Dry Toner Having Chemically Identified Binder Patents (Class 430/109.1)
  • Publication number: 20130244164
    Abstract: A toner having toner particles, each of which contains a binder resin, a wax and inorganic fine particles, wherein the inorganic fine particles are fixed at the surface of the toner particles as a result of a surface treatment by hot air, and the degree of uneven distribution of wax in the toner is controlled in a depth direction of the toner, from the toner surface towards a toner central portion.
    Type: Application
    Filed: November 24, 2011
    Publication date: September 19, 2013
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Hiroyuki Fujikawa, Kunihiko Nakamura, Nozomu Komatsu, Kosuke Fukudome, Yoshiaki Shiotari, Takayuki Itakura
  • Publication number: 20130244169
    Abstract: To provide a toner, which contains: a binder resin; a colorant; and wax, wherein the toner has Ta of 30° C. to 55° C., and Tb—Ta of 8° C. to 25° C., where Ta is a glass transition temperature of the toner determined from a constant heating component of a DSC curve of the toner obtained in a second heating process of temperature modulated differential scanning calorimetry, and Tb is a glass transition temperature of the toner determined from a constant heating component of a DSC curve of the toner obtained in a first heating process of temperature modulated differential scanning calorimetry.
    Type: Application
    Filed: November 2, 2011
    Publication date: September 19, 2013
    Inventors: Azumi Miyaake, Hideki Sugiura, Yuka Mizoguchi
  • Patent number: 8530128
    Abstract: The present invention relates to a polymerized toner including a low molecular weight polymer having a weight average molecular weight of 3000 to 30,000 and a method for preparing the same, wherein the polymerized toner can realize excellent gloss and offset feature and can also can exhibit excellent performance in the applications of high speed copying, development of transferred photos, etc.
    Type: Grant
    Filed: February 23, 2011
    Date of Patent: September 10, 2013
    Assignee: LG Chem, Ltd.
    Inventors: Wook Jang, Chang-Soon Lee
  • Patent number: 8530125
    Abstract: An aspect of the invention provides a developer that comprises first charged particles and second charged particles that have smaller charge than the first charged particles, or that are charged opposite to the first charged particles. Here, the first particles are colored, while the second particles may be colorless. Alternatively, the first particles are colored, while the second particles may have approximately the same color as a medium.
    Type: Grant
    Filed: April 16, 2009
    Date of Patent: September 10, 2013
    Assignee: Oki Data Corporation
    Inventor: Kazuteru Kurihara
  • Patent number: 8530131
    Abstract: Toner particles are provided which may, in embodiments, include a core and a shell, one or both of which may include a polyester gel. The gel in the shell and/or core may prevent a crystalline resin in the core from migrating to the toner surface.
    Type: Grant
    Filed: August 27, 2008
    Date of Patent: September 10, 2013
    Assignee: Xerox Corporation
    Inventors: Ke Zhou, Karen Ann Moffat, Maria N. V. McDougall, Edward G. Zwartz, Paul J. Gerroir
  • Patent number: 8524434
    Abstract: A toner having a toner particle including a core particle obtained by polymerizing a polymerizable monomer composition containing at least a polymerizable monomer, a colorant, a release agent, a polar resin, and a crystalline polyester in an aqueous medium and an outer shell formed by fixing resin fine particles to the surface of the core particle, wherein the resin constituting the resin fine particles is an amorphous resin and the acid value of the resin fine particles is 4.0 to 50.0 mgKOH/g.
    Type: Grant
    Filed: June 9, 2011
    Date of Patent: September 3, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tsuneyoshi Tominaga, Ryoichi Fujita, Tsutomu Shimano
  • Publication number: 20130224642
    Abstract: A toner to develop an electrostatic charge image, a toner supply device employing the toner, an apparatus to form an image employing the toner, and a method of forming an image using the toner are provided. The toner includes at least a binder resin, a colorant, and a releasing agent. By using the binder resin including a combination of a reduced molar weight binder resin, an increased molar weight binder resin, and the releasing agent having an effecdtive compatibility with the binder resin together, the toner has accurately-controlled dynamic viscoelastic properties represented by a loss tangent. The toner to develop an electrostatic charge image according to an embodiment has development stability, development lifetime, fixability, charging stability, gloss, an anti-offset property, and heat storage ability at predetermined levels or higher.
    Type: Application
    Filed: February 27, 2013
    Publication date: August 29, 2013
    Applicant: SAMSUNG ELECTRONICS CO., LTD.
    Inventor: Samsung Electronics Co., Ltd.
