Membrane Electrode Assembly (mea) Patents (Class 429/483)
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Patent number: 12261335Abstract: To provide a liquid composition capable of forming a polymer electrolyte membrane which is excellent in the initial power generation characteristics when made into a membrane electrode assembly, and which is excellent in durability and has few defects. This liquid composition comprises a liquid medium, a sulfonic acid group-containing fluorocarbon polymer and a hardly soluble cerium compound, wherein the ion exchange capacity of the sulfonic acid group-containing fluorocarbon polymer is from 1.36 to 2.50 meq/g dry resin, the average particle size of the hardly soluble cerium compound is from 1 nm to 3,000 nm, and the ratio of the total number of moles of cerium atoms in the hardly soluble cerium compound to the total number of moles of sulfonic acid groups in the sulfonic acid group-containing fluorocarbon polymer is from 0.001 to 0.3.Type: GrantFiled: May 28, 2021Date of Patent: March 25, 2025Assignee: AGC Inc.Inventors: Susumu Saito, Takumi Okuyama, Hiroyuki Watabe
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Patent number: 12230809Abstract: A catalyst which is suitable for use in an anode of a fuel cell. The catalyst comprises, in at least partially reduced form, (i) nickel and (ii) molybdenum and, optionally, (iii) rhenium and/or (iv) at least one transition metal which is different from nickel, molybdenum and rhenium, supported on (v) electrically conductive carbon modified with one or more elements selected from the lanthanides, yttrium, tin and titanium. The weight ratio (i):((ii)+(iii)+(iv)) is at least 2:1.Type: GrantFiled: October 15, 2020Date of Patent: February 18, 2025Assignee: GENCELL LTD.Inventors: Nino Borchtchoukova, Yair Haim Wijsboom, Gennadi Finkelshtain, Margarita Valentinova Gabrovska, Dimitrinka Aleksieva Nikolova
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Patent number: 12199291Abstract: An electrochemical cell (e.g., a fuel cell) includes an anode layer, a cathode layer, and an electrolyte membrane layer disposed between and spacing apart the anode layer and the cathode layer. The electrochemical cell further includes a functional layer disposed at an interface between the cathode layer and the electrode membrane layer. The functional layer includes a composition including a carbon material, an ionomer material, and optionally an amount of catalyst material.Type: GrantFiled: June 16, 2022Date of Patent: January 14, 2025Assignee: Robert Bosch GmbHInventors: Lei Cheng, Morteza Rezaei Talarposhti, Jonathan Braaten, Daniil Kitchaev, Nathan Craig, Christina Johnston
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Patent number: 12191437Abstract: An apparatus for pressing a battery cell includes a first pressing plate and a second pressing plate spaced from the first pressing plate to receive a battery cell therebetween and to press the battery cell. At least one of the first pressing plate or the second pressing plate is formed of a shape memory material to provide a pressing member.Type: GrantFiled: July 9, 2020Date of Patent: January 7, 2025Assignee: LG ENERGY SOLUTION, LTD.Inventor: Yeeun Kim
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Patent number: 12068488Abstract: A composition comprised of a tin (Sn) or lead (Pb) film, wherein the film is coated by a shell, wherein the shell: (a) is comprised of an active metal, and (b) is characterized by a thickness of less than 50 nm, is discloses herein. Further disclosed herein is the use of the composition for the oxidation of e.g., methanol, ethanol, formic acid, formaldehyde, dimethyl ether, methyl formate, and glucose.Type: GrantFiled: November 4, 2021Date of Patent: August 20, 2024Assignee: ARIEL SCIENTIFIC INNOVATIONS LTD.Inventors: Alex Schechter, Hanan Teller, Diwakar Kashyap
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Patent number: 11764368Abstract: A titanium material including a base metal made of pure titanium or a titanium alloy and a titanium oxide film formed on the base metal. Peak intensities obtained by thin-film X-ray diffraction analysis performed on an outer layer of the titanium material using an incident angle of 0.3° satisfy (I(104)+I(200))/I(101)?0.08?0.004×I(200), where I(104) is the peak intensity resulting from a plane (104) of a Ti2O3 phase, I(200) is the peak intensity resulting from a plane (200) of a TiO phase, I(101) is the peak intensity resulting from a plane (101) of an ?-Ti phase, and 0<I(104), 0?I(200), and 0<I(101). The titanium material is inexpensive and has both the electrical conductivity and corrosion resistance.Type: GrantFiled: December 18, 2017Date of Patent: September 19, 2023Assignee: Nippon Steel CorporationInventors: Hideya Kaminaka, Yoshitaka Nishiyama, Koichi Nose, Junko Imamura, Haruka Sato
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Patent number: 11745002Abstract: A microneedle array assembly includes a microneedle array that has a plurality of microneedles. A distribution manifold includes a fluid supply channel that is coupled in flow communication to a plurality of resistance channels. Each of the resistance channels are coupled in flow communication to a respective one of the microneedles of the microneedle array. The resistance channels have a resistance value to a fluid flow through each resistance channel that is in the range between about 5 times greater to about 100 times greater than a resistance to the fluid flow through the supply channel.Type: GrantFiled: March 21, 2022Date of Patent: September 5, 2023Assignee: SORRENTO THERAPEUTICS, INC.Inventors: Andrew T. Baker, Russell F. Ross
