Zinc Oxide Patents (Class 429/231)
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Patent number: 12155030Abstract: One aspect of the present invention is a nonaqueous electrolyte energy storage device including a positive electrode containing manganese-containing positive active material particles in which aluminum is present at least on a surface, and a nonaqueous electrolyte containing a salt represented by the following formula (1). Another aspect of the present invention is a method of producing a nonaqueous electrolyte energy storage device, including producing a positive electrode containing manganese-containing positive active material particles in which aluminum is present at least on a surface, and providing a nonaqueous electrolyte containing a salt represented by the following formula (1): wherein R1 is a hydrogen atom, a halogen atom, or an organic group, Mm+ is an alkali metal cation, an alkaline earth metal cation, or an onium cation. m is an integer equivalent to the number of valence of a cation represented by Mm+. when m is 2 or more, a plurality of R1s are each independently as defined above.Type: GrantFiled: September 5, 2019Date of Patent: November 26, 2024Assignee: GS Yuasa International Ltd.Inventor: Takashi Okajima
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Patent number: 12126014Abstract: Alkaline electrochemical cells are provided, wherein dissolved zinc oxide or zinc hydroxide is included at least in the free electrolyte solution, and/or solid zinc oxide or zinc hydroxide is included in the anode, so as to slow formation of a zinc oxide passivation layer on a zinc electrode. Methods for preparing such cells are also provided.Type: GrantFiled: August 12, 2022Date of Patent: October 22, 2024Assignee: Energizer Brands, LLCInventors: Robert P. Johnson, Robert E. Ray, Jr., Weiwei Huang, Zhufang Liu, Steven J. Limmer
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Patent number: 12095076Abstract: A negative electrode active material for a secondary battery includes a silicate composite particle. The silicate composite particle contains silicate phases, silicon particles dispersed in the silicate phases, and a carbon phase. The silicate phases contain at least one selected from the group consisting of an alkali metal and an alkaline earth metal. At least parts of the carbon phase coat at least parts of surfaces of the silicon particles.Type: GrantFiled: December 4, 2019Date of Patent: September 17, 2024Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.Inventors: Yosuke Sato, Yohei Uchiyama, Taisuke Asano
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Patent number: 12046749Abstract: Provided is a lithium secondary battery with improved t electrochemical characteristics through improvement of the structural stability by including a cathode active material doped with molybdenum (Mo). The lithium secondary battery includes a cathode; an anode; a separator positioned between the cathode and the anode; and an electrolyte. In particular, the cathode active material includes molybdenum (Mo) doped on a composite oxide of lithium and metal including manganese (Mn) and titanium (Ti).Type: GrantFiled: September 1, 2021Date of Patent: July 23, 2024Assignees: Hyundai Motor Company, Kia Corporation, Industry Academy Cooperation Foundation of Sejong UniversityInventors: Seung-Min Oh, KiSeok Koh, Yeolmae Yeo, Dongjun Kim, Yoon Sung Lee, Jieun Lee, Sa Heum Kim, Seung-Taek Myung
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Patent number: 12046746Abstract: A lithium metal negative electrode and a lithium metal battery including the lithium metal negative electrode. The lithium metal negative electrode includes a protective layer present on at least one surface of the negative electrode for stabilizing between the lithium metal and the electrolyte. The protective layer includes a polymer of alpha lipoic acid (ALA) and sulfur molecule (S8), a depolymerized product of the polymer, an inorganic sulfide-based compound, and at least one of an inorganic nitride-based compound, or an inorganic nitrate-based compound.Type: GrantFiled: July 15, 2020Date of Patent: July 23, 2024Assignees: LG ENERGY SOLUTION, LTD., KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGYInventors: Jong Keon Yoon, Yunjung Kim, Hyunwoong Yun, Sunwoo Hwang, Hoejin Hah, Hee-Tak Kim, Youngil Roh
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Patent number: 12027704Abstract: A sulfur-carbon composite and a lithium secondary battery including the same are discussed. More specifically, a network-shaped coating layer including a conductive polymer is formed on a surface of the sulfur-carbon composite, and thus the conductivity of the sulfur-carbon composite is enhanced and also, lithium ions move freely, and accordingly, when applied to lithium secondary batteries, the sulfur-carbon composite can enhance the performance of batteries.Type: GrantFiled: September 10, 2019Date of Patent: July 2, 2024Assignee: LG ENERGY SOLUTION, LTD.Inventors: Bong Soo Kim, Kwonnam Sohn
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Patent number: 12009504Abstract: According to one embodiment, provided is an electrode including a current collector and an active material-containing layer in contact with the current collector. The active material-containing layer contains a carbon nanotube and particles of titanium-containing oxide having an average particle size or 0.1 ?m to 3 ?m. A peel strength between the current collector and the active material-containing layer is within a range of 0.2 kN/m to 0.7 kN/m.Type: GrantFiled: February 26, 2021Date of Patent: June 11, 2024Assignee: KABUSHIKI KAISHA TOSHIBAInventors: Yasunobu Yamashita, Keigo Hoshina, Yasuhiro Harada, Norio Takami, Shinsuke Matsuno
