Core-shell Structure Patents (Class 430/110.2)
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Patent number: 8323865Abstract: Toners are provided which may be suitable for use in cold fusing pressure apparatus. The toners include low molecular weight amorphous resins having low softening points and low molecular weights, compared with resins utilized in conventional emulsion aggregation toners for low melt fusing applications.Type: GrantFiled: August 4, 2009Date of Patent: December 4, 2012Assignee: Xerox CorporationInventors: Allan K. Chen, Guerino G. Sacripante
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Patent number: 8318398Abstract: Environmentally friendly toner particles are provided which may include a bio-based amorphous polyester resin, optionally in combination with another amorphous resin and/or a crystalline resin. Methods for providing these toners are also provided.Type: GrantFiled: September 9, 2010Date of Patent: November 27, 2012Assignee: Xerox CorporationInventors: Guerino G. Sacripante, Valerie M. Farrugia, Ke Zhou, Edward G. Zwartz, Michael S. Hawkins
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Publication number: 20120295194Abstract: A toner composition includes toner particles including an average diameter ranging from about 3 ?m to about 10 ?m, an average particle density of about 1.4 g/cm3 or less, and for a given particle size configured to have a decreased mass and reduced particle momentum. The toner particle can include one of a solid core and a solid outer shell, a porous core and a porous outer shell, and a solid outer shell with a hollow core. The porous and solid cores can include a low density material.Type: ApplicationFiled: May 18, 2011Publication date: November 22, 2012Applicant: XEROX CORPORATIONInventors: George Cunha CARDOSO, Rachael McGrath, Dale Mashtare
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Patent number: 8313882Abstract: There are provided a toner and a two-component developer effective to make exudation of a release agent easy during fixing and to prevent occurrence of high-temperature offset, in which both the preservation stability and the fixing property are improved at the same time. The capsule toner comprises a toner base particle and a resin layer formed of fine resin particles with which a surface of the toner base particle is coated. In the capsule toner, both of the following expressions are satisfied: A<B; and (B?A)<3×103Pa where A is a storage elastic modulus of the toner base particle at a softening temperature of the toner base particle, and B is a storage elastic modulus of fine resin particle at the softening temperature of the toner base particle.Type: GrantFiled: March 9, 2010Date of Patent: November 20, 2012Assignee: Sharp Kabushiki KaishaInventors: Yoritaka Tsubaki, Yoshitaka Kawase
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Patent number: 8309288Abstract: A color toner is provided which has a dielectric strength equal to or lower than that of a black toner containing carbon black, and which has an improved charging rate and charge stability against changes in the environment.Type: GrantFiled: April 10, 2009Date of Patent: November 13, 2012Assignee: SAMSUNG Electronics Co., Ltd.Inventors: Hisao Okada, Mitsuru Oikawa
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Patent number: 8309290Abstract: A toner including toner particles comprising a binder resin, a coloring agent and a wax. The toner particles are prepared by agglomerating and/or fusing at least two kinds of resin particulates and particles of the coloring agent dispersed in an aqueous medium. A first resin particulate among the at least two kinds of resin particulates contains a resin having a polyester skeleton and the wax. At least 50% by weight of the binder resin is polyester resins.Type: GrantFiled: September 14, 2007Date of Patent: November 13, 2012Assignee: Ricoh Company, Ltd.Inventors: Atsushi Yamamoto, Chiyoshi Nozaki, Tsuyoshi Nozaki, Mitsuyo Matsumoto, Takuya Kadota, Hiroyuki Murakami, Katsunori Kurose, Yoshimichi Ishikawa
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Publication number: 20120282545Abstract: According to one embodiment, a toner includes at least one encapsulated particle containing a color developable compound, color developer and a color eraser and polymeric particles. The at least one encapsulated particle and the polymeric particles being aggregated and fused in dispersion liquid.Type: ApplicationFiled: July 13, 2012Publication date: November 8, 2012Applicant: TOSHIBA TEC KABUSHIKI KAISHAInventors: Takahito Kabai, Tsuyoshi Itou
