Abstract: Liquid electrographic toners are derived from organosols incorporating amphipathic copolymeric binder particles that include polymerizable, crystallizable compounds chemically incorporated into the dispersed portion of the copolymer. The invention further provides organosols that include amphipathic copolymeric binder particles that include a dispersed (D) portion and a solvated (S) portion, wherein the D portion has a high glass transition temperature, and at least one polymerizable, crystallizable compound is chemically incorporated into the D portion, the S portion, or both the D and S portion of the copolymer. Methods of making and electrographically printing liquid toners derived from these organosols are also described. The invention is particularly suited for preparing liquid toners for electrophotographic printing.

Abstract: Positive liquid electrographic toner compositions are provided comprising a liquid carrier having a Kauri-Butanol number less than about 30 mL and a plurality of positively charged toner particles dispersed in the liquid carrier. The toner particles comprise a polymeric binder comprising at least one amphipathic graft copolymer comprising one or more S material portions and one or more D material portions. The toner composition additionally comprises a charge control adjuvant that is an acid or a base. These compositions have surprising bulk conductivity and charge per mass properties, particularly as the toner particles are depleted from the toner composition during printing operations.

Abstract: The invention provides an ink composition comprising a charge generating material and a medium wherein the charge generating material absorbs radiation in both the near infra-red and visible regions of the electromagnetic spectrum. Also provided is an electrophotographic toner composition comprising a binder resin and the charge generating material. The compositions are useful in, for example, security marking wherein the composition is printed on an article or substrate. Methods of establishing the authenticity of an article or substrate are also provided which comprise detecting an absorption of infra-red radiation by the charge generating material.

Abstract: Liquid electrographic toner compositions are provided that comprise at least one visual enhancement additive encapsulated within an amphipathic copolymer. The amphipathic copolymer comprises one or more S portions and one or more D portions. Methods of making and methods of using these toner compositions are also provided.

Abstract: Liquid toner compositions having utility in electrographic applications. Organosol liquid toner compositions comprise binder particles dispersed in a nonaqueous liquid carrier, wherein the particles are derived from ingredients comprising one or more crosslinkable amphipathic copolymer(s). The organosol is easily combined with additional ingredients, such as one or more visual enhancement additives and other desired ingredients, and subjected to mixing processes to form a liquid toner composition. Methods of making and electrographically printing liquid toners derived from these organosols are also described.

Abstract: The invention provides liquid toner compositions in which the polymeric binder is chemically grown in the form of copolymeric binder particles dispersed in a liquid carrier. The polymeric binder includes one amphipathic copolymer comprising one or more S material portions and one or more D material portions, wherein the components of the composition comprise sufficient crosslinking functionality to provide a three dimensional gel of controlled rigidity which can be reversibly reduced to a fluid state by application of energy. The toners as described herein surprisingly provide compositions that are particularly suitable for electrophotographic processes wherein the transfer of the image from the surface of a photoconductor to an intermediate transfer material or directly to a print medium is carried out without film formation on the photoconductor.

Abstract: A liquid developer electrophotographic apparatus and method for developing one or more successive color images on a previous color image formed on a latent image retaining body, wherein peeling off the prior color image is prevented by establishing a reversible electrophoretic transfer efficiency of toner particles in the prior toner image to be not greater than 60% in the liquid developer for the successive color image while applying an electrical potential difference between the latent image retaining body and a developing electrode for the successive developing step(s). A resin content of the toner particles forming the previous color image may be selected to achieve the reversible electrophoretic transfer efficiency of 60% or less.

Abstract: Liquid electrographic toner compositions are provided comprising a liquid carrier having a Kauri-Butanol number less than about 30 mL and a plurality of toner particles dispersed in the liquid carrier. The toner particles comprise polymeric binder and a pigment comprising a first ionic dye component ionically complexed with a second ionic dye component in a predetermined ratio to form an ionically complexed colorant compound exhibiting a predetermined color. The colorant compound has a molecular weight of less than about 5000 Daltons and is substantially free of metals that are not covalently bonded to the colorant compound. Toners comprising pigments comprising a ionic dye component and a second ionic dye component complexed to form ionically complexed compounds that together in a colorant composition exhibit a predetermined color are also provided. Methods of making and using these toners are disclosed.

