Abstract: A lithium secondary battery includes a cathode formed from a cathode active material including a first cathode active material particle and a second cathode active material particle, an anode and a separator interposed between the cathode and the anode. The first cathode active material particle includes a lithium metal oxide including a continuous concentration gradient in at least one region between a central portion and a surface portion. The second cathode active material particle includes a lithium metal oxide including elements the same as those of the first cathode active material particle, and the second cathode active material particle has a uniform composition from a central portion to a surface.

Abstract: A positive electrode for an all-solid secondary battery including a sulfide-based solid electrolyte includes a first positive active material having an average particle diameter of about 15 ?m to about 20 ?m, a second positive active material having an average particle diameter of about 2 ?m to about 6 ?m, and a solid electrolyte, wherein at least one selected from the first positive active material and the second positive active material includes a coating layer including a lithium ion conductor, and each of the first positive active material and the second positive active material includes a core and a shell, wherein the shell includes a nickel-based active material containing cobalt. An all-solid secondary battery includes the positive electrode.

Abstract: Provided are: a positive electrode for solid-state batteries, which enables the achievement of high energy density, rate characteristics and durability; a solid-state battery; and a method for producing a solid-state battery. A positive electrode for solid-state batteries, which is provided with a collector and a positive electrode active material layer that contains a positive electrode active material, and which is configured such that: the ratio of the positive electrode active material, which is composed of primary particles, in the positive electrode active material layer is 60% by mass or more; the void fraction in the positive electrode active material layer is less than 20% by volume; and portions of the positive electrode active material layer other than the positive electrode active material, which is composed of primary particles, contain a solid electrolyte.

Abstract: An electrode material for a lithium ion secondary battery and method of forming the same, the electrode material including composite particles, each composite particle including a primary particle including thermally disproportionated silicon oxide, and an envelope disposed on the surface of the primary particle. The envelope includes turbostratic carbon having a Raman spectrum having: a D band having a peak intensity (ID) at wave number between 1330 cm?1 and 1360 cm?1; a G band having a peak intensity (IG) at wave number between 1530 cm?1 and 1600 cm?1; and a 2D band having a peak intensity (I2D) at wave number between 2650 cm?1 and 2750 cm?1, wherein a ratio of ID/IG ranges from greater than zero to about 1.0, and a ratio of I2D/IG ranges from about 0.4 to about 2.

Abstract: The present invention provides an electrolyte solution for a non-aqueous electrolyte solution battery capable of exhibiting excellent high-temperature cycle characteristics and excellent high-temperature storage characteristics at high temperature of 60° C. or above, and a non-aqueous electrolyte solution battery using the same. The electrolyte solution for a non-aqueous electrolyte solution battery of the present invention comprises at least: a non-aqueous solvent; a solute; at least one first compound represented by the following general formula (1); and at least one second compound represented by the following general formula (2).

Abstract: An aspect of the present invention achieves a nonaqueous electrolyte secondary battery laminated separator which has excellent heat resistance and exhibits an excellent initial battery characteristic when used in a nonaqueous electrolyte secondary battery. A nonaqueous electrolyte secondary battery laminated separator in accordance with an aspect of the present invention includes: a polyolefin porous film; and a porous layer which (i) is disposed on at least one surface of the polyolefin porous film and (ii) includes a heat resistant filler, the porous layer having a surface which has cracks, a ratio of a total area of the cracks to a surface area of the porous layer being 0.15% to 10%.

Abstract: An electrode material for a lithium ion secondary battery and method of forming the same, the electrode material including composite particles, each composite particle including: a primary particle including an electrochemically active material; and an envelope disposed on the surface of the primary particle. The envelope includes turbostratic carbon having a Raman spectrum having: a D band having a peak intensity (ID) at wave number between 1330 cm?1 and 1360 cm?1; a G band having a peak intensity (IG) at wave number between 1530 cm?1 and 1580 cm?1; and a 2D band having a peak intensity (I2D) at wave number between 2650 cm?1 and 2750 cm?1. In one embodiment, a ratio of ID/IG ranges from greater than zero to about 1.1, and a ratio of I2D/IG ranges from about 0.4 to about 2.

