Include Electrolyte Chemically Specified And Method Patents (Class 429/188)
  • Patent number: 11831044
    Abstract: An apparatus may include a plurality of cells surrounded by a plurality of heat generating material. The plurality of heat generating material are configured to release heat to each of the plurality of cells causing discharge from each of the plurality of cells in a low temperature environment.
    Type: Grant
    Filed: July 24, 2020
    Date of Patent: November 28, 2023
    Assignee: The Acrospace Corporation
    Inventor: Margot Wasz
  • Patent number: 11807543
    Abstract: A solid ionically conductive composition (e.g., nanoparticles of less than 1 micron or a continuous film) comprising at least one element selected from alkali metal, alkaline earth metal, aluminum, zinc, copper, and silver in combination with at least two elements selected from oxygen, sulfur, silicon, phosphorus, nitrogen, boron, gallium, indium, tin, germanium, arsenic, antimony, bismuth, transition metals, and lanthanides. Also described is a battery comprising an anode, a cathode, and a solid electrolyte (corresponding to the above ionically conductive composition) in contact with or as part of the anode and/or cathode. Further described is a thermal (e.g., plasma-based) method of producing the ionically conductive composition. Further described is a method for using an additive manufacturing (AM) process to produce an object constructed of the ionically conductive composition by use of particles of the ionically conductive composition as a feed material in the AM process.
    Type: Grant
    Filed: July 31, 2020
    Date of Patent: November 7, 2023
    Assignee: UT-Battelle, LLC
    Inventors: Andrew K. Kercher, Andrew S. Westover, Michael Naguib Abdelmalak, Nancy J. Dudney
  • Patent number: 11799170
    Abstract: The present invention provides a method for the fabrication of a LaZrGa(OH)x metal hydroxide precursor with a co-precipitation method in a continuous TFR reactor. The present invention also provides a method for the fabrication of an ion-doped all-solid-state lithium-ion conductive material with lithium ionic conductivity, and mixing which in the polymer base material, using a doctor-blade coating method to prepare a free standing double layered and triple layered organic-inorganic hybrid solid electrolyte membrane. Furthermore, the present invention provides an all-solid-state lithium battery using the aforementioned hybrid solid electrolyte membrane and measure the electrochemical performance. The all-solid-state lithium battery may enhance the lithium ionic conductivity, and lower the interfacial resistance between the solid electrolyte membrane and the electrode, therefore the battery may have excellent performance, and prevent the lithium-dendrite formation effectively to enhance the safety.
    Type: Grant
    Filed: July 23, 2021
    Date of Patent: October 24, 2023
    Assignee: MING CHI UNIVERSITY OF TECHNOLOGY
    Inventors: Chun-Chen Yang, Yi-Shiuan Wu, Kumlachew Zelalem Walle
  • Patent number: 11791455
    Abstract: In an aspect, a lithium-ion battery anode composition comprises a porous composite particle comprising carbon (C) and an active material comprising silicon (Si), wherein the carbon is characterized by a domain size (r), as estimated from an atomic pair distribution function G(r) obtained from a synchrotron x-ray diffraction measurement of the porous composite particle, ranging from around 10 ? (1 nm) to around 60 ? (6 nm). In a further aspect, a carbon material for use in making an anode composition for use in a Li-ion battery is characterized by a domain size (r), as estimated from an atomic pair distribution function G(r) obtained from a synchrotron x-ray diffraction measurement of the carbon material, ranging from around 10 ? (1 nm) to around 60 ? (6 nm).
    Type: Grant
    Filed: January 12, 2023
    Date of Patent: October 17, 2023
    Assignee: SILA NANOTECHNOLOGIES, INC.
    Inventors: Gleb Yushin, Matthew Clark, Adam Kajdos, Timothy Milakovich, Saujan Sivaram, Valentin Lulevich
  • Patent number: 11784349
    Abstract: An electrolyte for a lithium metal battery including a nonaqueous aprotic organic solvent and a lithium salt dissolved or ionized in the nonaqueous aprotic organic solvent. The nonaqueous aprotic organic solvent includes a cyclic carbonate, an acyclic carbonate, and an acyclic fluorinated ether. The lithium salt includes an aliphatic fluorinated disulfonimide lithium salt.
    Type: Grant
    Filed: April 1, 2021
    Date of Patent: October 10, 2023
    Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: Meinan He, Mei Cai, Shuru Chen
  • Patent number: 11780777
    Abstract: An electrochromic device includes a light transmissive first substrate, a working electrode disposed on the first substrate, a light transmissive second substrate facing the first substrate, a counter electrode disposed on the second substrate, and a lithium-rich anti-perovskite (LiRAP) material disposed between the first and second substrates. The LiRAP material includes an ionically conductive and electrically insulating LiRAP material.
