Zinc Oxide Patents (Class 429/231)
  • Patent number: 12155030
    Abstract: One aspect of the present invention is a nonaqueous electrolyte energy storage device including a positive electrode containing manganese-containing positive active material particles in which aluminum is present at least on a surface, and a nonaqueous electrolyte containing a salt represented by the following formula (1). Another aspect of the present invention is a method of producing a nonaqueous electrolyte energy storage device, including producing a positive electrode containing manganese-containing positive active material particles in which aluminum is present at least on a surface, and providing a nonaqueous electrolyte containing a salt represented by the following formula (1): wherein R1 is a hydrogen atom, a halogen atom, or an organic group, Mm+ is an alkali metal cation, an alkaline earth metal cation, or an onium cation. m is an integer equivalent to the number of valence of a cation represented by Mm+. when m is 2 or more, a plurality of R1s are each independently as defined above.
    Type: Grant
    Filed: September 5, 2019
    Date of Patent: November 26, 2024
    Assignee: GS Yuasa International Ltd.
    Inventor: Takashi Okajima
  • Patent number: 12126014
    Abstract: Alkaline electrochemical cells are provided, wherein dissolved zinc oxide or zinc hydroxide is included at least in the free electrolyte solution, and/or solid zinc oxide or zinc hydroxide is included in the anode, so as to slow formation of a zinc oxide passivation layer on a zinc electrode. Methods for preparing such cells are also provided.
    Type: Grant
    Filed: August 12, 2022
    Date of Patent: October 22, 2024
    Assignee: Energizer Brands, LLC
    Inventors: Robert P. Johnson, Robert E. Ray, Jr., Weiwei Huang, Zhufang Liu, Steven J. Limmer
  • Patent number: 12095076
    Abstract: A negative electrode active material for a secondary battery includes a silicate composite particle. The silicate composite particle contains silicate phases, silicon particles dispersed in the silicate phases, and a carbon phase. The silicate phases contain at least one selected from the group consisting of an alkali metal and an alkaline earth metal. At least parts of the carbon phase coat at least parts of surfaces of the silicon particles.
    Type: Grant
    Filed: December 4, 2019
    Date of Patent: September 17, 2024
    Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
    Inventors: Yosuke Sato, Yohei Uchiyama, Taisuke Asano
  • Patent number: 12046749
    Abstract: Provided is a lithium secondary battery with improved t electrochemical characteristics through improvement of the structural stability by including a cathode active material doped with molybdenum (Mo). The lithium secondary battery includes a cathode; an anode; a separator positioned between the cathode and the anode; and an electrolyte. In particular, the cathode active material includes molybdenum (Mo) doped on a composite oxide of lithium and metal including manganese (Mn) and titanium (Ti).
    Type: Grant
    Filed: September 1, 2021
    Date of Patent: July 23, 2024
    Assignees: Hyundai Motor Company, Kia Corporation, Industry Academy Cooperation Foundation of Sejong University
    Inventors: Seung-Min Oh, KiSeok Koh, Yeolmae Yeo, Dongjun Kim, Yoon Sung Lee, Jieun Lee, Sa Heum Kim, Seung-Taek Myung
  • Patent number: 12046746
    Abstract: A lithium metal negative electrode and a lithium metal battery including the lithium metal negative electrode. The lithium metal negative electrode includes a protective layer present on at least one surface of the negative electrode for stabilizing between the lithium metal and the electrolyte. The protective layer includes a polymer of alpha lipoic acid (ALA) and sulfur molecule (S8), a depolymerized product of the polymer, an inorganic sulfide-based compound, and at least one of an inorganic nitride-based compound, or an inorganic nitrate-based compound.
    Type: Grant
    Filed: July 15, 2020
    Date of Patent: July 23, 2024
    Assignees: LG ENERGY SOLUTION, LTD., KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY
    Inventors: Jong Keon Yoon, Yunjung Kim, Hyunwoong Yun, Sunwoo Hwang, Hoejin Hah, Hee-Tak Kim, Youngil Roh
  • Patent number: 12027704
    Abstract: A sulfur-carbon composite and a lithium secondary battery including the same are discussed. More specifically, a network-shaped coating layer including a conductive polymer is formed on a surface of the sulfur-carbon composite, and thus the conductivity of the sulfur-carbon composite is enhanced and also, lithium ions move freely, and accordingly, when applied to lithium secondary batteries, the sulfur-carbon composite can enhance the performance of batteries.
    Type: Grant
    Filed: September 10, 2019
    Date of Patent: July 2, 2024
    Assignee: LG ENERGY SOLUTION, LTD.
    Inventors: Bong Soo Kim, Kwonnam Sohn
  • Patent number: 12009504
    Abstract: According to one embodiment, provided is an electrode including a current collector and an active material-containing layer in contact with the current collector. The active material-containing layer contains a carbon nanotube and particles of titanium-containing oxide having an average particle size or 0.1 ?m to 3 ?m. A peel strength between the current collector and the active material-containing layer is within a range of 0.2 kN/m to 0.7 kN/m.
