Organic Polymer Containing Patents (Class 429/303)
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Publication number: 20140255791Abstract: The present invention is to provide a transparent/translucent Li-ion battery. The transparent/translucent Li-ion battery comprises an anode, a cathode, and an electrolyte. The anode comprises an electrode material holder with inner structures, a current collector, and an anode material. The current collector is formed along the wall of the inner structures of the electrode material holder, and the anode material is deposited on the current collector, and filled within the inner structures. The cathode is fabricated with the similar method as the anode by using a cathode material. The electrode material holder with the inner structures can be a patterned glass or quartz slice with concave parts, or an anodized aluminum oxide film with channels. The transparent/translucent Li-ion battery of the present invention provides high transparency and electrical storage capacity.Type: ApplicationFiled: February 24, 2014Publication date: September 11, 2014Applicant: Nano and Advanced Materials Institute LimitedInventors: Jianying Miao, Wei Li, Shing Hang Ng, King Ho So, Kwok Cheong Lai, Ricky Ka Cheong Luk
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Publication number: 20140255792Abstract: The invention relates to a polymer gel electrolyte system for use in an electrochemical cell having positive and negative electrodes, said electrolyte system comprising: (A) a poly(dialkylene ester) thermoplastic polyurethane composition; (B) an alkali metal salt; and (C) an aprotic organic solvent. The invention also provides an electrochemical cell comprising a positive electrode, a negative electrode, and (I) a polymer electrolyte disposed between said positive and negative electrodes, wherein the polymer electrolyte comprises (A) the poly(dialkylene ester) thermoplastic polyurethane composition; (B) an alkali metal salt; and (C) an aprotic organic solvent.Type: ApplicationFiled: October 24, 2012Publication date: September 11, 2014Applicant: Lubrizol Advanced Materials, Inc.Inventors: Feina Cao, Tesham Gor, Qiwei Lu, Yona Eckstein, Jian Xie, Donald A. Meltzer
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Patent number: 8828611Abstract: Disclosed is a non-aqueous electrolyte comprising: a first acrylate compound having one or two acryl groups; a second acrylate compound having three or more acryl groups; an electrolyte salt; and an organic solvent. Also, disclosed is an electrode comprising a coating layer formed partially or totally on a surface thereof, the coating layer comprising: (i) a reduced form of a first acrylate compound having one or two acryl groups; and (ii) a reduced form of a second acrylate compound having three or more acryl groups. Further, disclosed in an electrochemical device comprising a cathode, an anode, a separator and a non-aqueous electrolyte, wherein (i) the non-aqueous electrolyte is the above non-aqueous electrolyte; and/or (ii) the cathode and/or the anode is the above electrode.Type: GrantFiled: September 19, 2007Date of Patent: September 9, 2014Assignee: LG Chem, Ltd.Inventors: Su-Jin Yoon, Jeong-Ju Cho, Ho-Chun Lee
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Patent number: 8828579Abstract: The invention provides a battery, which can improve battery characteristics such as high temperature storage characteristics. The battery comprises a battery device, wherein a cathode and an anode are wound with a separator in between. The anode contains an anode material capable of inserting and extracting Li as an anode active material. An electrolytic solution is impregnated in the separator. The electrolytic solution contains a solvent, and an electrolyte salt such as Li[B(CF3)4] dissolved in the solvent, which is expressed by a chemical formula of Li[B(RF1)(RF2)(RF3)RF4]RF 1, RF 2, RF 3, and RF 4 represent a perfluoro alkyl group whose number of fluorine or carbon is from 1 to 12, respectively. Consequently, high temperature storage characteristics are improved.Type: GrantFiled: March 30, 2004Date of Patent: September 9, 2014Assignee: Sony CorporationInventors: Tadahiko Kubota, Momoe Adachi, Shigeru Fujita
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Patent number: 8828609Abstract: The invention relates to a method for manufacturing an electrochemical cell comprising an anode and a cathode separated by a separator and a gel electrolyte. The method comprises the steps of assembling the electrodes and the separator, and injecting a liquid electrolyte composition between the electrodes, the liquid electrolyte composition comprising a polymer, an aprotic liquid solvent and a lithium salt, wherein the polymer in the liquid electrolyte composition has functional groups capable of polymerizing via cationic polymerization, and the cell is submitted to an electrochemical cycling comprising a charging step and a discharging step.Type: GrantFiled: March 5, 2009Date of Patent: September 9, 2014Assignees: Hydro-Quebec, Dai-Ichi Kogyo Seiyaku Co., Ltd.Inventors: Karim Zaghib, Manabu Kikuta, Martin Dontigny, Abdelbast Guerfi, Michiyuki Kono