Abstract: The invention provides liquid toner compositions in which the polymeric binder is chemically grown in the form of copolymeric binder particles dispersed in a liquid carrier. The polymeric binder includes one amphipathic copolymer comprising one or more S material portions and one or more D material portions, wherein the components of the composition comprise sufficient acid and base functionality to provide a three dimensional gel of controlled rigidity which can be reversibly reduced to a fluid state by application of energy. The toners as described herein surprisingly provide compositions that are particularly suitable for electrophotographic processes wherein the transfer of the image from the surface of a photoconductor to an intermediate transfer material or directly to a print medium is carried out without film formation on the photoconductor.

Abstract: Amphipathic copolymers are provided comprising one or more S portions and one or more D portions. The copolymers have a chromophore covalently bonded thereto via a urethane, urea or amide linkage. These copolymers provide exceptionally useful components in toner compositions, because they provide easily prepared color-imparting particles that provide excellent color rendition.

Abstract: The invention provides liquid toner compositions in which the polymeric binder is chemically grown in the form of copolymeric binder particles dispersed in a liquid carrier. The polymeric binder includes one amphipathic copolymer that comprises the residue of a Soluble High Tg Monomer. The toners described herein exhibit surprisingly low fusion temperatures, yet are surprisingly resistant to blocking, are non-tacky and are resistant to marring and undesired erasure.

Abstract: The invention provides liquid toner compositions in which the polymeric binder is chemically grown in the form of copolymeric binder particles dispersed in a liquid carrier. The polymeric binder includes one amphipathic copolymer comprising one or more S material portions and one or more D material portions, wherein the components of the composition comprise sufficient proton donor and proton acceptor functionality to provide a three dimensional gel of controlled rigidity which can be reversibly reduced to a fluid state by application of energy. The toners as described herein surprisingly provide compositions that are particularly suitable for electrophotographic processes wherein the transfer of the image from the surface of a photoconductor to an intermediate transfer material or directly to a print medium is carried out without film formation on the photoconductor.

Abstract: An oil based ink composition for inkjet printer comprising colored resin particles obtained by dispersion polymerization of a monofunctional polymerizable monomer (A) and a macromonomer (M) copolymerizable with the monomer (A) with coloring component fine particles comprising a surface-treated coloring agent, which are dispersed in a non-aqueous solvent having a dielectric constant of from 1.5 to 20 and a surface tension of from 15 to 60 mN/m at 25° C., as seed particles, in the presence of a dispersion stabilizer (P) soluble in the non-aqueous solvent and a polymerization initiator.

Abstract: The invention provides liquid toner compositions in which the polymeric binder is chemically grown in the form of copolymeric binder particles dispersed in a liquid carrier. The polymeric binder includes one amphipathic copolymer comprising one or more S material portions and one or more D material portions, wherein the S material portion of the copolymer has molecular weight and solubility properties selected to provide a three dimensional gel of controlled rigidity which can be reversibly reduced to a fluid state by application of energy. The toners as described herein surprisingly provide compositions that are particularly suitable for electrophotographic processes wherein the transfer of the image from the surface of a photoconductor to an intermediate transfer material or directly to a print medium is carried out without film formation on the photoconductor.

Abstract: A toner particle adapted for use in electrostatic image formation, comprising a polymer and flakes of metal dispersed in the polymer.

Abstract: A liquid developer for high-quality image reproduction and a method of preparing the liquid developer. The liquid developer exhibits good pigment dispersion by the introduction of organosol. The liquid developer contains fine toner particles of a uniform size with a volume-average to number-average particle diameter ratio of 1.5-2.5, and thus can produce high-resolution images. The liquid developer preparation method is environmentally friendly, simple, and cost effective because no cosolvent is used, thus eliminating the need for a cosolvent removal process.

Abstract: There is provided a dispersion composition which has excellent dispersion stability and hardly sediments even after a long-term storage. This dispersion composition is a composition comprising a particulate material dispersed in an organic solvent, wherein a graft copolymer which has a particle diameter of 0.01-1 ?m and self-disperses in said organic solvent is adsorbed to at least a part of the outer surface of said particulate material and a graft chain of said graft copolymer comprises a polysiloxane and an alkylene group of 1-18 carbon atoms.

