Toner Having Identified External Additive On Outside Of Toner Particle (e.g., External Fluidity Agent, External Charge Control Agent, Etc.) Patents (Class 430/123.51)
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Patent number: 12187921Abstract: The powder adhesive comprises a thermoplastic resin and particles of an aromatic compound, wherein the particles of an aromatic compound are particles of a compound that has an aromatic ring and an azo bond bonded to the aromatic ring, or are particles of a compound comprising a heteroaromatic ring comprising nitrogen atom; the thermoplastic resin comprises an ester group; and, designating Es (mmol/g) as an ester group concentration in the thermoplastic resin, M (mass %) as a content of the aromatic compound particles in the powder adhesive, and N (mmol/g) as a nitrogen atom concentration in the aromatic compound particles, Es is from 1.0 mmol/g to 4.5 mmol/g, M is from 1.0×10?4 mass % to 1.0×100 mass %, and N is from 5.0 mmol/g to 15.0 mmol/g.Type: GrantFiled: July 26, 2021Date of Patent: January 7, 2025Assignee: Canon Kabushiki KaishaInventors: Yuhei Terui, Shohei Yamashita, Tsutomu Shimano, Koji Nishikawa, Kohei Matsuda, Yuki Nishizawa
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Patent number: 12061440Abstract: The present invention provides a method for producing a toner for electrostatic-image development comprising: a dispersing step of performing a dispersing treatment in which a cavitation effect is obtained on a color resin particle containing a binder resin, a colorant, a charge control agent, and a release agent in an aqueous dispersion medium so as to obtain a dispersion of the color resin particle; and a heating step of performing a heat treatment on the dispersion of the color resin particle at a temperature of equal to or more than a glass transition temperature of the color resin particle and 95° C. or less for a heating time of 5 minutes or more and 10 hours or less.Type: GrantFiled: December 26, 2019Date of Patent: August 13, 2024Assignee: ZEON CORPORATIONInventors: Kojiro Akazaki, Takeru Chiba, Takashi Iga
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Patent number: 11181843Abstract: An electrostatic-image developing toner includes toner particles, layered compound particles, and a free oil. The mass ratio Ma/Mb of the content Ma of the layered compound particles to the content Mb of the free oil is 0.05 or more and 100 or less.Type: GrantFiled: April 7, 2020Date of Patent: November 23, 2021Assignee: FUJIFILM Business Innovation Corp.Inventors: Sakiko Takeuchi, Daisuke Noguchi, Yuka Yamagishi, Yutaka Saito, Kazuhiko Nakamura
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Patent number: 11036156Abstract: A toner is provided which includes: a toner base particle including a binder resin; and an external additive including inorganic particles. A particle size distribution of primary particles of the inorganic particles has a plurality of peaks in the range of from 5 nm through 50 nm. The particle size distribution of the primary particles satisfies all of expressions (1) to (3) below: n1d>n2d??(1); 10<(n1d+n2d)??(2); and 30?{(n2h/n1h)×100}<100??(3), where n1d is a particle diameter (nm) at a peak n1 which is the highest peak among the plurality of peaks and n2d is a particle diameter (nm) of a peak n2 which is the second highest peak among the plurality of peaks, and n1h is a height of the peak n1 and n2h is a height of the peak n2.Type: GrantFiled: January 31, 2020Date of Patent: June 15, 2021Assignee: Ricoh Company, Ltd.Inventors: Kohtaroh Ogino, Masayuki Ishii, Masayuki Kakimoto, Shohichi Sugimoto
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Patent number: 9114604Abstract: An approach is provided for applying a release agent to a substrate having at least a first surface and a second surface. The approach involves determining a presence of at least one ink image applied to at least one portion of at least one of the first surface and the second surface of the substrate by way of at least one step of a printing process. The approach also involves causing, at least in part, the release agent to be applied to the substrate so as to cover the at least one portion of at least one of the first surface and the second surface of the substrate upon which the at least one ink image is applied.Type: GrantFiled: June 13, 2012Date of Patent: August 25, 2015Assignee: Xerox CorporationInventors: Jason LeFevre, Paul McConville, James Michael Chappell, Jennifer Rea, James Edward Williams
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Publication number: 20150111144Abstract: Composite materials such as composite particles have a solid non-elastomeric continuous phase made of an organic polymer having a glass transition temperature of at least 25° C. Dispersed within this solid non-elastomeric continuous phase are many multi-compartment porous chemically crosslinked elastomeric particles that have a mode particle size of at least 1 ?m and up to and including 10 ?m. The composite particles can be used as toner particles in electrophotographic imaging methods to provide fused toner images and especially stacked fused toner images.Type: ApplicationFiled: October 18, 2013Publication date: April 23, 2015Inventors: Mridula Nair, Joseph Salvatore Sedita, Peter David Rollinson
