Heterogeneous Patents (Class 430/134)
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Patent number: 11401397Abstract: The disclosure provides a very simple and convenient method for producing a porous material of a water-soluble polymer. The herein disclosed method for producing a porous material of a water-soluble polymer includes a step of preparing an emulsion containing a water-soluble polymer, water, and a dispersoid, wherein the water-soluble polymer is dissolved and the dispersoid is dispersed in the emulsion, and a step of evaporating and thereby removing the water and the dispersoid from the emulsion. The boiling point of the dispersoid is higher than the boiling point of water. The solubility of the water-soluble polymer in the dispersoid is lower than the solubility of the water-soluble polymer in water.Type: GrantFiled: May 29, 2019Date of Patent: August 2, 2022Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Akio Minakuchi, Tomoyuki Uezono, Hiroshi Uyama, Chiaki Yoshizawa
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Patent number: 10955765Abstract: A magnetic carrier comprising a magnetic carrier particle having a magnetic carrier particle having a magnetic carrier core particle and a resin coat layer formed on the magnetic carrier core particle surface, and inorganic fine particles A present on a surface of the magnetic carrier particle, wherein each of the inorganic fine particles A has a rectangular parallelepiped particle shape, the inorganic fine particles A have D1 of 10 to 60 nm, the inorganic fine particles A are inorganic particles which have been surface treated with a surface treatment agent or silane coupling agent-treated particles, SP1 of the resin coat layer and SP2 of the surface treatment agent satisfies SP1?SP2?14.00, and the coverage ratio of the magnetic carrier surface by the inorganic fine particles A as measured by ESCA is 5.0 to 20.0 atom %: and a two-component developer comprising at least the magnetic carrier and a toner.Type: GrantFiled: November 18, 2019Date of Patent: March 23, 2021Assignee: CANON KABUSHIKI KAISHAInventors: Yuto Onozaki, Ichiro Kanno, Ryo Nakajima, Kazuyuki Sakamoto, Nozomu Komatsu, Takakuni Kobori, Hiroyuki Fujikawa
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Patent number: 9765225Abstract: A conductive paste obtained by adding an organic solvent B to a vehicle containing a Ni powder, a binder resin component, and an organic solvent A. The Ni powder has an average primary particle size of 30 to 400 nm. The binder resin component is cellulose acetate butyrate. Organic solvent A is a solvent having a ? ? value of 11.5 or less with the cellulose acetate butyrate. Organic solvent B is a solvent having a ? ? value from 11.5 to 25.0 with the cellulose acetate butyrate. A ratio of the organic solvent B relative to a total of the organic solvent A and the organic solvent B is 5.0 to 40.0 wt %.Type: GrantFiled: March 11, 2016Date of Patent: September 19, 2017Assignee: MURATA MANUFACTURING CO., LTD.Inventors: Masahito Ishikawa, Naoaki Ogata
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Patent number: 8808953Abstract: An electrophotographic photoreceptor includes a conductive support, and an undercoat layer, a charge generation layer, and a charge transport layer that are provided in this order on the conductive support, wherein the undercoat layer includes at least metallic oxide particles, a reactive acceptor substance including an anthraquinone structure expressed by the following Formula 1, and a binder resin, the charge generation layer includes hydroxygallium phthalocyanine as a charge generation material, and a reflectance of incident light having a wavelength of 780 nm on a surface of the charge generation layer when the charge transport layer is removed is 17% or greater: wherein the anthraquinone structure expressed by Formula 1 is bonded to another structure at a position of *, and thus forms the reactive acceptor substance, and in Formula 1, n1 represents an integer of 1 to 7.Type: GrantFiled: July 30, 2012Date of Patent: August 19, 2014Assignee: Fuji Xerox Co., Ltd.Inventors: Satoya Sugiura, Shigeto Hashiba, Kazuhiro Koseki, Hirofumi Nakamura, Kenta Ide, Akihiro Nonaka, Kosuke Narita, Akihiro Kawasaki
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Patent number: 8753789Abstract: An electrophotographic photosensitive member comprises a charge-transporting layer which is a surface layer of the electrophotographic photosensitive member; wherein the charge-transporting layer has a matrix-domain structure having: a matrix comprising: at least one resin selected from the group consisting of a polycarbonate resin C and a polyester resin D; and at least one charge-transporting substance selected from the group consisting of a compound represented by the following formula (1) and a compound represented by the following formula (1?), and a domain comprising a polycarbonate resin A.Type: GrantFiled: August 18, 2011Date of Patent: June 17, 2014Assignee: Canon Kabushiki KaishaInventors: Harunobu Ogaki, Kazunori Noguchi, Atsushi Okuda, Shio Murai, Kazuhisa Shida, Takashi Anezaki