Abstract: A liquid ink for developing electrophotography images comprises: a) a carrier liquid having a Kauri-Butanol number less than 30; b) a grafted co-polymer comprising a (co)polymeric steric stabilizer covalently bonded to a thermoplastic (co)polymeric core that is insoluble in the carrier liquid, wherein the grafted co-polymer is derived from at least a polymerizable organic compound having at least one acid group or at least one acid group; c) a dispersant having, respectively, at least an amine group or at least one acid group to form an acid-base copolymer-dispersant system or a base-acid copolymer-dispersant system, wherein the mole ratio of the amine group to the acid group is between 0.3 and 1.5 in the base-acid copolymer-dispersant system and the mole ratio of the acid group to the base group in the acid-base copolymer dispersant system is between 0.3 and 1.

Abstract: A liquid developer which includes an insulating liquid, and toner fine particles containing a coloring agent and a toner resin. In the liquid developer, its electric capacitance does not significantly vary in an electric circuit where an electrical double-layer capacitor and an electronic resistance corresponding to a velocity of an electron exchange during an electrode reaction are connected in parallel, and a resistance corresponding to an electric conductivity of the insulating liquid is connected in series. The coloring agent has a coating layer so as to maintain distances between the toner fine particles. The insulating liquid has a viscosity of 0.5 mPa·s to 1000 mPa·s, a specific resistance of 1×1012 ?cm or more, and a surface tension of 30 dyn/cm or less, and may be a nonvolatile liquid having a boiling point of 100° C. or higher.

Abstract: The present invention relates to a liquid toner composition suited for development of electrostatic charge images, magnetic patterns or DEP (Direct Electrostatic Printing). More specifically the present invention relates to a specific liquid toner composition allowing transfusing of the toner image from a temporary carrier to the final substrate at low temperature.

Abstract: Charged toner particles for use in electrostatic imaging, comprising: a toner polymer; and at least one particulate fluorescent material, wherein the toner particles are formed with fibrous extensions.

Abstract: The invention provides liquid toner compositions in which the polymeric binder is chemically grown in the form of copolymeric binder particles dispersed in a liquid carrier. The polymeric binder includes one amphipathic copolymer comprising one or more S material portions and one or more D material portions, wherein the S material portion of the copolymer has molecular weight and solubility properties selected to provide a three dimensional gel of controlled rigidity which can be reversibly reduced to a fluid state by application of energy. The toners as described herein surprisingly provide compositions that are particularly suitable for electrophotographic processes wherein the transfer of the image from the surface of a photoconductor to an intermediate transfer material or directly to a print medium is carried out without film formation on the photoconductor.

Abstract: The invention provides liquid toner compositions in which the polymeric binder is chemically grown in the form of copolymeric binder particles dispersed in a liquid carrier. The polymeric binder includes one amphipathic copolymer comprising one or more S material portions and one or more D material portions, wherein the components of the composition comprise sufficient acid and base functionality to provide a three dimensional gel of controlled rigidity which can be reversibly reduced to a fluid state by application of energy. The toners as described herein surprisingly provide compositions that are particularly suitable for electrophotographic processes wherein the transfer of the image from the surface of a photoconductor to an intermediate transfer material or directly to a print medium is carried out without film formation on the photoconductor.

Abstract: The invention provides liquid toner compositions in which the polymeric binder is chemically grown in the form of copolymeric binder particles dispersed in a liquid carrier. The polymeric binder includes one amphipathic copolymer comprising one or more S material portions and one or more D material portions, wherein the components of the composition comprise sufficient crosslinking functionality to provide a three dimensional gel of controlled rigidity which can be reversibly reduced to a fluid state by application of energy. The toners as described herein surprisingly provide compositions that are particularly suitable for electrophotographic processes wherein the transfer of the image from the surface of a photoconductor to an intermediate transfer material or directly to a print medium is carried out without film formation on the photoconductor.

Abstract: Amphipathic copolymers are provided comprising one or more S portions and one or more D portions. The copolymers have a chromophore covalently bonded thereto via a urethane, urea or amide linkage. These copolymers provide exceptionally useful components in toner compositions, because they provide easily prepared color-imparting particles that provide excellent color rendition.

