With Acid Containing N Or P Constituent Patents (Class 429/203)
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Patent number: 11581567Abstract: The present invention provides a lithium ion battery and an electrolyte thereof. The electrolyte for the lithium ion battery includes a non-aqueous organic solvent, a lithium salt and additives, wherein the additives include additive A cyclophosphazene compound, additive B lithium fluorophosphate compound, and additive C selected from at least one of silane phosphate compound, silane phosphite compound and silane borate compound. Compared with conventional technologies, the nickel-rich positive electrode lithium ion battery using the electrolyte of the present invention has a desirable cyclic capacity retention rate, a desirable storage capacity retention rate and a low gas production at high temperature, and has a low DC internal resistance at low temperature, which can remarkably improve the thermal stability of lithium ion battery.Type: GrantFiled: February 14, 2018Date of Patent: February 14, 2023Assignee: CONTEMPORARY AMPEREX TECHNOLOGY CO., LIMITEDInventors: Ming Zhang, Changlong Han, Hao Zhang, Cuiping Zhang
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Patent number: 11424481Abstract: An electrolyte for a secondary battery, the electrolyte including an ionic liquid polymer including a repeating unit represented by Formula 1: wherein, in Formula 1, CY, R1, R2, R3, X1?, n, and m are the same as described in the specification.Type: GrantFiled: June 30, 2020Date of Patent: August 23, 2022Assignees: SAMSUNG ELECTRONICS CO., LTD., SAMSUNG SDI CO., LTD.Inventors: Hongsoo Choi, Tomonobu Mizumo, Yonggun Lee, Wonseok Chang, Toshinori Sugimoto, Myungjin Lee
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Patent number: 11258095Abstract: A solid-state rechargeable battery includes a pair of electrode layers and a solid electrolyte layer interposed between the pair of electrode layers. The pair of electrode layers each includes a phosphate having an olivine crystal structure. The phosphate contains a transition metal and lithium.Type: GrantFiled: January 13, 2020Date of Patent: February 22, 2022Assignee: TAIYO YUDEN CO. LTD.Inventor: Daigo Ito
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Patent number: 11201354Abstract: An electrolytic solution contains: an electrolyte including a lithium salt represented by general formula (1) below; an organic solvent including a linear carbonate represented by general formula (2) below; and an unsaturated cyclic carbonate, wherein the linear carbonate is contained at a mole ratio of 3 to 6 relative to the lithium salt, and/or the lithium salt is contained at a concentration of 1.1 to 3.8 mol/L.Type: GrantFiled: April 14, 2017Date of Patent: December 14, 2021Assignee: KABUSHIKI KAISHA TOYOTA JIDOSHOKKIInventors: Hiroyuki Sasaki, Tomoyuki Kawai, Yoshihiro Nakagaki, Ryota Okamoto, Kensuke Yotsumoto, Atsushi Minagata, Yuki Sugimoto, Yuuhi Sato
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Patent number: 10770750Abstract: A lithium ion conductor includes a first lithium ion conductor that contains at least one selected from among oxide crystals and glass ceramics, and a second lithium ion conductor that has a sintering temperature of not more than 600° C. The lithium ion conductivity of the first lithium ion conductor is higher than the lithium ion conductivity of the second lithium ion conductor.Type: GrantFiled: March 10, 2016Date of Patent: September 8, 2020Assignee: MURATA MANUFACTURING CO., LTD.Inventors: Keisuke Shimizu, Masamitsu Suzuki, Tatsuya Furuya, Kenji Kishimoto, Go Sudo, Yasushi Tamura, Yumiko Yoshida
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Patent number: 10707522Abstract: A method of making a solid state battery may include heating a flux sandwiched between a solid ceramic electrolyte and a group one metal. The flux may be heated such that it roughens a surface of the solid ceramic electrolyte and the group one metal melts and adheres to the surface of the solid ceramic electrolyte.Type: GrantFiled: September 24, 2015Date of Patent: July 7, 2020Assignee: Ford Global Technologies, LLCInventors: Venkataramani Anandan, Andrew Robert Drews, Mohan Karulkar
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Patent number: 10637117Abstract: The present invention relates to electrolyte additives for magnesium air batteries, which are compatible with rechargeable magnesium batteries and carry the promise of overcoming the hurdles, especially enhancing the overall performance of magnesium air batteries comprising an aqueous electrolyte. The electrolyte additive for a magnesium battery comprising a chelating agent which is capable of forming a complex with at least one of Fe(II), and Fe(III) ions, where the complex with at least one of Fe(II) and Fe(III) ions has a stability constant in aqueous solution at room temperature (about 25° C.) log K of greater than or equal to 6.0 and which is also capable of forming a complex with Mg(II) ions where the complex with Mg(II) ions has a stability constant in aqueous solution at room temperature (about 25° C.) log K of greater than or equal to 4.0.Type: GrantFiled: August 29, 2017Date of Patent: April 28, 2020Assignee: Helmholtz-Zentrum Geestachts Zentrum Fuer Material—Und Kuestenforschung GmbHInventors: Sviatlana Lamaka, Daniel Höche, Mikhail Zheludkevich