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Patent number: 9005865Abstract: A toner containing toner particles, each of which contains a binder resin and a colorant, and silica particles, wherein the silica particles have a volume average particle diameter (Dv) of 70 nm or more and 500 nm or less, the variation coefficient of diameters of the silica particles, based on volume distribution thereof, is 23% or less, and wherein when the silica particles are heated from 105° C. to 200° C., the ratio of mass decrease is 0.60% or less.Type: GrantFiled: February 14, 2014Date of Patent: April 14, 2015Assignee: Canon Kabushiki KaishaInventors: Naotaka Ikeda, Emi Watanabe, Yuhei Terui, Taiji Katsura
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Patent number: 9005864Abstract: A toner including: toner base particles; and an external additive, the toner base particles each comprising a binder resin and a colorant, wherein the external additive comprises non-spherical particles and spherical particles, wherein the non-spherical particles are each a secondary particle in which spherical primary particles are coalesced together, and wherein the non-spherical particles and the spherical particles in the external additive satisfy a relationship expressed by the following formula (1): 3Ca(%)<Cb(%)??Formula (1) where Ca is greater than 10% but smaller than 20% and Cb is greater than 40% but smaller than 70%, and Ca and Cb are values given by: Ca = ( an ? ? amount ? ? of ? ? the ? ? non ? - ? spherical ? ? particles ? ? ( % ? ? by ? ? mass ) / 100 ) × ( a ? ? projected ? ? area ? ? of ? ? the ? ? non ? - ? spherical ? ? particles ? ? ( cm 2 ? / ? g ) ) ( an ? ? amount ? ? of ? ? theType: GrantFiled: March 8, 2013Date of Patent: April 14, 2015Assignee: Ricoh Company, Ltd.Inventors: Syouko Satoh, Tsuneyasu Nagatomo, Satoshi Kojima, Osamu Uchinokura, Junichi Awamura, Daisuke Ito, Satoshi Ogawa, Kiwako Hirohara, Takahiro Honda, Daisuke Inoue
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Patent number: 8980519Abstract: A toner composition includes a resin, optionally a wax, a colorant, and an acicular surface additive. The toner composition is suitable for use in a single component development system and which composition possesses excellent charging, stability, and flow characteristics.Type: GrantFiled: May 23, 2013Date of Patent: March 17, 2015Assignee: Xerox CorporationInventors: Juan A. Morales-Tirado, Samir Kumar, Michael F. Zona
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Patent number: 8974999Abstract: Toner compositions that having spherical particles and provide stable density. The toner compositions also comprise and deliver a silicone oil to the cleaning subsystem in the image forming apparatus by incorporating an inorganic fine powder additive package that has been mixed with silicone oil in a manner such that the toner is blended with the inorganic fine powder and silicone oil.Type: GrantFiled: September 20, 2013Date of Patent: March 10, 2015Assignee: Xerox CorporationInventors: Juan A. Morales-Tirado, Mark E. Mang, Michael F. Zona, Samir Kumar, Susan J. LaFica
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Patent number: 8956796Abstract: Provided is an electrostatic charge image developing toner including toner base particles which contain a polyester resin and a vinyl resin and does not have a coating layer and wherein the concentration of the polyester resin on the particle surface is higher than the concentration of the polyester resin in the inside of the particles, and a sol-gel silica which has an average circularity of from 0.75 to 0.9, on the surface of the toner base particles.Type: GrantFiled: May 8, 2013Date of Patent: February 17, 2015Assignee: Fuji Xerox Co., Ltd.Inventors: Yasuo Kadokura, Kazufumi Tomita, Hideaki Yoshikawa
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Patent number: 8951708Abstract: The present embodiments relate to methods of making a toner composition. More specifically, the present embodiments relate to methods of including a functional material into a toner composition.Type: GrantFiled: June 5, 2013Date of Patent: February 10, 2015Assignee: Xerox CorporationInventors: Yu Liu, Cuong Vong, Sarah Vella, Gregory McGuire, Richard Klenkler, Nan-xing Hu, Paul Gerroir
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Patent number: 8945806Abstract: An electrostatic charge image developing toner includes toner particles that contain a colorant, a binder resin and a release agent, and an external additive, in which the external additive contains inorganic particles including an aliphatic alcohol having 5 or more carbon atoms and a melting point of 20° C. or lower on the surfaces thereof.Type: GrantFiled: July 25, 2012Date of Patent: February 3, 2015Assignee: Fuji Xerox Co., Ltd.Inventors: Eiji Kawakami, Shintaro Anno, Hirokazu Hamano, Michio Take
