Having Inorganic Binder Or Conductive Filler Patents (Class 429/232)
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Patent number: 8715856Abstract: Disclosed is a secondary battery including a cathode, an anode, a membrane and an electrolyte, wherein the cathode contains a mixture of a first cathode material defined herein and a second cathode material selected from the group consisting of a second-(a) cathode material defined herein and a second-(b) cathode material defined herein, and a combination thereof, wherein a mix ratio of the two cathode materials (first cathode material: second cathode material) is 50:50 to 90:10, and the membrane is an organic/inorganic composite porous membrane including (a) a polyolefin-based membrane substrate and (b) an active layer in which one or more areas selected from the group consisting of the surface of the substrate and a portion of pores of the substrate are coated with a mixture of inorganic particles and a binder polymer, wherein the active layer has a structure in which the inorganic particles are interconnected and fixed through a binder polymer and porous structures are formed by the interstitial volume betType: GrantFiled: September 1, 2011Date of Patent: May 6, 2014Assignee: LG Chem, Ltd.Inventors: Seungeun Choi, Eunyoung Goh, Hyang Mok Lee, Heegyoung Kang, Sangbaek Ryu, Kiwoong Kim
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Patent number: 8715539Abstract: The present invention provides a positive electrode material for a lithium secondary battery comprising a compound represented by the following Formula 1: LiMn1-xMxP1-yAsyO4??[Formula 1] wherein 0<x?0.1, 0<y?0.1, and M is at least one metal selected from the group consisting of magnesium (Mg), titanium (Ti), nickel (Ni), cobalt (Co), and iron (Fe). Positive electrode materials of the present invention, when used as a positive electrode material in a lithium secondary battery, provides increased discharge potential of the battery due to its high discharge capacity, excellent cycle characteristics and charge/discharge efficiency, and high discharge potential with respect to lithium.Type: GrantFiled: October 25, 2010Date of Patent: May 6, 2014Assignees: Hyundai Motor Company, Korea Electronics Technology InstituteInventors: Sa Heum Kim, Seung Ho Ahn, Dong Gun Kim, Young Jun Kim, Jun Ho Song
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Patent number: 8710136Abstract: Carbon blacks, such as rubber blacks, having a low PAH concentration are described. Furthermore, elastomeric or rubber compositions containing the carbon black of the present invention are further described, as well as methods of making carbon black having a low PAH concentration.Type: GrantFiled: August 12, 2011Date of Patent: April 29, 2014Assignee: Cabot CorporationInventors: Irina S. Yurovskaya, William L. Sifleet, Steven J. List, Martin C. Green, Anand Prakash
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Publication number: 20140113191Abstract: An electrode material for a secondary battery includes crystal primary particles of an electrode active material which releases or absorbs cations of a monovalent or divalent metal when subjected to electrochemical oxidation or reduction and which has a crystal lattice in which the cations can move only in a one-dimensional movable direction during the process of oxidation or reduction. The electrode material also includes an ion-conductive substance and conductive carbon which coexist on the surface of the primary particles, in which the ion-conductive substance has a property which allows two or three-dimensional movement of the cations, and the cations are movable via a layer in which the ion-conductive substance and the conductive carbon coexist.Type: ApplicationFiled: March 28, 2012Publication date: April 24, 2014Applicants: UNIVERSITY OF HYOGO, MITSUI ENGINEERING & SHIPBUILDING CO., LTD.Inventors: Tatsuya Nakamura, Naoki Hatta, Noriyuki Shimomura, Yusuke Yoshida, Hironari Miyauchi
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Publication number: 20140113175Abstract: A lithium ion battery containing conducting materials comprises a positive electrode, a negative electrode, a separator, an electrolyte, adhesives and sealing materials. The conducting materials in the positive electrode comprise metal carbides, metal borides or metal nitrides. The conducting materials in the negative electrode comprise metal carbides, metal borides or metal nitrides. The metal carbide is titanium carbonitride, tungsten carbide or titanium carbide, vanadium carbide, tantalum carbide, and eutectic of tungsten carbide and titanium carbide. The metal boride is molybdenum boride, tungsten boride or vanadium boride. The metal nitride is titanium nitride, tungsten nitride or tantalum nitride. The conducting materials in the positive electrode may also comprise powdered metals. The conducting materials in the negative electrode comprise powdered metals. The powdered metal is nickel powder, copper powder or chromium powder.Type: ApplicationFiled: June 2, 2011Publication date: April 24, 2014Inventor: Panyi ZHANG