Abstract: A liquid developer electrophotographic apparatus and method for developing one or more successive color images on a previous color image formed on a latent image retaining body, wherein peeling off the prior color image is prevented by establishing a reversible electrophoretic transfer efficiency of toner particles in the prior toner image to be not greater than 60% in the liquid developer for the successive color image while applying an electrical potential difference between the latent image retaining body and a developing electrode for the successive developing step(s). A resin content of the toner particles forming the previous color image may be selected to achieve the reversible electrophoretic transfer efficiency of 60% or less.

Abstract: The invention provides an ink composition comprising a charge generating material and a medium wherein the charge generating material absorbs radiation in both the near infra-red and visible regions of the electromagnetic spectrum. Also provided is an electrophotographic toner composition comprising a binder resin and the charge generating material. The compositions are useful in, for example, security marking wherein the composition is printed on an article or substrate. Methods of establishing the authenticity of an article or substrate are also provided which comprise detecting an absorption of infra-red radiation by the charge generating material.

Abstract: In electrophoretic media, it is advantageous to use pigment particles having about 1 to 15 percent by weight of a polymer chemically bonded to, or cross-linked around, the pigment particles. The polymer desirably has a branched chain structure with side chains extending from a main chain. Charged or chargeable groups can be incorporated into the polymer or can be bonded to the particles separately from the polymer. The polymer-coated particles can be prepared by first attaching a polymerizable or polymerization-initiating group to the particle and then reacting the particle with one or more polymerizable monomers or oligomers.

Abstract: A liquid ink composition and a method for producing the same, wherein the liquid ink composition includes a colorant, a charge control agent to regulate electrostatic properties of the colorant, and an organosol to disperse and bind the colorant and the charge control agent. The colorant may be coated with a thermoplastic resin to improve binding with the organosol. By coating the colorant with the thermoplastic resin, the affinity of the colorant for the organosol is facilitated, increasing a size of particles in the liquid ink composition, so that the control of the particles improves the image quality, and micro particles of the carbon black pigment alone do not substantially exist in the printer to prevent printing on a non-image area, thus producing a clear printed image and preventing contamination of other parts in the printer during printing.

Abstract: This invention relates to a liquid ink for developing electrophotographic images comprising: a) a carrier liquid having a Kauri-Butanol number less than 30; b) a plastisol; c) a dispersant; and d) a charge director wherein: a. for a positive charge director, the dispersant has amine groups and the plastisol comprises polymeric particles having acid groups and an acid value between 30 and 150 mg KOH/g such that the mole ratio of the amine groups to the acid groups is between 0.075 and 0.3; and b. for a negative charge director, the plastisol comprises a polymer having an amine value between 5 and 200 mg KOH/g and the dispersant has acid groups such that the mole ratio of the acid groups to the amine groups is between 0.075 and 0.3.

Abstract: A liquid developer electrophotographic apparatus and method for developing one or more successive color images on a previous color image formed on a latent image retaining body, wherein peeling off the prior color image is prevented by establishing a reversible electrophoretic transfer efficiency of toner particles in the prior toner image to be not greater than 60% in the liquid developer for the successive color image while applying an electrical potential difference between the latent image retaining body and a developing electrode for the successive developing step(s). A resin content of the toner particles forming the previous color image may be selected to achieve the reversible electrophoretic transfer efficiency of 60% or less.

Abstract: A toner for a liquid developer and the like which have low cohesive force and excellent dispersion stability and storage stability and which enable formation of high-quality images and are highly reliable. The toner for a liquid developer comprises an epoxy compound whose epoxy equivalent weight is 1000 or less. An aspect in which the epoxy compound is at least one selected from bisphenol A epoxy resins, novalak epoxy resins, bisphenol F epoxy resins, biphenyl epoxy resins, isocyanate-modified epoxy resins, naphthalene epoxy resins, dicyclo epoxy resins, and brominated epoxy resins, and the like are preferable.