  • Patent number: 8518625
    Abstract: An electrostatic image developing toner including toner core particles each containing at least a first resin and a colorant, and fine resin particles formed of a second resin, wherein part of each of the fine resin particles is embedded in each of the toner core particles, and the remaining part of the fine resin particle is exposed on a surface of the toner core particle to form a protrusion, and wherein when a rate of the part of the fine resin particle to the fine resin particle is indicated by an embedment rate, an average of the embedment rates in the fine resin particles is 40% to 80%.
    Type: Grant
    Filed: May 23, 2011
    Date of Patent: August 27, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Tomohiro Fukao, Takuya Kadota, Chieko Yamazaki, Yoshihiro Mikuriya, Tsuyoshi Nozaki, Yoshimichi Ishikawa, Atsushi Yamamoto, Kazuoki Fuwa, Tomoharu Miki
  • Patent number: 8518621
    Abstract: A toner for electrostatic image development containing a resin binder, a negatively chargeable charge control agent, and a positively chargeable charge control agent, wherein the resin binder contains at least one polyester, wherein a carboxylic acid component of the polyester contains isophthalic acid and/or an ester thereof and fumaric acid and/or an ester thereof, provided that if two or more polyesters are used, the carboxylic acid component is taken as an overall component, and wherein the negatively chargeable charge control agent contains a metal-containing azo dye and/or a metal complex of salicylic acid, and wherein the toner has a softening point of from 90° to 120° C. The toner for electrostatic image development of the present invention can be suitably used in developing latent images formed in, for example, electrophotography, an electrostatic recording method, an electrostatic printing method, or the like.
    Type: Grant
    Filed: January 19, 2010
    Date of Patent: August 27, 2013
    Assignee: Kao Corporation
    Inventors: Satoshi Kunii, Masahito Yamazaki, Yoshihiro Fukushima
  • Patent number: 8518622
    Abstract: A toner containing a binder resin, a colorant, and a releasing agent, wherein the colorant contains a mixed crystal of a C. I. PIGMENT YELLOW 185 and a C. I. PIGMENT YELLOW 139, and wherein a mass ratio of the C. I. PIGMENT YELLOW 185 to the C. I. PIGMENT YELLOW 139 (mass of the C. I. PIGMENT YELLOW 185/mass of the C. I. PIGMENT YELLOW 139) in the toner is 95/5 to 50/50.
    Type: Grant
    Filed: June 14, 2011
    Date of Patent: August 27, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Satoshi Ogawa, Daisuke Inoue, Daisuke Ito, Osamu Uchinokura, Junichi Awamura, Teruki Kusahara, Satoshi Kojima, Mamoru Hozumi, Shoko Sato
  • Publication number: 20130216944
    Abstract: A toner contains a binder resin, a colorant, and a releasing agent, wherein the toner contains toner particles, and wherein a proportion of the toner particles containing one or more voids having diameters D1 of larger than 0.0 ?m but 0.5 ?m or smaller is more than 5.0% to 60%, and a proportion of the toner particles containing one or more voids having diameters D2 of 1.0 ?m or larger is 10% or less.
    Type: Application
    Filed: October 18, 2011
    Publication date: August 22, 2013
    Inventors: Masana Shiba, Ryuta Chiba, Tsuneyasu Nagatomo
  • Patent number: 8512926
    Abstract: The invention provides an electrophotographic toner having a crystalline polyester resin; a non-crystalline polyester resin; a colorant; and a releasing agent. A resin (i), that is included in a toluene-soluble component of the toner and having a molecular weight of 30,000 to 100,000 as measured by gel permeation chromatography relative to polystyrene standards, has an acid value A. A resin (ii), that is included in a toluene-soluble component of the toner and having a molecular weight of 8,000 to 12,000 as measured by gel permeation chromatography relative to polystyrene standards, has an acid value B. A resin (iii), that is included in a toluene-insoluble component of the toner, has an acid value C. The acid values A, B, and C satisfy the inequation of B>A>C. The invention further provides an electrophotographic developer using the toner, a toner cartridge storing the toner, and an image forming method using the developer.
    Type: Grant
    Filed: March 12, 2008
    Date of Patent: August 20, 2013
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Katsumi Daimon, Yutaka Sugizaki, Susumu Yoshino, Hiroshi Nakazawa
  • Publication number: 20130196260
    Abstract: A toner including: a binder resin containing a non-crystalline resin and a crystalline resin; a colorant; and, a releasing agent, wherein the releasing agent has a melting point of 55° C. to 80° C., and wherein the toner satisfies the following Expressions 1 and 2: (Expression 1): 20,000 Pa·s?G1?50,000 Pa·s; and (Expression 2): (G4/G2)/(G3/G1) 1.00, where G1 is a storage modulus, G2 is a loss modulus, G3 is a storage modulus and G4 is a loss modulus, and the storage modulus G1 and the loss modulus G2 are measured at 80° C. when the toner is heated from 70° C. to 150° C. and the storage modulus G3 and the loss modulus G4 are measured at 80° C. when the toner heated to 150° C. is cooled to 70° C.
