Abstract: Disclosed is a lithium secondary battery, which is low in capacity loss after overdischarge, having excellent capacity restorability after overdischarge and shows an effect of preventing a battery from swelling at a high temperature.

Abstract: Disclosed is an electrolyte for a rechargeable lithium battery and a rechargeable lithium battery including the same. The electrolyte includes a lithium salt, a trialkylsilyl cyanide compound represented by the following Chemical Formula 1, and an organic solvent. In the above Chemical Formula 1, R1 to R3 are the same or different, and selected from C1 to C6 alkyls.

Abstract: Disclosed are a nonaqueous electrolyte for a lithium secondary battery containing a hetero polycyclic compound and a lithium secondary battery using the same.

Abstract: A nonaqueous secondary battery comprising: a positive electrode; a negative electrode; and a nonaqueous electrolyte solution, wherein the nonaqueous electrolyte solution contains: a cyclic nitrogen-containing compound represented by the general formula (1): wherein X represents an optionally branched divalent group derived from a chain saturated hydrocarbon and having 1 to 5 carbon atoms, ?C?CH2, ?C?O, ?C?S?O, ?O or ?S, and A1 and A2 may be the same or different and each represent an optionally substituted methylene group, ?C?O or ?SO2; and an amine derivative represented by the general formula (2): wherein R5 to R7 may be the same or different and each represent a hydrogen atom, or an optionally substituted lower alkyl group, lower alkenyl group, lower alkoxy group, lower alkylcarbonyloxy group, lower alkylcarbonyl group, lower cycloalkyl group or aryl group.

Abstract: A non-aqueous electrolyte usable in rechargeable lithium-ion batteries including a solution of LiPF6/carbonate based electrolytes with low concentrations of LiFOP such that the thermal stability is increased compared to a standard lithium battery. A method of making lithium tetrafluorophospahte (LiF4C2O4, LiFOP) including, reacting PF5 with lithium oxalate, recrystallizing DMC/dichloromethane from a 1:1 mixture of to separate LiF4OP from LiPF6 to form a lithium salt. An electric current producing rechargeable Li-ion cell. The rechargeable lithium ion cell includes an anode, a cathode, and a non-aqueous electrolyte comprising a solution of a lithium salt in a non-aqueous organic solvent containing lithium tetrafluorooxalatophosphate (LiPF4(C2O4), LiF4OP).

Abstract: To provide high energy density, good cycle properties and rate characteristics and long-term safety of a lithium ion battery containing at least an ionic liquid and a lithium salt. The above problems are solved by suppressing reduction and decomposition of the ionic liquid on an anode by using a graphite coated with an amorphous carbon or onto which an amorphous carbon is deposited as an anode active material.

Abstract: A nonaqueous electrolyte battery includes: an electrode group including a positive electrode and a negative electrode; and a nonaqueous electrolyte including an electrolytic solution, the electrode group including an insulating layer, the insulating layer containing a ceramic, the electrolytic solution including an electrolyte salt and an additive, the electrolyte salt including the compound of formula (1), and the additive being at least one of the compounds of formulae (2) to (14), and the compound of formula (1) being contained in 0.001 mol/L to 2.5 mol/L with respect to the electrolytic solution.

Abstract: Described herein are materials for use in electrolytes that provide a number of desirable characteristics when implemented within batteries, such as high stability during battery cycling up to high temperatures high voltages, high discharge capacity, high coulombic efficiency, and excellent retention of discharge capacity and coulombic efficiency over several cycles of charging and discharging. In some embodiments, a high voltage electrolyte includes a base electrolyte and a set of additive compounds, which impart these desirable performance characteristics.

Abstract: A battery electrolyte solution contains from 0.001 to 20% by weight of certain phosphorus-sulfur compounds. The phosphorus-sulfur compound performs effectively as a solid-electrolyte interphase (SEI) forming material. The phosphorus-sulfur compound has little adverse impact on the electrical properties of the battery, and in some cases actually improves battery performance. Batteries containing the electrolyte solution form robust and stable SEIs even when charged at high rates during initial formation cycles.

