Thermal Or Energy Treatment Of Radiation-sensitive Layer, E.g., Fusing, Annealing, Or Solvent After Treatment Of Radiation-sensitive Layer, Etc. Patents (Class 430/130)
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Patent number: 5516875Abstract: This invention concerns positive-working photodefinable polyimide precursors which make use of chemical amplification based on photoacid catalyzed cleavage of acid labile-poly(amic acetal esters).Type: GrantFiled: December 15, 1994Date of Patent: May 14, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventor: Howard E. Simmons, III
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Patent number: 5501928Abstract: A method of manufacturing a luminescent screen assembly on an interior surface of a faceplate panel 12 for a color CRT 10 includes the steps of uniformly applying a solution of a material to form an organic conductive (OC) layer and overcoating the OC layer with a solution to form an organic photoconductive (OPC) layer, on the interior surface of the faceplate panel. The OPC layer 34 is conditioned by directing a stream of dry gas thereon to warm the OPC layer to a preheat temperature, while maintaining the panel at a panel temperature less than the preheat temperature. The OPC layer is exposed to IR radiation to rapidly increase the temperature of the OPC layer to a curing temperature, greater than the preheat temperature, to remove some of the volatilizable constituents from the OPC layer, without substantially increasing the temperature of the panel.Type: GrantFiled: December 14, 1994Date of Patent: March 26, 1996Assignee: Thomson Consumer Electronics, Inc.Inventors: Pabitra Datta, Eugene S. Poliniak, Peter M. Ritt, Brian T. Collins, Harry R. Stork
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Patent number: 5482810Abstract: An excellent electrophotographic lithographic printing plate precursor capable of exhibiting a stable electrophotographic sensitivity and toner fogging density as well as less occurrence of background stains during printing can be produced in effective manner. The feature consists in a process for the production of an electrophotographic lithographic printing plate precursor having at least a photoconductive layer on a support, comprising coating a composition for a photoconductive layer comprising, as predominant components, a photoconductive material and a resin binder onto the support and then drying it by a drying air whose humidity is controlled to provide an absolute humidity of 5 to 70 g/kg . dried air.Type: GrantFiled: November 12, 1993Date of Patent: January 9, 1996Assignees: Fuji Photo Film Co., Ltd., Tomoegawa Paper Co., Ltd.Inventors: Takao Nakayama, Shigeyuki Dan, Ryosuke Iwashita, Saburo Umehara
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Patent number: 5418106Abstract: A method of restoring a used organic photoreceptor which includes a supporting substrate having a photoconductor layer contained on said substrate and an overlaying layer of charge transport material. The photoreceptor is heated to a temperature near or above the glass transition temperature of the charge transport layer for a time sufficient to allow for flowing and/or melting of the top surface of the charge transport layer, and then cooled to room temperature, followed by applying a new layer of charge transport material over the existing charge transport layer.Type: GrantFiled: July 1, 1993Date of Patent: May 23, 1995Assignee: Nu-Kote International, Inc.Inventors: Donald E. Snyder, Jr., William A. Donofrio, William J. Murphy
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Patent number: 5357088Abstract: A method for making a photographic composition gel ready for use in production from a good preservative frozen state, causing no change in photographic properties, wherein a photographic composition gel is melted to a sol by placing a light shielding dielectric preservative container holding lumps of a photographic composition gel in a dielectric heating apparatus which generates high frequencies capable of penetrating to a depth corresponding to the size of the above photographic composition gel lumps, and melting the photographic composition gel to a sol by irradiating the lumps of gel with the above high frequencies from the outside of the container.Type: GrantFiled: May 4, 1992Date of Patent: October 18, 1994Assignee: Konica CorporationInventors: Shinichi Suzuki, Hideaki Kimura, Kazuyoshi Ichikawa, Sanae Oyama