    Type: Grant
    Filed: April 11, 2022
    Date of Patent: October 10, 2023
    Assignee: HIVISQ TECHNOLOGIES SOCIEDAD LIMITADA
    Inventors: Adrian Winoto, Douglas Weir, Guillermo Garcia, Jason K. Holt, Amir Bayati, Bonil Koo, Hai Wang
  • Patent number: 11777087
    Abstract: A system for electrical energy production from chemical reagents in a compartmentalized cell includes: at least two electrodes, comprising at least one anode and at least one cathode; at least one separator, that separates the anodes and the cathodes; and an ionic liquid electrolyte system. The system can be a battery or one or more cells of a battery system. The ionic liquid electrolyte system comprises an ionic liquid solvent; an ether co-solvent, comprising a minority fraction, by weight, of the electrolyte; and a lithium salt. In preferred variations, the anode is a lithium metal anode and the cathode is a metal oxide cathode and the separator is a polyolefin separator.
    Type: Grant
    Filed: October 11, 2022
    Date of Patent: October 3, 2023
    Assignee: Cuberg, Inc.
    Inventors: Richard Y. Wang, Jason Koeller, Olivia Risset, Kaixiang Lin, Stephen Lawes, Mauro Pasta
  • Patent number: 11777169
    Abstract: A method of manufacturing a power storage module includes: stacking a plurality of power storage cells along a first direction; compressing the plurality of power storage cells along the first direction; aligning the plurality of power storage cells in a second direction orthogonal to the first direction after relieving pressing force of the compressing; compressing the plurality of power storage cells along the first direction after aligning the plurality of power storage cells in the second direction; disposing a restraint portion on both sides in the first direction with respect to the plurality of power storage cells under application of pressing force of the compressing; and restraining the plurality of power storage cells by the restraint portion along the first direction by relieving, after disposing the restraint portion, the pressing force of the compressing.
    Type: Grant
    Filed: February 15, 2022
    Date of Patent: October 3, 2023
    Assignee: PRIME PLANET ENERGY & SOLUTIONS, INC.
    Inventors: Wataru Okada, Seiichi Sakuramoto
  • Patent number: 11764347
    Abstract: Provided is a method of preparing a positive electrode active material, which includes preparing a mixture by mixing a lithium compound, a transition metal precursor, and a metal oxide additive, and sintering the mixture to form a lithium transition metal oxide, wherein the sintering is performed through two-stage temperature holding sections, a temperature of a first temperature holding section is in a range of 400° C. to 650° C., and a temperature of a second temperature holding section is in a range of 700° C. to 900° C. A positive electrode including a positive electrode active material prepared according to the method, and a lithium secondary battery including the positive electrode is also provided.
    Type: Grant
    Filed: October 17, 2018
    Date of Patent: September 19, 2023
    Inventors: Hyeon Hui Baek, Sung Ho Ban, Jun Ho Eom, Na Ri Park
  • Patent number: 11757089
    Abstract: A carbon matrix composite material, a preparation method therefor and a battery comprising the same. The carbon matrix composite material comprises micron-sized soft carbon, micron-sized hard carbon, a nano-active material, a first carbon coating layer and a second carbon coating layer, wherein the first carbon coating layer is coated on a surface of the nano-active material to form composite particles; the composite particles are dispersed on the surfaces of the soft carbon and the hard carbon, and in the second carbon coating layer; and the second carbon coating layer coats soft carbon, the hard carbon and the composite particles.
    Type: Grant
    Filed: September 30, 2018
    Date of Patent: September 12, 2023
    Assignee: BTR NEW MATERIAL GROUP CO., LTD.
    Inventors: Peng He, Eming Guo, Jianguo Ren, Youyuan Huang, Min Yue
  • Patent number: 11757130
    Abstract: An additive for a non-aqueous electrolyte solution that can exhibit high-temperature cycle properties at 50° C. or more and low-temperature output properties at ?20° C. or less in a well-balanced manner for a non-aqueous electrolyte solution battery. The additive for a non-aqueous electrolyte solution is represented by formula [1], wherein Z1, Z2, Z3, Z4, Mp+ and p are as defined in the specification.
    Type: Grant
    Filed: September 12, 2018
    Date of Patent: September 12, 2023
    Assignee: CENTRAL GLASS CO., LTD.
    Inventors: Takayoshi Morinaka, Susumu Iwasaki, Keita Nakahara, Makoto Kubo, Mikihiro Takahashi
  • Patent number: 11749868
    Abstract: The present invention relates to a separator capable of inhibiting the growth of lithium dendrites, and a lithium secondary battery including the same. According to the present invention, the stability and life cycle characteristic of a lithium secondary battery can be remarkably improved.
    Type: Grant
    Filed: May 17, 2019
    Date of Patent: September 5, 2023
    Assignee: LG Energy Solution, Ltd.
    Inventor: Jeongbeom Lee
  • Patent number: 11742518
    Abstract: An electrolyte includes at least one of a compound of Formula I, a compound of Formula II or a compound of Formula III; and a compound of Formula IV; where, R11, R12, R13, R21, R22, R31, R32, R33 and R34 are independently selected from H, halo, cyano, substituted or unsubstituted C1-C10 alkyl, substituted or unsubstituted C2-C10 alkenyl, and substituted or unsubstituted C6-C12 aryl; R41 and R44 are independently selected from H, F, cyano, substituted or unsubstituted C1-C10 alkyl, substituted or unsubstituted C2-C10 alkenyl, substituted or unsubstituted C6-C12 aryl, Ra—(O—Rb), or (O—Rb); and R42 and R43 are independently selected from Rc—(O—Rd) or (O—Rd). Rb is selected from substituted or unsubstituted C1-C4 alkyl; Ra, Rc and Rd are independently selected from substituted or unsubstituted C1-C4 alkylene, C2-C5 alkenylene, or C6-C12 aryl.