    Type: Grant
    Filed: February 26, 2021
    Date of Patent: June 11, 2024
    Assignee: KABUSHIKI KAISHA TOSHIBA
    Inventors: Yasunobu Yamashita, Keigo Hoshina, Yasuhiro Harada, Norio Takami, Shinsuke Matsuno
  • Patent number: 11936041
    Abstract: A lithium secondary battery includes a cathode formed from a cathode active material including a first cathode active material particle and a second cathode active material particle, an anode and a separator interposed between the cathode and the anode. The first cathode active material particle includes a lithium metal oxide including a continuous concentration gradient in at least one region between a central portion and a surface portion. The second cathode active material particle includes a lithium metal oxide including elements the same as those of the first cathode active material particle, and the second cathode active material particle has a uniform composition from a central portion to a surface.
    Type: Grant
    Filed: December 14, 2017
    Date of Patent: March 19, 2024
    Assignee: SK ON CO., LTD.
    Inventors: Kook Hyun Han, Kyung Bin Yoo, Duck Chul Hwang
  • Patent number: 11909043
    Abstract: A positive electrode for an all-solid secondary battery including a sulfide-based solid electrolyte includes a first positive active material having an average particle diameter of about 15 ?m to about 20 ?m, a second positive active material having an average particle diameter of about 2 ?m to about 6 ?m, and a solid electrolyte, wherein at least one selected from the first positive active material and the second positive active material includes a coating layer including a lithium ion conductor, and each of the first positive active material and the second positive active material includes a core and a shell, wherein the shell includes a nickel-based active material containing cobalt. An all-solid secondary battery includes the positive electrode.
    Type: Grant
    Filed: March 3, 2021
    Date of Patent: February 20, 2024
    Assignee: Samsung SDI Co., Ltd.
    Inventor: Taeri Kwon
  • Patent number: 11791452
    Abstract: Provided are: a positive electrode for solid-state batteries, which enables the achievement of high energy density, rate characteristics and durability; a solid-state battery; and a method for producing a solid-state battery. A positive electrode for solid-state batteries, which is provided with a collector and a positive electrode active material layer that contains a positive electrode active material, and which is configured such that: the ratio of the positive electrode active material, which is composed of primary particles, in the positive electrode active material layer is 60% by mass or more; the void fraction in the positive electrode active material layer is less than 20% by volume; and portions of the positive electrode active material layer other than the positive electrode active material, which is composed of primary particles, contain a solid electrolyte.
    Type: Grant
    Filed: February 2, 2018
    Date of Patent: October 17, 2023
    Assignee: HONDA MOTOR CO., LTD.
    Inventors: Hiroto Maeyama, Ushio Harada, Noriaki Kamaya, Sokichi Okubo, Toru Sukigara
  • Patent number: 11670763
    Abstract: An electrode material for a lithium ion secondary battery and method of forming the same, the electrode material including composite particles, each composite particle including a primary particle including thermally disproportionated silicon oxide, and an envelope disposed on the surface of the primary particle. The envelope includes turbostratic carbon having a Raman spectrum having: a D band having a peak intensity (ID) at wave number between 1330 cm?1 and 1360 cm?1; a G band having a peak intensity (IG) at wave number between 1530 cm?1 and 1600 cm?1; and a 2D band having a peak intensity (I2D) at wave number between 2650 cm?1 and 2750 cm?1, wherein a ratio of ID/IG ranges from greater than zero to about 1.0, and a ratio of I2D/IG ranges from about 0.4 to about 2.
    Type: Grant
    Filed: November 5, 2020
    Date of Patent: June 6, 2023
    Assignee: NANOGRAF CORPORATION
    Inventors: Cary Hayner, Seonbaek Ha, Kathryn Hicks, Joshua Lau, Christine Frysz
  • Patent number: 11652238
    Abstract: The present invention provides an electrolyte solution for a non-aqueous electrolyte solution battery capable of exhibiting excellent high-temperature cycle characteristics and excellent high-temperature storage characteristics at high temperature of 60° C. or above, and a non-aqueous electrolyte solution battery using the same. The electrolyte solution for a non-aqueous electrolyte solution battery of the present invention comprises at least: a non-aqueous solvent; a solute; at least one first compound represented by the following general formula (1); and at least one second compound represented by the following general formula (2).
    Type: Grant
    Filed: October 13, 2020
    Date of Patent: May 16, 2023
    Assignee: Central Glass Co., Ltd.
    Inventors: Takayoshi Morinaka, Makoto Kubo, Wataru Kawabata, Kenta Yamamoto, Mikihiro Takahashi
  • Patent number: 11594786
    Abstract: An aspect of the present invention achieves a nonaqueous electrolyte secondary battery laminated separator which has excellent heat resistance and exhibits an excellent initial battery characteristic when used in a nonaqueous electrolyte secondary battery. A nonaqueous electrolyte secondary battery laminated separator in accordance with an aspect of the present invention includes: a polyolefin porous film; and a porous layer which (i) is disposed on at least one surface of the polyolefin porous film and (ii) includes a heat resistant filler, the porous layer having a surface which has cracks, a ratio of a total area of the cracks to a surface area of the porous layer being 0.15% to 10%.