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Patent number: 5344731Abstract: A migration imaging system using a laser-addressable thermoplastic imaging member 10. The imaging member 10 comprises a supporting section 15 and a thermoplastic imaging surface layer 14. A charged, uniform layer of marking particles 24 is deposited on the imaging surface layer 14. An imagewise-modulated laser beam 24 transforms selected volumes of the imaging surface layer 14 in an imagewise pattern to a permeable state. Charged marking particles 42 that overlay a transformed volume then migrate into the imaging surface layer 14, due to an electrostatic attraction to the imaging member 10, so as to be retained. Unaddressed marking particles 56 are cleaned away by particle removing device 20B comprised of a magnetic brush utilizing hard magnetic carrier particles. The imaging member 10, or solely the imaging surface layer 14, may be transferred and bonded to a receiver member such as a drum for use as an exposure mask in a xeroprinting process, or to a receiver sheet 64 to provide a hard copy reproduction.Type: GrantFiled: July 23, 1992Date of Patent: September 6, 1994Assignee: Eastman Kodak CompanyInventors: Charles D. Deboer, Dennis R. Kamp, William Mey
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Patent number: 5330867Abstract: A layered imaging member comprised of a photogenerating layer of titanyl phthalocyanine prepared by depositing amorphous titanyl phthalocyanine on a substrate maintained at a temperature of from below 25.degree. to about minus 30.degree. C.; and contacting the substrate product with an aliphatic alcohol.Type: GrantFiled: August 24, 1992Date of Patent: July 19, 1994Assignee: Xerox CorporationInventors: Cheng-Kuo Hsiao, Ah-Mee Hor, James D. Mayo, Giuseppa Baranyi, Gregory J. Kovacs, Terry L. Bluhm, Zoran D. Popovic, B. W. Anissa Yeung
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Patent number: 5314779Abstract: A process for the preparation of layered photoconductive imaging members which comprises forming layers comprised of a mixture of cyclic oligomers with degrees of polymerization of from about 2 to about 20 and a catalyst, wherein one layer contains a conductive filler, the second layer contains a photogenerating pigment and the third layer contains charge transporting molecules, and heating said layers to convert the cyclic oligomer mixture in each layer to a polycarbonate resin.Type: GrantFiled: August 24, 1992Date of Patent: May 24, 1994Assignee: Xerox CorporationInventors: Peter G. Odell, Trevor I. Martin
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Patent number: 5302484Abstract: A process for the preparation of supporting substrates which comprises heating a mixture of cyclic oligomers with degrees of polymerization of from about 2 to about 20 and a catalyst.Type: GrantFiled: August 24, 1992Date of Patent: April 12, 1994Assignee: Xerox CorporationInventors: Peter G. Odell, Trevor I. Martin
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Patent number: 5300392Abstract: A process for the preparation of photoconductive imaging members which comprises coating a supporting substrate with a photogenerator layer comprised of photogenerating pigments, and subsequently applying to the photogenerating layer a mixture comprised of charge transport molecules and cyclic oligomers, and wherein said mixture is heated to obtain polycarbonate resin binder from said cyclic oligomers.Type: GrantFiled: June 29, 1992Date of Patent: April 5, 1994Assignee: Xerox CorporationInventors: Peter G. Odell, Dasarao K. Murti, Trevor I. Martin
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Patent number: 5300393Abstract: A process for the preparation of photoconductive imaging members which comprises coating a supporting substrate with a photogenerator layer comprised of photogenerating pigments and a mixture of cyclic oligomers wherein said mixture is heated to obtain a polycarbonate resin binder, and subsequently applying to the photogenerating layer a layer of charge transport molecules.Type: GrantFiled: August 14, 1992Date of Patent: April 5, 1994Assignee: Xerox CorporationInventors: Peter G. Odell, Trevor I. Martin, James D. Mayo
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Patent number: 5264312Abstract: A process for preparing a photoreceptor by forming a coating of a substrate followed by curing. The coating contains an electroactive material dissolved or dispersed in a polymerizable film forming monomer, which is first polymerized into a solid matrix.Type: GrantFiled: February 5, 1992Date of Patent: November 23, 1993Assignee: Xerox CorporatoinInventors: Milan Stolka, Ian D. Morrison, Bing R. Hseih
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Patent number: 5232804Abstract: An electrophotographic element comprises a single aggregate photoconductive layer which contains a continuous phase that has a high glass transition temperature T.sub.g, of at least about 110.degree. C. The required high glass transition temperatures can be obtained by using compositions for the aggregate photoconductive layer that contain organic charge transport agents with high glass transition temperatures or polymer binders with high glass transition temperatures, or combinations of both. In a preferred embodiment an aggregating bisphenol A polycarbonate is used in combination with a cobinder polymer that has a high glass transition temperature. The electrophotographic element of the invention can be dried at temperatures of at least about 100.degree. C., and preferably from about 110.degree. C. to about 145.degree. C., to eliminate the solvent used in coating.Type: GrantFiled: December 31, 1991Date of Patent: August 3, 1993Assignee: Eastman Kodak CompanyInventor: Michel F. Molaire
