Dry Toner Having Chemically Identified Binder Patents (Class 430/109.1)
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Patent number: 7498113Abstract: Provided are a toner for developing an electrostatic image comprising a crystalline resin having an ester bond and at least one of a sulfide bond or a disulfide bond in the main-chain, an electrostatic image developer and an image-forming process by using the same, a method of producing the toner for developing electrostatic image, and a resin particle dispersion using the same.Type: GrantFiled: October 6, 2005Date of Patent: March 3, 2009Assignee: Fuji Xerox Co., Ltd.Inventors: Yasuo Matsumura, Takashi Imai, Katsumi Daimon, Shuji Sato, Yusuke Ikeda, Yosuke Tsurumi, Hiroshi Nakazawa, Kazufumi Tomita, Shigeru Hayashi, Moegi Iguchi
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Patent number: 7494755Abstract: A method for forming toner particles includes polymerizing monomers to form a latex comprising polymer particles; combining the latex with unsaturated curable resin to form aggregates containing the polymer particles and the unsaturated curable resin particles; and heating the aggregates to form coalesced particles. A toner composition that may be formed by the process described herein contains toner particles containing polymer containing photoinitiator and unsaturated curable resin. Another toner composition that may be formed by the process described herein contains toner particles containing unsaturated curable resin and, on the surface of the toner particles, photoinitiator.Type: GrantFiled: November 30, 2005Date of Patent: February 24, 2009Assignee: Xerox CorporationInventors: Daryl W. Vanbesien, Jennifer Lynne Belelie, Peter Gordon Odell, Christine Deborah Anderson, Cuong Vong, David J. Sanders, Aleksey Tabachnik
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Patent number: 7488562Abstract: Provided are an electrophotographic toner, comprising a binder resin containing a coloring agent, a crystalline resin and an amorphous resin, wherein the crystalline resin has two or more peaks in weight-average molecular weight as determined by gel permeation chromatography, one of the peaks has a weight-average molecular weight in the range of 15,000 to 40,000, and another peak has a weight-average molecular weight in the range of 2,000 to 10,000 and a production method thereof, and an electrophotographic developer and an image-forming process using the electrophotographic toner.Type: GrantFiled: December 13, 2005Date of Patent: February 10, 2009Assignee: Fuji Xerox Co., Ltd.Inventors: Katsumi Daimon, Shuji Sato, Shigeru Hayashi, Yosuke Tsurumi, Yusuke Ikeda, Hiroshi Nakazawa
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Publication number: 20090035684Abstract: An image forming method is disclosed, which includes steps of cleaning toner remaining on a photoreceptor surface by a cleaning blade which is arranged on counter direction to rotation direction of the photoreceptor, supplying a fatty acid metal salt onto the photoreceptor surface after the cleaning, spreading the supplied fatty acid metal salt on the photoreceptor surface by using a spreading blade which is arranged on trail direction to rotation direction of the photoreceptor, charging the photoreceptor by a charging member, exposing the photoreceptor to form a latent image, developing the latent image by a developer to form a toner image on the photoreceptor, and transferring the toner image onto an image receiving member by a transfer roller facing to the photoreceptor through the image receiving material, in which the toner comprises a binder resin and a colorant, in which the toner has a glass transition point of from 20 to 45° C.Type: ApplicationFiled: July 7, 2008Publication date: February 5, 2009Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.Inventors: Yoshiyasu MATSUMOTO, Kenji YAMANE, Hiroyuki KOZURU
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Publication number: 20090029279Abstract: A toner is provided which is capable of preventing a decrease in a toner charge amount and thus preventing fog and a decrease in image density even in a case where images of low coverage are continuously printed or where a printing operation restarts immediately after long suspension of operation in an image forming apparatus. The toner contains coloring resin particles formed of a boron compound, a hinder resin, and a colorant, and an external additive of which a primary particle is adjusted to have a size of 16 nm or more and 30 nm or less and of which a volume resistivity is adjusted to 1×1012 ?·cm or more and 5×1015 ?·cm or less.Type: ApplicationFiled: July 15, 2008Publication date: January 29, 2009Inventors: Takamichi Mori, Takeshi Katoh, Takeshi Tsukiyama
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Publication number: 20090011355Abstract: There are provided a toner that allows prevention of environmental contamination and is nevertheless free from toner durability degradation, wherein a sufficiently wide color reproduction range can be secured even when it is applied to color toner, and variation in characteristics among toner particles can be suppressed, as well as a method of manufacturing a toner, a developing device, and an image forming apparatus. In the toner particle is formed the biomass resin-containing domain.Type: ApplicationFiled: July 7, 2008Publication date: January 8, 2009Inventor: Yasuhiro SHIBAI