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Patent number: 8808924Abstract: Disclosed is an electrolyte for a secondary battery, comprising an eutectic mixture consisting of: (a) am amide group-containing compound with at least one EDG introduced into the N-position thereof; and (b) an ionizable lithium salt. Also, provided are a secondary battery comprising such an electrolyte, and a method of adjusting an electrochemical stability window of an eutectic mixture consisting of an amide group-containing compound and a lithium salt by regulating electron donating properties of at least one substituent group introduced into the N-position of the amide group-containing compound.Type: GrantFiled: January 16, 2008Date of Patent: August 19, 2014Assignee: LG Chem, Ltd.Inventors: Byoung-Bae Lee, Shin-Jung Choi, Jae-Seung Oh, Ji-Won Park, Young-Kyu Han, Jae-Hoon Jung, Jae-Duk Park
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Publication number: 20140220451Abstract: Provided are a lithium secondary battery including a cathode, an anode, a separator, and a gel polymer electrolyte, wherein the gel polymer electrolyte includes an acrylate-based polymer and a charge voltage of the battery is in a range of 4.3 V to 5.0 V, and a method of preparing the lithium secondary battery. A high-voltage lithium secondary battery of the present invention has excellent capacity characteristics at a high voltage of 4.3 V or more.Type: ApplicationFiled: April 4, 2014Publication date: August 7, 2014Applicant: LG CHEM, LTD.Inventors: Sung Hoon Yu, Doo Kyung Yang, Sun Sik Shin, Song Taek Oh, Yoo Sun Kang, Kyung Mi Lee, Jin Hyun Park, Jung Don Suk
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Publication number: 20140220452Abstract: Provided are a lithium secondary battery including a cathode, an anode, a separator, and a gel polymer electrolyte, wherein i) the anode includes a silicon (Si)-based anode active material, ii) the gel polymer electrolyte is formed by polymerizing a composition that includes a monomer having a functional group bondable to metal ions, and iii) a charge voltage of the battery is in a range of 3.0 V to 5.0 V. Since the lithium secondary battery of the present invention may prevent the movement of metal ions dissolved from a cathode to an anode or reduce the precipitation of metal on the anode, the lifetime of the battery may not only be improved but capacity characteristics of the battery may also be excellent even in the case in which the battery is charged at a high voltage as well as normal voltage.Type: ApplicationFiled: April 8, 2014Publication date: August 7, 2014Applicant: LG CHEM, LTD.Inventors: Sung Hoon Yu, Yoo Sun Kang, Kyung Mi Lee, Jin Hyun Park, Jung Don Suk, Doo Kyung Yang
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Publication number: 20140220453Abstract: The invention relates to a novel lithium-sulphur type electrochemical battery A. According to the invention, the positive electrode (1) is made solely from a porous electronic conductor substrate forming a current collector and the electrolyte contains lithium polysulphides (Li2Sn) as sources of lithium and sulphur ions, said lithium polysulphides being formed ex-situ and not in the battery. The invention also relates to a method for the production of said device.Type: ApplicationFiled: August 31, 2012Publication date: August 7, 2014Applicant: Commissariat à l'énergie atomique et aux énergies alternativesInventors: Celine Barchasz, Sebastien Patoux, Yvan Reynier
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Publication number: 20140205909Abstract: The purpose of the present invention is to provide a zinc negative electrode mixture for forming negative electrodes of safe and economic batteries exhibiting excellent battery performance; and a gel electrolyte or a negative electrode mixture which can be suitably used for forming a storage battery exhibiting excellent battery performance such as a high cycle characteristic, rate characteristic, and coulombic efficiency while suppressing change in form, such as shape change and dendrite, and passivation of the electrode active material. Another purpose of the present invention is to provide a battery including the zinc negative electrode mixture or the gel electrolyte. (1) The zinc negative electrode mixture contains a zinc-containing compound and a conductive auxiliary agent. The zinc-containing compound and/or the conductive auxiliary agent contain(s) particles having an average particle size of 1000 ?m or smaller and/or particles having an aspect ratio (vertical/lateral) of 1.1 or higher.Type: ApplicationFiled: August 22, 2012Publication date: July 24, 2014Applicant: NIPPON SHOKUBAI CO., LTD.Inventors: Koji Yonehara, Hironobu Ono, Hiroko Harada, Yasuyuki Takazawa
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Publication number: 20140199597Abstract: The present disclosure provides an embodiment of an integrated structure that includes a first electrode of a first conductive material embedded in a first semiconductor substrate; a second electrode of a second conductive material embedded in a second semiconductor substrate; and a electrolyte disposed between the first and second electrodes. The first and second semiconductor substrates are bonded together through bonding pads such that the first and second electrodes are enclosed between the first and second semiconductor substrates. The second conductive material is different from the first conductive material.Type: ApplicationFiled: January 15, 2013Publication date: July 17, 2014Applicant: Taiwan Semiconductor Manufacturing Company, Ltd.Inventors: Chyi-Tsong Ni, I-Shi Wang, Yi Hsun Chiu, Ching-Hou Sue
