Halogen Containing Polymer Patents (Class 429/316)
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Patent number: 12155087Abstract: A separator for an electrochemical device comprising a porous polymer substrate, and a porous coating layer on at least one surface of the porous polymer substrate. The porous coating layer comprises inorganic particles and an ion conducting polymer. The ion conducting polymer comprises a fluorine-based copolymer comprising fluoroolefin-based segments with anionic functional groups present in side chains or terminals, and an electrochemical device comprising the same. It is possible to provide a separator with high ionic conductivity and an increased peel strength between the porous polymer substrate and the porous coating layer, and an electrochemical device with improved properties.Type: GrantFiled: May 14, 2020Date of Patent: November 26, 2024Assignee: LG ENERGY SOLUTION, LTD.Inventors: Hyun-Woong Yun, Jong-Keon Yoon, Hoe-Jin Hah
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Patent number: 12148882Abstract: The present disclosure relates to a method for manufacturing a solid-state battery, wherein slurry for a solid electrolyte layer is applied to each of the electrodes, and the electrodes are bound to each other before drying to obtain a solid-state battery. In the solid-state battery, each electrode is in close contact with the solid electrolyte membrane to provide excellent interfacial property, such as reduced resistance. In addition, the thickness of the solid electrolyte membrane may be controlled to a level of several microns to provide an effect of increasing the energy density of a unit cell.Type: GrantFiled: October 15, 2019Date of Patent: November 19, 2024Assignee: LG Energy Solution, Ltd.Inventors: Suk-Woo Lee, Eun-Bee Kim, Ji-Hoon Ryu, Jung-Pil Lee
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Patent number: 12057604Abstract: Improvements in the structural components and physical characteristics of lithium battery articles are provided. Standard lithium ion batteries, for example, are prone to certain phenomena related to short circuiting and have experienced high temperature occurrences and ultimate firing as a result. Structural concerns with battery components have been found to contribute to such problems. Improvements provided herein include the utilization of thin metallized current collectors (aluminum and/or copper, as examples), high shrinkage rate materials, materials that become nonconductive upon exposure to high temperatures, and combinations thereof. Such improvements accord the ability to withstand certain imperfections (dendrites, unexpected electrical surges, etc.) within the target lithium battery through provision of ostensibly an internal fuse within the subject lithium batteries themselves that prevents undesirable high temperature results from short circuits.Type: GrantFiled: November 30, 2020Date of Patent: August 6, 2024Assignee: Soteria Battery Innovation Group, Inc.Inventor: Brian G. Morin
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Patent number: 12027663Abstract: Provided is an ion-conductive solid electrolyte compound, as a crystalline oxide, including a stoichiometric formula of “Ax(M2TO8)y”. In the stoichiometric formula, A is a cation having an oxidation state of +1, M is a cation having an oxidation state of +4, +5, or +6, T is a cation having an oxidation state of +4, +5, or +6, and x and y are each independently a real number greater than 0, wherein x is equal to or less than 3y. The ion-conductive solid electrolyte compound has a high ionic conductivity and a low electronic conductivity.Type: GrantFiled: May 7, 2019Date of Patent: July 2, 2024Assignee: SAMSUNG ELECTRONICS CO., LTD.Inventors: Seung-Joo Kim, Jaegyeom Kim
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Patent number: 11967680Abstract: A gel polymer electrolyte composition, a secondary battery including the same, and a manufacturing method of a secondary battery are disclosed. Advantages of the disclosed aspects include increasing process efficiency by reducing the curing time of a gel polymer electrolyte while preventing leakage of an electrolyte.Type: GrantFiled: January 11, 2023Date of Patent: April 23, 2024Assignee: LG ENERGY SOLUTION, LTD.Inventors: Won Kyung Shin, Won Tae Lee, Young Ho Oh, Chul Haeng Lee, Kyoung Ho Ahn
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Patent number: 11967721Abstract: A battery cathode includes: a current collector; and a coating applied to the current collector, the coating including: conductive carbon; polyvinylidene fluoride binder polymer; acid-functionalized dispersant polymer; and electrochemically active layered metal oxide.Type: GrantFiled: November 23, 2022Date of Patent: April 23, 2024Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLCInventors: Bradley R Frieberg, Mengyuan Chen, Roland J. Koestner, Xiaosong Huang
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Patent number: 11961968Abstract: The present invention provides a lithium ion secondary battery which is provided with: a nonaqueous electrolyte solution; and a positive electrode and a negative electrode, each of which is capable of absorbing and desorbing lithium. This lithium ion secondary battery is configured such that the nonaqueous electrolyte solution contains (A) an electrolyte, (B) a nonaqueous organic solvent and (C) a compound that is obtained by substituting at least one hydrogen atom, which is bonded to a carbon atom in an aromatic ring of a compound that has at least one aromatic ring and no amino group, by a group that is represented by formula (1); and this lithium ion secondary battery is charged at a voltage within the range of 4.35-5 V for use.Type: GrantFiled: March 28, 2019Date of Patent: April 16, 2024Assignee: NISSAN CHEMICAL CORPORATIONInventor: Yuki Shibano