    Type: Application
    Filed: December 28, 2012
    Publication date: August 1, 2013
    Inventors: Ryuuta YOSHIDA, Takahiro HONDA, Junichi AWAMURA, Osamu UCHINOKURA, Masaki WATANABE, Daisuke INOUE, Tomoki MURAYAMA, Mamoru HOZUMI
  • Publication number: 20130196264
    Abstract: A decolorizable electrophotographic toner, including: toner particles, the toner particle comprising a binder resin; and colorant particles which contain an electron donating color developable agent, an electron accepting color developing agent, and a decolorizing temperature control agent, and have a capsule structure coated with an outer shell, wherein the ratio of an total exposed areas of the colorant particles to the total projected areas of the toner particles calculated on the basis of scanning electron microscope (SEM) observation of the toner is 5.0% or less.
    Type: Application
    Filed: March 14, 2013
    Publication date: August 1, 2013
    Applicant: TOSHIBA TEC KABUSHIKI KAISHA
    Inventor: Toshiba Tec Kabushiki Kaisha
  • Patent number: 8497056
    Abstract: A magenta toner characterized by satisfying, in DSC measurement, 40.0?Tg(0.5)?60.0 and 2.0?Tg(4.0)?Tg(0.5)?10.0, wherein when preparing a solution of which the magenta toner is dissolved in ethyl acetate, and defined the concentration of the thereof as Cm1 (mg/ml), and the light absorbance thereof at a wavelength of 538 nm as A(ethyl acetate)538, the ratio of A(ethyl acetate)538 to Cm1 satisfies the formula, A(ethyl acetate)538/Cm1<0.15, and, when preparing a solution of which the magenta toner is dissolved in chloroform, and defined the concentration of the thereof as Cm2 (mg/ml), and the light absorbance thereof at a wavelength of 538 nm as A(chloroform)538, the ratio of A(chloroform)538 to Cm2 satisfies the formula, 2.00<A(chloroform)538/Cm2<6.55.
    Type: Grant
    Filed: February 19, 2010
    Date of Patent: July 30, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Ayako Sekikawa, Takaaki Kaya, Atsushi Tani, Shigeto Tamura
  • Publication number: 20130183616
    Abstract: A decolorable electrophotographic toner, containing a color former compound, a color developing agent, a binder resin, and a release agent, wherein the toner has a pH of from 6 to 9 when dispersed in water with a pH of from 5.5 to 7 at a mass ratio of toner/water of 1/10.
    Type: Application
    Filed: February 26, 2013
    Publication date: July 18, 2013
    Applicants: TOSHIBA TEC KABUSHIKI KAISHA, KABUSHIKI KAISHA TOSHIBA
    Inventors: Kabushiki Kaisha Toshiba, Toshiba Tec Kabushiki Kaisha
  • Patent number: 8486597
    Abstract: A toner including an amorphous resin (R), a crystalline material (A) which is compatible with the amorphous resin (R) and has a melting point of 80° C. or lower, a resin (I) which is different from the amorphous resin (R), and a colorant, wherein the crystalline material (A) is capsulated by the resin (I) and the capsulated crystalline material (A) is present in the amorphous resin (R).
    Type: Grant
    Filed: April 5, 2011
    Date of Patent: July 16, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Atsushi Yamamoto, Takuya Kadota, Masayuki Hagi
  • Patent number: 8470506
    Abstract: The toner includes at least a binder resin, and a colorant. The toner has properties such that the percentage W(3000) of components having a molecular weight of 3,000 or less in tetrahydrofuran-soluble components of the toner determined by a GPC-RALLS viscosity analysis is 20% by weight or less; the molecular weight Mp at the peak top of the main peak in the molecular weight distribution curve of the tetrahydrofuran-soluble components is from 4,000 to 10,000; and the ratio Rt(Mp)/Rs(Mp) of an inertia square radius Rt(Mp) at the molecular weight Mp to an inertia square radius Rs(Mp) of linear polystyrene at the molecular weight Mp is greater than 0.98, wherein the inertia square radius Rs(Mp) is determined from a working curve obtained by subjecting plural polystyrenes having different molecular weights to the GPC-RALLS viscosity analysis.
    Type: Grant
    Filed: September 8, 2009
    Date of Patent: June 25, 2013
    Assignee: Ricoh Company, Limited
    Inventor: Atsushi Yamamoto
  • Publication number: 20130157183
    Abstract: A developer, including a toner including a binder resin comprising a crystalline resin; and a colorant, and a resin carrier comprising a resin; a magnetic particulate material having a magnetic anisotropy, dispersed in the resin, and having a saturated magnetization of from 16 to 30 emu/g, a coercive force of from 15 to 40 kA/m and an average particle diameter not less than 15 ?m and less than 100 ?m.
