Carboxylic Acid Or Ester Compound Adjuvant Patents (Class 430/108.4)
  • Publication number: 20140377698
    Abstract: This disclosure relates to a polymerized toner prepared by suspension polymerization. Particularly, this disclosure relates to a polymerized toner that further comprises a specific functional macro monomer, a polymer thereof, or a mixture thereof, in addition to a binder resin, and a pigment, a pigment stabilizer, a charge control agent and wax, which are dispersed in the binder resin, and thus can be fixed at low temperature in a development process, and exhibit high glossiness and excellent transfer efficiency.
    Type: Application
    Filed: December 4, 2012
    Publication date: December 25, 2014
    Applicant: LG CHEM, LTD.
    Inventors: Wook Jang, Chang-Soon Lee, Woo-Cheul Jung, Jung Woo Kim
  • Patent number: 8916323
    Abstract: The toner can obtain low-temperature fixing property, heat-resistant storability and long-term stability of charging while having excellent low-temperature fixing property. The toner is formed with toner particles containing a binder resin and a crystalline ester compound, the crystalline ester compound has a linear-chain structure, and the binder resin contains a styrene-acrylic resin including a structural unit derived from an acrylic ester monomer represented by general formula (1) below. In the general formula (1), R1 represents a hydrogen atom or a methyl group, and R2 represents a hydrogen atom, an alkyl group having 1 to 16 carbon atoms or an aryl group having 6 to 15 carbon atoms. m represents 2 or 3, and n represents an integer of 1 to 25.
    Type: Grant
    Filed: April 22, 2013
    Date of Patent: December 23, 2014
    Assignee: Konica Minolta, Inc.
    Inventors: Kouji Sugama, Hiroshi Nagasawa, Hiroyuki Konno, Takako Kawamura
  • Patent number: 8916320
    Abstract: A process for making a latex emulsion including contacting at least one amorphous polyester resin with at least two organic solvents to form a resin mixture, adding a neutralizing agent, and deionized water to the resin mixture, removing the solvent from the formed latex, and separating the solvent from water. Further, the process is carried out above the resin Tg for making the latex, which drives the latex particle size under 100 nm, where toners made from the latex show improved charging performance.
    Type: Grant
    Filed: January 15, 2013
    Date of Patent: December 23, 2014
    Assignee: Xerox Corporation
    Inventors: Shigang Qiu, Richard P N Veregin, Kimberly D Nosella, Santiago Faucher, Cuong Vong, Enno E Agur
  • Publication number: 20140370433
    Abstract: This disclosure relates to a polymerized toner prepared by suspension polymerization. Particularly, this disclosure relates to a polymerized toner that comprises a binder resin, and a pigment, a charge control agent, and wax, which are dispersed in the binder resin, and maintains peak molecular weight (Mn) of the binder resin, the ratio of number average molecular weight/peak molecular weight (Mn/Mp), and gel content (Gel %), and thereby, can realize high glossiness and excellent off set property when printing, and a method for preparing the same.
    Type: Application
    Filed: December 5, 2012
    Publication date: December 18, 2014
    Applicant: LG CHEM, LTD.
    Inventors: Wook Jang, Chang-Soon Lee, Joo-Yong Park, Woo-Cheul Jung
  • Publication number: 20140370430
    Abstract: A toner particle includes a core containing a styrene-based resin; a low melting point wax; optionally an additive package; and optionally a colorant, wherein the low melting point wax has a melting point of less than about 80° C. A method of making a toner particle includes forming a slimy by mixing together an emulsion containing a resin, a low melting point wax, optionally a colorant, optionally a surfactant, optionally a coagulant, and one or more additional optional additives; and heating the slurry to form aggregated particles in the slurry, wherein the aggregated particles form a core of the toner particles; and the low melting point wax has a melting point of less than about 80° C.
    Type: Application
    Filed: June 13, 2013
    Publication date: December 18, 2014
    Inventors: Grazyna E. KMIECIK-LAWRYNOWICZ, Samir KUMAR, Robert D. BAYLEY, Maura A. SWEENEY
  • Publication number: 20140370426
    Abstract: A non-magnetic single-component toner includes a toner base particle that contains at least a binder resin and a colorant, and an external additive, wherein the external additive includes an organic particle and an inorganic particle, the binder resin contains at least an amorphous polyester resin and a crystalline polyester resin, an endothermic peak of the crystalline polyester resin obtained by differential scanning calorimetry is from 50° C. to 100° C., the organic particle contains at least one kind selected from a group consisting of higher fatty acid, higher alcohol, fatty acid ester, and fatty acid amide, and the inorganic particle is treated with silicone oil.
    Type: Application
    Filed: October 23, 2013
    Publication date: December 18, 2014
    Applicant: FUJI XEROX CO., LTD.
