Abstract: A hydrogen generation apparatus (100) includes: a reformer (10) configured to generate a hydrogen-containing gas by using a raw material and steam; a raw material passage (21) through which the raw material that is supplied to the reformer (10) flows; a hydrodesulfurizer (13) provided downstream from a most downstream valve (11) on the raw material passage (21) and configured to remove a sulfur compound from the raw material; a sealer (15) provided on a passage (24) downstream from the reformer (10) and configured to block communication between the reformer (10) and the atmosphere; and a depressurizer (16) provided on the raw material passage (21) at a portion connecting the hydrodesulfurizer (13) and the reformer (10) and configured to release, to the atmosphere, pressure in the reformer (10) that has increased after the sealer (15) is closed.

Abstract: The present invention is a Solid Oxide Fuel Cell Reforming Power System that utilizes adiabatic reforming of reformate within this system. By utilizing adiabatic reforming of reformate within the system the system operates at a significantly higher efficiency than other Solid Oxide Reforming Power Systems that exist in the prior art. This is because energy is not lost while materials are cooled and reheated; instead the device operates at a higher temperature. This allows efficiencies higher than 65%.

Abstract: A fuel purification system includes a fuel cell stack and a fuel purification unit, such as a distillation unit. The fuel cell stack is adapted to provide heat to the fuel purification unit, and the fuel purification unit is adapted to provide a purified fuel to the fuel cell stack.

Abstract: A fuel cell system includes a diluting apparatus which comprises a first introducing portion, a second introducing portion and an inner space and a discharge portion, and a control unit which comprises discharged fuel gas quantity detection means, a current remaining fuel gas detection means and a purge treatment means. In this fuel cell system purging the fuel gas is controlled calculating a current remaining fuel gas quantity in the inner space based on a fuel gas quantity introduced into the inner space, a flow rate of an oxidizing off-gas, a ventilation rate and a flow rate of a diluting gas.

Abstract: A method for producing a purified carbon dioxide product suitable for EOR and surplus electricity uses a vaporous hydrocarbon feed and a SOFC system. A SOFC system includes a condensate removal system, an acid gas removal system, a hydrodesulfurization system, a sorption bed system, a pre-reformer, a solid oxide fuel cell, a CO2 separations system and a CO2 dehydration system operable to form the purified carbon dioxide product, where the SOFC system is operable to produce surplus electricity from the electricity produced by the solid oxide fuel cell. A method of operating the pre-reformer to maximize the internal reforming capacity of a downstream solid oxide fuel cell uses a pre-reformer fluidly coupled on the upstream side of a solid oxide fuel cell. A method of enhancing hydrocarbon fluid recovery from a hydrocarbon-bearing formation using a SOFC system.

Abstract: Provided are a carbon dioxide separator and method of use therefor for separating carbon dioxide gas from a mixed gas containing oxygen and carbon dioxide gases, said carbon dioxide separator comprising: a carbon dioxide separating stack having in sequence an anode electrode, an anion-exchange polymer electrolyte membrane and a cathode electrode; a reducing agent supply chamber for supplying a reducing agent to the anode electrode, said reducing agent supply chamber disposed on the outer surface of the anode electrode and comprising a space in which at least a part of the anode electrode side is exposed; and a mixed gas supply chamber for supplying the mixed gas to the cathode electrode, said mixed gas supply chamber disposed on an outer surface of the cathode electrode and comprising a space in which at least a part of the cathode electrode side is exposed. The anode and cathode electrodes are electrically connected.

Abstract: A method of operating a fuel cell system on a by-product gas containing a fuel constituent. The fuel cell system includes a fuel reformer for forming a reformate stream, a combustor for supplying heat energy to the fuel reformer, and a fuel cell stack. The method includes the steps of separating a by-product gas into a purified gas stream and a residual stream with a gaseous fuel purifier, feeding the purified gas stream to the fuel reformer configured to transform the purified gas stream to produce a reformate stream, and feeding the residual gas stream to a combustor configured to provide heat energy to the fuel reformer. The purified gas stream contains a higher concentration of preferable fuel constituents and a lower concentration of contaminants than the residual gas stream.