    Type: Grant
    Filed: December 24, 2019
    Date of Patent: August 29, 2023
    Assignee: NINGDE AMPEREX TECHNOLOGY LIMITED
    Inventors: Hui Cui, Shuirong Zhang, Chao Tang, Jianming Zheng
  • Patent number: 11721838
    Abstract: An electrolyte including an additive of compound of formula I, wherein n is an integer ranging from 0 to 10; R1 and R2 are each independently selected from a substituted or unsubstituted C1-C10 alkylidene group, a substituted or unsubstituted C2-C10 alkenylene group, or a substituted or unsubstituted C1-C10 alkyleneoxy group; A1 selected from CH, C, N, S, O, B or Si; A2 is selected from CH—R3, N—R3, S, O, B—R3 or SiH—R3; A3 selected from CH2, CH, C, N, S, O, B or Si; R3 is selected from hydrogen, halogen, a substituted or unsubstituted C1-C10 alkyl group, or a substituted or unsubstituted C3-C10 cycloalkyl group; X1 is selected from a substituted or unsubstituted C1-C10 alkylidene group, a substituted or unsubstituted C2-C10 alkenylene group, ?Rc?, or ?Rc—, wherein Rc is selected from a substituted or unsubstituted C2-C6 alkylidene group.
    Type: Grant
    Filed: March 30, 2021
    Date of Patent: August 8, 2023
    Assignee: NINGDE AMPEREX TECHNOLOGY LIMITED
    Inventors: Jian Liu, Wenqiang Li, Jianming Zheng, Xiexue Peng
  • Patent number: 11721843
    Abstract: A capacitor-assisted battery module includes a housing, a positive terminal, a negative terminal, one or more capacitor-assisted battery cells and one or more first switches. The one or more capacitor-assisted battery cells are disposed in the housing and include one or more battery terminals and one or more capacitor terminals. The one or more battery terminals are connected to battery electrodes. The one or more capacitor terminals are connected to capacitor electrodes. At least one of the one or more battery terminals and the capacitor terminals is connected to the negative terminal. One or more first switches is configured to connect the one or more capacitor terminals to the positive terminal. An overall voltage of the capacitor assisted battery module is measured across the positive terminal and the negative terminal.
    Type: Grant
    Filed: February 3, 2020
    Date of Patent: August 8, 2023
    Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: Dewen Kong, Xiaochao Que, Dave G. Rich, Si Chen, Meiyuan Wu, Haijing Liu
  • Patent number: 11710855
    Abstract: An all-solid-state battery is provided that includes a cathode layer, an anode layer, and a solid electrolyte layer, in which a porosity of the solid electrolyte layer is equal to or less than 10%. Moreover, the batter includes a surface roughness Rz1 of the cathode layer and a surface roughness Rz2 of the anode layer, such that Rz1+Rz2?25.
    Type: Grant
    Filed: September 20, 2019
    Date of Patent: July 25, 2023
    Assignee: MURATA MANUFACTURING CO., LTD.
    Inventors: Mamoru Nakashima, Masayuki Arimochi, Masamitsu Suzuki, Masahiro Morooka, Noriyuki Aoki, Keiko Hayashi
  • Patent number: 11695108
    Abstract: Cathode active materials are provided. The cathode active material can include a plurality of cathode active compound particles. A coating is disposed over each of the cathode active compound particles. The coating can include at least one of ZrO2, La2O3, a mixture of Al2O3 and ZrO2 or a mixture of Al2O3 and La2O3. The battery cells that include the cathode active material are also provided.
    Type: Grant
    Filed: August 1, 2019
    Date of Patent: July 4, 2023
    Assignee: Apple Inc.
    Inventors: Dapeng Wang, Huiming Wu, Hongli Dai, Xiaoping Wang, James Gilbert, John David Carter, Zhenzhen Yang, Anh Vu, Yan Li, Yanjie Cui, Christopher S. Johnson, Arthur Jeremy Kropf, Hakim H. Iddir
  • Patent number: 11695109
    Abstract: The present disclosure relates to a positive electrode active material, a preparing method therefor, and a lithium secondary battery including same. A positive electrode active material according to an embodiment comprises: a core including a lithium nickel composite oxide represented by Chemical Formula 1; and a surface layer present on the core and including at least one of a water-soluble ammonium-based organic compound and a water-soluble amine-based organic compound. The details of Chemical Formula 1 are as defined in the specification.
    Type: Grant
    Filed: April 18, 2019
    Date of Patent: July 4, 2023
    Assignee: Samsung SDI Co., Ltd.