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Publication number: 20120282544Abstract: A method for producing a developing agent including preparing a dispersion liquid containing first fine particles containing a binder resin and second fine particles containing a color developable compound, a color coupler, and a color eraser, and aggregating the first and second fine particles in the dispersion liquid to form aggregated particles.Type: ApplicationFiled: July 19, 2012Publication date: November 8, 2012Applicant: TOSHIBA TEC KABUSHIKI KAISHAInventors: Takahito Kabai, Tsuyoshi Itou
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Patent number: 8298669Abstract: A coated carrier that peeling and wearing of a coating layer are hard to be generated and a method of manufacturing the coated carrier are provided. The coated carrier includes a core particle including a magnetic body, a first resin layer coating the core particle, a resin particle layer including a resin particle fixed to the first resin layer as a single layer, and a second resin layer. The first resin layer includes a first resin having a first reactive group. The resin particle layer is formed of resin particles including a cross-linking resin having a second reactive group which can undergo a cross-linking reaction with the first reactive group. The second resin layer is provided so as to fill gaps between the resin particles.Type: GrantFiled: May 19, 2010Date of Patent: October 30, 2012Assignee: Sharp Kabushiki KaishaInventor: Yui Kawano
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Publication number: 20120264042Abstract: A method of preparing a carrier for electrophotography, including a core material and a coating material layer formed on the surface of the core material, including: coating the core material with the coating material; and burning the coating material with a high-frequency induction heater, wherein the core material has a saturated magnetization of from 40 to 95 Am2/kg.Type: ApplicationFiled: March 21, 2012Publication date: October 18, 2012Inventors: Masato Taikoji, Kousuke Suzuki, Shinichiro Yagi, Yuuki Mizutani
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Patent number: 8287637Abstract: Core-shell nanoscale pigment particles include a core organic pigment composition including nanoscale particles of organic pigments, and a shell layer of surface-deposited silica, where the organic pigment particles are selected from azo-type pigment particles, azo laked pigment particles, quinacridone pigment particles, phthalocyanine pigment particles, and mixtures thereof. The core-shell nanoscale pigment particles can also include an organic primer layer covering the core and located between the core and the shell layer. The core-shell nanoscale pigment particles can be made by preparing a core composition including nanoparticles of organic pigments, and encapsulating the core with shell layer of surface-deposited silica and an optional organic primer layer located between the core and the shell layer.Type: GrantFiled: March 25, 2009Date of Patent: October 16, 2012Assignee: Xerox CorporationInventors: Rina Carlini, Michelle N. Chretien, Sandra J. Gardner
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Patent number: 8283099Abstract: Disclosed are a biomass chemical toner composition and a method for manufacturing the same. First, a biomass resin is mixed with a first hydrophobic resin to form organic particles. The organic particles, a second hydrophobic resin, and a pigment are mixed by emulsion aggregation to form cores. Subsequently, a third hydrophobic resin is formed on the surface of the cores, and the third hydrophobic resin is further heated and coalesced to form a continuous structure encapsulating the cores. Accordingly, the biomass chemical toner obtained from the described method has good anti-humidity, good charge stability, and low fusing temperature.Type: GrantFiled: March 22, 2010Date of Patent: October 9, 2012Assignee: Industrial Technology Research InstituteInventors: Kuo-Tung Huang, Ju-Feng Liao, I-Jein Cheng, Jui-Fa Chang, Yu-Chin Lin, Hsiang-Yun Lee, Yu-Ying Hsu
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Patent number: 8273516Abstract: Toners are provided which include a resin including at least one baroplastic polymer. The baroplastic polymer, in embodiments, may be a block copolymer with discrete low glass transition temperature (Tg) domains and high Tg domains that plasticize one another at ambient temperature when subjected to pressures of from about 500 psi (about 3.45 MPa) to about 10,000 psi (about 69 MPa), enabling them to be extruded and molded without heat. The resulting polymers, in turn, may then be utilized to form toners.Type: GrantFiled: July 10, 2009Date of Patent: September 25, 2012Assignee: Xerox CorporationInventors: Jordan H. Wosnick, Karen Ann Moffat