Abstract: The present disclosure relates to an anode active material for a lithium secondary battery, a method of manufacturing the anode active material, and a lithium secondary battery including the anode active material. The anode active material includes natural graphite particles configured such that flaky natural graphite fragment particles having uneven (??) surface defects are structured in a cabbage shape or at random and granulated, the surface and the inside of the natural graphite particles including a gap formed between the flaky natural graphite fragment particles, and a coating layer including amorphous or semicrystalline carbon formed on the surface of the flaky natural graphite fragment particles that form the gap and the surface of the natural graphite particles.

Abstract: A nickel-based active material precursor includes a particulate structure including a core portion, an intermediate layer portion on the core portion, and a shell portion on the intermediate layer portion, wherein the intermediate layer portion and the shell portion include primary particles radially arranged on the core portion, and each of the core portion and the intermediate layer portion includes a cation or anion different from that of the shell portion. The cation includes at least one selected from boron (B), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), titanium (Ti), vanadium (V), tungsten (W), chromium (Cr), iron (Fe), copper (Cu), zirconium (Zr), and aluminium (Al), and the anion includes at least one selected from phosphate (PO4), BO2, B4O7, B3O5, and F.

Abstract: There are provided a method capable of producing a large amount of a carbonaceous material for a negative electrode of a non-aqueous electrolyte secondary battery from a carbon precursor impregnated with an alkali metal element or an alkali metal compound, and an apparatus for performing such production. The method for producing a carbonaceous material for a negative electrode of a non-aqueous electrolyte secondary battery includes a heat treatment step of feeding a carbon precursor containing an elemental alkali metal and/or an alkali metal compound, heating the carbon precursor in a temperature range from 1000° C. to 1500° C. in a non-oxidizing gas atmosphere to produce a carbonaceous material, and discharging the carbonaceous material; and an exhaust gas treatment step of contacting a non-oxidizing exhaust gas containing a gas and a flying carbonaceous matter evolved in the heat treatment step with water or an aqueous solution to treat the exhaust gas.

Abstract: Methods for fabricating electrodes include coating a current collector with a slurry to form a coated current collector. The slurry includes a dry fraction, including silicon particles, polymeric binders, and one or more types of naturally occurring carbonaceous filaments, and one or more solvents. The coated current collector is heat treated to produce the electrode having a layer of silicon-based host material. The one or more naturally occurring carbonaceous filaments can include animal fibers, chitin, alginate, cellulose, keratin, and chitosan, and can have an average length of 1 ?m to 50 ?m and an average diameter of 1 nm to 500 nm. The dry fraction can include 5 wt. % to 95 wt. % silicon particles, 0.1 wt. % to 15 wt. % polymeric binders, and 1 wt. % to 20 wt. % naturally occurring carbonaceous filaments. The method can include assembling a battery cell by disposing the electrode and a positive electrode in electrolyte.

Abstract: A battery cell having an anode or cathode comprising an acidified metal oxide (“AMO”) material, preferably in monodisperse nanoparticulate form 20 nm or less in size, having a pH<7 when suspended in a 5 wt % aqueous solution and a Hammett function H0>?12, at least on its surface.

Abstract: A method of manufacturing a positive electrode material for lithium ion secondary battery includes the following (?) and (?): (?) a positive electrode active material is prepared; and (?) the positive electrode material for lithium ion secondary battery is manufactured by forming a coat on at least a portion of a surface of the positive electrode active material. The coat is formed to satisfy the following (1) to (3): (1) the coat includes a lithium ion conductor and a ferroelectric substance; (2) the ferroelectric substance is dispersed in the lithium ion conductor; and (3) the lithium ion conductor is interposed at least partially between the positive electrode active material and the ferroelectric substance.

Abstract: A method of manufacturing a positive electrode material for lithium ion secondary battery includes the following (?) and (?): (?) a positive electrode active material is prepared; and (?) the positive electrode material for lithium ion secondary battery is manufactured by forming a coat on at least a portion of a surface of the positive electrode active material. The coat is formed to satisfy the following (1) to (3): (1) the coat includes a lithium ion conductor and a ferroelectric substance; (2) the ferroelectric substance is dispersed in the lithium ion conductor; and (3) the lithium ion conductor is interposed at least partially between the positive electrode active material and the ferroelectric substance.

