Abstract: An ionogel is formed by mixture of precursors, a catalyst, and an ionic liquid to form a sol-gel. The precursors and the catalyst react to form a solid-phase matrix that includes pores, wherein the ionic liquid is disposed within the pores. The gel is dried by way of thermal or vacuum drying to remove liquid byproducts of the precursor-catalyst reaction and to form a solid-state ionogel that comprises the solid-phase matrix with the ionic liquid disposed therein. The ionogel is immersed in a quantity of a liquid electrolyte that is soluble in the ionic liquid. As the liquid electrolyte dissolves into the ionic liquid, the ionic liquid is displaced by the liquid electrolyte, yielding an ionogel having the liquid electrolyte disposed within its pores.

Abstract: According to one embodiment, an electrode group is provided. The electrode group includes a positive electrode, a negative electrode, and a gel polymer layer interposed between the positive electrode and the negative electrode. At least a part of the negative electrode is opposed to the positive electrode. The gel polymer layer is formed of a gel electrolyte composed of a polymer material, an organic solvent and a lithium salt, and a sheet base member which supports the gel electrolyte, or the gel polymer layer is formed of only the gel electrolyte.

Abstract: Set forth herein are electrolyte compositions that include both organic and inorganic constituent components and which are suitable for use in rechargeable batteries. Also set forth herein are methods and systems for making and using these composite electrolytes.

Abstract: An electrochemical device includes an electrolyte having a hydroxamate or N-hydroxyamide compound.

Abstract: A method of manufacturing a negative electrode for a secondary battery includes a first step of preparing a lithium metal sheet coated with a lithium metal or to which the lithium metal is adhered in a form of a thin film on a release film and wound into a roll, a second step of laminating the lithium metal sheet to allow the lithium metal to be adjacent to a negative electrode material mixture, to thereby manufacture a negative electrode in which lithium metal is laminated and a third step of applying pressure to the negative electrode. The release film is coated with silicon. The negative electrode manufacturing method uniformly laminates or bonds lithium metal which is difficult to handle on the negative electrode material mixture of the secondary battery and advantageously enhances the speed of the pre-lithiation by using the patterned lithium metal.

Abstract: The present disclosure relates to an ion gel having superior ion conductivity and mechanical strength, a polymer electrolyte including the same, and a manufacturing method thereof. The method of manufacturing the ion gel is capable of simply and effectively manufacturing a polymer matrix through a one-pot reaction, thus exhibiting simple processing steps to thereby manifest excellent processing efficiency and generate economic benefits. Moreover, the polymer electrolyte including the ion gel can exhibit superior ion conductivity and mechanical strength despite the low glass transition temperature (Tg) of the monomer contained in the polymer matrix.

Abstract: A fuel cell electrolyte includes a nitrogen-doped phosphate tetrahedral network having a plurality of linked tetrahedra, each of the plurality of the linked tetrahedra having a phosphorus cation center and four anions including oxygen or nitrogen, the network having at least one compound of formula (I): H3+xPO4?xNx where x is any number between 0.001 and 3.

Abstract: Materials for decontamination of compounds having a phosphorous-sulfur bond or a phosphorous-oxygen bond. A porous polymer, such as poly(dicyclopentadiene), contains particles of zirconium hydroxide. The polymer optionally has hydroperoxide groups.

Abstract: To solve the problems that the existing non-aqueous electrolyte for lithium ion battery containing fluorinated solvent generates serious gas expansion when improving high-temperature cycle performance and affects high-temperature safety performance of battery. The application provides a non-aqueous electrolyte for lithium ion battery. The non-aqueous electrolyte for lithium ion battery comprises a compound A and a compound B, wherein the compound A is at least one of compounds represented by the following structural formula I, formula II and formula III; the compound B is a compound represented by the following structural formula IV; formula I: R1—COO—R2; formula II: R3—OCOO—R4.