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Patent number: 8268527Abstract: A toner is provided including a core particle comprising a binder resin, a colorant, and a release agent, and a shell layer comprising particles of a vinyl resin. The vinyl resin comprises 80% by weight or more of a unit of an aromatic compound having a vinyl-polymerizable functional group. A method of manufacturing the above toner is also provided, including steps of dissolving or dispersing the binder resin, the colorant, and the release agent in an organic solvent to prepare an oily liquid, dispersing the oily liquid in an aqueous medium to prepare the core particles, and adhering particles of a vinyl resin to the surfaces of the core particles to form shell layers.Type: GrantFiled: August 11, 2010Date of Patent: September 18, 2012Assignee: Ricoh Company, LimitedInventors: Takuya Kadota, Yoshihiro Mikuriya, Tsuyoshi Nozaki, Atsushi Yamamoto, Yoshimichi Ishikawa, Tomohiro Fukao, Tomoharu Miki
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Patent number: 8268525Abstract: A toner usable with electrophotography includes an iron (Fe) content in the toner is in a range of about 1.0×102 ppm to about 1.0×104 ppm and a circle equivalent diameter of a sectional area of an Fe agglomerating agent is in a range of about 1.0 nm to about 2.0×102 nm.Type: GrantFiled: January 20, 2010Date of Patent: September 18, 2012Assignee: SAMSUNG Electronics Co., Ltd.Inventors: Hae-ree Joo, Sung-jun Park, Jae-hwan Kim, Min-ho Yang, Kyeong Pang
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Patent number: 8257899Abstract: The present disclosure provides processes for the preparation of unsaturated polyesters. In embodiments, a process of the present disclosure includes reacting an organic diol with a cyclic alkylene carbonate in the presence of a first catalyst to thereby form a polyalkoxy diol, optionally adding thereto a further amount of cyclic alkylene carbonate in the presence of a second catalyst, and subsequently polycondensing the resulting mixture with a dicarboxylic acid in combination with an anhydride.Type: GrantFiled: August 27, 2009Date of Patent: September 4, 2012Assignee: Xerox CorporationInventor: Guerino G. Sacripante
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Patent number: 8257895Abstract: An emulsion aggregation toner composition includes toner particles including: an unsaturated polymeric resin, such as amorphous resins, crystalline resins, and combinations thereof; an optional colorant; an optional wax; an optional coagulant; and an IR absorber. The use of an IR absorber may permit formation of color toners that have uniform gloss and crease properties, i.e., the IR absorbers may prevent gloss and crease differences between color and black toners.Type: GrantFiled: October 9, 2009Date of Patent: September 4, 2012Assignee: Xerox CorporationInventors: Ke Zhou, Edward Graham Zwartz, Karen Ann Moffat, Guerino G. Sacripante
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Patent number: 8252495Abstract: The electrophotographic toner of the present invention comprises toner particles and inorganic fine powder externally added to the toner particles. The toner particles comprise a core particle containing at least a resin, a coloring agent and wax, a first shell layer that is formed on the surface of the core particle to prevent inorganic fine powder from being buried, and a second shell layer that is formed on the surface of the first shell layer to retain inorganic fine powder. This makes it possible to inhibit inorganic fine powder that is an external additive from being buried in a toner and prevent deterioration of developing performance, reduction in transfer efficiency, blocking of a developer and toner aggregation.Type: GrantFiled: March 7, 2006Date of Patent: August 28, 2012Assignee: Kyocera Document Solutions Inc.Inventor: Hideki Ota
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Patent number: 8252496Abstract: A method for producing a developing agent including preparing a dispersion liquid containing first fine particles containing a binder resin and second fine particles containing a color developable compound, a color coupler, and a color eraser, and aggregating the first and second fine particles in the dispersion liquid to form aggregated particles.Type: GrantFiled: February 11, 2010Date of Patent: August 28, 2012Assignee: Toshiba Tec Kabushiki KaishaInventors: Takahito Kabai, Tsuyoshi Itou