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Patent number: 8728690Abstract: A photoreceptor charge transport layer containing a spirodilactam and/or a lubricant has superior wear resistance.Type: GrantFiled: October 23, 2010Date of Patent: May 20, 2014Assignee: Xerox CorporationInventor: Jin Wu
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Publication number: 20120231379Abstract: Provided is a fluorine-containing resin particle dispersion including: fluorine-containing resin particles, a resin which is not dissolved in at least one solvent in a group of hydroxyl group-containing solvents including an alcohol-based solvent having 1 to 10 carbon atoms, containing no aromatic ring in the molecule structure, and a water-based medium, and which is adhered on the surface of the fluorine-containing resin particles, and at least one solvent, in which the resin is not dissolved, in the group of hydroxyl group-containing solvents, in which the fluorine-containing resin particles having the resin adhered on the surface thereof are dispersed.Type: ApplicationFiled: August 12, 2011Publication date: September 13, 2012Applicant: FUJI XEROX CO., LTD.Inventors: Katsumi NUKADA, Wataru YAMADA, Takatsugu DOI, Yuko IWADATE
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Patent number: 8227166Abstract: The presently disclosed embodiments relate generally to layers that are useful in imaging apparatus members and components, for use in electrophotographic, including digital, apparatuses. Embodiments pertain to an improved electrophotographic imaging member incorporating an outer layer having a nano- to micron-scale pattern imprinted into its surface to lower friction with the cleaning blade and improve print quality and performance. Embodiments also pertain to methods for making the improved imaging member.Type: GrantFiled: July 20, 2009Date of Patent: July 24, 2012Assignee: Xerox CorporationInventors: Woo Soo Kim, Nan-Xing Hu, Yvan Gagnon, Johann Junginger
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Patent number: 8080627Abstract: The present invention provides an electrophotographic photoreceptor having excellent lubricity and abrasion resistance by using a novel polycarbonate resin comprising structural units having a polysiloxane chain in the shape of grafts as represented by the following general formula (1) with a viscosity-average molecular weight of 12,000 to 100,000 as a binder resin for a charge transport layer of a electrophotographic photoreceptor. wherein R1 to R5 each independently represents hydrogen, fluorine, chlorine, bromine, iodine, an alkyl group, an aryl group, an alkoxy group or an aralkyl group. R6 represents an alkylene group. Y represents a polysiloxane chain.Type: GrantFiled: February 13, 2008Date of Patent: December 20, 2011Assignees: Shin-Etsu Chemical Co., Ltd., Mitsubishi Gas Chemical Company, Inc.Inventors: Masahiko Minemura, Noriyoshi Ogawa
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Patent number: 8080628Abstract: An electrophotographic photosensitive body which has both good image stability and wear resistance under high temperature and high humidity conditions can be obtained by using a novel polycarbonate resin, which contains a structural unit represented by the general formula (I) below and having a long-chain unsaturated hydrocarbon group having a double bond, as a binder resin for a charge transport layer of an electrophotographic photosensitive body. In the formula (I), R1-R4 preferably represent a hydrogen atom or a methyl group, respectively; a represents a number of 7-20; and R6 represents a hydrogen atom, a methyl group or a phenyl group. Particularly preferably, the structural unit represented by the general formula (I) below is derived from 1,1-bis(4-hydroxy-3-methylphenyl)-10-undecene or 1,1-bis(4-hydroxyphenyl)-10-undecene.Type: GrantFiled: March 28, 2007Date of Patent: December 20, 2011Assignee: Mitsubishi Gas Chemical Company, Inc.Inventor: Noriyoshi Ogawa
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Patent number: 7951516Abstract: The electrophotographic photoreceptor of the present invention includes a cylindrical support; a charge-generating layer and a charge-transporting layer that are layered onto the cylindrical support in this sequence from the cylindrical support side. The charge-transporting layer includes a charge transport material, and resins including a curable resin and a thermoplastic resin. The proportion of the content of the curable resin with respect to the total amount of the resins in the charge-transporting layer increases in the layer thickness direction with distance from the charge-generating layer side.Type: GrantFiled: May 29, 2007Date of Patent: May 31, 2011Assignee: Fuji Xerox Co., Ltd.Inventors: Tomotake Inagaki, Kazuyuki Tada, Tomomasa Sato, Naoki Morita, Kenji Ikeda