    Type: Application
    Filed: November 16, 2012
    Publication date: June 20, 2013
    Inventors: Hideyuki Santo, Masahide Yamada, Kazumi Suzuki, Shinya Nakayama, Atsushi Yamamoto, Tatsuya Morita, Shingo Sakashita, Yukiko Nakajima, Keiji Makabe, Daiki Yamashita
  • Patent number: 8460847
    Abstract: The present invention relates to a toner for electrophotography including a polyester obtained by subjecting a crystalline polyester-containing aqueous dispersion and a non-crystalline polyester-containing aqueous dispersion to aggregation and coalescence, as a resin binder, wherein the crystalline polyester is produced by polycondensing an alcohol component containing 70 mol % or more of an aliphatic diol having 2 to 8 carbon atoms with a carboxylic acid component containing 50 mol % or more of terephthalic acid. The toner is excellent in low-temperature fusing ability and pressure storage stability.
    Type: Grant
    Filed: August 14, 2009
    Date of Patent: June 11, 2013
    Assignee: Kao Corporation
    Inventors: Eiji Shirai, Takashi Kubo, Hiroshi Mizuhata, Shoichi Murata
  • Patent number: 8450040
    Abstract: A method of making toner particles, including mixing at least one emulsion of at least one resin, a colorant, an optional wax, and optional additives to form a slurry; heating the slurry to form aggregated particles in the slurry; freezing aggregation of the particles with a buffer solution; and heating the aggregated particles in the slurry to coalesce the particles into toner particles.
    Type: Grant
    Filed: October 22, 2009
    Date of Patent: May 28, 2013
    Assignee: Xerox Corporation
    Inventors: Kimberly D. Nosella, Allan K. Chen, Abdisamed Sheik-Qasim, Melanie L. Davis, Zhen Lai
  • Publication number: 20130130165
    Abstract: Provided is a toner comprising toner particles, wherein each of the toner particles has a core-shell structure composed of a core and a shell phase formed on the core, the shell phase contains a resin (B), and the core contains a binder resin (A), a colorant and a wax, wherein the toner particles contain the resin (B) in a specific amount with respect to the core, and wherein the solubility parameter (SP value) of the binder resin (A) is denoted by SP(A), the SP value of the resin (B) is denoted by SP(B), the SP value of a repeating unit with the smallest SP value from among repeating units constituting the resin (B) is denoted by SP(C), and the SP value of the wax is denoted by SP(W), each of the SP(A), SP(B), SP(C) and SP(W) satisfy specific relationships.
    Type: Application
    Filed: January 14, 2013
    Publication date: May 23, 2013
    Applicant: CANON KABUSHIKI KAISHA
    Inventor: Canon Kabushiki Kaisha
  • Publication number: 20130130170
    Abstract: Provided is a toner having an excellent low-temperature fixability and hot offset resistance, a broad fixing temperature latitude in low-temperature areas to high-temperature areas, and a high heat-resistant storage stability. The toner includes toner particles having a core-shell structure in which a shell phase containing a resin A is formed on a core containing a binder resin, a colorant and a wax. In measurement of resin A by a differential scanning calorimetry (DSC), the peak temperature TpA (° C.) of a maximum endothermic peak in the first temperature rise is at least 55° C. but not more than 80° C. In measurement of a viscoelasticity of resin A, the loss elastic modulus at TpA?10 (° C.) is at least 1×107 Pa but not more than 1×108 Pa. In measurement of the viscoelasticity of resin A, the loss elastic moduli at TpA (° C.), TpA+10 (° C.) and TpA+25 (° C.) satisfy specific conditions.
    Type: Application
    Filed: January 14, 2013
    Publication date: May 23, 2013
    Applicant: CANON KABUSHIKI KAISHA
    Inventor: Canon Kabushiki Kaisha
  • Publication number: 20130130168
    Abstract: Provided is a toner containing toner particles, each of which includes a binder resin containing a polyester as a main component, a colorant, and a wax, in which the binder resin includes a block polymer in which a segment capable of forming a crystalline structure and a segment incapable of forming a crystalline structure are bonded, the toner has a maximum endothermic peak from the binder resin, as determined by differential scanning calorimetry measurement, with a peak temperature in a specific range and with an endothermic quantity in a specific range, and the wax is an ester wax having a functionality of 3 or more.