    Inventors: Daisuke ISHIZUKA, Shinichi YAOI, Tomoaki TANAKA, Seijiro ISHIMARU, Kotaro YOSHIHARA, Yasushige NAKAMURA
  • Publication number: 20140356776
    Abstract: A toner particle includes a core including at least one resin, optionally a wax, and a colorant, and a shell comprising at least one charge control agent. The core is substantially free of the charge control agent. The toner particle has improved charging performance compared with core-shell toner particles having the charge control agent in the core of the toner particle.
    Type: Application
    Filed: May 31, 2013
    Publication date: December 4, 2014
    Inventors: ROBERT D. BAYLEY, MAURA A. SWEENEY, GRAZYNA E. KMIECIK-LAWRYNOWICZ, SHIGANG STEVEN QIU, TIE HWEE NG
  • Patent number: 8900784
    Abstract: To provide a toner which contains a binder resin, a colorant, and capsules, wherein the binder resin contains a thermoplastic elastomer, and wherein the capsules each encapsulate a plasticizer capable of softening the thermoplastic elastomer and the capsules are fractured upon application of predetermined pressure.
    Type: Grant
    Filed: May 14, 2012
    Date of Patent: December 2, 2014
    Assignee: Ricoh Company, Ltd.
    Inventors: Yasuo Katano, Yukimichi Someya, Shinji Tezuka, Fuminari Kaneko, Kohji Takeuchi, Kohji Matsuoka, Takuma Nakamura, Tsuneo Kurotori, Hidekazu Yaginuma
  • Publication number: 20140349228
    Abstract: A toner for electrostatic latent image development of the present invention includes toner particles containing toner mother particles and an external additive. The external additive contains fatty acid metal salt particles, and a volume based particle diameter (size) distribution of the fatty acid metal salt particles has two peaks on a side of smaller size and a side of larger size, respectively. A volume based mean particle diameter of the fatty acid metal salt particles having the peak on the side of smaller size is 3.0 ?m or smaller and a volume based mean particle diameter of the fatty acid metal salt particles having the peak on the side of larger size is larger than a volume based mean particle diameter of the toner mother particles.
    Type: Application
    Filed: May 22, 2014
    Publication date: November 27, 2014
    Applicant: Konica Minolta, Inc.
    Inventors: Futoshi KADONOME, Yukio HOSOYA, Kazue NAKAMURA, Saburou HIRAOKA, Yasuko UCHINO
  • Patent number: 8895216
    Abstract: An image forming apparatus includes an electrophotographic photoreceptor having a photosensitive layer, and a surface protective layer that contains fluororesin particles and a fluorinated alkyl group-containing copolymer; a charging unit that charges the surface of the electrophotographic photoreceptor; an electrostatic latent image forming unit that forms an electrostatic latent image; a developing unit that accommodates a developer, and develops the electrostatic latent image with the developer to form a toner image; a transfer unit that transfers the toner image to a recording medium; and a cleaning unit that removes the remained developer, wherein when the electrophotographic photoreceptor is rotated 50,000 times by repeating the formation of an image having image sections and non-image sections and having an image density of 7%, and then the surface of the electrophotographic photoreceptor is analyzed by X-ray photoelectron spectroscopy, the zinc coating ratio is in the range of from 50% to 100%.
    Type: Grant
    Filed: May 1, 2012
    Date of Patent: November 25, 2014
    Assignee: Fuji Xerox Co., Ltd.
    Inventor: Daisuke Haruyama
  • Publication number: 20140342280
    Abstract: A polymer colorant including polymer monomer units, and at least one alizarin unit which is incorporated into the polymer and which provides color to the polymer colorant and a process for preparing the polymer colorant. An article or composition containing the polymer colorant. A toner including the polymer colorant, and optionally, one or more ingredients selected from the group consisting of crystalline polyester resins, amorphous polyester resins, colorants, waxes, coagulants, mordants, and mixtures and combinations thereof. A polymer latex including an aqueous dispersion of polymer colorant, wherein the polymer colorant comprises polymer monomer units and at least one alizarin unit which is incorporated into the polymer and which provides color to the polymer colorant; and optionally, a mordant.
    Type: Application
    Filed: May 20, 2013
    Publication date: November 20, 2014
    Applicant: Xerox Corporation
    Inventors: Valerie M. Farrugia, Mihaela Maria Birau, Gabriel Iftime, Biby Esther Abraham
  • Patent number: 8889327
    Abstract: A toner for developing electrostatic images contains a binder resin, a colorant, a release agent, and a charge control agent. The release agent contains a wax having a polar group. The toner for developing electrostatic images has tan ? of 1 to 2 at a temperature of 80° C. to 145° C. as measured with a viscoelasticity measuring apparatus at a frequency of 10 Hz and a shear stress of 500 Pa, and has a breaking point of 180° C. or less in a temperature-tan ? curve.
    Type: Grant
    Filed: October 15, 2012
    Date of Patent: November 18, 2014
    Assignee: Kyocera Document Solutions Inc.
