Abstract: This invention provides a nonaqueous electrolyte secondary battery including a positive electrode capable of absorbing/desorbing lithium ions, a negative electrode capable of absorbing/desorbing lithium ions, a nonaqueous electrolyte, and a Positive Thermal Coefficient, wherein the Positive Thermal Coefficient satisfies expression (1) below50/P<R (1)where R (m.OMEGA.) is the resistance at 25.degree. C. of the Positive Thermal Coefficient and P (Ah) is the nominal capacity of the secondary battery.

Abstract: The present invention concerns a negative electrode for an alkaline cell, comprising a current collector supporting a paste containing an electrochemically active material and a binder, characterized in that said binder is a polymer containing hydrophilic and hydrophobic groups, said polymer being selected from an acrylic homopolymer, copolymer and terpolymer, an unsaturated organic acid copolymer and an unsaturated acid anhydride copolymer.

Abstract: Disclosed are a hydrogen-occluding alloy electrode comprising an alloy powder wherein the alloy comprises a Ti-V solid solution mother phase and a secondary phase predominantly containing a Ti-Ni phase or an AB.sub.2 Laves phase in which the secondary phase forms a three-dimensional reticulate skeleton in the alloy; said hydrogen-occluding alloy powder surface-treated with hydrofluoric acid, to provide a titanium hydride surface and surface-coated with at least one metal of Ni, Cu and Co.

Abstract: An electrochemical heat exchanger including a housing, at least one electrochemical cell within the housing with a first electrode and a hydrogen electrode at least partially immersed in a liquid electrolyte, and positive and negative terminals of the electrochemical cell connected through the housing to respective positive and negative ends of a power supply. The housing includes a gas space which is in communication with a heat exchange chamber. The heat exchange chamber can be a flexible chamber capable of expanding in response to an increase in pressure in the electrochemical cell and contracting in response to a decrease in pressure in the electrochemical cell or it can be a conduit whereby an element to be cooled is placed in thermal contact with either hydrogen gas or a liquid coolant.

Abstract: A safety device for use in a secondary battery having a battery case formed with a hole open to outside of the battery case, and a generating unit airtightly housed in the battery case. The safety device includes a disk spring mounted on the battery case to close the hole and having one side thereof convexed toward the inside of the battery case. A switch is provided on the backside of the disk spring. It is adapted to change over under a stress applied from the disk spring when the disk spring bends backward so that the other side thereof is convexed toward the outside of the battery case. The switch is provided in a current flow path of the secondary battery.

Abstract: A hydrogen storage alloy electrode for use in electro-chemical hydrogen storage cells, the electrode being in the form of a negative electrode fabricated by sintering a mixture of a hydrogen storage alloy containing manganese and an alloy containing a measured amount of manganese.

Abstract: A sealed nonaqueous secondary battery comprising a sealed-end battery case containing an electrodes assembly composed of a cathode, and an anode both capable of intercalating and deintercalating a light metal, a separator therebetween and a nonaqueous electrolytic solution, the opening of said battery case being sealed with an insulating gasket which is provided at the inner periphery of said opening and a sealing part which is held by the gasket and serves as a cathode or anode terminal, wherein the sealing part comprises an explosion-proof valve which is capable of being deformed to the direction opposite to the electrodes assembly with an increase in internal pressure, a vented terminal cap which is provided above the explosion-proof valve in the side opposite to the electrodes assembly, and a current breaker which is provided between the explosion-proof valve and the terminal cap; the current breaker having a piled structure composed of a first electric conductor having a penetrated hole which is provided

Abstract: There is provided a hydrogen-absorbing alloy for battery comprising a rapidly-quenched alloy having the composition represented by a general formula ANi.sub.a M.sub.b M'.sub.c T.sub.d (where, A is composed of La, Ce, Pr, Nd and Y, an amount of La content in A is 50-99 wt %, an amount of Ce content is 1-30 wt %, an amount of Pr content is 0-10 wt %, an amount of Nd content is 0-10 wt % and an amount of Y content is 0-10 wt %; M is at least one element selected from Co, Fe and Cu; M' is at least one element selected from Mn and Al; T is at least one element selected from B, Si, S, Cr, Ga, Ge, Mo, Ru, Rh, Pd, Ag, In, Sn, Sb, Bi, P, V, Nb, Ta and W; and a, b, c and d are atomic ratios and satisfy 3.2.ltoreq.a.ltoreq.4.0, 0.4.ltoreq.b.ltoreq.1.0, 0.3.ltoreq.c.ltoreq.0.8, 0.ltoreq.d.ltoreq.0.2, 4.9.ltoreq.a+b+c+d.ltoreq.5.4), characterized in that a hydrogen equilibrium pressure when the number of hydrogen atoms absorbed by one atom of the alloy at a temperature of 60.degree. C. is 0.4 is 0.05-0.6 atm.