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Patent number: 10211484Abstract: An electrolyte composition containing (i) at least one aprotic organic solvent; (ii) at least one conducting salt; (iii) acetic acid 2-[(methoxycarbonyl)oxy] methyl ester; and (vi) optionally one or more additives.Type: GrantFiled: November 3, 2015Date of Patent: February 19, 2019Assignee: Gotion Inc.Inventors: Rene Schmitz, Karolin Geyer
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Patent number: 9647471Abstract: A battery management system (BMS) monitors and reports on an operational state of a battery. In some embodiments the BMS can be part of a battery assembly. In at least one embodiment the BMS can monitor battery voltage, charge and discharge current, temperature and (via a measurement utilizing magnetism) chemical change in a battery. In some embodiments, a permanent magnet is placed within the battery and a magnetoresistance sensor on the battery management system circuit board is employed to measure the affected magnetic field from the chemical change within the battery as it moves from a discharged state to a charged state and back to a discharged state. This measurement provides for an accurate statement of the battery's present day state of charge and state of health.Type: GrantFiled: October 17, 2014Date of Patent: May 9, 2017Assignee: Trion Energy Solutions Corp.Inventors: Steve Waterford, Thomas R. Zwaska
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Patent number: 9384906Abstract: The present invention provides a nonaqueous electrolytic solution capable of improving electrochemical characteristics at high temperatures, which comprises at least one organic phosphorus compound represented by the following general formula (I), an energy storage device using the nonaqueous electrolytic solution, and a specific organic phosphorus compound. (In the formula, R1 and R2 each independently represent an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an alkoxy group, a cycloalkoxy group, an alkenyloxy group, an alkynyloxy group, a halogenoalkyl group, a halogenoalkoxy group, an aryl group, or an aryloxy group; R3 and R4 each independently represent a hydrogen atom, a halogen atom, or an alkyl group; m is an integer of from 1 to 4, n is 0 or 1, q is 1 or 2. When q is 1 and n is 0, X represents an alkoxy group, an alkynyloxy group, an alkyloxyalkoxy group, an aryloxy group, etc.Type: GrantFiled: April 12, 2012Date of Patent: July 5, 2016Assignee: UBE INDUSTRIES, LTD.Inventors: Koji Abe, Kei Shimamoto
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Patent number: 8993158Abstract: The present invention provides a non-aqueous electrolyte solution which contains a silyl ester group-containing phosphonic acid derivative.Type: GrantFiled: May 17, 2011Date of Patent: March 31, 2015Assignee: Mitsui Chemicals, Inc.Inventors: Takeshi Kobayashi, Shigeru Mio, Hidenobu Nogi, Takashi Hayashi
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Publication number: 20150064603Abstract: Flexible electrical devices are provided that include a coated inner carbon nanotube electrode that has an exterior surface, an outer carbon nanotube electrode disposed on the exterior surface of the coated inner carbon nanotube electrode, and an overlap region in which the coated inner carbon nanotube electrode and the outer carbon nanotube electrode overlap one another, in which the device has a fiber-like geometry and first and second electrode ends. Methods are provided for fabricating an electrical component that includes a flexible electrical component having a fiber-like geometry and includes carbon nanotube electrodes.Type: ApplicationFiled: August 28, 2014Publication date: March 5, 2015Inventors: Jesse Smithyman, Zhiyong Liang
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Patent number: 8945765Abstract: A secondary lithium battery electrolyte including a lithium salt, a nonaqueous organic solvent, and an electrolyte additive represented by Formula 1: where n is an integer in the range of 1 to 4. A secondary lithium battery having excellent cycle and high temperature retention characteristics can be provided by using such secondary lithium battery electrolyte.Type: GrantFiled: September 15, 2009Date of Patent: February 3, 2015Assignee: Samsung SDI Co., Ltd.Inventors: Seok-soo Lee, Young-gyoon Ryu, Dong-joon Lee
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Publication number: 20140178751Abstract: Provided is an electrolyte additive for a lithium ion secondary battery including an organic lithium compound and a hyper-branched structure material. The electrolyte additive enhances the decomposition voltage of the electrolyte up to 5.5 V, and increases the heat endurable temperature by 10° C. or more. The safety of the battery is thus improved.Type: ApplicationFiled: December 19, 2013Publication date: June 26, 2014Applicant: Industrial Technology Research InstituteInventors: Tsung-Hsiung Wang, Chung-Liang Chang, Jing-Pin Pan
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Publication number: 20140038061Abstract: The electrolyte includes a magnesium salt having the formula Mg(BX4)2 where X is selected from H, F and O-alkyl. The electrolyte also includes a solvent, the magnesium salt being dissolved in the solvent. Various solvents including aprotic solvents and molten salts such as ionic liquids may be utilized.Type: ApplicationFiled: December 19, 2012Publication date: February 6, 2014Applicant: Toyota Motor Engineering & Manufacturing North America, Inc.Inventor: Toyota Motor Engineering & Manufacturing North America, Inc.
