Abstract: This invention relates to a leather that contains scent-containing microcapsules in its cross section, wherein the walls of the microcapsules comprise reaction products of guanidine compounds and polyisocyanates.

Abstract: This invention concerns the application of substantially amorphous fluoropolymer compositions to stone so as to protect the stone from the deleterious effects of water and pollution.

Abstract: A heat and pressure consolidated laminate, and method for producing the same, is provided that includes in superimposed relationship a decorative layer consisting essentially of a leather material, an underlay layer, a substrate, and an optional backer layer. The substrate has a first surface and a second surface opposite one another. The underlay layer includes one or more cellulosic sheets impregnated with a thermosetting resin, and is disposed between the decorative layer and the first layer of the substrate. The backer layer includes one or more cellulosic sheets impregnated with a thermosetting resin, and is disposed contiguous with the second surface of the substrate.

Abstract: A heat and pressure consolidated flexible laminate, and a method for producing the same, is provided that includes in superimposed relationship, a flexible, resin coated backing layer consisting of one or more sheets, a decorative layer consisting essentially of a leather material and, optionally, an overlay.

Abstract: A coloured porous material comprising in its pores an effectively colouring amount of an organic pigment which is obtainable by fragmenting a meltable or solvent-soluble pigment precursor, and a process for its preparation. The instant coloured porous material powders are used as pigments for high molecular weight organic materials.

Abstract: This invention concerns the application of substantially amorphous fluoropolymer compositions to stone so as to protect the stone from the deleterious effects of water and pollution.

Abstract: Algal defacement of coated and non-coated porous masonry and wood construction materials is prevented by pre-treatment of the construction material with an aqueous composition of a copolymer that releases 2-propenal (acrolein) over time.

Abstract: A synthetic resin leather comprising a substrate at least one surface of which is arranged with a synthetic resin layer, wherein said synthetic resin layer contains 1 to 70 weight parts of bridged polyalkylene oxide to 100 weight parts of synthetic resin. As the synthetic resin, polyvinyl chloride resin, acrylic soft resin, mixed resin composed of 50-95 wt. % of thermoplastic polyurethane and 50-5 wt. % of acrylic soft resin, copolymer of polyester resin or polyolefin resin can be used. A surface coating layer containing powder of natural organic substance can be arranged over the surface of synthetic resin layer of said synthetic resin leather. As the powder of natural organic substance, collagen can be desirably used. Further, on the surface of the synthetic resin leather, it is desirable to mark a pattern and to make the height of convex part of the pattern higher than 0.05 mm.

Abstract: A calcium salt protective coating formed in situ by combining fatty acids with lime, also the associated method of forming the protective coating in situ. The fatty acids are preferably vegetable fatty acids such as from soapstock byproduct skimmings produced during the manufacture of vegetable oil. Experimental testing has shown that the protective coating is substantially impervious to moisture. The protective coating is a suitable covering for hay bales, silage, coal piles, and road salt piles. Further experimental testing has shown that the present invention is also suited to environmental soil bioremediation (“landfarming”) using microbes, in which the fatty acid ingredient, in addition to being used in formation of a protective coating that inhibits introduction of oxygen into the soil being treated, is also used as a carbon source for the microbial activity.

Abstract: A structural system includes a plurality of structural elements. Each of the elements includes an interior layer, an exterior layer, and an insulating layer between the interior layer and the exterior layer. The structural elements are stacked adjacent to one another to form a wall. A respective cushion is placed between adjacent structural elements. The cushions create airspaces such that there is no direct surface contact between adjacent structural elements. The exterior layers of the structural elements can be fabricated from cast concrete material, and can be provided with simulative exterior surfaces, for example, with exterior surfaces simulating the appearance of structural logs.