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Patent number: 8703009Abstract: The present invention provides for a lithium ion battery and process for creating such, comprising higher binder to carbon conductor ratios than presently used in the industry. The battery is characterized by much lower interfacial resistances at the anode and cathode as a result of initially mixing a carbon conductor with a binder, then with the active material. Further improvements in cycleability can also be realized by first mixing the carbon conductor with the active material first and then adding the binder.Type: GrantFiled: November 6, 2009Date of Patent: April 22, 2014Assignee: The Regents of the University of CaliforniaInventors: Gao Liu, Vincent S. Battaglia, Honghe Zheng
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Publication number: 20140106232Abstract: A three-dimensional nanobattery formed by individually wiring nanostructured electrodes and combining them with an electrolyte. Short, capped nanotubes termed ‘nanobaskets’ are formed by sputtering coating onto nanoporous templates. Metallic nanowires are grown by electrochemical deposition from the nanobaskets and through the template, making electrical contact with each nanobasket electrode. The same procedure can be used to fabricate both a battery anode and a battery cathode. A thin layer of electrolyte is placed between the two nanobasket electrodes, and electrical contact is made through the nanowires.Type: ApplicationFiled: November 4, 2013Publication date: April 17, 2014Applicant: The University of TulsaInventors: Dale Teeters, Paige Johnson
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Patent number: 8697288Abstract: Lithium ion secondary batteries are described that have high total energy, energy density and specific discharge capacity upon cycling at room temperature and at a moderate discharge rate. The improved batteries are based on high loading of positive electrode materials with high energy capacity. This capability is accomplished through the development of positive electrode active materials with very high specific energy capacity that can be loaded at high density into electrodes without sacrificing performance. The high loading of the positive electrode materials in the batteries are facilitated through using a polymer binder that has an average molecular weight higher than 800,000 atomic mass unit.Type: GrantFiled: May 24, 2012Date of Patent: April 15, 2014Assignee: Envia Systems, Inc.Inventors: James P. Buckley, Sujeet Kumar
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Patent number: 8697286Abstract: An anode active material for lithium batteries, an anode including the anode active material, a method of manufacturing the anode, and a lithium battery including the anode. The anode active material includes secondary particles formed of agglomerated primary nanoparticles. The primary nanoparticles include a non-carbonaceous material bound with hollow carbon nanofibers. The anode includes the anode active material and a polymeric binder having an electron donor group.Type: GrantFiled: October 2, 2009Date of Patent: April 15, 2014Assignee: Samsung Electronics Co., Ltd.Inventors: Jeong-hee Lee, Ho-suk Kang, Jeong-na Heo
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Patent number: 8697280Abstract: An electrode active material, a method of preparing the electrode active material, an electrode including the electrode active material, and a lithium secondary battery including the electrode; the electrode active material comprising a core active material; and a coating layer formed on a surface of the core active material, wherein the coating layer comprises a composition including a compound represented by Formula 1 below and a carbonaceous material, or a first coating layer including a carbonaceous material and a second coating layer including the compound represented by Formula 1 below: LixMy(PO4)z,??Formula 1 where M is selected from the group consisting of alkali metal, alkaline earth metal, a group 13 element, a group 14 element, a transition metal, a rare earth element, and combinations thereof; 1?x?3, 0?y?3, and 1?z?3.Type: GrantFiled: September 23, 2011Date of Patent: April 15, 2014Assignee: Samsung Electronics Co., Ltd.Inventors: Sang-kook Mah, Gue-sung Kim
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Patent number: 8697289Abstract: A battery electrode, includes: a collector; and an active material layer formed on a surface of the collector and including: an active material, and a conductive additive having a bulk density which is gradually decreased in a direction from a collector side of the active material layer to a surface side of the active material layer.Type: GrantFiled: June 18, 2008Date of Patent: April 15, 2014Assignee: Nissan Motor Co., Ltd.Inventors: Chizuru Matsuyama, Takuya Kinoshita, Kyouichi Watanabe, Yoshinori Naruoka
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Patent number: 8685566Abstract: A process to induce polymerization of an organic electronically conductive polymer in the presence of a partially delithiated alkali metal phosphate which acts as the polymerization initiator.Type: GrantFiled: June 1, 2010Date of Patent: April 1, 2014Inventors: Steen Brian Schougaard, Michel Gauthier, Christian Kuss, David Lepage, Guoxian Liang, Christophe Michot
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Patent number: 8679682Abstract: A nonaqueous-electrolyte battery includes a positive electrode, a negative electrode which is constituted of a negative-electrode current collector and a layer containing a negative active material and deposited on one or each side of the negative-electrode current collector and in which the layer contains at least one member selected from lithium carbonate, lithium sulfide, lithium phosphide, and lithium fluoride and further contains a lithium-titanium composite oxide, and a nonaqueous electrolyte.Type: GrantFiled: August 27, 2008Date of Patent: March 25, 2014Assignee: Kabushiki Kaisha ToshibaInventors: Hiroki Inagaki, Norio Takami, Shinsuke Matsuno