Abstract: A hydrogen generation apparatus 1 includes a raw material supply unit 4 for controlling a flow rate of a raw material to be supplied from an external element and containing hydrocarbon and an odorizing component; an odorizing component removing section 5 containing an adsorbing agent for adsorbing the odorizing component contained in the raw material; a combustor 2 for combusting the raw material; a reformer 30 for generating hydrogen-containing gas from the raw material which has passed the odorizing component removing section 5 by a reforming reaction using combustion heat supplied from the combustor 2; and a controller 16 for controlling the raw material supply unit to, during driving after the adsorbing agent or the odorizing component removing section 5 is exchanged or after the adsorbing agent is regenerated, makes the flow rate of the raw material to be supplied from the external element higher than the flow rate during the driving immediately before the exchange or regeneration.

Abstract: In a fuel cell system of the present invention, a reformed gas generated in a reformer (R1) being activated is supplied to a fuel cell stack (F1), and an off-gas discharged from the fuel cell stack (F1) is supplied to a heat supply device (B2) provided for a reformer (R2) being deactivated. By activating at least one reformer (Rn), all of a plurality of reformers (Rn) can be warmed-up. Therefore, energy consumption in a standby state can be suppressed, and the fuel cell system can be started-up quickly in emergencies. The reformed gas may be supplied to the heat supply device (B2) instead of the off-gas.

Abstract: A system and method in which a high temperature fuel cell stack exhaust stream is recycled back into the fuel inlet stream of the high temperature fuel cell stack. The recycled stream may be sent to a carbon dioxide separation device which separates carbon dioxide from the fuel exhaust stream. The carbon dioxide separation device may be a carbon dioxide trap, an electrochemical carbon dioxide separator, or a membrane separator. A water separator may be used in conjunction with the carbon dioxide separation device or used separately to continuously remove water from the recycled stream.

Abstract: A hydrogen circulation type fuel cell system equipped with an electrochemical cell executes discharging an anode off-gas with impurities being condensed toward the outside of the system at a proper timing.

Abstract: A method of operating a fuel cell system (100) comprises the steps of: generating a hydrogen-containing gas from a gas containing at least one of a nitrogen gas and a nitrogen compound, by a hydrogen generator (2); removing ammonia from the hydrogen-containing gas; detecting a temperature of the hydrogen-containing gas from which the ammonia has been removed; and starting supplying of the hydrogen-containing gas from the hydrogen generator (2) to the fuel cell (7), when the detected temperature of the hydrogen-containing gas is equal to or higher than a predetermined threshold.

Abstract: A power system for an aircraft includes a solid oxide fuel cell system which generates electric power for the aircraft and an exhaust stream; and a heat exchanger for transferring heat from the exhaust stream of the solid oxide fuel cell to a heat requiring system or component of the aircraft. The heat can be transferred to fuel for the primary engine of the aircraft. Further, the same fuel can be used to power both the primary engine and the SOFC. A heat exchanger is positioned to cool reformate before feeding to the fuel cell. SOFC exhaust is treated and used as inerting gas. Finally, oxidant to the SOFC can be obtained from the aircraft cabin, or exterior, or both.

Abstract: A method for producing a substantially desulfurized a hydrocarbon fuel stream at temperatures less than 100° C. The method includes providing a nondesulfurized fuel cell hydrocarbon fuel stream that may include water and passing the fuel stream sequentially through a zeolite Y adsorbent and a selective sulfur adsorbent. The zeolite Y adsorbent may be exchanged with copper ions. The method produces a substantially desulfurized hydrocarbon fuel stream containing less than 50 ppb sulfur.

Abstract: An example method of operating a fuel cell system includes calculating the rate of water produced in the fuel cell stack, determining the rate of water exiting the system, and controlling the condenser temperature to maintain the cathode gas exit temperature from the condenser below the temperature required to maintain water balance in the fuel cell system. The method collects the condensed vapor as water and purges a portion of the collected water containing contaminants from the system.

Abstract: A hydrogen generating apparatus (10) of the present invention includes a desulfurizer (7) which is supplied with a raw material and which is configured to remove sulfur compounds present in the raw material, a reformer (17) which is configured to form a hydrogen containing gas from the raw material which has passed through the desulfurizer (7), a meter device (3) which is configured to measure the amount of sulfur compounds removed by the desulfurizer (7) (which amount is hereinafter referred to as the amount of removal of sulfur compounds), and a controller (40), wherein the controller (40) is configured so as not to permit the next time start-up if the integrated value of the amount of removal of sulfur compounds measured by the meter device (3) becomes greater than or equal to a first threshold value.