    Type: Grant
    Filed: April 15, 2020
    Date of Patent: February 28, 2023
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Shizuka Iwata, Kosuke Kurakane
  • Patent number: 11588150
    Abstract: An electrode material for a lithium ion secondary battery and method of forming the same, the electrode material including composite particles, each composite particle including: a primary particle including an electrochemically active material; and an envelope disposed on the surface of the primary particle. The envelope includes turbostratic carbon having a Raman spectrum having: a D band having a peak intensity (ID) at wave number between 1330 cm?1 and 1360 cm?1; a G band having a peak intensity (IG) at wave number between 1530 cm?1 and 1580 cm?1; and a 2D band having a peak intensity (I2D) at wave number between 2650 cm?1 and 2750 cm?1. In one embodiment, a ratio of ID/IG ranges from greater than zero to about 1.1, and a ratio of I2D/IG ranges from about 0.4 to about 2.
    Type: Grant
    Filed: May 18, 2020
    Date of Patent: February 21, 2023
    Assignee: NANOGRAF CORPORATION
    Inventors: Joshua J. Lau, Aaron Yost, James McKinney, Cary Michael Hayner, Jack Cavanaugh, Seonbaek Ha
  • Patent number: 11545664
    Abstract: The present disclosure relates to an anode active material for a lithium secondary battery, a method of manufacturing the anode active material, and a lithium secondary battery including the anode active material. The anode active material includes natural graphite particles configured such that flaky natural graphite fragment particles having uneven (??) surface defects are structured in a cabbage shape or at random and granulated, the surface and the inside of the natural graphite particles including a gap formed between the flaky natural graphite fragment particles, and a coating layer including amorphous or semicrystalline carbon formed on the surface of the flaky natural graphite fragment particles that form the gap and the surface of the natural graphite particles.
    Type: Grant
    Filed: December 11, 2019
    Date of Patent: January 3, 2023
    Assignee: KNU-Industry Cooperation Foundation
    Inventors: Sung Man Lee, Ki Hoon Kim
  • Patent number: 11444281
    Abstract: A nickel-based active material precursor includes a particulate structure including a core portion, an intermediate layer portion on the core portion, and a shell portion on the intermediate layer portion, wherein the intermediate layer portion and the shell portion include primary particles radially arranged on the core portion, and each of the core portion and the intermediate layer portion includes a cation or anion different from that of the shell portion. The cation includes at least one selected from boron (B), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), titanium (Ti), vanadium (V), tungsten (W), chromium (Cr), iron (Fe), copper (Cu), zirconium (Zr), and aluminium (Al), and the anion includes at least one selected from phosphate (PO4), BO2, B4O7, B3O5, and F.
    Type: Grant
    Filed: October 16, 2019
    Date of Patent: September 13, 2022
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Pilsang Yun, Wooyoung Yang, Jangsuk Hyun
  • Patent number: 11394019
    Abstract: There are provided a method capable of producing a large amount of a carbonaceous material for a negative electrode of a non-aqueous electrolyte secondary battery from a carbon precursor impregnated with an alkali metal element or an alkali metal compound, and an apparatus for performing such production. The method for producing a carbonaceous material for a negative electrode of a non-aqueous electrolyte secondary battery includes a heat treatment step of feeding a carbon precursor containing an elemental alkali metal and/or an alkali metal compound, heating the carbon precursor in a temperature range from 1000° C. to 1500° C. in a non-oxidizing gas atmosphere to produce a carbonaceous material, and discharging the carbonaceous material; and an exhaust gas treatment step of contacting a non-oxidizing exhaust gas containing a gas and a flying carbonaceous matter evolved in the heat treatment step with water or an aqueous solution to treat the exhaust gas.
    Type: Grant
    Filed: June 6, 2019
    Date of Patent: July 19, 2022
    Assignees: KUREHA CORPORATION, TSUKISHIMA KIKAI CO., LTD.
    Inventors: Naohiro Sonobe, Mayu Komatsu, Koji Miwa, Kokei Ueno
  • Patent number: 11316142
    Abstract: Methods for fabricating electrodes include coating a current collector with a slurry to form a coated current collector. The slurry includes a dry fraction, including silicon particles, polymeric binders, and one or more types of naturally occurring carbonaceous filaments, and one or more solvents. The coated current collector is heat treated to produce the electrode having a layer of silicon-based host material. The one or more naturally occurring carbonaceous filaments can include animal fibers, chitin, alginate, cellulose, keratin, and chitosan, and can have an average length of 1 ?m to 50 ?m and an average diameter of 1 nm to 500 nm. The dry fraction can include 5 wt. % to 95 wt. % silicon particles, 0.1 wt. % to 15 wt. % polymeric binders, and 1 wt. % to 20 wt. % naturally occurring carbonaceous filaments. The method can include assembling a battery cell by disposing the electrode and a positive electrode in electrolyte.