    Inventor: Kwanghwan Cho
  • Patent number: 11682794
    Abstract: An additive, a non-aqueous electrolyte for a lithium secondary battery including the same, and a lithium secondary battery including the same are disclosed herein. In some embodiments, an additive includes at least one compound selected from the group consisting of the compounds represented by Formula 1 and Formula 2. In some embodiments, a non-aqueous electrolyte includes a lithium salt, an organic solvent, and an additive including at least one compound selected from the group consisting of the compounds represented by Formula 1 and Formula 2.
    Type: Grant
    Filed: November 20, 2018
    Date of Patent: June 20, 2023
    Inventors: Sung Hoon Yu, Chul Haeng Lee, Yoo Sun Kang
  • Patent number: 11670772
    Abstract: Negative electrode active material particles according to the present invention have composite particles that include: a sodium silicate phase with a Vickers hardness of 150 Hv or greater, and silicon particles dispersed in the sodium silicate phase.
    Type: Grant
    Filed: October 26, 2018
    Date of Patent: June 6, 2023
    Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
    Inventors: Yohei Uchiyama, Norihisa Yamamoto, Tatsuya Akira, Kazuro Hayashida
  • Patent number: 11664492
    Abstract: An electrode using a carbon nanotube as a conductive material, and excellent in resistance characteristics is provided. An electrode for a secondary battery herein disclosed has a collector, and an active material layer formed on the collector. The active material layer includes an active material and a carbon nanotube. At least a part of the surface of the carbon nanotube is coated with a material including an element with a lower electronegativity than that of carbon.
    Type: Grant
    Filed: July 30, 2019
    Date of Patent: May 30, 2023
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventor: Yuji Yamamoto
  • Patent number: 11662386
    Abstract: A method for inspecting self-discharge of a power storage device includes: a) continuously applying a continuous power-supply voltage to the power storage device that has been charged in advance from an external power supply to a first device voltage), the continuous power-supply voltage being higher than the first device voltage and having a constant magnitude; b) detecting a power-supply current flowing from the external power supply to the power storage device; and c) determining a self-discharge state of the power storage device based on the detected power-supply current.
    Type: Grant
    Filed: November 11, 2021
    Date of Patent: May 30, 2023
    Assignee: PRIME PLANET ENERGY & SOLUTIONS, INC.
    Inventor: Ruri Tanaka
  • Patent number: 11658279
    Abstract: Prelithiation methods and fast charging lithium ion cell are provided, which combine high energy density and high power density. Several structural and chemical modifications are disclosed to enable combination of features that achieve both goals simultaneously in fast charging cells having long cycling lifetime. The cells have anodes with high content of Si, Ge and/or Sn as principal anode material, and cathodes providing a relatively low C/A ratio, with the anodes being prelithiated to have a high lithium content, provided by a prelithiation algorithm. Disclosed algorithms determine lithium content achieved through prelithiation by optimizing the electrolyte to increase cycling lifetime, adjusting energy density with respect to other cell parameters, and possibly reducing the C/A ratio to maintain the required cycling lifetime.
    Type: Grant
    Filed: January 7, 2020
    Date of Patent: May 23, 2023
    Assignee: STOREDOT LTD.
    Inventors: Ivgeni Shterenberg, Eran Sella, Eynat Matzner, Shirel Cohen, Hadar Mazor Shafir, Daniel Aronov
  • Patent number: 11646457
    Abstract: A method for producing a lithium-sulfur battery with an improved lifetime. This method includes an activation step of forming a positive electrode active material-derived compound from a compound including elemental sulfur by charging and discharging the lithium-sulfur battery, where the battery includes the compound including elemental sulfur and an electrolyte liquid. Additionally, the positive electrode active material-derived compound has a solubility of 1% by weight or greater in the electrolyte liquid. The lithium-sulfur battery may be charged and discharged in a range of greater than 2.0 V and less than 2.4 V in the activation step. Further, the lithium-sulfur battery may be charged and discharged 3 times to 10 times in the activation step. This method avoids a complicated application process of and active material in preparing a lithium-sulfur battery.
    Type: Grant
    Filed: July 4, 2018
    Date of Patent: May 9, 2023
    Assignee: LG ENERGY SOLUTION, LTD.
    Inventors: Intae Park, Doo Kyung Yang
  • Patent number: 11637274
    Abstract: The present disclosure relates to a strip-like electrode for use in a cylindrical jelly roll which includes a strip-like electrode assembly wound cylindrically to form a hollow cavity at the core portion thereof, and a lithium secondary battery including the same. The strip-like electrode includes: a strip-like electrode current collector; a first electrode active material layer formed on at least one surface of the strip-like electrode current collector; and a second electrode active material layer formed on the first electrode active material layer, wherein the second electrode active material layer is formed to have a length smaller than the length of the first electrode active material layer so that a part of one longitudinal surface of the first electrode active material layer can be exposed to the outside.
    Type: Grant
    Filed: November 9, 2018
    Date of Patent: April 25, 2023
    Assignee: LG ENERGY SOLUTION, LTD.
    Inventors: Byoung-Hoon Ahn, Jung-Min Yang, Sang-Hoon Choy
  • Patent number: 11637319
    Abstract: The present application relates to an electrolytic solution and an electrochemical device comprising the electrolytic solution. The electrolytic solution comprises a carbonate compound having a silicon-containing functional group, so as to significantly improve the overcharge performance and high-temperature storage performance of an electrochemical device using the electrolytic solution.