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Patent number: 11735748Abstract: A power generation cell includes a resin-framed electrolyte membrane electrode assembly. The cathode of the resin-framed membrane electrode assembly has a larger surface dimension than the anode. An outer peripheral portion of the anode is positioned between a first buffer and a fuel gas flow field. An outer peripheral portion of the cathode is positioned between the resin frame member and the second buffer.Type: GrantFiled: February 27, 2022Date of Patent: August 22, 2023Assignee: Honda Motor Co., Ltd.Inventors: Masaru Oda, Takaaki Shikano, Satoshi Aoki, Takuma Yamawaki
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Patent number: 11618962Abstract: Disclosed is a technical idea of forming ruthenium and ruthenium-cobalt alloy nanowires having various diameters using electroplating. More particularly, a technology of forming ruthenium and ruthenium-cobalt alloy nanowires on a porous template, on pores of which nanotubes are deposited using atomic layer deposition (ALD), using electroplating, and annealing the ruthenium and ruthenium-cobalt alloy nanowires to form ruthenium-cobalt alloy nanowires having various diameters.Type: GrantFiled: November 30, 2020Date of Patent: April 4, 2023Assignee: KOREA UNIVERSITY RESEARCH AND BUSINESS FOUNDATIONInventors: Jun Hwan Moon, Seung Hyun Kim, Tae Soon Kim, Yoo Sang Jeon, Young Keun Kim
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Patent number: 11618105Abstract: Embodiments of the present disclosure are directed to methods, systems and devices, for precise and reduced spot-size capabilities using a laser to alter surfaces without chemical treatment, chemical waste, or chemical residues is provided for microfluidic systems (e.g., lab-on-a-disk, for example). In some embodiments, hydrophobic and super-hydrophilic areas can be created on surfaces in the same material at different areas and positions merely by using different laser settings (e.g., spot size, wavelength, spacing, and/or pulse duration). Accordingly, capillary forces that are a recurrent issue in a microfluidic devices (e.g., a centrifugal microfluidic disk) can be controlled for practical applications, including, for example when users handle the disks and insert a sample, the moment the substrate/device (e.g., disk) is placed in a system (e.g., a centrifugal system), capillary forces can take place and move the fluids, which becomes a problem for sequential bioassays taking place in substrate/device (e.Type: GrantFiled: June 3, 2022Date of Patent: April 4, 2023Assignee: Orbis Diagnostics LimitedInventors: Matheus Jose Teixeira Vargas, Miriam Cather Simpson, David Edward Williams
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Patent number: 11569523Abstract: The present disclosure relates to a polymer electrolyte membrane for medium and high temperature, a preparation method thereof and a high-temperature polymer electrolyte membrane fuel cell including the same, more particularly to a technology of preparing a composite membrane including an inorganic phosphate nanofiber incorporated into a phosphoric acid-doped polybenzimidazole (PBI) polymer membrane by adding an inorganic precursor capable of forming a nanofiber in a phosphoric acid solution when preparing phosphoric acid-doped polybenzimidazole and using the same as a high-temperature polymer electrolyte membrane which is thermally stable even at high temperatures of 200-300° C. without degradation of phosphoric acid and has high ion conductivity.Type: GrantFiled: April 27, 2020Date of Patent: January 31, 2023Assignee: Korea Institute of Science and TechnologyInventors: So Young Lee, Seung Ju Lee, Min Jae Lee, Hyun Seo Park, Jong Hyun Jang, Hyoung-Juhn Kim, Suk Woo Nam, Young Suk Jo, Yeong Cheon Kim
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Patent number: 11492431Abstract: The copolymer includes divalent units represented by formula —[CF2—CF2]—, divalent units represented by formula; and one or more divalent units independently represented by formula: The copolymer has an —SO2X equivalent weight in a range from 300 to 2000. A polymer electrolyte membrane that includes the copolymer and a membrane electrode assembly that includes such a polymer electrolyte membrane are also provided.Type: GrantFiled: September 14, 2018Date of Patent: November 8, 2022Assignee: 3M Innovative Properties CompanyInventors: Lisa P. Chen, Gregg D. Dahlke, Denis Duchesne, Steven J. Hamrock, Klaus Hintzer, Markus E. Hirschberg, Arne Thaler, Tilman C. Zipplies
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Patent number: 11376815Abstract: The present invention pertains to a multilayer assembly, to a process for the manufacture of said multilayer assembly, to a pipe comprising said multilayer assembly and to uses of said pipe in various applications.Type: GrantFiled: December 5, 2016Date of Patent: July 5, 2022Assignee: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.Inventors: Pasqua Colaianna, Amelia Mennella, Serena Carella, Marco Colladon, Stephen Edmondson
