Abstract: Disclosed are a catalyst for a fuel cell, a method of preparing the same, and an electrode for a fuel cell, a membrane-electrode assembly for a fuel cell, and a fuel cell system including the same, and the catalyst includes a carrier; and an active metal supported on the carrier, wherein the carrier is crystalline carbon bonded with a functional group represented by the following Chemical Formula 1 at the surface thereof. In Chemical Formula 1, each substituent is the same as described in the detailed description.

Abstract: A catalyst precursor is provided having a thermally decomposable porous support; an organic coating/filling compound, and a non-precious metal precursor, wherein the organic coating/filling compound and the non-precious metal catalyst precursor coat and/or fill the pores of the thermally decomposable porous support.

Abstract: The invention discloses core/shell, type catalyst particles comprising a Mcore/Mshell structure with Mcore=inner particle core and Mshell=outer particle shell, wherein the medium diameter of the catalyst particle (dcore+shell) is in the range of 20 to 100 nm, preferably in the range of 20 to 50 nm. The thickness of the outer shell (tshell) is about 5 to 20% of the diameter of the inner particle core of said catalyst particle, preferably comprising at least 3 atomic layers. The core/shell type catalyst particles, particularly the particles comprising a Pt˜based shell reveal a high specific activity. The catalyst particles are preferably supported on suitable support materials such as carbon black and are used as electrocatalysts for fuel cells.

Abstract: A nanofibrous catalyst and method of manufacture. A precursor solution of a transition metal based material is formed into a plurality of interconnected nanofibers by electro-spinning the precursor solution with the nanofibers converted to a catalytically active material by a heat treatment. Selected subsequent treatments can enhance catalytic activity.

Abstract: The invention disclosed is a catalyst composition for an air cathode for use in an electrochemical cell, in particular in alkaline electrolyte metal-air e.g. zinc-air, fuel cells. The catalyst composition comprises an active material CoTMMP and silver, supported on carbon wherein the ratio of silver to CoTMPP is 1:1 to 2.4:1. Optional ingredients include a hydrophobic and a hydrophobic bonding agent, MnO2, WC/Co or both. The catalyst composition is supported on microporous support layer and nickel foam or mesh to form an air cathode.

Abstract: A multimetallic nanoscale catalyst having a core portion enveloped by a shell portion and exhibiting high catalytic activity and improved catalytic durability. In various embodiments, the core/shell nanoparticles comprise a gold particle coated with a catalytically active platinum bimetallic material. The shape of the nanoparticles is substantially defined by the particle shape of the core portion. The nanoparticles may be dispersed on a high surface area substrate for use as a catalyst and is characterized by no significant loss in surface area and specific activity following extended potential cycling.

Abstract: A cathode catalyst for a fuel cell includes a carrier, and an active material including M selected from the group consisting of Ru, Pt, Rh, and combinations thereof, and Ch selected from the group consisting of S, Se, Te, and combinations thereof, with the proviso that the active material is not RuSe when the carrier is C.

Abstract: An electrode for fuel cells including a catalyst layer containing a benzoxazine monomer, a catalyst and a binder, and a fuel cell employing the electrode. The electrode for the fuel cells contains an even distribution of benzoxazine monomer, which is a hydrophilic (or phosphoric acidophilic) material and dissolves in phosphoric acid but does not poison catalysts, thereby improving the wetting capability of phosphoric acid (H3PO4) within the electrodes and thus allowing phosphoric acid to permeate first into micropores in electrodes. As a result, flooding is efficiently prevented. That is, liquid phosphoric acid existing in large amount within the electrodes inhibits gas diffusion which; this flooding occurs when phosphoric acid permeates into macropores in the electrodes. This prevention of flooding increases the three-phase interfacial area of gas (fuel gas or oxidized gas)-liquid (phosphoric acid)-solid (catalyst).

Abstract: An electrode for a fuel cell including a gas diffusion layer, and a catalyst layer bound to at least one surface of the gas diffusion layer and including a catalyst and a binder; and a fuel cell including the electrode.