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Patent number: 8247149Abstract: To provide an electrophotographic developer carrier including a carrier core material, and a coat layer containing a binder resin and conductivity-imparted microparticles which are produced by imparting conductivity to inorganic microparticles, the coat layer being formed over the carrier core material, wherein the electrophotographic developer carrier has a static resistivity of 10 [Log (?·cm)] or higher and a dynamic resistivity of 9 [Log (?)] or lower, and is used in an electrophotographic developer together with a negatively chargeable toner having an average circularity of 0.925 to 0.970, and wherein the toner includes a resin, a colorant and an inorganic layered mineral in which at least part of interlayer ions is modified with organic ions, and is granulated by dispersing and/or emulsifying an oil phase and/or a monomer phase containing at least a toner composition and/or a toner composition precursor in an aqueous medium.Type: GrantFiled: December 2, 2008Date of Patent: August 21, 2012Assignee: Ricoh Company, Ltd.Inventors: Shinichiro Yagi, Kousuke Suzuki, Masashi Nagayama
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Patent number: 8232034Abstract: The disclosure provides an electrophotographic toner and methods for preparing the electrographic toner. The electrographic toner includes a binder, a colorant and a releasing agent, wherein the electrophotographic toner includes strontium (Sr), iron (Fe), titanium (Ti), and silicon (Si) containing particles; wherein, if [Sr], [Fe], [Ti] and [Si] denote the intensities of Sr, Fe, Ti, and Si in the electrophotographic toner, respectively, as measured by X-ray fluorescence spectrometry, then the [Sr]/[Fe] ratio is in the range of about 5.0×10?1 to about 4.5, the [Ti]/[Fe] ratio is in the range of about 5.0×10?1 to about 8.1×10?1, and the [Si]/[Fe] ratio is in the range of about 2.0×10?3 to about 4.0×10?3.Type: GrantFiled: August 10, 2010Date of Patent: July 31, 2012Assignee: Samsung Electronics Co., Ltd.Inventors: Kyung-yeon Kang, Sang-yup Kim, Hong-chul Shin, Sung-jin Park
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Patent number: 8221948Abstract: Environmentally friendly toner particles are provided which may, in embodiments, include a bio-based amorphous polyester resin, optionally in combination with another amorphous resin and/or a crystalline resin. Toner particles may, in embodiments, have a core-shell configuration, with the shell formed of the bio-based amorphous polyester resin, the amorphous polyester resin, the crystalline polyester resin, or combinations thereof.Type: GrantFiled: February 6, 2009Date of Patent: July 17, 2012Assignee: Xerox CorporationInventors: Ke Zhou, Richard P. N. Veregin, Gwynne McAneney-Lannen, Edward G. Zwartz, Maria N. V. McDougall, Guerino Sacripante, Karen A. Moffat
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Patent number: 8221951Abstract: A toner and method for making a toner that includes an amorphous resin, a crystalline resin, and a cyanine dye. The cyanine dye improves heat cohesion without negatively effecting other desirable properties.Type: GrantFiled: March 5, 2010Date of Patent: July 17, 2012Assignee: Xerox CorporationInventors: Ke Zhou, Cuong Vong, Edward Graham Zwartz, Karen A. Moffat
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Patent number: 8216758Abstract: A toner whose flowability, chargeability and fixing property are enhanced, a developer, a developing device and an image forming apparatus are provided. The toner comprises a toner particle in which a shell layer is formed on a surface of a core particle, and external additive, where (1) the shell layer is formed in a film on the surface of the core particle, (2) a shape factor SF-2 is 120 or more and 140 or less, and (3) a BET specific surface area measured by the BET method is 1.2 m2/cm3 or more and 4.0 m2/cm3 or less. The developer containing such a toner is filled into the developing device in the image forming apparatus in order to form an image.Type: GrantFiled: May 29, 2009Date of Patent: July 10, 2012Assignee: Sharp Kabushiki KaishaInventors: Saori Yamada, Yoshitaka Kawase, Yoshiaki Akazawa
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Patent number: 8211607Abstract: Toner particles are provided which may, in embodiments, include a gel. In embodiments, the toner particles may have a core-shell configuration, with the gel in the core, the shell, or both. The gel may prevent a crystalline resin in the core of the toner particles from migrating to the toner surface.Type: GrantFiled: August 27, 2008Date of Patent: July 3, 2012Assignee: Xerox CorporationInventors: Ke Zhou, Karen Ann Moffat, Edward G. Zwartz, Richard P. N. Veregin, Maria N. V. McDougall