Abstract: An endoscope includes a window component made of a transparent material at the distal end of the endoscope, wherein the window component is not rotationally symmetric in relation to the direction of view, and an optical correction apparatus with a cylindrical lens for correcting the aberration of the window component. The correction apparatus may contain a second lens movable relative to the cylindrical lens.

Abstract: The invention provides a ceramic separator, which mainly includes a plurality of passive ceramic particles and an ion-conductive material located between the passive ceramic particles. The mass content of the passive ceramic particles is greater than 40% of the total mass of the ceramic separator. The ion-conductive material is mainly composed of a polymer base material which is capable of allowing metal ions to move inside the material, and an additive, which is capable of dissociating metal salts and is served as a plasticizer. The ceramic separator of the present invention has high-temperature stability and high-temperature electrical insulation.

Abstract: To address the existing problem of insufficient cycle performance and high-temperature storage performance of lithium ion battery electrolyte at high pressure, the disclosure provides a non-aqueous electrolyte for lithium ion battery. The non-aqueous electrolyte for lithium ion battery comprises a cyano-containing compound A and a compound B represented by formula I, The non-aqueous electrolyte for lithium ion battery provided by the disclosure contains both the cyano-containing compound A and the compound B, so that the lithium ion battery containing the non-aqueous electrolyte can have better cycle performance and high-temperature storage performance at high pressure.

Abstract: The present invention provides a bio-electrode composition including (A) an ionic material and (C) a metal powder, wherein the component (A) is a polymer compound containing a repeating unit-a having a structure selected from the group consisting of an ammonium salt, a sodium salt, a potassium salt, and a silver salt of any of fluorosulfonic acid, fluorosulfonimide, and fluorosulfonamide. This can form a living body contact layer for a bio-electrode that is excellent in electric conductivity and biocompatibility, light-weight, manufacturable at low cost, and free from large lowering of the electric conductivity even though it is wetted with water or dried.

Abstract: Methods of removing a passivation layer on a lithium-containing electrode and preparing a protective coating on the lithium-containing electrode by applying a graphene source are provided herein. A lithium-containing electrode with the protective coating including graphene and lithium-containing electrochemical cells including the same are also provided herein.

Abstract: A lithium-containing electrode with a protective coating and lithium-containing electrochemical cells including the same are provided herein. The protective coating has a first layer including a first fluoropolymeric matrix and Li—F compounds and a second layer including a second fluoropolymeric matrix. Methods of preparing the protective coating on the lithium-containing electrode by applying a first fluoropolymer and/or a first fluoropolymer precursor and a second fluoropolymer and/or a second fluoropolymer precursor are also provided herein.

Abstract: A lithium secondary battery including: a positive electrode, a negative electrode, and a sulfide solid electrolyte disposed between the positive electrode and the negative electrode, wherein the positive electrode includes a positive active material particle and a coating film including an oxide including lithium (Li) and zirconium (Zr) on a surface of the positive active material particle.

Abstract: A method for preparing an electrode for use in lithium batteries and the resulting electrodes are described The method comprises coating a slurry of silicon, sulfur doped graphene and polyacrylonitrile on a current collector followed by sluggish heat treatment.

Abstract: A non-humidified proton-conductive membrane according to the present invention includes a polymer and a proton-conductive substance. The polymer includes a glassy or crystalline first site having a glass-transition temperature or melting temperature higher than the service temperature of the proton-conductive membrane and a second site capable of forming a noncovalent bond. The proton-conductive substance includes a proton-releasing/binding site capable of noncovalently binding to the second site of the polymer and a proton coordination site capable of coordinating to protons, the proton-releasing/binding site and the proton coordination site being included in different molecules that interact with each other or being included in the same molecule. A proton-conductive mixed phase that includes the second site to which the proton-releasing/binding site of the proton-conductive substance is bound and the proton-conductive substance is lower than the service temperature of the proton-conductive membrane.

