Carboxylic Acid Or Ester Compound Adjuvant Patents (Class 430/108.4)
  • Publication number: 20130171552
    Abstract: The present invention provides a toner showing an excellent fixing property even in high-speed image formation and inhibiting contamination of the inside of an apparatus and thereby being capable of stably forming high-quality images not having unevenness of gloss over a long period of time. In the toner including toner particles containing a binder resin, an ester wax, and a coloring agent, the ester wax is prescribed by, in GC/MS analysis of components volatilized by heating the wax at 200° C. for 10 minutes, a relationship in the components having carbon atoms in specific ranges.
    Type: Application
    Filed: September 6, 2011
    Publication date: July 4, 2013
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Kazumi Yoshizaki, Yasushi Katsuta, Kenichi Nakayama, Takeshi Kaburagi, Hideki Kaneko
  • Publication number: 20130164669
    Abstract: A toner including a binder resin containing an ester bond, and a releasing agent, wherein the releasing agent includes first C30-C50 alkyl monoester compound and second C30-C50 alkyl monoester compound, wherein the number of carbon atoms of the first C30-C50 alkyl monoester compound is different from that of the second C30-C50 alkyl monoester compound, wherein the amount of the first C30-C50 alkyl monoester compound is largest and the amount of the second C30-C50 alkyl monoester compound is second largest or same as the amount of the first C3OC50 alkyl monoester compound, wherein the amount of the first C30-C50 alkyl monoester compound is 30% by mass or more but less than 50% by mass to the releasing agent, and wherein the amount of the second C30-C50 alkyl monoester compound is 10% by mass or more but less than 50% by mass to the releasing agent.
    Type: Application
    Filed: August 18, 2011
    Publication date: June 27, 2013
    Inventors: Hiroshi Yamashita, Yuichi Shirasu, Tomoki Murayama, Masaki Watanabe
  • Publication number: 20130157185
    Abstract: A toner includes a binder resin, a coloring agent, and a releasing agent containing two or more kinds of alkyl monoester compounds having a different number of carbon atoms in a range of from 30 to 50 carbon atoms. The toner has a crystallinity of 10% or more as measured by x-ray diffraction and/or the binder resin is a crystalline resin in an amount of 50% by weight or more of the binder resin. The two or more kinds of alkyl monoester compounds include a component A accounting for the largest amount ranging from 30% by weight to less than 50% by weight of the releasing agent and a component B accounting for the second largest amount ranging from 10% by weight to less than 50% by weight of the releasing agent.
    Type: Application
    Filed: December 5, 2012
    Publication date: June 20, 2013
    Inventors: Shingo SAKASHITA, Hiroshi Yamashita, Masahide Yamada, Shinya Nakayama, Atsushi Yamamoto, Yukiko Nakajima
  • Publication number: 20130157187
    Abstract: The disclosure describes a pigment treated with a rosin and a toner particle containing that rosin-treated pigment particle. The toner has a lower level of dielectric loss.
    Type: Application
    Filed: December 14, 2011
    Publication date: June 20, 2013
    Applicant: Xerox Corporation
    Inventors: Ke Zhou, Rina Carlini, Daryl W. Vanbesien, Cuong Vong, Karen A. Moffat, Richard P.N. Veregin
  • Patent number: 8460845
    Abstract: Provided is a cyan toner which, while being a capsule-type toner having excellent low-temperature fixability, has excellent offset resistance and charging performance and can obtain high-quality images. A cyan toner having at least a resin (a) having a polyester as a main component, a colorant, and a wax, in which glass transition temperatures (° C.) Tg(0.5) and Tg(4.0) obtained at a rate of temperature increase of 0.5° C./min or 4.0° C./min satisfy 40.0?Tg(0.5)?60.0 and 2.0?Tg(4.0)?Tg(0.5)?10.0, and wherein, when the concentration of the cyan toner in an ethyl acetate dispersion is Cc1 (mg/ml), and the light absorbance at a wavelength of 712 nm of the dispersion is A(ethyl acetate)712, A(ethyl acetate)712/Cc1<0.15 is satisfied, and wherein, when the concentration of the cyan toner in a chloroform solution is Cc2 (mg/ml), and the light absorbance at a wavelength of 712 nm of the solution is A(chloroform)712, 2.00<A(chloroform)712/Cc2<8.15 is satisfied.
    Type: Grant
    Filed: November 12, 2009
    Date of Patent: June 11, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takaaki Kaya, Ayako Sekikawa, Ryoichi Fujita, Shigeto Tamura, Makoto Kambayashi
  • Patent number: 8426097
    Abstract: An electrophotographic toner including a latex, a coloring agent, and a release agent, wherein a difference between an average circularity of toner having a particle size of D16p or less (S16) and an average circularity of toner having a particle size of D50p or less (S50) is about 0.01 or less, wherein the circularity is measured using a flow particle image analyzer (FPIA), and the ratio of an area of wax to a total cross-sectional area of the toner having a particle size of D16p or less is about 8/100 or greater, and wherein the area is measured using a transmission electron microscope (TEM).