Abstract: The invention relates to gas diffusion electrodes for rechargeable electrochemical cells, which comprise at least one support material bearing at least one catalyst, wherein the support material comprises at least one compound selected from the group consisting of electrically conductive metal oxides, carbides, nitrides, borides, silicides and organic semiconductors. The present invention further relates to a process for producing such gas diffusion electrodes and also rechargeable electrochemical cells comprising such gas diffusion electrodes.

Abstract: Novel cathode, electrolyte and oxygen separation materials are disclosed that operate at intermediate temperatures for use in solid oxide fuel cells and ion transport membranes based on oxides with perovskite related structures and an ordered arrangement of A site cations. The materials have significantly faster oxygen kinetics than in corresponding disordered perovskites.

Abstract: A hydrocarbon reforming catalyst, a method of preparing the hydrocarbon reforming catalyst, and a fuel cell including the hydrocarbon reforming catalyst. The hydrocarbon reforming catalyst includes an oxide support as well as a nickel active catalyst layer, a metal oxide, an alkali metal supported by the oxide support.

Abstract: An oxygen reduction electrode and a fuel cell including the same are provided. A catalyst layer of the oxygen reduction electrode includes a metalloporphyrin derivative as an additive. Accordingly, the oxygen reduction electrode can increase oxygen concentration and can easily form a triple phase boundary by reducing a flooding phenomenon caused by an electrolyte. A fuel cell including the same is also provided.

Abstract: This invention relates to a method for preparing an air electrode based on Pr2-xNiO4 with 0?x<2, comprising a step consisting in sintering a ceramic ink comprising Pr2-xNiO4 and a pore-forming agent at a temperature above 1000° C. and below or equal to 1150° C. This invention also relates to the air electrode thus obtained and its uses.

Abstract: A solid oxide fuel cell (SOFC) includes a cathode electrode, a solid oxide electrolyte, and an anode electrode having a first portion and a second portion, such that the first portion is located between the electrolyte and the second portion. The anode electrode comprises a cermet comprising a nickel containing phase and a ceramic phase. The first portion of the anode electrode contains a lower porosity and a lower ratio of the nickel containing phase to the ceramic phase than the second portion of the anode electrode. The nickel containing phase in the second portion of the anode electrode comprises nickel and at least one other metal which has a lower electrocatalytic activity than nickel.

Abstract: The present invention relates to a mixed metal oxide exhibiting perovskite-type structural characteristics in which there are cations of Ba, Ca or Sr, a rare earth metal and Fe, Cr, Cu, Co or Mn present in three different coordination sites or a composition thereof, to a cathode composed of the mixed metal oxide or composition thereof and to a solid oxide fuel cell comprising the cathode.

Abstract: Disclosed is a method for producing an electrolyte membrane for fuel cells, which is characterized in that a radically polymerizable monomer is graft-polymerized to a resin without using a photopolymerization initiator by bringing the radically polymerizable monomer into contact with the resin after irradiating the resin with ultraviolet light. The electrolyte membrane for fuel cells obtained by ultraviolet irradiation graft polymerization has both excellent oxidation resistance and excellent mechanical characteristics. By using such an electrolyte membrane, there can be obtained a fuel cell exhibiting extremely high performance.

Abstract: A catalyst layer including an electrocatalyst and an oxygen evolution catalyst, wherein the oxygen evolution catalyst includes a crystalline metal oxide including: (i) one of more first metals selected from the group consisting of yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, magnesium, calcium, strontium, barium, sodium, potassium, indium, thallium, tin, lead, antimony and bismuth; (ii) one or more second metals selected from the group consisting of Ru, Ir, Os and Rh; and (iii) oxygen characterised in that: (a) the atomic ratio of first metal(s):second metal(s) is from 1:1.5 to 1.5:1 (b) the atomic ratio of (first metal(s)+second metal(s)):oxygen is from 1:1 to 1:2 is disclosed.