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Patent number: 8911923Abstract: The toner for developing an electrostatic charge image includes toner particles containing a colorant, a binder resin, and a release agent, and an external additive, wherein the external additive contains inorganic particles having fluorine atom-containing oil on the hydrophobization-treated surfaces.Type: GrantFiled: August 2, 2012Date of Patent: December 16, 2014Assignee: Fuji Xerox Co., Ltd.Inventors: Yoshifumi Iida, Eiji Kawakami, Shintaro Anno, Masahiro Takagi
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Publication number: 20140363762Abstract: A two-component developing agent for developing an electrostatic latent image includes toner particles composed of toner base particles and an exterior additive attached on the toner base particles, and carrier particles composed of carrier core particles and a coating resin provided on the carrier core particles. The coating resin includes a sulfur atom and a resin obtained by polymerizing an isobutyl methacrylate monomer, and the toner base particles include a sulfur atom.Type: ApplicationFiled: May 28, 2014Publication date: December 11, 2014Applicant: Konica Minolta, Inc.Inventors: Kosuke NAKAMURA, Yoshiyasu MATSUMOTO, Satoshi UCHINO, Hidehito HARUKI, Hiroyuki KOZURU
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Patent number: 8846288Abstract: When being blended in a toner, a barium titanate external additive for toner enhances, in particular, the toner fluidity, electrical properties, and other relevant performance; concurrently achieves high image density and reduced background fog in a printer using the toner; and further reduces image defects, such as void, fading, and the like. An industrially advantageous producing method of the barium titanate external additive for toner is also provided. The external additive for toner of the present invention includes spherical barium titanate having a specific gravity of 5.6 g/ml or less.Type: GrantFiled: January 25, 2007Date of Patent: September 30, 2014Assignee: Nippon Chemical Industrial Co., Ltd.Inventors: Kazuo Ochiai, Shinji Tanabe, Naoaki Narishige
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Publication number: 20140234766Abstract: A toner T1 develops an electrostatic latent image, the toner T1 having relieved charge-up characteristics, improved development characteristics, and improved transfer characteristics. The toner T1 may ensure high charge stability against environmental condition changes, and an appropriate amount of charges at a high printing speed, may reduce background contamination on a photoreceptor, may prevent undesirable fusing onto a blade even after prolonged printing, and may have high transfer efficiency and high image uniformity. The toner T1 may have effective flowability and transportability, and may have good storage stability, so as to be unlikely to cause blocking when stored for an extended time.Type: ApplicationFiled: January 29, 2014Publication date: August 21, 2014Applicant: SAMSUNG Electronics Co., Ltd.Inventors: Se-young YOON, Sung-jin PARK, Seung-sik WOO, Hae-ree JOO
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Patent number: 8758967Abstract: A transparent toner for developing an electrostatic latent image includes toner particles containing a binder resin; and an external additive containing cerium oxide, in which a content of cerium in all toner particles is from 0.05% by weight to 0.20% by weight, the cerium oxide contains a praseodymium, and a content of praseodymium in all toner particles is from 0.001% by weight to 0.050% by weight.Type: GrantFiled: July 9, 2012Date of Patent: June 24, 2014Assignee: Fuji Xerox Co., LtdInventors: Koji Sasaki, Masanobu Ninomiya, Tetsuya Taguchi, Atsushi Sugawara, Yukiaki Nakamura
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Patent number: 8741528Abstract: An electrostatic charge image developing toner including toner particles containing a colorant, a binder resin and a release agent; and an external additive, in which the external additive contains inorganic particles having hydrocarbon oil that contains a saturated hydrocarbon having a ring structure on the surfaces thereof.Type: GrantFiled: August 3, 2012Date of Patent: June 3, 2014Assignee: Fuji Xerox Co., Ltd.Inventors: Shintaro Anno, Yoshifumi Iida, Eiji Kawakami, Masahiro Takagi
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Patent number: 8735036Abstract: An electrostatic charge image developing toner includes: toner particles; and an external additive having an average particle diameter of from about 70 nm to about 420 nm, an average circularity of equal to or less than about 0.9, and a standard deviation of the circularity of greater than 0.2.Type: GrantFiled: March 28, 2012Date of Patent: May 27, 2014Assignee: Fuji Xerox Co., Ltd.Inventors: Katsuyuki Kitajima, Yutaka Saito, Sakon Takahashi, Michio Take
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Patent number: 8735034Abstract: A toner for electrostatic image development containing toner matrix particles having at least a resin binder and a colorant, and an external additive, the external additive having composite oxide particles (an external additive A) that have titania and silica, wherein the external additive A has a core-shell structure in which a core portion has the titania and a shell portion has the silica, wherein the titania is present in the external additive A in an amount of from 75 to 95% by weight, and the resin binder comprising a polyester obtained by polycondensing a carboxylic acid component comprising an isophthalic acid compound and an alcohol component (a polyester A).Type: GrantFiled: December 2, 2011Date of Patent: May 27, 2014Assignee: Kao CorporationInventors: Masahito Yamazaki, Satoshi Kunii