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Patent number: 11367883Abstract: The present disclosure relates to an elastomeric cell frame for a fuel cell, a method of manufacturing the same, and a unit cell using the same, in which the elastomeric cell frame is integrally bonded to a membrane electrode assembly and a gas diffusion layer using a pair of elastomeric frames without a separate adhesive member. An elastomeric cell frame of a unit cell of a fuel cell according to an exemplary embodiment of the present disclosure includes: an insert including a membrane electrode assembly and a pair of gas diffusion layers disposed on and bonded to opposite surfaces of the membrane electrode assembly; and an elastomeric frame including a pair of elastomeric frames which is bonded to each other and has portions disposed on a lower surface and an upper surface of a rim of the insert, respectively, in an outer region of the insert.Type: GrantFiled: November 6, 2019Date of Patent: June 21, 2022Assignees: HYUNDAI MOTOR COMPANY, KIA MOTORS CORPORATIONInventors: Byeong-Heon Jeong, Jin Hyeok Yoo, Seong Il Heo
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Patent number: 11355759Abstract: A membrane electrode assembly comprises an anode electrode comprising an anode catalyst layer; a cathode electrode comprising a cathode catalyst layer; and a polymer electrolyte membrane interposed between the anode electrode and the cathode electrode; wherein at least one of the anode and cathode catalyst layers comprises a block co-polymer comprising poly(ethylene oxide) and poly(propylene oxide).Type: GrantFiled: April 13, 2018Date of Patent: June 7, 2022Assignee: BALLARD POWER SYSTEMS INC.Inventors: Rajesh Bashyam, Alan Young
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Patent number: 11355768Abstract: Disclosed are an electrolyte membrane for fuel cells that can prevent poisoning of catalysts and a method of producing the same. The electrolyte membrane for fuel cells includes an ion transport layer including an ionomer having proton conductivity, and a catalytic composite dispersed in the ion transport layer, wherein the catalytic composite includes a catalytic particle including a catalytic metal component having an activity of decomposing hydrogen peroxide, and a protective layer formed on at least a part of a surface of the catalytic particle to prevent the ionomer from contacting the catalytic metal component.Type: GrantFiled: November 11, 2020Date of Patent: June 7, 2022Assignees: Hyundai Motor Company, Kia Motors CorporationInventors: Byoungsu Kim, Bo Ki Hong
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Patent number: 11335920Abstract: Disclosed are a membrane electrode assembly with a sub-gasket and a manufacturing method thereof. The membrane electrode assembly includes an electrolyte membrane, the sub-gasket formed in an edge region of the electrolyte membrane to surround a central region of the electrolyte membrane, and an adhesive layer formed between the electrolyte membrane and the sub-gasket and including an adhesive material and an antioxidant. The electrolyte membrane is formed to have a flat surface in a first direction, the sub-gasket extends in the first direction and a second direction vertical to the first direction, and the antioxidant includes a metal salt hydrate.Type: GrantFiled: November 22, 2019Date of Patent: May 17, 2022Assignees: Hyundai Motor Company, Kia Motors CorporationInventors: Jae Jun Ko, In Yu Park, Bo Ki Hong
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Patent number: 11326083Abstract: The invention relates to a material including a support consisting of a porous composite material including at least one polymer phase forming a binder based on at least one polymer selected from thermoplastic polymers, elastomers, and elastomer thermoplastics, and at least one filler selected from thermally conductive fillers, the pores of the support consisting of the porous composite material being partially or entirely filled with at least one phase-change material. The invention also relates to a method for producing said material.Type: GrantFiled: April 7, 2016Date of Patent: May 10, 2022Assignee: HUTCHINSONInventors: Arnaud Prebe, Bruno Dufour, Fabrice Chopard, Nicolas Garois, Philippe Sonntag
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Patent number: 11311708Abstract: A microneedle array assembly includes a microneedle array that has a plurality of microneedles. A distribution manifold includes a fluid supply channel that is coupled in flow communication to a plurality of resistance channels. Each of the resistance channels are coupled in flow communication to a respective one of the microneedles of the microneedle array. The resistance channels have a resistance value to a fluid flow through each resistance channel that is in the range between about 5 times greater to about 100 times greater than a resistance to the fluid flow through the supply channel.Type: GrantFiled: April 17, 2017Date of Patent: April 26, 2022Assignee: SORRENTO THERAPEUTICS, INC.Inventors: Andrew T. Baker, Russell F. Ross
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Patent number: 11302929Abstract: Provided is a method with which it is possible to easily produce an electrode catalyst having excellent catalytic performance such as kinetically controlled current density. The method involves: a dispersion liquid preparation step of preparing a dispersion liquid by mixing (i) at least one type of solvent selected from the group consisting of sulfoxide compounds and amide compounds, (ii) a catalyst carrier powder constituted by a metal oxide, (iii) a platinum compound, (iv) a transition metal compound, and (v) an aromatic compound including a carboxyl group; and a loading step of heating the dispersion liquid to thereby load a platinum alloy of platinum and a transition metal on a surface of the catalyst carrier powder.Type: GrantFiled: August 25, 2017Date of Patent: April 12, 2022Assignees: MITSUI MINING & SMELTING CO., LTD., TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Yuichi Senoo, Koichi Miyake, Koji Taniguchi, Hiromu Watanabe, Naohiko Abe, Tatsuya Arai