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Publication number: 20090003885Abstract: A toner including a colorant and a binder resin is provided. The binder resin includes a first resin comprising a block X comprising a resin comprising a racemic mixture of optically active monomers of a D-form compound and an L-form compound, and a block Y comprising another resin. The weight ratio of the D-form compound to the L-form compound is from 48/52 to 52/48, and the weight ratio of the block Y to the block X is from 1/3 to 3/1. The toner is obtained by dispersing or emulsifying a toner constituent liquid, in which the colorant and the binder resin are dissolved or dispersed in an organic solvent, in an aqueous medium.Type: ApplicationFiled: June 27, 2008Publication date: January 1, 2009Inventors: Akiyoshi Sabu, Akihiro Kotsugai, Shinya Nakayama, Hiroshi Yamashita, Yoshihiro Moriya
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Publication number: 20080299476Abstract: The present disclosure relates to a method of forming a toner composition, and to a toner composition, that has a controlled particle size distribution, wherein the particle size distribution may be controlled by adjusting the concentration of a charge control additive in a chemical process of toner manufacture. The toner may therefore have a controlled amount of toner particles having diameters of less than or equal to about 4.0 microns. The toner may therefore provide improved resistance to filming on a given printer component.Type: ApplicationFiled: June 4, 2007Publication date: December 4, 2008Inventors: Danielle Renee Ashley, James Robert Combes, John Joseph Earley, Lale Gokbudak Lovell, George Pharris Marshall, Walter Mychajlowskij, Tao Yu
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Publication number: 20080268363Abstract: The present invention is toner particle that includes a binder resin and nonionic organic polymer particles. The particle has porosity.Type: ApplicationFiled: April 24, 2007Publication date: October 30, 2008Inventors: Mridula Nair, Xiqiang Yang, Tamara K. Jones, James G. Popowych
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Publication number: 20080268364Abstract: According to embodiments illustrated herein, there is provided a black toner having a resin, an optional additive, and at least two or more colored pigments, and the at least two or more colored pigments are selected from the group consisting of a blue pigment, a green pigment, a red pigment, a magenta pigment, a cyan pigment, a yellow pigment, a white pigment, and mixtures thereof, and the black toner has a calorimetric value L* of about less than 30.Type: ApplicationFiled: April 24, 2007Publication date: October 30, 2008Applicant: Xerox CorporationInventors: Mark Scheuer, Mark Petrush, James Winters, John Ianni, Julia Kohlmeier, William Hollenbaugh, Kip Jugle, Jeffrey McEwen
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Publication number: 20080254268Abstract: A color toner for electro printing, whereby a ceramic color print excellent in adhesion can be printed on a glass plate surface by a simple process without using a screen plate. The color toner for electro printing comprises toner matrix particles containing from 10 to 50 parts by mass of fine inorganic pigment particles, from 5 to 40 parts by mass of a heat decomposable binder resin having a disappearance temperature T100 of from 350 to 575° C., and from 40 to 85 parts by mass of glass frit, per 100 parts by mass of the total solid content of the toner matrix particles.Type: ApplicationFiled: April 2, 2008Publication date: October 16, 2008Applicant: ASAHI GLASS COMPANY LIMITEDInventors: Naoki Okahata, Satoshi Kashiwabara, Kazuo Sunahara
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Patent number: 7432032Abstract: To provide a toner production process in which at least radically polymerizable monomers are polymerized in at least one of a supercritical fluid and a subcritical fluid to thereby produce toner particles, wherein a polymer of the radically polymerizable monomers is insoluble in at least one of the supercritical fluid and the subcritical fluid.Type: GrantFiled: February 12, 2008Date of Patent: October 7, 2008Assignee: Ricoh Company, Ltd.Inventors: Chiaki Tanaka, Masayuki Ishii
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Publication number: 20080241726Abstract: Employed are a resin-filled ferrite carrier for an electrophotographic developer filled with a resin in voids of a porous ferrite core material, wherein the resin filled in the voids is a silicone resin which has a softening point of 40° C. or above and is cured at or above such softening point, and the filled amount is 7 to 30 parts by weight based on 100 parts by weight of the core material, a method for producing thereof band an electrophotographic developer using this ferrite carrier.Type: ApplicationFiled: March 4, 2008Publication date: October 2, 2008Applicant: POWDERTECH CO., LTD.Inventors: Hiromichi KOBAYASHI, Takao SUGIURA
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Publication number: 20080220359Abstract: Disclosed herein are toner particles generated by emulsion/aggregation processes. The processes are conducted under conditions that shorten the time for coalescence and post-formation washing, thereby increasing efficiency of the processes as compared to conventional processes.Type: ApplicationFiled: March 6, 2007Publication date: September 11, 2008Applicant: XEROX CORPORATIONInventors: Amgad W. SIFAIN, Emily L. MOORE, Anthony UTTARO, Peter V. NGUYEN, Jon T. OWENS, Ryan ACCETTA, Karen A. MOFFAT, Vladislav SKOROKHOD, Cuong VONG, Wafa F. BASHIR, Richard P. N. VEREGIN, Shigang S. QIU