Abstract: Liquid toner compositions having utility in electrographic applications. Organosol liquid toner compositions comprise binder particles dispersed in a nonaqueous liquid carrier, wherein the particles are derived from ingredients comprising one or more crosslinkable amphipathic copolymer(s). The organosol is easily combined with additional ingredients, such as one or more visual enhancement additives and other desired ingredients, and subjected to mixing processes to form a liquid toner composition. Methods of making and electrographically printing liquid toners derived from these organosols are also described.

Abstract: A liquid developer, a method of manufacturing the same and a method and apparatus for forming an image, which can attain high transfer efficiency and appropriate tolerance to repetitive image formation. The liquid developer includes toner particles dispersed in an electrically non-conductive liquid solvent. Each toner particle has a resin particle, which is non-soluble in the liquid developer, and pigment particles formed on the surface of the resin particle, whereby the pigment particles suppress contact between the resin particles. Preferably the resin particles have a glass transition temperature of not less than room temperature. One example of manufacturing the liquid developer includes a step of milling pigment particles in a resin particles dispersion liquid at a process temperature higher than the glass transition temperature of the resin particles, whereby the pigments are formed on the surface of the resin particles.

Abstract: A liquid developer, a method of manufacturing the same and a method and apparatus for forming an image, which can attain high transfer efficiency and appropriate tolerance to repetitive image formation. The liquid developer includes toner particles dispersed in an electrically non-conductive liquid solvent. Each toner particle has a resin particle, which is non-soluble in the liquid developer, and pigment particles formed on the surface of the resin particle, whereby the pigment particles suppress contact between the resin particles. Preferably the resin particles have a glass transition temperature of not less than room temperature. One example of manufacturing the liquid developer includes a step of milling pigment particles in a resin particles dispersion liquid at a process temperature higher than the glass transition temperature of the resin particles, whereby the pigments are formed on the surface of the resin particles.

Abstract: The invention provides liquid toner compositions in which the polymeric binder is chemically grown in the form of copolymeric binder particles dispersed in a liquid carrier. The polymeric binder includes one amphipathic copolymer that comprises the residue of a Soluble High TgMonomer. The toners described herein exhibit surprisingly low fusion temperatures, yet are surprisingly resistant to blocking, are non-tacky and are resistant to marring and undesired erasure.

Abstract: Liquid electrographic toners are derived from organosols incorporating amphipathic copolymeric binder particles that include polymerizable, crystallizable compounds chemically incorporated into the dispersed portion of the copolymer. The invention further provides organosols that include amphipathic copolymeric binder particles that include a dispersed (D) portion and a solvated (S) portion, wherein the D portion has a high glass transition temperature, and at least one polymerizable, crystallizable compound is chemically incorporated into the D portion, the S portion, or both the D and S portion of the copolymer. Methods of making and electrographically printing liquid toners derived from these organosols are also described. The invention is particularly suited for preparing liquid toners for electrophotographic printing.

Abstract: The invention provides liquid toner compositions in which the polymeric binder is chemically grown in the form of copolymeric binder particles dispersed in a liquid carrier. The polymeric binder includes one amphipathic copolymer comprising one or more S material portions and one or more D material portions, wherein the D material portion has a Tg greater than about 55° C. The toners as described herein surprisingly provide compositions that are particularly suitable for electrophotographic processes wherein the transfer of the image from the surface of a photoconductor to an intermediate transfer material or directly to a print medium is carried out without film formation on the photoconductor.

Abstract: A method and apparatus for fusing toner to a laser printed page. The apparatus includes a photosensitive drum, a laser optic system for tracing an image on the photosensitive drum, a toner supply electrically charged opposite the image traced on the photosensitive drum, and an ultraviolet light source for imparting energy to the toner to fuse the toner to the page. The apparatus facilitates faster print speeds and lower energy consumption than conventional laser printers that require heating elements to fuse the toner to the page.

Abstract: A liquid developer, a method of manufacturing the same and a method and apparatus for forming an image, which can attain high transfer efficiency and appropriate tolerance to repetitive image formation. The liquid developer includes toner particles dispersed in an electrically non-conductive liquid solvent. Each toner particle has a resin particle, which is non-soluble in the liquid developer, and pigment particles formed on the surface of the resin particle, whereby the pigment particles suppress contact between the resin particles. Preferably the resin particles have a glass transition temperature of not less than room temperature. One example of manufacturing the liquid developer includes a step of milling pigment particles in a resin particles dispersion liquid at a process temperature higher than the glass transition temperature of the resin particles, whereby the pigments are formed on the surface of the resin particles.