Abstract: This application relates to a metal oxide and a method for preparing the same. Specifically, Co3O4 is selected as a precursor of lithium cobalt oxide, and one or more metal elements M are doped in the particles of Co3O4 to obtain a doped lithium cobalt oxide precursor Co3-xMxO4, where 0<x?0.3. The difference value, measured by a spectrometer of a scanning electron microscope, of the weight percentage of one of M in two identical area regions is E, wherein 0<E?1% (wt. %). A lithium ion battery with lithium cobalt oxide prepared from the precursor as a cathode material shows great cycle stability, high-temperature energy storage performance and safety performance in a high-voltage (equal to or greater than 4.45 V) charging and discharging environment.

Abstract: An alkaline dry battery includes a positive electrode, a gel negative electrode, a separator disposed between the positive electrode and the negative electrode, and an alkaline electrolyte solution contained in the positive electrode, the negative electrode, and the separator. The negative electrode contains a negative electrode active material containing zinc and particulate terephthalic acid. The terephthalic acid contained in the negative electrode has an average particle diameter of 25 to 210 ?m.

Abstract: A polymer to be used as a binder for sulfur-based cathodes in lithium batteries that includes in its composition electrophilic groups capable of reaction with and entrapment of polysulfide species. Beneficial effects include reductions in capacity loss and ionic resistance gain.

Abstract: There is provided a novel slurry composition for forming a lithium secondary battery electrode which can improve homogeneity of an electrode active material and a conductive assistant even without using an organic solvent and can improve the binding of an electrode active material and a conductive assistant with an electrode collector, and a lithium secondary battery with improved charge/discharge cycle characteristics and battery capacity. A slurry composition for forming a lithium secondary battery electrode, characterized by comprising an electrode active material (A), a conductive assistant (B), and a pulverized cellulose fiber (C) as an aqueous binder, and a lithium secondary battery electrode and a lithium secondary battery which are obtained using the composition, and an aqueous binder used for the composition.

Abstract: A positive electrode active material for a nonaqueous electrolyte secondary battery contains a lithium composite oxide particle as a main component, in which a ratio of Ni to a total number of moles of all metal elements other than Li is greater than 30 mol %. The lithium composite oxide particle includes a secondary particle being aggregation of primary particles having an average particle diameter of 1 ?m or more, and a shell constituted around the secondary particle. A surface layer void is present between the secondary particle and the shell.

Abstract: Provided is a positive active material, a positive electrode including the positive active material, a lithium battery, and a manufacturing method of the same. The positive active material includes a core including a lithium nickel composite oxide and a coating layer formed on the core. The coating layer improves structural stability of the positive active material. Accordingly, lifespan properties of a lithium battery including the positive active material may be improved.

Abstract: A cathode and a lithium battery including the cathode have improved electrical characteristics. The cathode includes a cathode active material composition including a conducting agent, a binder, and a cathode active material, wherein the cathode active material includes a first lithium compound and a second lithium compound, the first lithium compound having an open-circuit voltage greater than an open-circuit voltage of the second lithium compound, and wherein the second lithium compound includes a metal oxide coating layer.

Abstract: In an aspect, a negative active material, a negative electrode and a lithium battery including the negative active material, and a method of manufacturing the negative active material is provided. The negative active material includes a silicon-based active material substrate; a metal oxide nanoparticle disposed on a surface of the silicon-based active material substrate. An initial irreversible capacity of the lithium battery may be decreased and lifespan characteristics may be improved by using the negative active material.

Abstract: Provided is a cathode active material including a complex coating layer, which includes M below, formed on a surface of the cathode active material through reaction of a lithium transition metal oxide represented by Formula 1 below with a coating precursor: LixMO2??(1) wherein M is represented by MnaM?1-b, M? is at least one selected from the group consisting of Al, Mg, Ni, Co, Cr, V, Fe, Cu, Zn, Ti and B, 0.95?x?1.5, and 0.5?a?1. The lithium secondary battery including the cathode active material exhibits improved lifespan and rate characteristics due to superior stability.