Abstract: The present invention provides a bio-electrode composition capable of forming a living body contact layer for a bio-electrode that is excellent in conductivity and biocompatibility, is light-weight, can be manufactured at low cost, and can control significant reduction in conductivity even though the bio-electrode is soaked in water or dried. The present invention is accomplished by a bio-electrode composition including an (A) ionic material and a (B) resin other than the component (A), in which the component (A) has both a repeating unit “a” of a sodium salt, a potassium salt, or an ammonium salt including a partial structure represented by the following general formula (1) and a repeating unit “b” having a silicon atom.

Abstract: The present invention provides an organic sulfur material comprising carbon, hydrogen, and sulfur as constituent elements, and having peaks in the vicinity of 480 cm?1, 1250 cm?1, 1440 cm?1, and 1900 cm?1 in a Raman spectrum detected by Raman spectroscopy. The peak in the vicinity of 1440 cm?1 is the most intense peak. This organic sulfur material, which is produced by using a liquid organic starting material, achieves high capacity. This organic sulfur material preferably does not have peaks in the vicinity of 846 cm?1 or 1066 cm?1.

Abstract: The present invention provides a bio-electrode composition capable of forming a living body contact layer for a bio-electrode that is excellent in conductivity and biocompatibility, is light-weight, can be manufactured at low cost, and can control significant reduction in conductivity even though the bio-electrode is soaked in water or dried. The present invention is accomplished by a bio-electrode composition including an (A) ionic material and a (B) resin other than the component (A), in which the component (A) has both a repeating unit “a” of a lithium salt, a sodium salt, a potassium salt, or an ammonium salt of sulfonamide including a partial structure represented by the following general formula (1) and a repeating unit “b” having a silicon atom, —R1—C(?O)—N?—SO2—Rf1M+??(1).

Abstract: A method for manufacturing a fluoride ion conducting electrolyte solution which can improve ionic conductivity includes a step of heating a fluoride and/or a solvent when the fluoride and the solvent are mixed, wherein a heating temperature at the step is lower than a temperature at which the solvent decomposes.

Abstract: An adhesive composition including a resin and an electro-conductive material, wherein the electro-conductive material is one or more salts selected from sodium salt, potassium salt, and calcium salt having two fluorosulfonic acid structures per molecule and 5 or more carbon atoms shown by formula (1): ?O3S—Y—La-A-Lb-Y—SO3?(Mn+)2/n (1), wherein, A represents a divalent hydrocarbon group having 1-30 carbon atoms and optionally substituted by a heteroatom or optionally interposed by a heteroatom; La and Lb each represent a linking group like an ether group, ester group; Y represents an alkylene group having 2-4 carbon atoms, containing 1-6 fluorine atoms, and optionally containing a carbonyl group; Mn+ represents any of Na+, K+, Ca2+. This can form a living body contact layer for a bio-electrode with excellent electric conductivity, biocompatibility, and light weight, which can be manufactured at low cost and without large lowering of electric conductivity even when it is wetted with water or dried.

Abstract: An electrolyte is provided. The electrolyte includes a polymer, a lithium salt, and an organic solvent. The polymer is a polymerization product of a reactive additive and an initiator, wherein the reactive additive includes at least an amide group and at least an epoxy group or ethyl group. A composition for electrolyte and a lithium battery employing the electrolyte are also provided.

Abstract: A solid electrolyte represented by general formula LiySiRx(MO4), where x is an integer from 1 to 3 inclusive, y=4?x, each R present is independently C1-C3 alkyl or C1-C3 alkoxy, and M is sulfur, selenium, or tellurium. Methods of making the solid electrolyte include combining a phenylsilane and a first acid to yield mixture including benzene and a second acid, and combining at least one of an alkali halide, and alkali amide, and an alkali alkoxide with the second acid to yield a product d represented by general formula LiySiRx(MO4)y. The second acid may be in the form of a liquid or a solid. The phenylsilane includes at least one C1-C3 alkyl substituent or at least one C1-C3 alkoxy substituent, and the first acid includes at least one of sulfuric acid, selenic acid, and telluric acid.