    Type: Grant
    Filed: December 3, 2009
    Date of Patent: April 23, 2013
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Yo-da Shin, Jun-young Lee, Jae-hwan Kim, Tae-hoe Koo
  • Publication number: 20130071783
    Abstract: According to an embodiment, provided is a developer, which is used for a full-color image forming apparatus, wherein the developer includes a monochrome toner and a color toner, each including a coloring material, an amorphous polyester resin, a crystalline polyester resin, and an ester wax which includes ester compounds having an alkyl group and also having a carbon number of from 32 to 48, the amorphous polyester resin to be blended in the monochrome toner has a melting point (Tm2) of from 140 to 155° C. and the amorphous polyester resin to be blended in the color toner has a melting point (Tm1) of from 115 to 130° C., and the Tm1 and the Tm2 satisfy the following formula (1): 10(° C.)?Tm2?Tm1?40(° C.).
    Type: Application
    Filed: September 6, 2012
    Publication date: March 21, 2013
    Applicants: TOSHIBA TEC KABUSHIKI KAISHA, KABUSHIKI KAISHA TOSHIBA
    Inventor: Koichi Kuroyama
  • Publication number: 20130065174
    Abstract: An object of the present invention is to provide a toner in which a charging amount and rise of the charging amount are hardly influenced by change in a temperature and humidity environment, and pigment dispersibility is high in order to provide an image output having high transparency, color mixing properties, and color nuance stability.
    Type: Application
    Filed: September 5, 2012
    Publication date: March 14, 2013
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Hitoshi Itabashi, Takashi Kenmoku, Akane Masumoto
  • Publication number: 20130059245
    Abstract: The present invention relates to a polymerized toner and a method for preparing the same, wherein the toner can realize an excellent offset feature, high transfer efficiency, and a uniform image and thus can exhibit excellent performances in the applications of high speed copying, development of transferred photos, etc.
    Type: Application
    Filed: February 22, 2011
    Publication date: March 7, 2013
    Applicant: LG CHEM, LTD.
    Inventors: Wook Jang, Hak-Soo Kim, Chang-Soon Lee
  • Publication number: 20130052578
    Abstract: A toner for electrostatic latent image development includes at least a binder resin, a colorant, a charge control agent, and a release agent. The release agent contains a synthetic ester wax and a natural ester wax. When a toner sample is measured by a differential scanning calorimeter in a way that the toner sample is heated from 30° C. to 170° C. at a rate of 10° C./min followed by cooling to 30° C. at a rate of 10° C./min and is then re-heated from 30° C. to 170° C. at a rate of 10° C./min, a fusion-starting temperature TB, a lower endothermic peak temperature T1 derived from one ester wax, an intermediate endothermic peak temperature T2, and a higher endothermic peak temperature T3 derived from another ester wax are respectively a certain temperature, and are observed during the re-heating.
    Type: Application
    Filed: August 28, 2012
    Publication date: February 28, 2013
    Applicant: KYOCERA DOCUMENT SOLUTIONS INC.
    Inventor: Masanori Sugahara
  • Patent number: 8383307
    Abstract: The toner includes a binder resin; a release agent; a colorant; and a dispersing resin configured to disperse the release agent. The dispersing resin includes a polyhydroxycarboxylic acid unit obtained from an optically active monomer. The polyhydroxycarboxylic acid unit has an optical purity of not greater than 80%, wherein the optical purity is defined as the absolute value of difference between the mole percentage of a L-monomer in the optically active monomer and the mole percentage of a D-monomer in the optically active monomer.
    Type: Grant
    Filed: October 8, 2009
    Date of Patent: February 26, 2013
    Assignee: Ricoh Company, Limited
    Inventors: Ryota Inoue, Akihiro Kotsugai, Toyoshi Sawada, Akiyoshi Sabu
  • Patent number: 8383311
    Abstract: A toner composition that includes at least one low molecular weight amorphous polyester resin, at least one high molecular weight amorphous polyester resin, at least one crystalline polyester resin, at least one wax, at least one biocide and at least one colorant, and wherein the toner composition has a minimum fusing temperature of from about 100° C. to about 125° C.