Abstract: Disclosed is an electrode assembly of a lithium secondary battery, including an anode plate, a cathode plate, a separator for separating the anode plate and the cathode plate and conducting lithium ions of an electrolyte, and a composite film disposed between the anode plate and the separator and/or between the cathode plate and the separator. The composite film includes 5 to 95 parts by weight of an inorganic clay and 95 to 5 parts by weight of an organic polymer binder.

Abstract: The present invention relates to a novel phosphate based composite anode material, preparation method and uses thereof. Specifically disclosed is a phosphate based composite cell anode material, the material having monoclinic and orthorhombic crystal lattice structures with the chemical formula of A3-xV2-yMY(PO4)3, wherein A is Li+, Na+ or the mixture thereof, M is Mg, Al, Sc, Ti, Cr, Mn, Fe, Co, Ni, Cu, Zn or Nb, 0?x?3.0, 0?y?2.0, and C is the carbon layer. Also disclosed are a preparation method and uses of the composite material. Unlike simple physical mixing, the composite material of the present invention has the advantages of an adjustable electric potential plateau, high reversible capacity, good cycle stability, power consumption early warning and the like.

Abstract: Disclosed is a nonaqueous secondary battery (100) comprising a positive electrode (155) having a positive current collector (151) made of a metal, and a positive electrode active material (153) composed of a lithium-metal complex oxide. The surface of the positive electrode active material (153) is coated with a lithium salt (158) having an average thickness of 20-50 nm.

Abstract: The disclosure provides a Ni—Mn composite oxalate powder, including a plurality of biwedge octahedron particles represented by the general formula: NiqMnxCoyMzC2O4.nH2O, wherein q+x+y+z=1, 0<q, x<1, 0?y<1, 0?z<0.15, 0?n?5, and M is at least one of Mg, Sr, Ba, Cd, Zn, Al, Ga, B, Zr, Ti, Ca, Ce, Y, Nb, Cr, Fe and V. The above powder may be further calcined with a lithium salt to form a lithium transition metal oxide powder for use as a positive electrode material in lithium ion-batteries.

Abstract: The present disclosure refers to a cathode material composite having improved conductivity, and a cathode and electrochemical device having the cathode material composite. In accordance with one embodiment of the present disclosure, a conductive polymer is positioned on the surface of a shell present in the form of a tetragonal structure in the lithium manganese oxide, thereby enhancing electrical conductivity to be highly involved in reaction around 3V, and providing a conductive path to improve the capacity, life and rate characteristics of an electrochemical device.

Abstract: A negative active material, a method of preparing the negative active material and a lithium ion battery comprising the negative active material are provided. The negative active material may comprise: a core (1) composed of a carbon material; and a plurality of composite materials (2) attached to a surface of the core (1), each of which may comprise a first material (21) and a second material (22) coated on the first material (21), in which the first material (21) may be at least one selected from the elements that may form an alloy with lithium, and the second material (22) may be at least one selected from the group consisting of transition metal oxides, transition metal nitrides and transition metal sulfides.

Abstract: The present invention provides an electrode material in which unevenness in a supporting amount of a carbonaceous film is less when using an electrode-active material having a carbonaceous film on a surface thereof as the electrode material, and which is capable of improving conductivity, and a method for producing the electrode material. The electrode material includes an aggregate formed by aggregating an electrode-active material in which a carbonaceous film is formed on a surface. In the electrode material, an average particle size of the aggregate is 0.5 to 100 ?m, a volume density of the aggregate is 50 to 80 vol % of a volume density in a case in which the aggregate is a solid, and 80% or more of the surface of the electrode-active material is covered with the carbonaceous film. Alternatively, the electrode material includes an aggregate formed by aggregating electrode-active material particles in which a carbonaceous film is formed on a surface.

Abstract: Provided is a lithium metal compound oxide having a layered structure, which is very excellent as a positive electrode active material of a battery that is mounted on, particularly, an electric vehicle or a hybrid vehicle. Suggested is a lithium metal compound oxide having a layered structure which is expressed by general formula of Li1+xM1?xO2 (M represents metal elements including three elements of Mn, Co, and Ni). In the lithium metal compound oxide having a layered structure, D50 is more than 4 ?m and less than 20 ?m, a ratio of a primary particle area to a secondary particle area of secondary particles having a size corresponding to the D50 (“primary particle area/secondary particle area”) is 0.004 to 0.035, and the minimum value of powder crushing strength that is obtained by crushing a powder using a microcompression tester is more than 70 MPa.