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Patent number: 7824830Abstract: A coating liquid including an N-alkoxymethylated nylon and a solvent, wherein the N-alkoxymethylated nylon includes one or more ions in an amount of from 200 to 500 ppm based on a weight of the N-alkoxymethylated nylon or one or more alkylamines in an amount of from 15 to 100 ppm based on a weight of the N-alkoxymethylated nylon. A photoreceptor including an electroconductive substrate; a charge blocking layer located overlying the substrate; a moiré preventing layer located overlying the charge blocking layer; and a photosensitive layer located overlying the moiré preventing layer, wherein the charge blocking layer is formed using the coating liquid.Type: GrantFiled: December 16, 2005Date of Patent: November 2, 2010Assignee: Ricoh Company LimitedInventors: Maiko Kondo, Tatsuya Niimi, Naohiro Toda, Takeshi Orito, Nozomu Tamoto, Katsuichi Ohta
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Patent number: 7799140Abstract: The disclosed embodiments are directed to processes for removing photoreceptor coatings from a substrate, wherein the photoreceptor coatings disposed over a substrate of an electrophotographic photoreceptor. More specifically, the invention discloses a photoreceptor coatings removal process comprises subjecting an electrophotographic photoreceptor to a stripping solution that separates the coatings from the substrate.Type: GrantFiled: June 17, 2009Date of Patent: September 21, 2010Assignee: Xerox CorporationInventors: Robert P. Altavela, Yuhua Tong, Edward F. Grabowski, Kent J. Evans, Adilson Ramos, Nancy Belknap, Helen R. Cherniack
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Patent number: 7767374Abstract: An method for producing an electrophotographic proreceptor includes a first coating step of applying a coating liquid containing a sublimable antioxidant and a photoconductive substance, onto a conductive substrate to form a first coating film thereon, a first drying step of drying the formed first coating film by heating to form a first photosensitive layer, a second coating step of applying the coating liquid used in the first coating step, onto the first photosensitive layer to form a second coating film, and a second drying step of drying the formed second coating film by heating to form a second photosensitive layer. In the second drying step, the drying condition is made to differ from the drying condition in the first drying step so that a degree of sublimation of the antioxidant in the second drying step is lower than that of sublimation of the antioxidant in the first drying step.Type: GrantFiled: December 14, 2006Date of Patent: August 3, 2010Assignee: Sharp Kabushiki KaishaInventors: Akiko Kihara, Rikiya Matsuo
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Patent number: 7759034Abstract: The present invention relates to an electrophotographic photosensitive member and an image forming apparatus provided with the electrophotographic photosensitive member. The electrophotographic photosensitive member includes a cylindrical body and a photosensitive layer formed on a circumferential surface of the cylindrical body and including a latent image forming area and a non-latent image forming area. The photosensitive layer includes a stress relaxation portion at the non-latent image forming area for releasing stress applied between the cylindrical body and the photosensitive layer. The present invention further relates to a method of producing the electrophotographic photosensitive member.Type: GrantFiled: November 28, 2006Date of Patent: July 20, 2010Assignee: Kyocera CorporationInventor: Kouichi Nakano
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Publication number: 20100080611Abstract: A developing roller is provided which supplies a toner to a photosensitive member to develop an electrostatic latent image formed on the photosensitive member. The developing roller has a surface layer which includes carbon black and a polyurethane resin. The polyurethane resin has a specific structure. The surface layer has a specific ester group concentration and a specific urethane group concentration.Type: ApplicationFiled: September 11, 2009Publication date: April 1, 2010Applicant: CANON KABUSHIKI KAISHAInventors: Masahiro Kurachi, Masaki Yamada, Yuji Sakurai, Minoru Nakamura
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Patent number: 7666560Abstract: An imaging member includes a charge generating layer and a charge transport layer. The charge transport layer includes a first surface in contact with the charge generating layer and a second surface. The charge transport layer includes a film forming polymer binder and a charge transport component dispersed therein. The concentration of the charge transport component in the charge transport layer is at a peak in a region of the charge transport intermediate the first and second surfaces of the charge transport layer.Type: GrantFiled: June 21, 2005Date of Patent: February 23, 2010Assignee: Xerox CorporationInventors: Satchidanand Mishra, Anthony M. Horgan, Kent Evans, George Liebermann, Kathleen M. Carmichael, Dennis J. Prosser, Richard L. Post, Edward Domm, Johann Junginger, Michael Zak