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Patent number: 8728695Abstract: An electrostatic charge image developing toner includes toner particles containing a colorant, a binder resin, and a release agent; and an external additive, wherein the external additive contains inorganic particles which include a compound represented by Formula (1) below on the surfaces thereof: wherein in Formula (1), R1 and R8 each independently represents an alkyl group, R2 to R7 each independently represents an alkyl group or a substituted or unsubstituted phenyl group, and at least three groups of R2 to R7 each independently represents a substituted or unsubstituted phenyl group.Type: GrantFiled: July 27, 2012Date of Patent: May 20, 2014Assignee: Fuji Xerox Co., Ltd.Inventors: Eiji Kawakami, Shintaro Anno, Hirokazu Hamano
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Patent number: 8722293Abstract: An electrostatic charge image developing toner includes toner particles, and an external additive. The toner particles are (1) prepared by forming aggregated particles by aggregating resin particles in a raw material dispersion in which the resin particles are dispersed, and causing the aggregated particles to coalesce by heating an aggregated particle dispersion in which the aggregated particles are dispersed so as to form the toner particles, or (2) obtained by kneading and pulverizing a material including a binder resin and a release agent, and the external additive is silica particles having an average diameter in the range of 100 nm to 500 nm, an average circularity in the range of 0.5 to 0.85, and an average of a ratio of a circle-equivalent diameter Da obtained by plane image analysis to a maximum height H obtained by 3-D image analysis of greater than 1.5 and less than 1.9.Type: GrantFiled: August 3, 2012Date of Patent: May 13, 2014Assignee: Fuji Xerox Co., Ltd.Inventors: Yoshifumi Iida, Hideaki Yoshikawa
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Patent number: 8722301Abstract: A transparent electrostatic charge image developing toner satisfies the relationships of the following Formulas (1), (2), and (3) wherein Dt (?m) is a volume average particle diameter, upper GSDv is an upper volume particle size distribution index, and lower GSDp is a lower number particle size distribution index: 18?Dt?30;??Formula (1): 1.05?upper GSDv?1.20;??Formula (2): 1.29?lower GSDp?1.50??Formula (3).Type: GrantFiled: April 12, 2012Date of Patent: May 13, 2014Assignee: Fuji Xerox Co., LtdInventors: Tsuyoshi Murakami, Satoshi Yoshida
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Patent number: 8715898Abstract: An electrostatic charge image developer includes a toner for developing an electrostatic charge image, containing toner particles including a polyester resin having a rosin skeleton and an external additive, and a carrier having core material particles and a coating resin layer which coats the surface of the core material particles, in which the hardness of the coating resin layer is from 1.2 times to 2.0 times that of the toner particles.Type: GrantFiled: June 27, 2012Date of Patent: May 6, 2014Assignee: Fuji Xerox Co., Ltd.Inventor: Kazuhiko Yanagida
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Patent number: 8703375Abstract: To provide a toner A containing: base particles, each containing polyester, microcrystalline wax, and a colorant; and spherical silica particles having an average primary particle diameter of 100 nm to 150 nm, wherein the microcrystalline wax has an onset temperature of 45° C. to 60° C. as determined by DSC, and a carbon number distribution of 25 to 55.Type: GrantFiled: July 22, 2011Date of Patent: April 22, 2014Assignee: Ricoh Company, Ltd.Inventors: Naohito Shimota, Takahiro Honda, Tsuneyasu Nagatomo, Ryuta Chiba
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Patent number: 8673532Abstract: A method for producing dry toner particles that have similar particle size and shape characteristics as chemically produced toners. The method includes melt-mixing a toner resin with a colorant and, optionally, a wax, to form a toner; grinding the toner to form toner particles; classifying the toner particles into particles averaging 4 to 10 microns in size; blending the classified toner particles with additives in a high-speed blender; and then processing the mixture with optional additional surface additives in a conical mixer. The method produces toner particles that have high circularity and sharper particle size distribution. The surface processing of the toner particles does not affect the internal constituents of the toner particles.Type: GrantFiled: June 26, 2012Date of Patent: March 18, 2014Assignee: Xerox CorporationInventors: Paul Casalmir, Bryan L. Norcott