    Inventor: Toshiki Takemori
  • Patent number: 8883946
    Abstract: Here is provided a charge control resin which is prompt in charge rising up, excellent in electrostatic charging propensity and easy in manufacturing. This charge control resin contains a polymer as an active ingredient having a constituent unit represented by following Formula (1) in the Formula (1), R1 is independent of one another, and is a hydrogen atom, a hydroxyl group, a halogen atom, a carboxy-containing group, a straight-chained or branched alkyl group having 1-18 carbon atoms, or a straight-chained or branched alkoxy group having 1-18 carbon atoms; R2 is a hydrogen atom, a hydroxyl group, a halogen atom, a carboxy-containing group, a straight-chained or branched alkyl group having 1-18 carbon atoms, or a straight-chained or branched alkoxy group having 1-18 carbon atoms; g is a number of 1-3; h is a number of 1-3; and M is a hydrogen atom, an alkali metal, a straight-chained or branched alkyl group having 1-18 carbon atoms, an ammonium radical or a mixture of any of these.
    Type: Grant
    Filed: May 17, 2012
    Date of Patent: November 11, 2014
    Assignee: Orient Chemical Industries Co., Ltd.
    Inventors: Masashi Yasumatsu, Kaori Inoue, Satoko Ozaki
  • Patent number: 8883385
    Abstract: A toner includes a binder resin, a coloring agent, and a releasing agent containing two or more kinds of alkyl monoester compounds having a different number of carbon atoms in a range of from 30 to 50 carbon atoms. The toner has a crystallinity of 10% or more as measured by x-ray diffraction and/or the binder resin is a crystalline resin in an amount of 50% by weight or more of the binder resin. The two or more kinds of alkyl monoester compounds include a component A accounting for the largest amount ranging from 30% by weight to less than 50% by weight of the releasing agent and a component B accounting for the second largest amount ranging from 10% by weight to less than 50% by weight of the releasing agent.
    Type: Grant
    Filed: December 5, 2012
    Date of Patent: November 11, 2014
    Assignee: Ricoh Company, Ltd.
    Inventors: Shingo Sakashita, Hiroshi Yamashita, Masahide Yamada, Shinya Nakayama, Atsushi Yamamoto, Yukiko Nakajima
  • Patent number: 8877415
    Abstract: A toner including a resin particle (C) is provided. The resin particle (C) includes a resin particle (B) and; a resin particle (A) or covering layer (P) that is adhered to a surface of the resin particle (B). The resin particle (B) includes a resin (b) having a polyhydroxycarboxylic acid skeleton. The resin particle (A) or covering layer (P) includes a resin (a). The resin (a) is a polyester resin having a polybasic acid unit and a polyol unit and has a weight average molecular weight within a range from 9,500 to 100,000.
    Type: Grant
    Filed: February 6, 2013
    Date of Patent: November 4, 2014
    Assignee: Ricoh Company, Ltd.
    Inventors: Daiki Yamashita, Shinya Nakayama, Atsushi Yamamoto, Yukiko Nakajima, Akiyoshi Sabu, Yoshihiro Moriya, Hideyuki Santo
  • Patent number: 8871417
    Abstract: To provide a toner comprising: a binder resin, a colorant, and a releasing agent, wherein the toner has a core shell structure, and wherein the core contains at least one resin selected from the group consisting of a hybrid resin and a polyester resin, where the hybrid resin is a resin in which a polyester resin and a vinyl resin are chemically bonded to each other, and the shell contains a resin prepared by polymerizing at least a styrene monomer and an ester monomer represented by the following General Formula (1): where, ‘n’ is 2 or 3, ‘X’ is any of 0 to 9, R1 is a hydrogen atom, or an alkyl group, and R2 is a hydrogen atom, an alkyl group, or a phenyl group.
    Type: Grant
    Filed: August 27, 2010
    Date of Patent: October 28, 2014
    Assignee: Ricoh Company, Ltd.
    Inventors: Tomoharu Miki, Takuya Kadota, Yoshihiro Mikuriya, Tsuyoshi Nozaki, Atsushi Yamamoto, Yoshimichi Ishikawa, Tomohiro Fukao
  • Patent number: 8871415
    Abstract: There is provided a toner for electrostatic-image development that can obtain heat-resistant storability, fixed image strength and long-term stability of charging while having excellent low-temperature fixing property. The toner is formed, with toner particles containing a binder resin and a crystalline ester compound, and the binder resin contains a styrene-acrylic resin including a structural unit derived from an acrylic ester monomer.
    Type: Grant
    Filed: April 17, 2013
    Date of Patent: October 28, 2014
    Assignee: Konica Minolta, Inc.
    Inventors: Hiroshi Nagasawa, Kouji Sugama, Hiroyuki Konno, Takaki Kawamura
  • Patent number: 8852838
    Abstract: An electrostatic charge image developing toner includes toner particles that contain a binder resin having a carboxyl group, in which the carboxyl group in the binder resin present on the surfaces of the toner particles forms an alkaline earth metal salt, and an amount of the alkaline earth metal which is detected through ion chromatography of the toner particles is in a range of from 1.00×10?10 mol/g to 0.90×10?6 mol/g.