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Patent number: 8628880Abstract: Redox flow battery systems having a supporting solution that contains Cl? ions can exhibit improved performance and characteristics. Furthermore, a supporting solution having mixed SO42? and Cl? ions can provide increased energy density and improved stability and solubility of one or more of the ionic species in the catholyte and/or anolyte. According to one example, a vanadium-based redox flow battery system is characterized by an anolyte having V2+ and V3+ in a supporting solution and a catholyte having V4+ and V5+ in a supporting solution. The supporting solution can contain Cl? ions or a mixture of SO42? and Cl? ions.Type: GrantFiled: September 28, 2010Date of Patent: January 14, 2014Assignee: Battelle Memorial InstituteInventors: Liyu Li, Soowhan Kim, Zhenguo Yang, Wei Wang, Jianlu Zhang, Baowei Chen, Zimin Nie, Guanguang Xia
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Publication number: 20140011082Abstract: According to one embodiment, there is provided a nonaqueous electrolyte secondary battery including a positive electrode, a negative electrode containing a titanium-containing oxide, and a nonaqueous electrolyte. The nonaqueous electrolyte contains carbon monoxide and at least one selected from difluorophosphoric acid and monofluorophosphoric acid. The ratio of the mass concentration of carbon monoxide to the sum of the mass concentrations of difluorophosphoric acid and monofluorophosphoric acid is in the range of 0.1 to 5%.Type: ApplicationFiled: July 3, 2013Publication date: January 9, 2014Inventors: Dai YAMAMOTO, Shinsuke Matsuno, Hidesato Saruwatari, Hiroko Watando, Sayaka Morimoto, Kazuya Kuriyama, Hideki Satake
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Publication number: 20130330598Abstract: A non-aqueous electrolyte solution for a lithium secondary battery and a lithium secondary battery including the same are provided. The non-aqueous electrolyte solution includes an organic solvent, an ionizable lithium salt, a dinitrile compound including an ether bond represented by Chemical Formula 1, and an aliphatic dinitrile compound represented by Chemical Formula 2. The lithium secondary battery including the non-aqueous electrolyte solution having the possibility of generating a swelling phenomenon while storing or charging/discharging at a high temperature may be restrained. In addition, a cycle life of the charging/discharging may be improved.Type: ApplicationFiled: August 14, 2013Publication date: December 12, 2013Applicant: LG CHEM, LTD.Inventors: You Jin Shim, Jae Seung Oh, Yeon Suk Hong, Byoung Bae Lee, Hyo Jin Lee
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Publication number: 20130196206Abstract: An organic electrolyte solution including a solvent; an electrolyte including a metal-ligand coordination compound; and an additive including a hydrophobic group and a metal affinic group.Type: ApplicationFiled: January 30, 2013Publication date: August 1, 2013Applicant: Samsung Electronics Co., Ltd.Inventor: Samsung Electronics Co., Ltd.