Abstract: Process for operating a high temperature fuel cell stack, the process comprising the following steps: b) connecting the fuel cell stack in parallel to a power supply unit at a predefined temperature and/or voltage of the fuel cell stack, h) applying a voltage from the power supply unit of between 700 to 1500 mV per fuel cell across the fuel cell stack irrespective of the electro-motive force of the fuel cell stack, i) heating up the fuel cell stack from the predefined temperature to operation temperature while maintaining the voltage per fuel cell the power supply unit, j) maintaining the fuel cell stack at or above a predetermined operation temperature and/or above a predetermined voltage until the fuel cell stack is to be put into operation, k) supplying fuel to the fuel cell stack, l) disconnecting the power supply unit followed by m) connecting a power-requiring load to the fuel cell stack.

Abstract: A method for determining a rate of accumulation of nitrogen in an anode side of a fuel cell stack. The method includes determining a concentration of nitrogen in an anode loop and determining a number of moles of nitrogen in the anode loop. The method also includes determining a rate of accumulation of nitrogen in the anode loop and determining a permeability factor of nitrogen through fuel cell membranes in the fuel cell stack using the determined rate of accumulation of nitrogen in the anode loop.

Abstract: The present invention provides in embodiments a method for purification of inlet gas streams for a solid oxide cell operated in both, electrolysis and fuel cell mode, the solid oxide cell comprising at least a first electrode, an electrolyte and a second electrode, the method comprising the steps of:—providing at least one scrubber in the gas stream at the inlet side of the first electrode of the solid oxide cell; and/or providing at least one scrubber in the gas stream at the inlet side of the second electrode of the solid oxide cell; and—purifying the gas streams towards the first and second electrode; wherein the at least one scrubber in the gas stream at the inlet side of the first electrode and/or the at least one scrubber in the gas stream at the inlet side of the second electrode comprises a material suitable as an electrolyte material and a material suitable as an electrode material, and wherein the material suitable as an electrolyte material and a material suitable as an electrode material form trip

Abstract: A fuel cell includes an electrolyte membrane, an anode which is disposed on one surface of the electrolyte membrane and includes an anode catalyst layer, a cathode which is disposed on the other surface of the electrolyte membrane and includes a cathode catalyst layer, and an adjustment unit which allows at least one of a relative humidity of a gas which is in contact with the anode catalyst layer and a relative humidity of a gas which is in contact with the cathode catalyst layer to be decreased down to less than 100% before a fuel is supplied at the time of starting.

Abstract: A controller (15) performs a stop operation of stopping electric power generation by a fuel cell (3); then performs an activity recovery operation of stopping the supply of a fuel gas by a fuel gas supply unit (10) to an anode (2a), causing an anode inert gas supply unit (13) to supply an inert gas to the anode (2a), and causing an oxidizing gas supply unit (11) to supply an oxidizing gas to a cathode (2b); and performs control such that the fuel gas supply unit (10) resumes supplying the fuel gas to the anode (2a) to resume the electric power generation by the fuel cell (3) after the cell voltage of the fuel cell (3) which is detected by a voltage detector (14) has decreased to a first voltage or lower.

Abstract: A fuel cell system 100 includes: a reformer 1 configured to generate a hydrogen-containing gas by using a raw material; a fuel cell 6 configured to generate electric power by using the hydrogen-containing gas; an ammonia remover 5 configured to remove ammonia from the hydrogen-containing gas generated in the reformer before the hydrogen-containing gas is supplied to the fuel cell; a fluid passage configured to allow the ammonia remover to be in communication with the atmosphere; an on-off valve 8 provided on the fluid passage and configured to allow and block the communication between the ammonia remover and the atmosphere; and a controller 80 configured to open the on-off valve in at least one of a water draining process and a water loading process of the ammonia remover.