Abstract: A nickel/zinc (Ni/Zn) flow battery employs a solid suspension charge material to maintain high charge density via stability of a suspension including a binder, conductive carbon and an electrolyte. Zinc oxide (ZnO) is employed as the anodic (anode) charge material and nickel hydroxide (Ni(OH)2) is employed as the cathodic (cathode) charge material, and form respective anodic and cathodic suspensions using carbon powder and additives to form particles having high stability and high energy density. The resulting suspensions are circulated in a charge cell connected to a load for providing electrical power.

Abstract: An electrode catalyst for a fuel cell including a carbon-based carrier and an active metal supported in the carrier, for example, an electrode catalyst for a fuel cell includes a carrier and an active metal supported in the carrier, wherein the electrode catalyst has an X value of 95 to 100% in Equation 1. X(%)=(XPS measurement value)/(TGA measurement value)×100??[Equation 1] wherein, the XPS measurement value represents a quantitative amount of the active metal present on a surface of the electrode catalyst, the TGA measurement value represents the XPS measurement value using a monochromated Al K?-ray, which is the quantitative amount of total active metal supported in the catalyst.

Abstract: The present invention is directed to the fabrication of thin aluminum anode batteries using a highly reproducible process that enables high volume manufacturing of the galvanic cells. In the present invention, semiconductor fabrication methods are used to fabricate aluminum galvanic cells, wherein a catalytic material to be used as the cathode is deposited on a substrate and an insulating spacing material is deposited on the cathode and patterned using photolithography. The spacing material can either be used as a sacrificial layer to expose the electrodes or serve as a support for one of the electrodes. Similarly, the aluminum anode may be deposited and patterned on another substrate and bonded to the first substrate, or can be deposited directly on the insulating material prior to patterning. The cell is packaged and connected to a delivery system to provide delivery of the electrolyte when activation of the cell is desired.

Abstract: A membrane-electrode assembly for a fuel cell includes an anode and a cathode facing each other and a polymer electrolyte membrane interposed therebetween. At least one of the anode and the cathode includes a conductive electrode substrate and a catalyst layer formed thereon, and the catalyst layer includes a first catalyst layer including a first metal catalyst that grows from the polymer electrolyte membrane toward the electrode substrate and a second catalyst layer including a second metal catalyst covering the first catalyst layer.

Abstract: Disclosed are metallized carbonaceous materials, processes for forming such materials, and electrodes and fuel cells comprising the disclosed materials.

Abstract: Anode catalysts for conversion of hydrocarbon feeds in solid oxide fuel cell membrane reactors. An anode catalyst may be a mixture of a metal with a metal oxide, for example a mixture of copper or copper-nickel alloy or copper-cobalt alloy with Cr2O3. Mixed oxides can be prepared by dissolving into water soluble salts of the different metals, chelating the metal ions with a chelating agent, neutralizing the solution, removing water by evaporation to form a gel which then is dried, and finally heating the dried gel to form a mixed oxide of the different metals. The chelating agent can be citrate ions, and ammonia can be added to the solution until the pH of the solution is about 8. The mixed oxide so formed then is reduced, for example by hydrogen, to form a composite comprising the metal (Cu, Cu—Co, Cu—Ni) and metal oxide, here Cr2O3.

Abstract: Provided are a fuel cell electrode and a membrane electrode assembly in which catalyst particles are prevented from dissolving and the function of added catalyst can be sufficiently exerted when the fuel cell is operating at high current density. The fuel cell electrode includes an electrode material containing: an electrocatalyst having catalyst particles supported on a conductive support; a first ion conductor having anion conductivity; and a second ion conductor having a cation conductivity, the first and second ion conductors covering the electrocatalyst. The first ion conductor is provided to cover the catalyst particles, and the second ion conductor is provided to cover the first ion conductor and exposed part of the conductive support. The membrane electrode assembly includes the fuel cell electrode as at least one of the anode and cathode.