Abstract: An electrochemical heat exchanger including a housing, at least one electrochemical cell within the housing with a first electrode and a hydrogen electrode at least partially immersed in a liquid electrolyte, and positive and negative terminals of the electrochemical cell connected through the housing to respective positive and negative ends of a power supply. The housing includes a gas space which is in communication with a heat exchange chamber. The heat exchange chamber can be a flexible chamber capable of expanding in response to an increase in pressure in the electrochemical cell and contracting in response to a decrease in pressure in the electrochemical cell or it can be a conduit whereby an element to be cooled is placed in thermal contact with either hydrogen gas or a liquid coolant.

Abstract: A nickel positive electrode for an alkaline storage battery having an improved utilization is disclosed. It comprises a nickel hydroxide powder and a cobalt hydroxide powder, wherein the cobalt hydroxide powder has a specific surface area of 10 m.sup.2 /g or larger and a particle diameter of one-half or less of that of the nickel hydroxide powder. A nickel-metal hydroxide storage battery having this nickel positive electrode is also disclosed.

Abstract: As an active material for its negative electrode, a hydrogen storage alloy for a Ni/H battery has the compositionMmNi.sub.v Al.sub.w Mn.sub.x Co.sub.y M.sub.z,where Mm is a misch metal, M is Fe, Cu, or a mixture of Fe and Cu, and where0.1.ltoreq.z.ltoreq.0.4,0.2.ltoreq.y.ltoreq.0.4,0.3.ltoreq.w.ltoreq.0.5,0.2.ltoreq.x.ltoreq.0.4, and4.9.ltoreq.v+w+x+y+z.ltoreq.5.1.The partial substitution of Co by M, in conjunction with a special production method including the steps of atomizing the molten alloy, followed by heat-treatment and pulverization, leads to an alloy having a particularly high cycle lifetime and discharge capability.

Abstract: This invention provides a method to make a hydrogen storage hydride electrode and a hydride battery, particularly a sealed type, suitable for various temperatures. The battery, according to this invention, is composed of a container, a positive electrode, a negative electrode suitable for various temperatures comprising of at least two hydrogen storage electrode materials and/or their hydrides, a separator positioned between the positive and negative electrodes, and an electrolyte in the container and in contact with the positive and negative electrodes and the separator. The negative electrode is a hydrogen storage hydride electrode which is composed of at least two hydrogen storage electrode alloys having compositions represented by A.sub.a B.sub.b C.sub.c . . . and A'.sub.a' B'.sub.b' C'.sub.c' . . . respectively; where the set of elements: A, B, C, . . . and the set of elements: A', B', C', . . . , both are consisting of 6 to 80 at. % of nickel, preferably 24-55 at.

Abstract: This invention relates to a titanium alloy anode for the electrolytic production of manganese dioxide, wherein the alloy anode is made of titanium as a base metal, and comprises at least three other metals selected from the group consisting of manganese, chromium, iron, silicon, aluminum, cerium, neodymium and mischmetal; the addition of which may be within the range of 8 to 20 weight percent based on the weight of the total composition. The alloy anode, being easy to manufacture and having irregular sectional profiles, is free from severe passivation during electrolytic production using high current density due to its combined properties. The alloy anode, being highly resistant to corrosion by the electrolysis solution, requires no activation treatment during the electrolytic process. The purposefully-designed shapes of the anode permit good attachment of the deposited product layer and prevent the deposition from cracking and peeling-off.

Abstract: A hydrogen occlusion electrode comprising a compact of a mixture powder including a titanium-nickel alloy which contains oxygen.

