Copper Component Is Active Material Patents (Class 429/220)
  • Publication number: 20140272585
    Abstract: An electrode for an electrochemical energy store, including an active material layer having an active material, a protective layer being at least partially applied to the active material, and the protective layer at least partially including a fluorophosphate-based material. Such an electrode offers a particularly high stability, even when high voltages are present. Also described is a method for manufacturing an electrode, to an electrochemical energy store and to the use of a fluorophosphate-based material for generating a protective layer for an active material of an electrode of an electrochemical energy store.
    Type: Application
    Filed: March 14, 2014
    Publication date: September 18, 2014
    Applicant: Robert Bosch GmbH
    Inventor: Ingo KERKAMM
  • Publication number: 20140272555
    Abstract: A lithium ion battery cathode material, and an electrode prepared from such material, is described. The cathode material has a layered-spinel composite structure. The lithium ion battery operates at a high voltage (i.e. up to about 5 V) and has a desirably high cycling performance and rate capability.
    Type: Application
    Filed: March 15, 2013
    Publication date: September 18, 2014
    Inventors: MARK GERRIT ROELOFS, Jun J. Liu
  • Patent number: 8835051
    Abstract: Negative active materials for rechargeable lithium batteries are provided. One negative active material includes a metal matrix, and an intermetallic compound including a Si active metal and an additive metal dispersed in the metal matrix. The additive metal may be Ca, Mg, Na, K, Sr, Rb, Ba, Cs, or a combination thereof. The metal matrix may comprise Cu and Al. The negative active material may comprise a X(aM-bSi)—Y(cCu-dAl) material, where X is from about 30 to about 70 wt %, Y is from about 30 to about 70 wt %, X+Y is 100 wt %, a+b is 100 wt %, a is from about 20 to 80 wt %, b is from about 20 to 80 wt %, c+d is 100 wt %, c is from about 80 to about 95 wt %, d is from about 5 to about 20 wt %, and M may be Ca, Mg, Na, K, Sr, Rb, Ba, Cs, or a combination thereof.
    Type: Grant
    Filed: March 21, 2008
    Date of Patent: September 16, 2014
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Goo-Jin Jeong, Min-Sook Sung, Sang-Min Lee, Yong-Mook Kang, Wan-Uk Choi, Sung-Soo Kim
  • Patent number: 8835050
    Abstract: An anode substrate which enables achievement of a battery having a high output voltage and a high energy density, and being superior in charge and discharge cycle characteristics; a secondary cell in which the anode substrate is used; a resin composition for use in forming the anode substrate; and a method for producing the anode substrate are provided. According to anode substrate 10 including metal film 13 formed on support 11 provided with patterned organic film 12 molded by a thermal imprint process or a photoimprint process, a battery having a high output voltage and a high energy density, and being superior in charge and discharge cycle characteristics can be provided.
    Type: Grant
    Filed: November 10, 2008
    Date of Patent: September 16, 2014
    Assignees: Tokyo Ohka Kogyo Co., Ltd, Kanto Gakuin University Surface Engineering Research Institute
    Inventors: Koichi Misumi, Mitsuhiro Watanabe, Hideo Honma
  • Patent number: 8835053
    Abstract: Negative active materials and rechargeable lithium batteries including the negative active materials are provided. The negative active material includes an intermetallic compound of Si and a metal, and a metal matrix including Cu and Al. The negative active material may provide a rechargeable lithium battery having high capacity and excellent cycle-life and cell efficiency.
    Type: Grant
    Filed: March 18, 2008
    Date of Patent: September 16, 2014
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Min-Seok Sung, Goo-Jin Jeong, Yong-Mook Kang, Sang-Min Lee, Wan-Uk Choi, Sung-Soo Kim
  • Publication number: 20140255781
    Abstract: A method of forming a carbon coating includes heat treating lithium transition metal composite oxide Li0.9+aMbM?cNdOe, in an atmosphere of a gas mixture including carbon dioxide and compound CnH(2n+2?a)[OH]a, wherein n is 1 to 20 and a is 0 or 1, or compound CnH(2n), wherein n is 2 to 6, wherein 0?a?1.6, 0?b?2, 0?c?2, 0?d?2, b, c, and d are not simultaneously equal to 0, e ranges from 1 to 4, M and M? are different from each other and are selected from Ni, Co, Mn, Mo, Cu, Fe, Cr, Ge, Al, Mg, Zr, W, Ru, Rh, Pd, Os, Ir, Pt, Sc, Ti, V, Ga, Nb, Ag, Hf, Au, Cs, B, and Ba, and N is different from M and M? and is selected from Ni, Co, Mn, Mo, Cu, Fe, Cr, Ge, Al, Mg, Zr, W, Ru, Rh, Pd, Os, Ir, Pt, Sc, Ti, V, Ga, Nb, Ag, Hf, Au, Cs, B, Ba, and a combination thereof, or selected from Ti, V, Si, B, F, S, and P, and at least one of the M, M?, and N comprises Ni, Co, Mn, Mo, Cu, or Fe.