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Patent number: 8211602Abstract: An image forming apparatus comprising an electrophotographic photoreceptor having a photosensitive layer on an electroconductive substrate, and a toner for developing an electrostatic charge image, wherein the photosensitive layer of the electrophotographic photoreceptor contains a phthalocyanine obtained via an acid paste step; the toner for developing an electrostatic charge image is a toner for developing an electrostatic charge image containing toner matrix particles formed in an aqueous medium; the toner has a volume median diameter (Dv50) of from 4.0 ?m to 7.0 ?m; and the relationship between the volume median diameter (Dv50) and the percentage in number (Dns) of toner particles having a particle diameter of from 2.00 ?m to 3.56 ?m satisfies the following formula (1): Dns?0.233 EXP(17.3/Dv50)??(1).Type: GrantFiled: August 3, 2010Date of Patent: July 3, 2012Assignee: Mitsubishi Chemical CorporationInventors: Teruyuki Mitsumori, Kozo Ishio, Hiroaki Takamura, Masaya Oota, Shiho Sano, Takeshi Oowada, Masakazu Sugihara, Teruki Senokuti, Shiro Yasutomi, Yumi Hirabaru
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Publication number: 20120156608Abstract: A toner for electrostatic image development which is excellent in latitude for environment conditions and is capable of giving prints superior in outputted image stability is disclosed, comprising a resin and a colorant, and the resin comprising a resin (A) having a structural unit represented by the following formula (1) or formula (2).Type: ApplicationFiled: December 9, 2011Publication date: June 21, 2012Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.Inventor: Shingo FUJIMOTO
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Patent number: 8197998Abstract: Toner particles are provided which may, in embodiments, include a core and a shell. In embodiments, charge control agents may be co-emulsified with a resin utilized to form a shell. The shell may prevent a crystalline resin in the core from migrating to the toner surface. Inclusion of the charge control agent in the shell itself may provide the resulting toner particles with desirable charge characteristics and sensitivity to relative humidity.Type: GrantFiled: May 20, 2009Date of Patent: June 12, 2012Assignee: Xerox CorporationInventors: Ke Zhou, Maria N. V. McDougall, Karen A. Moffat, Richard P. N. Veregin, Enno E. Agur
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Publication number: 20120141932Abstract: A method for producing a developer, the method includes aggregating first fine particles and second fine particles in a dispersion liquid, said dispersion liquid containing the first fine particles which contain at least a binder resin, and the second fine particles which contain a coloring compound, a color developer and a decolorizing agent and have been subjected to a master batch treatment; and forming aggregate particles.Type: ApplicationFiled: December 5, 2011Publication date: June 7, 2012Applicants: TOSHIBA TEC KABUSHIKI KAISHA, KABUSHIKI KAISHA TOSHIBAInventor: Toshiaki Yamauchi
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Patent number: 8187780Abstract: Environmentally friendly toner particles are provided which may, in embodiments, include a biodegradable semi-crystalline polyester resin and a biodegradable amorphous polyester resin.Type: GrantFiled: October 21, 2008Date of Patent: May 29, 2012Assignee: Xerox CorporationInventors: Gwynne McAneney-Lannen, Guerino G. Sacripante, Edward G. Zwartz, Maria N. V. McDougall
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Publication number: 20120129092Abstract: Methods of encapsulating particles (260) in polymer (280, 382, 384) and compositions of matter using such encapsulated particles (260). Methods include mixing particles (260) of one or more materials with one or more initial radical polymerizable monomers (265) and one or more initial charge-generating components (270) to form a first suspension of monomer-wetted particles (260/265/270), mixing the first suspension with an aqueous dispersant medium (275) to form a second suspension, adding one or more initial reaction initiators to at least one of the first suspension and the second suspension, subjecting the second suspension to homogenization sufficient to form a stable submicron emulsion having an aqueous continuous phase (275), and reacting available radical polymerizable monomers (265) of the emulsion to encapsulate the particles (260) in one or more layers of polymer (280, 382, 384) and to incorporate ionic species from available charge-generating components (270).Type: ApplicationFiled: July 31, 2009Publication date: May 24, 2012Inventors: Doris Pik-Yiu Chun, Hou T. Ng