    Type: Grant
    Filed: October 8, 2009
    Date of Patent: February 26, 2013
    Assignee: Xerox Corporation
    Inventors: Chieh-Min Cheng, Zhen Lai, Zhaoyang Ou, Dennis A. Mattison, Jr., Phil Dale, Christopher D. Blair, Steven M. Malachowski, Ryan Accetta
  • Patent number: 8367289
    Abstract: A toner is provided which is excellent in development stability in both a low-temperature, low-humidity environment and a high-temperature, high-humidity environment over a long time period. The toner includes toner particles containing at least a binder resin and a colorant, and a fatty acid metal salt. The fatty acid metal salt has a volume-based median diameter (D50s) of 0.15 ?m or more and 0.65 ?m or less, and the liberation ratio of the fatty acid metal salt in the toner is 1.0% or more and 25.0% or less.
    Type: Grant
    Filed: February 24, 2009
    Date of Patent: February 5, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Naoya Isono, Satoshi Handa, Katsuyuki Nonaka, Koji Abe, Yasuhiro Hashimoto, Akira Sugiyama, Yuhei Terui
  • Publication number: 20130029261
    Abstract: The present invention relates to a polymerized toner prepared by suspension polymerization. In particular, the polymerized toner comprises a plurality of toner particles that each comprising a binder resin, a pigment, a pigment stabilizer, a charge control agent, and a wax. The polymerized toner maintains a ratio of toner particles containing at least two wax domains per particle within a defined range. Thereby, the polymerized toner achieves high glossiness and good transfer efficiency.
    Type: Application
    Filed: July 26, 2012
    Publication date: January 31, 2013
    Applicant: LG CHEM, LTD.
    Inventors: Wook JANG, Chang-Soon LEE, Woo-Cheul JUNG, Joo-Yong PARK
  • Publication number: 20130029259
    Abstract: A developer for electrostatic latent image development including a positively chargeable toner and a fatty acid metal salt is used, in which the fatty acid metal salt is a metal salt selected from the group consisting of zinc, calcium, and magnesium salts of fatty acids of 12 to 20 carbon atoms and has a certain volume average particle diameter and particle size distribution.
    Type: Application
    Filed: July 20, 2012
    Publication date: January 31, 2013
    Applicant: KYOCERA DOCUMENT SOLUTIONS INC.
    Inventors: Masami Tujihiro, Yukinori Nakayama
  • Patent number: 8361688
    Abstract: Disclosed is a toner including: a resin; coloring agent and release agent including compound or compounds represented by the following general formula (1): R1—(COO—R2)n, wherein R1 is a linking group having carbon number of 2 to 8 which may be a cyclic structure and may have a hydroxy group or fatty acid ester group; and each R2 is an alkyl group having carbon number of N, (N-2) or (N-4) independently, N is a natural number from 10 to 30, and n is a natural number from 3 to 4, R2 with carbon number of N is 80 to 97 percent by mass, R2 with carbon number of (N-2) is 0.0 to 7.8 percent by mass, R2 with carbon number of (N-4) is 3.0 to 13.0 percent by mass, R2 with carbon number of (N-4) is included 1.5 percent by mass or more than R2 with carbon number of (N-2).
    Type: Grant
    Filed: January 6, 2010
    Date of Patent: January 29, 2013
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Mikio Kouyama, Kenji Hayashi, Hiroaki Obata, Noriyuki Kinpara, Hiroshi Nagasawa, Yasuhiko Muramatsu
  • Patent number: 8357479
    Abstract: A toner comprising: a component consisting of a thermoplastic resin containing an amorphous plant-derived resin having a carboxyl group; a component consisting of a crystalline epoxy resin having a glycidyl group; a component consisting of a cross-linked resin generated through a reaction between the carboxyl group of the plant-derived resin and the glycidyl group of the crystalline epoxy resin; and a colorant.
    Type: Grant
    Filed: August 27, 2010
    Date of Patent: January 22, 2013
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Satoru Ariyoshi, Yasuhiro Shibai
  • Publication number: 20120315575
    Abstract: The present invention is to provide a toner for developing electrostatic images having excellent fixability, peelability, shelf stability (blocking resistance), printing durability, printing durability after being left at high temperature and thin line reproducibility. A toner for developing electrostatic images, comprising colored resin particles comprising a binder resin, a colorant and a wax, wherein the wax contains a natural sunflower wax, and wherein the natural sunflower wax has an acid value of 10 mg KOH/g or less, and a content of the natural sunflower wax is in the range from 1 to 10 parts by weight with respect to 100 parts by weight of the binder resin.