Abstract: A compound made by copolymerizing a poly(N-isopropylacrylamide) chain transfer agent, an acrylate salt, and a polyethylene glycol diacrylate. A compound made by copolymerizing a polyethylene glycol, a glycerol ethoxylate, and an aliphatic diisocyanate.

Abstract: The use of fibril materials, such as fibril cellulose materials and other similar materials, in electrochemical cells and components thereof is generally described.

Abstract: A composite material including a carbon-containing material and a non-stoichiometric titanium compound shown by a chemical formula of Li4+xTi5?xO12, where x is in a range of 0<x<0.30, the composite material including at least one composite particle that has a core portion including the non-stoichiometric titanium compound and a mixed layer formed on a surface of the core portion, the mixed layer including non-stoichiometric titanium compound and carbon, and having an atomic ratio of titanium and carbon in a range of Ti/C=1/50 or more.

Abstract: The present invention relates to a method for producing a polymer electrolyte molded article, which comprises forming a polymer electrolyte precursor having a protective group and an ionic group, and deprotecting at least a portion of protective groups contained in the resulting molded article to obtain a polymer electrolyte molded article. According to the present invention, it is possible to obtain a polymer electrolyte material and a polymer electrolyte molded article, which are excellent in proton conductivity and are also excellent in fuel barrier properties, mechanical strength, physical durability, resistance to hot water, resistance to hot methanol, processability and chemical stability. A polymer electrolyte fuel cell using a polymer electrolyte membrane, polymer electrolyte parts or a membrane electrode assembly can achieve high output, high energy density and long-term durability.

Abstract: To provide a simple method whereby an ionic polymer membrane having a high ion exchange capacity and a low water uptake can be produced by converting a —SO2F group in a polymer to a pendant group having multiple ion exchange groups, while preventing a cross-linking reaction. At the time of obtaining an ionic polymer membrane by converting —SO2F (group (1)) in a polymer sequentially to —SO2NZ1Z2 (group (2)), —SO2N?(M?+)SO2(CF2)2SO2F (group (3)), —SO2N?(H+)SO2(CF2)2SO2F (group (4)) and —SO2N?(M?+)SO2(CF2)2SO3?M?+ (group (5)), the polymer is formed into a polymer membrane in the state of any one of the groups (1) to (4), and the polymer membrane is thermally treated in the state of group (4). Here, Z1 and Z2 are hydrogen atoms, etc., M?+ is a monovalent cation, and M?+ is a hydrogen ion or a monovalent cation.

Abstract: A secondary battery includes: a cathode; an anode; and an electrolytic solution. The cathode contains an active material capable of inserting and extracting an electrode reactant. A ratio IS/IF of a peak intensity IS derived from SO2? and a peak intensity IF derived from LiF2? is 0.04 or more, the peak intensity IS and the peak intensity IF being obtained by negative ion analysis on the active material with use of time-of-flight secondary ion mass spectrometry. Since a secondary battery according to the present invention has an intensity ratio IS/IF of 0.04 or more as obtained by a negative ion analysis of the active material using time-of-flight secondary ion mass spectrometry, the secondary battery is able to achieve excellent battery characteristics.

Abstract: A gel electrolyte for a rechargeable lithium battery includes a gel polymer including a repeating unit derived from a first monomer represented by A-L-E, a non-aqueous organic solvent, a lithium salt, and an additive. A rechargeable lithium battery includes the gel electrolyte. The additive includes a compound selected from compounds represented by compounds represented by derivatives thereof, and combinations thereof.