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Patent number: 11289711Abstract: Disclosed are a catalyst electrode for a fuel cell, a method for fabricating the catalyst electrode, and a fuel cell including the catalyst electrode. The presence of an ionomer-ionomer support composite in the catalyst electrode prevents the porous structure of the catalyst electrode from collapsing due to oxidation of a carbon support to avoid an increase in resistance to gas diffusion and can stably secure proton channels. The presence of carbon materials with high conductivity is effective in preventing the electrical conductivity of the electrode from deterioration resulting from the use of a metal oxide in the ionomer-ionomer support composite and is also effective in suppressing collapse of the porous structure of the electrode to prevent an increase in resistance to gas diffusion in the electrode. Based on these effects, the fuel cell exhibits excellent performance characteristics and prevents its performance from deteriorating during continuous operation.Type: GrantFiled: July 21, 2020Date of Patent: March 29, 2022Assignee: Korea Institute of Science and TechnologyInventors: Jong Hyun Jang, Hyun Seo Park, Hee-Young Park, Katie Heeyum Lim, Oh Sub Kim, Hyoung-Juhn Kim, Jin Young Kim, Sung Jong Yoo, Dirk Henkensmeir, So Young Lee
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Patent number: 11276866Abstract: The present invention relates to a catalyst for a solid polymer fuel cell that includes catalyst particles supported on a carbon powder carrier, the catalyst particles containing platinum, cobalt, and manganese. In the catalyst particles of the catalyst, the component ratio of platinum, cobalt, and manganese is Pt:Co:Mn=1:0.25 to 0.28:0.07 to 0.10 in a molar ratio, the average particle size is 3.4 to 5.0 nm, and further, in the particle size distribution of the catalyst particles, the proportion of catalyst particles having a particle size of 3.0 nm or less in the entire catalyst particles is 37% or less on a particle number basis. Then, a fluorine compound having a C—F bond is supported at least on the surface of the catalyst particles. The present invention is, with respect to the above ternary alloy catalyst, an invention particularly effective in improving the durability.Type: GrantFiled: September 20, 2018Date of Patent: March 15, 2022Assignee: TANAKA KIKINZOKU KOGYO K.K.Inventor: Minoru Ishida
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Patent number: 11271234Abstract: A solid polymer electrolyte fuel cell comprises a membrane electrode assembly comprising a polymer electrolyte disposed between an anode electrode and a cathode electrode, the anode and cathode electrodes each comprising a catalyst, a central region and a peripheral region, wherein the peripheral region of the cathode electrode comprises a cathode edge barrier layer; a fluid impermeable seal in contact with at least a portion of the anode and cathode peripheral regions and the cathode edge barrier layer; an anode flow field plate adjacent the anode electrode; and a cathode flow field plate adjacent the cathode electrode, wherein the cathode flow field separator plate comprises a cathode peripheral flow channel and at least one cathode central flow channel; wherein at least a portion of the cathode edge barrier layer traverses at least a portion of the cathode peripheral flow channel.Type: GrantFiled: August 10, 2017Date of Patent: March 8, 2022Assignee: BALLARD POWER SYSTEMS INC.Inventor: Manuel Schneiter
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Patent number: 11258086Abstract: A method of manufacturing a membrane electrode assembly, includes: forming catalyst coated membrane using an electrode catalyst layer containing an ionomer having a sulfonic acid group and a catalyst carrier, and an electrolyte membrane; applying an ionization accelerator having a low molecular weight component represented by a chemical formula ClHmOn (where l, m, and n are natural numbers) for accelerating generation of sulfate ions, to the catalyst coated membrane; performing UV irradiation on the ionization accelerator applied to the catalyst coated membrane; heating the catalyst coated membrane having the ionization accelerator subjected to the UV irradiation; and bonding a gas diffusion layer containing a radical inhibiting substance to an outer surface of at least one of the ionization accelerator subjected to the UV irradiation or the catalyst coated membrane.Type: GrantFiled: August 19, 2020Date of Patent: February 22, 2022Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventor: Kenji Tsubosaka