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Publication number: 20140186717Abstract: A lithium ion battery includes a cathode, an anode, and an electrolyte sandwiched between the cathode and the anode. The cathode includes a cathode active material. The anode is spaced from the cathode. The cathode active material includes a sulfur grafted poly(pyridinopyridine). The sulfur grafted poly(pyridinopyridine) includes a poly(pyridinopyridine) matrix and sulfur dispersed in the poly(pyridinopyridine) matrix. The sulfur includes a number of poly-sulfur groups or a number of elemental sulfur particles dispersed in the poly(pyridinopyridine) matrix. The electrolyte is a gel electrolyte.Type: ApplicationFiled: April 26, 2013Publication date: July 3, 2014Applicants: HON HAI PRECISION INDUSTRY CO., LTD., Tsinghua UniversityInventors: Li WANG, Xiang-Ming HE, Jian-Jun LI, Jian GAO
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Publication number: 20140186718Abstract: The disclosure relates to a gel polymer electrolyte and/or polymer modified electrode materials for lithium batteries.Type: ApplicationFiled: May 6, 2013Publication date: July 3, 2014Applicant: Industrial Technology Research InstituteInventors: Li-Duan Tsai, Chih-Ching Chang, Chia-Chen Fang, Wei-Hsin Wu, Chun-Lung Li, Yueh-Wei Lin
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Patent number: 8758944Abstract: Provided is a secondary battery containing polyalkyleneglycol diglycidylether represented by formula I added in a predetermined amount to an electrolyte for the battery. The secondary battery containing the above additive exhibits remarkably improved high-temperature characteristics, prevents deterioration in rate characteristics and cycle characteristics, and considerably reduces thickness swelling of the battery so as to prevent battery leakage, ultimately enhancing safety of the battery.Type: GrantFiled: November 7, 2008Date of Patent: June 24, 2014Assignee: LG Chem, Ltd.Inventors: Suyoung Ryu, Dongmyung Kim, Eun young Kim
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Publication number: 20140162134Abstract: A gel electrolyte secondary cell includes a positive electrode, a negative electrode and a gel electrolyte. The negative electrode includes a current collector, and a mixture of powders of a graphite carbonaceous material and a binder. The powders of the graphite carbonaceous material include sintered meso-carbon micro-beads. The gel electrolyte includes an electrolyte salt, a non-aqueous solvent and a high-molecular weight material. The non-aqueous solvent includes propylene carbonate and ethylene carbonate. A content of propylene carbonate ranges from 35 mol % to 75 mol %. The binder is in an amount 1 to 20 wt % based on total weight of the powders of the graphite carbonaceous material. The meso-carbon micro-beads can suitably decrease the impedance and the discharge capacity loss, thereby increasing the discharging capacity and/or charging/discharging efficiency of the gel electrolyte secondary cell.Type: ApplicationFiled: February 18, 2014Publication date: June 12, 2014Applicant: Sony CorporationInventors: Tadashi Senoo, Hiroyuki Akashi, Hideto Azuma, Mashio Shibuya, Kazuhiro Noda, Shinichiro Yamada, Toshikazu Yasuda, Koji Sekai
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Patent number: 8741490Abstract: Provided are a thickening agent for an alkaline battery, which can satisfactorily retain long-term discharge characteristics (discharge quantity and discharge time) and provide excellent impact resistance, and an alkaline battery used therewith. In the invention, the thickening agent for an alkaline battery comprises (A) a crosslinked polymer comprising, as essential constituent units, (a1) a water-soluble vinyl monomer and/or (a2) a vinyl monomer being converted into (a1) by hydrolysis, (b) a hydrolyzable crosslinking agent undergoing alkaline hydrolysis, and (c) a non-hydrolyzable crosslinking agent not undergoing alkaline hydrolysis, wherein (b) and (c) each has a content of 0.05% to 1% by weight based on the weight of (A), and satisfies Requirements (1) and (2) described below: Requirement (1): the weight ratio (b)/(c) between (b) and (c) is from 1.0 to 5.0; Requirement (2): a specific solution (S1) has a viscosity of 25 to 100 Pa·s at 25° C.Type: GrantFiled: September 28, 2009Date of Patent: June 3, 2014Assignee: Sanyo Chemical Industries, Ltd.Inventor: Yoshimasa Matsumoto
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Patent number: 8735001Abstract: A gel battery may be fabricated from a gel anode material and a gel cathode material. The battery may further comprise a gel electrolyte material. The gel materials may be in the form of thin films. A gel battery may be formed by contacting at least a portion of a gel anode with at least a portion of a gel electrolyte, and at least a portion of a gel cathode may also be in contact with at least a portion of the gel electrolyte. A battery formed by gel films may also be coated with a material. The gel battery, its anode, cathode, and electrolyte materials may all be non-toxic for an application to an animal.Type: GrantFiled: April 9, 2012Date of Patent: May 27, 2014Assignee: Empire Technology Development LLCInventor: Glenn Godden
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Patent number: 8715866Abstract: An electrolyte includes an eutectic mixture composed of (a) a hetero cyclic compound having a predetermined chemistry figure, and (b) an ionizable lithium salt. An electrochemical device having the electrolyte. The eutectic mixture included in the electrolyte exhibits inherent characteristics of an eutectic mixture such as excellent thermal stability and excellent chemical stability, thereby improving the problems such as evaporation, ignition and side reaction of an electrolyte caused by the usage of existing organic solvents.Type: GrantFiled: December 30, 2008Date of Patent: May 6, 2014Assignee: LG Chem, Ltd.Inventors: Byoung-Bae Lee, Jae-Seung Oh, Ji-Won Park, Shin-Jung Choi, Jae-Duk Park, Dong-Su Kim, Hyo-Jin Lee