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Patent number: 11949061Abstract: A secondary battery, suitable for a portable information terminal or a wearable device is provided. An electronic device having a novel structure which can have various forms and a secondary battery that fits the forms of the electronic device are provided. In the secondary battery, sealing is performed using a film provided with depressions or projections that ease stress on the film due to application of external force. A pattern of depressions or projections is formed on the film by pressing, e.g., embossing.Type: GrantFiled: August 31, 2022Date of Patent: April 2, 2024Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Minoru Takahashi, Ryota Tajima
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Patent number: 11817552Abstract: The present disclosure discloses a method for plasma modification of sodium super ionic conductor type solid electrolyte, which comprises: dielectric barrier discharge plasma modification of sodium super ionic conductor solid electrolyte particles to obtain activated sodium super ionic conductor solid electrolyte particles; weigh the polymer and the activated sodium super ionic conductor solid electrolyte particles in a predetermined proportion, dissolve the polymer and the activated sodium super ionic conductor solid electrolyte particles in an organic solvent to obtain a mixed solution, then pour the mixed solution into a preset mold, and then dry it to remove the organic solvent and form a composite solid electrolyte film. The composite solid electrolyte film is taken out of the mold and rolled to obtain the composite solid electrolyte film after rolling treatment.Type: GrantFiled: November 24, 2022Date of Patent: November 14, 2023Assignees: KUNMING UNIVERSITY OF SCIENCE AND TECHNOLOGY, JIANGSU FENGCHI CARBON-BASED NEW MATERIALS RESEARCH INSTITUTE CO., LTD.Inventors: Feng Liang, Minjie Hou, Da Zhang, Tao Zhang, Sunzu Xiang, Wenlong Jiang, Baoqiang Xu, Bin Yang
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Patent number: 11804619Abstract: The invention relates to a solid polymer electrolyte for a battery comprising at least one polymer which solvates the cations of a lithium salt, at least one lithium salt and at least one specifically selected halogenated polymer, and also to the lithium batteries comprising such a solid polymer electrolyte, in particular LMP batteries.Type: GrantFiled: September 17, 2018Date of Patent: October 31, 2023Assignee: BLUE SOLUTIONSInventors: Philippe Bernardo, Vincent Bodenez, Marc Deschamps, Mathieu Dru, Margaud Lecuyer
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Patent number: 11799125Abstract: Improvements in the structural components and physical characteristics of lithium battery articles are provided. Standard lithium ion batteries, for example, are prone to certain phenomena related to short circuiting and have experienced high temperature occurrences and ultimate firing as a result. Structural concerns with battery components have been found to contribute to such problems. Improvements provided herein include the utilization of thin metallized current collectors (aluminum and/or copper, as examples), high shrinkage rate materials, materials that become nonconductive upon exposure to high temperatures, and combinations thereof. Such improvements accord the ability to withstand certain imperfections (dendrites, unexpected electrical surges, etc.) within the target lithium battery through provision of ostensibly an internal fuse within the subject lithium batteries themselves that prevents undesirable high temperature results from short circuits.Type: GrantFiled: September 1, 2020Date of Patent: October 24, 2023Assignee: Soteria Battery Innovation Group, Inc.Inventors: Brian G Morin, Carl C. Hu
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Patent number: 11777175Abstract: A separator includes a porous substrate, and a porous layer formed on one or both surfaces of the substrate and containing a polyvinylidene fluoride type resin and a filler, in which the filler content in the porous layer is from 30 to 80% by mass with respect to the total mass of the polyvinylidene fluoride type resin and the filler, and the polyvinylidene fluoride type resin is at least one resin selected from the following resin A and B: resin A: a copolymer having a weight average molecular weight of from 100,000 to 350,000, and a content of HFP is more than 5% by mass but not more than 11% by mass; and resin B: a copolymer having a weight average molecular weight of from 100,000 to 1,000,000, in which a content of HFP is more than 11% by mass but not more than 15% by mass.Type: GrantFiled: June 30, 2016Date of Patent: October 3, 2023Assignee: TEIJIN LIMITEDInventors: Susumu Honda, Satoshi Nishikawa, Takashi Yoshitomi, Tomoya Hamada, Yoshimitsu Takano
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Patent number: 11557792Abstract: An electrolyte for a lithium-secondary battery including a solvent, a lithium salt and an additive, wherein the additive includes a diamine-based compound, and a lithium-secondary battery including the same.Type: GrantFiled: September 21, 2018Date of Patent: January 17, 2023Assignee: LG ENERGY SOLUTION, LTD.Inventors: Seung Yoon Yang, Dongwook Koh, Doo Kyung Yang