    Type: Application
    Filed: March 10, 2011
    Publication date: December 13, 2012
    Applicant: ZEON CORPORATION
    Inventor: Takuya Kaneda
  • Publication number: 20120315574
    Abstract: A toner is provided that exhibits a high long-term image stability even during high-speed printing and that also exhibits an excellent environmental stability. The toner comprises a binder resin, a colorant, and a nonionic surfactant, wherein the nonionic surfactant has an oxyethylene group (EO) and an oxypropylene group (PO) and has a ratio of the number of moles of the oxypropylene group to the number of moles of the oxyethylene group (PO/EO) of at least 0.01 and not more than 5.00; and when A (?g/g) is defined as a nonionic surfactant content on the surface of the toner that can be extracted by methanol from 1 g of the toner and B (m2/g) is defined as a theoretical specific surface area determined from a toner particle diameter distribution obtained by a precision particle diameter distribution analyzer that operates based on an aperture electrical resistance method, a ratio A/B is at least 100 ?g/m2 and not more than 9000 ?g/m2.
    Type: Application
    Filed: May 12, 2011
    Publication date: December 13, 2012
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Katsuyuki Nonaka, Yasuhiro Hashimoto, Naoya Isono, Akira Sugiyama, Yuhei Terui
  • Publication number: 20120315573
    Abstract: The present invention provides a modified charge control agent composition exhibiting a high charge-imparting effect, and an electrostatic image developing toner containing such a charge control agent composition and having a high electrostatic charge amount and an environmental stability. A composition comprising a metal compound (A) of aromatic hydroxycarboxylic acid having an aromatic hydroxycarboxylic acid bonded with a metal atom selected from a zirconium atom, a calcium atom, an aluminum atom, a chromium atom, a boron atom and a zinc atom via at least any of ionic bond, covalent bond and coordinate bond; and at least one inorganic pigment (B), wherein the pigment (B) is contained in an amount of from 1 to 20 parts by mass in 100 parts by mass of the composition.
    Type: Application
    Filed: August 21, 2012
    Publication date: December 13, 2012
    Applicant: HODOGAYA CHEMICAL CO., LTD.
    Inventors: Hideyuki OTSUKA, Masaki OKUBO, Osamu MUKUDAI
  • Publication number: 20120295191
    Abstract: A toner is provided which has toner particles containing a charging component and containing an aromatic compound represented by the following formula (1): wherein R1 to R3 each independently represent a hydrogen atom, a hydroxyl group, a carboxyl group, an alkyl group having 1 to 18 carbon atom(s) or an alkoxyl group having 1 to 18 carbon atom(s); R4 to R7 each independently represent a hydrogen atom, a hydroxyl group, an alkyl group having 1 to 18 carbon atom(s) or an alkoxyl group having 1 to 18 carbon atom(s); R8 represents a hydrogen atom or a methyl group; and m represents an integer of 1 to 3.
    Type: Application
    Filed: April 27, 2012
    Publication date: November 22, 2012
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Hitoshi Itabashi, Akane Masumoto, Takashi Kenmoku
  • Publication number: 20120295190
    Abstract: A toner is provided which has toner particles containing an aromatic compound represented by the following formula (1), and a colorant: wherein R1 to R3 each independently represent a hydrogen atom, a hydroxyl group, a carboxyl group, an alkyl group having 1 to 18 carbon atom(s) or an alkoxyl group having 1 to 18 carbon atom(s); R4 to R8 each independently represent a hydrogen atom, a hydroxyl group, an alkyl group having 1 to 18 carbon atom(s) or an alkoxyl group having 1 to 18 carbon atom(s); and m represents an integer of 1 to 3.
    Type: Application
    Filed: April 27, 2012
    Publication date: November 22, 2012
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Hitoshi Itabashi, Takashi Kenmoku, Akane Masumoto
  • Publication number: 20120288792
    Abstract: There is provided a developer that has excellent positive charging characteristics and charging stability, and which is compatible with high-speed developing. The developer of the invention contains toner particles and an insulating liquid, wherein a fatty acid ester is contained as the insulating liquid, a substance A expressed by the following formula (1) and/or a substance B expressed by the following formula (2) is further contained, and the total percentage in which substance A and substance B are contained is at least 0.1 wt % and no more than 3.0 wt %.
    Type: Application
    Filed: April 26, 2012
    Publication date: November 15, 2012
    Applicant: SEIKO EPSON CORPORATION
    Inventors: Takashi TESHIMA, Junichi ISHIKAWA
  • Publication number: 20120288791
    Abstract: In accordance with some embodiments, a toner including a first binder resin, a release agent, a release agent dispersing resin, and a colorant is provided. The first binder resin includes an amorphous polyester resin (a) having a polyhydroxycarboxylic acid skeleton in its main chain. The polyhydroxycarboxylic acid skeleton comprises optically-active monomers having an optical purity X of 80% by mole or less. The optical purity X is represented by the following formula: X (% by mole)=|X(L-form)?X(D-form)| wherein X(L-form) and X(D-form) represent ratios (% by mole) of L-form and D-form optically-active monomers, respectively. The release agent includes an ester of a fatty acid having an average carbon number of 18 to 24 with glycerin or a polyglycerin having an average polymerization degree of 2 to 10. The ester has a melting point of 55 to 80° C.
