Abstract: According to the invention there is a particle including a plurality of stacked sub-structures, each sub-structure including a stack of graphene layers, in which the separation between successive stacked sub-structures is greater than the separation between successive graphene layers in each sub-structure.

Abstract: A negative electrode includes an active material. The active material includes a silicon-based core and a two-dimensional, layered mesoporous carbon coating in continuous contact with the silicon-based core. The two-dimensional, layered mesoporous carbon coating is capable of expanding and contracting with the silicon-based core. The negative electrode also includes a binder.

Abstract: Disclosed is a lithium secondary battery, including a cathode, an anode and a non-aqueous electrolyte, wherein the cathode includes a cathode active material containing lithium-metal oxide of which at least one of metals has a concentration gradient region between a core part and a surface part thereof, and the anode includes hard carbon having an average lattice distance (d002) in the range of 3.6 to 3.8 ? and graphite having-an average lattice distance (d002) in the range of 3.356 to 3.360 ?, such that output and high-temperature storage properties may be improved.

Abstract: A composite anode active material including: a silicon material and a coating layer formed on at least a portion of a surface of the silicon material, wherein the coating layer is chemically bonded to the silicon material, and wherein the coating layer includes a hydrosilylation product of a C4-C30 alkene having a terminal —C(?O)OR group, wherein R is a hydrogen, a C1-C5 alkyl group, a C2-C6 heteroalkyl group, a C6-C12 aryl group, or a C7-C13 arylalkyl group, each of which except hydrogen is substituted or unsubstituted.

Abstract: The invention provides nonaqueous electrolyte secondary batteries having excellent output characteristics during large-current charging and discharging. A nonaqueous electrolyte secondary battery according to one aspect of the invention includes a positive electrode including a lithium transition metal oxide, a negative electrode including a negative electrode active material capable of storing and releasing lithium ions, and a nonaqueous electrolyte, the negative electrode active material including a carbon material as a main component, the negative electrode including a tungsten compound and/or a molybdenum compound. The tungsten compound and/or the molybdenum compound is preferably attached to the surface of the carbon material.

Abstract: A silicon-containing negative active material may include a silicon particle and a coating layer surrounding the silicon particle, and the coating layer may include carbon and a metallic particle.

Abstract: The purpose of the present invention is to provide: a composite active material for lithium secondary batteries, which is capable of providing a lithium secondary battery that has large charge and discharge capacity, high-rate charge and discharge characteristics and good cycle characteristics at the same time; and a method for producing the composite active material for lithium secondary batteries.

Abstract: A sulfur-carbon composite in which sulfur is combined with porous carbon is provided. In the sulfur-carbon composite, a mass loss ratio X at 500° C. in thermal mass analysis and a mass ratio Y of sulfur/(sulfur+carbon) in an observation visual field at a magnification of 1000 in SEM-EDS quantitative analysis satisfy the relationship of |X/Y?1|?0.12, and porous carbon has a mean pore diameter of 1 to 6 nm, and a specific surface area of 2000 m2g?1 or more and 3000 m2g?1 or less.

Abstract: A negative electrode material for a lithium ion battery containing a composite material, the composite material including silicon-containing particles, graphitic carbon material particles, and a carbonaceous carbon material, in which the composite material has a ratio (A/B) of an area (A) of a peak near 100 eV derived from metal Si to an area (B) of a peak near 103 eV derived from silicon oxide, as measured by XPS, of not less than 0.10 and not more than 2.30. Also disclosed is a paste including the negative electrode material, as well as a negative electrode for a lithium ion battery including a formed body of the paste and a lithium ion battery including the negative electrode.

Abstract: A graphene deposition process. The process includes the steps of placing a substrate into a deposition chamber and heating the chamber, generating radio frequency plasma at a location proximate to the substrate while flowing a precursor gas containing carbon through the plasma and over the substrate.