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Patent number: 8673496Abstract: An electrode composition containing a first conducting agent and a second conducting agent, an electrode for lithium secondary batteries, a method of manufacturing the electrode, and a lithium secondary battery including the electrode. The second conducting agent is an agglomerate formed of a conducting material and a fluorine-based polymer.Type: GrantFiled: December 30, 2010Date of Patent: March 18, 2014Assignee: Samsung SDI Co., Ltd.Inventors: Chae-Woong Cho, Woon-Suk Jang, Bum-Jin Chang, Ki-Jun Kim, Kwi-Seok Choi
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Publication number: 20140072698Abstract: An electrode for an energy store, in particular for a lithium-ion battery. To achieve a particularly good and long-term stable capacitance, the electrode includes an active material, optionally a binder, optionally a conductive additive, and a sorption agent; intermediate stages of the active material arising during a charging and/or discharging procedure of the energy store may be immobilized by the sorption agent. Furthermore, also described is a method for manufacturing an electrode for an energy store, and the use of a sorption agent for manufacturing an electrode for an electrochemical energy store.Type: ApplicationFiled: September 6, 2013Publication date: March 13, 2014Applicant: ROBERT BOSCH GMBHInventors: Marcus WEGNER, Jens GRIMMINGER, Martin TENZER, Jean FANOUS
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Patent number: 8658316Abstract: An electrode material containing an electrode active material, and a carbonaceous coating film which covers the electrode active material and contains sulfur; and an electrode material including a secondary particle including a plurality of primary particles as the electrode active material, wherein the primary particles are covered with a carbonaceous coating film so that the carbonaceous coating film is interposed between the primary particles and the carbonaceous coating film contains sulfur.Type: GrantFiled: December 10, 2008Date of Patent: February 25, 2014Assignee: Sumitomo Osaka Cement Co., Ltd.Inventors: Takao Kitagawa, Mitsumasa Saito
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Patent number: 8652687Abstract: The present invention provides an electrically conductive electrode comprising particles of an electroactive material and a conductive graphene polymer binder that bonds multiple particles of the electroactive material together, wherein the binder is in an amount of from 0.01% to 90% by weight based on the total electrode weight. Also provided are (a) a precursor solution or suspension to the graphene polymer binder for the electrode; (b) a paste containing electroactive particles and a graphene polymer dispersed in a liquid; (c) a method of producing the electrode from the precursor paste; and (d) an electrochemical cell (a battery or supercapacitor) containing such an electrode.Type: GrantFiled: December 24, 2009Date of Patent: February 18, 2014Assignee: Nanotek Instruments, Inc.Inventors: Aruna Zhamu, Bor Z. Jang
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Patent number: 8652688Abstract: A silicon-based anode comprises an alginate-containing binder. The many carboxy groups of alginate bind to a surface of silicon, creating strong, rigid hydrogen bonds that withstand battery cycling. The alginate-containing binder provides good performance to the anode by (1) improving the capacity of the anode in comparison to other commercially-available binders, (2) improving Columbonic efficiency during charging and discharging cycles, and (3) improving stability during charging and discharging cycles.Type: GrantFiled: September 7, 2011Date of Patent: February 18, 2014Assignees: Clemson University, Georgia Tech Research CorporationInventors: Gleb Yushin, Igor Luzinov, Bogdan Zdyrko, Oleksandr Magazynskyy, Igor Kovalenko
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Patent number: 8652361Abstract: The invention relates to a composite electrode material consisting of a carbon coated complex oxide, fibrous carbon and a binder. Said material is prepared by a method which comprises co-grinding an active electrode material and fibrous carbon, and adding a binder to the co-grinded mixture to lower the viscosity of the mixture. The fibrous carbon is preferably vapor grown carbon fibers.Type: GrantFiled: February 24, 2009Date of Patent: February 18, 2014Assignees: Hydro-Quebec, Showa Denko K.K.Inventors: Karim Zaghib, Chiaki Sotowa, Patrick Charest, Masataka Takeuchi, Abdelbast Guerfi
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Patent number: 8647777Abstract: Disclosed is a mixed material of lithium iron phosphate and carbon, which contains secondary particles as aggregates of lithium iron phosphate primary particles and a fibrous carbon which is present inside the secondary particles. An electrode containing such a mixed material, a battery comprising such an electrode, a method for producing such a mixed material, and a method for producing a battery are also disclosed.Type: GrantFiled: October 13, 2006Date of Patent: February 11, 2014Assignee: GS Yuasa International Ltd.Inventors: Yoshinobu Yasunaga, Tokuo Inamasu, Akihiro Fujii, Toshiyuki Nukuda