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Patent number: 7416827Abstract: Ultra low melt toner compositions with improved non-additive heat cohesion are disclosed. These toner compositions include toner particles comprising amorphous resins containing at least one unsaturated moiety, and when the toner particles are surface treated with a peroxy compound and optionally with a peroxy promoter compound, the surface of the toner particles is cross-linked to form a thin, robust shell. Processes for preparing the toner compositions are also described.Type: GrantFiled: June 30, 2005Date of Patent: August 26, 2008Assignee: Xerox CorporationInventors: Valerie M. Farrugia, Guerino G. Sacripante, Michael S. Hawkins, Ke Zhou
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Patent number: 7413839Abstract: The object of the present invention is to provide a toner characterized in that the toner comprises a first binder resin and a second binder resin, the first binder resin is an amorphous resin and the second binder resin is a crystalline resin, and the glass-transition temperature of the toner (TgA) is lower than the glass-transition temperature expressed by the following equation (1) (TgC). TgC = ? i = 1 n ? b i / ? i = 1 n ? ( b i TgB i ) Equation ? ? ( 1 ) In the above equation (1), “TgBi” represents the glass-transition temperature of the amorphous resin, “n” represents the number of amorphous resins, and “b” represents the content of the amorphous resin (part by mass). Examples of the preferred aspect of the present invention includes the one that at least a part of the amorphous resin and a part of the crystalline resin are compatible each other, and the one that the glass-transition temperature of the toner (TgA) is 10° C.Type: GrantFiled: March 17, 2005Date of Patent: August 19, 2008Assignee: Ricoh Company, Ltd.Inventors: Keiko Matsumoto, Toyoshi Sawada
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Publication number: 20080153024Abstract: An electrophotographic toner includes toner parent particles containing a binder resin, a colorant and a charge control agent; and an external additive added to the surface of the toner parent particles. The toner further includes positively chargeable silica and polymer beads in addition to large particle diameter silica, small particle diameter silica and titanium oxides. Thus, the toner can maintain its charge quantity and distribution stably even during environmental changes and after long image printing times, thereby preventing the contamination of the non-image part and the filming.Type: ApplicationFiled: July 23, 2007Publication date: June 26, 2008Inventor: Sang-woo Kim
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Patent number: 7390607Abstract: To provide a toner production process in which at least radically polymerizable monomers are polymerized in at least one of a supercritical fluid and a subcritical fluid to thereby produce toner particles, wherein a polymer of the radically polymerizable monomers is insoluble in at least one of the supercritical fluid and the subcritical fluid.Type: GrantFiled: July 12, 2006Date of Patent: June 24, 2008Assignee: Ricoh Company, Ltd.Inventors: Chiaki Tanaka, Masayuki Ishii
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Patent number: 7384722Abstract: A method for preparing a functional particulate organic material, including providing a suspension of a particulate organic material having an acid group on a surface thereof; reacting a metal cation with tri- or more-valence with the acid group; and reacting at least one of an organic acid and an organic acid salt with the metal cation. A toner prepared by the method mentioned above. An image forming method including developing a latent image with the toner; transferring the toner image on a receiving material optionally via an intermediate transfer medium, and fixing the toner image on the receiving material. A process cartridge including a developer container containing a developer including the toner mentioned above, and at least one of an image bearing member; a charger; a developing device; and a cleaner.Type: GrantFiled: June 21, 2004Date of Patent: June 10, 2008Assignee: Ricoh Company LimitedInventors: Shinji Ohtani, Hiroshi Yamashita, Yohichiroh Watanabe, Tsunemi Sugiyama, Takuya Saito
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Publication number: 20080131801Abstract: A method including polymerization performed with the use of a binder resin dispersion containing a styrene monomer, a compound having one or more unsaturated bond and sulfonic acid or sulfonate, and an acrylic ester monomer, wherein the contents of the monomers and the compound are 60 to 90 mol %, 1 mol ppm to 10 mol %, and 10 to 40 mol %, respectively.Type: ApplicationFiled: November 29, 2007Publication date: June 5, 2008Applicants: KABUSHIKI KAISHA TOSHIBA, TOSHIBA TEC KABUSHIKI KAISHAInventors: Motonari Udo, Takayasu Aoki, Takashi Urabe, Tsuyoshi Itou, Satoshi Araki, Masahiro Ikuta