Abstract: An energy storage device can include a cathode, an anode, and a separator between the cathode and the anode, where the anode comprises a first lithium ion intercalating carbon component and a second lithium ion intercalating carbon component. The first lithium ion intercalating carbon component can include hard carbon, and the second lithium ion intercalating component can include graphite or soft carbon. A ratio of the hard carbon to the graphite or of the hard carbon to the soft carbon can be between 1:19 to 19:1. The anode may comprise a first lithium ion intercalating carbon component, a second lithium ion intercalating carbon component and a third lithium ion intercalating carbon component. The first lithium ion intercalating carbon component can include hard carbon, the second lithium ion intercalating carbon component can include soft carbon, and the third lithium ion intercalating carbon component can include graphite.

Abstract: A method for in-situ measuring electrical properties of carbon nanotubes includes placing a first electrode in a chamber, wherein the first electrode defines a cavity. A growth substrate is suspend inside of the cavity, and a catalyst layer is located on the growth substrate. A measuring meter having a first terminal and a second terminal opposite to the first terminal is provided. The first terminal is electrically connected to the first electrode, and the second terminal is electrically connected to the growth substrate. A carbon source gas, a protective gas, and hydrogen are supplied to the cavity, to grow the carbon nanotubes on the catalyst layer. The electrical properties of the carbon nanotubes are obtained by the measuring meter.

Abstract: A nonaqueous electrolyte secondary battery is provided with a wound electrode assembly (40), a battery case (20) housing the wound electrode assembly (40), and a nonaqueous electrolyte solution (80) contained in the battery case (20). The nonaqueous electrolyte solution (80) includes an internal electrolyte solution and an external electrolyte solution. The internal electrolyte solution is contained in the interior of the wound electrode assembly (40). The external electrolyte solution (80a) is collected at the bottom of the battery case (20). The viscosity of the internal electrolyte solution is greater than the viscosity of the external electrolyte solution (80a).

Abstract: Disclosed herein are a preparation method of graphene, capable of easily preparing a graphene flake having a smaller thickness and a large area, and a dispersed composition of graphene obtained using the same. The preparation method of graphene includes applying a physical force to dispersion of a carbon-based material including graphite or a derivative thereof, and a dispersant, wherein the dispersant includes a mixture of plural kinds of polyaromatic hydrocarbon oxides, containing the polyaromatic hydrocarbon oxides having a molecular weight of 300 to 1000 in a content of 60% by weight or more, and the graphite or the derivative thereof is formed into a graphene flake having a thickness in nanoscale under application of a physical force.

Abstract: Capsules comprising crumpled graphene sheets that form a crumpled graphene shell encapsulating an internal cargo comprising nanostructures of a second component are provided. Also provided are anode materials for lithium ion batteries comprising the capsules, wherein the nanostructures are composed of an electrochemically active material, such as silicon.

Abstract: A negative active material for a rechargeable lithium battery, including crystalline carbon-based material particles, for which a maximum volume % in a graph of a particle size distribution on a volume basis is about 20 volume % or more.

Abstract: A negative electrode material for a lithium-ion secondary battery, in which the negative electrode material includes a composite particle including a spherical graphite particle and plural graphite particles that have a compressed shape and that aggregate or are combined so as to have nonparallel orientation planes, and the negative electrode material has an R-value in a Raman measurement of from 0.03 to 0.10, and has a pore volume as obtained by mercury porosimetry of from 0.2 mL/g to 1.0 mL/g in a pore diameter range of from 0.1 ?m to 8 ?m.

Abstract: An electrode has a first set of stripes of a graphite-containing material, and a second set of stripes of silicon-containing material interdigitated with the first set of stripes. A method of manufacturing an electrode includes extruding first and second materials simultaneously onto a substrate in interdigitated stripes, wherein the first material comprises a graphite-containing material and the second material comprises a silicon-containing material.