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Publication number: 20130164602Abstract: An energy storage device including an active electrolyte, a first electrode and a second electrode is provided. The active electrolyte contains protons and ion pairs with a redox ability. The first electrode and the second electrode coexist in the active electrolyte and are separated from each other. The first electrode and the second electrode respectively include an active material producing a redox-reaction with the active electrolyte or an active material producing ion adsorption/desorption with the active electrolyte. The active electrolyte receives electrons from the first electrode and/or the second electrode so as to perform a redox-reaction for charge storage.Type: ApplicationFiled: July 30, 2012Publication date: June 27, 2013Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventors: Li-Duan Tsai, Chung-Hsiang Chao, Jenn-Yeu Hwang, Chun-Lung Li
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Patent number: 8377546Abstract: A plastics electrode material includes a mixture having a nitrogen-containing conductive polymer and a conductive carbon material mixed with the polymer. The polymer is polyquinoline, polyphenylquinoxaline, polycarbazole, polypyridine, polypyrrole, polyaniline or polyindole. The conductive carbon material is 1% to 40% by weight of the mixture. The mixture is activated by a 0.2 M to 5 M proton-containing acidic electrolytic solution. The present invention further comprises second cells using the plastics electrode material. Because the conductive carbon material and high concentration acidic electrolytic solution are added to the polymer, the plastics electrode material has a high conductivity. Thus, the secondary cells have a high efficiency of charging and discharging and a long cyclic life.Type: GrantFiled: September 8, 2008Date of Patent: February 19, 2013Assignee: Silver H-Plus Technology Co., Ltd.Inventors: Chen-Chun Chuang, Ching-Yun Hsu, Li-Hsiang Perng
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Publication number: 20130022863Abstract: A non-aqueous electrolyte composition, useful in batteries, capacitors and the like, said electrolyte composition comprising an electrolyte support salt, a non-aqueous electrolyte carrier, and a polycyclic aromatic amine, e.g., a naphthyl amine.Type: ApplicationFiled: July 17, 2012Publication date: January 24, 2013Applicant: CHEMTURA CORPORATIONInventors: Venkat Madabusi, Gerard Mulqueen
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Publication number: 20130004840Abstract: A non-aqueous electrolyte additive for a lithium secondary battery, a non-aqueous electrolyte for a lithium secondary battery, and a lithium secondary battery, the additive including a bidentate phosphorus compound represented by the following Chemical Formula 1.Type: ApplicationFiled: February 1, 2012Publication date: January 3, 2013Inventors: Jung-Yi YU, Woo-Cheol Shin, Sang-Il Han, Mi-Hyun Lee, Tae-Hyun Bae
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Publication number: 20120321911Abstract: A battery is composed of a positive electrode in which a positive electrode active material layer including a positive electrode active material is formed on a positive electrode collector, a negative electrode in which a negative electrode active material layer including a negative electrode active material is formed on a negative electrode collector, a separator provided between the positive electrode and the negative electrode, and an electrolyte impregnated in the separator. The battery further includes at least one of a heteropoly acid and a heteropoly acid compound as an additive at least in one of the positive electrode, the negative electrode, the separator, and the electrolyte.Type: ApplicationFiled: June 17, 2010Publication date: December 20, 2012Applicant: SONY CORPORATIONInventors: Haruo Watanabe, Tomoyo Ooyama, Shunsuke Saito, Shinichi Katayama, Hideki Nakai, Yoshihiro Kudo, Yoshikazu Kato, Muneaki Ando, Koji Morita, Ichiro Yamada, Nobuya Okano, Noritoshi Araki, Shuhei Sugita, Kunihiko Hayashi, Yosuke Hosoya, Tadahiko Fujita, Shigeru Fujita
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Patent number: 8334404Abstract: A non-aqueous electrolyte usable in rechargeable lithium-ion batteries including a solution of LiPF6/carbonate based electrolytes with low concentrations of LiFOP such that the thermal stability is increased compared to a standard lithium battery. A method of making lithium tetrafluorophospahte (LiF4C2O4, LiFOP) including, reacting PF5 with lithium oxalate, recrystallizing DMC/dichloromethane from a 1:1 mixture of to separate LiF4OP from LiPF6 to form a lithium salt. An electric current producing rechargeable Li-ion cell. The rechargeable lithium ion cell includes an anode, a cathode, and a non-aqueous electrolyte comprising a solution of a lithium salt in a non-aqueous organic solvent containing lithium tetrafluorooxalatophosphate (LiPF4(C2O4), LiF4OP).Type: GrantFiled: September 3, 2009Date of Patent: December 18, 2012Assignee: Board of Governors for Higher Education, State of Rhode Island and Providence PlantationsInventors: Brett Lucht, Ang Xiao, Li Yang, Mengqing Xu
