Abstract: A graphene oxide based electrochemical cell and a battery containing a plurality of electrochemical cells, at least one of which is the graphene oxide based electrochemical cell. The graphene oxide based electrochemical cell includes an aqueous electrolyte solution, an anode and a cathode contained in a vessel, wherein the aqueous electrolyte solution includes water, graphene oxide nanosheets and CuCl2 dissolved in the water.

Abstract: A method for preparing a redox flow battery electrolyte is provided. In some embodiments, the method includes the processing of raw materials containing sources of chromium ions in a high oxidation state. In some embodiments, a solution of the raw materials in an acidic aqueous solution is subjected to a reducing process to reduce the chromium in a high oxide state to an aqueous electrolyte containing chromium (III) ions. In some embodiments, the reducing process is electrochemical process. In some embodiments, the reducing process is addition of an inorganic reductant. In some embodiments, the reducing process is addition of an organic reductant. In some embodiments, the inorganic reductant or the organic reductant includes iron powder.

Abstract: A surface-enabled, metal ion-exchanging battery device comprising a cathode, an anode, a porous separator, and a metal ion-containing electrolyte, wherein the metal ion is selected from (A) non-Li alkali metals; (B) alkaline-earth metals; (C) transition metals; (D) other metals such as aluminum (Al); or (E) a combination thereof; and wherein at least one of the electrodes contains therein a metal ion source prior to the first charge or discharge cycle of the device and at least the cathode comprises a functional material or nano-structured material having a metal ion-capturing functional group or metal ion-storing surface in direct contact with said electrolyte, and wherein the operation of the battery device does not involve the introduction of oxygen from outside the device and does not involve the formation of a metal oxide, metal sulfide, metal selenide, metal telluride, metal hydroxide, or metal-halogen compound.

Abstract: A method for preparing a redox flow battery electrolyte is provided. In some embodiments, the method includes the processing of raw materials containing sources of chromium ions and/or iron ions. The method further comprises the removal of impurities such as metal ions from those raw materials. In some embodiments, a reductant may be used to remove metal impurities from an aqueous electrolyte containing chromium ions and/or nickel ions. In some embodiments, the reductant is an amalgam. In some embodiments, the reductant is a zinc amalgam. Also provided is a method for removing ionic impurities from an aqueous acid solution. Further provided a redox flow battery comprising at least one electrolyte prepared from the above-identified methods.

Abstract: Representative embodiments provide a liquid or gel separator utilized to separate and space apart first and second conductors or electrodes of an energy storage device, such as a battery or a supercapacitor. A representative liquid or gel separator comprises a plurality of particles, typically having a size (in any dimension) between about 0.5 to about 50 microns; a first, ionic liquid electrolyte; and a polymer. In another representative embodiment, the plurality of particles comprise diatoms, diatomaceous frustules, and/or diatomaceous fragments or remains. Another representative embodiment further comprises a second electrolyte different from the first electrolyte; the plurality of particles are comprised of silicate glass; the first and second electrolytes comprise zinc tetrafluoroborate salt in 1-ethyl-3-methylimidalzolium tetrafluoroborate ionic liquid; and the polymer comprises polyvinyl alcohol (“PVA”) or polyvinylidene fluoride (“PVFD”).

Abstract: An organic electrolyte solution including a solvent; an electrolyte including a metal-ligand coordination compound; and an additive including a hydrophobic group and a metal affinic group.

Abstract: An energy storage device including an active electrolyte, a first electrode and a second electrode is provided. The active electrolyte contains protons and ion pairs with a redox ability. The first electrode and the second electrode coexist in the active electrolyte and are separated from each other. The first electrode and the second electrode respectively include an active material producing a redox-reaction with the active electrolyte or an active material producing ion adsorption/desorption with the active electrolyte. The active electrolyte receives electrons from the first electrode and/or the second electrode so as to perform a redox-reaction for charge storage.