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Patent number: 11251456Abstract: A heat treatment apparatus for a fuel cell membrane-electrode assembly is provided. The heat treatment apparatus includes a hot press installed on upper and lower sides of feeding path to move in the vertical direction on a frame and which presses the electrode catalyst layers on upper and lower surfaces of the membrane-electrode assembly sheet. A plurality of gripper modules are installed at set intervals in a base member along a feeding direction of the membrane-electrode assembly sheet, and selectively grip both side edges of the membrane-electrode assembly sheet. A driving unit reciprocally moves the base member in a direction perpendicular to the feeding direction of the membrane-electrode assembly sheet and in the feeding direction of the membrane-electrode assembly sheet.Type: GrantFiled: May 21, 2019Date of Patent: February 15, 2022Assignees: Hyundai Motor Company, Kia Motors CorporationInventors: Yoosuk Hong, Sung Hoon Jeong
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Patent number: 11251476Abstract: Electrochemical metal-air cells having nested electrodes provided in an annular or cylindrical configuration, including systems that contain such cells in a sealed container. Each cell may include an oxidant electrode (air cathode) and a fuel electrode (anode), both configured in annular form. A series of permeable bodies, screens, or current collectors may be provided as part of the fuel electrode. An annular oxygen evolution electrode may also be provided in the cells. In some cases, the fuel electrode is nested within the oxidant electrode, or vice versa. Optionally, a second oxidant electrode may be included in the cells. Ionically conductive medium or electrolyte may be contained in the cell. Each cell may have its own cell housing. Optionally, an air space or pocket may be formed in a cell via an oxidant electrode. The sealed container may contain the cells such that they are surrounded by air or an electrolyte.Type: GrantFiled: May 7, 2020Date of Patent: February 15, 2022Assignee: FORM ENERGY, INC.Inventors: Glenn Donahey, Ramkumar Krishnan, Jagjot Singh Grewal
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Patent number: 11233247Abstract: A composition comprised of a tin (Sn) or lead (Pb) film, wherein the film is coated by a shell, wherein the shell: (a) is comprised of an active metal, and (b) is characterized by a thickness of less than 50 nm, is discloses herein. Further disclosed herein is the use of the composition for the oxidation of e.g., methanol, ethanol, formic acid, formaldehyde, dimethyl ether, methyl formate, and glucose.Type: GrantFiled: August 27, 2017Date of Patent: January 25, 2022Assignee: ARIEL SCIENTIFIC INNOVATIONS LTD.Inventors: Alex Schechter, Hanan Teller, Diwakar Kashyap
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Patent number: 11228050Abstract: Some aspects of the invention may be directed to a catalyst layer for anodes of Alkaline Exchange Membrane Fuel Cells (AEMFC). Such catalyst layer may include catalyst nanoparticles and an ionomer. Each catalyst nanoparticle may include one or more nanoparticles of catalytically active metal supported on at least one nanoparticle of crystalline RuO2. The diameter of the at least one nanoparticle of the crystalline RuO2 may be about order of magnitude larger than the diameter of the one or more nanoparticles of catalytically active metal.Type: GrantFiled: July 30, 2018Date of Patent: January 18, 2022Assignee: HYDROLITE LTDInventors: Yair Paska, Miles Page, Charly David Azra, Ben Achrai, Anna Kitayev
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Patent number: 11220583Abstract: A block copolymer, an ion-exchange membrane including the block copolymer and a method of preparing the block copolymer are provided. The block copolymer may include a hydrophobic repeating unit and a hydrophilic repeating unit.Type: GrantFiled: June 10, 2020Date of Patent: January 11, 2022Assignee: Korea Institute Of Energy ResearchInventors: Byungchan Bae, Sung-Dae Yim, Chang-Soo Kim, Won-Yong Lee, Gu-Gon Park, Tae-Hyun Yang, Seok-Hee Park, Minjin Kim, Young-Jun Sohn, Seung-Gon Kim, Dong Won Shin, Adam Febriy-Anto Nugraha
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Patent number: 11196070Abstract: Disclosed are a membrane-electrode assembly for fuel cells and a method of manufacturing the same. The membrane-electrode assembly for fuel cells may include an electrolyte membrane including a phosphonic acid functionalized graphene oxide in order to improve the mechanical strength and proton conductivity thereof and a method of manufacturing the same.Type: GrantFiled: November 6, 2019Date of Patent: December 7, 2021Assignees: Hyundai Motor Company, Kia Motors Corporation, Industry Foundation of Chonnam National UniversityInventors: In Yu Park, Jong Kil Oh, Bo Ki Hong, Aniket Kumar, Sun Ju Song, Jae Woon Hong
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Patent number: 11189853Abstract: Embodiments of the invention include fuel cells incorporating sheets and/or powders of silica fibers and methods for producing such devices. The silica fibers may be formed via electrospinning of a sol gel produced with a silicon alkoxide reagent, such as tetraethyl ortho silicate, alcohol solvent, and an acid catalyst.Type: GrantFiled: September 23, 2019Date of Patent: November 30, 2021Assignee: AMERICAN NANO LLC.Inventors: Mitch Dellinger, Surya Raj Banks
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Catalyst layer composition for improved performance of membrane assembly electrode with ionic liquid