Abstract: Gel electrolytes, especially gel electrolytes for electrochemical cells, are generally described. In some embodiments, the gel electrolyte layers comprise components a) to c). Component a) may be at least one layer of at least one polymer comprising polymerized units of: a1) at least one monomer containing an ethylenically unsaturated unit and an amido group and a2) at least one crosslinker. Component b) may be at least one conducting salt and component c) may be at least one solvent. Electrodes may comprise the components a), d) and e), wherein component a) may be at least one layer of at least one polymer as described herein. Component d) may be at least one electroactive layer and component e) may be at least one ceramic layer. Furthermore, electrochemical cells comprising component a) which may be at least one layer of at least one polymer as described herein, are also provided.

Abstract: One embodiment includes a method of forming a hydrophilic particle containing electrode including providing a catalyst; providing hydrophilic particles suspended in a liquid to form a liquid suspension; contacting said catalyst with said liquid suspension; and, drying said liquid suspension contacting said catalyst to leave said hydrophilic particles attached to said catalyst.

Abstract: An electrochemical cell including at least one nitrogen-containing compound is disclosed. The at least one nitrogen-containing compound may form part of or be included in: an anode structure, a cathode structure, an electrolyte and/or a separator of the electrochemical cell. Also disclosed is a battery including the electrochemical cell.

Abstract: The invention relates to a BA diblock or BAB triblock copolymer, in which the A block is a non-substituted poly-oxyethylene chain having a mean molecular weight that is no higher than 100 kDa, and the B block is an anionic polymer which can be prepared using one or more monomers selected from among the vinyl monomers and derivatives thereof, said monomers being substituted with a (trifluoromethylsulfonyl)imide (TFSI) anion. The invention also relates to the uses of such a copolymer, in particular for preparing an electrolyte composition for lithium metal polymer (LMP) batteries.

Abstract: Provided are an electrode for solid-state batteries, a method of preparing the electrode, a solid-state battery including the electrode, and a bonding film used for the method of preparing the electrode. The electrode for solid-state batteries include a bonding layer interposed between an electrode layer and a current collecting member and bound to the electrode layer, where the bonding layer includes a first binder which is inactive to the solid electrolyte, a second binder which has a stronger binding ability to the current collecting member than a bonding strength of the first binder to the current collecting member; and a bonding layer conductive material.

Abstract: An electrolyte additive and electrolyte and lithium rechargeable battery including the electrolyte additive are provided. The electrolyte additive may be a monosubstituted pentafluorocyclotriphosphazene.

Abstract: The present invention provides a fuel cell electrode, and a method for manufacturing a membrane-electrode assembly (MEA) using the same. The fuel cell electrode is formed by adding carbon nanotubes to reinforce the mechanical strength of the electrode, cerium-zirconium oxide particles to prevent corrosion of a polymer electrolyte membrane, and an alloy catalyst prepared by alloying a second metal (such as Ir, Pd, Cu, Co, Cr, Ni, Mn, Mo, Au, Ag, V, etc.) with platinum to prevent the dissolution, migration, and agglomeration of platinum.

Abstract: When an active material with low ionic conductivity and low electric conductivity is used in a nonaqueous electrolyte secondary battery such as a lithium ion battery, it is necessary to reduce the sizes of particles; however, reduction in sizes of particles leads to a decrease in electrode density. Active material particles of an oxide, which include a transition metal and have an average size of 5 nm to 50 nm, are mixed with an electrolyte, a binder, and the like to form a slurry, and the slurry is applied to a collector. Then, the collector coated with the slurry is exposed to a magnetic field. Accordingly, the active material particles aggregate so that the density thereof increases. Alternatively, the active material particles may be applied to the collector in a magnetic field. The use of the aggregating active material particles makes it possible to increase the electrode density.

Abstract: One embodiment includes a method of forming a hydrophilic particle containing electrode including providing a catalyst; providing hydrophilic particles suspended in a liquid to form a liquid suspension; contacting said catalyst with said liquid suspension; and, drying said liquid suspension contacting said catalyst to leave said hydrophilic particles attached to said catalyst.