    Type: Application
    Filed: January 14, 2013
    Publication date: May 23, 2013
    Applicant: CANON KABUSHIKI KAISHA
    Inventor: Canon Kabushiki Kaisha
  • Patent number: 8440379
    Abstract: The present disclosure is drawn to a liquid electrophotographic ink, comprising a carrier liquid, and a pigment-polymer blend composition dispersed in the carrier liquid, the pigment-polymer blend composition comprising a pigment and a polymer blend of three distinct polymers. The polymer blend can comprise a first polymer having a melt flow rate of about 20 to about 70 g/10 min and a Vicat softening point of about 60° C. to about 70° C., a second polymer having a melt flow rate of about 80 to about 120 g/10 min, and a third polymer having an acidity of about 160 to about 230 mg KOH/g and a melt flow rate of at least 500 g/10 min. The liquid electrophotographic ink is typically formulated for printing from a liquid electrophotographic printer.
    Type: Grant
    Filed: June 10, 2008
    Date of Patent: May 14, 2013
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Stella Stolin Roditi, Albert Teishev, Keren Regev, Yael Warman
  • Patent number: 8440378
    Abstract: An electrostatic image developing toner includes a binding resin and a release agent, wherein an organic silicon compound including a siloxane bond is present in a domain of the release agent.
    Type: Grant
    Filed: August 24, 2010
    Date of Patent: May 14, 2013
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Masaru Takahashi, Shinya Nakashima, Shuji Sato
  • Patent number: 8435711
    Abstract: A toner comprising toner particles which comprise binder resin and colorant, wherein the binder resin is made from latexes which comprise a low molecular weight (LMW) latex of resin particles having a weight average molecular weight (Mw) less than 50,000 and a medium molecular weight (MMW) latex of resin particles having a Mw from 50,000 to 500,000, wherein the glass transition temperature (Tg) of the resin particles of the LMW latex is not greater than 52° C.
    Type: Grant
    Filed: October 21, 2008
    Date of Patent: May 7, 2013
    Assignee: Fujifilm Imaging Colorants Limited
    Inventors: Daniel Patrick Morris, John Dylan Morgan, Martin Russell Edwards
  • Patent number: 8431298
    Abstract: Provided are a toner and a toner manufacturing method with which high image density and a broad range of color reproduction are obtained, and with which high-quality images are also obtained. The toner is composed of toner particles that comprise a binding resin containing a polyester resin and a colorant, and contains 10-1,500 ppm of a metal element selected from titanium, germanium, and aluminum, and a cyclic phenol sulfide represented by general formula (1) selected from thiacalixarene, sulfinyl thiacalixarene and sulfonyl thiacalixarene.
    Type: Grant
    Filed: June 26, 2009
    Date of Patent: April 30, 2013
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Masahiro Anno, Masahiko Nakamura, Tsuyoshi Uchida, Kouichi Sugama, Kenichi Onaka, Junya Onishi
  • Patent number: 8431304
    Abstract: A toner containing: a non-crystalline polyester resin; a crystalline polyester resin; a releasing agent; a graft-modified polymer; and a colorant, wherein the graft-modified polymer is a polymer having a glass transition temperature of higher than 40° C. but lower than 80° C., and obtained by grafting an acrylic resin onto at least one of a hydrocarbon wax and a crystalline polyester resin, and wherein a SP value of the non-crystalline polyester resin is defined as SP1, a SP value of the crystalline polyester resin is defined as SP2, a SP value of the releasing agent is defined as SP3, and a SP value of the graft-modified polymer is defined as SP4, and SP1, SP2, SP3 and SP4 satisfy relations represented by Formulas (1) to (3): SP1 > SP4 > SP2 >SP3 Formula (1), 0.1 < SP1 ? SP4 < 1.0 Formula (2), and 0.1 < SP4 ? SP2 < 1.0 Formula (3).
    Type: Grant
    Filed: August 16, 2011
    Date of Patent: April 30, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Tsuyoshi Sugimoto, Naohiro Watanabe, Osamu Uchinokura, Tomoyuki Satoh, Shinya Hanatani, Mamoru Hozumi
  • Patent number: 8431299
    Abstract: A developer has a molecular weight distribution of its tetrahydrofuran soluble portion measured by a gel permeation chromatography. In the molecular weight distribution, the main peak is in a range from 2×103 to 3×104 weight-average molecular weight (Mw), the shoulder peak is in a range from 200 to 500 Mw, and a half-value width of the main peak is equal to or less than 50000. A glass-transition temperature Tg of the developer is a range from 55° C. to 80° C.
    Type: Grant
    Filed: February 16, 2010
    Date of Patent: April 30, 2013
    Assignee: Oki Data Corporation
    Inventor: Yuki Matsuura
  • Patent number: 8431320
    Abstract: Disclosed is a manufacturing method of toner which includes at least polyester resin and colorant, comprising the steps of: (A) dissolving, into an organic solvent, the polyester resin and ultrahigh molecular weight styrene resin in which a peak is present in a range larger than 500 thousands and smaller than 3 million in a molecular weight distribution, and preparing a binder resin solution; (B) dispersing the binder resin solution as binder resin solution droplets into an aqueous medium; (C) removing the organic solvent from the binder resin solution droplets, and preparing a resin particle dispersion; and (D) aggregating resin particles from which the organic solvent is removed and colorant particles containing the colorant with each other, and forming toner particles.