    Type: Application
    Filed: March 7, 2014
    Publication date: September 11, 2014
    Applicant: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: In Hyuk SON, Jun Young MUN, Jin-Hwan PARK, Chan Ho PAK, Seung Jae LEE, Hyo Rang KANG
  • Publication number: 20140248540
    Abstract: A process of electroless plating a tin or tin-alloy active material onto a metal substrate for the negative electrode of a rechargeable lithium battery comprising steps of (1) immersing the metal substrate in an aqueous plating solution containing metal ions to be plated, (2) plating tin or tin-alloy active material onto the metal substrate by contacting the metal substrate with a reducing metal by swiping one on the other, and (3) removing the plated metal substrate from the plating bath and rinsing with deionized water. A rechargeable lithium battery using tin or tin-alloy as the anode active material.
    Type: Application
    Filed: May 13, 2014
    Publication date: September 4, 2014
    Applicant: U.S. Government as represented by the Secretary of the Army
    Inventor: Shengshui ZHANG
  • Publication number: 20140242460
    Abstract: Disclosed are an anode active material for lithium secondary batteries and a method for manufacturing same, the anode active material comprising: a core part including a carbon-silicon complex and having a cavity therein; and a coated layer which is formed on the surface of the core part and includes a phosphor-based alloy.
    Type: Application
    Filed: May 1, 2014
    Publication date: August 28, 2014
    Applicant: LG Chem, Ltd.
    Inventors: Sang-Wook Woo, Je-Young Kim
  • Publication number: 20140242474
    Abstract: Disclosed is a high-capacity electrochemical energy storage device in which a conversion reaction proceeds as the oxidation-reduction reaction, and the separation (hysteresis) between the electrode potentials for oxidation and reduction is small. The electrochemical energy storage device includes a first electrode including a first active material, a second electrode including a second active material, and a non-aqueous electrolyte interposed between the first and second electrodes. At least one of the first and second active materials is a metal salt having a polyatomic anion and a metal ion, and the metal salt is capable of oxidation-reduction reaction involving reversible release and acceptance of the polyatomic anion.
    Type: Application
    Filed: March 11, 2013
    Publication date: August 28, 2014
    Applicant: PANASONIC CORPORATION
    Inventors: Tooru Matsui, Zempachi Ogumi, Toshiro Hirai, Akiyoshi Nakata
  • Publication number: 20140242463
    Abstract: The present invention provides a positive active material for a secondary lithium battery, a method of preparing the positive active material, and a secondary lithium battery including the positive active material, wherein the positive active material includes a lithium metal composite oxide core represented by the following Chemical Formula 1, and a coating layer including a fluorine compound and positioned at a shell of the lithium metal composite oxide core. LiwNixCoyMn1-x-y-zMzO2??[Chemical Formula 1] (1.2?w?1.5, 0<x<1, 0?y<1, 0.5?1-x-y-z, and M is at least one metal selected from the group consisting of Al, Mg, Fe, Cu, Zn, Cr, Ag, Ca, Na, K, In, Ga, Ge, V, Mo, Nb, Si, Ti, and Zr).
    Type: Application
    Filed: September 18, 2012
    Publication date: August 28, 2014
    Applicant: KOREA ELECTRONICS TECHNOLOGY INSTITUTE
    Inventors: Jun Ho Song, Young Jun Kim, Jeom-Soo Kim, Woo Suk Cho, Jae-Hun Kim, Jin Hwa Kim
  • Publication number: 20140234713
    Abstract: A novel hybrid lithium-ion anode material based on coaxially coated Si shells on vertically aligned carbon nanofiber (CNF) arrays. The unique cup-stacking graphitic microstructure makes the bare vertically aligned CNF array an effective Li+ intercalation medium. Highly reversible Li+ intercalation and extraction were observed at high power rates. More importantly, the highly conductive and mechanically stable CNF core optionally supports a coaxially coated amorphous Si shell which has much higher theoretical specific capacity by forming fully lithiated alloy. Addition of surface effect dominant sites in close proximity to the intercalation medium results in a hybrid device that includes advantages of both batteries and capacitors.
    Type: Application
    Filed: April 25, 2014
    Publication date: August 21, 2014
    Applicant: Catalyst Power Technologies
    Inventor: Ronald A. Rojeski
  • Publication number: 20140234711
    Abstract: A novel hybrid lithium-ion anode material based on coaxially coated Si shells on vertically aligned carbon nanofiber (CNF) arrays. The unique cup-stacking graphitic microstructure makes the bare vertically aligned CNF array an effective Li+ intercalation medium. Highly reversible Li+ intercalation and extraction were observed at high power rates. More importantly, the highly conductive and mechanically stable CNF core optionally supports a coaxially coated amorphous Si shell which has much higher theoretical specific capacity by forming fully lithiated alloy. Addition of surface effect dominant sites in close proximity to the intercalation medium results in a hybrid device that includes advantages of both batteries and capacitors.
    Type: Application
    Filed: April 25, 2014
    Publication date: August 21, 2014
    Applicant: Catalyst Power Technologies
    Inventor: Ronald A Rojeski
  • Publication number: 20140234714
    Abstract: A negative active material and a lithium battery are provided. The negative active material includes a composite core, and a coating layer formed on at least part of the composite core. The composite core includes a carbonaceous base and a metal/metalloid nanostructure disposed on the carbonaceous base. The coating layer includes a metal oxide coating layer and an amorphous carbonaceous coating layer.