Abstract: Silicon particles for active materials and electro-chemical cells are provided. The active materials comprising silicon particles described herein can be utilized as an electrode material for a battery. In certain embodiments, the composite material includes greater than 0% and less than about 90% by weight of silicon particles. The silicon particles have an average particle size between about 0.1 ?m and about 30 ?m and a surface including nanometer-sized features. The composite material also includes greater than 0% and less than about 90% by weight of one or more types of carbon phases. At least one of the one or more types of carbon phases is a substantially continuous phase.

Abstract: Electrolytes, anodes, lithium ion cells and methods are provided for preventing lithium metallization in lithium ion batteries to enhance their safety. Electrolytes comprise up to 20% ionic liquid additives which form a mobile solid electrolyte interface during charging of the cell and prevent lithium metallization and electrolyte decomposition on the anode while maintaining the lithium ion mobility at a level which enables fast charging of the batteries. Anodes are typically metalloid-based, for example include silicon, germanium, tin and/or aluminum. A surface layer on the anode bonds, at least some of the ionic liquid additive to form an immobilized layer that provides further protection at the interface between the anode and the electrolyte, prevents metallization of lithium on the former and decomposition of the latter.

Abstract: A rechargeable lithium battery that includes: a negative electrode including a negative active material, and a positive electrode including a positive active material and activated carbon. When the positive active material includes a lithium iron phosphate-based compound, the average particle diameter of the activated carbon is greater than or equal to about 1000% and less than or equal to about 3000% of the average particle diameter of the positive active material.

Abstract: The present invention relates to an artificial graphite material for a negative electrode of a lithium ion secondary battery which shows smaller deteriorations of the capacity of charging and discharging cycles and which has a reduced internal resistance and a high output characteristic. It is an artificial graphite material for a lithium ion secondary battery negative electrode, wherein the size L(112) of a crystallite in the c-axis direction is 5 to 25 nm; the ratio (ID/IG) of the intensities of peaks is 0.05 to 0.2; and the relative absorption intensity ratio (I4.8 K/I280 K) is 5.0 to 12.0.

Abstract: A rechargeable lithium battery that includes: a negative electrode including a negative active material, and a positive electrode including a positive active material and activated carbon. When the positive active material includes a lithium iron phosphate-based compound, the average particle diameter of the activated carbon is greater than or equal to about 1000% and less than or equal to about 3000% of the average particle diameter of the positive active material.

Abstract: Provided are an anode including spherical natural graphite having a surface coated with an amorphous carbon layer, wherein a crystal orientation ratio is in a range of 0.06 to 0.08 at a compressed density of 1.40 g/cc to 1.85 g/cc, and a lithium secondary battery including the anode. Initial efficiency, electrode adhesion, and capacity characteristics of the lithium secondary battery may be improved by using the anode of the present invention in the lithium secondary battery.

Abstract: The present invention provides an anode electrode of a lithium-ion battery, comprising an anode active material-coated graphene sheet, wherein the graphene sheet has two opposed parallel surfaces and at least 50% area of one of the surfaces is coated with an anode active material and wherein the graphene material is in an amount of from 0.1% to 99.5% by weight and the anode active material is in an amount of at least 0.5% by weight (preferably at least 60%), all based on the total weight of the graphene material and the anode active material combined.

Abstract: A catalyst carrier, an electrode catalyst, an electrode including the catalyst, a membrane electrode assembly including the electrode, and a fuel cell including the membrane electrode assembly. The catalyst carrier includes a carbon material having a chain structure including a chain of carbon particles, and an oxide-carbon composite particle in which a carbon particle encloses a particle of an oxide of a group IV element on the periodic table, the oxide-carbon composite particle being contained in the carbon material. The catalyst carrier has a BET specific surface area of 450 to 1100 m2/g.