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Patent number: 11936041Abstract: A lithium secondary battery includes a cathode formed from a cathode active material including a first cathode active material particle and a second cathode active material particle, an anode and a separator interposed between the cathode and the anode. The first cathode active material particle includes a lithium metal oxide including a continuous concentration gradient in at least one region between a central portion and a surface portion. The second cathode active material particle includes a lithium metal oxide including elements the same as those of the first cathode active material particle, and the second cathode active material particle has a uniform composition from a central portion to a surface.Type: GrantFiled: December 14, 2017Date of Patent: March 19, 2024Assignee: SK ON CO., LTD.Inventors: Kook Hyun Han, Kyung Bin Yoo, Duck Chul Hwang
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Patent number: 11909043Abstract: A positive electrode for an all-solid secondary battery including a sulfide-based solid electrolyte includes a first positive active material having an average particle diameter of about 15 ?m to about 20 ?m, a second positive active material having an average particle diameter of about 2 ?m to about 6 ?m, and a solid electrolyte, wherein at least one selected from the first positive active material and the second positive active material includes a coating layer including a lithium ion conductor, and each of the first positive active material and the second positive active material includes a core and a shell, wherein the shell includes a nickel-based active material containing cobalt. An all-solid secondary battery includes the positive electrode.Type: GrantFiled: March 3, 2021Date of Patent: February 20, 2024Assignee: Samsung SDI Co., Ltd.Inventor: Taeri Kwon
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Patent number: 11791452Abstract: Provided are: a positive electrode for solid-state batteries, which enables the achievement of high energy density, rate characteristics and durability; a solid-state battery; and a method for producing a solid-state battery. A positive electrode for solid-state batteries, which is provided with a collector and a positive electrode active material layer that contains a positive electrode active material, and which is configured such that: the ratio of the positive electrode active material, which is composed of primary particles, in the positive electrode active material layer is 60% by mass or more; the void fraction in the positive electrode active material layer is less than 20% by volume; and portions of the positive electrode active material layer other than the positive electrode active material, which is composed of primary particles, contain a solid electrolyte.Type: GrantFiled: February 2, 2018Date of Patent: October 17, 2023Assignee: HONDA MOTOR CO., LTD.Inventors: Hiroto Maeyama, Ushio Harada, Noriaki Kamaya, Sokichi Okubo, Toru Sukigara
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Patent number: 11670763Abstract: An electrode material for a lithium ion secondary battery and method of forming the same, the electrode material including composite particles, each composite particle including a primary particle including thermally disproportionated silicon oxide, and an envelope disposed on the surface of the primary particle. The envelope includes turbostratic carbon having a Raman spectrum having: a D band having a peak intensity (ID) at wave number between 1330 cm?1 and 1360 cm?1; a G band having a peak intensity (IG) at wave number between 1530 cm?1 and 1600 cm?1; and a 2D band having a peak intensity (I2D) at wave number between 2650 cm?1 and 2750 cm?1, wherein a ratio of ID/IG ranges from greater than zero to about 1.0, and a ratio of I2D/IG ranges from about 0.4 to about 2.Type: GrantFiled: November 5, 2020Date of Patent: June 6, 2023Assignee: NANOGRAF CORPORATIONInventors: Cary Hayner, Seonbaek Ha, Kathryn Hicks, Joshua Lau, Christine Frysz
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Patent number: 11652238Abstract: The present invention provides an electrolyte solution for a non-aqueous electrolyte solution battery capable of exhibiting excellent high-temperature cycle characteristics and excellent high-temperature storage characteristics at high temperature of 60° C. or above, and a non-aqueous electrolyte solution battery using the same. The electrolyte solution for a non-aqueous electrolyte solution battery of the present invention comprises at least: a non-aqueous solvent; a solute; at least one first compound represented by the following general formula (1); and at least one second compound represented by the following general formula (2).Type: GrantFiled: October 13, 2020Date of Patent: May 16, 2023Assignee: Central Glass Co., Ltd.Inventors: Takayoshi Morinaka, Makoto Kubo, Wataru Kawabata, Kenta Yamamoto, Mikihiro Takahashi