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Patent number: 7368214Abstract: An electrostatic latent image developing toner including, as a binder resin, a crystalline resin and at least one kind of non-crystalline resin, wherein, in a dynamic viscoelasticity measurement by a sine wave vibration method, a minimum value of the relaxation elasticity H in a relaxation spectrum obtained from frequency dispersion characteristics measured at temperatures of 60 and 80 degrees centigrade with a measurement frequency set in the range of 0.1 to 100 rad/sec and measurement strain set in the range of 0.02 to 4.5% is in the range of 10 to 900 Pa/cm2, and a relaxation time ? corresponding to the minimum value is in the range of 1 to 10,000 sec.Type: GrantFiled: June 3, 2005Date of Patent: May 6, 2008Assignee: Fuji Xerox Co., Ltd.Inventors: Takao Ishiyama, Hiroshi Nakazawa, Masanobu Ninomiya, Hideo Maehata, Yutaka Sugizaki, Shinpei Takagi
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Patent number: 7364828Abstract: The method of manufacturing toner for electrophotography includes the steps of dissolving or dispersing a toner composition containing a resin and a coloring agent into polymerizable monomers to provide a solution or a dispersed system, emulsifying the solution or the dispersed system with a first surface active agent in an aqueous medium to provide an emulsion, and polymerizing the polymerizable monomers in the emulsion to obtain toner. A second surface active agent having polarity opposite to polarity of the first surface active agent is added after the emulsifying step.Type: GrantFiled: January 10, 2006Date of Patent: April 29, 2008Assignee: Ricoh Company, Ltd.Inventors: Hiroshi Yamashita, Takuya Saito, Tsunemi Sugiyama, Yohichiroh Watanabe
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Publication number: 20080085460Abstract: A toner that when the complex elastic modulus measured at an angular frequency of 6.28 rad/sec., and a strain amount of 0.3% is 1×106 Pa or more and 1×108 Pa or less, the tangent loss is 0.5 or more and 1.8 or less.Type: ApplicationFiled: April 20, 2007Publication date: April 10, 2008Applicant: FUJI XEROX CO., LTD.Inventors: Masanobu Ninomiya, Toyofumi Inoue, Masataka Kuribayashi, Masashi Ikeda, Takafumi Koide
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Patent number: 7354687Abstract: Dry electrographic toner compositions are provided comprising a plurality of dry toner particles, wherein the toner particles comprise polymeric binder comprising at least one amphipathic copolymer comprising one or more S material portions and one or more D material portions. The dry electrographic toner composition comprises a wax associated with the dry toner particles, wherein substantially all of the wax is associated with the toner particle at the surface thereof. Methods of making electrographic toner compositions are also provided comprising preparing polymeric binder particles comprising at least one amphipathic copolymer comprising one or more S material portions and one or more D material portions, preparing toner particles, drying the toner particles, and milling the dry toner particles in the presence of a wax component to provide a dry toner particle composition having the wax associated with the toner particles.Type: GrantFiled: October 31, 2004Date of Patent: April 8, 2008Assignee: Samsung Electronics CompanyInventors: Leonard Stulc, Ronald J. Moudry, Zbigniew Tokarski, Charles W. Simpson, Gay L. Herman, A. Kristine Fordahl, James A. Baker
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Publication number: 20080076053Abstract: A method of preparing a latex for a toner composition and a method of preparing a toner composition using the same. The method of preparing the latex for the toner composition includes preparing a monomer solution by dissolving a polyester-based monomer in an organic solvent and adding a vinyl-based monomer thereto, preparing an aqueous macromonomer solution by dissolving a macromonomer in water, preparing a solution in which monomers and macromonomer are suspended by mixing the monomer solution and the aqueous macromonomer solution, and polymerizing the monomers by adding a hydrophobic polymerization initiator to the suspended solution.Type: ApplicationFiled: May 8, 2007Publication date: March 27, 2008Applicant: Samsung Electronics Co., Ltd.Inventors: Chang-kook HONG, Jeung-won Lee, Kyung-yol Yon, Min-young Cheong, Sang-eun Shim
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Patent number: 7348121Abstract: A toner including toner particles comprising a binder resin; and at least two kinds of particulate resins which are located on at least a surface of the toner particles, wherein the toner satisfies at least one of the following relationships (TgA?TgB)?20° C., wherein TgA and TgB represent glass transition temperatures (Tg) of a particulate resin (A) having a highest Tg and a particulate resin (B) having a lowest Tg among the at least two kinds of particulate resins, respectively; and 100,000?Mwc?6,000,000 and 8,000?Mwd?800,000, wherein Mwc and Mwd represent weight average molecular weights (Mw) of a particulate resin (C) having a highest Mw and a particulate resin (D) having a lowest Mw among the at least two kinds of particulate resins, respectively, wherein Mwc>Mwd.Type: GrantFiled: February 2, 2007Date of Patent: March 25, 2008Assignee: Ricoh Company LimitedInventors: Ryohta Inoue, Naohiro Watanabe, Masahide Yamada, Sonoh Matsuoka, Chiaki Tanaka, Takeshi Takada, Masahiro Ohki, Akinori Saitoh