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Patent number: 11462804Abstract: Various battery cell arrangements are presented herein. The battery cell can include an anode current collector. The battery cell can include a carbon-based anode coating layer that coats the anode current collector. A first bond between the anode current collector and the anode coating layer may have a first adhesion strength. The battery cell also includes a cathode, a separator layer that contacts the cathode, and a separator coating layer. The separator coating layer can be positioned between the anode coating layer and the separator layer. A second bond between the separator coating material and the anode coating material has a second adhesion strength. The second adhesion strength of the second bond may be greater than the first adhesion strength of the first bond.Type: GrantFiled: January 8, 2019Date of Patent: October 4, 2022Assignee: TeraWatt Technology Inc.Inventors: Hiroshi Imoto, Ken Ogata, Juichi Arai, Yang Yang
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Patent number: 11404747Abstract: A zinc-based battery includes a non-sintered separator system including a polymer separator and a coating on the polymer separator. The coating includes cellulose acetate that prevents metallic zinc penetration into the separator, and ceria bound with the cellulose acetate that chemically oxidizes metallic zinc to zinc oxide.Type: GrantFiled: February 18, 2022Date of Patent: August 2, 2022Assignee: ZAF ENERGY SYSTEMS, INCORPORATEDInventors: Adam Weisenstein, Allen Charkey, Melissa D. McIntyre
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Patent number: 11316183Abstract: The present specification relates to a complex electrolyte membrane, an enhanced complex electrolyte membrane and a fuel cell including the same.Type: GrantFiled: September 1, 2016Date of Patent: April 26, 2022Assignee: LG CHEM, LTD.Inventors: Curie Park, Hyuk Kim, Minkyu Min, Ji Hun Kim, Insung Bae
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Patent number: 11276849Abstract: The present invention provides a positive electrode for non-aqueous electrolyte secondary battery, having novel overcharge protection functions. The present invention provides a positive electrode for non-aqueous electrolyte secondary battery, comprising a carbon layer and a positive-electrode active material layer provided on the carbon layer, wherein the carbon layer includes graphitizable carbon.Type: GrantFiled: May 12, 2016Date of Patent: March 15, 2022Assignee: ELIIY POWER CO., LTDInventors: Tomitaro Hara, Yusuke Kuzushima
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Patent number: 11233227Abstract: A manufacturing method of a belt-shaped electrode plate includes: forming an active material layer by drying a wet active material layer by heating in a drying furnace; and bringing n pieces of cooling rolls or the like into contact with the belt-shaped electrode plate carried out from the drying furnace, so as to cool down the belt-shaped electrode plate by the cooling rolls or the like while the belt-shaped electrode plate is bent in the thickness direction and conveyed in the longitudinal direction by the cooling rolls or the like. The n pieces of cooling rolls or the like are disposed such that a contact length is shorter as a temperature difference of the belt-shaped electrode plate is larger.Type: GrantFiled: June 28, 2019Date of Patent: January 25, 2022Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventor: Naoya Kishimoto
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Patent number: 10826038Abstract: A secondary battery includes: a cathode and an anode opposed to each other with a separator in between; an electrolyte layer provided between the anode and the separator; and an adhesion layer provided between the anode and the electrolyte layer, wherein the anode includes an active material and a first polymer compound, the electrolyte layer includes an electrolytic solution and a second polymer compound, the adhesion layer includes a third polymer compound, the first polymer compound includes a polar group, the second polymer compound includes a polymer chain, and the third polymer compound includes a polar group and a polymer chain same as the polymer chain of the second polymer compound.Type: GrantFiled: August 23, 2013Date of Patent: November 3, 2020Assignee: MURATA MANUFACTURING CO., LTD.Inventors: Keitaro Kitada, Takashi Fujinaga
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Patent number: 10700331Abstract: A separator for a rechargeable lithium battery includes a backbone polymer, an ion conductive polymer coating the backbone polymer, and an electrolyte solution immersing the backbone polymer, wherein the backbone polymer and the ion conductive polymer are different from each other.Type: GrantFiled: May 31, 2013Date of Patent: June 30, 2020Assignees: Samsung SDI Co., Ltd., Robert Bosch GmbHInventors: In Kim, Hyung-Sik Kim, Duk-Jung Kim, Zin Park