Abstract: This invention discloses a method to make a light-weight and flexible electrode for electrochemical application especially for nickel hydride batteries. The method uses a conductive polymer as the substrate of an electrode. The conductive polymer can be an acidic or a basic type polymer. In the preparation of an electrode, the monomers of the conductive polymer can be used as the starting material. The electrode of this invention has about 20% more capacity than the electrode using nickel metal substrate.

Abstract: The present invention provides a non-aqueous secondary battery having an improved charge and discharge cycle property and high discharge voltage, high energy density, high capacity and increased stability as well as an excellent high electric current atitude by using a lithium-containing transition metal oxide as a positive electrode material and at least one of the specfified composite oxides as a negative electrode material. Accordingly, the feature of the present invention consists in that the negative electrode material mainly consists of at least one member selected from the group consisting of amorphous chalcogen compounds and amorphous oxides containing at least three atoms selected from the group consisting of Group 13, 14, 15 and 2 atoms of Periodic Table.

Abstract: The present invention discloses a method to make a high rate, fast oxygen recombination and long life rechargeable metal oxide-hydride batteries, and in particular, rechargeable nickel-hydride batteries. The battery, according to this invention, is composed of a high rate, fast oxygen recombination and long life hydrogen storage electrode as a negative electrode. The hydrogen storage material is prepared to have a thin oxide top surface layer and a metal-rich subsurface layer, especially a nickel-rich subsurface layer. In the microstructure, it is preferable that it consists of a nickel-rich composition in one type of the grains and/or in grain boundaries. The hydride electrode made has an electrochemical capacity from 1.15 to 2.40 AH/cc. Before or after cell assembly, sealing, and/or using, the hydrogen storage electrode is chemically or electrochemically precharged to a state having a half-cell open circuit potential of -0.790 to -0.905 V vs.

Abstract: Disclosed are a hydrogen-occluding alloy electrode comprising an alloy powder wherein the alloy comprises a Ti--V solid solution mother phase and a secondary phase predominantly containing a Ti--Ni phase or an AB.sub.2 Laves phase in which the secondary phase forms a three-dimensional reticulate skeleton in the alloy; said hydrogen-occluding alloy powder surface-treated with hydrofluoric acid to provide a titanium hydride surface and surface-coated with at least one metal of Ni, Cu and Co.

Abstract: A positive electrode and a negative electrode for an alkaline storage battery and manufacturing methods thereof are provided. The positive electrode includes a nickel porous body formed on a plate, active material particles containing nickel hydroxide and additives filled up into the nickel porous body, a conductive layer coated on the surface of active material particle, and a protective layer coated on the surface of the conductive layer, for increasing the binding force between the active material particles and preventing the contact between the active material particles and an electrolytic aqueous solution. The negative electrode comprises hydrogen storage metal particles.

Abstract: The present invention relates to manganese-containing nickel(II) hydroxide powders, wherein at least 50 mole % of the manganese are present in the trivalent oxidation state, a process for the preparation of such powders and battery electrodes and batteries made therefrom.

Abstract: An integrated primary-auxiliary electrode is provided for packaging into a battery container. The electrode includes a carrier substrate formed with a catalytic material. The electrode further includes a primary electrode which is formed on a first side of the carrier substrate with active electro-chemical materials for carrying out a charging-discharging cycle for the battery. The electrode further includes an auxiliary electrode which is formed on a second side of the carrier substrate by exposing the catalytic material of the carrier substrate thus acting to reduce an internal pressure of the battery when packaged into a battery container.

Abstract: An at least ternary metal alloy of the formula, AB.sub.(5-Y)X(.sub.y), is claimed. In this formula, A is selected from the rare earth elements, B is selected from the elements of groups 8, 9, and 10 of the periodic table of the elements, and X includes at least one of the following: antimony, arsenic, and bismuth. Ternary or higher-order substitutions, to the base AB.sub.5 alloys, that form strong kinetic interactions with the predominant metals in the base metal hydride are used to form metal alloys with high structural integrity after multiple cycles of hydrogen sorption.

Abstract: A rechargeable electrochemical battery having a solid organic electrolyte and a thin film cathode and anode. In particular, the battery employs a proton-conducting organic polymer which is a mixture of a strong acid and a base polymer, a thin film anode containing a hydride alloy, and a thin film cathode containing a NiO.sub.x active material. The battery is rechargeable and capable of fast discharging and recharging. Further, the battery can be hermetically sealed in a case.