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Publication number: 20080038653Abstract: An electrophotographic developer comprising a toner and a carrier is disclosed. The toner contains a toner binder resin, a colorant and a releasing agent, and a carrier contains a magnetic particles dispersed in a carrier binder resin, wherein the releasing agent contained in toner is composed of from 40 to 98% by weight of a first releasing agent component of an ester compound and 60 to 2% by weight of a second releasing agent component of a hydrocarbon compound having a branched-chain structure, and the carrier has a shape coefficient SF-1 of from 1.0 to 1.2 and a shape coefficient S-2 of from 1.1 to 2.5, and a volume based median diameter of from 10 to 100 ?m.Type: ApplicationFiled: July 20, 2007Publication date: February 14, 2008Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.Inventors: Hiroshi YAMAZAKI, Shingo FUJIMOTO, Ken OHMURA, Takao YAMANOUCHI
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Patent number: 7323280Abstract: A toner for developing an electrostatic image comprising toner particles which include a binder resin, a wax and a colorant, wherein the wax has a melting point of between 50 and 150° C., the wax exists in the toner particles in domains of 2 ?m or less mean particle size and (a) the mean circularity of the toner particles as measured by a Flow Particle Image Analyser is at least 0.90; and (b) the shape factor, SF1, of the toner particles is at most 165. A process for the manufacture of said toner which comprises the following steps: providing a latex dispersion; providing a wax dispersion; providing a colorant dispersion; mixing the latex dispersion, wax dispersion and colorant dispersion; and causing the mixture to flocculate.Type: GrantFiled: April 8, 2003Date of Patent: January 29, 2008Assignee: Fujifilm Imaging Colorants LimitedInventors: Daniel Patrick Morris, Martin Russell Edwards
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Patent number: 7318987Abstract: Dry electrographic toner compositions are provided comprising a plurality of dry toner particles, wherein the toner particles comprise polymeric binder comprising at least one amphipathic copolymer comprising one or more S material portions and one or more D material portions. The dry electrographic toner composition comprises a wax associated with the dry toner particles that has been entrained in the toner particle during the formation of the amphipathic copolymer. Methods of making the electrographic toner compositions are also provided. These toner compositions provide images having excellent durability and erasure resistance properties at low fusion temperatures and with little undesired offset.Type: GrantFiled: October 31, 2004Date of Patent: January 15, 2008Assignee: Samsung Electronics CompanyInventors: Charles W. Simpson, Ronald J. Moudry, Leonard Stulc, Zbigniew Tokarski, Gay L. Herman, A. Kristine Fordahl, James A. Baker
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Patent number: 7318988Abstract: The invention provides dry electrographic toner compositions comprising toner particles. The toner particles comprise polymeric binder comprising at least one amphipathic copolymer comprising one or more S material portions and one or more D material portions prepared from an organosol reaction process utilizing a liquid carrier reaction medium having a Kauri-Butanol number less than about 30 mL. The S material portion comprises at least one soluble component and at least one non-sorptive component, wherein the non-sorptive component is the reaction product of monomers having an absolute difference in Hildebrand solubility parameter from the liquid carrier of about 3.0 MPa1/2 or greater. Additionally, dry electrographic toner compositions are provided wherein the toner particles comprise polymeric binder comprising at least one amphipathic copolymer comprising one or more S material portions and one or more D material portions.Type: GrantFiled: October 28, 2004Date of Patent: January 15, 2008Assignee: Samsung Electronics CompanyInventors: Jiayi Zhu, James A. Baker
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Patent number: 7306886Abstract: Dry electrographic toner compositions are provided comprising a plurality of dry toner particles, wherein the toner particles comprise polymeric binder comprising at least one amphipathic copolymer comprising one or more S material portions and one or more D material portions. The dry electrographic toner composition comprises a wax associated with the dry toner particles, wherein a substantial portion of the wax is entrained in the toner particle and a substantial portion of the wax is associated with the toner particle at the surface thereof. Methods of making electrographic toner compositions are also provided comprising preparing polymeric binder particles comprising at least one amphipathic copolymer comprising one or more S material portions and one or more D material portions, and milling the particles before or after formulation as toner particles with wax in the liquid carrier prior to drying to form the dry toner composition.Type: GrantFiled: October 31, 2004Date of Patent: December 11, 2007Assignee: Samsung Electronics CompanyInventors: Gay L. Herman, Ronald J. Moudry, Zbigniew Tokarski, Charles W. Simpson, Leonard Stulc, A. Kristine Fordahl, James A. Baker