Abstract: A non-aqueous liquid electrolyte secondary battery, including a cathode, an anode and a non-aqueous liquid electrolyte present between the cathode and the anode. The non-aqueous liquid electrolyte secondary battery has a closed structure in which the cathode, the anode and the non-aqueous liquid electrolyte are insulated from at least carbon dioxide and water. The non-aqueous liquid electrolyte secondary battery has a discharge voltage of 3V or less relative to a Li/Li+ reference electrode. The non-aqueous liquid electrolyte includes two or more kinds of anions, and a non-aqueous liquid electrolyte for the non-aqueous liquid electrolyte secondary battery.

Abstract: A cathode composition is provided. The cathode composition includes at least one electroactive metal, wherein the electroactive metal is at least one selected from the group consisting of titanium, vanadium, niobium, molybdenum, nickel, iron, cobalt, chromium, manganese, silver, antimony, cadmium, tin, lead and zinc; a first alkali metal halide; an electrolyte salt comprising a reaction product of a second alkali metal halide and a metal halide, wherein the electrolyte salt has a melting point of less than about 300 degrees Centigrade; and a metal chlorosulfide compound having a formula (I) M1M2p+1SnCl4+3p?2n wherein “M1” is a metal selected from group IA of the periodic table, “M2” is a metal selected from group IIIA of the periodic table, “p” is 0 or 1, and “n” is equal to or greater than 0.5. An article and an energy storage device comprising the cathode composition is provided. A method of forming the energy storage device is provided.

Abstract: An electrode includes: an electrode collector and an electrode active material layer, wherein a film containing a salt represented by the following formula (I) is provided on the electrode active material layer: R1AnMx ??(I) wherein R1 represents an n-valent organic group containing a sulfur atom; n represents an integer of from 1 to 4; A represents an anion; M represents a metal ion; and x represents an integer of 1 or more.

Abstract: An object of the invention is to provide a nonaqueous electrolytic solution which is capable of bringing about a nonaqueous-electrolyte secondary battery improved in initial charge capacity, input/output characteristics, and impedance characteristics. The invention relates to a nonaqueous electrolytic solution which comprises: a nonaqueous solvent; LiPF6; and a specific fluorosulfonic acid salt, and to a nonaqueous-electrolyte secondary battery containing the nonaqueous electrolytic solution.

Abstract: The exemplary embodiment has an object to provide a nonaqueous electrolyte solution having a flame retardancy over a long period and having a good capacity maintenance rate. The exemplary embodiment is a nonaqueous electrolyte solution containing a lithium salt, at least one oxo-acid ester derivative of phosphorus selected from compounds represented by a predetermined formula, and at least one disulfonate ester selected from a cyclic disulfonate ester and a linear disulfonate ester represented by the predetermined formulae.

Abstract: The present invention provides an excellent nonaqueous electrolytic solution capable of improving low-temperature and high-temperature cycle properties and load characteristics after high-temperature charging storage, an electrochemical element using it, and an alkynyl compound used for it. The nonaqueous electrolytic solution of the present invention comprises containing at least one alkynyl compound represented by the following general formula (I) in an amount of from 0.01 to 10% by mass in the nonaqueous electrolytic solution. R1(O)n—X1—R2??(I) (In the formula, X1 represents a group —C(?O)—, a group —C(?O)—C(?O)—, a group —S(?O)2—, a group —P(?O) (—R3)—, or a group —X2—S(?O)2O—.

Abstract: An electrochemical device, having an anode containing magnesium; a cathode stable to a voltage of at least 3.2 V relative to a magnesium reference; and an electrolyte containing an electrochemically active magnesium salt obtained by mixing an organic magnesium compound with an aluminum compound in an ether solvent and separation of the electrochemically active salt from the reaction mixture is provided. The separated electrochemically active salt is stable and safe to handle in comparison to conventional Grignard based electrolyte systems.

Abstract: Silicon oxide based materials, including composites with various electrical conductive compositions, are formulated into desirable anodes. The anodes can be effectively combined into lithium ion batteries with high capacity cathode materials. In some formulations, supplemental lithium can be used to stabilize cycling as well as to reduce effects of first cycle irreversible capacity loss. Batteries are described with surprisingly good cycling properties with good specific capacities with respect to both cathode active weights and anode active weights.