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Patent number: 5223331Abstract: The present invention provides an organic device comprising a substrate having a polymerized monomolecular or built-up multi-monomolecular film, a first electrode, a second electrode with said film intervening between the electrodes, a third electrode connected directly or indirectly to the monomolecular or built-up multi-monomolecular film, which device is operated by applying a voltage between the third electrode and the second electrode to control an electric current flowing between the first electrode and the second electrode through said polymerized monomolecular or built-up multi-monomolecular film between the electrodes. If the polymerization of the monomolecular film is eliminated, the device can be imparted with learning functions because the polymerization of the film proceeds depending upon an amount of electricity flowing during the use of the device.Type: GrantFiled: April 1, 1991Date of Patent: June 29, 1993Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Kazufumi Ogawa, Norihisa Mino
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Patent number: 5213937Abstract: A process of preparing electrophotographic photoreceptor aluminum drums having coated layers with a constant thickness and properties is disclosed. After a carrier generation layer being dip coated, a process of conveyance is followed at a temperature same as that of the coating material.Type: GrantFiled: November 12, 1991Date of Patent: May 25, 1993Assignee: Konica CorporationInventor: Kan Miyake
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Patent number: 5167987Abstract: A process for fabricating an electrostatographic imaging member including providing a flexible substrate comprising a solid thermoplastic polymer, forming an imaging layer coating including a film forming polymer on the substrate, heating the coating and substrate, cooling the coating and substrate, and applying sufficient predetermined biaxial tensions to the substrate while the imaging layer coating and substrate are at a temperature greater than the glass transition temperature of the imaging layer coating to substantially compensate for all dimensional thermal contraction mismatches between the substrate and the imaging layer coating during cooling of the imaging layer coating and the substrate, removing application of the biaxial tension to the substrate, and cooling the substrate whereby the final hardened and cooled imaging layer coating and substrate are substantially free of internal stress and strain.Type: GrantFiled: November 4, 1991Date of Patent: December 1, 1992Assignee: Xerox CorporationInventor: Robert C. U. Yu
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Patent number: 5168542Abstract: Optical waveguides for use in planar structures, such as dielectric layers in multichip modules exhibit low optical loss. The optical waveguides are provided by methods that involve doping of the dielectric layers. The waveguides can be used to interconnect electronic elements and transmit signals at speeds that are compatible with high speed electronic elements.Type: GrantFiled: October 9, 1991Date of Patent: December 1, 1992Assignee: The Boeing CompanyInventors: Kishore K. Chakravorty, Chung-Ping Chien
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Patent number: 5157746Abstract: An optical waveguide array includes a two-dimensionally refractive index profile lens for focusing light beams in a scanning direction. The two-dimensionally refractive index profile lens is bonded to or integrally formed with the optical waveguide array. The refractive index is distributed in the two-dimensionally refractive index profile lens by changing the irradiation energy of ultraviolet ray during the manufacture. As a member for focusing the light beams in the irradiation direction which is perpendicular to the scanning direction, another two-dimensionally refractive index profile lens or a cylindrical lens is used. The optical waveguide array with such an inexpensive structure can focus the light beams both in the scanning direction and the irradiation direction. The resolution of the latent image formed on a photosensitive member can thus be improved.Type: GrantFiled: June 6, 1991Date of Patent: October 20, 1992Assignee: Brother Kogyo Kabushiki KaishaInventors: Manabu Tobita, Makoto Suzuki