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Patent number: 8652739Abstract: The present invention provides a toner for developing an electrostatic charge image including toner particles having residual ammonium ions and silica particles containing a chlorine compound as an external additive.Type: GrantFiled: February 9, 2011Date of Patent: February 18, 2014Assignee: Fuji Xerox Co., Ltd.Inventors: Hiroko Kobayashi, Yasuhiro Arima
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Patent number: 8652737Abstract: A toner which has i) toner base particles containing at least a binder resin and a colorant and ii) a fatty acid metal salt composition as an external additive. The fatty acid metal salt composition contains a nonionic surface-active agent and a fatty acid metal salt. This toner and an image forming process making use of the toner can keep the toner from adhering to a toner carrying member throughout running, promise a stable chargeability of the toner and can keep any deterioration of halftone image quality from being caused by excess charging of the toner and any image fog from being caused by insufficient charging of the toner.Type: GrantFiled: November 6, 2008Date of Patent: February 18, 2014Assignee: Canon Kabushiki KaishaInventors: Satoshi Handa, Naoya Isono, Katsuyuki Nonaka, Koji Abe, Yasuhiro Hashimoto, Akira Sugiyama, Yuhei Terui
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Patent number: 8647805Abstract: The present disclosure provides processes for producing toners. In embodiments, flow aids are added to a wet cake including the toner particles, prior to drying. The addition of the flow aid improves flow characteristics of the toner, thereby enhancing overall drying time, reducing the amount of coarse particles, and improving yield, without adversely affecting fusing and charging of the toner particles.Type: GrantFiled: September 22, 2010Date of Patent: February 11, 2014Assignee: Xerox CorporationInventors: Kimberly D. Nosella, Melanie Lynn Davis, Cuong Vong, Abdisamed Sheik-Qasim
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Patent number: 8632933Abstract: A developer for electrostatic latent image development including a positively chargeable toner and a fatty acid metal salt is used, in which the fatty acid metal salt is a metal salt selected from the group consisting of zinc, calcium, and magnesium salts of fatty acids of 12 to 20 carbon atoms and has a certain volume average particle diameter and particle size distribution.Type: GrantFiled: July 20, 2012Date of Patent: January 21, 2014Assignee: Kyocera Document Solutions Inc.Inventors: Masami Tujihiro, Yukinori Nakayama
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Publication number: 20140017607Abstract: An electrostatic charge image developing toner includes toner particles, and silica composite particles that contain silicon oxide and from 0.001% by weight to 10% by weight of titanium, and have an average particle size of from 30 nm to 500 nm, a particle size distribution index of from 1.10 to 1.50, and an average circularity of from 0.50 to 0.85.Type: ApplicationFiled: May 9, 2013Publication date: January 16, 2014Applicant: FUJI XEROX CO., LTD.Inventors: Yoshifumi IIDA, Takeshi IWANAGA, Yuka ZENITANI, Daisuke TOMITA
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Patent number: 8530129Abstract: Provided is an image forming method in which hydrophobized calcium carbonate particles having a number average particle diameter of 30 to 300 nm and hydrophobized strontium titanate particles having a number average particle diameter of 30 to 300 nm are applied to the surface of an image bearing member.Type: GrantFiled: July 1, 2011Date of Patent: September 10, 2013Assignee: Canon Kabushiki KaishaInventors: Masayuki Hama, Masaya Kawada, Masaharu Miura
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Publication number: 20130216793Abstract: A transparent toner for developing an electrostatic latent image includes toner particles containing a binder resin; and an external additive containing cerium oxide, in which a content of cerium in all toner particles is from 0.05% by weight to 0.20% by weight, the cerium oxide contains a praseodymium, and a content of praseodymium in all toner particles is from 0.001% by weight to 0.050% by weight.Type: ApplicationFiled: July 9, 2012Publication date: August 22, 2013Applicant: FUJI XEROX CO., LTD.Inventors: Koji SASAKI, Masanobu NINOMIYA, Tetsuya TAGUCHI, Atsushi SUGAWARA, Yukiaki NAKAMURA
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Patent number: 8512931Abstract: A toner comprising toner particles having at least one type of surface additive, the toner particles having an FPIA average circularity of at least 0.95, whereby at least 80% wt of the total amount of surface additives stays onto the surface of the toner particles when an ultrasonic treatment of 4500 to 4700 J/gram of toner is applied; a substrate printed or marked with the above-described toner; and a method for manufacturing a toner, said method including the steps of: mixing a binder resin, a colorant and optionally other additives, thereby forming a mixture, melting, kneading and milling said mixture, thereby obtaining a melted kneaded product, pulverizing said melted kneaded product, adding at least one surface additive before or while bringing the FPIA average circularity of said toner particles to 0.Type: GrantFiled: November 19, 2010Date of Patent: August 20, 2013Assignee: Xeikon Manufacturing N.V.Inventors: Lode Deprez, Werner Op De Beeck, Karlien Torfs