Abstract: A technology is provided that is capable of improving deterioration of a fuel cell due to non-stationary operation (startup/shutdown, fuel depletion). An anode-side catalyst composition comprising a catalyst having catalyst particles carried on electrically conductive material and an ion exchange resin, characterized in that the catalyst particle are formed of an alloy, of which oxygen reduction capability and water electrolysis are both lower than those of platinum, and which has hydrogen oxidation capability.

Abstract: A process for preparing a durable non-precious metal oxygen reduction electrocatalyst involves heat treatment of a ball-milled mixture of polyaniline and multiwalled carbon nanotubes in the presence of a Fe species. The catalyst is more durable than catalysts that use carbon black supports. Performance degradation was minimal or absent after 500 hours of operation at constant cell voltage of 0.40 V.

Abstract: An electrode catalyst for a fuel cell, the electrode catalyst including a first catalyst that exhibits hydrophilicity, the first catalyst including pores, wherein at least 50 volume percent of the pores have an average diameter of about 100 nanometers or less; a method of preparing the electrode catalyst; and a membrane electrode assembly (MEA) and a fuel cell that include the electrolyte catalyst. The electrode catalyst for a fuel cell rapidly controls the migration of phosphoric acid at an initial stage of operation of an MEA, thereby securing a path for the migration of a conductor and a path for the diffusion of a fuel, and thus, an activation time of the MEA is shortened.

Abstract: The present invention relates to an electro-catalyst M?aIrbMc, wherein M? is selected from the group consisting of Pt, Ta and Ru, and wherein the molar ratio a:b is within the range of 85:15 to 50:50 and the molar ratio a:c is within the range of 50:50 to 95:5, both calculated as pure metal and wherein M is selected from metals from Groups 3-15 of the Periodic System of Elements. The present invention further relates to an electrode comprising a support and the electro-catalyst. The present invention further relates to the use of the electro-catalyst and/or the electrode in electrochemical processes which comprise an oxygen reduction reaction (ORR), an oxygen evolution reaction (OER), a hydrogen evolution reaction (HER), a hydrogen oxidation reaction (HOR), a carbon monoxide oxidation reaction (COR) or a methanol oxidation reaction (MOR).

Abstract: The present invention relates to a catalyst composite material which includes a catalyst characterized by oxygen-reducing activity and which is selected from the group consisting of metals, metal oxides, and combinations thereof, and a resin layer which covers at least a portion of the surface of the catalyst and comprises an anion exchange resin layer and a cation exchange resin layer.

Abstract: Powdered grit comprising a fused cermet of zirconium oxide (ZrO2) doped with a dopant chosen from yttrium, scandium, and a mixture of scandium and of aluminium and/or of cerium, and of nickel (Ni) and/or of cobalt (Co), said cermet having a eutectic structure, the contents, in mol %, of zirconium oxide, nickel and cobalt being such that 0.250Ni+0.176Co?(ZrO2+dopant)?0.428Ni+0.333Co, and said powdered grit having a median diameter D50 of between 0.3 ?m and 100 ?m.

Abstract: The present invention discloses a hydrogen-recyclable fuel cell comprising anode set, cathode set, catalytic layer, proton exchange membrane, hydrogen delivering device, hydrogen-storage complex metal layer and hydrogen drawing device. The hydrogen delivering device delivers hydrogen to the catalytic layer which ionizes hydrogen into electrons and hydrogen ions. After the hydrogen ions pass through the proton exchange membrane, they react with the hydrogen-storage complex metal layer and the electrons to produce complex metal hydrides. The hydrogen drawing device draws hydrogen from the complex metal hydrides into the storage tank for further reuse.

Abstract: The invention provides part solid, part fluid and flow electrochemical cells, for example, metal-air and lithium-air batteries and three-dimensional electrode arrays for use in part solid, part fluid electrochemical and flow cells and metal-air and lithium-air batteries.