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Publication number: 20070281234Abstract: An objective is to provide a toner capable of obtaining clear prints with no image unevenness at low cost. Disclosed is an electrostatic charge image developing toner comprising toner particles each containing at least a binder resin, a colorant and wax, wherein a ratio {(S1/S)×100} of total area (S1) of peaks detected in a range of 36-42 ppm to total area (S) of peaks detected in a range of 0-50 ppm, in a spectrum obtained via measurement of the wax employing a 13C-NMR (nuclear magnetic resonance) measuring apparatus, satisfies the following inequality. 0.03?(S1/S)×100?0.50.Type: ApplicationFiled: April 10, 2007Publication date: December 6, 2007Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.Inventors: Kazuya ISOBE, Kouji SUGAMA, Hidemasa SAWADA
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Patent number: 7300736Abstract: A toner contains: (A) a binder resin; (B) a colorant; (C) a charge controlling agent; and (D) an additive. (A) contains: a polyester resin containing no tetrahydrofuran-insoluble component; and having components having a molecular weight not greater than 5×102 present in an amount of 4% or less by weight, a main peak present in a molecular weight range of from 3×103 to 9×103 as determined by gel permeation chromatography. (C) contains: a metal salt of salicylic acid or salicylic acid derivative. (D) contains: a hydrophobized silica having a primary particle diameter of from 0.01 to 0.03 ?m; and a hydrophobized titanium oxide having a primary particle diameter of from 0.01 to 0.03 ?m, a specific surface area of from 60 to 140 m2/g, one or more water-soluble components in an amount of 0.2% or more by weight, a transmittance not less than 35% for light having a wavelength of 300 nm and a transmittance not less than 80% for light having a wavelength of 600 nm.Type: GrantFiled: May 27, 2004Date of Patent: November 27, 2007Assignee: Ricoh Company, Ltd.Inventors: Hiroyuki Fushimi, Osamu Uchinokura
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Patent number: 7294442Abstract: A toner for developing an electrostatic image having a good combination of hot offset resistance and low temperature fixability. The toner includes (1) a resin having at least one group that can react with a compound having an active hydrogen in an amount of 2 pieces per molecule of the resin, and a colorant. The toner satisfies the following relationship: 3?G=R?Rideal?20, where G represents a ratio of a weight of components other than the colorant and the resin that are insoluble in the organic solvent to total weight of the toner, R represents a weight ratio of components included in the toner that are insoluble in the organic solvent to the total weight of the toner, and Rideal represents an ideal weight ratio of the colorant and the resin, which is calculated from a formula of the toner.Type: GrantFiled: October 27, 2006Date of Patent: November 13, 2007Assignee: Ricoh Company. Ltd.Inventors: Takeshi Takada, Chiaki Tanaka, Naohiro Watanabe
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Patent number: 7291435Abstract: The present invention provides a toner binder for electrophotography which comprises a polyester resin constituted of an alcohol component containing a polyoxyalkylene ether (A) of a bisphenol and an acid component, and the content of unreacted bisphenols in said polyester resin is 15 ppm or less.Type: GrantFiled: March 25, 2003Date of Patent: November 6, 2007Assignee: Sanyo Chemical Industries, Ltd.Inventor: Takashi Yamashiro
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Patent number: 7267864Abstract: The present invention provides an image supporting material for fixably supporting a color toner image, the material including a base material, a light scattering layer provided on the base material and containing a white pigment and a thermoplastic resin, and a color toner receptive layer provided on the light scattering layer and containing at least a thermoplastic resin, wherein the thermoplastic resin in the light scattering layer is constituted of a polyolefin or a polyolefinic copolymer having a temperature, at which viscosity becomes 5×103 Pa·s, of 100° C. or higher, and the thermoplastic resin in the color toner receptive layer is constituted of a resin obtained by melt mixing of a crystalline polyester resin and an amorphous resin and having a temperature, at which viscosity becomes 103 Pa·s, equal to or higher than 65° C. but lower than 80° C.Type: GrantFiled: September 15, 2004Date of Patent: September 11, 2007Assignee: Fuji Xerox Co., Ltd.Inventors: Osamu Ide, Shigeru Hayashi, Katsumi Daimon
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Publication number: 20070184376Abstract: A method of preparing a nonmagnetic one-component pulverized color electrophotographic developer, includes: preparing a master batch by melt-kneading at least two binder resins and wax; and melt-kneading a mixture of the master batch, a colorant, and a charge control agent. According to the method, paper jams can be decreased and a toner having wide fixing margin can be obtained by preventing wax from being dispersed mainly in a resin having a similar melting property as wax during melt-kneading to prepare a toner. An electrophotographic developer prepared using the method can prevent image contamination and developing member contamination. Also, the electrophotographic developer can guarantee wide fixing margin of the toner, and thus can be efficiently used in an electrophotographic image forming apparatus.Type: ApplicationFiled: November 21, 2006Publication date: August 9, 2007Inventors: Duck hee Lee, Seok-hoon Choi