Abstract: This lithium ion capacitor results from housing an electrode laminate body, which comprises a positive electrode, a negative electrode, and a separator, and a non-aqueous electrolyte, which contains a lithium-ion-containing electrolyte, in an external body, wherein the negative electrode has a negative electrode current collector and a negative electrode active material layer containing a negative electrode active material that can occlude and release lithium ions on one or both surfaces of the negative electrode current collector, and the following (i) to (iii) are all satisfied: (i) the negative electrode active material is a carbon composite material containing carbon black and a carbonaceous material; (ii) the negative electrode is doped with lithium ion at between 1,050 mAh/g and 2,500 mAh/g, inclusive, per unit mass of the negative electrode active material; and (iii) the thickness of the negative electrode active material layer is between 10 ?m and 60 ?m, inclusive, per side.

Abstract: An energy storage device includes a positive electrode and a negative electrode. The negative electrode includes graphite and non-graphitizable carbon, and a D50 particle size of the graphite at which a cumulative volume in a particle size distribution of a particle size reaches 50% is 2 ?m or more. A ratio of a mass of the non-graphitizable carbon to a total amount of a mass of the graphite and a mass of the non-graphitizable carbon is 5% by mass or more and 45% by mass or less and a ratio of the D50 particle size of the graphite to a D50 particle size of the non-graphitizable carbon is 1.02 or less.

Abstract: An electrode structure includes a rolled graphene film which is wound about a central axis, and a nanomaterial dispersed on a surface of the rolled graphene film.

Abstract: A battery includes electrodes including a positive electrode and a negative electrode; and a particle-containing insulating part that is provided between the positive electrode and the negative electrode and includes particles and a resin, wherein the particles are a material capable of undergoing an endothermic dehydration reaction and have a flat shape with an aspect ratio of 2/1 or more.

Abstract: Provided is an anode for a secondary battery including: a first anode active material; and a second anode active material having relatively lower hardness than that of the first anode active material. The first anode active material and the second anode active material satisfy Relational Formula 1 0.167<RB/RA<1, and have a volume ratio of 1:0.5˜2. In Relational Formula 1, RA is an average particle size of the first anode active material, and RB is an average particle size of the second anode active material.

Abstract: Provided are a porous silicon-based particle including a silicon (Si) or SiOx(0<x<2) particle, wherein the particle includes a plurality of nonlinear pores, and the nonlinear pores are formed as open pores in a surface of the particle, and a method of preparing the porous silicon-based particles. Porous silicon-based particles according to an embodiment of the present invention may be more easily dispersed in an anode active material slurry, may minimize side reactions with an electrolyte, and may reduce volume expansion during charge and discharge. Also, according to an embodiment of the present invention, the shape, form, and size of pores formed in the porous silicon-based particle may be controlled by adjusting the type of a metal catalyst, the concentration of the catalyst, and etching time.

Abstract: In an aspect, a negative active material for a rechargeable lithium battery that includes a silicon-based active material including a core including carbon and SiOx particles (0.5?x?1.5); and a coating layer surrounding the core, and a negative electrode and a rechargeable lithium battery including the same are provided.

Abstract: An electrode composite material is disclosed in the invention. The electrode composite material comprises ABxCyDz, wherein A is selected from at least one of polypyrrole, polyacrylonitrile, and polyacrylonitrile copolymer; B comprises sulfur; C is selected from carbon material; D is selected from metal oxides, l?x?20, 0?y<l, and 0?z<1. Comparing to the prior art, the conductivity of the electrode composite material is obviously increased, the material is dispersed uniformly and the size of the material is small. The electrochemical performance of the electrode composite material is improved. It has a good cycle life and high discharging capacity efficiency. A method for manufacturing the electrode composite material, a positive electrode using the electrode composite material and a battery including the same are also disclosed in the invention.

Abstract: In an aspect, a rechargeable lithium battery that includes a positive electrode including a composite positive active material; a negative electrode including a carbon-based negative active material; an electrolyte including an additive, and a lithium salt and an organic solvent, wherein a passivation film may be on a surface of the negative electrode of the rechargeable lithium battery.