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Publication number: 20140087238Abstract: A battery electrode assembly comprises a porous electrode plate having a plurality of large and small pores, a pore insert within a plurality of pores, the pore insert maintaining an electrolyte in the pores substantially throughout a discharge/charge cycle. The pore insert may be a gelled electrolyte. The pore insert may be a particulate material. The electrodes may be used in a battery having cells with opposing positive and negative tabs connected in series by an intercell connector.Type: ApplicationFiled: February 23, 2012Publication date: March 27, 2014Applicant: Firefly International Energy Group, Inc.Inventors: Kurtis C. Kelley, Mukesh Bhandari, Mathew Stone
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Patent number: 8673503Abstract: Disclosed are gel electrolytes comprising a polymer, which is a cross-linked polyurethane prepared from a poly(alkyleneoxide) triol and a diisocyanate compound; a lithium salt; and a solvent, which is a carbonate solvent, a lactone solvent, or mixtures thereof.Type: GrantFiled: June 4, 2010Date of Patent: March 18, 2014Assignee: Indian Institute of Technology BombayInventors: Ramamurthy Balaji, Ajit R. Kulkarni, Raman S. Srinivasa
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Publication number: 20140072881Abstract: A lithium battery including a negative electrode including a lithium metal or a lithium alloy; a positive electrode; and a polymer gel electrolyte contacting the negative electrode, wherein the polymer gel electrolyte has an ionic conductivity of about 10?3 S/cm or greater, a lithium ion transference number of about 0.15 or greater, and a lithium ion mobility of about 10?6 cm2/V×sec or greater, wherein the polymer gel electrolyte includes a lithium salt, a polymer capable of forming a complex with the lithium salt, an insulating inorganic filler, and an organic solvent, wherein the organic solvent is inert with respect to the lithium metal, wherein an anionic radius of the lithium salt is about 2.5 Angstroms or greater, and wherein a molecular weight of the lithium salt is about 145 or greater.Type: ApplicationFiled: August 26, 2013Publication date: March 13, 2014Applicants: NATIONAL UNIVERSITY CORPORATION MIE UNIVERSITY, SAMSUNG ELECTRONICS CO., LTD.Inventors: Min-sik PARK, Dong-joon LEE, Sang-bok MA, Dong-min IM, Won-sung CHOI, Osamu YAMAMOTO, Nobuyuki IMANISHI
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Publication number: 20140072880Abstract: Disclosed is a non-aqueous rechargeable lithium battery that includes a positive electrode including a positive active material being capable of intercalating and deintercalating lithium; a negative electrode including a negative active material; a polymer electrolyte including a gel polymer, a non-aqueous organic solvent, and a lithium salt; and a separator having compression strength of about 0.15 gf/cm2 to about 0.3 gf/cm2 per 1 ?m thickness.Type: ApplicationFiled: November 30, 2012Publication date: March 13, 2014Applicant: SAMSUNG SDI CO., LTD.Inventors: Kwang-Jo Cheong, Yong-Beom Lee, Hee-Sun Yun, Soo-Mi Eo
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Patent number: 8669296Abstract: A process for preparing a polyazole with an inherent viscosity, measured in at least 96% sulfuric acid at 25° C., greater than 2.9 dl/g, comprising the steps of i) mixing one or more aromatic tetraamino compounds with one or more aromatic carboxylic acids or esters thereof which comprise at least two acid groups per carboxylic acid monomer, or mixing one or more aromatic and/or heteroaromatic diaminocarboxylic acids, in polyphosphoric acid to form a solution and/or dispersion ii) heating the mixture from step i) under inert gas to temperatures in the range from 120° C. to 350° C. to form the polyazole, wherein in step ii), a mixture having a concentration of polyphosphoric acid, calculated as P2O5 (by acidimetric means), based on the total amount of H3PO4, polyphosphoric acid and water in the mixture, greater than 78.Type: GrantFiled: June 17, 2010Date of Patent: March 11, 2014Assignee: BASF SEInventors: Jörg Belack, Klaus Leitner, Hansjoachim Scupin, Oemer Uensal
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Publication number: 20140065475Abstract: A polymer electrolyte having improved reliability and safety by increasing thermal stability of a polymer of the polymer electrolyte and crosslinking density of a matrix of the polymer while improving electrode impregnation capability by inducing low viscosity in a pre-gel composition, and a lithium rechargeable battery including the same are disclosed. The polymer electrolyte is a cured product of a polymer electrolyte composition including a lithium salt, a non-aqueous organic solvent, and a pre-gel composition including a first monomer represented by Chemical Formula 1, a second monomer represented by Chemical Formula 2 and a third monomer represented by Chemical Formula 3.Type: ApplicationFiled: March 13, 2013Publication date: March 6, 2014Applicant: SAMSUNG SDI CO., LTD.Inventors: Kwangjo Cheong, Yongbeom Lee, Soomi Eo