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Patent number: 11594786Abstract: An aspect of the present invention achieves a nonaqueous electrolyte secondary battery laminated separator which has excellent heat resistance and exhibits an excellent initial battery characteristic when used in a nonaqueous electrolyte secondary battery. A nonaqueous electrolyte secondary battery laminated separator in accordance with an aspect of the present invention includes: a polyolefin porous film; and a porous layer which (i) is disposed on at least one surface of the polyolefin porous film and (ii) includes a heat resistant filler, the porous layer having a surface which has cracks, a ratio of a total area of the cracks to a surface area of the porous layer being 0.15% to 10%.Type: GrantFiled: April 15, 2020Date of Patent: February 28, 2023Assignee: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Shizuka Iwata, Kosuke Kurakane
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Patent number: 11588150Abstract: An electrode material for a lithium ion secondary battery and method of forming the same, the electrode material including composite particles, each composite particle including: a primary particle including an electrochemically active material; and an envelope disposed on the surface of the primary particle. The envelope includes turbostratic carbon having a Raman spectrum having: a D band having a peak intensity (ID) at wave number between 1330 cm?1 and 1360 cm?1; a G band having a peak intensity (IG) at wave number between 1530 cm?1 and 1580 cm?1; and a 2D band having a peak intensity (I2D) at wave number between 2650 cm?1 and 2750 cm?1. In one embodiment, a ratio of ID/IG ranges from greater than zero to about 1.1, and a ratio of I2D/IG ranges from about 0.4 to about 2.Type: GrantFiled: May 18, 2020Date of Patent: February 21, 2023Assignee: NANOGRAF CORPORATIONInventors: Joshua J. Lau, Aaron Yost, James McKinney, Cary Michael Hayner, Jack Cavanaugh, Seonbaek Ha
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Patent number: 11545664Abstract: The present disclosure relates to an anode active material for a lithium secondary battery, a method of manufacturing the anode active material, and a lithium secondary battery including the anode active material. The anode active material includes natural graphite particles configured such that flaky natural graphite fragment particles having uneven (??) surface defects are structured in a cabbage shape or at random and granulated, the surface and the inside of the natural graphite particles including a gap formed between the flaky natural graphite fragment particles, and a coating layer including amorphous or semicrystalline carbon formed on the surface of the flaky natural graphite fragment particles that form the gap and the surface of the natural graphite particles.Type: GrantFiled: December 11, 2019Date of Patent: January 3, 2023Assignee: KNU-Industry Cooperation FoundationInventors: Sung Man Lee, Ki Hoon Kim
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Patent number: 11444281Abstract: A nickel-based active material precursor includes a particulate structure including a core portion, an intermediate layer portion on the core portion, and a shell portion on the intermediate layer portion, wherein the intermediate layer portion and the shell portion include primary particles radially arranged on the core portion, and each of the core portion and the intermediate layer portion includes a cation or anion different from that of the shell portion. The cation includes at least one selected from boron (B), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), titanium (Ti), vanadium (V), tungsten (W), chromium (Cr), iron (Fe), copper (Cu), zirconium (Zr), and aluminium (Al), and the anion includes at least one selected from phosphate (PO4), BO2, B4O7, B3O5, and F.Type: GrantFiled: October 16, 2019Date of Patent: September 13, 2022Assignee: Samsung SDI Co., Ltd.Inventors: Pilsang Yun, Wooyoung Yang, Jangsuk Hyun
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Patent number: 11394019Abstract: There are provided a method capable of producing a large amount of a carbonaceous material for a negative electrode of a non-aqueous electrolyte secondary battery from a carbon precursor impregnated with an alkali metal element or an alkali metal compound, and an apparatus for performing such production. The method for producing a carbonaceous material for a negative electrode of a non-aqueous electrolyte secondary battery includes a heat treatment step of feeding a carbon precursor containing an elemental alkali metal and/or an alkali metal compound, heating the carbon precursor in a temperature range from 1000° C. to 1500° C. in a non-oxidizing gas atmosphere to produce a carbonaceous material, and discharging the carbonaceous material; and an exhaust gas treatment step of contacting a non-oxidizing exhaust gas containing a gas and a flying carbonaceous matter evolved in the heat treatment step with water or an aqueous solution to treat the exhaust gas.Type: GrantFiled: June 6, 2019Date of Patent: July 19, 2022Assignees: KUREHA CORPORATION, TSUKISHIMA KIKAI CO., LTD.Inventors: Naohiro Sonobe, Mayu Komatsu, Koji Miwa, Kokei Ueno