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Patent number: 8486601Abstract: A toner for electrostatic latent image development is disclosed comprising colored particles containing a binder resin and a colorant and external-additive particles attached to the surfaces of the colored particles, wherein the external-additive particles comprise resin particles covered with an inorganic layer, and the resin particles are bound to the inorganic layer by a siloxane bond. A preparation method of the toner is also disclosed.Type: GrantFiled: September 16, 2010Date of Patent: July 16, 2013Assignee: Konica Minolta Business Technologies, Inc.Inventors: Yukio Hosoya, Mikio Kouyama, Kenji Hayashi, Hiroaki Obata, Koji Shibata
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Patent number: 8372569Abstract: A toner is provided including toner particles A having a circularity of greater than 0.93 and not greater than 1.00 and toner particles B having a circularity of from 0.85 to 0.93, wherein the following relationships are satisfied: 70?RA?95, 5?RB?30, 0.014?SD?0.025, and 0.940?ED?0.950, wherein RA (% by number) represents a ratio of a number of the toner particles A to a total number of toner particles included in the toner, RB (% by number) represents a ratio of a number of the toner particles B to the total number of toner particles included in the toner, SD represents a standard deviation of circularity of the toner particles A, and ED represents an average envelope degree of the toner particles B.Type: GrantFiled: November 9, 2007Date of Patent: February 12, 2013Assignees: Ricoh Company, Ltd., Xeikon Manufacturing N.V.Inventors: Hideyuki Yamaguchi, Hachiroh Tosaka, Tomoyuki Satoh
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Publication number: 20130029259Abstract: A developer for electrostatic latent image development including a positively chargeable toner and a fatty acid metal salt is used, in which the fatty acid metal salt is a metal salt selected from the group consisting of zinc, calcium, and magnesium salts of fatty acids of 12 to 20 carbon atoms and has a certain volume average particle diameter and particle size distribution.Type: ApplicationFiled: July 20, 2012Publication date: January 31, 2013Applicant: KYOCERA DOCUMENT SOLUTIONS INC.Inventors: Masami Tujihiro, Yukinori Nakayama
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Patent number: 8192910Abstract: An image forming method, including charging the surface of an electrostatic latent image bearer by a charger; irradiating the surface of the electrostatic latent image bearer to form an electrostatic latent image thereon; developing the same with a toner to form a toner image; transferring the toner image onto a recording medium; and fixing the toner image thereon, wherein the charger is a charging roller contacting the electrostatic latent image bearer to charge the same, having a ten-point surface roughness of 5 to 30, and the toner includes a binder resin, a colorant, a release agent and an external additive including a composite oxide including titanium oxide in an amount of 80 to 95% by weight and silicon oxide, having a core-shell structure formed of a core including the titanium oxide and a shell including the silicon oxide and has a BET specific surface area of 50 to 100 m2/g.Type: GrantFiled: June 24, 2009Date of Patent: June 5, 2012Assignee: Ricoh Company, LimitedInventors: Hiroaki Katoh, Naoki Nakatake, Masayuki Hagi, Yoshitaka Sekiguchi, Kazuoki Fuwa, Yoshihiro Mikuriya, Hideaki Yasunaga
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Patent number: 8163450Abstract: A toner including toner particles; and external additives including a fatty acid metal salt having an average primary particle diameter of from 0.5 to 1.5 ?m; a positively chargeable particulate inorganic material; and a negatively chargeable particulate inorganic material. An image forming apparatus including a photoreceptor bearing an electrostatic image, and a center feed developing device configured to develop the electrostatic image with a developer including the toner to form a toner image, and a transfer device configured to transfer the toner image onto a receiving material preferably fed at a speed of from 500 to 1700 mm/s. An image forming method including forming an electrostatic image, developing the electrostatic image with the center feed developing device using the toner to form a toner image, and transferring the toner image onto a receiving material preferably fed at a speed of from 500 to 1700 mm/s.Type: GrantFiled: February 9, 2009Date of Patent: April 24, 2012Assignee: Ricoh Company LimitedInventor: Hiroyuki Kishida