Abstract: An anode or an electrolytic solution or both contain a metal salt including an unsaturated carbon bond. The electrolytic solution contains an unsaturated carbon bond cyclic ester carbonate represented by Formula (1) or a halogenated cyclic ester carbonate represented by Formula (2) or both, and contains a cyclic ester represented by Formula (3), where each of R1 and R2 is a group such as a hydrogen group, where each of R3 to R6 is a group such as a hydrogen group; and each of one or more of R3 to R6 is a group such as a halogen group, where X is an ether bond (—O—) or a methylene group (—CH2—); each of R7 to R10 is a group such as a hydrogen group; and each of R7 to R10 is a group such as an alkyl group when X is the ether bond.

Abstract: An energy storage device includes a first electrode comprising a first material and a second electrode comprising a second material, at least a portion of the first and second materials forming an interpenetrating network when dispersed in an electrolyte, the electrolyte, the first material and the second material are selected so that the first and second materials exert a repelling force on each other when combined. An electrochemical device, includes a first electrode in electrical communication with a first current collector; a second electrode in electrical communication with a second current collector; and an ionically conductive medium in ionic contact with said first and second electrodes, wherein at least a portion of the first and second electrodes form an interpenetrating network and wherein at least one of the first and second electrodes comprises an electrode structure providing two or more pathways to its current collector.

Abstract: Electrolyte, comprising an aprotic solvent, a lithium salt as conducting salt, and an additive, characterized in that the additive is a compound which contains a protonable nitrogen atom and is hydrolysable by water.

Abstract: An electrolytic solution comprising a purified lithium borate salt that when used in lithium ion battery, delivers superior performances that include negligible irreversible capacity upon cell formation, low impedance on both cathode and anode, and excellent stability when operated at high temperatures.

Abstract: A positive electrode active material for non-aqueous electrolyte secondary battery, comprising particles of a lithium transition metal complex oxide represented by the general formula: LiaNi1?x?y?zCoxMnyM?zM?wO2 wherein 1.00?a?1.25, 0?x?0.5, 0?y?0.5, 0.002?z?0.01, 0?w?0.05, M? is at least one kind of an element selected from W, Mo, Nb and Ta, and M? is at least one kind of an element selected from Zr, Al, Mg, Ti, B and V.

Abstract: A secondary battery capable of improving the cycle characteristics while securing the initial charge and discharge characteristics is provided. The secondary battery includes a cathode, an anode, and an electrolytic solution. The anode has an anode active material layer containing a plurality of anode active material particles having silicon (Si). The anode active material layer contains at least one of an oxide-containing film covering a surface of the anode active material particles and a metal material not being alloyed with an electrode reactant provided in a gap in the anode active material layer. The electrolytic solution contains a solvent containing an organic acid that has a portion including an electron attractive group such as —(O?)C—C(?O)— bond in the center and a hydroxyl group on the both ends.

Abstract: A nonaqueous electrolytic solution that can provide a battery that is low in gas generation, has a large capacity, and is excellent in storage characteristics and cycle characteristics.

Abstract: A nonaqueous electrolyte containing a monofluorophosphate and/or a difluorophosphate and a compound having a specific chemical structure or specific properties. The nonaqueous electrolyte can contain at least one of a saturated chain hydrocarbon, a saturated cyclic hydrocarbon, an aromatic compound having a halogen atom and an ether having a fluorine atom.

Abstract: A nonaqueous electrolyte battery includes: a positive electrode, a negative electrode, and a nonaqueous electrolyte containing a nonaqueous electrolytic solution, wherein the nonaqueous electrolytic solution contains a compound represented by the following general formula (I) wherein, in the general formula (I), each of R1 to R4 independently represents a group having a hydrocarbon group having at least one aromatic ring and at least one unsaturated bond or a hydrogen atom, provided that at least one of R1 to R4 is a group having a hydrocarbon group having at least one aromatic ring and at least one unsaturated bond; and each of A and B independently represents a carbonyl group, a sulfonyl group, or a methylene group, provided that at least one of A and B is a carbonyl group or a sulfonyl group.