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Patent number: 5128229Abstract: The electrophotosensitive material in accordance with the present invention containing a layer which contains polycarbonate as a binding resin and of which glass transition temperature is not lower than 62.degree. C. This layer is excellent in adhesion to the foundation. This layer may be a photosensitive layer containing a m-phenylenediamine compound as a charge transferring material, or a photosensitive layer containing a m-phenylenediamine compound and a perylene compound as a charge generating material. The present invention also provides a photosensitive layer of which the amount of residual tetrahydrofuran is adjusted to a predetermined value or less, thereby to prevent the photosensitive layer from being decreased in sensitivity due to ultraviolet rays or visible ray.Type: GrantFiled: September 20, 1990Date of Patent: July 7, 1992Assignee: Mita Industrial Co., Ltd.Inventors: Masato Katsukawa, Keizo Kimoto, Mitsuji Tsujita, Satoru Miura
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Patent number: 5116703Abstract: Materials and a process for producing the materials are useful in electrophotographic imaging members. The materials are produced through a sol-gel process wherein a hybrid material, which may be obtained through hydrolysis and condensation, includes an inorganic glassy network, a flexible organic subunit and a functional subunit. The latter two subunits may be unitary. The materials can be easily coated for fabricating electrophotographic imaging members and the like.Type: GrantFiled: December 15, 1989Date of Patent: May 26, 1992Assignee: Xerox CorporationInventors: Santokh S. Badesha, Milan Stolka, John F. Yanus, John H. Hodge
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Patent number: 5100749Abstract: An improved photosensitive member for electrophotography which comprises an intermediate layer, a photoconductive layer and a surface protecting layer each formed upwardly in this order on a conductive substrate, the photoconductive layer comprising a non-doped a-Si layer made of a amorphous silicon containing hydrogen and/or halogen of 40 at. % or more.Type: GrantFiled: February 19, 1991Date of Patent: March 31, 1992Assignee: Sharp Kabushiki KaishaInventors: Shiro Narikawa, Takashi Hayakawa, Kunio Ohashi
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Patent number: 5089369Abstract: In an electrophotographic imaging member having a supporting substrate and a charge generating layer, the supporting substrate is made of a material having a thermal contraction coefficient which is substantially the same as that of the charge generating layer. Substrate materials having a thermal contraction coefficient between about 5.0.times.10.sup.-5 /.degree.C. and about 9.0.times.10.sup.-5 /.degree.C. are preferred for use in combination with a benzimidazole perylene charge generating layer.Type: GrantFiled: June 29, 1990Date of Patent: February 18, 1992Assignee: Xerox CorporationInventor: Robert C. U. Yu
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Patent number: 5085968Abstract: A photosensitive member for electrophotography which comprises a conductive substrate and a photoconductive layer which is composed of an amorphous silicon layer and an amorphous silicon germanium layer containing a specific amount of hydrogen and/or halogen respectively, and being prepared by electron cyclotron resonance method respectively, which is useful for xerographic systems.Type: GrantFiled: December 3, 1990Date of Patent: February 4, 1992Assignee: Sharp Kabushiki KaishaInventors: Takashi Hayakawa, Shiro Narikawa, Kunio Ohashi
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Patent number: 5073466Abstract: An electrophotographic member comprising a support, a photoconductive layer formed thereon, and a surface layer formed thereon, said surface layer including or attaching a lubricating agent having a perfluoropolyoxyalkyl or perfluoropolyoxyalkylene group to form an organic surface protective lubricating layer, and a fixing group to be fixed to the surface layer, is excellent in moisture resistance, wear resistance and cleaning properties and thus useful in an electrophotographic apparatus with a long life and high reliability.Type: GrantFiled: August 16, 1989Date of Patent: December 17, 1991Assignees: Hitachi, Ltd., Hitachi Chemical Company, Ltd.Inventors: Fuminori Ishikawa, Kunihiro Tamahashi, Shigeharu Onuma, Masatoshi Wakagi, Masanobu Hanazono, Mitsuyoshi Shoji, Takayuki Nakakawaji, Yutaka Ito, Shigeki Komatsuzaki, Yasuo Shimamura, Chiaki Yamagishi