Abstract: The present invention relates to a negative electrode material for nonaqueous electrolyte secondary batteries, which is composed of a silicon composite body that has a structure wherein microcrystals or fine particles of silicon are dispersed in a substance having a composition different from that of the microcrystals or fine particles, said silicon composite body having a crystallite size of the microcrystals or fine particles of 8.0 nm or less as calculated using Scherrer's equation on the basis of the half width of the diffraction peak belonging to Si(220) in an X-ray diffraction. The present invention is able to provide a negative electrode material for nonaqueous electrolyte secondary batteries, which has excellent coulombic efficiency, and a nonaqueous electrolyte secondary battery.

Abstract: In an aspect, a positive active material for a rechargeable lithium battery including: a compound that reversibly intercalates and deintercalates lithium; and a coating layer coating the compound and including a metal nitrate is disclosed. Since the positive active material is structurally stable during the charge and discharge, the obtained battery may have excellent battery capacity and cycle-life characteristics and also have high power.

Abstract: A battery is provided including a positive electrode; a negative electrode including a first negative electrode active material; and an electrolytic solution, wherein the first negative electrode active material includes a core portion having a core portion surface, wherein the core portion has a median diameter of 0.3 ?m to 20 ?m, and a covering portion that covers at least part of the core portion surface, wherein the covering portion comprises at least Si, O and at least of one element M1 selected from Li, carbon (C), Mg, Al, Ca, Ti, Cr, Mn, Fe, Co, Ni, Cu, Ge, Zr, Mo, Ag, Sn, Ba, W, Ta, Na, and K.

Abstract: The present invention provides a negative electrode material for a lithium-ion secondary battery, the negative electrode material comprising silicon active material particles containing silicon and nitrogen, the silicon active material particles being capable of occluding and emitting lithium ions, wherein an amount of the nitrogen contained in each silicon active material particle is in the range from 100 ppm to 50,000 ppm, a negative electrode and lithium-ion secondary battery using the material, and a method of producing the material. The negative electrode material is suitable for a lithium-ion secondary battery negative electrode that has high first charge and discharge efficiency and excellent cycle performance and makes the best use of high battery capacity and low volume expansion rate of a silicon material such as a silicon oxide material.

Abstract: An improved electrolyte including a strontium additive suitable for lithium-sulfur batteries, a battery including the electrolyte, and a battery including a separator containing a strontium additive are disclosed. The presence of the strontium additive reduces sulfur-containing deposits on the battery anode, thereby providing a battery with relatively high energy density and good partial discharge performance.

Abstract: Provided are a cathode active material for a lithium secondary battery, a method of fabricating the same, and a lithium secondary battery including the same. The cathode active material includes a lithium composite transition metal oxide represented by Li1+(c-a)/2NiaCobMncO2-xFx (0.1?c?a?0.4, 0.13?a?0.3, 0.03?b?0.2, 0.4?c?0.6, (a+b+c)+(1+(c?a)/2)=2, 0<x?0.15, 1?a/b?6, 1.9?c/a?4.0, and 0.04?b/(a+b+c)?0.25), and layer-structured Li2MnO3. Since the lithium secondary battery including the cathode active material has a large capacity and generates less gas, lifespan characteristics and high rate capability are significantly improved, and especially voltage variation during charging and discharging operations is small.

Abstract: Disclosed here is a method for producing a graphene macro-assembly (GMA)-fullerene composite, comprising providing a GMA comprising a three-dimensional network of graphene sheets crosslinked by covalent carbon bonds, and incorporating at least 20 wt. % of at least one fullerene compound into the GMA based on the initial weight of the GMA to obtain a GMA-fullerene composite. Also described are a GMA-fullerene composite produced, an electrode comprising the GMA-fullerene composite, and a supercapacitor comprising the electrode and optionally an organic or ionic liquid electrolyte in contact with the electrode.