Abstract: An integrated contaminant separator and water-control loop (10) decontaminates a fuel reactant stream of a fuel cell (12). Water passes over surfaces of an ammonia dissolving means (61) within a separator scrubber (58) while the fuel reactant stream simultaneously passes over the surfaces to dissolve contaminants from the fuel reactant stream into the water. An accumulator (68) collects the separated contaminant stream, and ion exchange material (69) integrated within the accumulator removes contaminants from the stream. A water-control pump (84) directs flow of a de-contaminated water stream from the accumulator (68) through a water-control loop (78) having a heat exchanger (86) and back onto the scrubber (58) to flow over the packed bed (62). Separating contaminants from the fuel reactant stream and then isolating and concentrating the separated contaminants within the ion exchange material (69) minimizes cost and maintenance requirements.

Abstract: A heat and steam generator for eye application includes a heat and steam generating member making use of oxidative reaction of an oxidizable metal and is adapted to supply steam to eyes and surroundings. The heat and steam generator is adapted to release steam from its side brought into contact with eyes and surroundings for a period of 1 to 30 minutes to maintain the skin surface temperature to which it is applied at 34° C. to 43° C. over a period of 1 to 120 minutes. The heat and steam generator has a stiffness of 0.01 to 10 N/7 cm-width. The heat and steam generator is effective in improving near triad causing reduction in vision.

Abstract: A fuel purification system includes a fuel cell stack and a fuel purification unit, such as a distillation unit. The fuel cell stack is adapted to provide heat to the fuel purification unit, and the fuel purification unit is adapted to provide a purified fuel to the fuel cell stack.

Abstract: This disclosure relates to energy storage and generation systems, e.g., combination of flow battery and hydrogen fuel cell, that exhibit operational stability in harsh environments, e.g., both charging and discharging reactions in a regenerative fuel cell in the presence of a halogen ion or a mixture of halogen ions. This disclosure also relates to energy storage and generation systems that are capable of conducting both hydrogen evolution reactions (HERs) and hydrogen oxidation reactions (HORs) in the same system. This disclosure further relates to energy storage and generation systems having low cost, fast response time, and acceptable life and performance.

Abstract: A reformer for a fuel cell and a fuel cell system including the same are shown. The reformer includes a heat source for providing heat to evaporate a mixed fuel and having a predetermined flow path length through which the mixed fuel passes and a catalyst layer lining the internal surface of the flow path, and a reforming reactor for generating hydrogen gas from the mixed fuel through a chemical catalytic reaction by the heat and having a predetermined flow path length through which the mixed fuel passes and a catalyst layer lining the internal surface of the flow path. Either the heat source, or the reforming reactor, or both are formed from an alloy of a barrier layer forming metal and a mechanical strength enhancing metal.

Abstract: The fuel cell system in accordance with the invention is used for the generation of current and heat from liquid and gaseous fuels. Said system comprises a reformer and a fuel cell stack having an operating temperature above 120° C. and providing exhaust heat that is utilized for the generation of steam in the evaporation channels (2). The evaporation channels (2) are arranged so as to be in direct thermal contact with the stack (1) that is to be cooled. A pressure-maintaining device at the outlet of the evaporation channels (2) is disposed to adjust the pressure in said channels to a value that results in the desired stack temperature.

Abstract: A fuel cell power generation system 100 includes a mechanism for detachably holding an adsorptive desulfurization section 5 for adsorbing a sulfur component in a hydrocarbon-based raw material; a reformer for generating hydrogen-containing gas from the raw material which has passed the adsorptive desulfurization section 5; a fuel cell 8 for generating power using the hydrogen-containing gas as a fuel; a raw material supply section 4 for controlling a flow rate of the raw material to be supplied to the adsorptive desulfurization section 5; and an operating control section 16 for controlling a behavior of the raw material supply section 4 and a behavior of the fuel cell 8.

Abstract: A system is provided that combines an oxygen enrichment device (OBOGS) for generating oxygen-enriched air with a fuel cell system that includes, but is not limited to a fuel cell for using the oxygen-enriched air as a reaction gas within the fuel cell, as a result of which the output of the fuel cell is improved while the size and weight of the fuel cell remain the same.

Abstract: In a fuel cell system, a controller is programmed to control a first gas supply mechanism to deliver a first gas containing a fuel gas to a cathode in a pre-stop process performed at a system stop of the fuel cell system. The controller is programmed to control the first gas supply mechanism to stop the delivery of the first gas in a first state where a partial pressure difference between an anode and the cathode with respect to at least the fuel gas of remaining gases in the anode and in the cathode is reduced to or below a preset reference value.