    Type: Application
    Filed: December 19, 2013
    Publication date: August 21, 2014
    Applicant: Samsung SDI Co., Ltd.
    Inventors: Yu-Jeong Cho, Sang-Eun Park, So-Ra Lee, Su-Kyung Lee, Ui-Song Do, Chang-Su Shin, Jae-Myung Kim
  • Publication number: 20140234715
    Abstract: Battery systems using coated conversion materials as the active material in battery cathodes are provided herein. Protective coatings may be an oxide, phosphate, or fluoride, and may be lithiated. The coating may selectively isolate the conversion material from the electrolyte. Methods for fabricating batteries and battery systems with coated conversion material are also provided herein.
    Type: Application
    Filed: May 8, 2014
    Publication date: August 21, 2014
    Applicant: QuantumScape Corporation
    Inventors: Rainer Fasching, Joseph Han, Jon Shan, Ghyrn E. Loveness, Eric Tulsky, Timothy Holme
  • Publication number: 20140234712
    Abstract: A novel hybrid lithium-ion anode material based on coaxially coated Si shells on vertically aligned carbon nanofiber (CNF) arrays. The unique cup-stacking graphitic microstructure makes the bare vertically aligned CNF array an effective Li+ intercalation medium. Highly reversible Li+ intercalation and extraction were observed at high power rates. More importantly, the highly conductive and mechanically stable CNF core optionally supports a coaxially coated amorphous Si shell which has much higher theoretical specific capacity by forming fully lithiated alloy. Addition of surface effect dominant sites in close proximity to the intercalation medium results in a hybrid device that includes advantages of both batteries and capacitors.
    Type: Application
    Filed: April 25, 2014
    Publication date: August 21, 2014
    Applicant: Catalyst Power Technologies
    Inventor: Ronald A Rojeski
  • Publication number: 20140234710
    Abstract: A negative active material includes a conductive unit bound in island-like form to silicon-based nanowires on a carbonaceous base. Such negative active material may improve the electrical conductivity of the silicon-based nanowires, and suppress separation of the silicon-based nanowires caused from volume expansion, and thus may improve lifetime characteristics of a lithium battery.
    Type: Application
    Filed: January 9, 2014
    Publication date: August 21, 2014
    Applicant: SAMSUNG SDI CO., LTD.
    Inventors: Su-Kyung Lee, So-Ra Lee, Kyu-Nam Joo, Yu-Jeong Cho, Ui-Song Do, Chang-Su Shin, Ha-Na Yoo, Sang-Eun Park, Jae-Myung Kim
  • Publication number: 20140227596
    Abstract: A cathode material for a lithium ion secondary battery includes an oxide represented by a composition formula Li2-xMIIyM(Si,MB)O4, wherein MII represents a divalent element; M represents at least one element selected from the group consisting of Fe, Mn, Co and Ni; and MB represents, as an optional component, an element substituted for Si to compensate for a difference between an electric charge of [Li2]2+ and an electric change of [Li2-xMIIy]n+ as needed. In the composition formula representing the oxide, x and y are ?0.25<x?0.25 and 0<y?0.25.
    Type: Application
    Filed: September 14, 2012
    Publication date: August 14, 2014
    Applicant: Shoei Chemical Inc.
    Inventors: Hirokazu Sasaki, Atsushi Nemoto, Masahiko Miyahara
  • Publication number: 20140227594
    Abstract: Disclosed are a precursor of a positive active material for a rechargeable lithium battery and a preparation method thereof, and a positive active material and a rechargeable lithium battery including the same, and specifically a precursor for a rechargeable lithium battery is represented by the following Chemical Formula 1, wherein a manganese ion concentration deviation in the precursor is within 3 wt %. NixCoyMn1-x-y-zMz(OH)2??[Chemical Formula 1] (0<x<1, 0?y<1, 0.5?1?x?y?z, 0?z<1, and M is at least one kind of metal selected from the group consisting of Al, Mg, Fe, Cu, Zn, Cr, Ag, Ca, Na, K, In, Ga, Ge, V, Mo, Nb, Si, Ti, and Zr.
    Type: Application
    Filed: September 24, 2012
    Publication date: August 14, 2014
    Applicant: KOREA ELECTRONICS TECHNOLOGY INSTITUTE
    Inventors: Jun Ho Song, Young Jun Kim, Jae-Hun Kim
  • Publication number: 20140227595
    Abstract: The specification relates to a composite particle for storing lithium. The composite particle is used in an electrochemical cell. The composite particle includes a metal oxide on the surface of the composite particle, a major dimension that is approximately less than or equal to 40 microns and a formula of MM?Z, wherein M is from the group of Si and Sn, M? is from a group of Mn, Mg, Al, Mo, Bronze, Be, Ti, Cu, Ce, Li, Fe, Ni, Zn, Co, Zr, K, and Na, and Z is from the group of O, Cl, P, C, S, H, and F.
