Vapor Deposition Or Gas Diffusion Patents (Class 428/938)
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Patent number: 8980117Abstract: Provided is a piezoelectric material having a high Curie temperature and satisfactory piezoelectric characteristics, the piezoelectric material being represented by the following general formula (1): A(ZnxTi(1-x))yM(1-y)O3??(1) where A represents a Bi element, M represents at least one element selected from Fe, Al, Sc, Mn, Y, Ga, and Yb; x represents a numerical value of 0.4?x?0.6; and y represents a numerical value of 0.17?y?0.60.Type: GrantFiled: January 1, 2010Date of Patent: March 17, 2015Assignees: Canon Kabushiki Kaisha, Tokyo Institute of Technology, Sophia University, National Institute of Advanced Industrial Science and TechnologyInventors: Makoto Kubota, Toshihiro Ifuku, Hiroshi Funakubo, Keisuke Yazawa, Hiroshi Uchida, Takashi Iijima, Bong-yeon Lee
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Patent number: 8900717Abstract: The present invention discloses methods for producing synthetic surfaces that mimic collagen coated surfaces for cell culture comprising: providing a monomer source comprising one or more organic compounds which are capable of polymerization, wherein at least one organic compound is prolinol; creating a plasma of said monomer source; and contacting at least a portion of a surface with the plasma to provide a plasma polymer coated surface. Advantageously, such methods provide an animal-free, synthetic, chemically defined surface that mimics a collagen coated surface for cell culture. Advantageously, such methods not only reduce the cost and/or issues associated with animal-derived collagen but are also amenable to large scale manufacturing.Type: GrantFiled: May 15, 2012Date of Patent: December 2, 2014Assignee: Corning IncorporatedInventors: Xiaoxi (Kevin) Chen, Kristina Parry, Anita Mistry, Deepa Saxena
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Patent number: 7892654Abstract: Coating steel strips comprising, in % by weight, C: ?1.6%, Mn: 6-30%, Al: ?10%, Ni: ?10%, Cr: ?10%, Si: ?8%, Cu: ?3%, Nb: ?0.6%, Ti: ?0.3%, V: ?0.3%, P: ?0.1%, B: ?0.01%, the rest being iron and unavoidable impurities, and a method of forming steel strips are described. Up to now, such steel strips were not adequately coatable, with a metal coating ensuring outstanding corrosion-resistance and good welding properties. This is ensured by applying an aluminium layer to the steel strip before final annealing and applying the metal coating to said aluminium layer after final annealing.Type: GrantFiled: February 1, 2006Date of Patent: February 22, 2011Assignee: ThyssenKrupp Steel AGInventors: Harald Hofmann, Manfred Meurer, Bernd Schuhmacher, Slavcho Topalski
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Patent number: 7758925Abstract: A method for preparing a protective layer (38) on a surface of the substrate (36) that requires a bonding temperature (BT) above a detrimental phase transformation temperature range (28) of the substrate, and then cooling the layer and substrate without cracking the layer or detrimentally transforming the substrate. The protective layer (38) and the substrate (36) are cooled from the bonding temperature (BT) to a temperature (46) above the detrimental phase transformation range (28) at a first cooling rate (30) slow enough to avoid cracking the protective layer. Next, the protective layer and the substrate are cooled to a temperature below the detrimental phase transformation range of the substrate at a second cooling rate (27) fast enough to pass the detrimental phase transformation range before a substantial transformation of the substrate into the detrimental phase can occur.Type: GrantFiled: September 21, 2007Date of Patent: July 20, 2010Assignee: Siemens Energy, Inc.Inventor: Brij B. Seth
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Patent number: 7575418Abstract: Disclosed herein is a turbine component comprising a substrate; and a protective structure formed on the substrate, wherein the protective structure comprises an ?-? titanium alloy, a ?-titanium alloy or a near-? titanium alloy. Disclosed herein too is a process for providing a protective structure to a turbine component, comprising affixing a protective structure on a turbine component; wherein the protective structure comprises an ?-? titanium alloy, a near-? titanium alloy or a ?-titanium alloy.Type: GrantFiled: September 30, 2004Date of Patent: August 18, 2009Assignee: General Electric CompanyInventors: Michael Francis Xavier Gigliotti, Canan Uslu Hardwicke, Liang Jiang, Don Mark Lipkin, Samuel Vinod Thamboo
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Patent number: 7273662Abstract: An alloy including a Pt-group metal, Ni and Al in relative concentration to provide a ?-Ni+??-Ni3Al phase constitution, and a coating including the alloy.Type: GrantFiled: May 16, 2003Date of Patent: September 25, 2007Assignee: Iowa State University Research Foundation, Inc.Inventors: Brian Gleeson, Daniel Sordelet, Wen Wang