Abstract: The positive active material for a rechargeable lithium battery includes a composite material of a microporous carbon-based material and a lithium composite compound and a carbon layer on the surface of the composite material.

Abstract: Disclosed is an anode active material for lithium secondary batteries that includes natural graphite particles consisting of spherical particles of agglomerated graphite sheets, outer surfaces of which are not coated with a carbon-based material, wherein the surfaces of the particles have a degree of amorphization of at least 0.3 within a range within which an R value [R=I1350/I1580] (I1350 is the intensity of Raman around 1350 cm?1 and I1580 is the intensity of Raman around 1580 cm?1) of a Raman spectrum is in the range of 0.30 to 1.0.

Abstract: Provided are a porous silicon-based anode active material including crystalline silicon (Si) particles, and a plurality of pores on surfaces, or the surfaces and inside of the crystalline silicon particles, wherein at least one plane of crystal planes of at least a portion of the plurality of pores includes a (100) plane, and a method of preparing the porous silicon-based anode active material. Since a porous silicon-based anode active material of the present invention may allow volume expansion, which is occurred during charge and discharge of a lithium secondary battery, to be concentrated on pores instead of the outside of the anode active material, the porous silicon-based anode active material may improve life characteristics of the lithium secondary battery by efficiently controlling the volume expansion.

Abstract: In the graphene manufacturing method, a graphite oxide is formed from graphite, and then the graphite oxide is treated with a hydrochloric acid. The hydrochloric acid-treated graphite oxide is reduced at temperature of 120° C. or above and 200° C. or below by performing thermal treatment thereto. Since a low-temperature process is used for manufacturing graphene by performing thermal treatment at a relatively low temperature for a short time, this method has great economic feasibility and utilization. Due to a simple composing process and low thermal treatment temperature, graphene may be mass-produced with a low price. In particular, the graphene may be used as a cathode material for a lithium secondary battery, which exhibits a high capacity at a high voltage of 2V or above by reacting with Li, different from an anode material of a lithium secondary battery.

Abstract: A nonaqueous electrolyte secondary battery includes a positive electrode, a negative electrode, and a separator disposed between the positive electrode and the negative electrode. The separator includes a substrate layer and a surface layer formed on at least one principal plane of the substrate layer, the surface layer contains polyvinylidene fluoride and an inorganic material particle, and an amount of deformation against pressure of the surface layer is larger than that of the substrate layer.

Abstract: In an example of the method disclosed herein, a precipitate is formed in an aqueous mixture by mixing an SiOx precursor and an acid. The precipitate and a carbon material are added to a base, and the precipitate dissolves to form a solution having the carbon material therein. Hydrothermal synthesis is performed using the solution, and precursor nanostructures are grown on the carbon material. The precursor nanostructures on the carbon material are annealed so that the carbon material is removed and porous, one-dimensional SiOx (0<x?2) nanorods are formed.

Abstract: An electrode comprises a current collector and a multi-layer active material formed on the current collector. The multi-layer active material includes at least one active composite unit having a first layer consisting essentially of a first carbon material having electrochemical activity and a binder and a second layer formed on the first layer comprising a high energy density material. A top layer is formed on the active composite unit consisting essentially of a second carbon material having electrochemical activity and a binder. The electrode provides even current distribution and compensates for particle volume expansion.

Abstract: Provided is an electrocatalyst for solid polymer fuel cells capable of increasing the active surface area for reactions in a catalyst component, increasing the utilization efficiency of the catalyst, and reducing the amount of expensive precious metal catalyst used. Also provided are a membrane electrode assembly that uses this electrocatalyst and a solid polymer fuel cell. An electrocatalyst for a solid polymer fuel cell is provided with a catalyst and solid proton conducting material. A liquid conductive material retention part that retains a liquid proton conducting material that connects the catalyst and solid proton conducting material is provided between the same. The surface area of the catalyst exposed within the liquid conductive material retention part is larger than the surface area of the catalyst in contact with the solid proton conducting material.