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Patent number: 5057391Abstract: A photosensitive member for electrophotography comprising a photoconductive layer formed on an electro- conductive support, in which the photoconductive layer is composed of an amorphous silicon germanium layer formed by electron cyclotron resonance (ECR) method and containing hydrogen and/or halogen in an amount of more than 40 at. % to 65 at. % and an amorphous silicon nitride layer formed by ECR method and containing hydrogen and/or halogen in an amount of more than 40 at. % to 60 at. %, the amorphous silicon nitride layer being laminated on the amorphous silicon germanium layer; said member exhibiting an increased sensitivity to laser rays having a long wavelength and an improved charge retention capacity.Type: GrantFiled: May 15, 1990Date of Patent: October 15, 1991Assignee: Sharp Kabushiki KaishaInventors: Takashi Hayakawa, Shiro Narikawa, Kunio Ohashi, Yoshiharu Tsujimoto
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Patent number: 5055373Abstract: A multicolor recording material is disclosed, which comprises a support having provided thereon a coating layer comprising two or more kinds of microcapsules each containing at least a leuco dye capable of being colored by oxidation and a photo oxidizing agent outside said microcapsules, and a reducing agent as necessary components, with two or more leuco dyes capable of forming different colors from each other being retained in different kinds of said microcapusles respectively composed of walls of high polymers having different glass transition points.Type: GrantFiled: September 29, 1989Date of Patent: October 8, 1991Assignee: Fuji Photo Film Co., Ltd.Inventors: Keiso Saeki, Fumiaki Shinozaki, Toshiaki Endo
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Patent number: 5035973Abstract: An image forming method includes the steps of forming an electrostatic latent image on an image-carrying body, developing the electrostatic latent image using a developing agent, and transferring the developed image. A compound which reacts with nitrate ions causing an image flow and forms a water-insoluble substance is added on the surface of the image-carrying body, and then a cleaning is performed on the surface of the image-carrying body. The water-insoluble substance is removed from the surface of the image-carrying body, and therefore the image flow is prevented.Type: GrantFiled: November 1, 1988Date of Patent: July 30, 1991Assignee: Kabushiki Kaisha ToshibaInventor: Eiichi Kaga
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Patent number: 4990423Abstract: A photosensitive member for electrophotography which comprises a conductive substrate and a photoconductive layer, the photoconductive layer being an amorphous silicon germanium containing hydrogen and/or a halogen at a specific amount, deposited by electron cyclotron resonance method, which is useful for image formation apparatus such as a laser printer.Type: GrantFiled: June 20, 1989Date of Patent: February 5, 1991Assignee: Sharp Kabushiki KaishaInventors: Takashi Hayakawa, Shiro Narikawa, Kunio Ohashi
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Patent number: 4985330Abstract: A photosensitive material for electrophotography which comprises an electrically conductive support of a desired shape and an organic photoconductive layer formed on the substrate, is provided. The organic photoconductive layer is formed from a solution of an organic charge-generating compound, an organic charge transfer compound and an organic resin in an organic solvent after low temperature treatment thereof wherein the solution is cooled to a temperature sufficient not to cause the solutes to be precipitated or the solution to be coagulated for a time enough to allow interaction between the compounds and the resin binder and is returned to room temperature. This solution is applied to the support and dried to form a photoconductive layer on the support. The photoconductive layer may be of a single-layer structure or a double-layered structure wherein at least one sub-layer should be formed from a solution subjected to the low temperature treatment.Type: GrantFiled: November 7, 1989Date of Patent: January 15, 1991Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Sohji Tsuchiya, Mutsuaki Murakami, Susumu Yoshimura
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Patent number: 4971878Abstract: An electrophotographic photosensitive member is disclosed which comprises an electrically conductive substrate and a photoconductive layer formed on said substrate, wherein the photoconductive layer is made of amorphous silicon containing 40 atomic % or more of hydrogen and/or halogen.Type: GrantFiled: April 3, 1989Date of Patent: November 20, 1990Assignee: Sharp Kabushiki KaishaInventors: Takashi Hayakawa, Shiro Narikawa, Kunio Ohashi