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Publication number: 20140062411Abstract: Methods and articles relating to separation of electrolyte compositions within lithium batteries are provided. The lithium batteries described herein may include an anode having lithium as the active anode species and a cathode having sulfur as the active cathode species. Suitable electrolytes for the lithium batteries can comprise a heterogeneous electrolyte including a first electrolyte solvent (e.g., dioxolane (DOL)) that partitions towards the anode and is favorable towards the anode (referred to herein as an “anode-side electrolyte solvent”) and a second electrolyte solvent (e.g., 1,2-dimethoxyethane (DME)) that partitions towards the cathode and is favorable towards the cathode (and referred to herein as an “cathode-side electrolyte solvent”).Type: ApplicationFiled: November 13, 2013Publication date: March 6, 2014Applicant: SION POWER CORPORATIONInventors: Yuriy V. Mikhaylik, CHARICLEA SCORDILIS-KELLEY, IGOR P. KOVALEV, CATHIE BURGESS
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Publication number: 20140065489Abstract: There are provided a constitution which can suppress a decrease in the cycle performance in repetition of charging and discharging, and a lithium ion secondary battery comprising the constitution. An electrolyte-negative electrode structure (7) comprises: a negative electrode (4) in which a negative electrode active material layer (3) comprising a material capable of intercalating lithium ions is formed on a current collector (2); and a solid electrolyte (6) comprising an inorganic particle having lithium ion conductivity, a polymer gel to be impregnated with an electrolyte solution, and an organic polymer acting as a binder for the inorganic particle and being capable of being impregnated with the polymer gel, wherein the negative electrode active material layer (3) and the solid electrolyte (6) are unified through the organic polymer as a medium.Type: ApplicationFiled: August 16, 2013Publication date: March 6, 2014Applicant: HONDA MOTOR CO., LTD.Inventors: Kazuki SAIMEN, Yuki ITO
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Patent number: 8647779Abstract: A nonaqueous electrolyte composition includes: a nonaqueous solvent; an electrolyte salt; a matrix resin; a filler; and a surfactant.Type: GrantFiled: November 29, 2012Date of Patent: February 11, 2014Assignee: Sony CorporationInventors: Masaki Machida, Yosuke Kono
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Publication number: 20140023931Abstract: An electrochemical battery cell of a lithium ion battery has a physically cross-linked gel electrolyte situated between a negative electrode and a positive electrode. The gel electrolyte includes a block co-polymer host and a liquid electrolyte, which can transport lithium ions, absorbed into the block co-polymer host. The block co-polymer host includes poly(alkylene oxide) block units and physically cross-linkable block units. A few preferred physically cross-linkable block units that may be employed include polyamide block units and poly(terephthalate)ester block units.Type: ApplicationFiled: July 18, 2012Publication date: January 23, 2014Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLCInventor: Xiaosong Huang
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Publication number: 20140017571Abstract: Representative embodiments provide a liquid or gel separator utilized to separate and space apart first and second conductors or electrodes of an energy storage device, such as a battery or a supercapacitor. A representative liquid or gel separator comprises a plurality of particles, typically having a size (in any dimension) between about 0.5 to about 50 microns; a first, ionic liquid electrolyte; and a polymer. In another representative embodiment, the plurality of particles comprise diatoms, diatomaceous frustules, and/or diatomaceous fragments or remains. Another representative embodiment further comprises a second electrolyte different from the first electrolyte; the plurality of particles are comprised of silicate glass; the first and second electrolytes comprise zinc tetrafluoroborate salt in 1-ethyl-3-methylimidalzolium tetrafluoroborate ionic liquid; and the polymer comprises polyvinyl alcohol (“PVA”) or polyvinylidene fluoride (“PVFD”).Type: ApplicationFiled: August 9, 2012Publication date: January 16, 2014Applicant: NTHDEGREE TECHNOLOGIES WORLDWIDE INC.Inventors: Vera Nicholaevna Lockett, Mark D. Lowenthal, Neil O. Shotton, William Johnstone Ray, Theodore I. Kamins
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Publication number: 20140017558Abstract: Representative embodiments provide a liquid or gel separator utilized to separate and space apart first and second conductors or electrodes of an energy storage device, such as a battery or a capacitor. A representative liquid or gel separator comprises a plurality of particles selected from the group consisting of: diatoms, diatomaceous frustules, diatomaceous fragments, diatomaceous remains, and mixtures thereof; a first, ionic liquid electrolyte; and a polymer or, in the printable composition, a polymer or a polymeric precursor. Another representative embodiment further comprises a second electrolyte different from the first electrolyte; the first and second electrolytes comprise zinc tetrafluoroborate salt in 1-ethyl-3-methylimidalzolium tetrafluoroborate ionic liquid; and the polymer comprises polyvinyl alcohol (“PVA”) or polyvinylidene fluoride (“PVFD”). Additional components, such as additional electrolytes and solvents, may also be included.Type: ApplicationFiled: August 9, 2012Publication date: January 16, 2014Applicant: NthDegree Technologies Worldwide Inc.Inventors: Vera Nicholaevna Lockett, Mark David Lowenthal, Neil O. Shotton, William Johnstone Ray, Theodore I. Kamins