Abstract: Positive electrode active materials are described that have a high tap density and high specific discharge capacity upon cycling at room temperature and at a moderate discharge rate. Some materials of interest have the formula Li1+xNi?Mn?Co?O2, where x ranges from about 0.05 to about 0.25, ? ranges from about 0.1 to about 0.4, ? ranges from about 0.4 to about 0.65, and ? ranges from about 0.05 to about 0.3. The materials can be coated with a metal fluoride to improve the performance of the materials especially upon cycling. Also, the coated materials can exhibit a very significant decrease in the irreversible capacity lose upon the first charge and discharge of the battery.

Abstract: An electrode catalyst for a fuel cell including porous catalyst particles including a noble metal having oxygen-reduction activity and a carbonaceous support, wherein the porous catalyst particles are disposed on the carbonaceous support, and an electrochemical specific surface area of the porous catalyst particles is about 70 m2/g or more.

Abstract: An electrode for a fuel cell, a method of preparing the electrode, a catalyst slurry, and a fuel cell including the electrode. The electrode includes an electrode support and a catalyst layer formed on the electrode support, wherein the catalyst layer includes a catalyst material and a water-based binder, wherein the water-based binder is at least one selected from the group consisting of cellulose derivatives and composites of organic polymer materials and inorganic oxides.

Abstract: Disclosed is a Ni—Al alloy anode for molten carbonate fuel cell made by in-situ sintering the Ni—Al alloy. Further, disclosed is a method for preparing the same comprising steps of preparing a sheet with Ni—Al alloy powders (S1); and installing the sheet in a fuel cell without any heat treatment for sintering the Ni—Al alloy in the sheet and then in-situ sintering the Ni—Al alloy in the sheet during a pretreatment process of the cell with the sheet (S2), wherein a reaction activity of the Ni—Al alloy anode can be maintained, the method is simple and economic, and a mass production of the Ni—Al alloy anode and a scale-up in the method are easy.

Abstract: The present invention relates to a catalyst composition, a method for fabricating the same and a fuel cell including the same. The catalyst composition provided by the present invention includes: a catalyst carrier; and a metal solid solution, disposed on the surface of the catalyst carrier, in which the metal solid solution includes palladium and a second metal, and the second metal is selected from the group consisting of gold, platinum, ruthenium, nickel, silver and manganese. Accordingly, the catalyst composition provided by the present invention can exhibit excellent catalytic characteristics, and can be applied in a fuel cell to enhance the electrochemical properties and stability of the fuel cell.

Abstract: According to one embodiment, a catalyst-supporting substrate comprises a substrate and a catalyst layer including a plurality of pores, the catalyst layer being supported on the substrate. The average diameter of the section of the pore when the catalyst is cut in the thickness direction of the thickness is 5 nm to 400 nm, and the long-side to short-side ratio of the pore on the section is 1:1 to 10:1 in average.

Abstract: Disclosed is a method for producing a core-shell structured electrocatalyst for a fuel cell. The method includes uniformly supporting nano-sized core particles on a support to obtain a core support, and selectively forming a shell layer only on the surface of the core particles of the core support. According to the method, the core and the shell layer can be formed without the need for a post-treatment process, such as chemical treatment and heat treatment. Further disclosed is a core-shell structured electrocatalyst for a fuel cell produced by the method. The core-shell structured electrocatalyst has a large amount of supported catalyst and exhibits superior catalytic activity and excellent electrochemical properties. Further disclosed is a fuel cell including the core-shell structured electrocatalyst.

Abstract: A composite anode for a solid oxide fuel cell (SOFC), comprising an anode support layer (ASL) of Ni—YSZ and an anode functional layer (AFL) of Ni—GDC, displays enhanced mechanical stability and similar or improved electrical efficiency to that of a Ni—GDC ASL for otherwise identical SOFCs. A SOFC employing the composite anode can be used for power generation at temperatures below 700° C., where the composite anode may include a second AFL of GDC disposed between the Ni—GDC layer and a GDC electrolyte.