Abstract: A metal-air battery assembly having plurality of free standing metal-air cells forming a cell group within a battery case assembly. Each free standing cell has flexible, compressible walls capable of containing electrolyte, the walls comprising air cathodes including cathode current distributors. Each cell has a split anode assembly and current. The anode assembly has one or more reactive anode fuel plates and an anode current collector. Each of the cells is free standing and easily replaced. The battery case assembly has a mechanism for compressing the cells when the lid is closed and releasing the cell group for servicing when the lid is open.

Abstract: A gastight, sealed metal oxide/metal hydride storage battery, in particular, a nickel/metal hydride button cell, includes an auxiliary electrode with an active material composed of the same hydrogen storage alloy as that of the negative electrode with which the auxiliary electrode is electrically associated. As a result, the auxiliary electrode can maintain both oxygen consumption as well as hydrogen consumption (in the event of overcharging or polarity reversal of the cell). High gas consumption rates in the event of overcharging and polarity reversal are achieved with a strongly hydrophobic adjustment of the auxiliary electrode and a relatively weakly hydrophobic or hydrophilic adjustment of the negative electrode (by means of hydrophobic or hydrophilic binder additions, respectively), and by adding a highly conductive metal powder (Cu or Ni) to the mass of the negative electrode. Also achieved is a good discharge capacity, even at high currents of up to 2 CA.

Abstract: A hydrogen-absorbing alloy electrode for metal hydride alkaline batteries uses as hydrogen-absorbing material a powder of a rare earth element-nickel hydrogen-absorbing alloy obtained by pulverizing thin strips of said alloy prepared by single roll process and having an average thickness of 0.08 to 0.35 mm and a minimum size of crystal grains present in the roll-surface size of at least 0.2 .mu.m and a maximum size of crystal grains in the open-surface side of not more than 20 .mu.m. A process for producing the above electrode is also provided. The electrode can provide, when used as negative electrode, metal hydride alkaline batteries which are excellent in both high-rate discharge characteristics at an initial period of charge-discharge cycles and charge-discharge cycle characteristics.

Abstract: A monophase hydridable material for the negative electrode of a nickel-metal hydride storage battery with a "Lave's phase" structure of hexagonal C14 type (MgZn.sub.2) has the general formula:Zr.sub.1-x Ti.sub.x Ni.sub.a Mn.sub.b Al.sub.c Co.sub.d V.sub.

Abstract: A hydrogen-absorbing alloy electrode for metal hydride alkaline batteries is obtained by coating or filling a collector with a hydrogen-absorbing alloy powder consisting essentially of spherical particles and/or nearly spherical particles and then sintering the powder, the powder having an average particle diameter of 30 to 70 .mu.m and containing 5 to 30% by volume of particles having a diameter of at least 2 times the average diameter and 10 to 40% by volume of particles having a diameter of not more than 1/2 of the average diameter. This electrode can give metal hydride alkaline batteries having excellent high-rate discharge characteristics and a long life.

Abstract: A disordered multicomponent MgNi based electrochemical hydrogen storage material having a microstructure including a substantial volume fraction characterized by intermediate range order and exhibiting extraordinarily high storage capacity and methods of fabricating same.

Abstract: A module for liquid electrolyte, electric energy storing devices. The module includes a double-walled container having an innerwall and an outerwall and a rim. The container includes a first well for holding liquid electrolyte electric energy storing devices and which is defined by the inner wall. The container also includes a first electrolyte reservoir having a shelf and a lid for covering the first reservoir. The innerwall and outerwall define a second electrolyte reservoir which surrounds the first electrolyte reservoir so that the first and second reservoirs are in nested relationship. The reservoirs are designed so that a physical puncture of the module will cause the electrolyte from the first reservoir to mix with the electrolyte from the second before it leaks from the module.

Abstract: An electrochemical cell has an alkaline electrolyte comprising a stack placed in a container and composed of at least one anode and at least one cathode containing nickel hydroxide. An oxygen recombination system has at least one recombination electrode which is at least partially hydrophobic and has two opposite faces of large surface area. A first face is joined to the anode. The cell is characterized in that the recombination electrode is associated with a rigid structure which forms, in contact with the second face of the electrode, a nonreducible volume space of small width so as to allow oxygen access throughout the duration of use of the cell.