    Type: Grant
    Filed: August 2, 2012
    Date of Patent: October 7, 2014
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Satoshi Kamiwaki, Akira Matsumoto, Yukiaki Nakamura, Masanobu Ninomiya, Yusuke Ikeda
  • Patent number: 8852836
    Abstract: A toner including: a base resin; and charge-controlling resin particles contained in the base resin, wherein the toner is in shape of particles, and the charge-controlling resin particles are present in a region of each toner particle which is 500 nm in depth from a surface of the toner particle and an average of amounts of the charge-controlling resin particles present in the regions of the toner particles is 20% by volume to 70% by volume, wherein an average of embedment rates of the charge-controlling resin particles in the toner particles is 90% or higher, where each embedment rate is an average of embedment rates of the charge-controlling resin particles in each toner particle, and wherein the charge-controlling resin particles have a charge amount of 60 ?C/m2 or more as measured by a blow-off method.
    Type: Grant
    Filed: June 18, 2012
    Date of Patent: October 7, 2014
    Assignee: Ricoh Company, Ltd.
    Inventors: Masahiro Seki, Yoshitaka Sekiguchi, Ryota Inoue, Kazuoki Fuwa
  • Publication number: 20140295341
    Abstract: Metal-oxide composite particles are used as a toner additive.
    Type: Application
    Filed: October 25, 2012
    Publication date: October 2, 2014
    Inventors: Dmitry Fomitchev, Eugene N. Step
  • Publication number: 20140295339
    Abstract: An electrostatic charge image developing toner includes a toner particle including a core particle containing a polyester resin and a coating layer containing a vinyl resin that coats the surface of the core particle, and an external additive that is formed of silica particles having an average circularity of from 0.75 to 0.9 and an average value of ratios of circle equivalent diameters Da obtained by a plane image analysis to the maximum height H obtained by a stereoscopic image analysis of more than 1.5 and less than 1.9.
    Type: Application
    Filed: September 13, 2013
    Publication date: October 2, 2014
    Applicant: FUJI XEROX CO., LTD.
    Inventors: Yasuo KADOKURA, Emi MATSUSHITA, Hiroyoshi OKUNO
  • Publication number: 20140287353
    Abstract: An electrostatic charge image developing toner includes an amorphous polyester resin and a crystalline polyester resin as a binder resin, and by differential scanning calorimetry, which undergoes processes of a first temperature rise, cooling at a rate of ?10° C./min and a second temperature rise, an endothermic peak (1) derived from a resin in which at least the amorphous polyester resin and the crystalline polyester resin are compatible is present in the first temperature rise, an exothermic peak having an intensity of 0.1 J/g or more is not present during the first temperature rise, and at least one exothermic peak (2) is present in a temperature range which is lower than that of the endothermic peak (1) by from 5° C. to 15° C. during the second temperature rise.
    Type: Application
    Filed: September 13, 2013
    Publication date: September 25, 2014
    Applicant: FUJI XEROX CO., LTD.
    Inventors: Shinya SAKAMOTO, Satoshi YOSHIDA, Shinya NAKASHIMA, Tetsuya TAGUCHI
  • Patent number: 8841055
    Abstract: An emulsion aggregation toner composition is disclosed that includes toner particles with at least one small crystalline molecule, such as a trans-cinnamic diester, at least one amorphous resin, optional waxes, coagulants, pigments, and combinations thereof. In other embodiments, the small crystalline molecule is biodegradable and can be made using raw materials derived from renewable resources. Such small crystalline molecules are also compatible with amorphous binder resins, to provide toner compositions with reduced minimum fusing temperatures without sacrificing electrical performance. Processes for preparing emulsion aggregation toner compositions are also described.
    Type: Grant
    Filed: April 4, 2012
    Date of Patent: September 23, 2014
    Assignee: Xerox Corporation
    Inventors: Ke Zhou, Adela Goredema, Karen Moffat, Edward G. Zwartz, Mike Hawkins, Rosa Duque, Guerino G. Sacripante
  • Publication number: 20140272339
    Abstract: A fluorescing yellow polymeric toner particle comprises one or more non-fluorescing yellow colorants, and one or more fluorescing yellow colorants having one or more emission peak wavelengths of at least 480 nm and up to and including 600 nm. These fluorescing yellow polymeric toner particles can be used to provide multicolor toner images with increased yellow color gamut.
    Type: Application
    Filed: March 15, 2013
    Publication date: September 18, 2014
    Inventors: Dinesh Tyagi, Chung-Hui Kuo, Louise Granica
  • Publication number: 20140272696
    Abstract: Toner contains a mother toner particle that contains a crystalline resin; and wax; and a coloring agent, wherein the area of endothermic peak derived from the crystalline resin during a first temperature rising as measured by differential scanning calorimetry is at least 20 J/g, wherein the ratio of the area of endothermic peak derived from the wax during a second time temperature rising as measured by differential scanning calorimetry (DSC) to the area of endothermic peak derived from the wax during a first time temperature rising as measured by differential scanning calorimetry is at least 0.50, wherein the ratio of the area of endothermic peak derived from the wax during a first time temperature rising as measured by differential scanning calorimetry to the area of endothermic peak derived from the crystalline resin during a first temperature rising as measured by differential scanning calorimetry is at least 0.10.