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Patent number: 8647778Abstract: A process for preparing an at least partially lithiated transition metal oxyanion-based lithium-ion reversible electrode material, which includes providing a precursor of said lithium-ion reversible electrode material, heating said precursor, melting same at a temperature sufficient to produce a melt including an oxyanion containing liquid phase, cooling said melt under conditions to induce solidification thereof and obtain a solid electrode that is capable of reversible lithium ion deinsertion/insertion cycles for use in a lithium battery. Also, lithiated or partially lithiated oxyanion-based-lithium-ion reversible electrode materials obtained by the aforesaid process.Type: GrantFiled: September 14, 2012Date of Patent: February 11, 2014Inventors: Laurent Gauthier, Michel Gauthier, Donald Lavoie, Christophe Michot, Nathalie Ravet
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Publication number: 20140030603Abstract: An electrode for an electrochemical energy store, in particular a cathode for a lithium-sulfur battery. To obtain a particularly good rate capability, the electrode includes an electrically conductive matrix, in particular having a binder and a conductive additive. Locally delimited active areas are situated in the electrically conductive matrix, and the active areas have an active material, a conductive additive, and a binder. Moreover, an energy store is provided, such as a lithium-sulfur battery in particular, and a method for manufacturing an electrode is also provided.Type: ApplicationFiled: July 29, 2013Publication date: January 30, 2014Applicant: ROBERT BOSCH GMBHInventors: Marcus Wegner, Jean Fanous
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Patent number: 8637191Abstract: The present invention relates to a lithium secondary battery. The present invention provides the lithium secondary battery including a positive electrode, a negative electrode, and a non-aqueous electrolyte solution. The negative electrode includes a water-dispersible binder and a conduction agent. The non-aqueous electrolyte solution includes fluoroethylenecarbonate (FEC). The batteries of the present invention are advantageous in that they have a high efficiency charging lifespan characteristic and enable high capacity charging in a short time.Type: GrantFiled: October 21, 2010Date of Patent: January 28, 2014Assignee: LG Chem, Ltd.Inventors: Kwan Soo Lee, Cha Hun Ku, Duk Hyun Ryu, Jung Jin Kim, Byung Kyu Jung
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Patent number: 8637192Abstract: A nonaqueous electrolytic solution containing magnesium ions which shows excellent electrochemical characteristics and which can be manufactured in a general manufacturing environment such as a dry room, and an electrochemical device using the same are provided. A Mg battery has a positive-electrode can 1, a positive-electrode pellet 2 made of a positive-electrode active material or the like, a positive electrode 11 composed of a metallic net supporting body 3, a negative-electrode cup 4, a negative electrode 12 made of a negative-electrode active material 5, and a separator 6 impregnated with an electrolytic solution 7 and disposed between the positive-electrode pellet and the negative-electrode active material.Type: GrantFiled: June 4, 2009Date of Patent: January 28, 2014Assignee: Sony CorporationInventors: Kenta Yamamoto, Yuri Nakayama, Yui Senda
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Patent number: 8628884Abstract: An anode active material comprises metal core particles, metal nano wires formed on the metal core particles, pores between the metal core particles and the metal nano wires, and a carbon-based coating layer formed on a surface of the metal core particles and metal nano wires. In the anode active material according to the present invention, the metal core particles and metal nano wires are combined to form a single body, and a carbon-based coating layer is formed on the surface of the metal nano wires and metal core particles. Thus, volume changes in the pulverized metal core particles can be effectively buffered during charging and discharging, and the metal core particles are electrically connected through the metal nano wires. As a result, volume changes in the anode active material and degradation of the electrode can be prevented, thereby providing excellent initial charge/discharge efficiency and enhanced charge/discharge capacity.Type: GrantFiled: June 18, 2010Date of Patent: January 14, 2014Assignee: Samsung SDI Co., Ltd.Inventors: Gue-sung Kim, Jin-hwan Park, Yongnam Ham
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Publication number: 20140011092Abstract: An object of the present invention is to provide composite carbon fibers in which multiwalled carbon nanotubes are homogeneously dispersed between graphitized carbon nanofibers and near the surface of the graphitized carbon nanofibers, the composite carbon fibers being capable of easily being dispersed in a matrix such as resin without leaving aggregates, and also imparting low resistance. Disclosed are composite carbon fibers comprising multiwalled carbon nanotubes having a fiber diameter of 5 nm or more and 30 nm or less and graphitized carbon nanofibers having a fiber diameter of 50 nm or more and 300 nm or less, wherein the multiwalled carbon nanotubes are homogeneously dispersed between the graphitized carbon nanofibers and near the surface of the graphitized carbon nanofibers.Type: ApplicationFiled: July 3, 2013Publication date: January 9, 2014Applicant: Showa Denko K.KInventors: Ryuji YAMAMOTO, Takeshi NAKAMURA