    Type: Grant
    Filed: January 20, 2020
    Date of Patent: April 25, 2023
    Assignee: NINGDE AMPEREX TECHNOLOGY LIMITED
    Inventors: Xiexue Peng, Jiqiong Liu, Junfei Liu, Chao Tang
  • Patent number: 11637324
    Abstract: An electrolyte for a lithium ion battery includes a nonaqueous aprotic organic solvent and a lithium salt dissolved in the organic solvent. The organic solvent includes a cyclic carbonate, an acyclic carbonate, and an acyclic fluorinated ether for improved low temperature and high voltage performance as well as enhanced thermostability. The ether group has a general formula of R1—O—[R3—O]n—R2, where n=0 or 1, R1 and R2 are each straight-chain C1-C6 fluoroalkyl groups, and, when n=1, R3 is a methylene group or a polyethylene group.
    Type: Grant
    Filed: February 11, 2021
    Date of Patent: April 25, 2023
    Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: Meinan He, Mei Cai
  • Patent number: 11631895
    Abstract: The present invention provides an energy device having excellent properties. Also provided is a nonaqueous electrolyte solution containing a compound represented by the following Formula (1), wherein R11, R12 and R13 each independently represent an organic group having 1 to 3 carbon atoms; and R11 and R12, R11 and R13, or R12 and R13 are optionally bound with each other to form a 5-membered ring or a 6-membered ring, with a proviso that a total number of carbon atoms of R11, R12 and R13 is 7 or less.
    Type: Grant
    Filed: May 8, 2020
    Date of Patent: April 18, 2023
    Assignees: MITSUBISHI CHEMICAL CORPORATION, MU IONIC SOLUTIONS CORPORATION
    Inventors: Atsushi Watarai, Hiroyuki Tokuda, Akiko Yabe
  • Patent number: 11611106
    Abstract: The invention provides an electrolyte solution capable of providing an electrochemical device having low resistance and excellent high-temperature storage characteristics and cycle characteristics. The electrolyte solution contains lithium fluorosulfonate and a solvent containing a compound (1) represented by the following formula (1): CF2HCOOCH3.
    Type: Grant
    Filed: July 31, 2018
    Date of Patent: March 21, 2023
    Assignee: DAIKIN INDUSTRIES, LTD.
    Inventors: Yoshiko Kuwajima, Kenzou Takahashi, Shigeaki Yamazaki, Hiroyuki Arima, Tomoya Hidaka, Masakazu Kinoshita, Hisako Nakamura, Takaya Yamada, Toshiharu Shimooka, Yuuki Suzuki, Tatsuya Ohtsuka
  • Patent number: 11605814
    Abstract: A positive-electrode active material contains a lithium composite oxide containing manganese. The crystal structure of the lithium composite oxide belongs to a space group Fd-3m. The integrated intensity ratio I(111)/I(400) of a first peak I(111) on the (111) plane to a second peak I(400) on the (400) plane in an XRD pattern of the lithium composite oxide satisfies 0.05?I(111)/I(400)?0.90.
    Type: Grant
    Filed: November 14, 2019
    Date of Patent: March 14, 2023
    Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
    Inventors: Ryuichi Natsui, Kensuke Nakura, Junko Matsushita, Issei Ikeuchi
  • Patent number: 11600860
    Abstract: A lithium secondary battery is disclosed herein. In some embodiment, a lithium secondary battery which includes a positive electrode including a positive electrode material mixture layer, wherein the positive electrode material mixture layer has a loading capacity of 3.7 mAh/cm2 to 10 mAh/cm2, a negative electrode including a negative electrode material mixture layer, a separator disposed between the positive electrode and the negative electrode, and a non-aqueous electrolyte solution including a lithium salt, an organic solvent, and a compound represented by Formula 1, the concentration of the lithium salt in the non-aqueous electrolyte solution is 1.5 M to 3 M, the organic solvent is a mixed solvent including a cyclic carbonate-based organic solvent and a linear carbonate-based organic solvent, and the compound represented by Formula 1 is included in an amount of 0.1 wt % to 5 wt % based on a total weight of the non-aqueous electrolyte solution.
    Type: Grant
    Filed: June 7, 2019
    Date of Patent: March 7, 2023
    Inventors: Gwang Yeon Kim, Jeong Woo Oh, Chui Haeng Lee, Kyoung Ho Ahn, Won Kyung Shin
  • Patent number: 11600820
    Abstract: A positive electrode active material contains a lithium-rich lithium manganese-based oxide, wherein the lithium manganese-based oxide has a composition of the following chemical formula (1), and wherein a lithium ion conductive glass-ceramic solid electrolyte layer containing at least one selected from the group consisting of thio-LISICON(thio-lithium super ionic conductor), LISICON(lithium super ionic conductor), Li2S—SiS2—Li4SiO4, and Li2S—SiS2—P2S5—Lil is formed on the surface of the lithium manganese-based oxide particle: Li1?xMyMn1?x?yO2?zQz??(1) wherein, 0<x?0.2, 0<y?0.2, and 0?z?0.5; M is at least one element selected from the group consisting of Al, Mg, Ni, Co, Fe, Cr, V, Ti, Cu, B, Ca, Ga, In, Ru, Zn, Zr, Nb, Sn, Mo, Sr, Sb, W, Ti and Bi; and Q is at least one element selected from the group consisting of P, N, F, S and Cl.