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Patent number: 8182973Abstract: An electrostatic-image-developing toner is obtained by aggregating: resin particles, each of which has a core-shell structure, in which a difference in glass transition temperature between a resin constituting the core and a resin constituting the shell is about 20° C. or more; and releasing agent particles, each of which includes a polyester block copolymer having a weight-average molecular weight of about 3,000 or less and containing a non-crystalline polyester block containing a cyclic structure in the main chain and a crystalline polyester block containing no cyclic structure in the main chain.Type: GrantFiled: March 13, 2009Date of Patent: May 22, 2012Assignee: Fuji Xerox Co., Ltd.Inventors: Yasuo Matsumura, Hirotaka Matsuoka, Hideo Maehata, Takashi Imai
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Patent number: 8178274Abstract: The present disclosure provides toners and processes for preparing toner particles possessing excellent charging characteristics. The process includes forming a dispersion including at least one organic and/or organometallic charge control agent, and then combining that dispersion with an emulsion suitable for use in forming toner particles.Type: GrantFiled: July 21, 2008Date of Patent: May 15, 2012Assignee: Xerox CorporationInventors: Enno E. Agur, Daryl W. Vanbesien, Ke Zhou, Michael S. Hawkins, Maria N. V. McDougall, Richard P. N. Veregin, Edward G. Zwartz
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Publication number: 20120107737Abstract: Toner particles are provided which may, in embodiments, include a core and a shell formed in situ. The resins utilized to form the core, the shell, or both, may be contacted with a water soluble initiator. The resin, in embodiments present in the shell, cross-links at a temperature near the temperature for coalescence, and may prevent a crystalline resin in the core from migrating to the toner surface.Type: ApplicationFiled: January 6, 2012Publication date: May 3, 2012Applicant: XEROX CORPORATIONInventors: Ke Zhou, Edward G. Zwartz, Karen Ann Moffat
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Patent number: 8168361Abstract: An emulsion aggregation toner composition includes toner particles including: an amorphous polyester resin; an optional crystalline resin; an optional colorant; an optional wax; an optional coagulant; and a polymeric or oligomeric hydroxy ketone photo initiator capable of initiating crosslinking of said polyester resin, wherein at least one of the amorphous polyester resin and the optional crystalline resin when present is unsaturated.Type: GrantFiled: October 15, 2009Date of Patent: May 1, 2012Assignee: Xerox CorporationInventors: Ke Zhou, Daryl W. Vanbesien, Edward G. Zwartz, Guerino G. Sacripante, Karen A. Moffat
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Publication number: 20120100476Abstract: The present invention relates to a pressure fixing toner which can be fixed at a lower temperature to enable energy-efficient high-speed printing, and a preparation method thereof. The pressure fixing toner comprises: a core which comprises a wax mixture including a wax and a pigment; and a shell which comprises a polymer or copolymer of at least one kind of polymerizable monomer selected from the group consisting of an aromatic vinyl-based monomer, an acrylate-based monomer, a methacrylate-based monomer and a diene-based monomer, and surrounds the core. The content of the wax of the core is 44-93 parts by weight based on 100 parts by weight of the total toner.Type: ApplicationFiled: June 16, 2010Publication date: April 26, 2012Applicant: LG CHEM, LTD.Inventors: Wook Jang, Chang-Soon Lee
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Patent number: 8142970Abstract: A toner having a core with a first latex having a specific glass transition temperature, and further having a shell surrounding the core with a second latex having a specific glass transition temperature and possessing functional groups, and processes for producing the same.Type: GrantFiled: August 24, 2010Date of Patent: March 27, 2012Assignee: Xerox CorporationInventors: Zhen Lai, Yuhua Tong, Chieh-Min Cheng, Peter V. Nguyen, Jon T. Owens