Patent number: 11189851Abstract: A membrane electrode assembly for a polymer electrolyte membrane fuel cell includes an anodic catalyst layer, a cathodic catalyst layer, and a polymer electrolyte membrane mediating protic communication between the anodic and cathodic catalyst layers. The cathodic catalyst layer includes an ionic liquid, 1-methyl-2,3,4,6,7,8-hexahydro-1H-pyrimido[1,2-a]pyrimidin-9-ium 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate, in admixture with carbon-supported particles of platinum or a platinum alloy. The ionic liquid improves performance in both high moisture and low moisture operating conditions.Type: GrantFiled: January 3, 2019Date of Patent: November 30, 2021Assignees: Toyota Motor Engineering & Manufacturing North America, Inc., Toyota Jidosha Kabushiki KaishaInventors: Kan Huang, Hongfei Jia, Hisao Kato -
Patent number: 11171385Abstract: A method of forming a separator for a lithium-ion battery includes arranging a polymer film in contact with a sacrificial layer to form a cutting stack. The method includes disposing the cutting stack between a first vitreous substrate and a second vitreous substrate. The method includes applying an infrared laser to the cutting stack through the first vitreous substrate to generate heat at the sacrificial layer. The method also includes transferring heat from the sacrificial layer to the polymer film to thereby cut out a portion of the polymer film and form the separator. A method of cutting a polymer film and a cutting system are also explained.Type: GrantFiled: July 12, 2018Date of Patent: November 9, 2021Assignee: GM Global Technology Operations LLCInventors: Hongliang Wang, Brian J. Koch, Michael P. Balogh, Sean R. Wagner
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Patent number: 11170943Abstract: A supercapacitor electrode includes a substrate and at least one nitrogen-doped ultra-nanocrystalline diamond layer. The nitrogen-doped ultra-nanocrystalline diamond layer is disposed on the substrate. The nitrogen-doped ultra-nanocrystalline diamond layer is a dense continuous film. A conductivity of the supercapacitor electrode is 130 S/cm or more. In addition, a manufacturing method of a supercapacitor electrode is provided.Type: GrantFiled: May 3, 2020Date of Patent: November 9, 2021Assignee: National Taiwan University of Science and TechnologyInventors: Bohr-Ran Huang, Adhimoorthy Saravanan, Shyan-Kay Jou
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Patent number: 11158864Abstract: Improved catalyst layers for use in fuel cell membrane electrode assemblies, and methods for making such catalyst layers, are provided. Catalyst layers can comprise structured units of catalyst, catalyst support, and ionomer. The structured units can provide for more efficient electrical energy production and/or increased lifespan of fuel cells utilizing such membrane electrode assemblies. Catalyst layers can be directly deposited on exchange membranes, such as proton exchange membranes.Type: GrantFiled: June 2, 2020Date of Patent: October 26, 2021Assignee: Nikola CorporationInventor: John Slack
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Patent number: 11145873Abstract: A membrane electrode assembly includes an electrolyte membrane, and a pair of electrodes sandwiching the electrolyte membrane. The pair of electrodes each include a catalyst layer, and a gas diffusion layer disposed on the catalyst layer on an opposite side to the electrolyte membrane. At least one of the catalyst layers contains first catalyst particles, and second catalyst particles. The first catalyst particles are either platinum particles or platinum alloy particles, or both. The second catalyst particles are core-shell particles having a core part and a shell part, the core part formed of at least one selected from transition metals other than platinum, the shell part covering the core part and formed of at least one of platinum and a platinum alloy. In the catalyst layer, the second catalyst particles are present in a smaller percentage in an electrolyte membrane side than they are in a gas diffusion layer side.Type: GrantFiled: February 19, 2018Date of Patent: October 12, 2021Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.Inventors: Kazuya Yamasaki, Hitoshi Ishimoto, Motohiro Sakata
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Patent number: 11121381Abstract: Provided is a method for manufacturing a fuel cell stack that can manufacture the fuel cell stack efficiently, can improve the precision for joining and can improve the power generation efficiency. The method for manufacturing a fuel cell stack repeatedly stacks a separator, an electrode assembly and a separator in this order in accordance with the laminated structure of the fuel cell stack to be manufactured to manufacture the fuel cell stack. When the electrode assembly is stacked on the separator, the method pressurizes the electrode assembly stacked on the separator and applies laser light to the electrode assembly to join the resin frame of the electrode assembly to the separator. When the separator is stacked on the electrode assembly, the method pressurizes the separator stacked on the electrode assembly and applies laser light to the separator to join the separator to the resin frame of the electrode assembly.Type: GrantFiled: March 7, 2019Date of Patent: September 14, 2021Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Shunsuke Suzuki, Tomokazu Hayashi