Abstract: A battery is composed of a positive electrode in which a positive electrode active material layer including a positive electrode active material is formed on a positive electrode collector, a negative electrode in which a negative electrode active material layer including a negative electrode active material is formed on a negative electrode collector, a separator provided between the positive electrode and the negative electrode, and an electrolyte impregnated in the separator. The battery further includes at least one of a heteropoly acid and a heteropoly acid compound as an additive at least in one of the positive electrode, the negative electrode, the separator, and the electrolyte.

Abstract: An anode or an electrolytic solution or both contain a metal salt including an unsaturated carbon bond. The electrolytic solution contains an unsaturated carbon bond cyclic ester carbonate represented by Formula (1) or a halogenated cyclic ester carbonate represented by Formula (2) or both, and contains a cyclic ester represented by Formula (3), where each of R1 and R2 is a group such as a hydrogen group, where each of R3 to R6 is a group such as a hydrogen group; and each of one or more of R3 to R6 is a group such as a halogen group, where X is an ether bond (—O—) or a methylene group (—CH2—); each of R7 to R10 is a group such as a hydrogen group; and each of R7 to R10 is a group such as an alkyl group when X is the ether bond.

Abstract: A surface-enabled, metal ion-exchanging battery device comprising a cathode, an anode, a porous separator, and a metal ion-containing electrolyte, wherein the metal ion is selected from (A) non-Li alkali metals; (B) alkaline-earth metals; (C) transition metals; (D) other metals such as aluminum (Al); or (E) a combination thereof; and wherein at least one of the electrodes contains therein a metal ion source prior to the first charge or discharge cycle of the device and at least the cathode comprises a functional material or nano-structured material having a metal ion-capturing functional group or metal ion-storing surface in direct contact with said electrolyte, and wherein the operation of the battery device does not involve the introduction of oxygen from outside the device and does not involve the formation of a metal oxide, metal sulfide, metal selenide, metal telluride, metal hydroxide, or metal-halogen compound.

Abstract: A phosphate based compound basically comprising—A: exchangeable cations used in charging and discharging, e.g. Li, Na, K, Ag, —B: non-exchangeable cations from the transition metals, group 3-12 of the periodic table of elements, e.g. Fe, Mn, Co, Cr, Ti, V, Cu, Sc, —C: 60 Mol-%-90 Mol-%, preferably 75 Mol-% of the compound being phosphate (PO4)3? anions, where oxygen is or may be partially substituted by a halide (e.g. F, Cl) and/or OH? to a maximum concentration of 10 Mol-% of the oxygen of the anions and wherein said (PO4)3? coordination polyhedra may be partially substituted by one or more of: SiO44 silicate, BO33? borate, CO32? carbonate, H2O water up to a maximum amount of <31 Mol-% of the anions, said compound being in crystalline form and having open elongate channels extending through the unit cell of the structure and with the compound being present either in single crystal form or as an anisotropic microcrystalline or nanocrystalline material.

Abstract: A nonaqueous electrolyte includes: a nonaqueous solvent; an electrolyte salt; a hydrocarbon compound having a nitrile group; and at least one of a heteropolyacid and a heteropolyacid compound.

Abstract: A nonaqueous electrolyte includes: a nonaqueous solvent; an electrolyte salt; an imide salt; and at least one of a heteropolyacid and a heteropolyacid compound.

Abstract: A nonaqueous electrolyte includes: a solvent, an electrolyte salt, and at least one of heteropolyacid salt compounds represented by the following formulae (I) and (II): HxAy[BD12O40].zH2O (I), HpAq[B5D30O110].rH2O (II). A represents Li, Na, K, Rb, Cs, Mg, Ca, Al, NH4, or an ammonium salt or phosphonium salt; B represents P, Si, As or Ge; D represents at least one element selected from Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Zr, Nb, Mo, Tc, Rh, Cd, In, Sn, Ta, W, Re and Tl; x, y and z are values falling within the ranges of (0?x?1), (2?y?4) and (0?z?5), respectively; and p, q and r are values falling within the ranges of (0?p?5), (10?q?15) and (0?r?15), respectively.