Abstract: A leather-like sheet product comprising (a) a sheet layer (1) composed of a fiber assembly (1) of fine fibers and an elastic polymer (A) existent in a space between fibers of the fiber assembly (1), (b) a sheet layer (2) essentially composed of a fiber assembly (2) or composed of a fiber assembly (2) and an elastic polymer (C) existent in a space between fibers of the fiber assembly (2), and (c) an adhesive layer composed of an elastic polymer (B) for bonding together the sheet layer (1) and the sheet layer (2), wherein

Abstract: A chromium-free wood preservative consisting essentially of 1 to 35% by weight of a mixture of 25 to 75 parts by weight of a fatty amine ethoxylate and 75 to 25 parts by weight of at least one member of the group consisting of an unsaturated fatty acid of 3 to 25 carbon atoms and their copper and zinc salts and water.

Abstract: This invention relates to an article comprising a bio-supportive media which bio-degrades at a preferred rate, comprising at least one bio-limiting agent and at least one nutritional source on a substrate. The media may be characterized as a polymer, composite, or amalgam of commonly used materials. The invention relates to altering the physical/chemical composition of the media such that biodegradation can occur at a specific, usually accelerated, preferred rate. Further, the biodegradation rate may be managed and balanced concurrently with the ability to provide for the exposure of integral component(s) which are bio-active. This relationship essentially provides for a managed release or managed availability of agent(s) which creates a new set of ecological conditions.

Abstract: Compositions having improved sability which, when applied to a variety of substrates and cured, form transparent coatings having superior abrasion resistant properties. The coating compositions are aqueous-organic solvent mixtures containing a mixture of hydrolysis products and partial condensates of an epoxy functional silane and a tetrafunctional silane and a multifunctional compound selected from the group consisting of multifunctional carboxylic acids, multifunctional anhydrides and combinations thereof.

Abstract: Disclosed are novel methods for a protecting or preserving wood, wood composites and other cellulosic materials, and in addition, disrupting the feeding behavior and growth cycle of termites, wood-borers and other insects, by applying certain compositions thereto which contain azadirachtin carried in neem tree extracts. Disclosed are novel neem extract compositions for coating, penetrating, treating, and curing said cellulosic materials which are non-toxic and provide long active lifetimes. The compositions contain the neem extracts in combination with binding and bittering agents which enhance the effectiveness of the extracts.

Abstract: Disclosed are novel methods for a protecting or preserving wood, wood composites and other cellulosic materials, and in addition, disrupting the feeding behavior and growth cycle of termites, wood-borers and other insects, by applying certain compositions thereto which contain azadirachtin carried in neem tree extracts. Disclosed are novel neem extract compositions for coating, penetrating, treating, and curing said cellulosic materials which are non-toxic and provide long active lifetimes. The compositions contain the neem extracts in combination with binding and bittering agents which enhance the effectiveness of the extracts. The compositions are made from natural, active ingredients and are water resistant. The compositions are found to be non-reactive and non-toxic to vertebrates and non-polluting of surrounding soils. When used as intended in non-aerobic applications, the compositions are resistant to oxidation and ozonation. In addition, when used as intended in areas without sunlight, i.e.

Abstract: Provided is an artificial stone molded product in which protrusions or embedded grooves for a figure or a pattern are provided integrally on or in a flat surface of a substrate, and a main composition comprises an aggregate of an inorganic material and a resin, characterized in that

Abstract: A leather covering piece for a vehicle interior lining comprises a leather piece and an intermediate layer connected with the leather piece. A hardenable mass is applied onto the intermediate layer or the leather piece. The hardened mass gives the leather covering piece such an inherent rigidity that it maintains a curved shape and can be inserted into an injection mold. The stacking of prefabricated leather covering pieces is also possible. The shape of the leather covering piece already corresponds to that of the finished product, in particular of the vehicle interior lining for which it is used. The leather covering piece is back-molded in order to obtain a stable carrier piece which gives the entire interior lining more stability.