Abstract: A fuel cell system includes an anode circuit by means of which unused gas from the anode region of a fuel cell can be recirculated via a recirculation delivery device into the anode region. At least one liquid separator is provided in the anode circuit. The liquid separator is integrated with the recirculation delivery device to form an assembly. Fresh hydrogen is supplied to the anode region by feeding the hydrogen into the liquid separator.

Abstract: A polybenzimidazole-base complex includes a polybenzimidazole-based material and a base, wherein a peak corresponding to NH of an imidazole ring of the polybenzimidazole-based material does not appear at a chemical shift of 12 to 15 ppm in a 1H nuclear magnetic resonance (1H-NMR) spectrum of the polybenzimidazole-base complex. A crosslinked material may be formed as a polymerization product of a polybenzimidazole-base complex and a benzoxazine-based monomer. The crosslinked material may be used an electrolyte membrane for a fuel cell comprising the crosslinked material, and a fuel cell may include the electrolyte membrane.

Abstract: An anode reactant recycling system for a fuel cell is disclosed, the system including a hollow main body, a bleed conduit, an injector, a water separator, and a hydrophilic porous media. The anode reactant recycling system for a fuel cell is configured to minimize a required number of components, eliminate the need for the anode heat exchanger, use a single valve for removal of condensate and reactant byproducts from the anode reactant recycling system, and provide an upstream volume for startup pressurization.

Abstract: A power generator includes a fuel container adapted to hold a hydrogen containing fuel. A two stage valve is coupled between a fuel cell and a fuel container and between a water reservoir and the fuel container. A pressure responsive actuator is coupled to the two stage valve and the fuel container.

Abstract: A combined cycle fuel cell includes a fuel cell such as a solid-oxide fuel cell (SOFC) comprising an anode that generates a tail gas. A hydrocarbon fuel reforming system that mixes a hydrocarbon fuel with the fuel cell tail gas downstream of the fuel cell partly or fully converts the hydrocarbon fuel into hydrogen (H2) and carbon monoxide (CO). A fuel path diverts a first portion of the reformed fuel to the inlet of the fuel cell anode. A cooler such as an Organic Rankine cycle (ORC) is optionally configured to remove heat from a residual portion of the reformed fuel and to deliver the cooled residual portion of the reformed fuel to a bottoming cycle that may be an external or internal combustion engine such as a reciprocating gas engine or gas turbine that is driven in response to the cooled residual portion of the reformed fuel.

Abstract: A system and method are provided for boosting overall performance of a fuel cell while simultaneously separating a nearly pure stream of CO2 for sequestration or for use in generating electrical power to further increase overall efficiency of the process. The system and method employ a heat exchanger system configured to generate a stream of fuel that is returned to the inlet of the fuel cell anode with a higher molar concentration of carbon monoxide (CO) and hydrogen (H2) fuel than was initially present in the fuel cell anode outlet.

Abstract: A fuel purification system includes a fuel cell stack and a fuel purification unit, such as a distillation unit. The fuel cell stack is adapted to provide heat to the fuel purification unit, and the fuel purification unit is adapted to provide a purified fuel to the fuel cell stack.

Abstract: A fuel cell system that includes a control system for regulating the power produced by the fuel cell system. The fuel cell system includes a fuel cell stack adapted to produce electrical power from a feed. In some embodiments, the fuel cell system includes a fuel processing assembly adapted to produce the feed for the fuel cell stack from one or more feedstocks. The control system regulates the power produced by the fuel cell system to prevent damage to, and/or failure of, the system.

Abstract: Method for processing an article comprising mixed conducting metal oxide material. The method comprises contacting the article with an oxygen-containing gas and either reducing the temperature of the oxygen-containing gas during a cooling period or increasing the temperature of the oxygen-containing gas during a heating period; during the cooling period, reducing the oxygen activity in the oxygen-containing gas during at least a portion of the cooling period and increasing the rate at which the temperature of the oxygen-containing gas is reduced during at least a portion of the cooling period; and during the heating period, increasing the oxygen activity in the oxygen-containing gas during at least a portion of the heating period and decreasing the rate at which the temperature of the oxygen-containing gas is increased during at least a portion of the heating period.