    Type: Grant
    Filed: September 7, 2018
    Date of Patent: March 7, 2023
    Inventors: Gi Beom Han, Jintae Hwang, Wang Mo Jung, Min Kyu You, Chi Ho Jo, Sungbin Park, Inseong Ju, Hyuck Hur, Younguk Park, Tae Gu Yoo
  • Patent number: 11600861
    Abstract: An additive, an electrolyte for a rechargeable lithium battery, and a rechargeable lithium battery, the additive being represented by Chemical Formula 1:
    Type: Grant
    Filed: June 18, 2020
    Date of Patent: March 7, 2023
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Wonseok Cho, Younghye Kang, Dongyoung Kim, Soojin Kim, Aeran Kim, Suyeol Ryu, Jeongmin Shin, Junyong Lee, Tae Jin Lee, Jin-Hyeok Lim, Myunghwan Jeong, Hyunbong Choi, Jungmin Han
  • Patent number: 11600868
    Abstract: Provided is a method for producing a nonaqueous electrolyte secondary battery, and a production system therefor, that allow forming a good SEI film in a shorter time. The production method includes an assembly step, an initial charging step and a high-temperature aging step.
    Type: Grant
    Filed: June 17, 2019
    Date of Patent: March 7, 2023
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventor: Takashi Miura
  • Patent number: 11577468
    Abstract: Disclosed is a 3-D printing apparatus. The apparatus includes an ink output module including an ink supply unit having an ink for forming an electrode portion, electrolyte or packaging portion received therein and an ink discharge unit coupled to the ink supply unit; a driving unit having the ink output module mounted thereon to move the ink output module in an X, Y, Z axis direction with respect to a substrate where a supercapacitor or secondary battery will be formed; a dispenser connected to the ink supply unit to supply gas having controlled pressure to the ink supply unit through a gas supply tube and to supply the ink within the ink supply unit through the ink discharge unit; and a controller controlling the output of the ink by transmitting a control command for fabricating the supercapacitor or the secondary battery to the dispenser and the driving unit.
    Type: Grant
    Filed: April 3, 2020
    Date of Patent: February 14, 2023
    Assignee: KOREA INSTITUTE OF ENERGY RESEARCH
    Inventors: Jung Joon Yoo, Jeong Hun Baek, Yong Il Kim, Ha Na Yoon, Bo Yun Jang, Jong Huy Kim
  • Patent number: 11569532
    Abstract: An aqueous secondary battery including: a positive electrode; a negative electrode; a separator; and an aqueous electrolytic solution including water and a metal salt represented by Chemical Formula 1 AxDy and having molality of about 5 M to about 40 M wherein in Chemical Formula 1, A is at least one metal ion selected from a sodium ion, a potassium ion, a magnesium ion, a calcium ion, a strontium ion, a zinc ion, or a barium ion, D is at least one type of atomic group ion selected from Cl?, SO42?, NO3?, ClO4?, SCN?, CF3SO3?, C4F3SO3?, (CF3SO2)2N?, AlO2?, AlCl4?, AsF6?, SbF6?, BR4?, and PO2F2?, and 0<x?2, and 0<y?2.
    Type: Grant
    Filed: March 6, 2020
    Date of Patent: January 31, 2023
    Assignee: SEOUL NATIONAL UNIVERSITY R&DB FOUNDATION
    Inventors: Kisuk Kang, Myeong Hwan Lee, Sung Joo Kim
  • Patent number: 11551880
    Abstract: A poly(vinylphosphonic acid) (PVPA)-(NH4)2MoO4), gel polymer electrolyte can be prepared by incorporating redox-mediated Mo, or similar metal, into a PVPA, or similar polymer, matrix. Gel polymer electrolytes including PVPA/MoX, x representing the percent fraction Mo in PVPA, can be used to make supercapacitors including active carbon electrodes. The electrolytes can be in gel form, bendable and stretchable in a device. Devices including this gel electrolyte can have a specific capacitance (Cs) of 1276 F/g, i.e., a more than 50-fold increase relative to a PVPA system without Mo. A PVPA/Mo10 supercapacitor can have an energy density of 180.2 Wh/kg at power density of 500 W/kg, and devices with this hydrogel structure may maintain 85+% of their initial capacitance performance after 2300 charge-discharge cycles.
    Type: Grant
    Filed: April 4, 2022
    Date of Patent: January 10, 2023
    Assignee: Imam Abdulrahman Bin Faisal University
    Inventors: Ayhan Bozkurt, Emre Cevik
  • Patent number: 11539075
    Abstract: Disclosed are an electrolyte for a lithium secondary battery and a lithium secondary battery comprising the same. The electrolyte for a lithium secondary battery, according to an embodiment, can comprise: a nonaqueous organic solvent; a lithium salt; a first additive comprising a compound represented by a specific chemical formula; and a second additive including at least one of lithium difluorophosphate (LiPO2F2), a cyclic carbonate including a fluorine atom, and a dinitrile compound.