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Patent number: 8623554Abstract: An electrode material comprising a particle containing at least one member selected from the particles containing silicon, tin, silicon compound and tin compound, and fibrous carbon. The particle includes: (1) a particle comprising at least one member of a silicon particle, tin particle, particle containing a lithium-ion-intercalatable/releasable silicon compound and particle containing a lithium-ion-intercalatable/releasable tin compound; or (2) a particle comprising a silicon and/or silicon compound-containing carbonaceous material deposited onto at least a portion of the surfaces of a carbon particle having a graphite structure. The lithium secondary battery using the electrode material as a negative electrode has high discharging capacity and is excellent in cycle characteristics and characteristics under a load of large current.Type: GrantFiled: January 15, 2010Date of Patent: January 7, 2014Assignee: Show A Denko K.K.Inventors: Youichi Nanba, Satoshi Iinou, Tsutomu Masuko
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Patent number: 8609282Abstract: An electrode conductive material, an electrode material including the electrode conductive material, an electrode including the electrode material, and a lithium battery including the electrode material. When the electrode conductive material is used, the amount of a conductive material required is decreased, capacity of the lithium battery is improved, and a charge and discharge rate is increased.Type: GrantFiled: November 30, 2010Date of Patent: December 17, 2013Assignee: Samsung SDI Co., Ltd.Inventors: Deok-Hyun Kim, Jae-Myung Kim, Kyu-Nam Joo, So-Ra Lee, Jong-Hee Lee, Young-Su Kim, Gu-Hyun Chung, Beom-Kwon Kim
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Patent number: 8603673Abstract: A nonaqueous electrolyte secondary battery includes a positive electrode; a negative electrode; and a nonaqueous electrolyte, wherein the negative electrode has a negative electrode mixture layer including a negative electrode active material; a polymer containing vinylidene fluoride as a repeating unit; a polymer containing acrylonitrile as a repeating unit; and a vapor-grown carbon fiber; and the nonaqueous electrolyte contains a fluorocarbon based polymer compound.Type: GrantFiled: April 2, 2010Date of Patent: December 10, 2013Assignee: Sony CorporationInventor: Mashio Shibuya
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Publication number: 20130323607Abstract: A secondary electrochemical cell comprises an anode, a cathode including electrochemically active cathode material, a separator between the anode and the cathode, and an electrolyte. The electrolyte comprises at least one salt dissolved in at least one organic solvent. The separator in combination with the electrolyte has an area-specific resistance of less than about 2 ohm-cm2.Type: ApplicationFiled: May 29, 2012Publication date: December 5, 2013Inventors: Nikolai Nikolaevich ISSAEV, Alexander KAPLAN, Junan KAO, Kirakodu Seetharama NANJUNDASWAMY, Michael POZIN, Fan ZHANG
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Publication number: 20130323593Abstract: A rechargeable energy storage unit is proposed. The rechargeable energy storage unit has a first and a second electrode. The first electrode is assigned an energy storage material in the form of metal particles made from at least one metal which can be deoxidized during charging operation of the energy storage unit and can be oxidized during discharging operation of the energy storage unit. The metal particles are incorporated into a matrix-forming carrier material.Type: ApplicationFiled: February 15, 2012Publication date: December 5, 2013Inventors: Ines Becker, Thomas Purucker
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Publication number: 20130316250Abstract: The present invention relates to novel compositions, electrodes, electrochemical storage devices (batteries) and ionic conduction devices that use cubic ionic conductor (“CUBICON”) compounds, preferably nitridophosphate compounds. The cubic ionic conductor compound have a framework formula [MT3X10]n- (1) and a general formula AxMT3X10 (2), where M is a cation in octahedral coordination, T is a cation in tetrahedral coordination, X is an anion, and the framework has a net negative charge of ?n, where a variable number of potentially mobile additional chemical species, A, can fit into the open space within this framework with a net charge of +n.Type: ApplicationFiled: April 30, 2013Publication date: November 28, 2013Applicant: Brookhaven Science Associates, LLCInventor: Brookhaven Science Associates, LLC