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Patent number: 8137885Abstract: A hybrid toner includes micro cylinders, cores inserted into the micro cylinders, and an external addition layer covering the micro cylinders to which the cores are inserted. The hybrid toner prevents a toner blocking phenomenon, image contamination, and low storage stability which occur due to dispersion of wax and colorants to an outer surface of the toner.Type: GrantFiled: April 4, 2008Date of Patent: March 20, 2012Assignee: Samsung Electronics Co., Ltd.Inventors: In Kim, Sang-deok Kim, Kyung-yol Yon
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Patent number: 8133649Abstract: Toner particles are provided which may, in embodiments, include a high molecular weight branched or cross-linked polyester to decrease image gloss and to increase toner elasticity to prevent surface additives impaction. In embodiments, the toner particles may have a core-shell configuration, with the high molecular weight polyester in the core, the shell, or both.Type: GrantFiled: December 1, 2008Date of Patent: March 13, 2012Assignee: Xerox CorporationInventors: Maria N. V. McDougall, Ke Zhou, Edward G. Zwartz, Daryl W. Vanbesien, John L. Pawlak, Paul J. Gerroir, Suxia Yang, Richard P. N. Veregin, Karen Ann Moffat
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Publication number: 20120040285Abstract: A process for producing a core-shell toner is provided in which the toner has core particles containing at least a binder resin (1), a colorant and a release agent and shell layers which contain at least a resin (2) and with which the core particles are covered; and the process including the steps of (A) mixing a binder resin-(1) dispersion, a colorant dispersion and a release agent dispersion, (B) adding to a mixed dispersion thus obtained an agglomerating agent to effect agglomeration, (C) adding to core agglomerated particles thus formed a mixture prepared by mixing the resin-(2) dispersion and a metal salt to make the resin (2) adhere to the surfaces of the core agglomerated particles, and (D) heating core-shell agglomerated particles thus formed to a temperature not lower than the glass transition temperatures of the binder resin (1) and resin (2) to effect fusion thereof.Type: ApplicationFiled: May 19, 2010Publication date: February 16, 2012Applicant: CANON KABUSHIKI KAISHAInventors: Takaho Shibata, Masayoshi Kato, Ryuji Higashi, Takayuki Toyoda, Ryo Natori, Yuya Chimoto
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Patent number: 8105744Abstract: An image forming method includes forming an electrostatic latent image on a surface of a latent image carrier; developing the electrostatic latent image with a developing agent including a toner to form a toner image; transferring the toner image onto a surface of a target to obtain a transferred toner image; and fixing the transferred toner image; wherein the toner includes a resin particle having a core-shell structure, both of a resin constituting the core and a resin constituting the shell are a non-crystalline resin, glass transition temperatures of the resin constituting the core and the resin constituting the shell are different by about 20° C. or greater, the resin constituting the shell includes an acidic polar group, a basic polar group, or an alcoholic hydroxy group, and the fixing of the transferred toner image is performed by applying a pressure on the transferred toner image without heating.Type: GrantFiled: March 12, 2008Date of Patent: January 31, 2012Assignee: Fuji Xerox Co., Ltd.Inventor: Yasuo Matsumura
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Patent number: 8097391Abstract: Provided is a toner for developing electrostatic image which is excellent in shelf stability, and is further excellent in low-temperature fixability so as to be capable of maintaining a high fixing rate even at a low fixing temperature. A toner for developing electrostatic image is used which comprises colored resin particles containing a binder resin, a colorant, and a parting agent, wherein the parting agent is an aliphatic hydrocarbon polymer obtained by polymerizing an aliphatic hydrocarbon monomer.Type: GrantFiled: January 29, 2007Date of Patent: January 17, 2012Assignee: Zeon CorporationInventor: Takashi Iga
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Patent number: 8092972Abstract: Toner particles are provided which may, in embodiments, include a core and a shell formed in situ. The resins utilized to form the core, the shell, or both, may be contacted with a water soluble initiator. The resin, in embodiments present in the shell, cross-links at a temperature near the temperature for coalescence, and may prevent a crystalline resin in the core from migrating to the toner surface.Type: GrantFiled: August 27, 2008Date of Patent: January 10, 2012Assignee: Xerox CorporationInventors: Ke Zhou, Edward G. Zwartz, Karen Ann Moffat