    Type: Grant
    Filed: September 17, 2019
    Date of Patent: April 26, 2022
    Assignee: GM Global Technology Operations LLC
    Inventors: Meng Jiang, Raghunathan K, Ion C. Halalay, Mark W. Verbrugge
  • Patent number: 11302912
    Abstract: A battery cell having an anode or cathode comprising an acidified metal oxide (“AMO”) material, preferably in monodisperse nanoparticulate form 20 nm or less in size, having a pH<7 when suspended in a 5 wt % aqueous solution and a Hammett function H0>?12, at least on its surface.
    Type: Grant
    Filed: February 3, 2020
    Date of Patent: April 12, 2022
    Assignee: HHeLi, LLC
    Inventors: Paige L. Johnson, Jonathan G. Neff
  • Patent number: 11171331
    Abstract: A method of manufacturing a positive electrode material for lithium ion secondary battery includes the following (?) and (?): (?) a positive electrode active material is prepared; and (?) the positive electrode material for lithium ion secondary battery is manufactured by forming a coat on at least a portion of a surface of the positive electrode active material. The coat is formed to satisfy the following (1) to (3): (1) the coat includes a lithium ion conductor and a ferroelectric substance; (2) the ferroelectric substance is dispersed in the lithium ion conductor; and (3) the lithium ion conductor is interposed at least partially between the positive electrode active material and the ferroelectric substance.
    Type: Grant
    Filed: April 30, 2021
    Date of Patent: November 9, 2021
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Daisuke Horikawa, Ryuta Sugiura
  • Patent number: 11139470
    Abstract: A method of manufacturing a positive electrode material for lithium ion secondary battery includes the following (?) and (?): (?) a positive electrode active material is prepared; and (?) the positive electrode material for lithium ion secondary battery is manufactured by forming a coat on at least a portion of a surface of the positive electrode active material. The coat is formed to satisfy the following (1) to (3): (1) the coat includes a lithium ion conductor and a ferroelectric substance; (2) the ferroelectric substance is dispersed in the lithium ion conductor; and (3) the lithium ion conductor is interposed at least partially between the positive electrode active material and the ferroelectric substance.
    Type: Grant
    Filed: February 15, 2018
    Date of Patent: October 5, 2021
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Daisuke Horikawa, Ryuta Sugiura
  • Patent number: 11081686
    Abstract: This application relates to a metal oxide and a method for preparing the same. Specifically, Co3O4 is selected as a precursor of lithium cobalt oxide, and one or more metal elements M are doped in the particles of Co3O4 to obtain a doped lithium cobalt oxide precursor Co3-xMxO4, where 0<x?0.3. The difference value, measured by a spectrometer of a scanning electron microscope, of the weight percentage of one of M in two identical area regions is E, wherein 0<E?1% (wt. %). A lithium ion battery with lithium cobalt oxide prepared from the precursor as a cathode material shows great cycle stability, high-temperature energy storage performance and safety performance in a high-voltage (equal to or greater than 4.45 V) charging and discharging environment.
    Type: Grant
    Filed: December 12, 2018
    Date of Patent: August 3, 2021
    Assignee: NINGDE AMPEREX TECHNOLOGY LIMITED
    Inventors: Meng Wang, Leimin Xu, Liang Wang, Pengwei Chen
  • Patent number: 10847786
    Abstract: An alkaline dry battery includes a positive electrode, a gel negative electrode, a separator disposed between the positive electrode and the negative electrode, and an alkaline electrolyte solution contained in the positive electrode, the negative electrode, and the separator. The negative electrode contains a negative electrode active material containing zinc and particulate terephthalic acid. The terephthalic acid contained in the negative electrode has an average particle diameter of 25 to 210 ?m.
    Type: Grant
    Filed: July 18, 2017
    Date of Patent: November 24, 2020
    Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
    Inventors: Yasufumi Takahashi, Satoshi Fujiyoshi
  • Patent number: 10141604
    Abstract: A polymer to be used as a binder for sulfur-based cathodes in lithium batteries that includes in its composition electrophilic groups capable of reaction with and entrapment of polysulfide species. Beneficial effects include reductions in capacity loss and ionic resistance gain.
    Type: Grant
    Filed: August 14, 2017
    Date of Patent: November 27, 2018
    Assignee: Seeo, Inc.
    Inventors: Russell Clayton Pratt, Hany Basam Eitouni, Kulandaivelu Sivanandan
  • Patent number: 10020513
    Abstract: There is provided a novel slurry composition for forming a lithium secondary battery electrode which can improve homogeneity of an electrode active material and a conductive assistant even without using an organic solvent and can improve the binding of an electrode active material and a conductive assistant with an electrode collector, and a lithium secondary battery with improved charge/discharge cycle characteristics and battery capacity. A slurry composition for forming a lithium secondary battery electrode, characterized by comprising an electrode active material (A), a conductive assistant (B), and a pulverized cellulose fiber (C) as an aqueous binder, and a lithium secondary battery electrode and a lithium secondary battery which are obtained using the composition, and an aqueous binder used for the composition.