Abstract: A desulfurization unit for a fuel cell system includes a first desulfurizer arranged in a temperature environment ranging from 50° C. to 200° C. and accommodating a desulfurizing agent including a porous material serving as a base material, the desulfurizing agent exerting a desulfurization effect in a normal temperature range, the first desulfurizer adsorbing a sulfur compound included in a source gas in the temperature environment ranging from 50° C. to 200° C. when the source gas having a low dew point is supplied through a source gas passage to the first desulfurizer and when the source gas having a high dew point is supplied through the source gas passage to the first desulfurizer.

Abstract: A fuel cell system includes a source gas passage including a first desulfurizer that has a desulfurization performance relative to a source gas having a relatively higher dew point, and a second desulfurizer that has the desulfurization performance relative to a source gas having a relatively lower dew point and the source gas having the relatively higher dew point. The desulfurization performance of the second desulfurizer relative to the source gas having the relatively higher dew point is lower than the desulfurization performance of the second desulfurizer relative to the source gas having the relatively lower dew point. The first desulfurizer, the second desulfurizer, and a flowmeter are arranged at the source gas passage in the aforementioned order from an upstream side to a downstream side of the source gas passage in a flow direction of the source gas.

Abstract: Various hot box fuel cell system components are provided, such as heat exchangers, steam generator and other components.

Abstract: The invention relates to a method for operating a direct oxidation fuel cell in which the fuel cell is supplied generally with methanol via a transport device for the fuel. The invention likewise relates to a corresponding arrangement comprising a direct oxidation fuel cell, a fuel reservoir and at least one device for transporting the fuel through the fuel cell.

Abstract: Various hot box fuel cell system components are provided, such as heat exchangers, steam generator and other components.

Abstract: The invention provides a method for the production of electrical energy from an ammonium (NH4+) containing aqueous liquid comprising (a) separating at least part of the ammonium as ammonium salt or concentrated ammonium salt comprising solution from the ammonium containing aqueous liquid, (b) decomposing at least part of the ammonium salt or salt solution into an ammonia (NH3) comprising gas and one or more other decomposition products, and (c) feeding at least part of the ammonia comprising gas to an fuel cell.

Abstract: A fuel cell system that can dispose of an odorant through the use of a simple configuration and assure enhanced hydrogen safety. A hydrogenation device is positioned between a fuel tank and a fuel cell. The hydrogenation device incorporates a hydrogenation catalyst for hydrogenating the odorant.

Abstract: The present invention relates to a preheating arrangement in a fuel cell apparatus, the fuel cell apparatus comprising at least a fuel cell unit having an anode side and a cathode side with an electrolyte therebetween, the fuel cell apparatus having at least a fuel inlet to the anode side and an oxygen-containing air inlet to the cathode side as well as a sulphur removal unit and a fuel modifying unit and an afterburner for combustion the exhaust gases from the anode and/or cathode side. According to the invention, the afterburner is provided with a separate fuel inlet channel for introducing fuel to the afterburner during the start-up phase of the fuel cell apparatus and that at least a part of the exhaust gases formed in the combustion of the separately fed fuel is arranged to be directed from the afterburner for heating at least the sulphur removal unit and/or the fuel modifying unit during the start-up phase.

Abstract: A fuel cell system (10) of the present invention comprises determination means (50) for consuming a fuel gas present at a gas leak detection portion of a fuel gas supply system (31, 32) through the power generation of a fuel cell (20), and performing a gas leak determination on the basis of a pressure decrease margin of the fuel gas present at the gas leak detection portion, and comprises discharge means (H51) for reducing the pressure at the gas leak detection portion by purging the fuel gas present at the gas leak detection portion to the outside of the fuel gas supply system (31, 32). By not only consuming the fuel gas present at the gas leak detection portion through power generation, but also purging the fuel gas to the outside of the fuel gas supply system, the pressure at the gas leak detection portion can be brought close to a target pressure within a short time period, and the gas leak determination can be performed in a short period of time and with a high level of precision.

Abstract: An open type fuel cell system is provided including a recirculating unit that recirculates hydrogen discharged from a main fuel cell into the main fuel cell and a reproducing unit that removes water and impurities produced in operation of the main fuel cell. The open type fuel cell system is adapted so that it does not discharge hydrogen supplied to a main fuel cell into the atmosphere.