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Publication number: 20130316245Abstract: The invention concerns a method for manufacturing of a battery electrode material comprising the steps of: a) applying an electric field to at least one polymer, conductive particles and at least one solvent whereby said conductive particles become arranged between the electrodes in at least two lines that are oriented in the same direction as the electric field line, and b) stabilizing the at least one polymer, conductive particles and at least one solvent by removing at least some of said at least one solvent while maintaining the electric field in step a) whereby the at least two lines of conductive particles will remain in their position when said electric field is removed. Further, the invention concerns a battery electrode material comprising at least one polymer and conductive particles, wherein said conductive particles form at least two lines that are oriented parallel and/or co-linear to each other.Type: ApplicationFiled: December 21, 2011Publication date: November 28, 2013Applicant: Condalign ASInventors: Mark Buchanan, Geir Helgesen, Matti Knaapila, Preben J.S. Vie, Gorm Krogh Johnsen, Rahul Fotedar
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Solid polymer electrolyte battery and method for manufacturing positive electrode sheet used therein
Patent number: 8592090Abstract: An organic electrolyte battery (10) including positive electrode material (2) and negative electrode material (4) and, interposed therebetween, organic electrolyte (6), wherein positive electrode active material particles (8) as a constituent of the positive electrode have surfaces at least partially coated with attachment (12) with electronic conductance and ionic conductance not easily oxidized even when supplied with oxygen from the positive electrode active material. The above attachment (12) is composed of microparticles of inorganic solid electrolyte with ionic conductance (14) and microparticles of conductive material with electronic conductance (16).Type: GrantFiled: May 18, 2005Date of Patent: November 26, 2013Assignee: Central Research Institute of Electric Power IndustryInventors: Hajime Miyashiro, Yo Kobayashi, Shiro Seki, Toru Iwahori -
Patent number: 8592082Abstract: A secondary battery includes an electrode assembly, which has improved safety by reducing a density of an active material centrally positioned in the electrode assembly. In the secondary battery, an electrode assembly includes a first electrode plate, a second electrode plate and a separator between the first electrode plate and the second electrode plate, the first electrode plate including a first electrode current collector and a first active material layer on the first electrode current collector, the first active material layer including a first active material, a binder and a conductive agent, and a portion of the first active material layer at a central portion of the electrode assembly including the first active material at a lower density than a density of the first active material at a portion of the first active material layer at a peripheral portion of the electrode assembly.Type: GrantFiled: July 18, 2012Date of Patent: November 26, 2013Assignee: Samsung SDI Co., Ltd.Inventors: Chanho Lee, Kiwoon Kim, Young Ju Ahn, Jinho Lee, Junpyo Park
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Patent number: 8592087Abstract: A negative active material, an electrode including the same, and a lithium battery including the electrode. The negative active material has no volumetric expansion and has high solubility with respect to lithium. In addition, the negative active material is in the form of spherical particles, and thus does not require a separate granulating process. Moreover, the negative active material may enhance the capacity of a lithium battery.Type: GrantFiled: December 17, 2010Date of Patent: November 26, 2013Assignee: Samsung SDI, Co., Ltd.Inventors: Deok-Hyun Kim, Jae-Myung Kim, Kyu-Nam Joo, So-Ra Lee, Jong-Hee Lee, Young-Su Kim, Gu-Hyun Chung, Beom-Kwon Kim
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Patent number: 8580437Abstract: A method for forming a negative electrode for a lithium secondary battery, includes providing a paste comprising graphite particulates comprise assembled or bound graphite particles in each of which a plurality of flat-shaped particles are assembled or bound together so that the planes of orientation are not parallel to one another, and the mixture including 3 to 10 parts by weight of the organic binder per 100 parts by weight of the graphite particulates, a binder and a solvent, coating the paste on a current collector, drying the paste coated on the current collector to form a mixture of the graphite particulates and the binder, and integrating the mixture with the current collector by pressing to provide a density of the mixture of graphite particulates and organic binder of 1.5 to 1.9 g/cm3.Type: GrantFiled: January 27, 2012Date of Patent: November 12, 2013Assignee: Hitachi Chemical Company, Ltd.Inventors: Yoshito Ishii, Tatsuya Nishida, Atsushi Fujita, Kazuo Yamada
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Publication number: 20130295462Abstract: A carbon black having a combination of properties with values in ranges selected to promote high conductivity, high hydrophobicity, and reduced outgassing in lead acid batteries while maintaining high charge acceptance and cycleability. The carbon black has a Brunauer-Emmett-Teller (BET) surface area ranging from 100 m2/g to 1100 m2/g combined with one or more properties, e.g., a surface energy (SE) of 10 mJ/m2 or less, and/or a Raman microcrystalline planar size (La) of at least 22 ?, e.g., ranging from 22 ? to 50 ?. In some cases, the carbon black has a statistical thickness surface area (STSA) of at least 100 m2/g, e.g., ranging from 100 m2/g to 600 m2/g.Type: ApplicationFiled: April 4, 2013Publication date: November 7, 2013Inventors: Paolina Atanassova, Berislav Blizanac, Kenneth C. Koehlert, Geoffrey D. Moeser, Miodrag Oljaca, Yipeng Sun, Danny Pierre, Jeffrey S. Sawrey