    Type: Application
    Filed: February 14, 2013
    Publication date: August 14, 2014
    Inventor: Shailesh Upreti
  • Patent number: 8802293
    Abstract: A positive-electrode material includes lithium vanadium phosphate particles having an average primary particle diameter from 0.3 ?m to 2.6 ?m and crystallite sizes from 24 nm to 33 nm. The lithium vanadium phosphate particles are coated with a conductive carbon of a range of 0.5 mass % to 2.4 mass % with respect to a total lithium vanadium phosphate particles.
    Type: Grant
    Filed: September 7, 2012
    Date of Patent: August 12, 2014
    Assignees: Fuji Jukogyo Kabushiki Kaisha, Nippon Chemical Industrial Co., Ltd.
    Inventors: Kazuki Takimoto, Hideo Yanagita, Tsutomu Kikuchi
  • Publication number: 20140220392
    Abstract: A system and method producing electrodes in an aqueous electrolyte battery that maximizes energy storage, reduces electrochemical decomposition of the electrolyte, and uses Prussian Blue analogue materials for both electrodes, with an anode electrode including an electrochemically active hexacyanometalate group having two possible redox reactions of different potentials. These potentials may be tuned by substituting different electrochemically inactive components.
    Type: Application
    Filed: May 29, 2013
    Publication date: August 7, 2014
    Applicant: ALVEO ENERGY, INC.
    Inventors: Colin Deane Wessells, Robert Alan Huggins
  • Patent number: 8795885
    Abstract: A lithium-ion battery having an anode including an array of nanowires electrochemically coated with a polymer electrolyte, and surrounded by a cathode matrix, forming thereby interpenetrating electrodes, wherein the diffusion length of the Li+ ions is significantly decreased, leading to faster charging/discharging, greater reversibility, and longer battery lifetime, is described. The battery design is applicable to a variety of battery materials. Methods for directly electrodepositing Cu2Sb from aqueous solutions at room temperature using citric acid as a complexing agent to form an array of nanowires for the anode, are also described. Conformal coating of poly-[Zn(4-vinyl-4?methyl-2,2?-bipyridine)3](PF6)2 by electroreductive polymerization onto films and high-aspect ratio nanowire arrays for a solid-state electrolyte is also described, as is reductive electropolymerization of a variety of vinyl monomers, such as those containing the acrylate functional group.
    Type: Grant
    Filed: February 23, 2009
    Date of Patent: August 5, 2014
    Assignee: Colorado State University Research Foundation
    Inventors: Amy L. Prieto, James M. Mosby, Timothy S. Arthur
  • Publication number: 20140212736
    Abstract: In some examples, a primary battery comprising a cathode comprising at least one active material and at least one of a metal oxide and metal fluoride, wherein the active material exhibits a first discharge capacity and the at least one of metal oxide and metal fluoride exhibits a second discharge capacity at a voltage lower than the first discharge capacity; an anode comprising a metal as an electron source; and an electrolyte between the cathode and anode. The metal reacts with the electrolyte below a third discharge capacity at a voltage lower than the second discharge capacity to form a gas, where the metal reacts with the active material at the first discharge capacity, and, following the consumption of the active material of the cathode, the metal reacts with the at least one of metal oxide and metal fluoride of the cathode prior to reacting with the electrolyte below the third discharge capacity.
    Type: Application
    Filed: January 31, 2013
    Publication date: July 31, 2014
    Applicant: Medtronic, Inc.
    Inventor: Kaimin Chen
  • Publication number: 20140212755
    Abstract: An as-prepared cathode for a secondary battery, the cathode including an alkaline source material including an alkali metal oxide, an alkali metal sulfide, an alkali metal salt, or a combination of any two or more thereof.
    Type: Application
    Filed: January 29, 2013
    Publication date: July 31, 2014
    Applicant: UChicago Argonne, LLC
    Inventors: Huiming Wu, Khalil Amine, Ali Abouimrane
  • Publication number: 20140212735
    Abstract: A system and method of forming a thin film battery includes a substrate, a first current collector formed on the substrate, a cathode layer formed on a portion of the first current collector, a solid layer of electrolyte material formed on the cathode layer, a silicon-metal thin film anode layer formed on the solid layer of electrolyte material and a second current collector electrically coupled to the silicon-metal thin film anode layer. A method and a system for forming the thin film battery are also disclosed.
    Type: Application
    Filed: January 25, 2013
    Publication date: July 31, 2014
    Inventors: Wenming Li, Byunghoon Yoon, Ann Koo
  • Publication number: 20140212694
    Abstract: A composite anode active material, an anode including the composite anode active material, a lithium battery including the anode, and a method of preparing the composite anode active material, the composite anode active material including a core including a ternary alloy, the ternary alloy being capable of intercalating and deintercalating lithium; and a carbonaceous coating layer on the core.
    Type: Application
    Filed: December 16, 2013
    Publication date: July 31, 2014
    Applicant: SAMSUNG SDI CO., LTD.