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Patent number: 10468663Abstract: An electrode with a porous binder coating layer may be manufactured in a method including (S10) a step of preparing the electrode including an active material layer formed on at least one surface of a current collector; (S20) a step of acquiring a binder emulsion by adding a binder to a dispersion medium; and (S30) a step of coating the binder emulsion acquired at the step (S20) on a surface of the active material layer of the electrode in a screen printing method using a mesh to form a binder coating layer of a porous structure.Type: GrantFiled: March 11, 2016Date of Patent: November 5, 2019Assignee: LG Chem, Ltd.Inventors: Hyun-Kyung Shin, Min-Hyung Kim, Dong-Wook Sung, In-Hyouk Sung, Ji-Eun Lee, Joo-Sung Lee
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Patent number: 10367228Abstract: New homopolymers and copolymers of diester-based polymers have been synthesized. When these polymers are combined with electrolyte salts, such polymer electrolytes have shown excellent electrochemical oxidation stability in lithium battery cells. Their stability along with their excellent ionic conductivities make them especially suitable as electrolytes in high energy density lithium battery cells.Type: GrantFiled: August 21, 2017Date of Patent: July 30, 2019Assignee: Seeo, Inc.Inventors: Malar Azagarsamy, Hany Basam Eitouni, Kulandaivelu Sivanandan
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Patent number: 9991514Abstract: Provided are a method of manufacturing a lithium nickel complex oxide including mixing a nickel-containing mixed transition metal precursor, a lithium compound, and a polyvinylidene fluoride-hexafluoropropylene (PVdF-HFP) copolymer, and heat treating the mixture, a lithium nickel complex oxide manufactured thereby, and a cathode active material including the lithium nickel complex oxide. The method of manufacturing a lithium nickel complex oxide according to an embodiment of the present invention may adjust a ratio of divalent nickel (NiII) to trivalent nickel (NiIII) by using a polyvinylidene fluoride-hexafluoropropylene (PVdF-HFP) copolymer, and thus, the method may improve capacity of a secondary battery.Type: GrantFiled: August 12, 2014Date of Patent: June 5, 2018Assignee: LG Chem, Ltd.Inventors: Ji Hye Kim, Sung Bin Park, Wang Mo Jung, Sang Seung Oh, Byung Chun Park
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Patent number: 9887433Abstract: The present invention provides copolymers of polyethylene oxide methacrylate and alkenyl group-containing methacrylate, method for preparing the same and use thereof. The copolymers may be used for preparing solid phase electrolytes having high ionic conductivity and enhanced physical properties.Type: GrantFiled: July 11, 2014Date of Patent: February 6, 2018Assignee: SEOUL NATIONAL UNIVERSITY R&DB FOUNDATIONInventors: Jong-Chan Lee, Ji-Hoon Baik, Dong-Gyun Kim, Jimin Shim
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Patent number: 9356271Abstract: An electrochemical stack comprising carrier ions, an anode comprising an anode active material layer, a cathode comprising a cathode active material layer, a separator between the anode and the cathode comprising a porous dielectric material and a non-aqueous electrolyte, and an ionically permeable conductor layer located between the separator and an electrode active material layer.Type: GrantFiled: January 24, 2012Date of Patent: May 31, 2016Assignee: ENOVIX CORPORATIONInventors: Murali Ramasubramanian, Robert Spotnitz, Nirav Shah, Ashok Lahiri, Christopher Castledine, III, James D. Wilcox, Michael J. Armstrong, Robert A. Cole, Brian Brusca, Harold J. Rust, III, Ken S. Matsubayashi, Laurie J. Lauchlan, Gunther A. Koblmiller
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Vinylidene fluoride resin composition, resin film, back sheet for solar cells, and solar cell module
Patent number: 9318634Abstract: Provided is a vinylidene fluoride resin composition resistant to yellowing in the test for evaluation of durability of moist heat resistance, even when it is laminated directly on an ethylene vinyl acetate copolymer (EVA)-based sealing material, and a resin film, a back sheet for solar cells and a solar cell module comprising the same. A vinylidene fluoride resin composition at least comprising a vinylidene fluoride resin having a peak value ratio of head-to-tail bond to head-to-head bond (head-to-tail bond/head-to-head bond), as determined by 1H-NMR, of 11.5 or less and a mass-average molecular weight (Mw) of 1.30×105 or more, and an antioxidant is processed into a vinylidene fluoride resin film having a thickness of 10 to 200 ?m. The vinylidene fluoride resin film and an electric insulating resin film such as polyethylene terephthalate-based film are laminated, to give a back sheet for solar cells.Type: GrantFiled: July 12, 2012Date of Patent: April 19, 2016Assignee: Denka Company LimitedInventors: Tatsunori Sumino, Fukumu Komoda, Koji Nakajima -
Patent number: 9263740Abstract: A battery capable of inhibiting swollenness of the battery is provided. A cathode and an anode are layered with a separator and an electrolyte layer in between. The anode contains an anode active material containing Sn or Si as an element. The electrolyte layer contains an electrolytic solution and a high molecular weight compound. It is preferable that the distance between the cathode and the anode is from 15 ?m to 50 ?m, and the distance between the cathode and the separator and the distance between the anode and the separator are respectively from 3 ?m to 20 ?m. Thereby, expansion of the anode is absorbed, stress on the anode is reduced, and occurrence of wrinkles in the anode is inhibited.Type: GrantFiled: November 22, 2005Date of Patent: February 16, 2016Assignee: Sony CorporationInventor: Hiroshi Seino