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Patent number: 8603682Abstract: Disclosed is a secondary battery including (i) a cathode; (ii) an anode; (iii) a separator; and (iv) a gel polymer electrolyte composition including an electrolyte solvent, an electrolyte salt, and a polymerizable monomer, wherein a polymerization initiator is coated or added on at least one battery device element in contact with the gel polymer electrolyte composition. Also, the secondary battery including a cathode, an anode, a separator, and a gel polymer electrolyte is manufactured by the steps of: coating or adding a polymerization initiator on/to at least one battery device element in contact with the gel polymer electrolyte; inserting the cathode, the anode, and the separator into a battery case; and forming the gel polymer electrolyte by injecting a gel polymer electrolyte composition including an electrolyte solvent, an electrolyte salt, and a polymerizable monomer into the battery case, and carrying out polymerization.Type: GrantFiled: May 14, 2008Date of Patent: December 10, 2013Assignee: LG Chem, Ltd.Inventors: Sunghoon Yu, Jeong-Ju Cho, Soojin Kim, Soo-Hyun Ha
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Patent number: 8574770Abstract: A non-aqueous battery comprising a positive electrode material capable of being doped with and liberating lithium, a negative electrode material capable of being doped with and liberating lithium, and a polymer electrolyte disposed between the positive and negative electrode materials. The polymer electrolyte is formed by mixing a vinylidene fluoride copolymer and a nonaqueous electrolytic solution with a solvent, followed by evaporation of the solvent, so as to retain a high proportion of the nonaqueous electrolytic solution, leading to high electroconductivity and excellent strength in this state. The vinylidene fluoride copolymer comprises 80 to 97 wt. % of vinylidene fluoride monomer units and 3 to 20 wt. % of units of at least one monomer copolymerizable with vinylidene fluoride monomer, and has an inherent viscosity of 1.7 to 7 dl/g, as measured at 30° C. in a solution at a concentration of 4 g of polymer in 1 liter of N,N-dimethylformamide.Type: GrantFiled: September 21, 2011Date of Patent: November 5, 2013Assignee: Kureha CorporationInventors: Takumi Katsurao, Katsuo Horie, Yukio Ichikawa, Aisaku Nagai
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Patent number: 8574771Abstract: A rechargeable lithium battery is provided. The battery includes an electrolyte including a lithium salt, a non-aqueous organic solvent including an ethylene carbonate-based compound and a pyrocarbonate-based additive; a negative electrode that includes a negative active material including a crystalline-based carbon core and an amorphous-based carbon shell surrounding the crystalline-based carbon core; and a positive electrode comprising a positive active material.Type: GrantFiled: December 29, 2006Date of Patent: November 5, 2013Assignee: Samsung SDI Co., Ltd.Inventors: Hyun-Seok Kim, Heon-Cheol Shin
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Patent number: 8574534Abstract: The invention is directed to a method for producing a film of porous carbon, the method comprising carbonizing a film of an ionic liquid, wherein the ionic liquid has the general formula (X+a)x(Y?b)y, wherein the variables a and b are, independently, non-zero integers, and the subscript variables x and y are, independently, non-zero integers, such that a·x=b·y, and at least one of X+ and Y? possesses at least one carbon-nitrogen unsaturated bond. The invention is also directed to a composition comprising a porous carbon film possessing a nitrogen content of at least 10 atom %.Type: GrantFiled: March 18, 2010Date of Patent: November 5, 2013Assignee: UT-Battelle, LLCInventors: Sheng Dai, Huimin Luo, Je Seung Lee
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Publication number: 20130280618Abstract: The present invention includes an electrolyte in which an organic acid lithium salt (A) and a boron compound (B) are mixed.Type: ApplicationFiled: September 26, 2011Publication date: October 24, 2013Applicant: SEKISUI CHEMICAL CO., LTD.Inventors: Kenichi Shinmei, Yoshiharu Konno, Masashi Kanoh
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Publication number: 20130280579Abstract: An electrochemical cell includes solid-state, printable anode layer, cathode layer and non-aqueous gel electrolyte layer coupled to the anode layer and cathode layer. The electrolyte layer provides physical separation between the anode layer and the cathode layer, and comprises a composition configured to provide ionic communication between the anode layer and cathode layer by facilitating transmission of multivalent ions between the anode layer and the cathode layer.Type: ApplicationFiled: March 5, 2013Publication date: October 24, 2013Inventors: Paul K. Wright, James W. Evans, Christine Ho
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Patent number: 8557473Abstract: Crosslinked sulfonated triblock copolymers exhibit lower methanol permeability and good physical strength relative to the perfluorinated proton conductive membranes typically used in Direct Methanol Fuel Cells. Examples of triblock copolymers that can be used as fuel cell membranes include SEBS, SIBS, and SEPS. The chemically cross-linked and sulfonated SIBS, SEBS, and SEPS exhibit lower swelling and tolerate higher sulfonation levels than the un-cross-linked counterparts. These copolymers are easily sulfonated using known procedures and can be manufactured at a fraction of the cost of the typical perfluorinated proton conductive membranes.Type: GrantFiled: December 11, 2007Date of Patent: October 15, 2013Assignee: Bose CorporationInventor: Agota F. Fehervari