    Type: Grant
    Filed: April 5, 2018
    Date of Patent: December 27, 2022
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Hyunbong Choi, Pavel Shatunov, Olga Tsay, Aeran Kim, Woo Cheol Shin, Jeongmin Shin
  • Patent number: 11527777
    Abstract: The present disclosure provides a non-aqueous electrolyte for a lithium-ion battery and a lithium-ion battery using the non-aqueous electrolyte. The non-aqueous electrolyte includes (a) a lithium, (b) a non-aqueous organic solvent, and (c) at least one compound represented by formula 1; where the non-aqueous electrolyte further includes at least one of the following components (d) and (e): (d) a nitrile compound including at least one of 1,3,6-hexane trinitrile, glycerol trinitrile, and 3-methoxypropionitrile, and (e) vinyl sulfate. Through the synergy effect between them, the positive electrode is protected and meanwhile the negative electrode is also be protected to a certain extent, and an impedance of a film is lowered. The battery has an excellent high temperature storage performance, high temperature cycle performance and low temperature charge and discharge performance.
    Type: Grant
    Filed: December 11, 2020
    Date of Patent: December 13, 2022
    Inventors: Changan Zeng, Suli Li
  • Patent number: 11527752
    Abstract: This application provides a positive active material and a preparation method thereof, an electrochemical battery, a battery module, a battery pack, and an apparatus. The positive active material includes an inner core and a coating layer, where the coating layer coats a surface of the inner core. The inner core is selected from a ternary material with a molecular formula of Li1+a[NixCoyMnzMbM?c]O2?dYd, where distribution of each of the doping elements M, M?, and Y in the inner core meets the following condition: there is a reduced mass concentration gradient from an outer side of the inner core to a center of the inner core. The positive active material herein features high gram capacity, high structural stability, and high thermal stability, so that the electrochemical battery has excellent cycle performance and storage performance and high initial discharge gram capacity.
    Type: Grant
    Filed: December 22, 2020
    Date of Patent: December 13, 2022
    Assignee: CONTEMPORARY AMPEREX TECHNOLOGY CO., LIMITED
    Inventors: Qi Wu, Jinhua He, Changyin Ji
  • Patent number: 11512390
    Abstract: The system and method includes the suspension of a free-standing carbon article within a reaction chamber, the introduction of the chemical precursor in a reaction environment within the chamber, and heating of the carbon article in the presence of the chemical precursor leading to deposition in a site-specific manner.
    Type: Grant
    Filed: July 16, 2019
    Date of Patent: November 29, 2022
    Assignees: Rochester Institute of Technology
    Inventors: Brian J. Landi, Cory D. Cress, Anthony P. Leggiero
  • Patent number: 11508991
    Abstract: The invention relates to the simultaneous use of a first salt comprising a nitrate anion (NO3?) and a second salt comprising an anion other than nitrate, at least one of the first and second salts being a lithium salt, as ionic conductivity promoters in a rechargeable lithium-metal-gel battery. The invention also relates to a lithium-gel battery comprising a mixture of said first salt and said second salt, to a non-aqueous gel electrolyte comprising such mixture and to a lithium battery positive electrode comprising said mixture.
    Type: Grant
    Filed: November 19, 2018
    Date of Patent: November 22, 2022
    Assignee: BLUE SOLUTIONS
    Inventors: Marc Deschamps, Renaud Bouchet, Margaud Lecuyer, Julien Rolland
  • Patent number: 11502336
    Abstract: A system and method for a liquid electrolyte used in secondary electrochemical cells having at least one electrode including a TMCCC material, the liquid electrolyte enabling an increased lifetime while allowing for fast discharge to extremely high depth of discharge. The addition of dinitriles to liquid electrolytes in electrochemical cells in which energy storage is achieved by ion intercalation in transition metal cyanide coordination compounds (TMCCC) has the advantage of increasing device lifetime by inhibiting common chemical and electrochemical degradation mechanisms.
    Type: Grant
    Filed: February 8, 2022
    Date of Patent: November 15, 2022
    Assignee: Natron Energy, Inc.
    Inventors: Majid Keshavarz, Daniel Friebel, Peter Benjamin Herman, Grace Marjorie Yee, Alex J. Klevay
  • Patent number: 11502301
    Abstract: The presently disclosed and/or claimed inventive process(es), procedure(s), method(s), product(s), result(s), and/or concept(s) (collectively hereinafter referred to as the “presently disclosed and/or claimed inventive concept(s)”) relates generally to the composition of a binder for use in battery electrodes and methods of preparing such. More particularly, but not by way of limitation, the presently disclosed and/or claimed inventive concept(s) relates to a binder composition containing an ionizable water soluble polymer and a redispersible powder containing a latex, a protective colloid, and an anticaking agent for use in the production and manufacture of electrodes of a lithium ion battery. Additionally, the presently disclosed and/or claimed inventive concept(s) relates generally to the compositions and methods of making electrodes, both anodes and cathodes, with a binder composition containing an ionizable water soluble polymer and a redispersible powder.