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Patent number: 9142859Abstract: The present invention relates to polymer-silicon composite particles using silicon having high energy density, a method of making the same, an anode and a lithium secondary battery including the same. The silicon having high energy density is used as an anode active material to provide a lithium secondary battery having large capacity. Silicon-polymer composite particles having a metal plated on the surface thereof are provided to solve the problem that silicon has low electrical conductivity and a method of preparing the same is provided to produce an electrode having improved electrical conductivity. Furthermore, silicon-polymer composite particles having a metal coated on the surface thereof through electroless plating are prepared and an electrode is formed using the silicon-polymer composite particles.Type: GrantFiled: July 11, 2011Date of Patent: September 22, 2015Assignee: LG Chem, Ltd.Inventors: Sun Jung Hwang, Dong Seok Shin, Yoon Kyung Kwon, Geun Chang Chung, Jung Seok Choi
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Publication number: 20150140473Abstract: The invention pertains to a process for manufacturing a fluoropolynner film comprising a fluoropolymer hybrid organic/inorganic composite, said process comprising the following steps: (i) providing a mixture of:—at least one fluoropolymer [polymer (F)];—at least one metal compound [compound (M)] having formula: X4-mAYm wherein m is an integer from 1 to 4, A is a metal selected from the group consisting of Si, Ti and Zr, Y is a hydrolysable group and X is a hydrocarbon group, optionally comprising one or more functional groups;—a liquid medium consisting essentially of at least one ionic liquid (IL) and, optionally, at least one additive (A);—optionally, at least one electrolytic salt (ES); and—optionally, at least one organic solvent (S); (ii) hydrolysing and/or polycondensing said compound (M) to yield a liquid mixture comprising fluoropolymer hybrid organic/inorganic composite comprising inorganic domains and incorporating said liquid medium; (iii) processing a film from the liquid mixture obtained in stepType: ApplicationFiled: April 22, 2013Publication date: May 21, 2015Inventors: Julio A. Abusleme, Jean Le Bideau, Aurélie Guyomard-Lack, Dominique Guyomard, Bernard Lestriez
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Publication number: 20150132638Abstract: An electrolyte sheet including an electrolyte layer that includes electrolyte particles and a binder, and a base material stacked on the electrolyte layer, wherein the electrolyte particles have an ionic conductivity of 1.0×10?5 S/cm or more; the ratio of the electrolyte particles relative to the total weight of the electrolyte particles and the binder is 50 wt % or more and 99.5 wt % or less; and, after transferring the electrolyte layer in a transfer test, the electrolyte particles and the binder do not remain on the base material, and the electrolyte layer is transferred to an object without peeling.Type: ApplicationFiled: November 28, 2012Publication date: May 14, 2015Applicant: IDEMITSU KOSAN CO., LTD.Inventors: Hitomi Adachi, Hiroyuki Tamura, Toshiaki Tsuno
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Patent number: 9017881Abstract: Provided are an electrolyte comprising an amide compound of a specific structure, in which an alkoxy group is substituted with an amine group, and an ionizable lithium salt, and an electrochemical device containing the same. The electrolyte may have excellent thermal and chemical stability and a wide electrochemical window. Also, the electrolyte may have a sufficiently low viscosity and a high ionic conductivity, and thus, may be usefully applied as an electrolyte of electrochemical devices using various anode materials.Type: GrantFiled: September 2, 2011Date of Patent: April 28, 2015Assignee: LG Chem, Ltd.Inventors: Byoung-Bae Lee, Jae-Seung Oh, Ji-Won Park, Hyo-Jin Lee, Dong-Su Kim, Yeon-Suk Hong
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Patent number: 8968939Abstract: A solid electrolyte material that can react with an electrode active material to forms a high-resistance portion includes fluorine.Type: GrantFiled: April 28, 2010Date of Patent: March 3, 2015Assignee: Toyota Jidosha Kabushiki KaishaInventors: Yasushi Tsuchida, Koji Kawamoto, Yukiyoshi Ueno, Shigenori Hama, Masato Kamiya, Hiroshi Nagase
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Publication number: 20140349160Abstract: The purpose of the present invention is to provide a redox flow secondary battery which has low electrical resistance and excellent current efficiency in addition to durability. The present invention relates to: an electrolyte membrane for redox flow secondary batteries, which contains an ion exchange resin composition containing a fluorine-based polymer electrolyte; and a redox flow secondary battery which uses the electrolyte membrane for redox flow secondary batteries.Type: ApplicationFiled: December 27, 2012Publication date: November 27, 2014Applicant: ASAHI KASEI E-MATERIALS CORPORATIONInventors: Akihiro Kato, Naoto Miyake