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Patent number: 4912008Abstract: In an electrophotographic photosensitive device, which comprises an electroconductive support, a photoconductive layer provided thereon, and a surface protective layer provided on the photoconductive layer, the surface protective layer being made from a film having a density of localized states of not more than 5.times.10.sup.17 cm.sup.-3 and a higher dark resistance than that of the photoconductive layer, the surface protective layer is less susceptible to deterioration, adhesion to the photoconductive layer is enhanced, and thus the device has a prolonged life.Type: GrantFiled: May 31, 1988Date of Patent: March 27, 1990Assignee: Hitachi, Ltd.Inventors: Megumi Naruse, Kunihiro Tamahashi, Mitsuo Chigasaki, Masanobu Hanazono
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Method of making an electrophotographic inorganic photosensitive element using ultraviolet radiation
Patent number: 4908292Abstract: A method and apparatus of manufacturing a photosensitive member including an electrically conductive support and a photoconductive layer formed on said support for use in electrophotography is characterized by including the steps of introducing a reacting gas containing predetermined components for forming said photoconductive layer on said support into said reaction chamber and irradiating ultraviolet light to activate said predetermined components while maintaining said support at a predetermined temperature thereby causing said predetermined components to be deposited onto said support.Type: GrantFiled: July 11, 1988Date of Patent: March 13, 1990Assignee: Ricoh Company, Ltd.Inventors: Yukio Ide, Kohichi Ohshima, Itaru Fujimura, Yoshiyuki Kageyama -
Patent number: 4902595Abstract: A photosensitive member of the present invention comprising an electrically conductive substrate, a photosensitive layer comprising an organic material and a hydrogen-containing amorphous carbon overcoat layer containing halogen atoms and at least one or more elements selected from the group consisting of chalcogen and elements in Group III, IV and V of the periodic table.The overcoat layer contains hydrogen in an amount of about 5 to about 50 atomic % based on the combined amount of hydrogen atoms and carbon atoms.Type: GrantFiled: July 12, 1988Date of Patent: February 20, 1990Assignee: Minolta Camera Kabushiki KaishaInventors: Kenji Masaki, Izumi Osawa, Yumiko Takedomi, Masanori Fujiwara
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Patent number: 4873165Abstract: An electrophotographic photoreceptor is disclosed, which comprises a support, a light-sensitive layer and a surface layer, the surface layer being predominantly composed of carbon and containing an element capable of forming a tetrahedral bond.Type: GrantFiled: January 15, 1988Date of Patent: October 10, 1989Assignee: Fuji Xerox Co., Ltd.Inventors: Ken-ichi Karakida, Shigeru Yagi
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Patent number: 4855203Abstract: A layered photoresponsive imaging member comprised of a supporting substrate; an amorphous photoconductive layer and a hole transport layer dispersed in a resinous binder, which layer is formulated from a solution mixture; and wherein the photoconductive layer is prepared by a process which comprises dissolving an inorganic photoconductive component in a solvent, removing the suspended particles therefrom, depositing the resulting solution on the supporting substrate, and subsequently heating the aforementioned member.Type: GrantFiled: August 31, 1987Date of Patent: August 8, 1989Assignee: Xerox CorporationInventors: Santokh S. Badesha, Geoffrey M. T. Foley, Damodar M. Pai, Richard H. Zallen, Michael L. Slade, Martin A. Abkowitz
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Patent number: 4849315Abstract: A process for restoring imaging members, which comprises (1) providing a hydrogenated or halogenated amorphous silicon imaging member subsequent to its utilization in and removal from an electrophotographic imaging apparatus; and (2) contacting this member with a fluorine containing composition for an effective time period thereby resulting in an imaging member that when incorporated into an electrophotographic imaging apparatus enables the achievement of images with substantially no white spots as compared to the removed member.Type: GrantFiled: July 20, 1987Date of Patent: July 18, 1989Assignee: Xerox CorporationInventors: Damodar M. Pai, Santokh S. Badesha
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Patent number: 4835083Abstract: An electroconductive film is provided which has a first region constituted of a lamination layer comprising an electroconductive layer and an insulating layer, and a second layer having reduced or eliminated electroconductivity. Another type of electroconductive film is also provided having a first region constituted of a limination layer containing a compound having a polymerizable double bond and comprising an electroconductive layer and an insulating layer, and a second layer which is modified and having changed dissolution characteristics. The layer may be formed of a monomolecular film or monomolecular built-up film. A patterning method by use of the above electroconductive film is also provided.Type: GrantFiled: April 15, 1987Date of Patent: May 30, 1989Assignee: Canon Kabushiki KaishaInventors: Kunihiro Sakai, Kenji Saitoh, Toshihiko Miyazaki, Ken Eguchi, Haruki Kawada, Toshiaki Kimura, Kiyoshi Takimoto, Hiroshi Matsuda, Yukuo Nishimura, Yoshinori Tomida