Abstract: The present invention relates to a coloured porous material comprising in its pores an effectively colouring amount of an organic pigment which is obtainable by fragmenting a meltable or solvent-soluble pigment precursor, and to a process for its preparation. The present invention also relates to the use of the instant coloured porous material powders as pigments for high molecular weight organic materials.

Abstract: Antifoulant compositions include 10,10′-oxybisphenoxarsine and/or phenarsazine oxide with a quaternary ammonium salt. The antifoulant compositions may also include adjuvants such as fungicides, ultraviolet absorbers, and antioxidants. The antifoulant compositions can be used in fresh or sea water paints. In addition, the antifoulant composition may be used to stain or impregnate wood, thus preserving the wood.

Abstract: The present invention is directed towards a tanned leather product that is impregnated with a plurality of microspheres containing a temperature stabilizing material. The present invention is also directed to a tanning process for embedding the microspheres into the leather. The thermal stabilizing material is a phase change material that allows the leather to have enhanced thermal properties when exposed to heat or cold.

Abstract: This invention relates to fluorochemical compositions, their preparation and their use as water- and oil-repellents, and substrates treated therewith. The fluorochemical composition comprises a mixture of fluorochemical compounds and/or polymers, each component having at least two fluoroaliphatic groups and a large hydrocarbon moiety such as derived from dimer acids, and the polymer having at least one fluoroaliphatic group and a plurality of said hydrocarbon moiety.

Abstract: A method for imparting water, oil or stain repellency to HARD SURFACES comprising application to the surface of an effective amount of a composition comprising monomers copolymerized in the following percentages by weight:(a) from about 40% to about 90% of at least one monomer of formula I:R.sub.f --Q--A--C(O)--C(R).dbd.CH.sub.2 IwhereinR.sub.f is a straight or branched-chain perfluoroalkyl group of 2 to about 20 carbon atoms,R is H or CH.sub.3,A is O, S, or NR.sub.1 wherein R.sub.1 is H or a C.sub.1 -C.sub.4 alkyl, and Q is alkylene of 1 to about 15 carbon atoms, hydroxyalkylene of 3 to about 15 carbon atoms,--(C.sub.n H.sub.2n) (OC.sub.q H.sub.2q).sub.m --, --SO.sub.2 --NR.sub.1 (C.sub.n H.sub.2n)-- or --CONR.sub.1 (C.sub.n H.sub.2n)-- wherein R.sub.1 is H or C.sub.1 -C.sub.4 alkyl, n is 1 to about 15, q is 2 to about 4, and m is 1 to about 15;(b) from about 2% to about 50% of a monomer of formula IIA or IIB or a mixture thereof:(CH.sub.2 .dbd.C(R)COZ(CH.sub.2).sub.r.sup.+ NR.sub.2 R.sub.3 R.sub.4)X.sup.

Abstract: The present invention provides a method for making a ceramic matrix composite comprising forming an infiltrated fiber reinforcement by infiltrating a plurality of plies of a fibrous material with a precursor polymer which decomposes to a substantially pure product selected from the group consisting of a refractory metal carbide and a refractory metal boride, and exposing the infiltrated fiber reinforcement to conditions effective to cure the precursor polymer and to decompose the precursor polymer to said substantially pure product.

Abstract: A method for impregnating rock or landscaping material with bio-active and/or colored fluid. To impregnate the rock or landscaping material with bio-active chemical, the rock or landscaping material is heated to dehydrate it, and cooled to an ambient temperature in a dehumidified chamber, and then placed in a pressurizable container which is filled with bio-active chemical. The pressurizable container is placed under pressure for a sufficient time that the bio-active fluid is forced into the interstices of the rock or landscaping material. When the rock or landscaping material is removed from the pressurizable container, it has been impregnated with bio-active chemical and gradually emits the bio-active chemical. The rock or landscaping material may be cleaned using water or a solvent. The bio-active chemical used can be a herbicide, pesticide, plant or insect growth hormones, repellents of cats, dogs, mice, or other pests, or fertilizers.