Abstract: The invention relates to an energy converter cell, consisting of a negative metal electrode, preferably a tin electrode, a positive electrode consisting of graphite and an electrolyte that is positioned between the electrodes and is in contact with the latter, the electrolyte containing in the charged state a manganate(IV) salt that is dissolved in water and an alkali hydroxide. The energy converter cell forms a galvanic element, which can be discharged by delivering electrical energy to an ohmic consumer resistor that is connected to the electrodes and can be charged by a supply of thermal energy. In addition, supplied electrical energy can be electrochemically stored in the cell.

Abstract: A method for preparing a redox flow battery electrolyte is provided. In some embodiments, the method includes the processing of raw materials containing sources of chromium ions in a high oxidation state. In some embodiments, a solution of the raw materials in an acidic aqueous solution is subjected to a reducing process to reduce the chromium in a high oxide state to an aqueous electrolyte containing chromium (III) ions. In some embodiments, the reducing process is electrochemical process. In some embodiments, the reducing process is addition of an inorganic reductant. In some embodiments, the reducing process is addition of an organic reductant. In some embodiments, the inorganic reductant or the organic reductant includes iron powder.

Abstract: A storage battery is provided such that in its charged condition the positive electrode comprises lead dioxide and the negative electrode comprises zinc. Upon discharge, the lead dioxide is reduced to lead monoxide and the zinc is oxidized to zinc oxide. The electrolyte comprises an aqueous solution of a chromate salt.

Abstract: The present invention provides compositions, formulations and methods providing for the effective dissolution of inorganic fluorides in solvents via incorporation of a dissociating agent component. Dissociating agents of the present invention participate in chemical reactions in solution, such as complex formation, acid-base reactions, and adduct formation reactions, that result in enhancement in the dissolution of inorganic fluorides in a range of solvent environments. Dissociating agents comprising Lewis acids, Lewis bases, anion receptors, cation receptors or combinations thereof are provided that significantly increase the extent of dissolution of a range of inorganic fluorides, particularly inorganic fluorides, such as LiF, that are highly insoluble in many solvents in the absence of the dissociating agents of the present invention.

Abstract: The invention relates to an energy converter cell, consisting of a negative metal electrode, preferably a tin electrode, a positive electrode consisting of graphite and an electrolyte that is positioned between the electrodes and is in contact with the latter, the electrolyte containing in the charged state a manganate (IV) salt that is dissolved in water and an alkali hydroxide. The energy converter cell forms a galvanic element, which can be discharged by delivering electrical energy to an ohmic consumer resistor that is connected to the electrodes and can be charged by a supply of thermal energy. In addition, supplied electrical energy can be electrochemically stored in the cell.

Abstract: An electric cell using aluminum in a negative electrode has a positive electrode, the negative electrode containing aluminum or aluminum alloy, and an electrolyte arranged between the positive electrode and the negative electrode. The electrolyte includes: at least one ion selected from a group of a sulfate ion (SO42−) and a nitrate ion (NO3−); and an additive. The additive is selected from an organic acid, a salt of the organic acid, an hydrate of the organic acid, an ester of the organic acid, an ion of the organic acid, and derivatives thereof. Thus, the electric cell of the present invention using aluminum in a negative electrode allows the improvements in the voltage and the capacity of the cell as the generation of gas depending on the self-discharge can be prevented.

Abstract: A nickel hydride secondary cell having a positive electrode which contains nickel oxide or nickel hydroxide, a negative electrode which contains a hydrogen occlusion alloy, and an electrolytic solution containing an alkali metal salt as a corrosion inhibitor, which cell has an increased maintenance rate of charge after storage.