    Inventors: Yo-Han PARK, Young-Ugk KIM, Seung-Uk KWON, Jae-Hyuk KIM, Soon-Sung SUH, Yury MATULEVICH, Duk-Hyoung YOON, Hee-Young CHU, Chang-Ui JEONG
  • Publication number: 20140209832
    Abstract: A positive electrode active material for a non-aqueous secondary battery having high capacity and high rate characteristics is intended to be provided. Further, a positive electrode for a non-aqueous secondary battery and a non-aqueous secondary battery are intended to be provided by using the positive electrode active material. The positive electrode active material for the non-aqueous secondary battery contains a lithium composite oxide having an olivine structure represented by the chemical formula: Li1+AMnXM1?X(PO4)1+B in which A>0, B>0, M represents a metal element, M in the chemical formula is one or more metal elements selected from Fe, Ni, Co, Ti, Cu, Zn, Mg, V, and Zr, the ratio A/B in the chemical formula is within a range of: 2<A/B?7, and the value of X is within a range of: 0.3?X<1.
    Type: Application
    Filed: January 29, 2014
    Publication date: July 31, 2014
    Applicant: Hitachi Metals, Ltd.
    Inventors: Takashi NAKABAYASHI, Shin TAKAHASHI, Kan KITAGAWA, Toyotaka YUASA, Shuichi TAKANO, Mitsuru KOBAYASHI
  • Patent number: 8790829
    Abstract: The present invention provides a nonaqueous secondary battery with a high capacity, an excellent level of safety, and excellent charge-discharge cycle characteristics. The negative electrode contains, as negative electrode active materials, a graphite carbon material and a material containing Si as a constituent element, and the positive electrode includes, as a positive electrode active material, a lithium-containing composite oxide represented by the following general composition formula (1) and containing sulfur in a range of 0.01 mass % to 0.5 mass %: Li1+yMO2??(1) where y satisfies ?0.3?y<0.3, M represents a group of five or more elements including Ni, Co, Mn, Mg and at least one of Al, Ba, Sr, Ti and Zr, and when a, b, c and d represent Ni, Co, Mn, and Mg, respectively, in mol % and e represents a total of Al, Ba, Sr, Ti and Zr in mol % of all of the elements making up M, a, b, c, d, and e satisfy 70?a?97, 0.5<b<30, 0.5<c<30, 0.5<d<30, ?10<c?d<10, ?8?(c?d)/d?8, and e<10.
    Type: Grant
    Filed: September 8, 2011
    Date of Patent: July 29, 2014
    Assignee: Hitachi Maxell, Ltd.
    Inventors: Satoshi Kono, Masayuki Yamada, Akira Inaba, Kazutaka Matsuo
  • Patent number: 8790827
    Abstract: A positive electrode active material includes: a secondary particle obtained upon aggregation of a primary particle that is a lithium complex oxide particle in which at least nickel (Ni) and cobalt (Co) are solid-solved as transition metals, wherein an average composition of the whole of the secondary particle is represented by the following formula (1): LixCoyNizM1-y-zOb-aXa ??Formula (1) wherein an existent amount of cobalt (Co) becomes large from a center of the primary particle toward the surface thereof; and an existent amount of cobalt (Co) in the primary particle existing in the vicinity of the surface of the secondary particle is larger than an existent amount of cobalt (Co) in the primary particle existing in the vicinity of the center of the secondary particle.
    Type: Grant
    Filed: June 10, 2011
    Date of Patent: July 29, 2014
    Assignee: Sony Corporation
    Inventors: Asuki Yanagihara, Tomoyo Ooyama, Yoshihiro Kudo, Guohua Li
  • Publication number: 20140199597
    Abstract: The present disclosure provides an embodiment of an integrated structure that includes a first electrode of a first conductive material embedded in a first semiconductor substrate; a second electrode of a second conductive material embedded in a second semiconductor substrate; and a electrolyte disposed between the first and second electrodes. The first and second semiconductor substrates are bonded together through bonding pads such that the first and second electrodes are enclosed between the first and second semiconductor substrates. The second conductive material is different from the first conductive material.
    Type: Application
    Filed: January 15, 2013
    Publication date: July 17, 2014
    Applicant: Taiwan Semiconductor Manufacturing Company, Ltd.
    Inventors: Chyi-Tsong Ni, I-Shi Wang, Yi Hsun Chiu, Ching-Hou Sue
  • Publication number: 20140193711
    Abstract: Embodiments of the present disclosure pertain to methods of preparing porous silicon particulates by: (a) electrochemically etching a silicon substrate, where electrochemical etching comprises exposure of the silicon substrate to an electric current density, and where electrochemical etching produces a porous silicon film over the silicon substrate; (b) separating the porous silicon film from the silicon substrate, where the separating comprises a gradual increase of the electric current density in sequential increments; (c) repeating steps (a) and (b) a plurality of times; (d) electrochemically etching the silicon substrate in accordance with step (a) to produce a porous silicon film over the silicon substrate; (e) chemically etching the porous silicon film and the silicon substrate; and (f) splitting the porous silicon film and the silicon substrate to form porous silicon particulates.