Abstract: Leather can be pretreated to obtain good body, soft feel, and excellent grain smoothness and solidity with products having a molecular weight of 700 to 30,000 and which are obtainable by reaction ofA. polysuccinimide having a molecular weight, determined as the number-average, of 500 to 10,000, withB. 5 to 90 mol % based on the succinimide units of polysuccinimide A, and/or secondary amine, the nitrogen substituents of which contain 1 to 60 carbon atoms and which can be unsubstituted or substituted, at least 2.5 mol % of the nitrogen substituents of the amine containing at least 12 carbon atoms,C. optionally, (i) derivatives of C.sub.1 -C.sub.18 -monocarboxylic acids, C.sub.2 -C.sub.10 -dicarboxylic acids, and/or (ii) monoisocyanates, diisocyanates epichlorohydrin (for reaction of amino and/or hydroxyl groups on the nitrogen substituents of the reaction product of A and B), andD. 95 to 10 mol % of ring-opening base in the presence of water.

Abstract: An antimicrobial agent comprising allyl isothiocyanate (AIT) packaged in a packaging material having a structure wherein part of the pores of a porous packaging substrate is filled with, or said pores are partially or entirely narrowed by a resin impervious to AIT vapor, and a method for controlling the AIT vapor release speed comprising enclosing AIT in the above-mentioned packaging material. According to the present invention, the AIT vapor release speed can be controlled, whereby enabling sustained release of AIT vapor and persistent effect of antimicrobial action. In addition, the antimicrobial agent of the present invention can be widely applied to food industries and various other fields where breeding and reproduction of deleterious microorganisms pose problems, since it is economical, compact and easy to use.

Abstract: The present invention is directed to a method of producing wear resistant traffic paint composition. In accordance with the method, a traffic marking of a traffic paint composition having low GPC number average molecular weight latex binder when applied to the road surface exhibits improved wear resistance over those traffic paint compositions having high GPC number average molecular weight latex binders. The wear resistance is further enhanced by modifying the latex polymer used in the composition with acetoacetyl functional pendant moiety and amino silane.

Abstract: A process for the formation of epoxy resin/hide composite materials is provided in which the components of epoxy resin systems (epoxy resin and hardener) are mixed at a temperature lower than that at which significant reaction between these reagents occurs. The epoxy resin system components are mixed into solution in an aprotic solvent, which prepares the epoxy resin system for impregnation into the hide. The hide, presoaked in an aprotic solvent for a period of time, is next placed in the epoxy resin system/aprotic solvent solution for a period of time, during which the hide is impregnated with the epoxy resin reactants. Once impregnated, the hide is removed from the solution, and the excess epoxy resin material is removed from the hide surface. Thereafter, the solvent may be evaporated from the system, although this step is optional. The impregnated hide is further processed at an elevated temperature (but at a temperature lower than that at which hide decomposes significantly--105.degree.-160.degree. C.

Abstract: Hide/leather-polymer composite materials are provided by the impregnation of polymer systems into interstitial void spaces in the collagen fiber network of the hide/leather precursors, providing a broad spectrum of composite materials possessing a wide variety of bulk mechanical properties. Preferably, the polymer systems employed in the inventive composites are bismaleimides, when high modulus, strength and flexural modulus are desired, and siloxane-based polymers, when elastomeric bulk properties are desired.

Abstract: A graphite lubricated leather and a method for producing a graphite lubricated leather is provided. A chrome tanned leather having internal fiber matrix is lubricated by application of a graphite powder suspended in a gluteraldehyde solution which has the effect of penetrating and bonding with the internal fiber matrix of the chrome tanned leather. A highly lubricated dry metallic appearing leather product is provided by the treatment.

Abstract: A method of protecting a porous material sensitive to corrosion caused by pollutants in the atmosphere. The method comprises treating the surface of the material with an agent containing more than 90% by weight of silica sol. The agent contains substantially no solid particles with a diameter exceeding about 1 micron. Porous building materials comprising a layer of gelled silica sol present in the pores below the material surface are prepared by the method.