    Type: Application
    Filed: February 4, 2014
    Publication date: September 18, 2014
    Inventors: Hiroshi YAMASHITA, Toyoshi Sawada, Hideyuki Santo
  • Publication number: 20140255841
    Abstract: A toner having charge control agents which impart excellent triboelectric charging characteristics. In embodiments, the toner particles are made by a process in which charge control agent is added and adhered to the particle surface through washing steps and is maintained through the drying steps. The process of the present embodiments impart desirable charging characteristics to the toner particles.
    Type: Application
    Filed: May 22, 2014
    Publication date: September 11, 2014
    Applicant: XEROX CORPORATION
    Inventors: Robert D. Bayley, Maura A. Sweeney, Grazyna E. Kmiecik-Lawrynowicz, Daniel W. Asarese
  • Patent number: 8828633
    Abstract: To obtain a toner which has excellent charge rise and stability, tends to have a sharp charge distribution, has excellent pigment dispersion properties, exhibits no disarray in an image even during a high-speed copying operation, and can stably output high-resolution images. A toner comprising toner particle containing a binder resin, a colorant, resin PA, and resin PB, wherein the resin PA has unit A represented by Formula (1), the resin PB has unit B represented by Formula (2), a content “a” of the unit A in the toner particle is 2.00 ?mol/g or more, and a molar ratio b/a of the content “a” and a content “b” of the unit B in the toner particle is 0.10 or more and 10.00 or less.
    Type: Grant
    Filed: December 20, 2010
    Date of Patent: September 9, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hitoshi Itabashi, Takashi Kenmoku, Harumi Takada
  • Patent number: 8822121
    Abstract: A toner to develop an electrostatic charge image, a toner supply device employing the toner, an apparatus to form an image employing the toner, and a method of forming an image using the toner are provided. The toner includes at least a binder resin, a colorant, and a releasing agent. By using the binder resin including a combination of a reduced molar weight binder resin, an increased molar weight binder resin, and the releasing agent having an effecdtive compatibility with the binder resin together, the toner has accurately-controlled dynamic viscoelastic properties represented by a loss tangent. The toner to develop an electrostatic charge image according to an embodiment has development stability, development lifetime, fixability, charging stability, gloss, an anti-offset property, and heat storage ability at predetermined levels or higher.
    Type: Grant
    Filed: February 27, 2013
    Date of Patent: September 2, 2014
    Assignee: SAMSUNG Electronics Co., Ltd.
    Inventors: Kyeong Pang, Tae-hoe Koo, Su-bum Park, Yo-da Shin, Seung-jun Lee, Hae-ree Joo, Jun-young Lee
  • Patent number: 8822118
    Abstract: Toner containing a binder resin that contains at least one kind of resin having a crystalline polyester unit as its main component and a releasing agent containing a straight-chain mono ester having 48 or more carbon atoms accounting for 40% by weight or more of the releasing agent.
    Type: Grant
    Filed: March 4, 2013
    Date of Patent: September 2, 2014
    Assignee: Ricoh Company, Ltd.
    Inventors: Atsushi Yamamoto, Shinya Nakayama, Hideyuki Santo, Suzuka Amemori, Shingo Sakashita, Masahide Yamada
  • Patent number: 8808955
    Abstract: A toner includes a coloring agent, a binder resin comprising a crystalline resin having a urethane skeleton and/or urea skeleton, and a releasing agent (a microcrystalline wax). A development agent, a process cartridge, and an image forming apparatus employ the toner to form images on recording media electrophotographically.
    Type: Grant
    Filed: September 10, 2012
    Date of Patent: August 19, 2014
    Assignee: Ricoh Company, Ltd.
    Inventors: Shinya Nakayama, Atsushi Yamamoto, Hideyuki Santo, Daiki Yamashita, Suzuka Amemori, Masahide Yamada
  • Patent number: 8795939
    Abstract: A toner, including a lactone compound having not less than 14-membered rings; and a resin including a crystalline polyester unit.
    Type: Grant
    Filed: October 1, 2012
    Date of Patent: August 5, 2014
    Assignee: Ricoh Company, Ltd.
    Inventors: Atsushi Yamamoto, Shinya Nakayama, Masahide Yamada, Hideyuki Santo, Suzuka Amemori
  • Publication number: 20140205944
    Abstract: Disclosed is a toner for developing electrostatic images comprising a colored resin particle containing a binder resin, a colorant and a softening agent, and an external additive, wherein the colored resin particle contains a diester compound represented by the following general formula (1) as the softening agent, and a content of the diester compound is in the range from 1 to 15 parts by mass with respect to 100 parts by mass of the colored resin particle, and the toner has a softening temperature “Ts” of 55 to 70° C., a flow starting temperature “Tfb” of 80 to 100° C. and a glass transition temperature of 40 to 70° C. in a flow tester: wherein, R1 is an ethylene group or a trimethylene group; and each of R2 and R3 is independently a linear alkyl group having 11 to 25 carbons.