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Publication number: 20130260257Abstract: Provided are a multi-layered structure electrolyte including a gel polymer electrolyte on opposite surfaces of a ceramic solid electrolyte, for a lithium ion secondary battery including positive and negative electrodes capable of intercalating/deintercalating lithium ions, and a lithium ion secondary battery including the electrode. The electrolyte includes a gel polymer electrolyte on opposite surfaces of a ceramic solid electrolyte.Type: ApplicationFiled: September 5, 2012Publication date: October 3, 2013Applicant: Samsung Corning Precision Materials Co., Ltd.Inventor: Shin Jung CHOI
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Publication number: 20130230779Abstract: An object of the present invention is to provide a gel electrolyte for a lithium ion secondary battery having flame retardancy over a long period and a good capacity maintenance rate. The gel electrolyte for a lithium ion secondary battery according to the exemplary embodiment contains a lithium salt, a copolymer of at least one first monomer selected from compounds represented by chemical formulae (1) and (2) and a second monomer represented by chemical formula (4), at least one oxo-acid ester derivative of phosphorus selected from compounds represented by chemical formulae (5) to (7), and at least one disulfonate ester selected from a cyclic-chain type disulfonate ester represented by chemical formula (8) and a linear-chain type disulfonate ester represented by chemical formula (9).Type: ApplicationFiled: December 22, 2011Publication date: September 5, 2013Applicant: NEC ENERGY DEVICES, LTD.Inventors: Shinako Kaneko, Yasutaka Kono, Hitoshi Ishikawa
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Publication number: 20130230778Abstract: Provided is a lithium ion conductive composite electrolyte that can prevent leakage of electrolyte solution, and that have excellent cycle performance and lithium ion conductivity, and a lithium ion secondary battery. A lithium ion conductive composite electrolyte 1 is formed so that a lithium ion conductive polymer gel electrolyte is held in a porous body 2 formed from lithium ion conductive inorganic solid electrolyte particles and an organic polymer. The lithium ion conductive inorganic solid electrolyte particles are formed from a composite metal oxide that has a garnet structure, and is represented by the chemical formula Li7?yLa3?xAxZr2?yMyO12 (wherein 0?x 3, 0?y?2, A is one of Y, Nd, Sm, and Gd, and M is Nb or Ta). A lithium ion secondary battery 11 includes the lithium ion conductive composite electrolyte 1 between a positive electrode 12 and a negative electrode 13.Type: ApplicationFiled: March 1, 2013Publication date: September 5, 2013Applicant: HONDA MOTOR CO., LTD.Inventors: Kazuki SAIMEN, Yuki ITO, Yuji ISOGAI
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Patent number: 8501339Abstract: Active metal and active metal intercalation electrode structures and battery cells having ionically conductive protective architecture including an active metal (e.g., lithium) conductive impervious layer separated from the electrode (anode) by a porous separator impregnated with a non-aqueous electrolyte (anolyte). This protective architecture prevents the active metal from deleterious reaction with the environment on the other (cathode) side of the impervious layer, which may include aqueous or non-aqueous liquid electrolytes (catholytes) and/or a variety electrochemically active materials, including liquid, solid and gaseous oxidizers. Safety additives and designs that facilitate manufacture are also provided.Type: GrantFiled: September 13, 2012Date of Patent: August 6, 2013Assignee: PolyPlus Battery CompanyInventors: Steven J. Visco, Bruce D. Katz, Yevgeniy S. Nimon, Lutgard C. De Jonghe
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Publication number: 20130177819Abstract: A rechargeable lithium battery includes a negative electrode including a negative active material, a positive electrode including a positive active material, an electrolyte including a polymer, an additive having a borate structure, a lithium salt, and an organic solvent. The electrolyte includes about 0.1 wt % to about 10 wt % of the additive having a borate structure based on 100 wt % of the electrolyte. The organic solvent includes an acetate-based compound and a cyclic carbonate-based compound, and an amount of the acetate-based compound is larger than that of the cyclic carbonate-based compound.Type: ApplicationFiled: September 14, 2012Publication date: July 11, 2013Applicant: Samsung SDI Co., Ltd.Inventor: Su-Hee Han
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Publication number: 20130177818Abstract: A rechargeable lithium battery includes a negative electrode including a negative active material, a positive electrode including a positive active material, and an electrolyte including LiPO2F2 and a sultone-based compound.Type: ApplicationFiled: August 15, 2012Publication date: July 11, 2013Inventors: Su-Hee Han, Young-Gyu Kim, Byung-Hwa Kim