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Patent number: 8574762Abstract: Provided are negative electrode compositions for lithium-ion electrochemical cells that include metal oxides and polymeric binders. Also provided are electrochemical cells and battery packs that include electrodes made with these compositions.Type: GrantFiled: September 2, 2011Date of Patent: November 5, 2013Assignee: 3M Innovative Properties CompanyInventors: Jeffrey R. Dahn, Jing Li, Mark N. Obrovac
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Patent number: 8574766Abstract: A solid state battery excellent in pressure formability is provided. A positive electrode composite material layer includes sulfide glass unheated and a positive electrode active material. The sulfide glass and the positive electrode active material are pressure-formed and in contact with each other. A negative electrode composite material layer includes sulfide glass unheated and a negative electrode active material. The sulfide glass and the negative electrode active material are pressure-formed and in contact with each other.Type: GrantFiled: March 21, 2008Date of Patent: November 5, 2013Assignee: Toyota Jidosha Kabushiki KaishaInventors: Kenji Kimura, Masahiro Tatsumisago, Akitoshi Hayashi
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Patent number: 8574760Abstract: The present invention relates to an electrode comprising electrode active material particles, conductive particles, a binder and wax, wherein the electrode active material particles are interconnected by a network of the conductive particles, and the paths of the conductive particles interconnecting the electrode active materials are partially or entirely fixed by the wax. Furthermore, the present invention provides an electrochemical device comprising the electrode. By use of wax having a low meting viscosity in order to partially or entirely fix the paths of the conductive particles, which interconnect the spaced electrode active material particles, the present invention can improve processability and safety of the electrochemical device.Type: GrantFiled: January 3, 2007Date of Patent: November 5, 2013Assignee: LG Chem, Ltd.Inventors: Je Young Kim, Pil Kyu Park, Soon Ho Ahn, Yong Tae Lee
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Patent number: 8568928Abstract: A non-aqueous electrolyte secondary battery has a positive electrode (1), a negative electrode (2), and a non-aqueous electrolyte. The positive electrode has a positive electrode mixture layer containing a positive electrode active material, a binder agent, and a conductive agent. The positive electrode active material in the positive electrode mixture layer contains an olivine-type lithium-containing metal phosphate represented by the general formula LixMPO4, where M is at least one element selected from the group consisting of Co, Ni, Mn, and Fe, and x is 0<x<1.3. The conductive agent in the positive electrode mixture layer is composed of a mixture of carbon particles and carbon fiber.Type: GrantFiled: October 19, 2007Date of Patent: October 29, 2013Assignee: Sanyo Electric Co., Ltd.Inventors: Hironori Shirakata, Koji Hasumi, Hiroyuki Akita, Kazunori Donoue, Yoshinori Kida
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Patent number: 8563172Abstract: An anode composition for a lithium secondary battery includes an anode active material, a binder, and a conductive material. The active material includes a plurality of anode active material particles, each of which includes a core made of metal or metalloid allowing alloying or dealloying with lithium, or a compound containing the metal or metalloid; and a shell formed at an outer portion of the core and having Ketjen black. The conductive material includes carbon nano fiber. The anode composition uses a metal-based anode active material that may controls the volume expansion, and also uses conductive material with excellent dispersion so that the life characteristic of the battery may be improved.Type: GrantFiled: October 21, 2011Date of Patent: October 22, 2013Assignee: LG Chem, Ltd.Inventors: Yo-Han Kwon, Byung-Hun Oh
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Publication number: 20130266859Abstract: A graphene oxide used as a raw material of a conductive additive for forming an active material layer with high electron conductivity with a small amount of a conductive additive is provided. A positive electrode for a nonaqueous secondary battery using the graphene oxide as a conductive additive is provided. The graphene oxide is used as a raw material of a conductive additive in a positive electrode for a nonaqueous secondary battery and, in the graphene oxide, the weight ratio of oxygen to carbon is greater than or equal to 0.405.Type: ApplicationFiled: March 14, 2013Publication date: October 10, 2013Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.Inventor: SEMICONDUCTOR ENERGY LABORATORY CO. LTD.