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Patent number: 11085124Abstract: An electrochemical reaction device comprises: an anode unit to oxidize water and thus generate oxygen; a cathode unit to reduce carbon dioxide and thus generate a carbon compound and hydrogen; a separator separating the anode and cathode units; and a power supply connected to the anode and cathode units, the cathode unit including: a porous member having a first surface and a second surface; a flow path plate facing the first surface; and a reduction catalyst on the second surface, and the flow path plate including: a flow path through which a target gas containing the carbon dioxide flows; and a porous film separating a first space and a second space inside the flow path and being permeated with an ionic liquid, the ionic liquid being configured to separate the carbon dioxide from the target gas.Type: GrantFiled: September 4, 2019Date of Patent: August 10, 2021Assignee: KABUSHIKI KAISHA TOSHIBAInventors: Masakazu Yamagiwa, Ryota Kitagawa, Yuki Kudo, Akihiko Ono, Satoshi Mikoshiba, Jun Tamura, Yoshitsune Sugano, Asahi Motoshige
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Patent number: 11088379Abstract: An electrolyte membrane of a membrane-electrode assembly has improved chemical durability. The electrolyte membrane includes a composite, which includes an antioxidant in an ionic state and a first ionomer surrounding the antioxidant. The composite is dispersed in a second ionomer, which is a polymer matrix. A manufacturing method for the electrolyte membrane includes preparing an antioxidant solution, mixing the antioxidant solution and a first ionomer dispersion solution, drying the mixture to produce a composite having an antioxidant and a first ionomer surrounding the antioxidant, introducing and mixing the composite with a second ionomer dispersion solution, and applying that mixture to a substrate and drying the mixture to manufacture an electrolyte membrane.Type: GrantFiled: April 16, 2019Date of Patent: August 10, 2021Assignees: HYUNDIA MOTOR COMPANY, KIA MOTORS CORPORATIONInventor: Yong Min Kim
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Patent number: 11078578Abstract: A system comprises a first electrode, an electrolyte membrane, and a second electrode. The first electrode is configured to reduce oxygen in a gas to an oxygen carrier ion at an intermediate temperature. The electrolyte membrane is configured to transport the oxygen carrier ion, and the second electrode is configured to oxidize the oxygen carrier ion to an oxygen molecule. Oxidation of the oxygen molecule consumes less than four electrons.Type: GrantFiled: January 25, 2018Date of Patent: August 3, 2021Assignee: Palo Alto Research Center IncorporatedInventors: Divyaraj Desai, Jessica Louis Baker Rivest
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Patent number: 11081707Abstract: The invention relates to a fuel cell (2), comprising at least one membrane-electrode unit (10) having a first electrode (21) and a second electrode (22), which are separated from each other by a membrane (18), and at least two bipolar plates (40), which connect the membrane-electrode unit (10) on both sides, wherein the bipolar plates (40) are penetrated by a first supply channel, for supplying a fuel, and by a second supply channel, for supplying an oxidation means, wherein a first distribution structure (50) facing the first electrode (21) connects to a first edge of the first supply channel, and a second distribution structure (60) facing the second electrode (22) connects to a second edge of the second supply channel. The first electrode (21) extends along the membrane (18) in a region which is spaced apart from the first edge of the first supply channel, and the second electrode (22) extends along the membrane (18) in a region which is spaced apart from the second edge of the second supply channel.Type: GrantFiled: November 30, 2017Date of Patent: August 3, 2021Assignee: Robert Bosch GmbHInventor: Martin Schulte Moenting
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Patent number: 11038190Abstract: A membrane electrode assembly for a fuel cell that includes a membrane electrode unit with a membrane and two electrodes which make surface contact with both faces of the membrane. The membrane electrode assembly has a seal support that surrounds the periphery of the membrane and that overlaps the latter. The membrane electrode also has a connecting layer which continuously overlaps the membrane and the seal support, an inner edge section of the connecting layer being bonded to the membrane electrode unit and an outer edge section of the connecting layer being bonded to the seal support on the same flat face of the connecting layer. A seal is connected outside the membrane to the seal support. A fuel cell is provided that includes a plurality of membrane electrode assemblies. A motor vehicle includes the fuel cell and a method is provided for producing the membrane electrode assembly.Type: GrantFiled: April 27, 2015Date of Patent: June 15, 2021Assignee: Volkswagen AktiengesellschaftInventor: Benno Andreas-Schott
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Patent number: 11034808Abstract: The present application relates to a polymer, a method for manufacturing the same, and an electrolyte membrane including the same.Type: GrantFiled: December 2, 2015Date of Patent: June 15, 2021Assignee: LG CHEM, LTD.Inventors: Hyungsam Choi, Byungguk Kim, Youngsik Eom, Chong Kyu Shin, Keun Won Song