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Patent number: 8163456Abstract: An image forming method and image forming apparatus based on the application thereof wherein comet-like deposits do not appear on the surface of the photoreceptor even after prolonged use of small-diameter toner, and there is no dropout or damage on the photoreceptor surface in the image forming process using an intermediate transfer member. This image forming method contains a process wherein the toner developed on an electrophotographic photoreceptor is transferred onto an intermediate transfer member, and the toner contains at least a metallic oxide and metallic soap added as external additive agents, and the protective layer contains a resin component obtained by reaction of at least a curable compound, and alumina particles.Type: GrantFiled: March 25, 2009Date of Patent: April 24, 2012Assignee: Konica Minolta Business Technologies, Inc.Inventors: Hirofumi Hayata, Masahiko Kurachi, Toshiyuki Fujita
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Patent number: 8153343Abstract: A toner in which even a toner containing crystalline polyester exhibits excellent fixing property, chargeability, color reproducibility, and long-term stability, as well as a two-component developer, a developing device, and an image forming apparatus are provided. The toner includes toner base particles which contain a colorant and a binder resin containing at least crystalline polyester and an amorphous resin; and a mixed oxide of aluminum oxide and silicon dioxide externally added to the toner base particles, and the toner is so adjusted that the binder resin contains 20% by weight to 50% by weight of the crystalline polyester and that a compositional proportion of aluminum oxide in the mixed oxide of aluminum oxide and silicon dioxide falls within a range of 35% by weight or more and less than 50% by weight.Type: GrantFiled: December 29, 2008Date of Patent: April 10, 2012Assignee: Sharp Kabushiki KaishaInventors: Masahiko Kubo, Satoru Ariyoshi
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Patent number: 8105743Abstract: The present invention provides an organic silicone fine particle for latent electrostatic image developing toners, wherein the organic silicone fine particle has a volume average particle diameter of 0.05 ?m to 6.0 ?m which is obtained by measurement based on Coulter principle, and has a hemispherical polysiloxane cross-linked structure. By mixing an appropriate amount of an organic silicone resin particle formed in a deformed shape (a hemispherical shape) in a toner or developer, the present invention prevents movement of the organic silicone resin particle from surface functional sites, the movement caused by a phenomenon such as detachment thereof from a toner surface or rolling movement on the toner surface, by the effect of its shape, and makes it possible to effectively achieve the expected function.Type: GrantFiled: March 12, 2008Date of Patent: January 31, 2012Assignee: Ricoh Company, Ltd.Inventors: Masayuki Ishii, Ryota Inoue, Yoshihiro Moriya, Shingo Sakashita
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Patent number: 8092965Abstract: Provided is a method for forming an image containing the steps of: (a) forming an electrostatic latent image on an electrostatic latent image carrier; and (b) developing the electrostatic latent image by a two component developer comprising a toner and a carrier, wherein the two component developer is continually replenished in the developing step (b); and the toner includes: colored particles; and external additive particles comprising a complex oxide incorporating silicon atoms and at least one of titanium atoms and aluminum atoms, and a surface existing ratio of the silicon atoms (R2) in a surface of the external additive particles being larger than an average existing ratio of the silicon atoms (R1) in an entirety of the external additive particles.Type: GrantFiled: February 17, 2009Date of Patent: January 10, 2012Assignee: Konica Minolta Business Technologies, Inc.Inventors: Masahiro Anno, Masahiko Nakamura, Tsuyoshi Uchida, Kenichi Onaka, Junya Onishi, Naoya Tonegawa
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Patent number: 8080357Abstract: When being blended particularly in a color toner, a barium titanate external additive for toner enhances the toner fluidity, electrical properties, and other relevant performance; concurrently achieves high image density and reduced background fog in a color printer using the toner; and further retains high image quality even under a high-temperature high-humidity environment and a low-temperature low-humidity environment. An industrially advantageous producing method of the barium titanate external additive for toner is also provided. The external additive for toner of the present invention includes spherical barium titanate having undergone coating treatment with a hydrophobicizing agent.Type: GrantFiled: January 25, 2007Date of Patent: December 20, 2011Assignee: Nippon Chemical Industrial Co., Ltd.Inventors: Kazuo Ochiai, Shinji Tanabe, Naoaki Narishige