    Type: Application
    Filed: September 19, 2012
    Publication date: July 24, 2014
    Applicant: ZEON CORPORATION
    Inventor: Azusa Masuda
  • Publication number: 20140199623
    Abstract: The disclosure describes a process to produce toner with tunable gloss levels comprising a stabilizer to freeze particle growth following aggregation, where the stabilizer does not chelate metal ions.
    Type: Application
    Filed: January 15, 2013
    Publication date: July 17, 2014
    Applicant: XEROX CORPORATION
    Inventors: Yulin Wang, Ke Zhou, Tie Hwee Ng, Edward Graham Zwartz, Cuong Vong, Shigang Qiu
  • Patent number: 8778584
    Abstract: The present disclosure provides toners and methods for their production. In embodiments, the amount of coagulant utilized in producing those toners may be less than amounts currently in use, which may have a beneficial effect by reducing the time for coalescence. Modified waxes may also be utilized which provide excellent gloss and charging characteristics.
    Type: Grant
    Filed: October 15, 2009
    Date of Patent: July 15, 2014
    Assignee: Xerox Corporation
    Inventors: Mark E. Mang, Grazyna Kmiecik-Lawrynowicz, Maura A. Sweeney, Timothy L. Lincoln
  • Patent number: 8778585
    Abstract: A toner with good low-temperature fixability even in light-pressure type fixing units, which causes no contamination of fixing films and provides images having stable image densities and excellent image quality after long-term use. The toner includes a toner particle containing a binder resin, a coloring agent, a release agents (a) and (b) The release agent (a) is a monofunctional or bifunctional ester wax; the release agent (b) is a hydrocarbon wax; a solubility of the release agent (a) into the binder resin is higher than that of the release agent (b). When tetrahydrofuran-soluble components of the toner are subjected to GPC, a proportion of components having a molecular weight of 500 or less is 2.5 area % or less. When the tetrahydrofuran-soluble components at 25° C. are subjected to SEC-MALLS, a weight-average molecular weight Mw thereof is 5,000-100,000, and the Mw and the radius of gyration Rw thereof satisfy 5.0×10?4?Rw/Mw?1.0×10?2.
    Type: Grant
    Filed: September 12, 2011
    Date of Patent: July 15, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takashi Matsui, Michihisa Magome, Tomohisa Sano, Shuichi Hiroko, Yoshitaka Suzumura, Shotaro Nomura
  • Patent number: 8758968
    Abstract: To provide a toner, containing: a binder resin; a crystalline polyester resin; a colorant; and wax, wherein the toner has a fluidized powder characteristic value of 35% to 45%, and a BET specific surface area of 2.8 m2/g to 4 m2/g, and wherein the toner has an intensity ratio P2850/P828 of 0.10 to 0.20, where P2850 is an intensity of a peak at 2850 cm?1 which is attributed from the wax and the crystalline polyester resin, and P828 is an intensity of a peak at 828 cm?1 which is attributed from the binder resin, as measured by total reflectance infrared spectroscopy.
    Type: Grant
    Filed: November 2, 2011
    Date of Patent: June 24, 2014
    Assignee: Ricoh Company, Ltd.
    Inventors: Naohiro Watanabe, Tsuyoshi Sugimoto, Shinya Hanatani, Mamoru Hozumi, Osamu Uchinokura
  • Patent number: 8758972
    Abstract: A toner produced by a method including dissolving or dispersing toner components comprising a resin, a colorant, and a release agent in a solvent to prepare a toner components liquid, discharging the toner components liquid from multiple nozzles provided on a thin film by vibrating the thin film by a mechanical vibration unit to form liquid droplets, and drying the liquid droplets into solid particles of the toner. The particle diameter distribution that is a ratio of a weight average particle diameter to a number average particle diameter of the toner is between 1.00 and 1.15, and a weight average particle diameter of the release agent in the toner is between 1% and 30% of an aperture diameter of the nozzle.
    Type: Grant
    Filed: July 6, 2009
    Date of Patent: June 24, 2014
    Assignee: Ricoh Company, Limited
    Inventors: Takahiro Honda, Yohichiroh Watanabe, Yoshihiro Norikane, Shinji Ohtani
  • Publication number: 20140154621
    Abstract: The disclosure relates generally to toner additives, and in particular, toner additives that provide desired higher toner charge and low relative humidity (RH) sensitivity. The toner additives comprise titania nanotubes or titania nanosheets in combination with or in place of the commonly used anatase or rutile crystalline titania.