Abstract: A liquid toner comprising:

Abstract: An electrophotographic liquid developer includes a carrier liquid and toner particles. The toner particles include a colorant and a resin component and are dispersed in the carrier liquid. The resin component includes a polyester resin as a main component. When 0.3 g of the liquid developer is dropped on a filter paper (which is defined in JIS P 3801) from a point of 10 mm height, the carrier liquid diffuses in the filter paper at a speed not lower than 1 mm/minute.

Abstract: An oil based ink composition for inkjet printer comprising colored resin particles obtained by dispersion polymerization of a monofunctional polymerizable monomer (A) and a monofunctional polymerizable monomer (B) copolymerizable with the monomer (A) having a substituent containing a silicon atom and/or a fluorine atom with coloring component fine particles comprising a surface-treated coloring agent, which are dispersed in a non-aqueous solvent having a dielectric constant of from 1.5 to 20 and a surface tension of from 15 to 60 mN/m at 25° C., as seed particles, in the presence of a dispersion stabilizer (P) soluble in the non-aqueous solvent and a polymerization initiator.

Abstract: An oil based ink composition for inkjet printer comprising colored resin particles obtained by dispersion polymerization of a monofunctional polymerizable monomer (A) and a macromonomer (M) copolymerizable with the monomer (A) with coloring component fine particles comprising a surface-treated coloring agent, which are dispersed in a non-aqueous solvent having a dielectric constant of from 1.5 to 20 and a surface tension of from 15 to 60 mN/m at 25° C., as seed particles, in the presence of a dispersion stabilizer (P) soluble in the non-aqueous solvent and a polymerization initiator.

Abstract: A liquid developer for high-quality image reproduction and a method of preparing the liquid developer. The liquid developer exhibits good pigment dispersion by the introduction of organosol. The liquid developer contains fine toner particles of a uniform size with a volume-average to number-average particle diameter ratio of 1.5-2.5, and thus can produce high-resolution images. The liquid developer preparation method is environmentally friendly, simple, and cost effective because no cosolvent is used, thus eliminating the need for a cosolvent removal process.

Abstract: A composition comprises a non-aqueous solvent containing reverse micelle particles formed of block polymers having amphipathic properties. A particle composition and a composition wherein particles are dispersed, which exhibits excellent dispersion properties and can form superbly uniform particles, is provided. Further, display elements, a recording method, and recording apparatus, which employ the composition having excellent dispersion properties and forming superbly uniform particles, are provided.

Abstract: The present invention relates to a liquid toner composition suited for development of electrostatic charge images, magnetic patterns or DEP (Direct Electrostatic Printing). More specifically the present invention relates to a specific liquid toner composition allowing transfusing of the toner image from a temporary carrier to the final substrate at low temperature.

Abstract: This invention relates to a phase change developer comprising: (a) a carrier having a Kauri-butanol number less than 30; and (b) an organosol comprising a graft (co)polymeric steric stabilizer covalently bonded to a thermoplastic (co)polymeric core that is insoluble in said carrier, and said (co)polymeric steric stabilizer comprises a crystallizing polymeric moiety that independently and reversibly crystallizes at or above 30° C., wherein said phase change developer has a melting point at or above 22° C.

Abstract: There is provided a dispersion composition which has excellent dispersion stability and hardly sediments even after a long-term storage. This dispersion composition is a composition comprising a particulate material dispersed in an organic solvent, wherein a graft copolymer which has a particle diameter of 0.01-1 &mgr;m and self-disperses in said organic solvent is adsorbed to at least a part of the outer surface of said particulate material and a graft chain of said graft copolymer comprises a polysiloxane and an alkylene group of 1-18 carbon atoms.

Abstract: This invention relates to a developer storage and delivery system for liquid electrophotography containing: a) a container having an open end; b) a developer inside said container wherein said developer has a viscosity greater than 10 pascal second; and c) a heater near said open end wherein said heater lower the viscosity of said developer to less than 0.01 pascal second.