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Patent number: 11316142Abstract: Methods for fabricating electrodes include coating a current collector with a slurry to form a coated current collector. The slurry includes a dry fraction, including silicon particles, polymeric binders, and one or more types of naturally occurring carbonaceous filaments, and one or more solvents. The coated current collector is heat treated to produce the electrode having a layer of silicon-based host material. The one or more naturally occurring carbonaceous filaments can include animal fibers, chitin, alginate, cellulose, keratin, and chitosan, and can have an average length of 1 ?m to 50 ?m and an average diameter of 1 nm to 500 nm. The dry fraction can include 5 wt. % to 95 wt. % silicon particles, 0.1 wt. % to 15 wt. % polymeric binders, and 1 wt. % to 20 wt. % naturally occurring carbonaceous filaments. The method can include assembling a battery cell by disposing the electrode and a positive electrode in electrolyte.Type: GrantFiled: September 17, 2019Date of Patent: April 26, 2022Assignee: GM Global Technology Operations LLCInventors: Meng Jiang, Raghunathan K, Ion C. Halalay, Mark W. Verbrugge
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Patent number: 11302912Abstract: A battery cell having an anode or cathode comprising an acidified metal oxide (“AMO”) material, preferably in monodisperse nanoparticulate form 20 nm or less in size, having a pH<7 when suspended in a 5 wt % aqueous solution and a Hammett function H0>?12, at least on its surface.Type: GrantFiled: February 3, 2020Date of Patent: April 12, 2022Assignee: HHeLi, LLCInventors: Paige L. Johnson, Jonathan G. Neff
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Patent number: 11171331Abstract: A method of manufacturing a positive electrode material for lithium ion secondary battery includes the following (?) and (?): (?) a positive electrode active material is prepared; and (?) the positive electrode material for lithium ion secondary battery is manufactured by forming a coat on at least a portion of a surface of the positive electrode active material. The coat is formed to satisfy the following (1) to (3): (1) the coat includes a lithium ion conductor and a ferroelectric substance; (2) the ferroelectric substance is dispersed in the lithium ion conductor; and (3) the lithium ion conductor is interposed at least partially between the positive electrode active material and the ferroelectric substance.Type: GrantFiled: April 30, 2021Date of Patent: November 9, 2021Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Daisuke Horikawa, Ryuta Sugiura
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Patent number: 11139470Abstract: A method of manufacturing a positive electrode material for lithium ion secondary battery includes the following (?) and (?): (?) a positive electrode active material is prepared; and (?) the positive electrode material for lithium ion secondary battery is manufactured by forming a coat on at least a portion of a surface of the positive electrode active material. The coat is formed to satisfy the following (1) to (3): (1) the coat includes a lithium ion conductor and a ferroelectric substance; (2) the ferroelectric substance is dispersed in the lithium ion conductor; and (3) the lithium ion conductor is interposed at least partially between the positive electrode active material and the ferroelectric substance.Type: GrantFiled: February 15, 2018Date of Patent: October 5, 2021Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Daisuke Horikawa, Ryuta Sugiura
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Patent number: 11081686Abstract: This application relates to a metal oxide and a method for preparing the same. Specifically, Co3O4 is selected as a precursor of lithium cobalt oxide, and one or more metal elements M are doped in the particles of Co3O4 to obtain a doped lithium cobalt oxide precursor Co3-xMxO4, where 0<x?0.3. The difference value, measured by a spectrometer of a scanning electron microscope, of the weight percentage of one of M in two identical area regions is E, wherein 0<E?1% (wt. %). A lithium ion battery with lithium cobalt oxide prepared from the precursor as a cathode material shows great cycle stability, high-temperature energy storage performance and safety performance in a high-voltage (equal to or greater than 4.45 V) charging and discharging environment.Type: GrantFiled: December 12, 2018Date of Patent: August 3, 2021Assignee: NINGDE AMPEREX TECHNOLOGY LIMITEDInventors: Meng Wang, Leimin Xu, Liang Wang, Pengwei Chen
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Patent number: 10847786Abstract: An alkaline dry battery includes a positive electrode, a gel negative electrode, a separator disposed between the positive electrode and the negative electrode, and an alkaline electrolyte solution contained in the positive electrode, the negative electrode, and the separator. The negative electrode contains a negative electrode active material containing zinc and particulate terephthalic acid. The terephthalic acid contained in the negative electrode has an average particle diameter of 25 to 210 ?m.Type: GrantFiled: July 18, 2017Date of Patent: November 24, 2020Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.Inventors: Yasufumi Takahashi, Satoshi Fujiyoshi
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Patent number: 10141604Abstract: A polymer to be used as a binder for sulfur-based cathodes in lithium batteries that includes in its composition electrophilic groups capable of reaction with and entrapment of polysulfide species. Beneficial effects include reductions in capacity loss and ionic resistance gain.Type: GrantFiled: August 14, 2017Date of Patent: November 27, 2018Assignee: Seeo, Inc.Inventors: Russell Clayton Pratt, Hany Basam Eitouni, Kulandaivelu Sivanandan