    Type: Grant
    Filed: July 20, 2011
    Date of Patent: April 30, 2013
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Masaharu Matsubara, Hiroyuki Kozuru, Noboru Ueda
  • Patent number: 8431302
    Abstract: The present disclosure provides toners having a tunable gloss level, electrophotographic apparatuses for using such toners as well as processes for making such toners.
    Type: Grant
    Filed: February 22, 2010
    Date of Patent: April 30, 2013
    Assignee: Xerox Corporation
    Inventors: Edward Graham Zwartz, T. Brian McAneney, Valerie M. Farrugia, Jordan H. Wosnick, Richard P. N. Veregin, Eric Rotberg
  • Patent number: 8431308
    Abstract: Toner for developing an electrostatic image, which satisfies charging stability, low-temperature fixability, high-temperature storage characteristics, and durability with respect to an environment up to a predetermined level or above, and a method of preparing the toner. The toner includes: a core layer including a first binder resin, a colorant, and a releasing agent; and a shell layer covering the core layer and including a second binder resin, wherein the first binder resin includes about 70 wt % or above of amorphous polyester resin and about 30 wt % or below of crystalline polyester resin, the second binder resin includes an amorphous polyester resin, and a melting temperature (Tm(C)) of the crystalline polyester resin, a melting temperature (Tm(W)) of the releasing agent, and a melting point (Tm(T)) of the toner satisfy the following conditions: ?20° C.?Tm(W)?Tm(C)?20° C.; and 0° C.<Tm(C)?Tm(T)?10° C.
    Type: Grant
    Filed: October 18, 2010
    Date of Patent: April 30, 2013
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Kyeong Pang, Jae-hwan Kim, Jin-mo Hong, Yo-da Shin, Su-bum Park, Jeong-hyun Lee, Mi-rim Cho
  • Patent number: 8431306
    Abstract: Embodiments include a toner having a polyester resin derived from diacids and diesters, in combination with at least one diol, in embodiments a cycloaliphatic diol, an optional crystalline resin, an optional colorant, and an optional wax.
    Type: Grant
    Filed: March 9, 2010
    Date of Patent: April 30, 2013
    Assignee: Xerox Corporation
    Inventors: Guerino G. Sacripante, Daryl W. Vanbesien, Biritawit Asfaw, Rosa M. Duque, Sonja Hadzidedic
  • Patent number: 8431307
    Abstract: The disclosure provides an electrographic toner having a core layer, which includes a binder, a colorant and two or more types of releasing agents, and a shell layer covering the core layer, and a method of preparing the same.
    Type: Grant
    Filed: November 2, 2010
    Date of Patent: April 30, 2013
    Assignee: SAMSUNG Electronics Co., Ltd.
    Inventors: Jae-hwan Kim, Kyeong Pang, Jin-mo Hong, Su-bum Park, Jeong-hyun Lee, Mi-rim Cho
  • Patent number: 8431321
    Abstract: There are provided a toner that allows prevention of environmental contamination and is nevertheless free from toner durability degradation, wherein a sufficiently wide color reproduction range can be secured even when it is applied to color toner, and variation in characteristics among toner particles can be suppressed, as well as a method of manufacturing a toner, a developing device, and an image forming apparatus. In the toner particle is formed the biomass resin-containing domain.
    Type: Grant
    Filed: January 11, 2012
    Date of Patent: April 30, 2013
    Assignee: Sharp Kabushiki Kaisha
    Inventor: Yasuhiro Shibai
  • Publication number: 20130095423
    Abstract: A toner for developing electrostatic images contains a binder resin, a colorant, a release agent, and a charge control agent. The release agent contains a wax having a polar group. The toner for developing electrostatic images has tan ? of 1 to 2 at a temperature of 80° C. to 145° C. as measured with a viscoelasticity measuring apparatus at a frequency of 10 Hz and a shear stress of 500 Pa, and has a breaking point of 180° C. or less in a temperature-tan ? curve.
    Type: Application
    Filed: October 15, 2012
    Publication date: April 18, 2013
    Applicant: KYOCERA DOCUMENT SOLUTIONS INC.
    Inventor: Kyocera Document Solutions Inc.
  • Publication number: 20130078562
    Abstract: An electrostatic image developing toner including: first toner particles which contain a first binder resin and a photoluminescent pigment; and second toner particles which contain a second binder resin and do not contain a photoluminescent pigment, wherein the proportion of the second toner particles is in a range from 5% by number to 80% by number with respect to a total number of all toner particles.
    Type: Application
    Filed: February 1, 2012
    Publication date: March 28, 2013
    Applicant: Fuji Xerox Co., Ltd.