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Patent number: 7413840Abstract: A production method of an electrophotographic photosensitive member which has high productivity when producing a surface layer in which depressed portions which are independent respectively are formed on an electrophotographic photosensitive member surface, and can produce highly uniform depressed portions in a photosensitive member surface, characterized by producing the surface layer by (1) a coating step of producing a coating liquid for a surface layer containing a binder resin and a specific solvent, and coating it on a surface of a cylindrical supporting member, (2) a condensation step of holding the cylindrical supporting member on which the coating liquid for a surface layer is coated, and condensing the surface of the cylindrical supporting member, and (3) a drying step of baking the cylindrical supporting member.Type: GrantFiled: June 28, 2007Date of Patent: August 19, 2008Assignee: Canon Kabushiki KaishaInventors: Harunobu Ogaki, Atsushi Ochi
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Patent number: 7371491Abstract: A photoreceptor including an electroconductive substrate; and a charge blocking layer; a moiré preventing layer; and a photosensitive layer, which are overlaid overlying the substrate in this order, wherein the photosensitive layer includes a titanyl phthalocyanine crystal which has an average primary particle diameter not greater than 0.25 ?m, and has an X-ray diffraction spectrum such that a maximum peak is observed at a Bragg (2?) angle of 27.2°±0.2°; a peak is observed at Bragg (2?) angle of 9.4°±0.2°, 9.6±0.2° and 24.0±0.2°; a lowest angle peak is observed at an angle of 7.3°±0.2°; no peak is observed between the lowest angle peak and the 9.4° peak; and no peak is observed at a Bragg (2?) angle of 26.3°±0.2°, when a Cu—K? X-ray having a wavelength of 0.1542 nm (1.542 ?) is used.Type: GrantFiled: September 20, 2004Date of Patent: May 13, 2008Assignee: Ricoh Company LimitedInventors: Tatsuya Niimi, Nozomu Tamoto, Katsuichi Ohta
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Patent number: 7335452Abstract: The present disclosure provides photoreceptors and methods for fabricating photoreceptors. Photoreceptor device surfaces and fabrication methods have been designed to suppress a “plywood effect.” One method includes providing a substrate, rotating the substrate, lathing the substrate with a cutting tool and a cutting fluid by at least one pass, cleaning the substrate to remove the cutting fluid, and depositing onto the substrate at least one layer.Type: GrantFiled: November 18, 2004Date of Patent: February 26, 2008Assignee: Xerox CorporationInventors: Philip G. Perry, Gary J. Maier, Gene W. O'Dell, William G. Herbert
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Patent number: 7267914Abstract: An electrophotographic photoconductor, including an electrically conductive substrate, an undercoat layer containing a filler and a binder resin and provided on the substrate, and a photoconductive layer provided on the undercoat layer and containing a binder resin. At least one compound selected from crown ethers, polyalkyleneglycol ethers, polyethyleneglycol monocarboxylic acid esters, polyethyleneglycol dicarboxylic acid esters, and hydroxy-terminated random or block copolymers containing oxypropylene and oxyethylene groups is incorporated into (a) the undercoat layer or (b) into a charge generating layer of the photoconductive layer. In the case of (a), the photoconductive layer is a dried coating of a composition containing at least one solvent selected from cyclic ethers, ketones and aromatic hydrocarbons.Type: GrantFiled: December 6, 2002Date of Patent: September 11, 2007Assignee: Ricoh Company, Ltd.Inventors: Hirofumi Yamanami, Yukari Yamada
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Patent number: 7232635Abstract: A method of forming a toner image employing a photoreceptor is described. The photoreceptor comprises a photosensitive layer on a cylindrical conductive substrate, Formula (1) and Formula (2) are held, 0<Pmax<2P??Formula (1) 2?(Pmax/D)×100?50??Formula (2) wherein P (?m) is the average of the coating layer thickness in central section in the width direction of the photoreceptor, Pmax (?m) is average of the image forming region, and D (?m) is average of distance between point, at which said maximum value is obtained, and edge of the coating layer.Type: GrantFiled: January 24, 2003Date of Patent: June 19, 2007Assignee: Konica CorporationInventors: Nobuaki Kobayashi, Masao Asano