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Patent number: 4818563Abstract: A process for forming a deposited film comprises introducing into a film forming space housing a substrate therein an active species (A) formed by decomposition of a compound containing germanium and a halogen and an active species (B) formed from a chemical substance for film formation which is reactive with said active species (A) separately from each other, then providing them with heat energy and thereby allowing both the species to react with each other thereby to form a deposited film on the substrate.Type: GrantFiled: February 20, 1986Date of Patent: April 4, 1989Assignee: Canon Kabushiki KaishaInventors: Shunichi Ishihara, Shigeru Ohno, Masahiro Kanai, Shunri Oda, Isamu Shimizu
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Patent number: 4804607Abstract: Disclosed is an electrophotosensitive member and its preparing method. The electrophotosensitive member comprises an electrically conductive substrate, a photosensitive layer, and an overcoat layer having a rough surface with convexities and concavities. The number of convexities and concavities are about 500 to 3000 per 1 cm in a linear distance, and the maximum depth difference of the convexities and concavities is about 0.05 to 1.5 .mu.m. The rough surface having the convexities and concavities is formed directly on the overcoat layer. The electrophotosensitive member according to the present invention reduces the friction coefficient of the contacting area between the electrophotosensitive member and a cleaning device, and improves the durability of the overcoat layer and the photosensitive layer.Type: GrantFiled: September 28, 1987Date of Patent: February 14, 1989Assignee: Minolta Camera Kabushika KaishaInventor: Fumitoshi Atsumi
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Patent number: 4784874Abstract: A process for forming a deposited film comprises introducing into a film forming space housing a substrate therein an active species (A) formed by decomposition of a compound containing carbon and halogen and an active species (B) formed from a chemical substance for film formation which is chemically mutually reactive with said active species (A) separately from each other, then providing them with heat energy and thereby allowing both the species to react chemically with each other to form a deposited film on the substrate.Type: GrantFiled: February 20, 1986Date of Patent: November 15, 1988Assignee: Canon Kabushiki KaishaInventors: Shunichi Ishihara, Shigeru Ohno, Masahiro Kanai, Shunri Oda, Isamu Shimizu
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Patent number: 4778692Abstract: A process for forming a deposited film, which comprises introducing into a film forming space for formation of a deposited film on a substrate an active species (A) formed by decomposition of a compound containing silicon and a halogen and an active species (B) formed from a germanium containing compound for film formation which is chemically mutually reactive with said active species (A) separately from each other, and then permitting the above respective active species and said germanium containing compounds to react chemically with each other by excitation by irradiation of light energy thereby to form a deposited film on the above substrate.Type: GrantFiled: February 20, 1986Date of Patent: October 18, 1988Assignee: Canon Kabushiki KaishaInventors: Shunichi Ishihara, Shigeru Ohno, Masahiro Kanai, Shunri Oda, Isamu Shimizu
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Patent number: 4760004Abstract: Compounds of the formulae I, II and III ##STR1## in which R is --F, --Cl, --Br, C.sub.1 -C.sub.18 alkoxy, and n is the number 0, 1, 2 or 3, are suitable in particular for use as photoconductive substances.Type: GrantFiled: November 12, 1987Date of Patent: July 26, 1988Assignee: Ciba-Geigy CorporationInventors: Alain C. Rochat, Edward E. Jaffe, Jin Mizuguchi
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Patent number: 4673627Abstract: An electrophotographic lithographic printing plate is described, comprising an electrically conductive support and a photoconductive layer on the support, said layer being made mainly of a photoconductive zinc oxide and a resin binder, wherein in the surface of the photoconductive layer, the degree of exposure of photoconductive zinc oxide is from 10% to 70%.Type: GrantFiled: December 26, 1985Date of Patent: June 16, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Kenji Kunichika, Yoshikatsu Kagawa, Chikashi Ohishi, Sho Nakao, Yasuzi Asao