Abstract: A battery that includes a cathode, anode and an electrolytic solution containing an organic electrolyte solvent including a compound of the formula: R1—CO—NR2—OR3 wherein R1 is selected from alkanes, alkenes, alkynes, aryls and their substituted derivatives and perfluorinated analogues; R2 is selected from alkanes, alkenes, alkynes, aryls and their substituted derivatives; R3 is selected from alkanes, alkenes, alkynes, aryls and their substituted derivatives wherein the electrolyte is stable at voltages of greater than 4.0 volts.

Abstract: Disclosed is an electrolyte for a rechargeable lithium battery and a rechargeable lithium battery including the same, and the electrolyte includes a lithium salt composition including a first lithium salt; and a second lithium salt of lithium bisfluorosulfonyl imide represented by the following Chemical Formula 1 at a mole ratio of 1:0.05 to 1:1, and a non-aqueous organic solvent.

Abstract: A non-aqueous electrolyte secondary battery has a positive electrode (1), a negative electrode (2), a separator (3) interposed between the positive electrode and the negative electrode, and a non-aqueous electrolyte solution in which a solute is dissolved in a non-aqueous solvent. The negative electrode contains a negative electrode active material capable of alloying with lithium and the non-aqueous solvent of the non-aqueous electrolyte solution contains one ore more fluorinated cyclic carbonates and a carboxylic ester. In addition, the non-aqueous electrolyte solution contains a nitrile compound having a chain saturated hydrocarbon group having two or more carbon atoms.

Abstract: An electrolyte for a lithium secondary battery including a lithium salt, a nonaqueous organic solvent, and an additive, in which the additive is composed of one or more compounds including a purinone or a purinone derivative. The lithium secondary battery with improved life and high-temperature storage may be provided by using the electrolyte for a lithium secondary battery according to an embodiment of the present invention.

Abstract: A non-aqueous electrolyte solution for a lithium secondary battery includes a lithium salt and a carbonate organic solvent. The non-aqueous electrolyte solution further includes a fluoro group-containing sulphonate compound expressed by Chemical Formula 1. When the non-aqueous electrolyte solution is employed for a lithium secondary battery, low-temperature discharging characteristics and life cycle characteristics are greatly improved. Also, even though a battery is stored at a high temperature in a fully-charged state or a charging/discharging process is under progress, the decomposition reaction of a carbonate-based organic solvent is restrained, thereby solving the swelling problem and improving high-temperature life cycle characteristics.

Abstract: The invention is to provide a nonaqueous-electrolyte battery which comprises a current collector, a positive electrode containing a lithium-containing phosphoric acid compound represented by LixMPO4 as a positive-electrode active material, a negative electrode containing a negative-electrode active material capable of occluding and releasing lithium ions, and a nonaqueous electrolytic solution containing a chain ether and a cyclic carbonate having an unsaturated bond.

Abstract: An electrolyte for a lithium rechargeable battery, a lithium rechargeable battery including the same, and a method of manufacturing lithium rechargeable battery, the electrolyte including a first additive, a second additive, a lithium salt; and a non-aqueous organic solvent.

Abstract: The present invention generally relates to batteries or other electrochemical devices, and systems and materials for use in these, including novel electrode materials and designs. In some embodiments, the present invention relates to small-scale batteries or microbatteries. For example, in one aspect of the invention, a battery may have a volume of no more than about 5 mm3, while having an energy density of at least about 400 W h/l. In some cases, the battery may include an electrode comprising a porous electroactive compound. In some embodiments, the pores of the porous electrode may be at least partially filled with a liquid such as a liquid electrolyte. The electrode may be formed from a unitary material. Other aspects of the invention are directed to techniques of making such electrodes or batteries, techniques of forming electrical connections to and packaging such batteries, techniques of using such electrodes or batteries, or the like.

Abstract: A redox shuttle is provided to prevent overcharge of high voltage batteries, such as high voltage lithium ion (Li-ion) batteries. An exemplary redox shuttle includes a methylated closo-monocarborate anion.