    Inventors: Masaru TAKAHASHI, Shotaro TAKAHASHI, Atsushi SUGITATE, Shuji SATO
  • Patent number: 8404419
    Abstract: Provided is an electrostatic image developing toner containing, (i) toner particles containing: a binder resin having a domain-matrix structure; and (ii) a colorant; wherein the toner particles have a volume-based median diameter of 4.3 to 7.0 ?m; a domain phase in the binder resin contains a polymer containing a structure unit derived from a diene monomer, the domain phase has a Feret diameter of 50 to 300 nm; and a glass transition temperature of the polymer composing the domain phase is ?85 to +35° C.
    Type: Grant
    Filed: April 28, 2011
    Date of Patent: March 26, 2013
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Hiroyuki Konno, Kazuhiko Nakajima
  • Publication number: 20130059245
    Abstract: The present invention relates to a polymerized toner and a method for preparing the same, wherein the toner can realize an excellent offset feature, high transfer efficiency, and a uniform image and thus can exhibit excellent performances in the applications of high speed copying, development of transferred photos, etc.
    Type: Application
    Filed: February 22, 2011
    Publication date: March 7, 2013
    Applicant: LG CHEM, LTD.
    Inventors: Wook Jang, Hak-Soo Kim, Chang-Soon Lee
  • Patent number: 8389187
    Abstract: A transparent toner for electrostatic latent image developing, including a binder resin and a release agent, the difference between Tm and Tc being from about 30° C. to about 50° C., wherein Tm is an endothermic peak temperature of the release agent determined in a temperature rising process and Tc is an exothermic peak temperature of the release agent determined in a temperature decreasing process, in a measurement by a differential scanning calorimeter (DSC) according an ASTM method, and the toner having a weight average molecular weight of from about 35,000 to about 70,000.
    Type: Grant
    Filed: September 25, 2009
    Date of Patent: March 5, 2013
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yasuo Kadokura, Atsushi Sugawara, Masaru Takahashi, Yusuke Ikeda, Masanobu Ninomiya
  • Patent number: 8383309
    Abstract: A chemical toner composition that includes at least one curable amorphous resin and at least one sublimation colorant.
    Type: Grant
    Filed: November 3, 2009
    Date of Patent: February 26, 2013
    Assignee: Xerox Corporation
    Inventors: Yulin Wang, Ke Zhou, Edward G. Zwartz, T. Hwee Ng
  • Patent number: 8383310
    Abstract: The present disclosure relates to a binder resin system suitable for use in forming toner compositions. In embodiments, the binder resin system includes at least one amorphous resin, at least one crystalline resin, and at least one fatty acid salt. The presence of the fatty acid salt reduces plasticization which may otherwise occur upon combining the amorphous and crystalline resins, thereby increasing the glass transition temperature of the binder resin, as well as any toner produced with such binder resin. Toners produced with the disclosed binder resin may also include one or more optional ingredients such as optional colorants, optional waxes, and combinations thereof.
    Type: Grant
    Filed: April 27, 2010
    Date of Patent: February 26, 2013
    Assignee: Xerox Corporation
    Inventors: Mark E. Mang, Timothy L. Lincoln
  • Patent number: 8377618
    Abstract: A toner is provided including a mother toner including a crystalline polyester resin, an amorphous resin, and a wax, and an external additive in an amount of from 0.30 to 0.55 parts by weight based on 100 parts by weight of the mother toner. The toner satisfies the following equation 0.36?(2.77×C/R+1.97×W/R)/X?1.85, wherein each of C, W, and R represents a height of an absorbance peak specific to the crystalline polyester resin, the wax, and the amorphous resin, respectively, measured by a FT-IR ATR method, and X represents an amount (parts by weight) of the external additive. An image forming method and apparatus using the toner are also provided.
    Type: Grant
    Filed: September 15, 2008
    Date of Patent: February 19, 2013
    Assignee: Ricoh Company Limited
    Inventors: Hyo Shu, Yasuaki Iwamoto, Yasutada Shitara, Minoru Masuda
  • Patent number: 8372569
    Abstract: A toner is provided including toner particles A having a circularity of greater than 0.93 and not greater than 1.00 and toner particles B having a circularity of from 0.85 to 0.93, wherein the following relationships are satisfied: 70?RA?95, 5?RB?30, 0.014?SD?0.025, and 0.940?ED?0.950, wherein RA (% by number) represents a ratio of a number of the toner particles A to a total number of toner particles included in the toner, RB (% by number) represents a ratio of a number of the toner particles B to the total number of toner particles included in the toner, SD represents a standard deviation of circularity of the toner particles A, and ED represents an average envelope degree of the toner particles B.