    Type: Grant
    Filed: September 20, 2012
    Date of Patent: July 10, 2018
    Assignees: NISSAN CHEMICAL INDUSTRIES, LTD., IWATE UNIVERSITY
    Inventors: Hisato Hayashi, Masaaki Ozawa, Osamu Uesugi, Yoshihiro Kadoma
  • Patent number: 9997774
    Abstract: A positive electrode active material for a nonaqueous electrolyte secondary battery contains a lithium composite oxide particle as a main component, in which a ratio of Ni to a total number of moles of all metal elements other than Li is greater than 30 mol %. The lithium composite oxide particle includes a secondary particle being aggregation of primary particles having an average particle diameter of 1 ?m or more, and a shell constituted around the secondary particle. A surface layer void is present between the secondary particle and the shell.
    Type: Grant
    Filed: December 10, 2015
    Date of Patent: June 12, 2018
    Assignee: PANASONIC CORPORATION
    Inventor: Hidekazu Hiratsuka
  • Patent number: 9859555
    Abstract: Provided is a positive active material, a positive electrode including the positive active material, a lithium battery, and a manufacturing method of the same. The positive active material includes a core including a lithium nickel composite oxide and a coating layer formed on the core. The coating layer improves structural stability of the positive active material. Accordingly, lifespan properties of a lithium battery including the positive active material may be improved.
    Type: Grant
    Filed: January 26, 2015
    Date of Patent: January 2, 2018
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Jung-Yeon Won, Eun-Young Goh, Jin-Hyon Lee, Ju-Hee Sohn, Jong-Ki Lee, Seung-Wan Kim, Ju-Hyeong Han
  • Patent number: 9172086
    Abstract: A cathode and a lithium battery including the cathode have improved electrical characteristics. The cathode includes a cathode active material composition including a conducting agent, a binder, and a cathode active material, wherein the cathode active material includes a first lithium compound and a second lithium compound, the first lithium compound having an open-circuit voltage greater than an open-circuit voltage of the second lithium compound, and wherein the second lithium compound includes a metal oxide coating layer.
    Type: Grant
    Filed: December 4, 2009
    Date of Patent: October 27, 2015
    Assignee: Samsung SDI Co., Ltd.
    Inventor: Kyu-Sung Park
  • Publication number: 20150140359
    Abstract: In an aspect, a negative active material, a negative electrode and a lithium battery including the negative active material, and a method of manufacturing the negative active material is provided. The negative active material includes a silicon-based active material substrate; a metal oxide nanoparticle disposed on a surface of the silicon-based active material substrate. An initial irreversible capacity of the lithium battery may be decreased and lifespan characteristics may be improved by using the negative active material.
    Type: Application
    Filed: April 25, 2014
    Publication date: May 21, 2015
    Applicant: Samsung SDI Co., Ltd.
    Inventors: Sang-Eun Park, Young-Ugk Kim, Hyun-Ki Park, Chang-Su Shin, Ui-Song Do, Sung-Su Kim
  • Publication number: 20150132651
    Abstract: Provided is a cathode active material including a complex coating layer, which includes M below, formed on a surface of the cathode active material through reaction of a lithium transition metal oxide represented by Formula 1 below with a coating precursor: LixMO2??(1) wherein M is represented by MnaM?1-b, M? is at least one selected from the group consisting of Al, Mg, Ni, Co, Cr, V, Fe, Cu, Zn, Ti and B, 0.95?x?1.5, and 0.5?a?1. The lithium secondary battery including the cathode active material exhibits improved lifespan and rate characteristics due to superior stability.
    Type: Application
    Filed: January 15, 2015
    Publication date: May 14, 2015
    Applicant: LG CHEM, LTD.
    Inventors: Bo Ram Lee, Hye Lim Jeon, Sun Sik Shin, Sangwook Lee, Wang Mo Jung
  • Patent number: 9029003
    Abstract: Disclosed is an electrode assembly of a lithium secondary battery, including an anode plate, a cathode plate, a separator for separating the anode plate and the cathode plate and conducting lithium ions of an electrolyte, and a composite film disposed between the anode plate and the separator and/or between the cathode plate and the separator. The composite film includes 5 to 95 parts by weight of an inorganic clay and 95 to 5 parts by weight of an organic polymer binder.