Abstract: A rechargeable lithium battery includes an electrolyte including an additive such as an ethylene carbonate-based compound represented by Chemical Formula 1 and a silicon-included compound, and a negative electrode including a negative active material including an active element selected from the group consisting of Si, Sn, Ga, Cd, Al, Pb, Zn, Bi, In, Mg, and Ge. In Chemical formula 1, X and Y are independently selected from the group consisting of hydrogen, a halogen, and a C1 through C5 fluoroalkyl, provided that at least one of X and Y is selected from the group consisting of a halogen and a C1 through C5 fluoroalkyl. The rechargeable lithium battery has a suppressed volume expansion characteristic due to a high-capacity negative active material, and has excellent reliability and cycle-life characteristics.

Abstract: The present invention generally relates to electrochemical batteries, and more specifically, to the combined additives in the non-aqueous electrolyte for rechargeable lithium-ion batteries containing spinel-based cathode that may enhance the performance of the batteries. The mixed additives comprising of 1,8-bis(dialkylamino)naphthalene, wherein alky group is described by CnH2n+1, n=1 to 3, and vinylene carbonate (VC) are added to the electrolyte of the lithium-ion batteries greatly improve the capacity recovery and reduce AC impedance growth during the high temperature storage. The incorporation of the two kinds of additives within the electrolyte of the battery can also improve the high temperature cycling performance.

Abstract: An electrochemical energy generation system can include a sealed vessel that contains inside (i) at least one electrochemical cell, which has two electrodes and a reaction zone between them; (ii) a liquefied halogen reactant, such as a liquefied molecular chlorine; (iii) at least one metal halide electrolyte; and (iv) a flow circuit that can be used for delivering the halogen reactant and the electrolyte to the at least one cell. The sealed vessel can maintain an inside pressure above a liquefication pressure for the halogen reactant. Also disclosed are methods of using and methods of making for electrochemical energy generation systems.

Abstract: A rechargeable battery and associated methods, the rechargeable battery including an anode, a cathode, wherein the cathode includes a ternary cathode-active material, a separator interposed between the cathode and the anode, an electrolyte, and a housing enclosing the electrolyte, the anode, and the cathode, wherein the electrolyte includes a lithium salt, a non-aqueous organic solvent, about 0.5 weight % to about 5 weight % of succinonitrile, and at least one of about 1 weight % to about 10 weight % of halogenated ethylene carbonate and about 1 weight % to about 5 weight % of vinyl ethylene carbonate.

Abstract: The present invention includes (1) an ester compound having a specific structure, (2) a nonaqueous electrolytic solution for lithium secondary battery comprising an electrolyte dissolved in a nonaqueous solvent and containing an ester compound having a specific structure in an amount of from 0.01 to 10% by weight of the nonaqueous electrolytic solution, which is excellent in initial battery capacity and cycle property, and (3) a lithium secondary battery comprising a positive electrode, a negative electrode and a nonaqueous electrolytic solution of an electrolyte salt dissolved in a nonaqueous solvent, wherein the nonaqueous electrolytic solution contains an ester compound having a specific structure in an amount of from 0.01 to 10% by weight of the nonaqueous electrolytic solution.

Abstract: A secondary battery having a cathode, an anode, and an electrolyte is provided. The cathode includes a cathode active material containing at least one kind selected from the group consisting of sulfur S and phosphorus P in a portion near the particle surface of a lithium composite oxide. A content of the kind in the portion is larger than that in the particle of the lithium composite oxide.

Abstract: This invention described the preparation of a series of compounds selected from the group comprising tris(1,1,1,3,3,3-hexafluoro-iso-propyl)phosphate, tris(perfluoroethyl)phosphate, tris(perfluoro-iso-propyl)phosphate, bis(1,1,1-trifluoroethyl)fluorophosphate, tris(1,1,1-trifluoroethyl)phosphate, hexakis(1,1,1-trifluoroethoxy)phosphazene, tris(1,1,1-trifluoroethoxy)trifluorophosphazene, hexakis(perfluoro-t-butyl)phosphazene and tris(perfluoro-t-butyl)phosphate. These compounds may be used as co-solvents, solutes or additives in non-aqueous electrolytes in various electrochemical devices. The inclusion of these compounds in electrolyte systems can enable rechargeable chemistries at high voltages that are otherwise impossible with state-of-the-art electrolyte technologies. These compounds are chosen because of their beneficial effect on the interphasial chemistries formed at high potentials, such as 5.0 V class cathodes for new Li ion chemistries.