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Patent number: 8895101Abstract: The present invention relates to a method for manufacturing a cable-type secondary battery comprising an electrode that extends longitudinally in a parallel arrangement and that includes a current collector having a horizontal cross section of a predetermined shape and an active material layer formed on the current collector, and the electrode is formed by putting an electrode slurry including an active material, a polymer binder, and a solvent into an extruder, by extrusion-coating the electrode slurry on the current collector while continuously providing the current collector to the extruder, and by drying the current collector coated with the electrode slurry to form an active material layer.Type: GrantFiled: September 20, 2011Date of Patent: November 25, 2014Assignee: LG Chem, Ltd.Inventors: Yo-Han Kwon, Joo-Sung Lee, Je-Young Kim, Jong-Hun Kim
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Patent number: 8828579Abstract: The invention provides a battery, which can improve battery characteristics such as high temperature storage characteristics. The battery comprises a battery device, wherein a cathode and an anode are wound with a separator in between. The anode contains an anode material capable of inserting and extracting Li as an anode active material. An electrolytic solution is impregnated in the separator. The electrolytic solution contains a solvent, and an electrolyte salt such as Li[B(CF3)4] dissolved in the solvent, which is expressed by a chemical formula of Li[B(RF1)(RF2)(RF3)RF4]RF 1, RF 2, RF 3, and RF 4 represent a perfluoro alkyl group whose number of fluorine or carbon is from 1 to 12, respectively. Consequently, high temperature storage characteristics are improved.Type: GrantFiled: March 30, 2004Date of Patent: September 9, 2014Assignee: Sony CorporationInventors: Tadahiko Kubota, Momoe Adachi, Shigeru Fujita
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Publication number: 20140186719Abstract: A method is provided for forming a sodium-containing particle electrolyte structure. The method provides sodium-containing particles (e.g., NASICON), dispersed in a liquid phase polymer, to form a polymer film with sodium-containing particles distributed in the polymer film. The liquid phase polymer is a result of dissolving the polymer in a solvent or melting the polymer in an extrusion process. In one aspect, the method forms a plurality of polymer film layers, where each polymer film layer includes sodium-containing particles. For example, the plurality of polymer film layers may form a stack having a top layer and a bottom layer, where with percentage of sodium-containing particles in the polymer film layers increasing from the bottom layer to the top layer. In another aspect, the sodium-containing particles are coated with a dopant. A sodium-containing particle electrolyte structure and a battery made using the sodium-containing particle electrolyte structure are also presented.Type: ApplicationFiled: March 6, 2014Publication date: July 3, 2014Applicant: Sharp Laboratories of America, Inc.Inventors: Long Wang, Yuhao Lu, Jong-Jan Lee
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Patent number: 8722280Abstract: A hyper-branched polymer having a degree of branching in the range of about 0.05 to about 1 includes a dendritic unit, a linear unit, and a terminal unit, wherein the hyper-branched polymer, an electrode for a fuel cell including the hyper-branched polymer, an electrolyte membrane for a fuel cell including the hyper-branched polymer, and a fuel cell including at least one of the electrode and the electrolyte membrane. Such a hyper-branched polymer included in a fuel cell provides excellent thermal resistance and phosphoric acid resistance and increase the performance of the fuel cell.Type: GrantFiled: December 16, 2009Date of Patent: May 13, 2014Assignees: Samsung Electronics Co., Ltd., SNU R&DB FoundationInventors: Seong-woo Choi, Cheol-hee Ahn, Jung-ock Park, Mi-jung Yim
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Publication number: 20140093784Abstract: Disclosed is an integrated electrode assembly having a structure in which a cathode, an anode, and a separation layer disposed between the cathode and the anode are integrated with one another, wherein the separation layer has a multilayer structure including at least one two-phase electrolyte including a liquid phase component and a polymer matrix and at least one three-phase electrolyte including a liquid phase component, a solid component, and a polymer matrix, wherein the polymer matrices of the separation layer are coupled to the cathode or the anode and the liquid phase components of the separation layer are partially introduced into an electrode in a process of manufacturing the electrode assembly.Type: ApplicationFiled: December 5, 2013Publication date: April 3, 2014Applicant: LG CHEM, LTD.Inventors: YoHan KWON, Sung-Kyun CHANG, Seung-tae HONG, Je Young KIM, SungJin KIM
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Patent number: 8632916Abstract: The lithium ion polymer battery includes a positive electrode plate formed with a positive electrode mixture layer having a lithium composite oxide as a positive electrode active material, a negative electrode plate, a separator, and a gel nonaqueous electrolyte, the positive electrode active material having an average particle diameter of 4.5 to 15.5 ?m and a specific surface area of 0.13 to 0.80 m2/g, the positive electrode mixture layer containing at least one of aluminum, titanium, or zirconium based coupling agent having an alkyl or an alkoxy groups having 1 to 18 carbon atoms at a content of 0.01% or more and 5% or less by mass with respect to the mass of the positive electrode active material, and the gel nonaqueous electrolyte being formed from a nonaqueous electrolyte containing a monomer having a (meth)acrylic end group. Thus improved nail penetration characteristics and superior cycle characteristics are obtained.Type: GrantFiled: December 23, 2010Date of Patent: January 21, 2014Assignee: SANYO Electric Co., Ltd.Inventors: Kentaro Takahashi, Shinya Furukawa