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Patent number: 8088544Abstract: Nano-sized particles for use in making emulsion aggregation toner particles have a core portion and a shell portion, wherein the core portion of the nano-sized particles includes crystalline resin and the shell portion includes amorphous resin and is substantially to completely free of the crystalline resin.Type: GrantFiled: July 30, 2007Date of Patent: January 3, 2012Assignee: Xerox CorporationInventor: Guerino G. Sacripante
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Publication number: 20110318685Abstract: A method of making toner particles, including mixing at least one emulsion of at least one resin, a colorant, an optional wax, and optional additives to form a slurry; heating the slurry to form aggregated particles in the slurry; freezing aggregation of the particles by adjusting the pH; and heating the aggregated particles in the slurry to coalesce the particles into toner particles.Type: ApplicationFiled: June 29, 2010Publication date: December 29, 2011Applicant: XEROX CORPORATIONInventors: Daryl W. Vanbesien, Paul Gerroir, Karen A. Moffat, Melanie L. Davis, Abdisamed Sheik-Qasim, David Kurceba, Faisal Shamshad, Michael D'Amato, Juan A. Morales-Tirado
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Patent number: 8084180Abstract: Toner particles are provided which may, in embodiments, include a core possessing at least one polyester resin in combination with a colorant, optional wax, and optional other additives, and a shell over the core including a high molecular weight amorphous polyester resin. The high molecular weight amorphous polyester resin in the shell may prevent any crystalline polyester resin in the core from migrating to the toner surface.Type: GrantFiled: June 6, 2008Date of Patent: December 27, 2011Assignee: Xerox CorporationInventors: Ke Zhou, Maria N. V. McDougall, Edward G. Zwartz, Karen Ann Moffat, Paul J. Gerroir
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Patent number: 8080352Abstract: Toner particles, including at least one binder, at least one colorant, and at least one metal oxide surface additive, wherein the at least one metal oxide surface additive is a metal oxide particle covalently bonded with at least one polycondensation polymer.Type: GrantFiled: October 4, 2007Date of Patent: December 20, 2011Assignee: Xerox CorporationInventor: Karen A. Moffat
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Electrographic carrier, developer, developing method, image forming apparatus, and process cartridge
Patent number: 8067141Abstract: A carrier is provided including a core and a resin layer located overlying the core, wherein the carrier has a weight average particle diameter (Dw) of from 22 to 50 ?m, a ratio (Dw/Dp) of the weight average particle diameter (Dw) to a number average particle diameter (Dp) of from 1 to 1.30, a shape factor SF-1 of from 100 to 120, and a shape factor SF-2 of from 100 to 120, and wherein the carrier comprises core particles satisfying the following relationship 0.52<(d/D)<1.0 in an amount of from 0 to 10,000 ppm by number: wherein D (?m) represents a diameter of a circle having the same area as that of a projected image of a core particle and d (?m) represents a diameter of a circle having the same area as that of a projected image of a maximum hollow present in the core particle.Type: GrantFiled: August 31, 2007Date of Patent: November 29, 2011Assignee: Ricoh Company, Ltd.Inventors: Kimitoshi Yamaguchi, Naoki Imahashi, Masashi Nagayama -
Publication number: 20110281209Abstract: A toner containing: a core containing at least a first binder resin, a colorant, and a releasing agent; and a shell containing at least a second binder resin; wherein the toner has a core-shell structure, and has a softening index of 86° C. to 95° C. and a thermal hardness of 0.7 to 1.8.Type: ApplicationFiled: May 9, 2011Publication date: November 17, 2011Inventors: Hideki SUGIURA, Yuka MIZOGUCHI
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Publication number: 20110262858Abstract: The present invention relates to a porous toner particle with encapsulated metallic flakes. The porous particle containing metallic flakes can be useful for reproduction of a metallic hue upon fusing to a substrate, preferably golden or silvery hue, and for manufacturing of printed circuits, by a printing process, especially electrophotography.Type: ApplicationFiled: April 26, 2010Publication date: October 27, 2011Inventors: Mridula Nair, Xiqiang Yang, Joseph S. Sedita