    Type: Application
    Filed: December 5, 2012
    Publication date: June 5, 2014
    Applicants: NATIONAL RESEARCH COUNCIL OF CANADA, XEROX CORPORATION
    Inventors: RICHARD P. VEREGIN, Qingbin Li, Andriy Kovalenko, Sergey Gusarov
  • Patent number: 8741521
    Abstract: A toner containing toner particles, each toner particle containing: a releasing agent; a colorant; and a binder resin containing at least a crystalline polyester resin and a non-crystalline polyester resin, wherein in the case where a volume average particle diameter of the toner is defined as Dv, the toner contains a group of the toner particles having 4/5 Dv, and a group of the toner particles having 6/5 Dv, and wherein an endothermic value A of the crystalline polyester resin at a first temperature increase in DSC of the toner, an endothermic value B of the crystalline polyester resin at a first temperature increase in DSC of the group of the toner particle having 4/5 Dv, and an endothermic value C of the crystalline polyester resin at a first temperature increase in DSC of the group of the toner particles having 6/5 Dv satisfy the relation represented by the following formulas: 50<(B/A)×100<90, and 110<(C/A)×100<150.
    Type: Grant
    Filed: September 14, 2011
    Date of Patent: June 3, 2014
    Assignee: Ricoh Company, Ltd.
    Inventors: Mamoru Hozumi, Tsuyoshi Sugimoto, Naohiro Watanabe, Tomoyuki Satoh, Shinya Hanatani, Osamu Uchinokura, Kiwako Hirohara
  • Publication number: 20140147780
    Abstract: A toner is prepared by wet granulation methods, including a monoester wax having carbon atoms of from 36 to 46 on average as a release agent. The toner has a DSC endothermic energy amount (?H1) originating from the wax of from 10 to 12 mJ/mg and a DSC endothermic energy amount (?H2) originating from the wax of from 0.6 to 0.9 times as much as ?H1 after a part of the wax is separated by hexane extraction from the toner. The hexane extraction includes mixing 1 g of the toner in 7 ml of n-hexane to prepare a mixture; stirring the mixture at 120 rpm for 1 min by a pot mill to prepare a dispersion; and subjecting the dispersion to suction filtration.
    Type: Application
    Filed: October 23, 2013
    Publication date: May 29, 2014
    Inventors: Tsuyoshi NOZAKI, Takuya Kadota, Yoshihiro Mikuriya, Yoshimichi Ishikawa, Kazuoki Fuwa, Tomohiro Fukao, Tomoharu Miki
  • Publication number: 20140147782
    Abstract: For electrostatic charge image developing toner including toner base particles including a binder resin and a releasing agent, and an external additive attached to the toner base particles, an ester wax including a carboxylic acid component and an alcohol component each having a specific composition is used as the releasing agent, and an endothermic start temperature of the releasing agent is a predetermined temperature or more.
    Type: Application
    Filed: November 26, 2013
    Publication date: May 29, 2014
    Applicant: KYOCERA DOCUMENT SOLUTIONS INC.
    Inventors: Toshiki TAKEMORI, Masanori SUGAHARA
  • Publication number: 20140140731
    Abstract: A toner including: a binder resin; a releasing agent; and a colorant, wherein the binder resin contains a crystalline polyester resin and a non-crystalline polyester resin, wherein the releasing agent has an endothermic peak temperature of 60° C. to 80° C. at the second temperature rising in differential scanning calorimetry, and wherein the releasing agent is an ester wax which satisfies the following expressions (1) and (2): 1.1 Pa·s??*a?2.0 Pa·s . . . Expression (1) 0.001??*b/?*a?1.00 . . . Expression (2) where in Expressions (1) and (2), ?*a denotes a complex viscosity (Pa·s) determined by measuring a dynamic viscoelasticity of the releasing agent at a measurement frequency of 6.28 rad/s, and ?*b denotes a complex viscosity (Pa·s) determined by measuring a dynamic viscoelasticity of the releasing agent at a measurement frequency of 62.8 rad/s.
    Type: Application
    Filed: July 3, 2012
    Publication date: May 22, 2014
    Inventors: Mamoru Hozumi, Junichi Awamura, Teruki Kusahara, Daisuke Ito, Satoshi Ogawa, Takahiro Honda, Kiwako Hirohara, Osamu Uchinokura, Satoshi Kojima, Syouko Satoh, Tsuneyasu Nagatomo, Masaki Watanabe, Masaaki Oka, Yasuaki Ohta
  • Publication number: 20140141366
    Abstract: In a toner including toner particles obtained by performing suspension polymerization using a monomer composition containing a polymerizable monomer and a polar resin and in a method for manufacturing the above toner, the polar resin satisfies the following conditions (1) to (4). (1) The polar resin is a styrene-based resin. (2) A main peak molecular weight Mp is 5,000 to 100,000. (3) When the acid value of a low molecular weight component is represented by A and the acid value of a high molecular weight component is represented by B, 0.80?A/B?1.20 is satisfied. (4) The acid value is 5.0 to 40.0 mgKOH/g.