Abstract: In a lithium-ion secondary battery (100), positive electrode active material particles (610) each include a shell portion (612) made of a layered lithium-transition metal oxide, a hollow portion (614) formed inside the shell portion (612), and a through-hole (616) penetrating through the shell portion (612). A positive electrode active material layer (223) has a density A of 1.80 g/cm3?A?2.35 g/cm3, and a negative electrode active material layer (243) has a density B of 0.95 g/cm3?B?1.25 g/cm3.

Abstract: An electrode for a rechargeable battery and a rechargeable battery, the electrode including a current collector; an electrode active material layer; and an electrolyte solution impregnation layer, wherein the electrolyte solution impregnation layer includes a metal oxide and a conductive material.

Abstract: An electrode active material including an ordered mesoporous metal oxide; and at least one conductive carbon material disposed in a pore of the ordered mesoporous metal oxide. Also, an electrode including the electrode active material, and a lithium battery including the electrode.

Abstract: The present invention provides a process for producing a graphene-enhanced anode active material for use in a lithium battery. The process comprises (a) providing a continuous film of a graphene material into a deposition zone; (b) introducing vapor or atoms of a precursor anode active material into the deposition zone, allowing the vapor or atoms to deposit onto a surface of the graphene material film to form a sheet of an anode active material-coated graphene material; and (c) mechanically breaking this sheet into multiple pieces of anode active material-coated graphene; wherein the graphene material is in an amount of from 0.1% to 99.5% by weight and the anode active material is in an amount of at least 0.5% by weight, all based on the total weight of the graphene material and the anode active material combined.

Abstract: The present invention provides an anode electrode of a lithium-ion battery, comprising an anode active material-coated graphene sheet, wherein the graphene sheet has two opposed parallel surfaces and at least 50% area of one of the surfaces is coated with an anode active material and wherein the graphene material is in an amount of from 0.1% to 99.5% by weight and the anode active material is in an amount of at least 0.5% by weight (preferably at least 60%), all based on the total weight of the graphene material and the anode active material combined.

Abstract: A nickel zinc battery cell includes a metallic zinc-based current collection substrate as a part of the negative electrode. The metallic zinc-based current collector may be made of or be coated with a zinc metal or zinc alloy material and may be a foil, perforated, or expanded material. Battery cells incorporating the zinc-based current collector exhibit good cycle lifetime and initial charge performance.

Abstract: In a battery production process, a positive electrode active material having a reaction-suppressing layer that does not easily peel off formed on the surface thereof, and a positive electrode and an all-solid-state battery that use said material are provided. The present invention involves positive electrode active material particles for an all-solid-state battery containing sulfide-based solid electrolyte. The positive electrode active material particles are an aggregate containing two or more particles. The surface of the aggregate is coated with a reaction-suppressing layer for suppressing reactions with the sulfide-based solid electrolyte.

Abstract: This invention provides a nanocomposite-based lithium battery electrode comprising: (a) A porous aggregate of electrically conductive nano-filaments that are substantially interconnected, intersected, physically contacted, or chemically bonded to form a three-dimensional network of electron-conducting paths, wherein the nano-filaments have a diameter or thickness less than 1 ?m (preferably less than 500 nm); and (b) Sub-micron or nanometer-scale electro-active particles that are bonded to a surface of the nano-filaments with a conductive binder material, wherein the particles comprise an electro-active material capable of absorbing and desorbing lithium ions and wherein the electro-active material content is no less than 25% by weight based on the total weight of the particles, the binder material, and the filaments. Preferably, these electro-active particles are coated with a thin carbon layer. This electrode can be an anode or a cathode.

Abstract: The present invention relates to a negative electrode active material for a rechargeable lithium battery, a method for preparing the same, and a rechargeable lithium battery using the same, and provides a negative electrode active material for a rechargeable lithium battery of a carbon-metal complex or a mixture type, containing a carbon-based active material including a first ceramic coating layer, a metal-based active material or a metal-base active material including a first ceramic coating layer, and a carbon-based active material.