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Patent number: 7205079Abstract: A photoconductive imaging member includes a substrate, hole blocking layer, a photogenerating layer, and a charge transport layer, wherein the charge transport layer is formed in a sol-gel process. The charge transport layer includes an in situ formed organic-inorganic composite, and exhibits increased wear resistant and retains excellent electrical properties.Type: GrantFiled: July 9, 2004Date of Patent: April 17, 2007Assignee: Xerox CorporationInventors: Jin Wu, Liang-Bih Lin, Geoffrey M. T. Foley, Cindy C. Chen, Lanhui Zhang
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Patent number: 7060404Abstract: A photoreceptor including an electroconductive substrate; and a photosensitive layer located overlying the electroconductive substrate and comprising a charge generation material, a charge transport material and an inorganic filler, wherein the content of the inorganic filler at a surface side of the photosensitive layer is greater than that at a bottom side of the photosensitive layer near the electroconductive substrate, and wherein an outermost layer of the photoreceptor has a water vapor permeability not greater than 50 g·m?2·24 h?1.Type: GrantFiled: May 1, 2002Date of Patent: June 13, 2006Assignee: Ricoh Company, Ltd.Inventors: Hidetoshi Kami, Tatsuya Niimi, Akihiko Matsuyama, Eiji Kurimoto, Nozomu Tamoto
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Patent number: 7052813Abstract: A charge transport layer for an imaging member comprising a first and second charge transport layer wherein the second charge transport layer comprises a charge transport component, a hindered phenol covalently bonded to a polymer, and an additional polymer binder other than the polymer containing the hindered phenol. The charge transport layer exhibits excellent wear resistance, excellent electrical performance, and excellent print quality.Type: GrantFiled: August 4, 2005Date of Patent: May 30, 2006Assignee: Xerox CorporationInventors: Yuhua Tong, Timothy J. Fuller, Colleen A. Helbig, Kent J. Evans, John F. Yanus, Karen S. Garland, Paul J. DeFeo, Anita P. Lynch, Kathleen M. Carmichael, Damodar M. Pai, Dale S. Renfer, Markus R. Silvestri
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Patent number: 6833226Abstract: In an electrophotographic apparatus including an electrophotographic photosensitive member around which a charger, an exposure device, a developing device and a transfer device are provided in this order and not having any charge elimination device between the transfer device and the charger the electrophotographic photosensitive member includes a support and a charge generation layer provided thereon containing a phthalocyanine compound and a charge transport layer, and has a light-area dark attenuation rate A and a dark-area dark attenuation rate B which satisfy the following expression (1): 1.0≦light-area dark attenuation rate A/dark-area dark attenuation rate B≦1.7 (1).Type: GrantFiled: March 27, 2002Date of Patent: December 21, 2004Assignee: Canon Kabushiki KaishaInventors: Kumiko Takizawa, Hideki Ogawa, Wataru Kitamura
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Patent number: 6720121Abstract: An electrophotographic photoconductor and method of manufacturing thereof exhibits excellent characteristics of residual potential and repetition potential by containment of an additive of a compound. The electrophotographic photoconductor includes a conductive substrate and a photosensitive layer on the substrate, in which the photosensitive layer contains tri(4-nitrophenyl) phosphate.Type: GrantFiled: April 3, 2002Date of Patent: April 13, 2004Assignee: Fuji Electric Imaging Device Co. Ltd.Inventors: Yoichi Nakamura, Koichi Aizawa, Teruo Sasaki, Kenichi Hara
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Publication number: 20040053149Abstract: A photoreceptor including an electroconductive substrate; a charge generation layer located overlying the electroconductive substrate optionally with an intermediate layer therebetween; and a charge transport layer formed overlying the charge generation layer using a non-halogenated solvent and including a charge transport material and a resin, wherein the charge generation layer includes a polyvinyl acetal resin and a charge generation material having an average particle diameter less than a roughness of a surface of either the electroconductive substrate or the intermediate layer, on which the charge generation layer is located.Type: ApplicationFiled: June 27, 2003Publication date: March 18, 2004Inventors: Naohiro Toda, Tatsuya Niimi