    Type: Grant
    Filed: May 21, 2014
    Date of Patent: November 15, 2022
    Assignee: Hercules LLC
    Inventors: Sung Gun Chu, Alan E Goliaszewski
  • Patent number: 11495831
    Abstract: A system and method for a liquid electrolyte used in secondary electrochemical cells having at least one electrode including a TMCCC material, the liquid electrolyte enabling an increased lifetime while allowing for fast discharge to extremely high depth of discharge. The addition of dinitriles to liquid electrolytes in electrochemical cells in which energy storage is achieved by ion intercalation in transition metal cyanide coordination compounds (TMCCC) has the advantage of increasing device lifetime by inhibiting common chemical and electrochemical degradation mechanisms.
    Type: Grant
    Filed: February 8, 2022
    Date of Patent: November 8, 2022
    Assignee: Natron Energy, Inc.
    Inventors: Majid Keshavarz, Daniel Friebel, Peter Benjamin Herman, Grace Marjorie Yee, Alex J. Klevay
  • Patent number: 11495830
    Abstract: A system and method for a liquid electrolyte used in secondary electrochemical cells having at least one electrode including a TMCCC material, the liquid electrolyte enabling an increased lifetime while allowing for fast discharge to extremely high depth of discharge. The addition of dinitriles to liquid electrolytes in electrochemical cells in which energy storage is achieved by ion intercalation in transition metal cyanide coordination compounds (TMCCC) has the advantage of increasing device lifetime by inhibiting common chemical and electrochemical degradation mechanisms.
    Type: Grant
    Filed: February 8, 2022
    Date of Patent: November 8, 2022
    Assignee: Natron Energy, Inc.
    Inventors: Majid Keshavarz, Daniel Friebel, Peter Benjamin Herman, Grace Marjorie Yee, Alex J. Klevay
  • Patent number: 11485931
    Abstract: A fragrance composition comprising a compound represented by Formula (1) as an active ingredient: wherein, in Formula (1), R1 represents a linear, branched, or cyclic alkyl group having 1 to 6 carbon atoms.
    Type: Grant
    Filed: June 26, 2019
    Date of Patent: November 1, 2022
    Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Atsushi Okamoto, Eriko Kushida, Umi Yokobori
  • Patent number: 11479473
    Abstract: A method is provided for manufacturing a nanoparticle material having an ionic conductivity as a battery material for Fluoride ion Batteries, thus, being capable for overcoming high resistances at the surfaces, grain-boundaries of nanoparticles or compartments of the nanoparticles by a material treatment selected from: (i) a ball-mill procedure under aerosol and/or vapour-pressure atmosphere, (ii) excess-synthesis, (iii) ball-milling with surface stabilizing and conductivity enhancing solid or/and gel/liquid additives or (iv) functionalizing the material to obtain functionalized nanoparticles (GSNP) comprising a dispersion of graphene, nanotubes and/or a further additive selected from carbon-black, graphite, Si and/or CFX, Herein, fluorides (EmmFh), fluorides composites (Em1m1Em2m2 . . .
    Type: Grant
    Filed: August 31, 2018
    Date of Patent: October 25, 2022
    Assignee: AMBERCON TECHNOLOGY (UK) LIMITED
    Inventors: Raiker Witter, Irshad Mohammad, Palanivel Molaiyan, Suresh Kumar
  • Patent number: 11482701
    Abstract: A method of operating a battery comprises discharging a cathode comprising manganese dioxide to within a 2nd electron capacity of the manganese dioxide at a C-rate of equal to or slower than C/10, recharging the battery, and cycling the battery during use a plurality of times. The cathode is in a battery, and the battery comprises the cathode, an anode, a separator disposed between the anode and the cathode, and an electrolyte. The cathode comprises the manganese dioxide and a conductive carbon. The anode comprises: a metal component and a conductive carbon. The metal component can be a metal, metal oxide, or metal hydroxide, and the metal of the metal component can be zinc, lithium, aluminum, magnesium, iron, cadmium and a combination thereof.
    Type: Grant
    Filed: August 1, 2018
    Date of Patent: October 25, 2022
    Assignee: RESEARCH FOUNDATION OF THE CITY UNIVERSITY OF NEW YORK
    Inventors: Snehal Kolhekar, Gautam G. Yadav, Jinchao Huang, Sanjoy Banerjee, Michael Nyce
  • Patent number: 11476505
    Abstract: An electrochemical cell, including a first electrode, a first volume of electrolyte in contact with the first electrode, a second volume of electrolyte, a first separator positioned between the first volume and the second volume, a second electrode in contact with the second volume, and a third volume of electrolyte. A second separator is positioned between the second volume and the third volume. A lithium reservoir electrode is in contact with the third volume.
    Type: Grant
    Filed: June 24, 2020
    Date of Patent: October 18, 2022
    Inventors: Manikandan Palanisamy, Mihit Hitendra Parekh, Vilas Ganpat Pol