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Publication number: 20130236789Abstract: To provide a conductive agent for a nonaqueous electrolyte secondary battery and the like, in which oxidative decomposition reaction of an electrolyte is sufficiently suppressed during charging and discharging under high-temperature, high-voltage conditions and thus the cycle characteristics under these conditions are improved. A conductive agent main body composed of carbon and a compound attached to a surface of the conductive agent main body are contained. The average particle size of primary particles or secondary particles of the conductive agent main body is larger than the average particle size of the compound and the compound contains at least one metal element selected from the group consisting of aluminum, zirconium, magnesium, and a rare earth element.Type: ApplicationFiled: November 28, 2011Publication date: September 12, 2013Applicant: SANYO ELECTRIC CO., LTD.Inventors: Hiroyuki Matsumoto, Takeshi Ogasawara
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Patent number: 8530098Abstract: Disclosed is an electrolyte for a rechargeable lithium battery including: a first additive having an oxidation potential of 4.1 to 4.6V; a second additive having an oxidation potential of 4.4 to 5.0V; a non-aqueous organic solvent; and a lithium salt.Type: GrantFiled: May 18, 2010Date of Patent: September 10, 2013Assignee: Samsung SDI Co., Ltd.Inventors: Jin-Hee Kim, Jin-Sung Kim
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Patent number: 8524395Abstract: The present invention relates to nonaqueous electrolyte secondary batteries and durable anode materials and anodes for use in nonaqueous electrolyte secondary batteries. The present invention also relates to methods for producing these anode materials. In the present invention, a metal-semiconductor alloy layer is formed on an anode material by contacting a portion of the anode material with a displacement solution. The displacement solution contains ions of the metal to be deposited and a dissolution component for dissolving a part of the semiconductor in the anode material. When the anode material is contacted with the displacement solution, the dissolution component dissolves a part of the semiconductor in the anode material thereby providing electrons to reduce the metal ions and deposit the metal on the anode material. After deposition, the anode material and metal are annealed to form a uniform metal-semiconductor alloy layer.Type: GrantFiled: February 15, 2012Date of Patent: September 3, 2013Assignee: Enovix CorporationInventors: Murali Ramasubramanian, Robert Spotnitz
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Publication number: 20130209869Abstract: A novel hybrid lithium-ion anode material based on coaxially coated Si shells on vertically aligned carbon nanofiber (CNF) arrays. The unique cup-stacking graphitic microstructure makes the bare vertically aligned CNF array an effective Li+ intercalation medium. Highly reversible Li+ intercalation and extraction were observed at high power rates. More importantly, the highly conductive and mechanically stable CNF core optionally supports a coaxially coated amorphous Si shell which has much higher theoretical specific capacity by forming fully lithiated alloy. Addition of surface effect dominant sites in close proximity to the intercalation medium results in a hybrid device that includes advantages of both batteries and capacitors.Type: ApplicationFiled: February 27, 2013Publication date: August 15, 2013Inventor: Ronald A. Rojeski
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Patent number: 8501858Abstract: Graphite nanoplatelets of expanded graphite and polymer composites produced therefrom are described. The graphite is expanded from an intercalated graphite by microwaves or radiofrequency waves in the presence of a gaseous atmosphere. The composites have barrier and/or conductive properties due to the expanded graphite.Type: GrantFiled: May 17, 2006Date of Patent: August 6, 2013Assignee: Board of Trustees of Michigan State UniversityInventors: Lawrence T. Drzal, Hiroyuki Fukushima
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Patent number: 8501352Abstract: A composite material having: particles of a first lithium-metal oxide compound, particles of a conductive second lithium-metal oxide compound, a conductive matrix, and a polymeric binder.Type: GrantFiled: February 3, 2006Date of Patent: August 6, 2013Assignee: The United States of America, as represented by the Secretary of the NavyInventors: Arnold Stux, Karen Lyons