Abstract: The invention relates to Chevrel-phase materials and methods of preparing these materials utilizing a precursor approach. The Chevrel-phase materials are useful in assembling electrodes, e.g., cathodes, for use in electrochemical cells, such as rechargeable batteries. The Chevrel-phase materials have a general formula of Mo6Z8 and the precursors have a general formula of MxMo6Z8. The cathode containing the Chevrel-phase material in accordance with the invention can be combined with a magnesium-containing anode and an electrolyte.

Abstract: Disclosed is an electrode for secondary batteries including an electrode mixture including an electrode active material, binder and conductive material coated on a current collector wherein a conductive material is coated to a thickness of 1 to 80 ?m on the current collector and the electrode mixture is coated on a coating layer of the conductive material so as to improve electrical conductivity.

Abstract: Ultrafast battery devices having enhanced reliability and power density are provided. Such batteries can include a cathode including a first silicon substrate having a cathode structured surface, an anode including a second silicon substrate having an anode structured surface positioned adjacent to the cathode such that the cathode structured surface faces the anode structured surface, and an electrolyte disposed between the cathode and the anode. The anode structured surface can be coated with an anodic active material and the cathode structured surface can be coated with a cathodic active material.

Abstract: A composite cathode active material, a method of preparing the composite cathode active material, a cathode including the composite cathode active material, and a lithium battery including the cathode. The composite cathode active material includes a lithium intercalatable material; and a garnet oxide, wherein an amount of the garnet oxide is about 1.9 wt % or less, based on a total weight of the composite cathode active material.

Abstract: A composite particle is provided. The particle comprises a first particle component and a second particle component in which: (a) the first particle component comprises a body portion and a surface portion, the surface portion comprising one or more structural features and one or more voids, whereby the surface portion and body portion define together a structured particle; and (b) the second component comprises a removable filler; characterised in that (i) one or both of the body portion and the surface portion comprise an active material; and (ii) the filler is contained within one or more voids comprised within the surface portion of the first component.

Abstract: Disclosed are a method of manufacturing an electrode for secondary batteries that includes surface-treating a current collector so as to have a morphology wherein a surface roughness Ra of 0.001 ?m to 10 ?m is formed over the entire surface thereof to enhance adhesion between an electrode active material and the current collector and an electrode for secondary batteries that is manufactured using the method.

Abstract: The present disclosure relates to an anode active material comprising a composite of a core-shell structure, a lithium secondary battery comprising the same, and a method of manufacturing the anode active material. According to an aspect of the present disclosure, there is provided an anode active material of a core-shell structure comprising a core including alloyed (quasi)metal oxide-Li (MOx—Liy) and a shell including a carbon material coated on a surface of the core. According to another aspect of the present disclosure, there is provided a method of manufacturing the anode active material of the core-shell structure. According to an aspect of the present disclosure, an anode active material with high capacity, excellent cycle characteristics and volume expansion control capacity, and high initial efficiency is provided.

Abstract: This invention relates to a negative electrode material for lithium-ion batteries comprising silicon and having a chemically treated or coated surface influencing the zeta potential of the surface. The active material consists of particles or particles and wires comprising a core (11) comprising silicon, wherein the particles have a positive zeta potential in an interval between pH 3.5 and 9.5, and preferably between pH 4 and 9.5. The core is either chemically treated with an amino-functional metal oxide, or the core is at least partly covered with OySiHx groups, with 1<x<3, 1<y<3, and x>y, or is covered by adsorbed inorganic nanoparticles or cationic multivalent metal ions or oxides.

Abstract: A Li-ion battery is disclosed, the Li-ion battery including an anode, a cathode, a lithium donor formed from a Li-containing material, and an electrolyte in communication with the anode, the cathode, and the lithium donor. The lithium donor may be incorporated into the anode, incorporated into the cathode, a layer formed on either an anode side or a cathode side of a separator of the battery. The lithium donor is formed from Li-containing material insensitive to oxygen and aqueous moisture.

Abstract: Provided is a lithium secondary battery having improved discharge characteristics in a range of high-rate discharge while minimizing a dead volume and at the same time, having increased cell capacity via increased electrode density and electrode loading amounts, by inclusion of two or more active materials having different redox levels so as to exert superior discharge characteristics in the range of high-rate discharge via sequential action of cathode active materials in a discharge process, and preferably having different particle diameters.