    Type: Application
    Filed: July 10, 2012
    Publication date: May 22, 2014
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Yasushi Katsuta, Shinya Yachi, Takeshi Shimura, Nobuhisa Abe, Kenta Kamikura
  • Patent number: 8715897
    Abstract: The present disclosure provides polyesters suitable for use in forming toners. In embodiments, a polyester may be subjected to phase inversion emulsification, in which charge control agents are added so that the polyester emulsion includes charge control agents therein. The resulting polyester emulsion with charge control agents may then be utilized to form toner particles.
    Type: Grant
    Filed: November 16, 2009
    Date of Patent: May 6, 2014
    Assignee: Xerox Corporation
    Inventors: Robert D. Bayley, Yuhua Tong, Timothy L. Lincoln, Grazyna Kmiecik-Lawrynowicz, Maura A. Sweeney
  • Publication number: 20140120467
    Abstract: A toner having charge control agents which impart excellent triboelectric charging characteristics.
    Type: Application
    Filed: November 1, 2012
    Publication date: May 1, 2014
    Applicant: Xerox Corporation
    Inventors: Maura A. Sweeney, Robert D. Bayley, Grazyna E. Kmiecik-Lawrynowicz, Brian S. Wang
  • Publication number: 20140113227
    Abstract: An electrostatic charge image developing toner is provided which includes a core particle that contains an amorphous polyester resin and a colorant; and a shell layer that covers the core particle and contains a polystyrene resin, wherein a softening temperature Ma of the shell layer and a softening temperature Mb of the core particle satisfy a relationship of 10° C.?Ma-Mb?45° C.
    Type: Application
    Filed: June 6, 2013
    Publication date: April 24, 2014
    Inventors: Tomohiro SHINYA, Shinpei TAKAGI, Soichiro KITAGAWA, Shinya SAKAMOTO
  • Patent number: 8703374
    Abstract: Toner particles include a shell and a core, wherein the shell includes charge control agent-treated spacer particles that cause protrusions from the toner particle surface.
    Type: Grant
    Filed: March 9, 2012
    Date of Patent: April 22, 2014
    Assignee: Xerox Corporation
    Inventors: Maura A. Sweeney, Robert D. Bayley, Grazyna E. Kmiecik-Lawrynowicz, Anne Marie Sweeney-Jones
  • Patent number: 8691485
    Abstract: The present disclosure provides toners and methods for their production. In embodiments, the toner may include a core/shell configuration, with a non-crosslinked resin and a crosslinked resin in the core, with a second non-crosslinked resin in the shell, pigment/pigments and a wax possessing both branched and linear carbons.
    Type: Grant
    Filed: October 8, 2009
    Date of Patent: April 8, 2014
    Assignee: Xerox Corporation
    Inventors: Daniel W. Asarese, Grazyna E. Kmiecik-Lawrynowicz, Samir Kumar, Maura A. Sweeney, Siddhesh N. Pawar, Robert D. Bayley
  • Publication number: 20140087299
    Abstract: A toner including toner particles, each of which comprising a charging component, a polymer having a partial structure represented by the following formula (1) as the side chain, and a colorant: (R1 represents a hydroxyl group, a carboxyl group, an alkyl group having 1 to 18 carbon atoms, or an alkoxyl group having 1 to 18 carbon atoms; R2 represents a hydrogen atom, a hydroxyl group, an alkyl group having 1 to 18 carbon atoms, or an alkoxyl group having 1 to 18 carbon atoms; m represents an integer of 0 to 3; if m is 2 or 3, R1 can be each independently selected; n represents an integer of 1 to 3; and * represents a coupling site in the polymer.
    Type: Application
    Filed: May 17, 2012
    Publication date: March 27, 2014
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Takashi Kenmoku, Hitoshi Itabashi, Akane Masumoto
  • Patent number: 8679714
    Abstract: A toner including: a first binder resin; a colorant; a releasing agent; and a crystalline organic compound, wherein the first binder resin contains an amorphous polyester resin (a) having a polyhydroxycarboxylic acid skeleton derived from optically active monomers in a part of a main chain of the amorphous polyester resin, and the polyhydroxycarboxylic acid skeleton has an optical purity X, calculated on the monomer basis, of 80% or less, and the optical purity X is determined from the equation, Optical Purity X (%)=|X(L-form)?X(D-form)| wherein the crystalline organic compound is any one of a crystalline polyester resin (b) and a crystalline low molecular compound having a melting point of 60° C. to 100° C., and being selected from a group consisting of fatty acid having 16 to 24 carbon atoms, alcohol having 16 to 24 carbon atoms, a fatty acid ester compound, and aliphatic carboxylic acid amide.
    Type: Grant
    Filed: September 9, 2010
    Date of Patent: March 25, 2014
    Assignee: Ricoh Company, Ltd.
    Inventors: Ryota Inoue, Akihiro Kotsugai, Yoshihiro Moriya, Akiyoshi Sabu, Shingo Sakashita, Keiko Osaka, Yukiko Nakajima, Yoshitaka Yamauchi, Daiki Yamashita