    Type: Application
    Filed: January 7, 2014
    Publication date: July 10, 2014
    Applicants: Lockheed Martin Corporation, William Marsh Rice University
    Inventors: Sibani Lisa Biswal, Michael S. Wong, Madhuri Thakur, Steven L. Sinsabaugh
  • Publication number: 20140193714
    Abstract: A cathode active material including a lithium metal oxide composite having a first domain and a second domain and represented by Formula 1: x[Li2-y(M1)1-z(M2)y+zO3]-(1?x)[LiMeO2]??Formula 1 wherein 0<x<1, 0?y<1, 0?z<1, 0<y+z<1, M1 includes at least one transition metal, M2 includes at least one metal selected from magnesium (Mg), aluminum (Al), vanadium (V), zinc (Zn), molybdenum (Mo), niobium (Nb), lanthanum (La), and ruthenium (Ru), and Me includes at least one metal selected from nickel (Ni), cobalt (Co), manganese (Mn), iron (Fe), chromium (Cr), titanium (Ti), copper (Cu), aluminum (Al), magnesium (Mg), zirconium (Zr), and boron (B).
    Type: Application
    Filed: July 30, 2013
    Publication date: July 10, 2014
    Applicants: Samsung Fine Chemicals Co., Ltd., Samsung SDI Co., Ltd.
    Inventors: Myung-hoon KIM, Jae-gu YOON, Min-sik PARK, Jin-hwan PARK
  • Patent number: 8771875
    Abstract: A substance includes an oxide including at least one element selected from the group including cobalt Co, nickel Ni, manganese Mn, iron Fe, and copper Cu; and silicon Si chemically bonded to the surface of the oxide. Also, a battery includes a cathode, an anode, and an electrolyte, wherein the cathode includes an oxide including at least one selected from the group including cobalt Co, nickel Ni, manganese Mn, iron Fe, and copper Cu; and a substance including silicon Si chemically bonded to the surface of the oxide.
    Type: Grant
    Filed: August 28, 2008
    Date of Patent: July 8, 2014
    Assignee: Sony Corporation
    Inventors: Yoshinori Gamoh, Hiroshi Imoto
  • Publication number: 20140186707
    Abstract: A method is provided for fabricating a battery using an anode preloaded with consumable metals. The method forms an ion-permeable membrane immersed in an electrolyte. A preloaded anode is immersed in the electrolyte, comprising MeaX, where X is a material such as carbon, metal capable of being alloyed with Me, intercalation oxides, electrochemically active organic compounds, and combinations of the above-listed materials. Me is a metal such as alkali metals, alkaline earth metals, and combinations of the above-listed metals. A cathode is also immersed in the electrolyte and separated from the preloaded anode by the ion-permeable membrane. The cathode comprises M1YM2Z(CN)N.MH2O. After a plurality of initial charge and discharge operations are preformed, an anode is formed comprising MebX overlying the current collector in a battery discharge state, where 0?b<a.
    Type: Application
    Filed: March 6, 2014
    Publication date: July 3, 2014
    Applicant: Sharp Laboratories of America, Inc.
    Inventors: Yuhao Lu, Long Wang, Jong-Jan Lee
  • Publication number: 20140186706
    Abstract: A method is presented for fabricating an anode preloaded with consumable metals. The method provides a material (X), which may be one of the following materials: carbon, metals able to be electrochemically alloyed with a metal (Me), intercalation oxides, electrochemically active organic compounds, and combinations of the above-listed materials. The method loads the metal (Me) into the material (X). Typically, Me is an alkali metal, alkaline earth metal, or a combination of the two. As a result, the method forms a preloaded anode comprising Me/X for use in a battery comprising a M1YM2Z(CN)N·MH2O cathode, where M1 and M2 are transition metals. The method loads the metal (Me) into the material (X) using physical (mechanical) mixing, a chemical reaction, or an electrochemical reaction. Also provided is preloaded anode, preloaded with consumable metals.
    Type: Application
    Filed: March 6, 2014
    Publication date: July 3, 2014
    Applicant: Sharp Laboratories of America, Inc.
    Inventors: Long Wang, Yuhao Lu, Jong-Jan Lee
  • Publication number: 20140178759
    Abstract: A composition comprising at least one graphene-supported metal oxide monolith, said monolith comprising a three-dimensional structure of graphene sheets crosslinked by covalent carbon bonds, wherein the graphene sheets are coated by at least one metal oxide such as iron oxide or titanium oxide. Also provided is an electrode comprising the aforementioned graphene-supported metal oxide monolith, wherein the electrode can be substantially free of any carbon-black and substantially free of any binder.
    Type: Application
    Filed: March 15, 2013
    Publication date: June 26, 2014
    Applicant: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
    Inventor: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
  • Publication number: 20140178758
    Abstract: Disclosed is a device for producing an electric current and a method for making the same. The device for producing an electric current, comprising: an anode comprising a stack formed by alternately stacking of at least one Si layer and at least one carbon material layer, and a LiPON layer on the stack; a cathode; and an electrolyte between the anode and the cathode.
    Type: Application
    Filed: December 24, 2012
    Publication date: June 26, 2014
    Applicant: EPISTAR CORPORATION
    Inventors: Chih-Jung CHEN, Shu-Fen HU, Ru-Shi LIU, Tai-Feng HUNG
  • Publication number: 20140178749
    Abstract: In an aspect, a positive active material for a rechargeable lithium battery that includes a first positive active material; and a second positive active material including LiaMn1-xMxO2 (M is selected from Co, Ni, Mn, Fe. Cu, V, Si, Al, Sn, Pb, Sn, Ti, Sr, Mg, Ca or a combination thereof; x is 0?x?1.0; and a is 0.9?a?1.1) is disclosed.