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Patent number: 7939235Abstract: A toner includes a polyol-based resin having multiple hydroxyl groups in a molecular chain thereof in which a ratio of epoxy group to hydroxyl group is from 0.990 to 1.010. A stirring and transfer device satisfies 1000000??×?×??16000000, wherein ? represents a number of rotation per minute, ? (mm) represents a pitch and ? (mm) represents a transfer path length of the stirring and transfer device. A temperature Tin (° C.) in a development device during stirring and transfer of a two component developing agent satisfies 3020 C.<Tin<60° C., and the toner satisfies Y??0.5X+45, 5?X<40, 5?Y?35, wherein X (%) represents a degree of agglomeration of a mother toner particle and Y (%) represents a degree of agglomeration of the toner which has been preserved at 55° C. for 24 hours.Type: GrantFiled: March 13, 2008Date of Patent: May 10, 2011Assignee: Ricoh Company LimitedInventors: Takahiro Honda, Hiroyuki Fushimi, Fumihiro Sasaki, Hisashi Nakajima, Hiroshi Yamada, Yasuo Asahina
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Publication number: 20110045401Abstract: An image forming apparatus, wherein a surface resistivity Rse[?] of a charger and a volume resistivity Rsw [?·cm] of the composition having a low softening point satisfy the following relationship: 0.8×10?1Rse<Rvw<1.5×10Rse is provided. The image forming apparatus contains a photoreceptor; a charger configured to charge the photoreceptor with a charger contacting thereto; an irradiator configured to irradiate the photoreceptor to form an electrostatic latent image thereon; an image developer configured to develop the electrostatic latent image with a toner to form a toner image on the photoreceptor; a transferer configured to transfer the toner image onto a recording material directly or through an intermediate transferer; and a fixer configured to fix the toner image on the recording material, wherein the toner comprises: a binder resin; a colorant; a composition having a low softening point; and an external additive.Type: ApplicationFiled: October 26, 2010Publication date: February 24, 2011Inventors: Hiroyuki MURAKAMI, Masahide Inoue, Chiyoshi Nozaki, Tsuyoshi Nozaki, Atsushi Yamamoto, Takuya Kadota, Mitsuyo Matsumoto, Katsunori Kurose, Yoshimichi Ishikawa
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Patent number: 7867685Abstract: An image forming method, including charging a photoreceptor with a charger contacting thereto; irradiating the photoreceptor to form an electrostatic latent image thereon; developing the electrostatic latent image with a toner to form a toner image on the photoreceptor; transferring the toner image onto a recording material directly or through an intermediate transferer; and fixing the toner image on the recording material, wherein the toner includes a binder resin; a colorant; a composition having a low softening point; and an external additive, and wherein a surface resistivity Rse [?] of the charger and a volume resistivity Rsw [?·cm] of the composition having a low softening point satisfy the following relationship: 0.8×10?1Rse<Rvw<1.5×10Rse.Type: GrantFiled: September 7, 2007Date of Patent: January 11, 2011Assignee: Ricoh Company, LimitedInventors: Hiroyuki Murakami, Masahide Inoue, Chiyoshi Nozaki, Tsuyoshi Nozaki, Atsushi Yamamoto, Takuya Kadota, Mitsuyo Matsumoto, Katsunori Kurose, Yoshimichi Ishikawa
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Patent number: 7862977Abstract: A method to form an image using a trickle developing system, wherein (a) the toner comprises colorant particles with a volume median diameter of 3 to 8 ?m having first inorganic particles on surfaces of the colorant particles to form toner particles; (b) the carrier comprises magnetic particles with a weight average particle diameter (D4) of 20 to 40 ?m having second inorganic particles on surfaces of the magnetic particles to form carrier particles; and (c) an area ratio of element (A) based on a total area of surfaces of the carrier particles is 0.5 to 3.0 area % determined by using an X-ray analysis, provided that element (A) represents one or more elements commonly contained in the first inorganic particles and in the second inorganic particles.Type: GrantFiled: April 3, 2007Date of Patent: January 4, 2011Assignee: Konica Minolta Business Technologies, Inc.Inventors: Makoto Kobayashi, Yoshiyasu Matsumoto
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Publication number: 20100330488Abstract: The present invention is to provide a positively-chargeable toner for developing electrostatic images, which is excellent in reproductivity of thin lines and in durability and has a stable charging ability and flowability over time. A positively-chargeable toner comprises a colored resin particle and external additives, wherein a spherical colloidal silica particle having a number average primary particle diameter of 30 to 80 nm and a triboelectric charge amount of ?50 to +300 ?C/g, and a fumed silica particle having a number average primary particle diameter of 5 to 25 nm are contained as the external additives, and wherein a content of the spherical colloidal silica particle is in the range from 0.3 to 2 parts by weight and a content of the fumed silica particle is in the range from 0.1 to 1 parts by weight with respect to 100 parts by weight of the colored resin particle.Type: ApplicationFiled: September 26, 2008Publication date: December 30, 2010Applicant: ZEON CORPORATIONInventor: Osamu Ieda