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Patent number: 7241511Abstract: A rubber based composite material having a rubber composition and, adhered thereto, a reinforcing material having a coating film containing a metal or a metal compound capable of reacting with sulfur formed on the surface of the material, characterized in that the oxygen content in the coating film increases toward the reinforcing material in the thickness direction.Type: GrantFiled: May 14, 2003Date of Patent: July 10, 2007Assignee: Bridgestone CorporationInventors: Kenji Sato, Shinichiro Sugi, Nobuko Kato, Kenichi Sugimoto
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Patent number: 7238429Abstract: Performance and reliability of microelectromechanical system (MEMS) components enhanced dramatically through the incorporation of protective thin film coatings. Current-generation MEMS devices prepared by the LIGA technique employ transition metals such as Ni, Cu, Fe, or alloys thereof, and hence lack stability in oxidizing, corrosive, and/or high temperature environments. Fabrication of a superhard, self-lubricating coating based on a ternary boride compound AlMgB14 is described in this letter as a potential breakthrough in protective coating technology for LIGA microdevices. Nanoindentation tests show that hardness of AlMgB14 films prepared by pulsed laser deposition ranges from 45 GPa to 51 GPa, when deposited at room temperature and 573 K, respectively. Extremely low friction coefficients of 0.04-0.05, which are thought to result from a self-lubricating effect, have also been confirmed by nanoscratch tests on the AlMgB14 films.Type: GrantFiled: September 21, 2004Date of Patent: July 3, 2007Assignee: Iowa State University Research Foundation, Inc.Inventors: Bruce Allan Cook, Yun Tian, Joel Lee Harringa, Alan Paul Constant, Alan Mark Russell, Palaniappa A. Molian
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Patent number: 7101591Abstract: This invention provides a process for producing an organic polymer film whereby when using it as an interlayer insulating film in a semiconductor device, the film exhibits higher adhesiveness at its interfaces where other semiconductor materials are in contact with the lower and the upper surface of the film while an effective dielectric constant in the whole organic polymer film can be further reduced. Specifically, a plurality of organic monomers vaporized is sprayed onto a heated substrate surface via plasma generated in a reaction chamber to form a copolymer film comprising frame composed of a plurality of organic monomer units.Type: GrantFiled: July 1, 2002Date of Patent: September 5, 2006Assignee: NEC CorporationInventors: Yoshihiro Hayashi, Jun Kawahara
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Patent number: 7060367Abstract: A blade with improved sharpness and durability is disclosed. The blade includes a base plate having an edge and a coating layer for coating the edge. The coating layer is formed of a material handling metal, and a tip of the coating layer is sharpened. It is preferred that an angle (Ba) between two tapered surfaces be between 15 to 45 degrees.Type: GrantFiled: June 4, 2001Date of Patent: June 13, 2006Assignee: Kai R&D Center Co., Ltd.Inventors: Katsuaki Yamada, Hiroshi Ohtsubo, Hiroyuki Tashita
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Patent number: 7049009Abstract: A method of sputter depositing silver selenide and controlling the stoichiometry and nodular defect formations of a sputter deposited silver-selenide film. The method includes depositing silver-selenide using a sputter deposition process at a pressure of about 0.3 mTorr to about 10 mTorr. In accordance with one aspect of the invention, an RF sputter deposition process may be used preferably at pressures of about 2 mTorr to about 3 mTorr. In accordance with another aspect of the invention, a pulse DC sputter deposition process may be used preferably at pressures of about 4 mTorr to about 5 mTorr.Type: GrantFiled: December 16, 2004Date of Patent: May 23, 2006Assignee: Micron Technology, Inc.Inventors: Jiutao Li, Keith Hampton, Allen McTeer
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Patent number: 7026057Abstract: A new article of manufacture, for example a faucet or other article of hardware, has a specified decorative color, and is resistant to corrosion, abrasion and attack by chemicals. The article includes a substrate, one or more corrosion resistant layers applied to the substrate, a thin transition layer having a composition that varies systematically from a first composition to a second composition and in which the first composition has, at least in part, the function of corrosion protection, and in which the second composition determines the visible color or that portion of the substrate to which the transition layer is applied.Type: GrantFiled: January 23, 2002Date of Patent: April 11, 2006Assignee: Moen IncorporatedInventors: James G. Sheek, Jarek Grembowicz, Inho Song, Timothy J. O'Brien