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Patent number: 10020513Abstract: There is provided a novel slurry composition for forming a lithium secondary battery electrode which can improve homogeneity of an electrode active material and a conductive assistant even without using an organic solvent and can improve the binding of an electrode active material and a conductive assistant with an electrode collector, and a lithium secondary battery with improved charge/discharge cycle characteristics and battery capacity. A slurry composition for forming a lithium secondary battery electrode, characterized by comprising an electrode active material (A), a conductive assistant (B), and a pulverized cellulose fiber (C) as an aqueous binder, and a lithium secondary battery electrode and a lithium secondary battery which are obtained using the composition, and an aqueous binder used for the composition.Type: GrantFiled: September 20, 2012Date of Patent: July 10, 2018Assignees: NISSAN CHEMICAL INDUSTRIES, LTD., IWATE UNIVERSITYInventors: Hisato Hayashi, Masaaki Ozawa, Osamu Uesugi, Yoshihiro Kadoma
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Patent number: 9997774Abstract: A positive electrode active material for a nonaqueous electrolyte secondary battery contains a lithium composite oxide particle as a main component, in which a ratio of Ni to a total number of moles of all metal elements other than Li is greater than 30 mol %. The lithium composite oxide particle includes a secondary particle being aggregation of primary particles having an average particle diameter of 1 ?m or more, and a shell constituted around the secondary particle. A surface layer void is present between the secondary particle and the shell.Type: GrantFiled: December 10, 2015Date of Patent: June 12, 2018Assignee: PANASONIC CORPORATIONInventor: Hidekazu Hiratsuka
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Patent number: 9859555Abstract: Provided is a positive active material, a positive electrode including the positive active material, a lithium battery, and a manufacturing method of the same. The positive active material includes a core including a lithium nickel composite oxide and a coating layer formed on the core. The coating layer improves structural stability of the positive active material. Accordingly, lifespan properties of a lithium battery including the positive active material may be improved.Type: GrantFiled: January 26, 2015Date of Patent: January 2, 2018Assignee: Samsung SDI Co., Ltd.Inventors: Jung-Yeon Won, Eun-Young Goh, Jin-Hyon Lee, Ju-Hee Sohn, Jong-Ki Lee, Seung-Wan Kim, Ju-Hyeong Han
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Patent number: 9172086Abstract: A cathode and a lithium battery including the cathode have improved electrical characteristics. The cathode includes a cathode active material composition including a conducting agent, a binder, and a cathode active material, wherein the cathode active material includes a first lithium compound and a second lithium compound, the first lithium compound having an open-circuit voltage greater than an open-circuit voltage of the second lithium compound, and wherein the second lithium compound includes a metal oxide coating layer.Type: GrantFiled: December 4, 2009Date of Patent: October 27, 2015Assignee: Samsung SDI Co., Ltd.Inventor: Kyu-Sung Park
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Publication number: 20150140359Abstract: In an aspect, a negative active material, a negative electrode and a lithium battery including the negative active material, and a method of manufacturing the negative active material is provided. The negative active material includes a silicon-based active material substrate; a metal oxide nanoparticle disposed on a surface of the silicon-based active material substrate. An initial irreversible capacity of the lithium battery may be decreased and lifespan characteristics may be improved by using the negative active material.Type: ApplicationFiled: April 25, 2014Publication date: May 21, 2015Applicant: Samsung SDI Co., Ltd.Inventors: Sang-Eun Park, Young-Ugk Kim, Hyun-Ki Park, Chang-Su Shin, Ui-Song Do, Sung-Su Kim
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Publication number: 20150132651Abstract: Provided is a cathode active material including a complex coating layer, which includes M below, formed on a surface of the cathode active material through reaction of a lithium transition metal oxide represented by Formula 1 below with a coating precursor: LixMO2??(1) wherein M is represented by MnaM?1-b, M? is at least one selected from the group consisting of Al, Mg, Ni, Co, Cr, V, Fe, Cu, Zn, Ti and B, 0.95?x?1.5, and 0.5?a?1. The lithium secondary battery including the cathode active material exhibits improved lifespan and rate characteristics due to superior stability.Type: ApplicationFiled: January 15, 2015Publication date: May 14, 2015Applicant: LG CHEM, LTD.Inventors: Bo Ram Lee, Hye Lim Jeon, Sun Sik Shin, Sangwook Lee, Wang Mo Jung
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Patent number: 9029003Abstract: Disclosed is an electrode assembly of a lithium secondary battery, including an anode plate, a cathode plate, a separator for separating the anode plate and the cathode plate and conducting lithium ions of an electrolyte, and a composite film disposed between the anode plate and the separator and/or between the cathode plate and the separator. The composite film includes 5 to 95 parts by weight of an inorganic clay and 95 to 5 parts by weight of an organic polymer binder.Type: GrantFiled: March 1, 2012Date of Patent: May 12, 2015Assignee: Industrial Technology Research InstituteInventors: Angelia Sulaiman Lo, Chun-Wei Su, Chyi-Ming Leu, Chih-Jen Yang, Chang-Rung Yang, Jen-Chih Lo, Tzong-Ming Lee, Jing-Pin Pan