Abstract: We report a heteroatom-doped carbon framework that acts both as conductive network and polysulfide immobilizer for lithium-sulfur cathodes. The doped carbon forms chemical bonding with elemental sulfur and/or sulfur compound. This can significantly inhibit the diffusion of lithium polysulfides in the electrolyte, leading to high capacity retention and high coulombic efficiency.

Abstract: A solid polymer electrolyte composition having good conductivity and better mechanical strength is provided. The solid polymer electrolyte composition includes at least one lithium salt and a crosslinking polymer containing at least a first segment, a second segment, a third segment, and a fourth segment. The first segment includes polyalkylene oxide and/or polysiloxane backbone. The second segment includes urea and/or urethane linkages. The third segment includes silane domain. The fourth segment includes phenylene structure. Moreover, the solid polymer electrolyte composition further includes an additive for improving ionic conductivity thereof.

Abstract: Methods of manufacturing electrochemical cells having a current collector which, at least in part, underlies a catalyst layer are discussed. A method comprises patterning a current collector to have at least one electrolyte opening, disposing an electrolyte into or through the at least one opening, and disposing a catalyst, at least in part, over the disposed electrolyte. Optionally, the method comprises pattering a substrate and attaching a patterned current collector to each side thereof. Patterning of the current collector can include patterning a continuous sheet, which comprises at least a first and a second separable current collector. In one such example, a continuous carbon-fiber sheet impregnated or laminated with a non-porous material is patterned. In another such example, a continuous plastic material sheet impregnated with one or more electrical conductive particles is patterned. Among other things, the pattern of the current collector can include an extruded slot or adjacently-disposable strips.

Abstract: A novel anode for a lithium battery cell is provided. The anode contains silicon nanoparticles embedded in a solid polymer electrolyte. The electrolyte can also act as a binder for the silicon nanoparticles. A plurality of voids is dispersed throughout the solid polymer electrolyte. The anode may also contain electronically conductive carbon particles. Upon charging of the cell, the silicon nanoparticles expand as take up lithium ions. The solid polymer electrolyte can deform reversibly in response to the expansion of the nanoparticles and transfer the volume expansion to the voids.

Abstract: Provided are an electrolyte comprising an amide compound of a specific structure, in which an alkoxy group is substituted with an amine group, and an ionizable lithium salt, and an electrochemical device containing the same. The electrolyte may have excellent thermal and chemical stability and a wide electrochemical window. Also, the electrolyte may have a sufficiently low viscosity and a high ionic conductivity, and thus, may be usefully applied as an electrolyte of electrochemical devices using various anode materials.

Abstract: A solid-state electrolyte for rechargeable lithium batteries. The solid state electrolyte comprises a large unsaturated aromatic anion and a lithium charge carrier. The large unsaturated aromatic anion is selected from a di-lithium phthalocyanine and a di-lithium porphyrin, wherein one of the lithium ions of the unsaturated aromatic anion is replaced with a nitrogenous cation.

Abstract: A solid electrolyte material that can react with an electrode active material to forms a high-resistance portion includes fluorine.

Abstract: The Coulombic efficiency of metal deposition/stripping can be improved while also preventing dendrite formation and growth by an improved electrolyte composition. The electrolyte composition also reduces the risk of flammability. The electrolyte composition includes a polymer and/or additives to form high quality SEI layers on the anode surface and to prevent further reactions between metal and electrolyte components. The electrolyte composition further includes additives to suppress dendrite growth during charge/discharge processes. The electrolyte composition can also be applied to lithium and other kinds of energy storage devices.

Abstract: Hybrid radical energy storage devices, such as batteries or electrochemical devices, and methods of use and making are disclosed. Also described herein are electrodes and electrolytes useful in energy storage devices, for example, radical polymer cathode materials and electrolytes for use in organic radical batteries.