    Type: Application
    Filed: April 26, 2012
    Publication date: November 15, 2012
    Inventors: Shingo Sakashita, Kazumi Suzuki, Tatsuya Morita
  • Patent number: 8293444
    Abstract: A toner that includes at least one polyester resin wherein the amount of free polyvalent acid monomer in the polyester resin is less than 4 mg/gram, and wherein the percentage of the at least one polyester resin with a MW less than 1500 is less than about 10%.
    Type: Grant
    Filed: June 24, 2009
    Date of Patent: October 23, 2012
    Assignee: Xerox Corporation
    Inventors: John L. Pawlak, Timothy L. Lincoln, William H. Hollenbaugh, Jr., Yuhua Tong, Brendan H. Williamson
  • Publication number: 20120251938
    Abstract: A method for producing colored resin particles including: dissolving or dispersing at least binder resin and colorant in organic solvent to prepare oil phase; dissolving resin A and basic compound in aqueous medium to prepare aqueous phase, the resin A having solubility <2.0 g/100 g water having temperature 25° C. and pH 3.0 and solubility ?2.0 g/100 g water having temperature 25° C. and pH 10.0; dispersing the oil phase in the aqueous phase to prepare core particle dispersion liquid; dispersing resin particles in aqueous medium to prepare resin particle dispersion liquid, and adding the resin particle dispersion liquid to the core particle dispersion liquid so that the resin particles are attached onto the core particles, to prepare dispersion liquid containing particles each having the core particle and the resin particles attached thereonto; removing the organic solvent from the dispersion liquid; washing the particles; and drying the particles.
    Type: Application
    Filed: February 1, 2012
    Publication date: October 4, 2012
    Inventors: Atsushi Yamamoto, Takuya Kadota, Yoshihiro Mikuriya, Tsuyoshi Nozaki, Yoshimichi Ishikawa, Kazuoki Fuwa, Tomohiro Fukao, Tomoharu Miki
  • Publication number: 20120244466
    Abstract: A washing process using one or more ionic liquids (ILs) as a washing aid agent for toners, including toners produced using such ILs, such as, low melt toners, is provided. ILs are environmentally sound, green solvents that act to swell toner particle surfaces so that surface absorbed and adsorbed pollutants, such as, surfactants and other manufacturing reactants, can be effectively removed. The resulting toners have good charging, charge maintenance and RH sensitivity.
    Type: Application
    Filed: March 22, 2011
    Publication date: September 27, 2012
    Applicant: XEROX CORPORATION
    Inventors: Zhen Lai, Chieh-Min Cheng, Zhaoyang Ou
  • Publication number: 20120231387
    Abstract: A toner including a mother particle and an external additive is provided. The mother particle includes a core including a crystalline polyester, an amorphous polyester, a colorant, and a release agent; and a shell including resin particles. A deformation amount H1 of the toner compressed by a pressure of 0.5 mN under a temperature of 25° C. is between 0.2 and 1.5 ?m. A difference D between the deformation amount H1 and a deformation amount H2 of the toner compressed by a pressure of 0.5 mN under a temperature of 50° C. is between 0.0 and 1.0 ?m. A surface roughness Ra of the toner melted at 90° C. is between 0.02 and 0.40 ?m.
    Type: Application
    Filed: February 17, 2012
    Publication date: September 13, 2012
    Inventor: Hideki SUGIURA
  • Publication number: 20120231386
    Abstract: A toner composition including a colorant-polyester polymer having at least one colorant and at least one polyester resin, an optional non-colorant polyester polymer, an optional additional colorant, an optional wax, and an optional additive, where the colorant is covalently linked to some or all of the polyester resin and the polyester resin is obtained by polymerizing a lactone using an enzyme catalyst. Methods for preparing a toner composition including an emulsion aggregation process.
    Type: Application
    Filed: March 9, 2011
    Publication date: September 13, 2012
    Applicant: XEROX CORPORATION
    Inventors: Santiago FAUCHER, Kimberly D. NOSELLA, Shigang S. QIU
  • Patent number: 8252493
    Abstract: Single component toners are provided with at least one surface additive including a large polymeric spacer, and processes for producing the same. In embodiments, the toner is a non-magnetic single component toner produced by emulsion aggregation methods. The large polymeric spacer additives provide excellent flow characteristics to the resulting toners, and reduce the incidence of clogging failure and print defects such as ghosting, white bands, and low toner density compared with conventionally produced toners.