Abstract: A nickel positive electrode for an alkaline storage battery includes an active material mixture and a conductive support. The active material mixture, which is composed mainly of nickel hydroxide, additionally contains nickel powder, a second powder compound and at least one of cobalt, cobalt hydroxide and cobalt oxide. The nickel powder has a specific surface area of from 0.1 to 3 m.sup.2 /g and an average particle diameter of from 0.1 to 15 micrometers, and the second powder compound contains at least one element including Ca, Sr, Ba, Cu, Ag or Y. A sealed nickel-hydrogen storage battery may incorporate the nickel positive electrode.

Abstract: A voltage regulator for a sealed rechargeable storage battery containing one or more rechargeable working cells and at least one regulator cell. The regulator cells are capable of consuming gas in a gas space within the sealed battery during charging of the working cells. The regulator cell is in gaseous communication with the gas space, and having a voltage stabilizer maintaining a preselected voltage range to the regulator cell and maintain a current to the regulator cell depending on the gas to be consumed.

Abstract: A dual air electrode metal-air cell having a casing including an upper cathode mask wall, a lower cathode mask wall, and a plurality of side walls; a metal anode with at least upper and lower sides covered with separator materials; an upper air cathode positioned between the upper cathode mask wall and the separator materials on the upper side of the anode; a lower air cathode positioned between the lower cathode mask wall and the separator materials on the lower side of the anode; a gas vent positioned on one or more of the side walls of the casing; and a liquid electrolyte substantially trapped by the separator materials. The separator materials comprise one ore more layers of an absorbent fibrous web and one or more layers of a microporous membrane that, when wet, is gas-impermeable and liquid-permeable.

Abstract: An enclosed non-aqueous secondary cell is herein disclosed, in which a group of electrodes comprising positive and negative electrodes allowing absorption and release of a light metal and separators are accommodated in a closed-end cell-armoring can together with a non-aqueous electrolyte and an opening of the armoring can is closed by an insulating gasket positioned around the inner periphery of the opening of the can and a closing lid fitted in and supported by the gasket and simultaneously serving as a positive or negative terminal, wherein the closing lid comprises an explosion-proof valve capable of deforming towards the direction opposite to the group of electrodes in response to an increase in the internal pressure of the cell, a terminal cap provided with vent holes and arranged at the side of the explosion-proof valve opposed to the group of electrodes and a non-reverse type switch which is positioned between the explosion-proof valve and the terminal cap and serves to shut-off the electrical connect

Abstract: A rechargeable metal-air electrochemical cell comprising a hydrogen-oxygen recombination electrode recombines hydrogen produced at the anode with oxygen to replenish the supply of water in the cell. The cell comprises an oxygen gas-permeable, liquid water-impermeable air cathode disposed in the cell case such that the cell is substantially impermeable to liquid water and the cell can receive and discharge oxygen gas through an opening in the cell case. During the discharge mode of the cell, the recombination electrode is inactive, and during the recharge mode, the recombination electrode catalyzes the electrochemical recombination of hydrogen and oxygen in the cell to form water. According to another aspect, the cell can comprise a device for indicating the end of the charge mode by sensing the level of current between the cathode and the recombination electrode and comparing that current level to a predetermined current level.

Abstract: Metals useful in the formation of hydrides for applications such as batteries are advantageously activated by hydriding/dehydriding process. This process involves repeatedly stepping the potential of metal/metal hydride electrodes in electrochemical cells. The process activates hydrogen-storing materials that are difficult to activate by conventional means.

Abstract: This invention disclosures a method to make an improved hydrogen/hydride electrode for electro-chemical applications. The method comprises the steps of: (1) preparing the slurry of hydrogen storage material; (2) pasting the slurry onto and/or into a substrate current collector to make a wet pasted electrode; (3) drying the wet pasted electrode; and (4) sintering the pasted electrode. The aforementioned method is very useful for the hydrogen storage alloy comprising of Ti, 2-70 at. %; Zr, 2-70 at. % and Ni, 5-80 at. %. It is also useful for a pseudo AB.sub.5 - or AB.sub.2 -type alloy. In particular, a high capacity hydrogen storage electrode comprising a multicomponent hydrogen storage alloy having composition represented by the formula: Ti.sub.a Zr.sub.b Ni.sub.c Nb.sub.y R.sub.z M.sub.