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Patent number: 7018720Abstract: The layer sequence built on a substrate in thin-film technology includes an electrically conductive sputtered layer and an electrically conductive reinforcing layer for reinforcing or strengthening the sputtered layer, which is applied on the sputtered layer by a method other than sputtering. In order to remove conducting material from the conductive layers with the aid of a laser for the purposes of adjustment while producing as little contaminating material as possible, the electrically conductive reinforcing layer has a reduced thickness or is completely eliminated in regions of the electrically conductive layers to be adjusted than in other regions outside of the regions to be adjusted.Type: GrantFiled: March 21, 2000Date of Patent: March 28, 2006Assignee: Robert Bosch GmbHInventors: Martin Schallner, Soeren Steinert
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Patent number: 6984453Abstract: An object is the provision of a peelable electrodeposited copper foil with carrier foil that stabilizes the peel strength between the carrier foil and the electrodeposited copper foil layer even when used in manufacture of the printed wiring boards that requires pressing at the temperatures of 200° C. or higher. For the purpose of achieving the object, the electrodeposited copper foil with carrier foil 1, which includes an adhesive interface layer 4 arranged on one face of the carrier foil 2 and an electrodeposited copper foil layer 3 arranged on the adhesive interface layer 4, characterized in that the adhesive interface layer 4 is composed of a metal oxide layer ML and an organic material layer OL, and the like are used.Type: GrantFiled: December 12, 2002Date of Patent: January 10, 2006Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Akiko Sugimoto, Junshi Yoshioka, Makoto Dobashi
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Patent number: 6933053Abstract: In accordance with one aspect of the present invention, a process for forming a specific reactive element barrier on a titanium and aluminum containing substrate is provided. The process includes creating a dry air atmosphere with a concentration of water vapor below about 750 ppm at a temperature above about 550° C. contiguous to a surface of the substrate on which the barrier layer is to be formed. The temperature is maintained above 550° C. and the water vapor concentration is maintained below about 100 ppm while the water vapor in the dry air atmosphere is reacted with specific reactive elements at the substrate surface. The reaction forms a specific reactive element oxide barrier layer which is strongly bonded to the substrate surface. The barrier layer includes an aluminum oxide layer at the substrate/barrier layer interface and a second oxide layer at a barrier layer/atmosphere interface.Type: GrantFiled: March 18, 2003Date of Patent: August 23, 2005Inventor: Donald L. Alger
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Patent number: 6913839Abstract: A coated article having a high resistance to particle-impact damage has a substrate, and a layered coating overlying the substrate. The layered coating includes a substantially continuous quasicrystalline layer, and a substantially continuous ductile metallic layer in facing contact with the quasicrystalline layer. The coated article is preferably used in applications where it is subjected to particle-impact conditions.Type: GrantFiled: February 28, 2003Date of Patent: July 5, 2005Assignee: General Electric CompanyInventors: Ramgopal Darolia, Robert Edward Schafrik
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Patent number: 6881498Abstract: A surface processing method and power transmission component includes refining a surface region of a metal from a first roughness to a second roughness less than the first roughness. A solid lubricous coating or a hard coating is then deposited on the surface region. The metal has a surface hardness above 50 Rc to reduce the risk that the metal will deform under the coating and leave the coating unsupported. The surface region of the metal may be transformed into a nitrogen-containing compound or solid solution surface region before the surface refining step and deposition of the coating.Type: GrantFiled: June 24, 2004Date of Patent: April 19, 2005Assignee: Sikorsky Aircraft CorporationInventors: Clark VanTine Cooper, Harsh Vinayak
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Patent number: 6855437Abstract: The subject of the invention is a layer system for the decorative coating of galvanizable work pieces. In order to have a layer system which meets strict requirements with regard to corrosion resistance and which, at the same time, has a high abrasion resistance and, in addition, provides a high degree of freedom with regard to decorative coloration, the invention proposes a layer system which is formed by galvanic deposition and comprises a base coat consisting of at least one bright layer and one discontinuous chrome layer as well as a cover coat of mechanically resistant materials deposited by the PVD process.Type: GrantFiled: January 26, 2001Date of Patent: February 15, 2005Assignee: Enthone Inc.Inventors: Hiltrud Tolls, Elmar Tolls
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Patent number: 6849344Abstract: A titanium article having improved corrosion resistance resulting from a direct or indirect attachment of a platinum group metal or alloy thereof or incorporation of this metal or alloy thereof into a minor surface portion of the article.Type: GrantFiled: June 3, 2003Date of Patent: February 1, 2005Assignee: Titanium Metals Corp.Inventors: James S. Grauman, James G. Miller, Roy E. Adams