    Type: Grant
    Filed: October 15, 2008
    Date of Patent: August 28, 2012
    Assignee: Xerox Corporation
    Inventors: Samir Kumar, Grazyna L. Kmiecik-Lawrynowicz, Maura A. Sweeney, Michael L. Grande, Julie C. Pickering, Timothy L. Lincoln
  • Patent number: 8252494
    Abstract: A fluorescent particle includes a fluorescent pigment, such as a trans-dicarboxylic-indenofluorenone, and at least one stabilizing wax chemically attached to the fluorescent pigment. The stabilizing wax includes an amine group at its terminal end and the fluorescent pigment includes at least one carboxylic acid group, where the amine group reacts with the carboxylic acid group to form an amide bond. A method for making fluorescent particles for use in toners by chemically attaching at least one stabilizing wax to a fluorescent pigment where the at least one stabilizing wax includes an amine group at its terminal end and the fluorescent pigment includes at least one carboxylic acid group. A toner may include a resin and the fluorescent particle.
    Type: Grant
    Filed: May 3, 2010
    Date of Patent: August 28, 2012
    Assignee: Xerox Corporation
    Inventors: Daryl W. Vanbesien, Maria M. Birau, C. Geoffrey Allen, Carol A. Jennings, Peter G. Odell
  • Publication number: 20120214096
    Abstract: A toner to develop an electrostatic charge image, a method of preparing the toner, a toner supply device employing the toner, an apparatus to form an image employing the toner, and a method of forming an image using the toner are provided. The toner includes a binder resin including a first type of binder resin having a first weight-average molecular weight and a second type of binder resin having a second weight-average molecular weight different than the first weight-average molecular weight, a colorant, and a releasing agent.
    Type: Application
    Filed: February 17, 2012
    Publication date: August 23, 2012
    Applicant: Samsung Electronics Co., Ltd
    Inventors: Kyeong PANG, Tae-hoe Koo, Su-bum Park, Ju-yeon Lee, Jun-young Lee
  • Patent number: 8247146
    Abstract: Use of a wax in a toner, such as carnauba wax, to give an increase in charge control agent in a toner, such as a magenta toner, to give an increased glass transition temperature is disclosed. The toner may contain a resin comprising amorphous and crystalline polyesters to provide good low melt characteristics.
    Type: Grant
    Filed: October 5, 2010
    Date of Patent: August 21, 2012
    Assignee: Xerox Corporation
    Inventors: Mark E. Mang, Eugene F. Young
  • Publication number: 20120208118
    Abstract: Environmentally friendly resin particles are provided which include a monomer having a color, which is able to impart color to the resulting resin. The resulting resin may be used to form various articles, including toner. A toner of the present disclosure may thus include the bio-based polyester resin, optionally in combination with another amorphous resin and/or a crystalline resin. Methods for providing these resins are also provided.
    Type: Application
    Filed: February 14, 2011
    Publication date: August 16, 2012
    Applicant: XEROX CORPORATION
    Inventor: Valerie M. Farrugia
  • Publication number: 20120196218
    Abstract: A toner for developing an electrostatic charge image includes a core layer including a first binder resin, a colorant and a releasing agent; and a shell layer coating the core layer and including a second binder resin. The first binder resin of the core layer includes a low molecular weight amorphous polyester resin having a weight-average molecular weight of about 6000 g/mol to about 20000 g/mol, a high molecular weight amorphous polyester resin having a weight-average molecular weight of about 25000 g/mol to about 100000 g/mol, and a crystalline polyester resin having a weight-average molecular weight of about 8000 g/mol to about 30000 g/mol. The second binder resin of the shell layer includes the low and high molecular weight amorphous polyester resins.
    Type: Application
    Filed: January 10, 2012
    Publication date: August 2, 2012
    Applicant: Samsung Electronics Co., Ltd.
    Inventors: Jin-mo HONG, Takeshi Yoshida, Sung-jin Park
  • Patent number: 8227164
    Abstract: A toner, including a colorant; a binder resin; a release agent; and a fixing supplemental component, wherein the toner has a storage elastic modulus G? (Pa) satisfying the following conditions: 5.0×104<G?<5.0×105 at 80° C. 1.0×104<G?<1.0×105 at 90° C. 5.0×103<G?<5.0×104 at 100° C. 1.0×103<G?<1.0×104 at 120° C. 1.0×103<G?<1.0×104 at 150° C.
    Type: Grant
    Filed: May 11, 2010
    Date of Patent: July 24, 2012
    Assignee: Ricoh Company, Limited
    Inventors: Tsuyoshi Sugimoto, Naohito Shimota, Hiroshi Yamashita, Satoshi Ogawa, Masana Shiba, Junichi Awamura, Tsuneyasu Nagatomo, Masaki Watanabe
  • Publication number: 20120183896
    Abstract: Disclosed is a polyester resin comprising the polycondensation product of (a) at least one diacid, acid ester, or diester; and (b) at least one diol; wherein either (i) at least one diacid, acid ester, or diester comprises a rosin diacid, rosin acid ester, or rosin diester; or (ii) at least one diol comprises a rosin diol. Also disclosed is a toner composition comprising particles which comprise the disclosed polyester resin and an optional colorant.