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Patent number: 11038183Abstract: An apparatus of manufacturing an elastomeric cell frame for a fuel cell may include, as the apparatus of manufacturing the elastomeric cell frame including an insert in which a membrane electrode assembly and a gas diffusion layer have been bonded, and a sheet-like elastomeric frame made of a thermoplastic elastomer (TPE) integrated into an external area of the insert to form the unit cell of the fuel cell, a lower jig module accommodated so that the overlapping area, in which the insert and the elastomeric frame overlap at a predetermined area, is accommodated, and an upper jig module mounted above the lower jig module to provide heat and pressure to the overlapping area to thermally bond an interface between the insert and the elastomeric frame in the overlapping area.Type: GrantFiled: November 19, 2019Date of Patent: June 15, 2021Assignees: Hyundai Motor Gompany, Kia CorporationInventors: Jin Hyeok Yoo, Byung Gun Song, Byeong-Heon Jeong
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Patent number: 11035053Abstract: Disclosed are ruthenium nanoparticles having an essentially face-centered cubic structure. Disclosed is a method for producing ruthenium nanoparticles having an essentially face-centered cubic structure. This production method includes a step (i) of maintaining a solution containing ruthenium (III) acetylacetonate, polyvinylpyrrolidone, and triethylene glycol at a temperature of 180° C. or higher.Type: GrantFiled: September 13, 2012Date of Patent: June 15, 2021Assignee: JAPAN SCIENCE AND TECHNOLOGY AGENCYInventors: Hiroshi Kitagawa, Kohei Kusada
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Patent number: 11024866Abstract: An elastomeric cell frame forming a unit cell of a fuel cell stack may include an insert in which a membrane electrode assembly and a pair of gas diffusion layers are bonded to each other; and an elastomeric frame disposed to surround a periphery of side surfaces of the insert, in which the side surfaces of the insert are positioned between the upper and lower surfaces of the insert, one of upper and lower surfaces of the insert and side surfaces of the insert and bonded with the periphery of the surface of the insert and the side surfaces of the insert into an integrated structure by thermal bonding.Type: GrantFiled: October 31, 2019Date of Patent: June 1, 2021Assignees: Hyundai Motor Company, Kia Motors CorporationInventors: Byeong-Heon Jeong, Jin Hyeok Yoo, Seong Il Heo
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Patent number: 11024910Abstract: The present disclosure relates to the development and improvement of a High-Temperature Sulfate/Sulfide device, in particular a High-Temperature battery using a Sulfate/Sulfide redox couple (HTSSB) for electrical energy storage at elevated temperatures and the like, and electrical energy storage device comprising the same.Type: GrantFiled: February 22, 2018Date of Patent: June 1, 2021Assignee: Universidade De AveiroInventors: Tao Yang, Sergey M. Mikhalev, Aliaksandr Shaula, Duncan P. Fagg
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Patent number: 11018363Abstract: A fuel cell includes: a membrane-electrode-gas diffusion layer assembly; a separator positioned in one side with respect to the membrane-electrode-gas diffusion layer assembly; a frame member supporting the membrane-electrode-gas diffusion layer assembly and joined to the separator, wherein the frame member includes: a base layer; an adhesive layer having thermoplasticity, having a linear expansion coefficient greater than that of the base layer, and joining the base layer and the separator; and a coating, layer provided on a side, opposite to the adhesive layer, of the base layer, having a liner expansion coefficient greater than that of the base layer, and not containing an adhesive component.Type: GrantFiled: October 8, 2018Date of Patent: May 25, 2021Assignee: Toyota Jidosha Kabushiki KaishaInventor: Kazunori Shibata
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Patent number: 11005107Abstract: A method for improving the performance and/or stability of non-precious metal catalysts in fuel cells and other electrochemical devices. Improved membrane electrode assemblies (MEAs) and fuel cells containing the same are provided. Such MEAs include a catalyst layer made up of at least two sub-layers containing ionomers of differing equivalent weights. The sub-layers may optionally contain mixtures of ionomers. Also provided are methods of making and using the described devices.Type: GrantFiled: September 29, 2017Date of Patent: May 11, 2021Assignee: NISSHINBO HOLDINGS INC.Inventors: Dustin William H Banham, Siyu Ye, Takeaki Kishimoto, Kyoung Bai
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Patent number: 11005121Abstract: A sealing part has an outer peripheral point of the sealing part within a range from 0 degree to 90 degrees around a center point of the sealing part relative to a stacking direction, and that is located at a distance of a first length L1 from the center point. Each point on the outer peripheral line within a first range satisfies L2?L1, where L2 is a second length that is a distance from the center point to that point. Each point on the outer peripheral line within a second range satisfies L3<L1, where L3 is a distance from the center point to that point, and is located on the opposite side of the outer peripheral point from the center point or at the same position as the outer peripheral point in the direction perpendicular to the stacking direction.Type: GrantFiled: October 2, 2017Date of Patent: May 11, 2021Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Kenji Sato, Hideya Kadono