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Publication number: 20040234736Abstract: Materials such as titanium are vapor-deposited to form a film on a substrate while the substrate is thermally coupled to a temperature-controlling thermal source. Varying the temperature conditions of the substrate when the film is deposited varies the intrinsic stress of the film, which varies the change in substrate shape caused by the presence of the film. A film having a desired intrinsic stress may be obtained by control of the substrate temperature when the film is deposited. A stress-controlled titanium film may be used, for example, as an adhesion layer between a silicon movable structure in an optical MEMS device and a gold layer serving as a reflecting surface.Type: ApplicationFiled: May 20, 2003Publication date: November 25, 2004Inventors: Ho Bun Chan, Martin Haueis
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Patent number: 6822880Abstract: A thin film hydrogen getter and EMI shielding are provided for protecting GaAs circuitry sealed in an hermetic package. The thin film getter comprises a multilayer metal film that is deposited by vacuum evaporation techniques onto a conductive metal, such as aluminum or copper, that serves as the EMI shielding. The conductive layer is first formed on an interior surface. The multilayer hydrogen getter film comprises (1) a titanium film and (2) a palladium film that is deposited on the titanium film. Both the titanium and the palladium are deposited during the same coating process run, thereby preventing the titanium from being oxidized. The palladium continues to prevent the titanium from being oxidized once the getter is exposed to the atmosphere. However, hydrogen is easily able to diffuse through the palladium into the titanium where it is chemically bound up, since palladium is highly permeable to hydrogen.Type: GrantFiled: November 25, 2003Date of Patent: November 23, 2004Assignee: Raytheon CompanyInventors: Alan L. Kovacs, Matthew H. Peter, Kurt S. Ketola, Jacques F. Linder
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Publication number: 20040191556Abstract: A comparatively high vacuum pressure method of manufacturing two-way shape memory effect devices produces devices having a compositional gradient through the thickness of a film of shape memory alloy. The shape memory alloy film exhibits two-way shape memory effect, which is useful for fabricating cyclical actuating devices without need of a biasing mechanism. Examples of shape memory alloys include Ni:Ti-, Au:Cd-, Fe:Mn:Si- and Cu:Ni:Al-based binary, ternary and higher order alloys. Three-dimensional devices may be mass produced using the shape memory alloy and process.Type: ApplicationFiled: December 11, 2003Publication date: September 30, 2004Inventor: Peter A. Jardine
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Patent number: 6749951Abstract: A coated article having a high resistance to wear damage has a substrate, and a layered coating overlying the substrate. The layered coating includes a ductile metallic layer overlying and in facing contact with the substrate, and a protective layer overlying and in facing contact with the ductile metallic layer and including a mixture of a quasicrystalline metallic phase and a non-quasicrystalline ductile phase. The coated article is preferably used in applications where it is subjected to wear conditions.Type: GrantFiled: March 14, 2003Date of Patent: June 15, 2004Assignee: General Electric CompanyInventors: Ramgopal Darolia, Robert Edward Schafrik
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Patent number: 6730415Abstract: A film is formed on the surface of a soft metal portion (2) such that the film contains phosphorus and either platinum or palladium, and further, at least one element having homogeneous solubility with platinum or palladium, with the content of the phosphorus being in a range of about 15 to 25 atomic %, or contains boron and iron with the content of the boron being in a range of from about 15 to 25 atomic %. Thus, a soft metal is made up by turning the film into a hard layer (3) made of an amorphous alloy.Type: GrantFiled: April 19, 2002Date of Patent: May 4, 2004Assignee: Citizen Watch Co., Ltd.Inventors: Yoshitsugu Shibuya, Eigou Hashimoto, Junji Satoh, Masahiro Satoh, Seiichi Hiroe
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Publication number: 20040081833Abstract: The present invention is directed to a process for depositing at least one layer (3) based on tungsten and/or on molybdenum by chemical vapor deposition on a non-conductive substrate (1), such as glass, ceramic, glass-ceramic, or polymer, which includes providing at least one tungsten- and/or molybdenum-containing precursor in the form of a metal halide and/or of an organometallic compound, and at least one reducing agent, such as hydrogen or silane, to form the at least one metal layer. The present invention also relates to the substrate obtained by the preceding process and its applications, especially for producing a glazing, mirrors, or emissive screens.Type: ApplicationFiled: October 9, 2003Publication date: April 29, 2004Applicant: Saint-Gobain VitrageInventor: Georges Zagdoun