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Publication number: 20070166637Abstract: A method of preparing a toner, including: preparing a colorant dispersion by mixing a reactive emulsifier and a colorant; preparing a toner composition by mixing a macromonomer including a hydrophilic group, a hydrophobic group and at least one reactive functional group, at least one polymerizable monomer and a chain transfer agent with the colorant dispersion; emulsion polymerizing the toner composition in a medium; and separating and drying the polymerized toner, wherein the amounts of the macromonomer and the chain transfer agent are controlled to regulate the configuration of toner particles. A toner prepared using the method, an image forming method using the toner, and an image forming apparatus using the toner are also provided by the invention. According to the method, the size and configuration of toner particles are easily controlled. In addition, the method minimizes the use of a surfactant, and decreases polluted water and waste water, which is very advantageous environmentally.Type: ApplicationFiled: November 27, 2006Publication date: July 19, 2007Inventors: Jun-young Lee, Kyung-yol Yon, Chang-kook Hong, Min-young Cheong
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Patent number: 7244538Abstract: The present invention was investigated for the purpose of providing a binder resin for toner which is excellent in the low temperature fixing property which can cope with the development of high-speed copier machines, and is excellent in the offset resistance, blocking resistance, pulverizability and development durability. As a result, it was found that the purpose could be achieved by using, as a binder resin for toner, a resin that can be obtained from at least three different vinyl polymers with different molecular weight, contents of functional groups, and preferably from a crosslinking agent having the vinyl polymer structure, and that contains a specific gel component. This resin has excellent melting property at low temperatures, and has suitable performance as a material for toner and a toner in high-speed copier machines.Type: GrantFiled: August 8, 2003Date of Patent: July 17, 2007Assignee: Mitsui Chemicals, Inc.Inventors: Kazuya Sakata, Takeshi Yoshida
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Publication number: 20070154830Abstract: A method of preparing a toner includes: preparing high molecular weight latex particles by polymerizing a toner composition including a macromonomer having a hydrophilic group, a hydrophobic group and at least one reactive functional group, at least one polymerizable monomer, a colorant and wax; aggregating the high molecular latex particles in the absence of an emulsifier, a colorant, and wax; and separating and drying the aggregated high molecular weight latex particles. A toner is prepared using the method described above. An image forming method using the toner and an image forming apparatus employing the toner are also provided. Using the method described above, polymerizable toner particles can be prepared using a simplified process and the colorant and was inside the toner can be easily dispersed.Type: ApplicationFiled: November 13, 2006Publication date: July 5, 2007Inventors: Chang-kook Hong, Kyung-yol Yon, Jun-young Lee, Min-young Cheong
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Patent number: 7226984Abstract: Provided is a binder for an electrostatic image developing toner using a polyester resin in which at least a part of a carboxylic acid component (a) and/or an alcohol component (b) comprises a carboxy-modified polyolefin or a hydroxyl-terminated polyalkadiene that may be hydrogenated containing an aliphatic hydrocarbon group (x) having a carbon number of 100 to 1,000. The binder is excellent in environmental stability and does not generate a peculiar odor around a copier or a printer when the binder is used in a toner, and a toner using the binder.Type: GrantFiled: April 25, 2003Date of Patent: June 5, 2007Assignee: Sanyo Chemical Industries, LtdInventor: Masakazu Iwata
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Patent number: 7205357Abstract: A polyester resin composition for a toner comprising a titanium compound in an amount of from 0.005 to 4% by weight, and an inorganic phosphorus compound in an amount of from 0.001 to 5% by weight; a toner comprising the polyester resin composition as defined above; and a process for preparing the polyester resin composition for a toner as defined above, comprising the step of polycondensing the raw material monomers for the polyester in the presence of a titanium compound and an inorganic phosphorus compound. The polyester resin composition for a toner is suitably used as a resin binder for a toner for developing a latent image formed in electrophotography, electrostatic recording method, electrostatic printing method or the like, a process for preparing the same, and a toner comprising the polyester resin composition.Type: GrantFiled: October 28, 2003Date of Patent: April 17, 2007Assignee: Kao CorporationInventors: Takashi Kubo, Katsutoshi Aoki, Eiji Shirai
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Patent number: 7202003Abstract: Dry electrophotographic toner compositions are provided comprising an amphipathic copolymer comprising basic functionalities covalently bonded to the amphipathic copolymer. Methods of making the toner compositions are also provided. The present toner compositions exhibit unique charge characteristics and unique chemical and charge interaction properties.Type: GrantFiled: June 30, 2004Date of Patent: April 10, 2007Assignee: Samsung Electronics CompanyInventors: Ronald J. Moudry, James A. Baker, Zbigniew Tokarski, Julie Y. Qian