    Type: Grant
    Filed: March 1, 2012
    Date of Patent: May 12, 2015
    Assignee: Industrial Technology Research Institute
    Inventors: Angelia Sulaiman Lo, Chun-Wei Su, Chyi-Ming Leu, Chih-Jen Yang, Chang-Rung Yang, Jen-Chih Lo, Tzong-Ming Lee, Jing-Pin Pan
  • Publication number: 20150125749
    Abstract: The present invention relates to a novel phosphate based composite anode material, preparation method and uses thereof. Specifically disclosed is a phosphate based composite cell anode material, the material having monoclinic and orthorhombic crystal lattice structures with the chemical formula of A3-xV2-yMY(PO4)3, wherein A is Li+, Na+ or the mixture thereof, M is Mg, Al, Sc, Ti, Cr, Mn, Fe, Co, Ni, Cu, Zn or Nb, 0?x?3.0, 0?y?2.0, and C is the carbon layer. Also disclosed are a preparation method and uses of the composite material. Unlike simple physical mixing, the composite material of the present invention has the advantages of an adjustable electric potential plateau, high reversible capacity, good cycle stability, power consumption early warning and the like.
    Type: Application
    Filed: September 12, 2012
    Publication date: May 7, 2015
    Applicant: Ningbo Institute of Materials & Engineering, Chinese Academy of Sciences
    Inventors: Yuanhao Tang, Chenyun Wang, Deyu Wang, Jun Li
  • Patent number: 9023531
    Abstract: Disclosed is a nonaqueous secondary battery (100) comprising a positive electrode (155) having a positive current collector (151) made of a metal, and a positive electrode active material (153) composed of a lithium-metal complex oxide. The surface of the positive electrode active material (153) is coated with a lithium salt (158) having an average thickness of 20-50 nm.
    Type: Grant
    Filed: October 17, 2008
    Date of Patent: May 5, 2015
    Assignees: Toyota Jidosha Kabushiki Kaisha, Sumitomo Metal Mining Co., Ltd.
    Inventors: Tomoyoshi Ueki, Yutaka Oyama, Takuichi Arai, Kazuhiro Ohkawa, Koichi Yokoyama, Ryuichi Kuzuo, Katsuya Kase, Syuhei Oda
  • Publication number: 20150104706
    Abstract: The disclosure provides a Ni—Mn composite oxalate powder, including a plurality of biwedge octahedron particles represented by the general formula: NiqMnxCoyMzC2O4.nH2O, wherein q+x+y+z=1, 0<q, x<1, 0?y<1, 0?z<0.15, 0?n?5, and M is at least one of Mg, Sr, Ba, Cd, Zn, Al, Ga, B, Zr, Ti, Ca, Ce, Y, Nb, Cr, Fe and V. The above powder may be further calcined with a lithium salt to form a lithium transition metal oxide powder for use as a positive electrode material in lithium ion-batteries.
    Type: Application
    Filed: December 26, 2013
    Publication date: April 16, 2015
    Applicants: NATIONAL TAIWAN UNIVERSITY, INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE
    Inventors: Hung-Chun WU, Yu-Ting CHEN, Nae-Lih WU, Wen-Chin CHEN, Shih-Chieh LIAO, Yih-Chyng WU
  • Publication number: 20150104707
    Abstract: The present disclosure refers to a cathode material composite having improved conductivity, and a cathode and electrochemical device having the cathode material composite. In accordance with one embodiment of the present disclosure, a conductive polymer is positioned on the surface of a shell present in the form of a tetragonal structure in the lithium manganese oxide, thereby enhancing electrical conductivity to be highly involved in reaction around 3V, and providing a conductive path to improve the capacity, life and rate characteristics of an electrochemical device.
    Type: Application
    Filed: December 18, 2014
    Publication date: April 16, 2015
    Applicant: LG Chem, Ltd.
    Inventors: Ji-Hye Park, Song-Taek Oh, Hyeok-Moo Lee
  • Patent number: 9005812
    Abstract: A negative active material, a method of preparing the negative active material and a lithium ion battery comprising the negative active material are provided. The negative active material may comprise: a core (1) composed of a carbon material; and a plurality of composite materials (2) attached to a surface of the core (1), each of which may comprise a first material (21) and a second material (22) coated on the first material (21), in which the first material (21) may be at least one selected from the elements that may form an alloy with lithium, and the second material (22) may be at least one selected from the group consisting of transition metal oxides, transition metal nitrides and transition metal sulfides.
    Type: Grant
    Filed: August 31, 2011
    Date of Patent: April 14, 2015
    Assignee: Shenzhen BYD Auto R&D Company Limited
    Inventors: Yongjun Ma, Pei Tu, Zizhu Guo
  • Publication number: 20150099175
    Abstract: The present invention provides an electrode material in which unevenness in a supporting amount of a carbonaceous film is less when using an electrode-active material having a carbonaceous film on a surface thereof as the electrode material, and which is capable of improving conductivity, and a method for producing the electrode material. The electrode material includes an aggregate formed by aggregating an electrode-active material in which a carbonaceous film is formed on a surface. In the electrode material, an average particle size of the aggregate is 0.5 to 100 ?m, a volume density of the aggregate is 50 to 80 vol % of a volume density in a case in which the aggregate is a solid, and 80% or more of the surface of the electrode-active material is covered with the carbonaceous film. Alternatively, the electrode material includes an aggregate formed by aggregating electrode-active material particles in which a carbonaceous film is formed on a surface.