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Patent number: 6720088Abstract: A group of alloys suitable for use in a high-temperature, oxidative environment, a protective coating system comprising a diffusion barrier that comprises an alloy selected from the group, an article comprising the diffusion barrier layer, and a method for protecting an article from a high-temperature oxidative environment comprising disposing the diffusion barrier layer onto a substrate are presented.Type: GrantFiled: February 5, 2002Date of Patent: April 13, 2004Assignee: General Electric CompanyInventors: Ji-Cheng Zhao, Melvin Robert Jackson, Richard John Grylls, Ramgopal Darolia
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Patent number: 6699593Abstract: A highly corrosion-resistant material and a corrosion-resistant member which are improved in corrosion resistance, adhesion, contact electrical resistance, electrical conductivity, airtightness, etc. and are suitable for use as, e.g., a metallic separator for polymer electrolyte fuel cells (PEFC); and a process for producing them. A thin noble-metal layer is formed on the desired part of the surface of a metallic base and then subjected to compression working. The coated base may further be subjected to anticorrosive treatment with a liquid phase containing a peroxide or ozone or with an active gas atmosphere.Type: GrantFiled: February 28, 2002Date of Patent: March 2, 2004Assignee: Daido Tokushuko Kabushiki KaishaInventors: Yasushi Kaneta, Shinobu Takagi, Hiroaki Yoshida, Yoshihisa Suzuki, Masaki Shinkawa
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Publication number: 20040038068Abstract: A multi-layer coating including a polymeric basecoat layer wherein the polymer of the basecoat layer is cured at subatmospheric pressure.Type: ApplicationFiled: August 26, 2002Publication date: February 26, 2004Inventors: John G. Finch, Joseph A. Elmer, Daniel E. Ford, Patrick A. Sullivan, Robert C. Bishop
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Patent number: 6682828Abstract: The coating plant includes a device for running a sheet to be coated along a traveling path past a window for the evaporation or sublimation of elements A an B, sources for the evaporation or sublimation of elements A and element B placed successively in a direction parallel to the traveling path so as to emit elements A and B through the window and a screen for reducing the angle of emission from the source of element B below the limit represented by an exit edge of the window, the screen being mounted so as to move translationally perpendicular to the traveling path and to move along the traveling path between the source of element A and the source of element B so as to obtain either a —A—AB—A— or a —B—AB—B—coating.Type: GrantFiled: July 22, 2002Date of Patent: January 27, 2004Assignee: UsinorInventors: Daniel Chaleix, Patrick Choquet, Alain Lamande, Colin Scott, Christophe Olier
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Publication number: 20030232214Abstract: A method is provided for making vehicle trim components that have a layer(s) including chromium (Cr), in metallic, oxide, nitride, and/or carbide form. In certain embodiments, a Cr inclusive gas is used in conjunction with a vapor deposition apparatus (e.g., PECVD apparatus) in order to form a Cr inclusive layer on a substrate. In certain example embodiments, the substrate may be provided with a conductive layer thereon, and may be electrically biased in the deposition chamber. The Cr inclusive layer may be at least partially amorphous in certain example embodiments.Type: ApplicationFiled: June 18, 2002Publication date: December 18, 2003Inventor: Vijayen S. Veerasamy
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Patent number: 6652991Abstract: The addition of small amounts of CeO2 and Cr to intermetallic compositions of NiAl and FeAl improves ductility, thermal stability, thermal shock resistance, and resistance to oxidation, sulphidization and carburization.Type: GrantFiled: October 9, 2002Date of Patent: November 25, 2003Assignee: The Governors of the University of AlbertaInventors: You Wang, Weixing Chen
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Patent number: 6617044Abstract: A surface treating process according to the present invention, a vapor deposited film is formed from an easily oxidizable vapor-depositing material on the surface of a work by evaporating the vapor-depositing material in a state in which the vapor deposition controlling gas has been supplied to at least zones near a melting/evaporating source and the work within a treating chamber. Thus, the vapor deposited film can be formed stably on the surface of a desired work without requirement of a long time for providing a high degree of vacuum and without use of a special apparatus. In addition, the use of the surface treating process ensures that a corrosion resistance can be provided to a rare earth metal-based permanent magnet extremely liable to be oxidized, without degradation of a high magnetic characteristic of the magnet.Type: GrantFiled: March 12, 2002Date of Patent: September 9, 2003Assignee: Sumitomo Special Metals Co., Ltd.Inventors: Takeshi Nishiuchi, Yoshimi Tochishita, Fumiaki Kikui, Mitsuo Kizawa