Abstract: A magnesium/manganese dioxide electrochemical cell that has been stored fowing partial usage is improved by increasing the cathode moisture content at the time of making the cell to reduce the self discharge and increase the operating capacity after the cell has been stored following partial usage.

Abstract: An electrolyte for a Redox flow battery contains from 1 to 4 normal hydrochloric acid and at least 0.5 mole/liter of an active material, and further contains from 0.1 to 4 normalities of an acid comprising an anion which does not inhibit the electrode reactions in addition to the hydrochloric acid. This electrolyte reduces the cell resistivity and improves the solubility of active materials.

Abstract: A process for producing an anolyte and a catholyte for redox cells which comprises the steps of heating chromium ore together with carbonaceous substances to produce a pre-reduced chromium product produced a part of iron and chromium in chromium ore, dissolving the pre-reduced chromium product in hydrochloric acid and/or sulfuric acid iron and chromium. Thus, the dissolving step can be simplified, the predetermined concentration can be simply regulated.

Abstract: A battery cell which comprises an anode element of magnesium alloy metal, a carbon or stainless steel current collector, and a manganese-dioxide-type cathode mix and electrolyte comprising mainly manganese dioxide with the addition of potassium monoperoxysulfate to substantially improve the open-circuit voltage of the battery cell and to substantially decrease polarization. Additions to said mix of such metal oxides as nickel oxide, lead dioxide, cobalt oxide, aluminum oxide, copper oxide, silver oxide or others substantially contribute to increased battery capacity. The addition of lithium chloride to the above improved battery cell in small amounts substantially increases the low-temperature range of these battery cells without improvement of battery capacity.

Abstract: A redox flow battery with a positive half-cell compartment containing bromide ion, bromine and a complexing organic liquid for bromine, and a negative electrode half-cell compartment containing chromium ion, and including electrolyte fluid communication therebetween.

Abstract: In a redox battery using a titanium redox system or chromium redox system as an active material for the negative electrode or a manganese redox system as an active material for the positive electrode, the electromotive force of the battery and the stability of electrolyte solutions are enhanced by addition of a chelating agent such as citric acid or a complexing agent such as phosphoric acid to the redox system used therein.

Abstract: A method of producing a thickened electrolyte for a primary cell, which involves mixing, at about room temperature, aqueous solutions of calcium chloride, zinc chloride, and ammonium chloride with a tanning agent, such as chromium sulphate, and starch as a thickening agent, aging the resulting mixture until a thickened electrolyte with a compressive strength of 0.05-0.85 kg/cm.sup.2 is obtained and pressing said electrolyte through at least one drawhole at a rate of at least 0.05 m/sec, the resulting viscosity of the electrolyte being sufficient to apply a layer of the thickened electrolyte to the negative electrode of a primary cell.

Abstract: The addition of cathode materials comprising Cu.sup.++, Fe.sup.+++, Cr.sup.+++ or Au.sup.+++, in the form of salts such as the nitrate or halide, e.g. Fe(NO.sub.3).sub.3 or CuCl.sub.2, to low melting nitrate electrolyte cells increases cell potential. Other ions such as Co.sup.++, Eu.sup.+++, La.sup.+++, Ni.sup.++, Mn.sup.++, Ce.sup.+++, Pr.sup.+++, Nd.sup.+++, Gd.sup.+++, Sm.sup.+++ and Tb.sup.+++, in the form of salts thereof, can also be used, but yield smaller cell potentials. Such cathodic materials in the form of a suitable salt, such as a nitrate or halide, e.g. Fe(NO.sub.3).sub.3 or CuCl.sub.2, are added to low melting fused nitrate electrolytes, e.g. a LiNO.sub.3, KNO.sub.3 mixture, in a concentration sufficient to increase cell potential, using Li or Ca anodes. A suitable metal current collector such as a Ni screen can be used as a cathode. The above cathodic materials can be used in conjunction with other cathodic materials such as AgNO.sub.3, which undergoes reduction to the free metal.