    Type: Application
    Filed: December 11, 2014
    Publication date: April 9, 2015
    Applicant: SUMITOMO OSAKA CEMENT CO., LTD.
    Inventors: Takao KITAGAWA, Hirofumi YASUMIISHI, Masaru UEHARA
  • Publication number: 20150093641
    Abstract: Provided is a lithium metal compound oxide having a layered structure, which is very excellent as a positive electrode active material of a battery that is mounted on, particularly, an electric vehicle or a hybrid vehicle. Suggested is a lithium metal compound oxide having a layered structure which is expressed by general formula of Li1+xM1?xO2 (M represents metal elements including three elements of Mn, Co, and Ni). In the lithium metal compound oxide having a layered structure, D50 is more than 4 ?m and less than 20 ?m, a ratio of a primary particle area to a secondary particle area of secondary particles having a size corresponding to the D50 (“primary particle area/secondary particle area”) is 0.004 to 0.035, and the minimum value of powder crushing strength that is obtained by crushing a powder using a microcompression tester is more than 70 MPa.
    Type: Application
    Filed: April 16, 2013
    Publication date: April 2, 2015
    Inventors: Tetsuya Mitsumoto, Hitohiko Ide, Shinya Kagei, Yoshimi Hata
  • Publication number: 20150072232
    Abstract: In a lithium-ion secondary battery (100), positive electrode active material particles (610) each include a shell portion (612) made of a layered lithium-transition metal oxide, a hollow portion (614) formed inside the shell portion (612), and a through-hole (616) penetrating through the shell portion (612). A positive electrode active material layer (223) has a density A of 1.80 g/cm3?A?2.35 g/cm3, and a negative electrode active material layer (243) has a density B of 0.95 g/cm3?B?1.25 g/cm3.
    Type: Application
    Filed: March 30, 2012
    Publication date: March 12, 2015
    Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventor: Hiroki Nagai
  • Publication number: 20150064556
    Abstract: An electrode for a rechargeable battery and a rechargeable battery, the electrode including a current collector; an electrode active material layer; and an electrolyte solution impregnation layer, wherein the electrolyte solution impregnation layer includes a metal oxide and a conductive material.
    Type: Application
    Filed: January 17, 2014
    Publication date: March 5, 2015
    Applicant: SAMSUNG SDI CO., LTD.
    Inventors: Jin-Hyon LEE, Ju-Hee SOHN, Jung-Yeon WON, Eun-Young GOH, Jong-Ki LEE, Sang-In PARK
  • Publication number: 20150064560
    Abstract: An electrode active material including an ordered mesoporous metal oxide; and at least one conductive carbon material disposed in a pore of the ordered mesoporous metal oxide. Also, an electrode including the electrode active material, and a lithium battery including the electrode.
    Type: Application
    Filed: August 25, 2014
    Publication date: March 5, 2015
    Inventors: Jeongkuk SHON, Jaeman CHOI, Junhwan KU, Kuntae KWON, Moonseok KWON, Minsang SONG, Seungsik HWANG, Jiman KIM, Gwiok PARK
  • Publication number: 20150044564
    Abstract: The present invention provides an anode electrode of a lithium-ion battery, comprising an anode active material-coated graphene sheet, wherein the graphene sheet has two opposed parallel surfaces and at least 50% area of one of the surfaces is coated with an anode active material and wherein the graphene material is in an amount of from 0.1% to 99.5% by weight and the anode active material is in an amount of at least 0.5% by weight (preferably at least 60%), all based on the total weight of the graphene material and the anode active material combined.
    Type: Application
    Filed: August 8, 2013
    Publication date: February 12, 2015
    Inventors: Yanbo Wang, Bor Z. Jang, Hui He, Aruna Zhamu
  • Publication number: 20150044565
    Abstract: The present invention provides a process for producing a graphene-enhanced anode active material for use in a lithium battery. The process comprises (a) providing a continuous film of a graphene material into a deposition zone; (b) introducing vapor or atoms of a precursor anode active material into the deposition zone, allowing the vapor or atoms to deposit onto a surface of the graphene material film to form a sheet of an anode active material-coated graphene material; and (c) mechanically breaking this sheet into multiple pieces of anode active material-coated graphene; wherein the graphene material is in an amount of from 0.1% to 99.5% by weight and the anode active material is in an amount of at least 0.5% by weight, all based on the total weight of the graphene material and the anode active material combined.
    Type: Application
    Filed: August 8, 2013
    Publication date: February 12, 2015
    Inventors: Yanbo Wang, Bor Z. Jang, Hui He, Aruna Zhamu
  • Patent number: 8940430
    Abstract: A nickel zinc battery cell includes a metallic zinc-based current collection substrate as a part of the negative electrode. The metallic zinc-based current collector may be made of or be coated with a zinc metal or zinc alloy material and may be a foil, perforated, or expanded material. Battery cells incorporating the zinc-based current collector exhibit good cycle lifetime and initial charge performance.