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Patent number: 4618560Abstract: Multi-active photoconductive insulating elements which exhibit very high electrophotographic speed and panchromatic sensitivity, and whose manufacture can be effectively controlled to provide an electrical contrast ranging from a very low to a very high level, are comprised of a charge-generation layer and a charge-transport layer in electrical contact therewith and contain, as the charge-generating agent within the charge-generation layer, certain crystalline forms of N,N'-bis(2-phenethyl)perylene-3,4:9,10-bis(dicarboximide) characterized by particular spectral absorption and X-ray diffraction characteristics.Type: GrantFiled: August 5, 1985Date of Patent: October 21, 1986Assignee: Eastman Kodak CompanyInventors: Paul M. Borsenberger, Michael T. Regan, William J. Staudenmayer
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Patent number: 4569895Abstract: An article having improved electrostatic charge transfer properties. The improvement in charge transfer properties results from subjecting a layer of photoconductive-insulative material or dielectric material on the charge donor or a layer of dielectric material on the charge receptor, or both layers, to plasma treatment process to provide an oxygen-enriched surface to the photoconductive-insulative layer and/or the dielectric layer.Type: GrantFiled: October 30, 1984Date of Patent: February 11, 1986Assignee: Minnesota Mining and Manufacturing CompanyInventors: Stephen J. Willett, Hsin H. Chou, Carol E. Hendrickson, William A. Hendrickson
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Patent number: 4551405Abstract: Image-forming member for electrophotography comprising a charge generation layer composed of hydrogenated amorphous silicon.Type: GrantFiled: December 23, 1983Date of Patent: November 5, 1985Assignee: Canon Kabushiki KaishaInventors: Katsumi Nakagawa, Toshiyuki Komatsu, Yutaka Hirai, Teruo Misumi, Tadaji Fukuda
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Patent number: 4536461Abstract: Disclosed is a laminated photosensitive material for the electrophotography, which comprises an electroconductive substrate, a charge-generating layer composed of a vacuum deposition film of metal-free phthalocyanine formed on the substrate and a charge-transporting layer formed on the charge-generating layer, wherein the metal-free phthalocyanine film is a metal-free phthalocyanine particle layer composed mainly of .alpha.-type fine crystals having a crystal particle size of 100 to 2000 .ANG. and the vacuum deposition film has a thickness of 500 to 3000 .ANG. and a dark electroconductivity lower than 10.sup.-10 (.OMEGA.-cm).sup.-1.In this laminated photosensitive material, the initial charge quantity is improved, and the electrophotographic characteristics are stabilized when the photosensitive materials is used repeatedly or continuously.Type: GrantFiled: June 15, 1984Date of Patent: August 20, 1985Assignee: Mita Industrial Co., Ltd.Inventors: Kaname Nakatani, Junichi Hanna, Hiroshi Kokado
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Patent number: 4507375Abstract: A layer of amorphous silicon containing H, preferably 10-40 atomic %H, is used as a photoconductive layer for electrophotographic photosensitive member.Type: GrantFiled: February 17, 1984Date of Patent: March 26, 1985Assignee: Canon Kabushiki KaishaInventors: Yutaka Hirai, Toshiyuki Komatsu, Katsumi Nakagawa, Teruo Misumi, Tadaji Fukuda
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Patent number: 4472492Abstract: A method for fabricating an electrophotographic image forming member, wherein the first photoconductive layer consisting of an amorphous inorganic semiconductive material is formed on a substrate suited for the electrophotographic process, then the second photoconductive layer, which is different from the first photoconductive layer and consists of amorphous silicon containing therein silicon as the matrix and at least one of hydrogen and halogen atoms, is formed on the first photoconductive layer, and thereafter, the second photoconductive layer is annealed by irradiating a laser beam on the surface of the second photoconductive layer.Type: GrantFiled: July 8, 1983Date of Patent: September 18, 1984Assignee: Canon Kabushiki KaishaInventors: Junichiro Kanbe, Tadaji Fukuda, Toru Takahashi
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Patent number: RE35198Abstract: Image-forming member for electrophotography comprising a charge generation layer composed of hydrogenated amorphous silicon.Type: GrantFiled: September 15, 1993Date of Patent: April 2, 1996Assignee: Canon Kabushiki KaishaInventors: Katsumi Nakagawa, Toshiyuki Komatsu, Yutaka Hirai, Teruo Misumi, Tadaji Fukuda