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Patent number: 6613445Abstract: A method for forming a metal-containing layer on a substrate is disclosed. A slurry of the metal is first deposited on the substrate; followed by heating to remove volatile material from the slurry, and to form a layer of the metal. In another embodiment, a slurry of aluminum is deposited over the slurry of the metal, before or after the metal has been heat-treated to some degree. A diffusion heat treatment results in a coating which includes the noble-metal aluminide compound. Related articles are also disclosed.Type: GrantFiled: January 16, 2002Date of Patent: September 2, 2003Assignee: General Electric CompanyInventors: D. Sangeeta, Howard John Farr
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Patent number: 6613452Abstract: A system and method for producing a corrosion-resistant article includes a metal substrate and a multi-layer resistant coating disposed over the metal substrate. The coating is operable to resist corrosion and hydrogen embrittlement of the metal substrate. The coating includes a first layer comprising a material galvanically similar to the metal substrate. The coating also includes a second layer disposed over the first layer. The second layer comprises a metal anodic to the metal substrate. The corrosion resistant article may also include a corrosion resistant interface layer at the boundary of the first and second layers. The interface layer may be formed by diffusing a portion of the second layer into the first layer.Type: GrantFiled: January 16, 2001Date of Patent: September 2, 2003Assignee: Northrop Grumman CorporationInventor: John Douglas Weir
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Publication number: 20030162048Abstract: The present invention discloses devices and a method of fabrication of devices using a shape memory effect, thin film with a compositional gradient through the thickness of the film. Specifically, a NiTi SME thin film is disclosed that can be used in actuators, MEMS devices and flow control. The process of fabrication includes a gradual heating of the target over time during the sputter deposition of a thin film on a substrate under high vacuum, without compositional modification. The resulting thin film exhibits two-way shape memory effect that can be cyclically applied without an external bias force.Type: ApplicationFiled: October 28, 2002Publication date: August 28, 2003Inventors: Ken K. Ho, Gregory P. Carman, Peter A. Jardine
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Material treatment for reduced cutting energy and improved temperature capability of honeycomb seals
Patent number: 6610416Abstract: The present invention provides for a method to reduce the strength of the honeycomb of a jet turbine stator, increasing its machinability, with a resultant reduction in measured peak tooth temperature, while maintaining or even improving its high temperature capability, so as not to limit its operating environment. The air seal functionality is unaffected, and even improved in some instances. The machinability of the honeycomb is increased by using a light element diffused into the honeycomb ribbon to produce the effect of reducing its strength and ductility while maintaining the environmental resistance needed. The present invention also includes the stator honeycomb produced by the foregoing method.Type: GrantFiled: April 26, 2001Date of Patent: August 26, 2003Assignee: General Electric CompanyInventors: Thomas Tracy Wallace, Brent Ross Tholke -
Publication number: 20030157378Abstract: A film forming method comprising: supplying a reactive gas comprising a compound including a metal atom between facing electrodes; arranging a substrate between the electrodes; making the reactive gas in a plasma state by applying a voltage between the electrodes under atmospheric pressure or under a pressure in a vicinity of the atmospheric pressure and discharging; and forming a metal film on a surface of the substrate by supplying a reducing gas having a reducing property into a plasma atmosphere in which the reactive gas in the plasma state exists.Type: ApplicationFiled: February 11, 2003Publication date: August 21, 2003Inventors: Wataru Mizuno, Kazuhiro Fukuda, Yoshikazu Kondo, Yoshiro Toda, Kiyoshi Oishi, Akira Nishiwaki
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Patent number: 6607846Abstract: A titanium article having improved corrosion resistance resulting from an appliqué of a platinum group metal or alloy thereof attached to a minor surface portion of the article.Type: GrantFiled: September 25, 2002Date of Patent: August 19, 2003Assignee: Titanium Metals CorporationInventors: James S. Grauman, James G. Miller, Roy E. Adams