Abstract: A non-aqueous electrolyte for a battery comprises a non-aqueous solvent containing a specified cyclic phosphazene compound and a specified difluorophosphate compound, a specified aniline derivative and a support salt.

Abstract: The objective of the present invention is to prevent deterioration and expanding of anode active material and to improve charge-discharge cycle characteristics in a non-aqueous electrolyte secondary battery comprising an anode of which current collector has thereon a thin layer of an anode active material containing a metal. To solve this problem, in a non-aqueous electrolyte secondary battery wherein a thin layer of anode active material containing a metal which absorbs and discharges lithium is formed on a current collector and the thin layer of the anode active material is divided into columns by a gap formed along the thickness thereof, a compound represented by the following formula is contained in the non-aqueous electrolyte. A-N?C?O In the above formula, A represents an element or a group other than hydrogen.

Abstract: A negative electrode for a lithium ion battery includes an active electrode material, a conductive additive, and a binder for holding the active electrode material and the conductive additive together. The binder is chosen from polyethyleneimine, copolymers of polyethyleneimine, amine functionalized polyamides, proteins, and combinations thereof.

Abstract: Disclosed is a lithium secondary battery comprising a cathode including a lithium-containing transition metal oxide, and a non-aqueous electrolyte with addition of a compound of formula (1). Incorporation of the compound (1) into the electrolyte significantly improves the high-temperature performance and cycle life characteristics of the battery.

Abstract: Disclosed is a nonaqueous electrolytic solution which enables formation of a nonaqueous-electrolyte battery having high capacity and excellent storage characteristics at high temperatures, while sufficiently enhancing safety at the time of overcharge. A nonaqueous-electrolyte battery produced by using the nonaqueous electrolytic solution is also disclosed. The nonaqueous electrolytic solution comprises an electrolyte and a nonaqueous solvent, and includes any of specific nonaqueous electrolytic solutions (A) to (D).

Abstract: Disclosed is an electrolyte for a lithium secondary battery. The electrolyte includes a non-aqueous solvent and a sulfone based organic compound represented by the following Formulae (I), (II), or (III), or a mixture thereof: where R and R? are independently selected from the group consisting of primary alkyl groups, secondary alkyl groups, tertiary alkyl groups, alkenyl groups, aryl groups; halogen substituted primary alkyl groups, halogen substituted secondary alkyl groups, halogen substituted tertiary alkyl groups, halogen substituted alkenyl groups, and halogen substituted aryl groups, and n is from 0 to 3.

Abstract: To provide a non-aqueous electrolyte solution for secondary batteries which has excellent compatibility even in a state where a lithium salt is dissolved therein and further has excellent nonflammability and cycle properties, and a secondary battery having such a non-aqueous electrolyte solution for secondary batteries. A non-aqueous electrolyte solution for secondary batteries, which comprise a lithium salt, a specific hydrofluoromonoether and a specific hydrofluoropolyether, and a secondary battery containing such a non-aqueous electrolyte solution for secondary batteries.

Abstract: An object of the present invention is to provide an electrolyte solution for lithium-ion secondary batteries comprising a tetraalkylphosphonium salt which improves the cycle characteristics and safety of lithium-ion batteries, and to provide a lithium-ion secondary battery using the electrolyte solution. Disclosed is an electrolyte comprising a tetraalkylphosphonium salt represented by general formula (1) wherein R1 represents a linear, branched or alicyclic alkyl group having 2 to 6 carbon atoms and R2 represents a linear, branched or alicyclic alkyl group having 1 to 14 carbon atoms, provided that R1 and R2 are different from each other and the total number of carbon atoms in the phosphonium cation is 20 or less; and X represents an anion.