adhesive tape comprising the medical adhesive tape having the base film equipped with the pressure-sensitive adhesive layer and a liquid-absorbing pad disposed in a central region of the pressure-sensitive adhesive layer are also described.Type: GrantFiled: April 11, 2001Date of Patent: August 9, 2005Assignee: Nitto Denko CorporationInventors: Takashi Kinoshita, Atsushi Hamada, Tetsuo Watanabe, Fumiya Shirai, Kenji Furumori
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Patent number: 6905767Abstract: A method of making and polymer compositions with enhanced adhesion that include a rubbery or glassy polymer, about 0.1 to 30% by weight of carbon black filler and from about 0.1 to 5% by weight of carbon filler. Preferred polymers are polybutadiene, brominated isobutylene methylstyrene, polystyrene or polymethylmethacrylate and preferred carbon fillers are colloidal silica, pure graphite particles and a carbon black filler heat treated to an extent sufficient to reduce interaction with the polymer.Type: GrantFiled: January 31, 2003Date of Patent: June 14, 2005Assignee: The Research Foundation of State University of New YorkInventors: Miriam Rafailovich, Mordecai Bronner