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Publication number: 20030152799Abstract: A coated superalloy article is prepared by furnishing a nickel-base superalloy article substrate having a rhenium content of not less than about 4.0 percent by weight, and thereafter depositing an aluminum-containing coating onto a surface of the article substrate. The aluminum-containing coating includes an additive zone having an average aluminum content of not greater than about 27 percent by weight, and a diffusion zone of interdiffusion with the article substrate. A ratio of a thickness of the additive zone to a thickness of the diffusion zone is not greater than about 3:1, and is preferably about 1:1.Type: ApplicationFiled: February 8, 2002Publication date: August 14, 2003Inventors: Theodore Robert Grossman, Ronald Gustav Rajala, Dwayne Edward Burnett, William Scott Walston, Wendy Howard Murphy
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Patent number: 6599636Abstract: A titanium aluminide substrate (4) is vulnerable to air oxidation, limiting the use of this substrate in a variety of industrial applications, including the aircraft and aerospace industries. A bilayer reactive barrier (2) is formed on a titanium aluminide substrate. The barrier layer includes an &agr;-Al2O3 layer (6) from the reaction of oxygen from the disassociation of water with alumina in a gaseous and water vapor atmosphere at high temperatures and low oxygen concentration. During the process, titanium migrates through the &agr;-Al2O3 to a gas/barrier layer surface (14) and is oxidized to form a Ti2O3 layer (8). A surface of the Ti2O3 layer is subsequently oxidized to form a TiO2 layer (12). In this manner, a triple layer barrier is formed in which the immersible TiO2 and &agr;-Al2O3 are separated by Ti2O3. The three layers are bonded to each with a bond strength greater than 4500 kPa.Type: GrantFiled: October 31, 2000Date of Patent: July 29, 2003Inventor: Donald L. Alger
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Patent number: 6586114Abstract: An article, particularly a metallic article, is coated with a multi-layer coating having the color or appearance of dark copper. The coating comprises a chromium, refractory metal or refractory metal alloy adhesion promoting layer, a titanium-zirconium alloy nitride or titanium-zirconium alloy carbonitride protective and color layer, and a titanium-zirconium alloy oxide or titanium-zirconium oxynitride color enhancing layer.Type: GrantFiled: July 24, 2002Date of Patent: July 1, 2003Assignee: Vapor Technologies, Inc.Inventor: Bryce Randolph Anton
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Patent number: 6544669Abstract: A method of making cookware and bakeware having a stick resistant and mar resistant cook surface comprising the steps of providing a cooking utensil having a cook surface, and cryogenically treating the cooking utensil at one or more selected temperatures comprising −100° F. to −300° F. or lower to harden said cook surface. The cooking utensil may have a bare metal cook surface, or it may be coated with a stick resistant coating such as one of a PTFE, metal nitride or sulfide coating or combinations thereof prior to the cryogenic hardening treatment.Type: GrantFiled: August 24, 2001Date of Patent: April 8, 2003Assignee: Clad Metals LLCInventor: William A. Groll
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Publication number: 20030059634Abstract: A personal ornament having a white coating layer comprises a base article made of a metal, and a white-colored stainless steel coating layer formed by a dry plating process on at least a part of the surface of the base article. Another personal ornament having a white coating layer comprises a base article made of a nonferrous metal, an underlying plating layer formed on the surface of the base article, and a white-colored stainless steel coating layer formed by a dry plating process on at least a part of the surface of the underlying plating layer.Type: ApplicationFiled: February 26, 2002Publication date: March 27, 2003Inventors: Koichi Naoi, Akiyoshi Takagi, Yukio Miya, Fumio Tase, Kazumi Hamano
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Publication number: 20030047139Abstract: A method of introducing small amounts of a refractory element into a vapor deposition coating. A second material (30), containing at least two elements which are desired to be deposited as a coating on a base material, has placed over it a first material (20) substantially comprising such two elements and a refractory element. The first material (20) is adapted to permit transport of the at least two elements in the second material (30) through the first material (20) when the first (20) and second (30) material are in a molten state and in touching contact with the other so as to permit evaporation of the two elements and the refractory element from an exposed surface. Heat is supplied to the first (20) and second (30) materials to permit evaporation of the at least two elements of second material (30) and the refractory element in the first material (20), and the resulting vapors are condensed as a deposit on a base material (50).Type: ApplicationFiled: October 16, 2002Publication date: March 13, 2003Inventors: Reed Roeder Corderman, Melvin Robert Jackson, Richard Arthur Nardi