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Publication number: 20150125749Abstract: The present invention relates to a novel phosphate based composite anode material, preparation method and uses thereof. Specifically disclosed is a phosphate based composite cell anode material, the material having monoclinic and orthorhombic crystal lattice structures with the chemical formula of A3-xV2-yMY(PO4)3, wherein A is Li+, Na+ or the mixture thereof, M is Mg, Al, Sc, Ti, Cr, Mn, Fe, Co, Ni, Cu, Zn or Nb, 0?x?3.0, 0?y?2.0, and C is the carbon layer. Also disclosed are a preparation method and uses of the composite material. Unlike simple physical mixing, the composite material of the present invention has the advantages of an adjustable electric potential plateau, high reversible capacity, good cycle stability, power consumption early warning and the like.Type: ApplicationFiled: September 12, 2012Publication date: May 7, 2015Applicant: Ningbo Institute of Materials & Engineering, Chinese Academy of SciencesInventors: Yuanhao Tang, Chenyun Wang, Deyu Wang, Jun Li
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Patent number: 9023531Abstract: Disclosed is a nonaqueous secondary battery (100) comprising a positive electrode (155) having a positive current collector (151) made of a metal, and a positive electrode active material (153) composed of a lithium-metal complex oxide. The surface of the positive electrode active material (153) is coated with a lithium salt (158) having an average thickness of 20-50 nm.Type: GrantFiled: October 17, 2008Date of Patent: May 5, 2015Assignees: Toyota Jidosha Kabushiki Kaisha, Sumitomo Metal Mining Co., Ltd.Inventors: Tomoyoshi Ueki, Yutaka Oyama, Takuichi Arai, Kazuhiro Ohkawa, Koichi Yokoyama, Ryuichi Kuzuo, Katsuya Kase, Syuhei Oda
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Publication number: 20150104706Abstract: The disclosure provides a Ni—Mn composite oxalate powder, including a plurality of biwedge octahedron particles represented by the general formula: NiqMnxCoyMzC2O4.nH2O, wherein q+x+y+z=1, 0<q, x<1, 0?y<1, 0?z<0.15, 0?n?5, and M is at least one of Mg, Sr, Ba, Cd, Zn, Al, Ga, B, Zr, Ti, Ca, Ce, Y, Nb, Cr, Fe and V. The above powder may be further calcined with a lithium salt to form a lithium transition metal oxide powder for use as a positive electrode material in lithium ion-batteries.Type: ApplicationFiled: December 26, 2013Publication date: April 16, 2015Applicants: NATIONAL TAIWAN UNIVERSITY, INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventors: Hung-Chun WU, Yu-Ting CHEN, Nae-Lih WU, Wen-Chin CHEN, Shih-Chieh LIAO, Yih-Chyng WU
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Publication number: 20150104707Abstract: The present disclosure refers to a cathode material composite having improved conductivity, and a cathode and electrochemical device having the cathode material composite. In accordance with one embodiment of the present disclosure, a conductive polymer is positioned on the surface of a shell present in the form of a tetragonal structure in the lithium manganese oxide, thereby enhancing electrical conductivity to be highly involved in reaction around 3V, and providing a conductive path to improve the capacity, life and rate characteristics of an electrochemical device.Type: ApplicationFiled: December 18, 2014Publication date: April 16, 2015Applicant: LG Chem, Ltd.Inventors: Ji-Hye Park, Song-Taek Oh, Hyeok-Moo Lee
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Patent number: 9005812Abstract: A negative active material, a method of preparing the negative active material and a lithium ion battery comprising the negative active material are provided. The negative active material may comprise: a core (1) composed of a carbon material; and a plurality of composite materials (2) attached to a surface of the core (1), each of which may comprise a first material (21) and a second material (22) coated on the first material (21), in which the first material (21) may be at least one selected from the elements that may form an alloy with lithium, and the second material (22) may be at least one selected from the group consisting of transition metal oxides, transition metal nitrides and transition metal sulfides.Type: GrantFiled: August 31, 2011Date of Patent: April 14, 2015Assignee: Shenzhen BYD Auto R&D Company LimitedInventors: Yongjun Ma, Pei Tu, Zizhu Guo
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Publication number: 20150099175Abstract: The present invention provides an electrode material in which unevenness in a supporting amount of a carbonaceous film is less when using an electrode-active material having a carbonaceous film on a surface thereof as the electrode material, and which is capable of improving conductivity, and a method for producing the electrode material. The electrode material includes an aggregate formed by aggregating an electrode-active material in which a carbonaceous film is formed on a surface. In the electrode material, an average particle size of the aggregate is 0.5 to 100 ?m, a volume density of the aggregate is 50 to 80 vol % of a volume density in a case in which the aggregate is a solid, and 80% or more of the surface of the electrode-active material is covered with the carbonaceous film. Alternatively, the electrode material includes an aggregate formed by aggregating electrode-active material particles in which a carbonaceous film is formed on a surface.Type: ApplicationFiled: December 11, 2014Publication date: April 9, 2015Applicant: SUMITOMO OSAKA CEMENT CO., LTD.Inventors: Takao KITAGAWA, Hirofumi YASUMIISHI, Masaru UEHARA