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Patent number: 7169522Abstract: The toner for developing a latent electrostatic image to form an image contains a binder resin and 2% by weight to 15% by weight of a coloring agent. The coverage of the toner with the coloring agent on a surface of the toner is 1.5% by atom to 15% by atom. The toner prevents scatterings and toner deposition on the background of images and provides high quality images even after printing several tens of sheets at high temperature and in high humidity.Type: GrantFiled: March 12, 2003Date of Patent: January 30, 2007Assignee: Ricoh Company, Ltd.Inventors: Hideki Sugiura, Satoshi Mochizuki, Yasuo Asahina, Kazuhiko Umemura, Minoru Masuda, Tomomi Tamura
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Patent number: 7163775Abstract: A toner for developing an electrostatic image having a good combination of hot offset resistance and low temperature fixability. The toner includes (1) a resin having at least one group that can react with a compound having an active hydrogen in an amount of 2 pieces per molecule of the resin, and a colorant. The toner satisfies the following relationship: 3?G=R?Rideal?20, where G represents a ratio of a weight of components other than the colorant and the resin that are insoluble in the organic solvent to total weight of the toner, R represents a weight ratio of components included in the toner that are insoluble in the organic solvent to the total weight of the toner, and Rideal represents an ideal weight ratio of the colorant and the resin, which is calculated from a formula of the toner.Type: GrantFiled: March 19, 2004Date of Patent: January 16, 2007Assignee: Ricoh Company LimitedInventors: Takeshi Takada, Chiaki Tanaka, Naohiro Watanabe
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Patent number: 7160663Abstract: A toner includes toner particles and an inorganic fine powder mixed with the toner particles. The toner particles contain a binder resin, a coloring agent, a releasing agent, and a sulfur-containing resin. The toner particles contain at least one element selected from the group consisting of magnesium, calcium, barium, zinc, aluminum, and phosphorus and satisfy the relationship: 4?T/S?30 wherein T represents the total content of the element in ppm, and S represents the content of sulfur in ppm. The weight-average particle diameter (D4) of the toner is in the range of 3 to 10 ?m. The average circularity of the toner is within the range of 0.950 to 0.995.Type: GrantFiled: March 25, 2004Date of Patent: January 9, 2007Assignee: Canon Kabushiki KaishaInventors: Keiji Komoto, Yasushi Katsuta, Yushi Mikuriya, Takeshi Kaburagi, Emi Tosaka
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Patent number: 7138214Abstract: A positively chargeable toner, comprising: toner particles that are formed by allowing resin particles containing an amino-group and colorant particles to aggregate, the toner having an amine value in a range of 5 to 35 KOHmg/g, being excellent in fixing properties, heat resistant storing property and chargeability.Type: GrantFiled: March 3, 2004Date of Patent: November 21, 2006Assignee: Konica Minolta Business Technologies, Inc.Inventors: Yoshihiro Mikuriya, Masahiro Anno
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Patent number: 7135264Abstract: The present invention relates to amphipathic copolymeric binder particles chemically grown in a substantially nonaqueous liquid carrier to form an organosol. The invention also pertains to dry particulate electrographic toners incorporating an organosol comprising an amphipathic copolymer wherein the amphipathic copolymer incorporates one or more S portions and one or more D portions. Methods of making dry electrophotographic toner particles, and methods of electrographically forming an image on a substrate using these toners, are also described. Preferably, fluidized drying techniques are used to form the dry toner particles from the organosol.Type: GrantFiled: June 30, 2003Date of Patent: November 14, 2006Assignee: Samsung Electronics CompanyInventors: Julie Y. Qian, Gay L. Herman, James A. Baker
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Patent number: 7112394Abstract: A toner composition includes a thermoset resin, cross-linking agent, and optionally additives such as colorants. The thermally cross-linkable toner composition may be fixed, using standard fusing systems, to yield images that withstand rigorous processing conditions, such as, for example, the high temperatures reached in flexible packaging processes.Type: GrantFiled: March 1, 2004Date of Patent: September 26, 2006Assignee: Xerox CorporationInventor: Thomas W. Smith
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Patent number: 7087353Abstract: A non-contact heat fixing toner, comprising a binder resin, a colorant, an infrared absorbing agent, a first wax and a second wax, wherein a difference (X-Y) between the maximum peak temperature (X; ° C.) in the differential thermal curve in the first wax and Tg (Y; ° C.) of the binder resin is within the range from ?5 to +10° C.Type: GrantFiled: October 31, 2003Date of Patent: August 8, 2006Assignee: Konica Minolta Business Technologies, Inc.Inventors: Yoshihiro Mikuriya, Minoru Nakamura, Masahiro Anno, Junichi Tamaoki, Chiyoshi Nozaki