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Publication number: 20030031882Abstract: Non-flat surfaces, such as domes with complex curves, are coated with particle specks of genuine gold deposited onto a film substrate layer. The particles are made from vapor deposited or sputter deposited genuine gold upon film laminates, which are preferably segmented and cut to form the genuine gold particle specks. These genuine gold particle specks are mixed in a resin binder and sprayed upon the non-flat surfaces, forming a visually seamless cover upon the non-flat surface.Type: ApplicationFiled: August 3, 2002Publication date: February 13, 2003Inventor: Charles E. Quick
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Patent number: 6517954Abstract: The invention relates to an aluminium alloy, in particular for a layer of a friction bearing, for example, which, apart from aluminium and smelt-related impurities, additionally contains soft-phase formers, e.g. Sn, Pb, Bi, Sb or similar. The alloy contains added quantities of at least one element from the group of elements consisting of Sc, Y, Hf, Nb, Ta, La, lanthanides and actinides in a maximum of 10% by weight, preferably 4% by weight, in particular between 0.015% by weight and 3.25% by weight, relative to 100% by weight of alloy, the remainder being aluminium with smelt-related impurities.Type: GrantFiled: December 8, 2000Date of Patent: February 11, 2003Assignee: Miba Gleitlager AktiengesellschaftInventors: Robert Mergen, Markus Manner
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Patent number: 6506503Abstract: The invention relates to an intermediate layer, in particular a bonding layer, made from an alloy with an aluminium base, for multi-layered materials with layers of differing composition, in particular friction bearings. The alloy contains added quantities of at least one element from a group of elements consisting of Sc, Y, Hf, Nb, Ta, La, lanthanides and actinides in a maximum of 10% by weight, preferably 4% by weight, in particular between 0.015% by weight and 3.25% by weight, relative to 100% by weight of alloy, the remainder being aluminium with smelt-related impurities.Type: GrantFiled: February 26, 2001Date of Patent: January 14, 2003Assignee: Miba Gleitlager AktiengesellschaftInventors: Robert Mergen, Markus Manner
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Patent number: 6503641Abstract: An electrical conductor for use in an electronic structure is disclosed which includes a conductor body that is formed of an alloy including between about 0.001 atomic % and about 2 atomic % of an element selected from the group consisting of Ti, Zr, In, Sn and Hf; and a liner abutting the conductor body which is formed of an alloy that includes Ta, W, Ti, Nb and V. The invention further discloses a liner for use in a semiconductor interconnect that is formed of a material selected from the group consisting of Ti, Hf, In, Sn, Zr and alloys thereof, TiCu3, Ta1−XTix, Ta1−X, Hfx, Ta1−X, Inxy, Ta1−XSnx, Ta1−XZrx.Type: GrantFiled: December 18, 2000Date of Patent: January 7, 2003Assignee: International Business Machines CorporationInventors: Cyril Cabral, Jr., Roy Arthur Carruthers, James McKell Edwin Harper, Chao-Kun Hu, Kim Yang Lee, Ismail Cevdet Noyan, Robert Rosenberg, Thomas McCarroll Shaw
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Publication number: 20020187363Abstract: The coating plant includes a device for running a sheet to be coated along a traveling path past a window for the evaporation or sublimation of elements A an B, sources for the evaporation or sublimation of elements A and element B placed successively in a direction parallel to the traveling path so as to emit elements A and B through the window and a screen for reducing the angle of emission from the source of element B below the limit represented by an exit edge of the window, the screen being mounted so as to move translationally perpendicular to the traveling path and to move along the traveling path between the source of element A and the source of element B so as to obtain either a —A—AB—A— or a —B—AB—B—coating.Type: ApplicationFiled: July 22, 2002Publication date: December 12, 2002Applicant: USINORInventors: Daniel Chaleix, Patrick Choquet, Alain Lamande, Colin Scott, Christophe Olier
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Publication number: 20020182436Abstract: Reactive foils and their uses are provided as localized heat sources useful, for example, in ignition, joining and propulsion. An improved reactive foil is preferably a freestanding multilayered foil structure made up of alternating layers selected from materials that will react with one another in an exothermic and self-propagating reaction. Upon reacting, this foil supplies highly localized heat energy that may be applied, for example, to joining layers, or directly to bulk materials that are to be joined. This foil heat-source allows rapid bonding to occur at room temperature in virtually any environment (e.g., air, vacuum, water, etc.). If a joining material is used, the foil reaction will supply enough heat to melt the joining materials, which upon cooling will form a strong bond, joining two or more bulk materials. If no joining material is used, the foil reaction supplies heat directly to at least two bulk materials, melting a portion of each bulk, which upon cooling, form a strong bond.Type: ApplicationFiled: April 18, 2002Publication date: December 5, 2002Inventors: Timothy P. Weihs, Todd Hufnagel, Omar Knio, Michael Reiss, David van Heerden, Howard Feldmesser