    Type: Grant
    Filed: November 9, 2007
    Date of Patent: February 12, 2013
    Assignees: Ricoh Company, Ltd., Xeikon Manufacturing N.V.
    Inventors: Hideyuki Yamaguchi, Hachiroh Tosaka, Tomoyuki Satoh
  • Publication number: 20130034808
    Abstract: A pulverizer including a solid-gas mixer to mix a compressed gas and particles of a raw material to be pulverized to prepare a solid-gas mixture; a particle path controlling nozzle connected with the solid-gas mixer to feed the solid-gas mixture fed from the solid-gas mixer while accelerating the solid-gas mixture and controlling the particles of the raw material so as to choose different flow paths based on particle diameters of the particles of the raw material; a collision member; and an accelerating tube connected with the particle path controlling nozzle to further accelerate the solid-gas mixture fed from the particle path controlling nozzle while maintaining the flow paths of the particles and ejecting the accelerated solid-gas mixture toward the collision member to pulverize the raw material.
    Type: Application
    Filed: July 24, 2012
    Publication date: February 7, 2013
    Inventor: Keisuke YAGOME
  • Patent number: 8367292
    Abstract: A toner including a binder resin, a coloring agent, and a releasing agent, the toner formed by dispersing a toner liquid material which is prepared by dispersing the binder resin, the prepolymer, an elongation agent and/or a cross-linking agent for the prepolymer, the coloring agent, and the releasing agent in an organic solvent, dispersing the toner liquid material in an aqueous medium to obtain a liquid dispersion in at least one of cross linking reaction and elongation reaction, and removing the organic solvent from the liquid dispersion, and the toner satisfying the following relationship: 1.35< or =M(g)/M(p)< or =1.90, where M(g) represents the content of the gel composition formed in the at least one of cross linking reaction and elongation reaction and M(P) represents the content of the prepolymer in the toner liquid material when the total of M(P) and the content of the binder resin in the toner liquid material is set to be 100 g.
    Type: Grant
    Filed: February 19, 2010
    Date of Patent: February 5, 2013
    Assignee: Ricoh Company, Limited
    Inventors: Teruki Kusahara, Junichi Awamura, Tomomi Suzuki, Toshihiko Karato
  • Publication number: 20130029261
    Abstract: The present invention relates to a polymerized toner prepared by suspension polymerization. In particular, the polymerized toner comprises a plurality of toner particles that each comprising a binder resin, a pigment, a pigment stabilizer, a charge control agent, and a wax. The polymerized toner maintains a ratio of toner particles containing at least two wax domains per particle within a defined range. Thereby, the polymerized toner achieves high glossiness and good transfer efficiency.
    Type: Application
    Filed: July 26, 2012
    Publication date: January 31, 2013
    Applicant: LG CHEM, LTD.
    Inventors: Wook JANG, Chang-Soon LEE, Woo-Cheul JUNG, Joo-Yong PARK
  • Publication number: 20130029257
    Abstract: The present invention relates to a thermochromic color-memory toner containing: a microcapsule pigment encapsulating a thermochromic color-memory composition; and a binder resin, in which the microcapsule pigment shows a hysteresis characteristic that, in a temperature-rise process, decoloration starts when the temperature reaches t3 and the pigment completely reaches a decolored state in a temperature region of t4 or higher, and in a temperature-drop process, coloration starts when the temperature reaches t2 and the pigment completely reaches a colored state in a temperature region of ti or lower, and ti is in a range of from ?50 to 0° C. and t4 is in a range of from 50 to 150° C.
    Type: Application
    Filed: November 13, 2009
    Publication date: January 31, 2013
    Applicant: THE PILOT INK CO., LTD.
    Inventors: Katsuyuki Fujita, Yoshiaki Ono, Yutaka Shibahashi
  • Publication number: 20130029260
    Abstract: A toner including: a core particle; and fine resin particles, the core particle containing at least a binder resin, a releasing agent and a colorant, wherein the toner is in shape of particles, and each toner particle has a sea-island structure having the core particle and island portions, which are convex portions formed from the fine resin particles on surface of the core particle, wherein the binder resin contains first and second resins, and the fine resin particles are made of third resin, wherein the first resin is crystalline resin, and the second and third resins are non-crystalline resin, wherein the second resin has glass transition temperature (Tg2) and the crystalline resin has melting point (Tc1) where Tg2 is higher than Tc1, and wherein the third resin has glass transition temperature (Tg3) and the toner has glass transition temperature (Tgt) wherein Tg3 is higher than Tgt.
    Type: Application
    Filed: July 25, 2012
    Publication date: January 31, 2013
    Inventors: Tsuyoshi NOZAKI, Tomoharu Miki, Tomohiro Fukao, Kazuoki Fuwa, Yoshimichi Ishikawa, Yoshihiro Mikuriya, Takuya Kadota