Abstract: A zinc negative electrode comprising a zinc active material, Ba(OH).sub.2 or Sr(OH).sub.2 and a conductive matrix including a metallic oxide which is more electropositive than zinc. The zinc negative electrode is incorporated into a zinc secondary battery having an electrolyte whose electrolyte constituent is a low percentage of the electrolyte. The zinc negative electrode is split into electrode assemblies separated by a porous hydrophobic element.

Abstract: Non-uniform heterogeneous powder particles for electrochemical uses, and said powder particles comprising at least two separate and distinct hydrogen storage alloys selected from the group consisting of: Ovonic LaNi.sub.5 type alloys, Ovonic TiNi type alloys, and Ovonic MgNi based alloys.

Abstract: The present invention discloses four main groups of hydrogen storage/hydride electrode materials for electrochemical applications as the active material of the negative electrode of a hydride battery. The compositions of these four groups are represented by the formulas: (1) Ti.sub.a Nb.sub.b Ni.sub.c R.sub.x D.sub.y Q.sub.p, (2) Ti.sub.a Hf.sub.b Ni.sub.c R.sub.x D.sub.y Q.sub.p, (3) Ti.sub.a Ta.sub.b Ni.sub.c R.sub.x D.sub.y Q.sub.p, (4) Ti.sub.a V.sub.b Ni.sub.c R.sub.x D.sub.y Q.sub.

Abstract: A solid state battery comprising a substrate; at least one multilayered electrochemical cell deposited onto the substrate, each layer of the multilayered electrochemical cell composing: a layer of negative electrode material capable of electrochemically adsorbing and desorbing ions during charge and discharge; a layer of positive electrode material capable of electrochemically desorbing and adsorbing ions during charge and discharge; and a layer of insulating/conducting material disposed between the layer of positive electrode material and the layer of negative electrode material, where the layer of insulating/conducting material is electrically insulating and capable of readily conducting or transposing ions from the layer positive electrode material to the layer of negative electrode material while the battery is charging and from the layer of negative electrode material to the layer of positive electrode material while the battery is discharging; and an electrically conductive layer deposited a top the las

Abstract: An alkaline storage battery made using a hydrogen-storing alloy for the negative electrode has suffered from the problems that the negative electrode is oxidized with oxygen gas generated from the positive electrode during overdischarge to cause increase of internal resistance and deterioration of charging and discharging cycle characteristics. Disclosed is a solution to the above problems which incorporates into the hydrogen-storing alloy negative electrode one of yttrium and yttrium compounds or a mixture thereof in such a state that it covers the surface of the hydrogen-storing alloy powder.

Abstract: A method for manufacturing a hydrogen absorbing alloy including, comprising the steps of (a) causing a punched metal sheet to run in a slurry of hydrogen absorbing alloy powder, to thereby cause the slurry to be adhered onto the punched metal sheet, the punched metal sheet having a plurality of apertures arranged in a staggered fashion; (b) drying the punched metal sheet on which the slurry has been adhered, to thereby obtain an electrode sheet; (c) cutting the electrode sheet into electrode sheet fragments, each electrode sheet fragment having a first axis and a second axis perpendicular to the first axis, and each electrode sheet fragment having aperture-formed portions and aperture-non-formed portions therein; (d) rolling an electrode sheet fragment in a rolling direction parallel to the first axis of the electrode sheet fragment, the electrode sheet fragment having an aperture array arrangement such that any given line running along the electrode sheet fragment parallel to the second axis of the electrode

Abstract: An improved metal hydride hydrogen storage alloy electrochemical cell (10) includes a positive electrode (20) and a negative electrode (30) having disposed therebetween, a polymer electrolyte (40). The polymer electrolyte (40) comprises a polymer support structure fabricated of, for example, polyvinyl alcohol or polyvinyl acetate, and having dispersed therein an electrolyte active species such as, for example, KOH. The improved electrolyte for a metal hydride hydrogen storage alloy cell provides a battery cell free from electrolyte leakage, and having ionic conductivities which allow for an efficient use of the metal hydride electrodes.