    Type: Application
    Filed: January 17, 2011
    Publication date: July 19, 2012
    Applicant: XEROX CORPORATION
    Inventors: Guerino G. Sacripante, Ke Zhou, Edward G. Zwartz, Paul J. Gerroir, Michael S. Hawkins
  • Patent number: 8216755
    Abstract: A toner manufactured by a method including the steps of dissolving or dispersing toner components comprising a binder resin, a colorant, and an encapsulated plasticizer to prepare an oily toner components liquid, and emulsifying or dispersing the oily toner components liquid in an aqueous medium to prepare the toner.
    Type: Grant
    Filed: June 1, 2009
    Date of Patent: July 10, 2012
    Assignee: Ricoh Company, Limited
    Inventors: Yoshimichi Ishikawa, Chiyoshi Nozaki, Tsuyoshi Nozaki, Takuya Kadota, Katsunori Kurose, Mitsuyo Matsumoto, Atsushi Yamamoto
  • Publication number: 20120171604
    Abstract: The invention relates to a coloured polymer dispersion containing, as main ingredients: (a) a coloured polymer produced by polymerisation of monomer A with monomer B, monomer A being a pigment B which is coated with a polymerisable wax D wherein the polymerisable function is an ethylenically unsaturated group, monomer B being a ethylenically unsaturated compound; (b) at least one non-ionic surface-active additive E based on polyethers and/or polyglycerines; (c) at least one anionic surface-active additive F based on sulfonates, sulfates, phosphonates, phosphates or carboxylates; and (d) water.
    Type: Application
    Filed: March 16, 2012
    Publication date: July 5, 2012
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Franz-Leo HEINRICHS, Anais BIALY, Klaus SAITMACHER, Josef RITTER
  • Patent number: 8211607
    Abstract: Toner particles are provided which may, in embodiments, include a gel. In embodiments, the toner particles may have a core-shell configuration, with the gel in the core, the shell, or both. The gel may prevent a crystalline resin in the core of the toner particles from migrating to the toner surface.
    Type: Grant
    Filed: August 27, 2008
    Date of Patent: July 3, 2012
    Assignee: Xerox Corporation
    Inventors: Ke Zhou, Karen Ann Moffat, Edward G. Zwartz, Richard P. N. Veregin, Maria N. V. McDougall
  • Patent number: 8211608
    Abstract: The present invention relates to a resin emulsion which has a good emulsification performance even when produced by using a crosslinked polyester resin as a binder resin, and also is capable of producing a toner having an excellent storage property therefrom; and a process for producing the resin emulsion. The process for producing a resin emulsion according to the present invention, includes the steps of: (a) mixing a resin containing a polyester having at least one constitutional unit selected from the group consisting of a constitutional unit derived from a trivalent or higher-valent alcohol component and a constitutional unit derived from a trivalent or higher-valent carboxylic acid component, an anionic surfactant, a nonionic surfactant and an aqueous medium with each other at a temperature not lower than a softening temperature (Ts) of the resin as measured by a flow tester method, the nonionic surfactant and the aqueous medium being used in amounts of from 0.1 to 1.
    Type: Grant
    Filed: April 17, 2008
    Date of Patent: July 3, 2012
    Assignee: Kao Corporation
    Inventors: Hiroshi Mizuhata, Nobumichi Kamiyoshi, Shinichi Sata
  • Publication number: 20120156607
    Abstract: Environmentally friendly toner particles are provided which may include a bio-based amorphous polyester resin, optionally in combination with another amorphous resin and/or a crystalline resin. Methods for providing these toners are also provided. In embodiments, the bio-based amorphous polyester resin is modified with a multi-functional bio-based acid, thereby providing acid-functionalized polyesters, which can be readily emulsified in emulsion aggregation processes for toner fabrication.
    Type: Application
    Filed: December 21, 2010
    Publication date: June 21, 2012
    Applicant: XEROX CORPORATION
    Inventors: Valerie M. Farrugia, Guerino G. Sacripante, Sonja Hadzidedic
  • Publication number: 20120135344
    Abstract: The present invention is to provide a toner for developing electrostatic images having a low minimum fixing temperature, and high hot offset resistance and high heat-resistant shelf stability, and a method for producing the toner. Also, the present invention is to provide a toner for developing electrostatic images, comprising a binder resin, a colorant, a release agent and a retention aid, wherein the retention aid is a copolymer of 70 to 98% by weight styrene and 2 to 30% by weight (meth)alkyl acrylate, and the copolymer has a glass transition temperature of 5 to 60° C.