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Publication number: 20120251892Abstract: An electrolyte for a lithium secondary battery including a lithium salt, a nonaqueous organic solvent, and an additive, in which the additive is composed of one or more compounds including a purinone or a purinone derivative. The lithium secondary battery with improved life and high-temperature storage may be provided by using the electrolyte for a lithium secondary battery according to an embodiment of the present invention.Type: ApplicationFiled: March 28, 2012Publication date: October 4, 2012Applicant: Samsung Electronics Co., Ltd.Inventors: Yoon-sok KANG, Jun-young Mun, Min-sik Park, Jin-hwan Park, Mi-jeong Song
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Patent number: 8277973Abstract: A nonaqueous electrolyte composition containing an electrolyte salt, a nonaqueous solvent and a compound having a phosphorus-hydrogen bond or a phosphorus-carbon bond is provided. Also provided is a nonaqueous electrolyte secondary battery including: a cathode and an anode having a material capable of occluding and releasing lithium ions as a cathode active material and an anode active material, respectively; a nonaqueous electrolyte composition; a separator; and an outer package member for housing the anode, the cathode, the nonaqueous electrolyte composition and the separator. The nonaqueous electrolyte composition includes an electrolyte salt, a nonaqueous solvent and a compound having a phosphorus-hydrogen bond or a phosphorus-carbon bond.Type: GrantFiled: June 14, 2007Date of Patent: October 2, 2012Assignee: Sony CorporationInventor: Atsumichi Kawashima
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Publication number: 20120219854Abstract: Disclosed is a nonaqueous electrolytic solution which enables formation of a nonaqueous-electrolyte battery having high capacity and excellent storage characteristics at high temperatures, while sufficiently enhancing safety at the time of overcharge. A nonaqueous-electrolyte battery produced by using the nonaqueous electrolytic solution is also disclosed. The nonaqueous electrolytic solution comprises an electrolyte and a nonaqueous solvent, and includes any of specific nonaqueous electrolytic solutions (A) to (D).Type: ApplicationFiled: May 8, 2012Publication date: August 30, 2012Applicant: MITSUBISHI CHEMICAL CORPORATIONInventors: Yumiko NAKAGAWA, Minoru KOTATO, Daisuke NODA, Shinichi KINOSHITA
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Publication number: 20120164525Abstract: A lithium secondary battery includes a positive electrode, a negative electrode, and an electrolyte solution. The positive electrode contains a positive electrode active material including element M2 incorporated in a crystal structure in a surface layer area of a complex oxide, the oxide including the element M1 and being represented by the following formula (1), M2 being different from M1. The element M2 is at least one kind selected from the group consisting of magnesium Mg, calcium Ca, titanium Ti, zirconium Zr, sulfur S, fluorine F, iron Fe, copper Cu, boron B, aluminum Al, phosphorus P, carbon C, manganese Mn, nickel Ni, and cobalt Co. Li1+a(MnbCocNi1?b?c)1?aM1dO2?e??(1) M1 is at least one kind of aluminum, magnesium, zirconium, titanium, barium Ba, boron, silicon Si, and iron, a satisfies 0<a<0.25, b satisfies 0.5?b<0.7, c satisfies 0?c<1?b, d satisfies 0.01?d?0.2, and e satisfies 0?e?1.Type: ApplicationFiled: December 14, 2011Publication date: June 28, 2012Applicant: SONY CORPORATIONInventors: Kazuaki Endoh, Akira Takamuku, Masaharu Senoue, Guohua Li, Kenichi Kawase, Yosuke Hosoya
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Publication number: 20120140378Abstract: A rechargeable energy storage device is disclosed. In at least one embodiment the energy storage device includes an air electrode providing an electrochemical process comprising reduction and evolution of oxygen and a capacitive electrode enables an electrode process consisting of non-faradic reactions based on ion absorption/desorption and/or faradic reactions. This rechargeable energy storage device is a hybrid system of fuel cells and ultracapacitors, pseudocapacitors, and/or secondary batteries.Type: ApplicationFiled: December 3, 2010Publication date: June 7, 2012Applicant: IMRA AMERICA, INC.Inventors: Bing TAN, Zhendong Hu, Yong Che