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Publication number: 20130295466Abstract: A solid electrolyte for an electrochemical device includes a composite of a plastic crystal matrix electrolyte doped with an ionic salt and a crosslinked polymer structure having a linear polymer as a side chain chemically bonded thereto. The linear polymer has a weight average molecular weight of 100 to 5,000 and one functional group. The electrolyte has high ionic conductivity comparable to that of a liquid electrolyte due to the use of the plastic crystal, and high mechanical strength comparable to that of a solid electrolyte due to the introduction of the crosslinked polymer structure. A method for preparing the solid electrolyte does not essentially require the use of a solvent, eliminating the need for drying. The electrolyte is suitable for use in a cable-type battery whose shape is easy to change due to its high ionic conductivity and high mechanical strength comparable to that of a solid electrolyte.Type: ApplicationFiled: July 8, 2013Publication date: November 7, 2013Inventors: Yo-Han KWON, Je-Young KIM, Byung-Hun OH, Ki-Tae KIM
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Patent number: 8574770Abstract: A non-aqueous battery comprising a positive electrode material capable of being doped with and liberating lithium, a negative electrode material capable of being doped with and liberating lithium, and a polymer electrolyte disposed between the positive and negative electrode materials. The polymer electrolyte is formed by mixing a vinylidene fluoride copolymer and a nonaqueous electrolytic solution with a solvent, followed by evaporation of the solvent, so as to retain a high proportion of the nonaqueous electrolytic solution, leading to high electroconductivity and excellent strength in this state. The vinylidene fluoride copolymer comprises 80 to 97 wt. % of vinylidene fluoride monomer units and 3 to 20 wt. % of units of at least one monomer copolymerizable with vinylidene fluoride monomer, and has an inherent viscosity of 1.7 to 7 dl/g, as measured at 30° C. in a solution at a concentration of 4 g of polymer in 1 liter of N,N-dimethylformamide.Type: GrantFiled: September 21, 2011Date of Patent: November 5, 2013Assignee: Kureha CorporationInventors: Takumi Katsurao, Katsuo Horie, Yukio Ichikawa, Aisaku Nagai
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Publication number: 20130280620Abstract: This invention concerns copolymers that may be used for incorporation into electrolytic membranes for lithium generators, comprising at least one vinyl ether repetitive motif comprising a pendant cyclic carbonate group.Type: ApplicationFiled: October 6, 2011Publication date: October 24, 2013Applicants: Commissariat A L'Energie Atomique ET Aux Energies Alternatives, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUEInventors: Hervé Galiano, Bruno Ameduri, Bernard Boutevin, Ali Alaaeddine
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Publication number: 20130273436Abstract: A lithium ion secondary battery is provided, including: a positive electrode and a negative electrode into which, and from which, lithium ions can be introduced and be discharged reversibly, and an electrolyte membrane placed therebetween, wherein the electrolyte membrane is obtained using an electrolyte made by blending (A) a polyanion type lithium salt, (B) a boron compound, and (C) an organic solvent.Type: ApplicationFiled: October 18, 2011Publication date: October 17, 2013Applicants: MIE UNIVERSITY, SEKISUI CHEMICAL CO., LTD.Inventors: Kenichi Shinmei, Masashi Kanoh, Rasika Dasanayake Aluthge, Masaru Heishi, Takahito Itoh
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Publication number: 20130196190Abstract: Disclosed is a battery including: a positive electrode; a negative electrode; and an electrolyte including a fluidic electrolyte in which an electrolytic solution containing a solvent and an electrolyte salt is present while maintaining fluidity, and a non-fluidic electrolyte in which an electrolytic solution containing a solvent and an electrolyte salt is supported by a polymeric material.Type: ApplicationFiled: January 23, 2013Publication date: August 1, 2013Applicant: SONY CORPORATIONInventor: Sony Corporation
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Publication number: 20130196234Abstract: An electrolyte composition and catalyst ink, a solid electrolyte membrane formed by printing the electrolyte composition and catalyst ink, and a secondary battery including the solid electrolyte membrane. An electrolyte composition includes a solvent; a lithium salt dissolved in the solvent; and a cycloolefin-based monomer dissolved or dispersed in the solvent and a catalyst ink includes a catalyst that promotes the ring-opening and polymerization reactions of the cycloolefin monomers of the electrolyte composition.Type: ApplicationFiled: March 14, 2013Publication date: August 1, 2013Applicant: SAMSUNG ELECTRONICS CO., LTD.Inventor: SAMSUNG ELECTRONICS CO., LTD.