Abstract: This invention provides a fuel cell electrode catalyst in which at least one transition metal element and at least one chalcogen element are supported on a conductive support, wherein the fuel cell electrode catalyst comprises a core portion comprising a transition metal crystal and a shell portion comprising surface atoms of the transition metal crystal particle and chalcogen elements coordinating to the surface atoms, and the outer circumference of the core portion is being partially covered with the shell portion. The fuel cell electrode catalyst has a high level of oxygen reduction performance, high activity as a fuel cell catalyst and comprises a transition metal element and a chalcogen element.

Abstract: In one aspect, the present subject matter is directed to a composite anode for a hydrocarbon solid oxide fuel cell, the anode comprising a layered perovskite ceramic and a bi-metallic alloy.

Abstract: A membrane-electrode assembly for a fuel cell includes an anode and a cathode facing each other and a polymer electrolyte membrane interposed therebetween. At least one of the anode and the cathode includes a conductive electrode substrate and a catalyst layer formed thereon, and the catalyst layer includes a first catalyst layer including a first metal catalyst that grows from the polymer electrolyte membrane toward the electrode substrate and a second catalyst layer including a second metal catalyst covering the first catalyst layer.

Abstract: A porous carbonaceous composite material including a core including a carbon nanotube (CNT); and a coating layer on the core, the coating layer including a carbonaceous material including a hetero element.

Abstract: Compositions, electrodes, systems, and/or methods for water electrolysis and other electrochemical techniques are provided. In some cases, the compositions, electrodes, systems, and/or methods are for electrolysis which can be used for energy storage, particularly in the area of energy conversion, and/or production of oxygen, hydrogen, and/or oxygen and/or hydrogen containing species. In some embodiments, the water for electrolysis comprises at least one impurity and/or at least one additive which has little or no substantially affect on the performance of the electrode.

Abstract: Provided is a method for manufacturing a mixed catalyst containing a metal oxide nanowire, and an electrode and a fuel cell which include a mixed catalyst manufactured by the method. The method includes: forming a metal/polymer nanowire by electrospinning a polymer solution containing a first metal precursor and a second metal precursor; forming a metal oxide nanowire by heat-treating the metal/polymer mixture nanowire; and mixing the metal oxide nanowire with active metal nanoparticles. Here, the metal of the second metal precursor is used as a dopant for the metal oxide nanowire. In the event an electrode catalyst layer of a fuel cell is formed using the manufactured mixed catalyst, the fuel cell has the advantages of significantly improved performance and reduced costs in generating electricity.

Abstract: A process includes patterning a surface of a platinum group metal-based electrode by contacting the electrode with an adsorbate to form a patterned platinum group metal-based electrode including platinum group metal sites blocked with adsorbate molecules and platinum group metal sites which are not blocked.

Abstract: A material for a solid oxide fuel cell, the material including: a first compound having a perovskite crystal structure, a first ionic conductivity, a first electronic conductivity, and a first thermal expansion coefficient, wherein the first compound is represented by Formula 1 below; and a second compound having a perovskite crystal structure, a second ionic conductivity, a second electronic conductivity, and a second thermal expansion coefficient, BaaSrbCoxFeyZ1-x-yO3-?,??Formula 1 wherein Z is a transition metal element, a lanthanide element, or a combination thereof, a and b satisfy 0.4?a?0.6 and 0.4?b?0.6, respectively, x and y satisfy 0.6?x?0.9 and 0.1?y?0.4, respectively, and ? is selected so that the first compound is electrically neutral.

Abstract: This invention relates to an electrode catalyst for a fuel cell comprising catalyst metal particles of noble metal-base metal-Ce (cerium) ternary alloy carried on carbon materials, wherein the noble metal is at least one member selected from among Pt, Ru, Rh, Pd, Ag and Au, the base metal is at least one member selected from among Ir, Co, Fe, Ni and Mn, and the relative proportion (i.e., the molar proportion) of noble metal:base metal:Ce (cerium) is 20 to 95:5 to 60:0.1 to 3. The electrode catalyst for a fuel cell inhibits deterioration of an electrolyte membrane or an electrolyte in an electrode catalyst layer, improves durability, and, in particular, improves the capacity for power generation in the high current density region.