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Publication number: 20150093641Abstract: Provided is a lithium metal compound oxide having a layered structure, which is very excellent as a positive electrode active material of a battery that is mounted on, particularly, an electric vehicle or a hybrid vehicle. Suggested is a lithium metal compound oxide having a layered structure which is expressed by general formula of Li1+xM1?xO2 (M represents metal elements including three elements of Mn, Co, and Ni). In the lithium metal compound oxide having a layered structure, D50 is more than 4 ?m and less than 20 ?m, a ratio of a primary particle area to a secondary particle area of secondary particles having a size corresponding to the D50 (“primary particle area/secondary particle area”) is 0.004 to 0.035, and the minimum value of powder crushing strength that is obtained by crushing a powder using a microcompression tester is more than 70 MPa.Type: ApplicationFiled: April 16, 2013Publication date: April 2, 2015Inventors: Tetsuya Mitsumoto, Hitohiko Ide, Shinya Kagei, Yoshimi Hata
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Publication number: 20150072232Abstract: In a lithium-ion secondary battery (100), positive electrode active material particles (610) each include a shell portion (612) made of a layered lithium-transition metal oxide, a hollow portion (614) formed inside the shell portion (612), and a through-hole (616) penetrating through the shell portion (612). A positive electrode active material layer (223) has a density A of 1.80 g/cm3?A?2.35 g/cm3, and a negative electrode active material layer (243) has a density B of 0.95 g/cm3?B?1.25 g/cm3.Type: ApplicationFiled: March 30, 2012Publication date: March 12, 2015Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventor: Hiroki Nagai
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Publication number: 20150064556Abstract: An electrode for a rechargeable battery and a rechargeable battery, the electrode including a current collector; an electrode active material layer; and an electrolyte solution impregnation layer, wherein the electrolyte solution impregnation layer includes a metal oxide and a conductive material.Type: ApplicationFiled: January 17, 2014Publication date: March 5, 2015Applicant: SAMSUNG SDI CO., LTD.Inventors: Jin-Hyon LEE, Ju-Hee SOHN, Jung-Yeon WON, Eun-Young GOH, Jong-Ki LEE, Sang-In PARK
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ELECTRODE ACTIVE MATERIAL, ELECTRODE INCLUDING THE SAME, AND LITHIUM BATTERY INCLUDING THE ELECTRODE
Publication number: 20150064560Abstract: An electrode active material including an ordered mesoporous metal oxide; and at least one conductive carbon material disposed in a pore of the ordered mesoporous metal oxide. Also, an electrode including the electrode active material, and a lithium battery including the electrode.Type: ApplicationFiled: August 25, 2014Publication date: March 5, 2015Inventors: Jeongkuk SHON, Jaeman CHOI, Junhwan KU, Kuntae KWON, Moonseok KWON, Minsang SONG, Seungsik HWANG, Jiman KIM, Gwiok PARK -
Publication number: 20150044564Abstract: The present invention provides an anode electrode of a lithium-ion battery, comprising an anode active material-coated graphene sheet, wherein the graphene sheet has two opposed parallel surfaces and at least 50% area of one of the surfaces is coated with an anode active material and wherein the graphene material is in an amount of from 0.1% to 99.5% by weight and the anode active material is in an amount of at least 0.5% by weight (preferably at least 60%), all based on the total weight of the graphene material and the anode active material combined.Type: ApplicationFiled: August 8, 2013Publication date: February 12, 2015Inventors: Yanbo Wang, Bor Z. Jang, Hui He, Aruna Zhamu
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Publication number: 20150044565Abstract: The present invention provides a process for producing a graphene-enhanced anode active material for use in a lithium battery. The process comprises (a) providing a continuous film of a graphene material into a deposition zone; (b) introducing vapor or atoms of a precursor anode active material into the deposition zone, allowing the vapor or atoms to deposit onto a surface of the graphene material film to form a sheet of an anode active material-coated graphene material; and (c) mechanically breaking this sheet into multiple pieces of anode active material-coated graphene; wherein the graphene material is in an amount of from 0.1% to 99.5% by weight and the anode active material is in an amount of at least 0.5% by weight, all based on the total weight of the graphene material and the anode active material combined.Type: ApplicationFiled: August 8, 2013Publication date: February 12, 2015Inventors: Yanbo Wang, Bor Z. Jang, Hui He, Aruna Zhamu
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Patent number: 8940430Abstract: A nickel zinc battery cell includes a metallic zinc-based current collection substrate as a part of the negative electrode. The metallic zinc-based current collector may be made of or be coated with a zinc metal or zinc alloy material and may be a foil, perforated, or expanded material. Battery cells incorporating the zinc-based current collector exhibit good cycle lifetime and initial charge performance.Type: GrantFiled: February 8, 2008Date of Patent: January 27, 2015Assignee: PowerGenix Systems, Inc.Inventors: Jeffrey Phillips, Samaresh Mohanta, Zhen Gang Fan, Ru Jun Ma, Feng Feng, Lou Uzel, Chi Yau, Jason Zhao, Zeiad M. Muntasser