    Type: Application
    Filed: July 23, 2013
    Publication date: June 26, 2014
    Applicant: SAMSUNG SDI CO., LTD.
    Inventors: Jung-Woo AN, Sumihito ISHIDA
  • Publication number: 20140170481
    Abstract: It is an object of this exemplary embodiment to provide a lithium ion battery using a lithium manganese complex oxide, in which the dissolution of manganese and resistance increase are inhibited, and which is excellent in life characteristics at high temperature. One aspect of this exemplary embodiment is a lithium ion battery comprising at least a positive electrode comprising a positive electrode active material, and an electrolytic solution, wherein the positive electrode active material is a lithium manganese complex oxide, the positive electrode comprises a bismuth oxide, and a metal compound attached to part of a surface of the lithium manganese complex oxide, and a dissolution rate of a metal of the metal compound in the electrolytic solution is lower than a dissolution rate of manganese of the lithium manganese complex oxide.
    Type: Application
    Filed: June 13, 2012
    Publication date: June 19, 2014
    Inventor: Akinobu Nakamura
  • Publication number: 20140170491
    Abstract: A composition is provided that includes mesoporous carbon domains. Each of the mesoporous carbon domains is incorporated with particles of metal or metal oxide in an amount of from 40 to 85 total weight percent of the composition. The metal or metal oxide particles can include tin, cobalt, copper, molybdenum, nickel, iron, or ruthenium, or an oxide thereof. The resulting composition when combined with a binder from a battery electrode. Such a battery electrode operating as an anode in a lithium ion battery has specific capacities of more than 1000 miliAmperes-hour per gram after 15 of the galvanostatic cycles.
    Type: Application
    Filed: December 19, 2012
    Publication date: June 19, 2014
    Applicant: Toyota Motor Engineering & Manufacturing North America, Inc.
    Inventors: Jiajun Chen, Kazuhisa Yano
  • Publication number: 20140170493
    Abstract: The disclosure is related to battery systems. More specifically, embodiments of the disclosure provide a nanostructured conversion material for use as the active material in battery cathodes. In an implementation, a nanostructured conversion material is a glassy material and includes a metal material, one or more oxidizing species, and a reducing cation species mixed at a scale of less than 1 nm. The glassy conversion material is substantially homogeneous within a volume of 1000nm3.
    Type: Application
    Filed: June 19, 2013
    Publication date: June 19, 2014
    Inventors: Timothy Holme, Jagdeep Singh, Rainer Fasching, Joseph Han, Weston Arthur Hermann, Cheng Chieh Chao, Bradley O. Stimson, Karl Brown
  • Publication number: 20140170492
    Abstract: Provided is a positive electrode material for a lithium battery with an atomic ratio expressed by the formula (I) Lia(MxMn2-x)(O4-yZy) for 0.8?a?1.2, 0?x?1 and 0?y?1 in which M is one or more of Li, Na, K, Ca, Mg, Al, Ti, Sc, Ge, V, Cr, Zr, Co, Ni, Zn, Cu, La, Ce, Mn, Hf, Nb, Ta, Mo, W, Ru, Ag, Sn, Pb and Si and Z is one or more of OH, halogens, N, P, S and O, and the primary particles of the positive electrode material have a spheroidal topography. The adjacent (111) family planes of the primary particles are connected by curved surfaces without obvious edges. A preparing method of a positive electrode material for a lithium battery and a lithium battery are also provided. The positive electrode material of the present invention provides a good high-temperature cycling performance and filling capability.
    Type: Application
    Filed: May 23, 2011
    Publication date: June 19, 2014
    Inventors: Yonggao Xia, Zhaoping Liu, Yaletu Saixi
  • Publication number: 20140162124
    Abstract: A cathode active material capable of increasing a capacity and improving high temperature characteristics or cycle characteristics, a method of manufacturing it, a cathode using the cathode active material, and a battery using the cathode active material are provided. In a cathode active material contained in a cathode, a coating layer is provided on at least part of complex oxide particle containing at least lithium (Li) and cobalt (Co). The coating layer is an oxide which contains lithium (Li) and at least one of nickel (Ni) and manganese (Mn).
    Type: Application
    Filed: February 14, 2014
    Publication date: June 12, 2014
    Applicant: Sony Corporation
    Inventors: Haruo Watanabe, Kenji Ogisu, Koji Morita, Masanori Soma, Yosuke Hosoya, Hideto Azuma, Tomoyo Ooyama
  • Publication number: 20140162125
    Abstract: The current disclosure relates to an anode material with the general formula MySb-M?Ox—C, where M and M? are metals and M?Ox—C forms a matrix containing MySb. It also relates to an anode material with the general formula MySn-M?Cx—C, where M and M? are metals and M?Cx—C forms a matrix containing MySn. It further relates to an anode material with the general formula Mo3Sb7-C, where —C forms a matrix containing Mo3Sb7. The disclosure also relates to an anode material with the general formula MySb-M?Cx—C, where M and M? are metals and M?Cx—C forms a matrix containing MySb. Other embodiments of this disclosure relate to anodes or rechargeable batteries containing these materials as well as methods of making these materials using ball-milling techniques and furnace heating.