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Publication number: 20120121975Abstract: Compositions including glass fibers with a high surface atomic percentage of oxygen bonded to silicon wherein the fibers form at least part of a battery separator or other battery component.Type: ApplicationFiled: November 23, 2011Publication date: May 17, 2012Applicant: HOLLINGSWORTH & VOSE COMPANYInventors: Mohan Rajaram, George C. Zguris
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Patent number: 8168831Abstract: A non-aqueous electrolyte cell comprises a positive electrode, a negative electrode and a non-aqueous electrolyte containing a support salt. The non-aqueous electrolyte further comprises a phosphazene derivative. The phosphazene derivative having a specified structure functions as an electrode stabilizing agent or a non-combustion agent.Type: GrantFiled: June 4, 2009Date of Patent: May 1, 2012Assignee: Bridgestone CorporationInventors: Masashi Otsuki, Shigeki Endo, Takao Ogino, Yasuo Horikawa
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Publication number: 20110311885Abstract: A nonaqueous electrolyte includes: a nonaqueous solvent; an electrolyte salt; an imide salt; and at least one of a heteropolyacid and a heteropolyacid compound.Type: ApplicationFiled: May 18, 2011Publication date: December 22, 2011Applicant: SONY CORPORATIONInventors: Ichiro Yamada, Shunsuke Saito, Haruo Watanabe, Tadahiko Kubota
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Publication number: 20110311864Abstract: A nonaqueous electrolyte includes: a nonaqueous solvent; an electrolyte salt; a hydrocarbon compound having a nitrile group; and at least one of a heteropolyacid and a heteropolyacid compound.Type: ApplicationFiled: June 10, 2011Publication date: December 22, 2011Applicant: SONY CORPORATIONInventors: Ichiro Yamada, Shunsuke Saito, Haruo Watanabe, Tadahiko Kubota
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Publication number: 20110274965Abstract: A nonaqueous electrolyte includes: a solvent, an electrolyte salt, and at least one of heteropolyacid salt compounds represented by the following formulae (I) and (II): HxAy[BD12O40].zH2O (I), HpAq[B5D30O110].rH2O (II). A represents Li, Na, K, Rb, Cs, Mg, Ca, Al, NH4, or an ammonium salt or phosphonium salt; B represents P, Si, As or Ge; D represents at least one element selected from Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Zr, Nb, Mo, Tc, Rh, Cd, In, Sn, Ta, W, Re and Tl; x, y and z are values falling within the ranges of (0?x?1), (2?y?4) and (0?z?5), respectively; and p, q and r are values falling within the ranges of (0?p?5), (10?q?15) and (0?r?15), respectively.Type: ApplicationFiled: February 23, 2011Publication date: November 10, 2011Applicant: SONY CORPORATIONInventors: Ichiro Yamada, Shunsuke Saito, Haruo Watanabe, Tadahiko Kubota
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Publication number: 20110217600Abstract: A nonaqueous electrolyte battery is provided and includes a positive electrode, a negative electrode, and an electrolyte. The electrolyte contains a nonaqueous solvent, an electrolyte salt, a matrix polymer and a ceramic powder, and further contains a polyacid and/or a polyacid compound.Type: ApplicationFiled: February 23, 2011Publication date: September 8, 2011Applicant: SONY CORPORATIONInventors: Yumiko Torimizu, Haruo Watanabe, Fumihata Yamamoto, Masaki Machida, Yuki Ogawa
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Publication number: 20110212359Abstract: The present invention provides a lithium-ion electrochemical cell comprising an ionic liquid electrolyte solution and a positive electrode having a carbon sheet current collector.Type: ApplicationFiled: November 23, 2010Publication date: September 1, 2011Applicant: Leyden Energy, Inc.Inventors: Hongli Dai, Michael Erickson, Marc Juzkow
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Publication number: 20110165471Abstract: Provided is an anode for use in electrochemical cells, wherein the anode active layer has a first layer comprising lithium metal and a multi-layer structure comprising single ion conducting layers and polymer layers in contact with the first layer comprising lithium metal or in contact with an intermediate protective layer, such as a temporary protective metal layer, on the surface of the lithium-containing first layer. Another aspect of the invention provides an anode active layer formed by the in-situ deposition of lithium vapor and a reactive gas. The anodes of the current invention are particularly useful in electrochemical cells comprising sulfur-containing cathode active materials, such as elemental sulfur.Type: ApplicationFiled: July 25, 2008Publication date: July 7, 2011Applicant: Sion Power CorporationInventors: Terje A. Skotheim, Christopher J. Sheehan, Yuriy V. Mikhaylik, John D. Affinito