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Patent number: 8481215Abstract: An electrolyte includes (a) a eutectic mixture of an alkoxy alkyl group-containing amide compound and an ionizable lithium salt; and (b) a carbonate-based compound. The electrolyte has excellent thermal and chemical stability and exhibits a low lowest limit of electrochemical window. Also, the electrolyte shows low viscosity and high ion conductivity, so it may be usefully applied as an electrolyte of electrochemical devices using various anode materials.Type: GrantFiled: July 24, 2009Date of Patent: July 9, 2013Assignee: LG Chem, Ltd.Inventors: Byoung-Bae Lee, Jae-Seung Oh, Ji-Won Park, Dong-Su Kim, Hyo-Jin Lee, Yeon-Suk Hong
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Publication number: 20130164630Abstract: A secondary battery includes: a cathode; an anode; and a gel electrolyte. The gel electrolyte includes an electrolytic solution and a polymer compound. The electrolytic solution includes an unsaturated cyclic ester carbonate represented by the following Formula (1), where X is a divalent group in which m number of >C?CR1-R1 and n number of >CR3R4 are bonded in any order; each of R1 to R4 is one of a hydrogen group, a halogen group, a monovalent hydrocarbon group, a monovalent halogenated hydrocarbon group, a monovalent oxygen-containing hydrocarbon group, and a monovalent halogenated oxygen-containing hydrocarbon group; any two or more of the R1 to the R4 are allowed to be bonded to one another; and m and n satisfy m?1 and n?0.Type: ApplicationFiled: December 11, 2012Publication date: June 27, 2013Applicant: SONY CORPORATIONInventor: Sony Corporation
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Patent number: 8460831Abstract: The present invention relates to paste-like masses that can be used in electrochemical elements, comprising a heterogeneous mixture of (A) a matrix containing or comprising at least one organic polymer, precursors thereof, or prepolymers thereof, (B) an electrochemically activatable inorganic or largely inorganic liquid that does not dissolve the matrix or essentially does not dissolve the matrix, and, if required, (C) a powdery solid that is essentially inert relative to the electrochemically activatable liquid.Type: GrantFiled: November 8, 2004Date of Patent: June 11, 2013Assignee: Leclanche' SAInventors: Peter Birke, Gerold Neumann
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Publication number: 20130143096Abstract: Electrode protection in electrochemical cells, and more specifically, electrode protection in both aqueous and non-aqueous electrochemical cells, including rechargeable lithium batteries, are presented. In one embodiment, an electrochemical cell includes an anode comprising lithium and a multi-layered structure positioned between the anode and an electrolyte of the cell. A multi-layered structure can include at least a first single-ion conductive material layer (e.g., a lithiated metal layer), and at least a first polymeric layer positioned between the anode and the single-ion conductive material. The invention also can provide an electrode stabilization layer positioned within the electrode, i.e., between one portion and another portion of an electrode, to control depletion and re-plating of electrode material upon charge and discharge of a battery.Type: ApplicationFiled: November 15, 2012Publication date: June 6, 2013Applicant: Sion Power CorporationInventor: Sion Power Corporation
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Publication number: 20130136998Abstract: An electrolyte composition including a macro azo initiator containing a polyethylene oxide repeating unit, and a multi-functional urethane acrylate-based monomer, a gel polymer electrolyte including the electrolyte composition, and a lithium battery including the gel polymer electrolyte.Type: ApplicationFiled: September 12, 2012Publication date: May 30, 2013Applicant: SAMSUNG ELECTRONICS CO., LTD.Inventors: Seung-sik Hwang, Moon-seok Kwon, Myung-hoon Kim, Jeong-kuk Shon, Min-sang Song, Jae-man Choi
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Patent number: 8445141Abstract: The present invention relates to a sulfonic acid group-containing polymer excellent in ion conductivity and durability, a method for producing the same, a resin composition containing the sulfonic acid group-containing polymer, a polymer electrolyte membrane, a polymer electrolyte membrane/electrode assembly, and a fuel cell. The sulfonic acid group-containing polymer of the present invention, in a first embodiment, includes a constituent represented by the following chemical formula 1: wherein X represents hydrogen or a monovalent cation species; Y represents a sulfone group or a ketone group; and n represents an arbitrary integer not less than 2.Type: GrantFiled: June 6, 2006Date of Patent: May 21, 2013Assignee: Toyo Boseki Kabushiki KaishaInventors: Kota Kitamura, Yoshimitsu Sakaguchi, Hiroki Yamaguchi, Masahiro Yamashita, Kousuke Sasai
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Patent number: 8394539Abstract: Lithium salts with fluorinated chelated orthoborate anions are prepared and used as electrolytes or electrolyte additives in lithium-ion batteries. The lithium salts have two chelate rings formed by the coordination of two bidentate ligands to a single boron atom. In addition, each chelate ring has two oxygen atoms bonded to one boron atom, methylene groups bonded to the two oxygen atoms, and one or more fluorinated carbon atoms bonded to and forming a cyclic bridge between the methylene groups.Type: GrantFiled: June 21, 2012Date of Patent: March 12, 2013Assignee: GM Global Technology Operations LLCInventors: Olt E. Geiculescu, Ion C. Halalay, Darryl D. Desmarteau, Stephen E. Creager