    Type: Application
    Filed: February 18, 2014
    Publication date: June 12, 2014
    Inventors: Arumugam Manthiram, Danielle Applestone, Sukeun Yoon
  • Patent number: 8748041
    Abstract: Disclosed is a positive electrode active material that provides an improved capacity density. Specifically disclosed is a positive electrode active material for a lithium ion battery with a layered structure represented by Lix(NiyM1-y)Oz (wherein M represents at least one element selected from a group consisting of Mn, Co, Mg, Al, Ti, Cr, Fe, Cu, and Zr; x is in the range from 0.9 to 1.2; y is in the range from 0.3 to 0.95; and z is in the range from 1.8 to 2.4), wherein, when a value obtained by dividing an average of peak intensities observed between 1420 and 1450 cm?1 and between 1470 and 1500 cm?1 by the maximum intensity of a peak appearing between 520 and 620 cm?1 in an infrared absorption spectrum obtained by FT-IR is represented by A, A satisfies the following relational formula: 0.20y?0.05?A?0.53y?0.06.
    Type: Grant
    Filed: March 3, 2010
    Date of Patent: June 10, 2014
    Assignee: JX Nippon Mining & Metals Corporation
    Inventors: Hirohito Satoh, Yoshio Kajiya, Ryuichi Nagase
  • Publication number: 20140154575
    Abstract: A method is provided for fabricating a cyanometallate cathode battery. The method provides a cathode of AXM1YM2Z(CN)N.MH2O, where “A” is selected from a first group of metals, and where M1 and M2 are transition metals. The method provides an anode and a metal ion-permeable membrane separating the anode from the cathode. A third electrode is also provided including “B” metal ions selected from the first group of metals. Typically, the first group of metals includes alkali and alkaline metals. The method intercalates “B” metal ions from the third electrode to the anode, the cathode, or both the anode and cathode to form a completely fabricated battery. In one aspect, a solid electrolyte interface (SEI) layer including the “B” metal ions overlies a surface of the anode, the cathode, or both the anode and cathode. A cyanometallate cathode battery is also provided.
    Type: Application
    Filed: February 6, 2014
    Publication date: June 5, 2014
    Applicant: Sharp Laboratories of America, Inc.
    Inventors: Yuhao Lu, Long Wang, Jong-Jan Lee
  • Patent number: 8741455
    Abstract: A secondary hybrid aqueous energy storage device includes an anode electrode, a cathode electrode which is capable of reversibly intercalating sodium cations, a separator, and a sodium cation containing aqueous electrolyte, wherein an initial active cathode electrode material comprises an alkali metal containing active cathode electrode material which deintercalates alkali metal ions during initial charging of the device.
    Type: Grant
    Filed: August 29, 2011
    Date of Patent: June 3, 2014
    Assignee: Carnegie Mellon University
    Inventor: Jay Whitacre
  • Publication number: 20140141331
    Abstract: The present invention relates to a cathode active material for a lithium secondary battery, a method for preparing the same, and a lithium secondary battery including the same. Provided is a cathode active material composed of a lithium-excess lithium metal composite compound including Li2MnO3 having a layered structure, and doped with a fluoro compound, wherein an FWHM (half value width) value is within a range from 0.164 degree to 0.185 degree.
    Type: Application
    Filed: November 19, 2013
    Publication date: May 22, 2014
    Applicant: SAMSUNG FINE CHEMICALS CO., LTD
    Inventors: Misun Lee, Jongseok Moon, Taehyeon Kim, Shin Jung Choi
  • Patent number: 8722248
    Abstract: The present invention relates to an active element for a battery whose material contains copper oxyphosphate and an additive improving the conductivity. The proportion of the additive improving the conductivity in the material is between 3 and 7 wt. %, preferably between approximately 3 wt. % and approximately 5 wt. %, and the proportion of the copper oxyphosphate in the material adds up to 100 wt. %. The invention additionally relates to a battery having an active element of this type as well as a method for producing an active element of this type and a battery of this type. The battery according to the invention is suitable in particular for use in medical implants.
    Type: Grant
    Filed: August 26, 2008
    Date of Patent: May 13, 2014
    Assignee: Biotronik CRM Patent AG
    Inventors: Juergen Drews, Tim Traulsen, Gerd Fehrmann, Thomas Hucke, Roland Staub
  • Publication number: 20140127573
    Abstract: A particulate composite of silicon, tin, and aluminum (or other suitable metal) is prepared as a negative electrode composition with increased lithium insertion capacity and durability for use with a metal current collector in cells of a lithium-ion battery or a lithium-sulfur battery. This electrode material is formed such that the silicon is present as a distinct amorphous phase in separate matrix phases of crystalline tin and crystalline aluminum. While the distinct tin and aluminum phases provide electron conductivity, each phase accommodates the insertion and extraction of lithium in the operation of the cell and all phases interact in minimizing mechanical damage to the material as the cell experiences repeated charge and discharge cycles. Other suitable metals for use in the composite with silicon and tin include copper and titanium.
    Type: Application
    Filed: January 10, 2014
    Publication date: May 8, 2014
    Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventor: Xingcheng Xiao