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Publication number: 20150024280Abstract: In a battery production process, a positive electrode active material having a reaction-suppressing layer that does not easily peel off formed on the surface thereof, and a positive electrode and an all-solid-state battery that use said material are provided. The present invention involves positive electrode active material particles for an all-solid-state battery containing sulfide-based solid electrolyte. The positive electrode active material particles are an aggregate containing two or more particles. The surface of the aggregate is coated with a reaction-suppressing layer for suppressing reactions with the sulfide-based solid electrolyte.Type: ApplicationFiled: May 23, 2011Publication date: January 22, 2015Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventor: Takayuki Uchiyama
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Patent number: 8936874Abstract: This invention provides a nanocomposite-based lithium battery electrode comprising: (a) A porous aggregate of electrically conductive nano-filaments that are substantially interconnected, intersected, physically contacted, or chemically bonded to form a three-dimensional network of electron-conducting paths, wherein the nano-filaments have a diameter or thickness less than 1 ?m (preferably less than 500 nm); and (b) Sub-micron or nanometer-scale electro-active particles that are bonded to a surface of the nano-filaments with a conductive binder material, wherein the particles comprise an electro-active material capable of absorbing and desorbing lithium ions and wherein the electro-active material content is no less than 25% by weight based on the total weight of the particles, the binder material, and the filaments. Preferably, these electro-active particles are coated with a thin carbon layer. This electrode can be an anode or a cathode.Type: GrantFiled: June 4, 2008Date of Patent: January 20, 2015Assignee: Nanotek Instruments, Inc.Inventors: Jinjun Shi, Aruna Zhamu, Bor Z. Jang
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Publication number: 20150017527Abstract: The present invention relates to a negative electrode active material for a rechargeable lithium battery, a method for preparing the same, and a rechargeable lithium battery using the same, and provides a negative electrode active material for a rechargeable lithium battery of a carbon-metal complex or a mixture type, containing a carbon-based active material including a first ceramic coating layer, a metal-based active material or a metal-base active material including a first ceramic coating layer, and a carbon-based active material.Type: ApplicationFiled: November 15, 2013Publication date: January 15, 2015Applicant: POSCO CHEMTECH CO., LTD.Inventors: Kyoung Muk LEE, Heon Young LEE, Mi Ryeong LEE, Eun Byeol HYEONG
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Publication number: 20150010832Abstract: The invention relates to Chevrel-phase materials and methods of preparing these materials utilizing a precursor approach. The Chevrel-phase materials are useful in assembling electrodes, e.g., cathodes, for use in electrochemical cells, such as rechargeable batteries. The Chevrel-phase materials have a general formula of Mo6Z8 and the precursors have a general formula of MxMo6Z8. The cathode containing the Chevrel-phase material in accordance with the invention can be combined with a magnesium-containing anode and an electrolyte.Type: ApplicationFiled: July 8, 2014Publication date: January 8, 2015Applicant: UNIVERSITY OF PITTSBURGH - OF THE COMMONWEALTH SYSTEM OF HIGHER EDUCATIONInventors: Prashant N. Kumta, Partha Saha, Moni Kanchan Datta, Ayyakkannu Manivannan
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Publication number: 20150004471Abstract: Ultrafast battery devices having enhanced reliability and power density are provided. Such batteries can include a cathode including a first silicon substrate having a cathode structured surface, an anode including a second silicon substrate having an anode structured surface positioned adjacent to the cathode such that the cathode structured surface faces the anode structured surface, and an electrolyte disposed between the cathode and the anode. The anode structured surface can be coated with an anodic active material and the cathode structured surface can be coated with a cathodic active material.Type: ApplicationFiled: June 28, 2013Publication date: January 1, 2015Inventors: Zhaohui Chen, Yang Liu, Charles W. Holzwarth, Nicolas Cirigliano, Bum Ki Moon
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Publication number: 20150004487Abstract: Disclosed is an electrode for secondary batteries including an electrode mixture including an electrode active material, binder and conductive material coated on a current collector wherein a conductive material is coated to a thickness of 1 to 80 ?m on the current collector and the electrode mixture is coated on a coating layer of the conductive material so as to improve electrical conductivity.Type: ApplicationFiled: September 18, 2014Publication date: January 1, 2015Applicant: LG Chem, Ltd.Inventors: Min Hee Lee, Tae Jin Park, Daehong Kim