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Publication number: 20110143196Abstract: Objects of the present invention are to improve the adhesion and processing characteristics of electrode composite layers and to provide a lithium secondary battery by which a decrease in battery capacity during high-temperature storage at 50° C. or higher is suppressed. The lithium secondary battery of the present invention comprises a positive electrode capable of storing and releasing lithium ions, a negative electrode capable of storing and releasing lithium ions, a separator disposed between the positive electrode and the negative electrode, and an electrolyte, wherein the negative electrode or the electrolyte contains a nonvolatile liquid.Type: ApplicationFiled: December 7, 2010Publication date: June 16, 2011Inventors: Takefumi OKUMURA, Ryo Inoue, Toshio Haba, Chieko Araki
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Patent number: 7914932Abstract: An all-solid-state battery having a high output power and a long life, exhibiting high safety, and being produced at a low cost is provided. The all-solid-state battery has a cathode comprising a cathode material, an anode comprising an anode material, and a solid electrolyte layer comprising a solid electrolyte, wherein the cathode material, the anode material, and the solid electrolyte are a compound shown by the following formulas (1), (2), and (3), respectively: MaN1bX1c ??(1) MdN2eX2f ??(2) MgN3hX3i ??(3) wherein M represents H, Li, Na, Mg, Al, K, or Ca and X1, X2, and X3 are polyanions, each of N1 and N2 is at least one atom selected from the group consisting of transition metals, Al, and Cu, and N3 is at least one atom selected from the group consisting of Ti, Ge, Hf, Zr, Al, Cr, Ga, Fe, Sc, and In.Type: GrantFiled: February 23, 2007Date of Patent: March 29, 2011Assignees: NGK Insulators, Ltd., Kyushu UniversityInventors: Toshihiro Yoshida, Hiroyuki Katsukawa, Shigeto Okada
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Patent number: 7833391Abstract: An apparatus for splitting water to produce hydrogen having at least one photoelectrochemical cell. The photoelectrochemical cell includes at least one water permeable photoelectrode having a light sensitive, nano-crystalline catalytic material layer, a polymer electrolyte membrane, a metallic substrate disposed between the light sensitive nano-crystalline catalytic material layer and the polymer electrolyte membrane adjacent to the polymer electrolyte membrane layer, and at least one photovoltaic device connected in series to the light sensitive nano-crystalline material layer and disposed between the light sensitive nano-crystalline catalytic material layer and the metallic substrate layer.Type: GrantFiled: July 26, 2007Date of Patent: November 16, 2010Assignee: Gas Technology InstituteInventors: Qinbai Fan, William E. Liss
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Publication number: 20100255382Abstract: Provided is a secondary battery comprising a separator having an inorganic layer wherein active sites of inorganic particles in the inorganic layer are modified into non-reactive sites. Use of the separator leads to improvements in wettability of an electrolyte and thermoelectric stability and storage characteristics of the secondary battery. Provided is also a method of manufacturing the same secondary battery.Type: ApplicationFiled: November 21, 2008Publication date: October 7, 2010Applicant: LG CHEM, LTD.Inventors: Yo Jin Kim, Seung Don Choi, Han Ho Lee
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Publication number: 20100143805Abstract: This invention relates to overcharge protection and molecular redox shuttles in rechargeable lithium-ion cells. For this, specific nitroxyls or oxoammonium salts are used in the electrolyte. This invention also relates to a method of producing such lithium-ion cells and to a method of recharging such lithium-ion cells. This invention also pertains to some nitroxyls compounds and oxoammonium salts.Type: ApplicationFiled: February 29, 2008Publication date: June 10, 2010Applicant: CIBA CORPORATIONInventors: Tobias Hintermann, Peter Nesvadba, Markus Frey, Lucienne Bugnon Folger
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Publication number: 20100143797Abstract: A secondary lithium battery electrolyte including a lithium salt, a nonaqueous organic solvent, and an electrolyte additive represented by Formula 1: where n is an integer in the range of 1 to 4. A secondary lithium battery having excellent cycle and high temperature retention characteristics can be provided by using such secondary lithium battery electrolyte.Type: ApplicationFiled: September 15, 2009Publication date: June 10, 2010Applicant: Samsung SDI Co., LtdInventors: Seok-soo LEE, Young-gyoon RYU, Dong-Ioon LEE