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Publication number: 20130157144Abstract: A solid electrolyte includes an interpenetrating polymer network, a plasticizer and a lithium salt. The plasticizer and the lithium salt are dispersed in the interpenetrating polymer network. The interpenetrating polymer network includes ?CH2—CH2—O?n segments, and is formed by polymerizing a first monomer R1—O?CH2—CH2—O?nR2 with a second monomer R3—O?CH2—CH2—O?mR4 under an initiator. The “R1”, “R2” or “R3” respectively includes —C?C— group or —C?C— group. The “R4” includes an alkyl group or a hydrogen atom. The “m” and “n” are integers. A molecular weight of the first monomer or a molecular weight of the second monomer is greater than or equal to 100, and less than or equal to 800. The first monomer is less than or equal to 50% of the second monomer by weight. The lithium salt is less than or equal to 10% the second monomer by weight. A lithium based battery using the solid electrolyte is also provided.Type: ApplicationFiled: October 16, 2012Publication date: June 20, 2013Inventors: LI WANG, XIANG-MING HE, JIAN-JUN LI, JIAN GAO, CHANG-YIN JIANG
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Publication number: 20130122398Abstract: An electrochemical or electric layer system, having at least two electrode layers and at least one ion-conducting layer disposed between two electrode layers. The ion-conducting layer has at least one ion-conducting solid electrolyte and at least one binder at grain boundaries of the at least one ion-conducting solid electrolyte for improving the ion conductivity over the grain boundaries and the adhesion of the layers.Type: ApplicationFiled: May 16, 2011Publication date: May 16, 2013Applicant: CONTINENTAL AUTOMOTIVE GMBHInventors: Peter Birke, Olaf Böse, Michael Keller, Michael Schiemann, Hans-Georg Schweiger
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Publication number: 20130017453Abstract: A fabrication process for conformal coating of a thin polymer electrolyte layer on nanostructured electrode materials for three-dimensional micro/nanobattery applications, compositions thereof, and devices incorporating such compositions. In embodiments, conformal coatings (such as uniform thickness of around 20-30 nanometer) of polymer Polymethylmethacralate (PMMA) electrolyte layers around individual Ni—Sn nanowires were used as anodes for Li ion battery. This configuration showed high discharge capacity and excellent capacity retention even at high rates over extended cycling, allowing for scalable increase in areal capacity with electrode thickness. Such conformal nanoscale anode-electrolyte architectures were shown to be efficient Li-ion battery system.Type: ApplicationFiled: December 10, 2010Publication date: January 17, 2013Applicant: William Marsh Rice UniversityInventors: Pulickel M. Ajayan, Fung Soung Ou, Manikoth M. Shajiumon, Sanketh R. Gowda, Arava L.M. Reedy
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Publication number: 20120326073Abstract: A polymer electrolyte composition including a metal salt and at least one polymer comprising a poly(glycidyl ether), where the at least one polymer is amorphous at ambient temperature. The poly(glycidyl ether) polymer can be a blend of poly(glycidyl ether) polymers, can be a poly(glycidyl ether) polymer blended with a mechanically strong solid polymer, and can be a block of a block copolymer that also includes a polymer block forming a mechanically strong solid polymer.Type: ApplicationFiled: December 16, 2011Publication date: December 27, 2012Inventors: Nathaniel A. Lynd, Glenn H. Fredrickson, Craig J. Hawker, Edward J. Kramer, Kate Barteau
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Patent number: RE44264Abstract: Provided are a composite polymer electrolyte for a lithium secondary battery in which a composite polymer matrix multi-layer structure composed of a plurality of polymer matrices with different pore sizes is impregnated with an electrolyte solution, and a method of manufacturing the same. Among the polymer matrices, a microporous polymer matrix with a smaller pore size contains a lithium cationic single-ion conducting inorganic filler, thereby enhancing ionic conductivity, the distribution uniformity of the impregnated electrolyte solution, and maintenance characteristics. The microporous polymer matrix containing the lithium cationic single-ion conducting inorganic filler is coated on a surface of a porous polymer matrix to form the composite polymer matrix multi-layer structure, which is then impregnated with the electrolyte solution, to manufacture the composite polymer electrolyte. The composite polymer electrolyte is used in a unit battery.Type: GrantFiled: July 15, 2010Date of Patent: June 4, 2013Assignee: Electronics and Telecommunications Research InstituteInventors: Young Gi Lee, Kwang Man Kim, Kwang Sun Ryu, Soon Ho Chang