    Type: Grant
    Filed: February 8, 2008
    Date of Patent: January 27, 2015
    Assignee: PowerGenix Systems, Inc.
    Inventors: Jeffrey Phillips, Samaresh Mohanta, Zhen Gang Fan, Ru Jun Ma, Feng Feng, Lou Uzel, Chi Yau, Jason Zhao, Zeiad M. Muntasser
  • Publication number: 20150024280
    Abstract: In a battery production process, a positive electrode active material having a reaction-suppressing layer that does not easily peel off formed on the surface thereof, and a positive electrode and an all-solid-state battery that use said material are provided. The present invention involves positive electrode active material particles for an all-solid-state battery containing sulfide-based solid electrolyte. The positive electrode active material particles are an aggregate containing two or more particles. The surface of the aggregate is coated with a reaction-suppressing layer for suppressing reactions with the sulfide-based solid electrolyte.
    Type: Application
    Filed: May 23, 2011
    Publication date: January 22, 2015
    Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventor: Takayuki Uchiyama
  • Patent number: 8936874
    Abstract: This invention provides a nanocomposite-based lithium battery electrode comprising: (a) A porous aggregate of electrically conductive nano-filaments that are substantially interconnected, intersected, physically contacted, or chemically bonded to form a three-dimensional network of electron-conducting paths, wherein the nano-filaments have a diameter or thickness less than 1 ?m (preferably less than 500 nm); and (b) Sub-micron or nanometer-scale electro-active particles that are bonded to a surface of the nano-filaments with a conductive binder material, wherein the particles comprise an electro-active material capable of absorbing and desorbing lithium ions and wherein the electro-active material content is no less than 25% by weight based on the total weight of the particles, the binder material, and the filaments. Preferably, these electro-active particles are coated with a thin carbon layer. This electrode can be an anode or a cathode.
    Type: Grant
    Filed: June 4, 2008
    Date of Patent: January 20, 2015
    Assignee: Nanotek Instruments, Inc.
    Inventors: Jinjun Shi, Aruna Zhamu, Bor Z. Jang
  • Publication number: 20150017527
    Abstract: The present invention relates to a negative electrode active material for a rechargeable lithium battery, a method for preparing the same, and a rechargeable lithium battery using the same, and provides a negative electrode active material for a rechargeable lithium battery of a carbon-metal complex or a mixture type, containing a carbon-based active material including a first ceramic coating layer, a metal-based active material or a metal-base active material including a first ceramic coating layer, and a carbon-based active material.
    Type: Application
    Filed: November 15, 2013
    Publication date: January 15, 2015
    Applicant: POSCO CHEMTECH CO., LTD.
    Inventors: Kyoung Muk LEE, Heon Young LEE, Mi Ryeong LEE, Eun Byeol HYEONG
  • Publication number: 20150010832
    Abstract: The invention relates to Chevrel-phase materials and methods of preparing these materials utilizing a precursor approach. The Chevrel-phase materials are useful in assembling electrodes, e.g., cathodes, for use in electrochemical cells, such as rechargeable batteries. The Chevrel-phase materials have a general formula of Mo6Z8 and the precursors have a general formula of MxMo6Z8. The cathode containing the Chevrel-phase material in accordance with the invention can be combined with a magnesium-containing anode and an electrolyte.
    Type: Application
    Filed: July 8, 2014
    Publication date: January 8, 2015
    Applicant: UNIVERSITY OF PITTSBURGH - OF THE COMMONWEALTH SYSTEM OF HIGHER EDUCATION
    Inventors: Prashant N. Kumta, Partha Saha, Moni Kanchan Datta, Ayyakkannu Manivannan
  • Publication number: 20150004471
    Abstract: Ultrafast battery devices having enhanced reliability and power density are provided. Such batteries can include a cathode including a first silicon substrate having a cathode structured surface, an anode including a second silicon substrate having an anode structured surface positioned adjacent to the cathode such that the cathode structured surface faces the anode structured surface, and an electrolyte disposed between the cathode and the anode. The anode structured surface can be coated with an anodic active material and the cathode structured surface can be coated with a cathodic active material.
    Type: Application
    Filed: June 28, 2013
    Publication date: January 1, 2015
    Inventors: Zhaohui Chen, Yang Liu, Charles W. Holzwarth, Nicolas Cirigliano, Bum Ki Moon
  • Publication number: 20150004487
    Abstract: Disclosed is an electrode for secondary batteries including an electrode mixture including an electrode active material, binder and conductive material coated on a current collector wherein a conductive material is coated to a thickness of 1 to 80 ?m on the current collector and the electrode mixture is coated on a coating layer of the conductive material so as to improve electrical conductivity.
    Type: Application
    Filed: September 18, 2014
    Publication date: January 1, 2015
    Applicant: LG Chem, Ltd.
    Inventors: Min Hee Lee, Tae Jin Park, Daehong Kim