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Publication number: 20100136426Abstract: A resistance-stabilizing additive to an electrolyte for a battery cell in an implantable medical device is presented. At least one resistance-stabilizing additive is selected from a group comprising an electron withdrawing group, an aromatic diacid salt, an inorganic salt, an aliphatic organic acid, an aromatic diacid, and an aromatic monoacid.Type: ApplicationFiled: January 7, 2010Publication date: June 3, 2010Applicant: Medtronic, Inc.Inventors: Donald R. Merritt, Craig L. Schmidt
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Publication number: 20100104948Abstract: Provided is an anode for use in electrochemical cells, wherein the anode active layer has a first layer comprising lithium metal and a multi-layer structure comprising single ion conducting layers and polymer layers in contact with the first layer comprising lithium metal or in contact with an intermediate protective layer, such as a temporary protective metal layer, on the surface of the lithium-containing first layer. Another aspect of the invention provides an anode active layer formed by the in-situ deposition of lithium vapor and a reactive gas. The anodes of the current invention are particularly useful in electrochemical cells comprising sulfur-containing cathode active materials, such as elemental sulfur.Type: ApplicationFiled: July 25, 2008Publication date: April 29, 2010Applicant: Sion Power CorporationInventors: Terje A. Skotheim, Christopher J. Sheehan, Yuriy V. Mikhaylik, John Affinito
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Publication number: 20100062346Abstract: A non-aqueous electrolyte usable in rechargeable lithium-ion batteries including a solution of LiPF6/carbonate based electrolytes with low concentrations of LiFOP such that the thermal stability is increased compared to a standard lithium battery. A method of making lithium tetrafluorophospahte (LiF4C2O4, LiFOP) including, reacting PF5 with lithium oxalate, recrystallizing DMC/dichloromethane from a 1:1 mixture of to separate LiF4OP from LiPF6 to form a lithium salt. An electric current producing rechargeable Li-ion cell. The rechargeable lithium ion cell includes an anode, a cathode, and a non-aqueous electrolyte comprising a solution of a lithium salt in a non-aqueous organic solvent containing lithium tetrafluorooxalatophosphate (LiPF4(C2O4), LiF4OP).Type: ApplicationFiled: September 3, 2009Publication date: March 11, 2010Applicant: BOARD OF GOVERNORS FOR HIGHER EDUCATION, STATE OF RHODE ISLAND AND PROVIDENCEInventors: Brett Lucht, Ang Xiao, Li Yang, Mengqing Xu
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Publication number: 20100038578Abstract: A quaternary ammonium salt of the formula (1), electrolytic solution and electrochemical device using the salt wherein R1 is straight-chain or branched alkyl having 1 to 4 carbon atoms, R2 is straight-chain or branched alkyl having 1 to 3 carbon atoms, and X? is N(CN)2?, SCN?, NO3?, NCO? or NO2?.Type: ApplicationFiled: January 12, 2006Publication date: February 18, 2010Inventors: Tetsuo Nishida, Kazutaka Hirano, Megumi Tomisaki, Akihiro Nabeshima, Yoshinobu Abe, Hiroaki Tokuda, Akinori Oka
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Publication number: 20100035147Abstract: A nonaqueous electrolytic solution that can provide a battery that is low in gas generation, has a large capacity, and is excellent in storage characteristics and cycle characteristics contains an electrolyte and a nonaqueous solvent dissolving the electrolyte and further contains 0.001 vol % or more and less than 1 vol % of a compound represented by Formula (1) in the nonaqueous solvent. Alternatively, the nonaqueous electrolytic solution contains 0.001 vol % or more and less than 5 vol % of a compound represented by Formula (1) in the nonaqueous solvent and further contains at least one compound selected from the group consisting of cyclic carbonate compounds having carbon-carbon unsaturated bonds, cyclic carbonate compounds having fluorine atoms, monofluorophosphates, and difluorophosphates. In Formula (1), R1 to R3 each independently represent an alkyl group of 1 to 12 carbon atoms, which may be substituted by a halogen atom; and n represents an integer of 0 to 6.Type: ApplicationFiled: March 17, 2008Publication date: February 11, 2010Applicant: MITSUBISHI CHEMICAL CORPORATIONInventors: Minoru Kotato, Shinichi Kinoshita
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Publication number: 20100028773Abstract: A composition for a battery containing an electroconductive assistant improves battery performance of a battery produced using this composition as a result of achieving dispersion stabilization without inhibiting electroconductivity of the electroconductive assistant.Type: ApplicationFiled: March 4, 2008Publication date: February 4, 2010Inventors: Naohisa Hirota, Tadashi Itabashi, Shinichiro Maki, Daisuke Nakasone