Abstract: A method to make new improved high capacity rechargeable hydride batteries comprising steps of (1) preparing an improved hydrogen storage material represented by the composition formula: A.sub.a B.sub.b Ni.sub.c D.sub.y M.sub.x R.sub.z, where A is one or more element chosen from the group of Ti, Zr, Mg; B is one or more elements chosen from the group of Al, V, Mn, Nb, Si, Pd, and Ag; D is one or more elements chosen from the group of Cr, Mn, Fe, Co, Cu, Zn, Mo, W and Sn; R is one or more elements chosen from the group of C, B, Ca, Sb, Bi, Y, Hf, Ta, N, O, Ge, Ga and Mm, where Mm is mischmetal; M is one or more elements chosen from the group of Li, Na, K, Rb, Cs, P and S; and where a, b, c, y, x and z are defined by: 0.10.ltoreq.a.ltoreq.0.85, 0.01.ltoreq.b.ltoreq.0.65, 0.02.ltoreq.c.ltoreq.0.75, 0.ltoreq.y.ltoreq.0.30, 0.ltoreq.x.ltoreq.0.30, 0.ltoreq.z.ltoreq.0.30 and a+b+c+y+x+z=1.00; (2) preparing a high capacity (1.15-2.

Abstract: The present invention provides a hydrogen storing alloy electrode having a large discharging capacity and a long lifetime at a high temperature. The electrode is also excellent in discharging characteristics in the early charging and discharging cycles. In one aspect of the present invention, the hydrogen storing alloy electrode is made of a hydrogen storing alloy represented by the general formula ZrMn.sub.m V.sub.x X.sub.y Ni.sub.z or a hydride thereof, wherein X is Al, Zn or W; m, x, y, and z are respectively mole ratio of Mn, V, X, and Ni to Zr: 0.4.ltoreq.m.ltoreq.0.8, 0.1.ltoreq.x.ltoreq.0.3, 1.0.ltoreq.z.ltoreq.1.5, and 2.0.ltoreq.m+x+y+z.ltoreq.2.4; when X is Al or Zn, 0<y.ltoreq.0.2; and when X is W, 0<y.ltoreq.0.1. The alloy has mainly C15-type Laves phases with a crystal structure of MgCu.sub.2 type face center cubix. The alloy has a crystal lattice constant .alpha. 7.03 angstroms or more and 7.10 angstroms or less.

Abstract: A rectangular nickel-metal hydride secondary cell permits improving the air-tightness and also permits preventing a metal case from being deformed in a step of folding an open end portion of the metal case. The rectangular nickel-metal hydride secondary cell, includes a rectangular cylindrical metal case having a bottom, an electrode group housed in the metal case, an alkali electrolyte contained in the metal case, a rectangular sealing plate mounted near the open end portion of the metal case. An insulating gasket is interposed in a compressed state between the inner wall near the open end of the metal case and the sealing plate. The metal case comprises a folded portion formed by inwardly folding the open end portion of the metal case and an inwardly projecting stepped portion formed along the inner surface of the metal case below the folded portion.

Abstract: A disordered electrochemical hydrogen storage alloy comprising:(Base Alloy).sub.a Co.sub.b Mn.sub.c Fe.sub.d Sn.sub.ewhere the Base Alloy comprises 0.1 to 60 atomic percent Ti, 0.1 to 40 atomic percent Zr, 0 to 60 atomic percent V, 0.1 to 57 atomic percent Ni, and 0 to 56 atomic percent Cr; b is 0 to 7.5 atomic percent; c is 13 to 17 atomic percent; d is 0 to 3.5 atomic percent; e is 0 to 1.5 atomic percent; and a+b+c+d+e=100 atomic percent.

Abstract: At least one of a positive electrode and a negative electrode constituting an electrode assembly comprises at least two divided electrode portions not connected through electron conduction. The divided electrode portions each have an electrode lead extending outward from a battery container, which has at least two external terminals of the same polarity which is provided by the lead. The external terminals of the same polarity are connected to each other via a resistor having a PTC effect. The battery is assured of improved safety even when large-sized.