Abstract: The invention provides a process for water-proofing gypsum materials which comprises adding, to a pulverulent gypsum plaster composition containing from 10 to 90% by weight of gypsum based on the total weight of the composition, a mixture ofa) from 1.0 to 15% by weight, based on the total weight of the composition, of one or more dispersion powders redispersible in water and based on vinyl acetate copolymers with ethylene and/or vinyl esters of C.sub.5 -C.sub.15 -monocarboxylic acids, styrene copolymers with acrylic esters of alcohols having from 1 to 18 carbon atoms, vinyl chloride copolymers with ethylene and/or vinyl esters of C.sub.2 -C.sub.15 monocarboxylic acids, andb) from 0.05 to 5.0% by weight, based on the total weight of the composition, of one or more thixotropic additives from the group consisting of polyacrylic acids and their salts, smectites, bentonites, carboxymethylcelluloses and melamine-formaldehyde condensates.

Abstract: A method for impregnating rock or mineral with scented and/or colored fluid. To impregnate the rock or mineral with scented fluid, the rock or mineral is heated to dehydrate it, and cooled to an ambient temperature in a dehumidified chamber, and then placed in a pressurizable container which is filled with scented fluid. The pressurizable container is placed under pressure for a sufficient time that the scented fluid is forced into the interstices of the rock or mineral. When the rock or mineral is removed from the pressurizable container, it has been impregnated with scented fluid and emits a pleasant odor. The rock or mineral may be cleaned using water or a solvent.

Abstract: There is described the use of compounds of the formula (II) ##STR1## in which R has the meaning given in the description, as root penetration inhibitors.

Abstract: Products of reaction of an aluminum compound (A), a boron-containing acid (B), a phosphorus-containing acid (P) and an amine (N) are characterized in that 1 mol of (A) has been reacted with from 0.3 to 1.19 mol of B, (from 1.8 to 2.19)+x mol of P and (from 0.3 to 3.69)+y mol of N, where x=from -1.5 to +1.5 and y=from 0 to 12. These reaction products may contain, if desired, up to 30 mol of water per mole of A employed and may be used in a very wide variety of ways, for example as binders, coating compositions or insulating material.

Abstract: There is disclosed a method for treating and protecting a substrate, said method comprising coating the surface of said substrate with a composition comprising a blend of(A) a polydimethylsiloxane polymer having a viscosity at 25.degree. C. of 5 to 100,000 cS; and(B) a polyisobutylene oligomer having a number average molecular weight of 200 to 550. The treatment imparts an aesthetically pleasing appearance to the surfaces of plastic, rubber or leather substrates whereby surface gloss is enhanced, but not excessively, as is the case for a comparable all-silicone treating agent.

Abstract: A novel coating for waterproofing and sealing a rigid structural unit using a styrene polymeric film cast from an organic solvent is disclosed. The coating is easily maintained as damaged areas and imperfections can be repaired by simply applying additional liquid composition to the damaged area, and the liquid composition remelts the existing film allowing the newly formed film to be continuous. In addition, the composition can be applied to structural units in sub-freezing temperatures or to wet surfaces. Novel methods relating to the use of the liquid coating composition are also disclosed.

Abstract: A composition which contains a 2-halo-2-halomethyl glutaronitrile and a 4,5-polymethylene-4-isothiazolin-3-one. The compositions exhibit anti-microbial activity and certain combinations of isothiazolinones together with the glutaronitrile are surprisingly effective against both bacteria and fungi.

Abstract: Disclosed are compositions for application to a surface to protect the surface from ultra-violet radiation, which include zinc oxide particles having a substantially rod shape.