    Type: Application
    Filed: November 23, 2011
    Publication date: May 31, 2012
    Applicant: ZEON CORPORATION
    Inventor: Azusa Wada
  • Patent number: 8187780
    Abstract: Environmentally friendly toner particles are provided which may, in embodiments, include a biodegradable semi-crystalline polyester resin and a biodegradable amorphous polyester resin.
    Type: Grant
    Filed: October 21, 2008
    Date of Patent: May 29, 2012
    Assignee: Xerox Corporation
    Inventors: Gwynne McAneney-Lannen, Guerino G. Sacripante, Edward G. Zwartz, Maria N. V. McDougall
  • Patent number: 8182973
    Abstract: An electrostatic-image-developing toner is obtained by aggregating: resin particles, each of which has a core-shell structure, in which a difference in glass transition temperature between a resin constituting the core and a resin constituting the shell is about 20° C. or more; and releasing agent particles, each of which includes a polyester block copolymer having a weight-average molecular weight of about 3,000 or less and containing a non-crystalline polyester block containing a cyclic structure in the main chain and a crystalline polyester block containing no cyclic structure in the main chain.
    Type: Grant
    Filed: March 13, 2009
    Date of Patent: May 22, 2012
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yasuo Matsumura, Hirotaka Matsuoka, Hideo Maehata, Takashi Imai
  • Publication number: 20120122027
    Abstract: To provide a toner, containing: a binder resin; a crystalline polyester resin; a colorant; and wax, wherein the toner has a fluidized powder characteristic value of 35% to 45%, and a BET specific surface area of 2.8 m2/g to 4 m2/g, and wherein the toner has an intensity ratio P2850/P828 of 0.10 to 0.20, where P2850 is an intensity of a peak at 2850 cm?1 which is attributed from the wax and the crystalline polyester resin, and P828 is an intensity of a peak at 828 cm?1 which is attributed from the binder resin, as measured by total reflectance infrared spectroscopy.
    Type: Application
    Filed: November 2, 2011
    Publication date: May 17, 2012
    Inventors: Naohiro WATANABE, Tsuyoshi Sugimoto, Shlnya Hanatanl, Mamru Hozumi, Osamu Uchinokura
  • Patent number: 8178269
    Abstract: Emulsion aggregation toner particles including a resin, polysaccharide particles, an optional wax, and an optional colorant. The toner particles contain about 1 to about 50 wt % polysaccharide particles based on the total weight of the toner particles.
    Type: Grant
    Filed: March 5, 2010
    Date of Patent: May 15, 2012
    Assignee: Xerox Corporation
    Inventors: Ke Zhou, Guerino G. Sacripante, Paul Joseph Gerroir, Edward Graham Zwartz, Michael S. Hawkins
  • Publication number: 20120107737
    Abstract: Toner particles are provided which may, in embodiments, include a core and a shell formed in situ. The resins utilized to form the core, the shell, or both, may be contacted with a water soluble initiator. The resin, in embodiments present in the shell, cross-links at a temperature near the temperature for coalescence, and may prevent a crystalline resin in the core from migrating to the toner surface.
    Type: Application
    Filed: January 6, 2012
    Publication date: May 3, 2012
    Applicant: XEROX CORPORATION
    Inventors: Ke Zhou, Edward G. Zwartz, Karen Ann Moffat
  • Patent number: 8168361
    Abstract: An emulsion aggregation toner composition includes toner particles including: an amorphous polyester resin; an optional crystalline resin; an optional colorant; an optional wax; an optional coagulant; and a polymeric or oligomeric hydroxy ketone photo initiator capable of initiating crosslinking of said polyester resin, wherein at least one of the amorphous polyester resin and the optional crystalline resin when present is unsaturated.
    Type: Grant
    Filed: October 15, 2009
    Date of Patent: May 1, 2012
    Assignee: Xerox Corporation
    Inventors: Ke Zhou, Daryl W. Vanbesien, Edward G. Zwartz, Guerino G. Sacripante, Karen A. Moffat
  • Publication number: 20120100476
    Abstract: The present invention relates to a pressure fixing toner which can be fixed at a lower temperature to enable energy-efficient high-speed printing, and a preparation method thereof. The pressure fixing toner comprises: a core which comprises a wax mixture including a wax and a pigment; and a shell which comprises a polymer or copolymer of at least one kind of polymerizable monomer selected from the group consisting of an aromatic vinyl-based monomer, an acrylate-based monomer, a methacrylate-based monomer and a diene-based monomer, and surrounds the core. The content of the wax of the core is 44-93 parts by weight based on 100 parts by weight of the total toner.
    Type: Application
    Filed: June 16, 2010
    Publication date: April 26, 2012
    Applicant: LG CHEM, LTD.
    Inventors: Wook Jang, Chang-Soon Lee