Abstract: Natural and artificial animal skins are provided with randomly spaced protuberances which simulate natural quill marks of ostrich skins. The protuberances are created from die formed depressions into which is adhered an individual glob of hot melt material. The glob has a generally semi-spherical mass extending above the inner surface of the animal skin. During manufacture of articles therefrom, the globs have the tendency to accentuate the appearance of the quill marks.

Abstract: Materials, particularly wood materials and calcium carbonate-containing materials such as concrete and marble, can be protected from the growth of algae by being treated with a compound containing tin covalently bonded to a silylating group such that cleavage of the covalent bonds due to hydrolysis or photolysis is minimized, thus making the treatment ecologically safe. One such compound is (n-Bu).sub.3 SnCH.sub.2 CH.sub.2 Si(OEt).sub.3. The tin compound can either be incorporated into raw materials from which materials are to be made, or it can be applied to the finished materials. When the tin compound is applied to a material that is algae streaked, the streaking should disappear.

Abstract: A finished leather comprising a leather to which has been applied a fat liquoring and/or water repellant agent, and a particularly formulated polyurethane adhesive improving bottoming coat composition applied thereto.

Abstract: Oil- and water-repellency is imparted to the surface of a porous ceramic material, in particular of "cotto", by applying a phosphoric monoester having formula: ##STR1## where: L is a divalent organic group; m=1; Y is --F or --CF.sub.3 ;Z.sup.+ is a cation; R.sub.f is a polyperfluoroalkylene oxide chain.

Abstract: Cured aminoplast resins are recycled by a process in which said resins, which may contain fillers, are treated with an aqueous sulfite, hydrogen sulfite or disulfite solution and the resulting low molecular weight degradation products are used in chemical processes. The resulting low molecular weight degradation products of cured aminoplast resins are used for coating moldings, for tanning leather and skins and for the production of moldings which contain cured aminoplast resins or consist thereof.

Abstract: The invention concerns graft copolymers, useful for the treatment of leather, comprising monomers of the formula ##STR1## grafted onto a base polymer comprising monomers of the formula ##STR2## wherein R.sub.1 and R.sub.2 stand for a hydrocarbon group having 2 to 24 carbon atoms, with the proviso that the groups R.sub.1 and R.sub.2 have van der Waals volumes which differ from one another by less than 30 percent.

Abstract: A flexible laminate, wherein a substrate of leather carries a coating which enhances the appearance and/or the quality of the substrate, is formed between an anvil and a ram in a press. The coating has an inner layer which overlies and fills or nearly fills scratches and/or other unevennesses in one side of the substrate, and an outer layer which overlies the inner layer can be made of a plastic material. The outer layer is first applied to a flexible plastic or paper carrier, and the inner layer is sprayed or otherwise applied to the outer layer before the resulting coating is introduced into or conveyed through the clearance between the anvil and the ram. The exposed surface of the outer layer can be smooth or it can be profiled to imitate the grain of a particular type of leather, such as ostrich leather or alligator leather.

Abstract: Methods for treating siliceous and carbon central structures with a water repellant composition and a paint are provided. An effective amount of water repellant composition is dispersed in paint or in paint and water, and the mixture then is applied in a continuous process after mixing to the object to be treated.

Abstract: Building materials such as concrete can be protected from the growth of algae by being treated with a compound containing tin covalently bonded to a silylating group such that cleavage of the covalent bonds due to hydrolysis or photolysis is minimized, thus making the treatment ecologically safe. One such compound is (n-Bu).sub.3 SnCH.sub.2 CH.sub.2 Si(OEt).sub.3. The tin compound can either be incorporated into raw materials from which building materials are to be made, or it can be applied to the finished building materials. When the tin compound is applied to a building material that is algae streaked, the streaking should disappear.

Abstract: A concrete surface having at least a residual amount of sodium fluorophosphate. A method to reduce scaling due to freezing and thawing is also disclosed. The method comprises contacting the surface of a concrete with a system containing at least sodium fluorophosphate. The sodium fluorophosphate closes the pores to water and other foreign matter.