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Patent number: 6696214Abstract: The invention provides an electrophotographic photoreceptor, in which suppression of image defects and high sensitivity are compatible, and a method for production thereof. The invention also provides a coating fluid for forming a photosensitive layer and a method for production thereof, as well as an image-forming apparatus using said electrophoto-graphic photoreceptor. Briefly, the electrophoto-graphic photoreceptors may be constructed by forming an undercoating layer on a conductive support, and then forming a photosensitive layer on the undercoating layer. The undercoating layer contains titanium oxide particles in at least either needle shape or dendrite shape. The photosensitive layer contains an electric charge-generating material of which the primary particle size and cohesive particle size are in a range of 0.01 &mgr;m-10 &mgr;m. Accordingly, in the electrophotographic photoreceptors, it is possible to maintain high sensitivity and excellent durability and to form an image with no defect.Type: GrantFiled: January 6, 2003Date of Patent: February 24, 2004Assignee: Sharp Kabushiki KaishaInventors: Satoshi Katayama, Mikio Kakui, Masayuki Sakamoto, Tatsuhiro Morita, Sayaka Fujita, Tadashi Nakamura
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Patent number: 6645687Abstract: A process comprising forming chlorogallium phthalocyanine (ClGaPc) in N-methyl-2-pyrrolidinone (NMP) to provide a ClGaPc (NMP) Type I; separately dry milling and then wet treating the Type I product to form Type II ClGaPc (NMP); blending the ClGaPc Type II product with hydroxygallium phthalocyanine (HOGaPc) Type V and a resin to form a coating mixture; coating the resulting mixture to form a photoconductive charge generator layer.Type: GrantFiled: May 10, 2002Date of Patent: November 11, 2003Assignee: Xerox CorporationInventors: Cuong Vong, George Liebermann, Richard A. Burt, Ah-Mee Hor
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Patent number: 6632578Abstract: A process for producing an electrophotographic light-receiving member having a conductive support and a light-receiving member having a photoconductive layer formed on the surface of the conductive support and composed of a non-single crystal material containing silicon atoms as a main component, hydrogen atoms and/or halogen atoms. The photoconductive layer is formed at a flow rate (X) sccm of n Si supply gas and a discharge space volume (Z) cm3 satisfying (A) and a flow rate (X) sccm of the Si supply gas and density (Y) W/cm3 of the electric power input to the discharge space satisfying the following relation (B) wherein 3×10−3≦X/Z≦1×10−2 (A) and 3×10−4≦Y/X≦7×10−4 (B).Type: GrantFiled: September 27, 2002Date of Patent: October 14, 2003Assignee: Canon Kabushiki KaishaInventors: Hiroaki Niino, Satoshi Kojima, Shinji Tsuchida
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Patent number: 6605400Abstract: An electrophotographic photoreceptor is disclosed. A surface layer of the photoreceptor comprises binder resin having silicon or fluorine atoms and dioxolan or a derivative thereof at 0.001 to 10 weight percent.Type: GrantFiled: July 6, 1998Date of Patent: August 12, 2003Assignee: Konica CorporationInventors: Akihiko Itami, Masao Asano
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Publication number: 20030113642Abstract: A photoreceptor including an electroconductive substrate; and a photosensitive layer located overlying the electroconductive substrate and comprising a charge generation material, a charge transport material and an inorganic filler, wherein the content of the inorganic filler at a surface side of the photosensitive layer is greater than that at a bottom side of the photosensitive layer near the electroconductive substrate, and wherein an outermost layer of the photoreceptor has a water vapor permeability not greater than 50 g·m−2·24 h−1.Type: ApplicationFiled: May 1, 2002Publication date: June 19, 2003Inventors: Hidetoshi Kami, Tatsuya Niimi, Akihiko Matsuyama, Eiji Kurimoto, Nozomu Tamoto
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Publication number: 20030031944Abstract: An electrophotographic photoconductor includes a photosensitive layer on a conductive substrate. The photosensitive layer contains a pigment that consists of crystallites composed of molecules having a titanylphthalocyanine structure, wherein a crystallite diameter of the pigment is not smaller than 20 nm and a primary particle diameter of the pigment is not larger than 500 nm.Type: ApplicationFiled: April 24, 2002Publication date: February 13, 2003Applicant: FUJI ELECTRIC IMAGING DEVICE CO., LTD.Inventor: Mikio Yamazaki
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Publication number: 20030013029Abstract: A process including: forming a first chlorogallium phthalocyanine (ClGaPc) in N-methyl-2-pyrrolidone (NMP) to form a ClGaPc (NMP) Type-I product; forming a second chlorogallium phthalocyanine in dimethyl sulfoxide (DMSO) to form a ClGaPc (DMSO) Type-I product; separately dry milling and then wet treating the Type-I products to form respective Type-II products; blending the Type-II products together along with a resin to form a coating mixture; and coating the mixture to form a charge generator layer in an electrostatographic imaging article.Type: ApplicationFiled: March 23, 2001Publication date: January 16, 2003Applicant: Xerox CorporationInventors: Richard A. Burt, George Liebermann, Cheng-Kuo Hsiao, Ah-Mee Hor
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Patent number: 6492080Abstract: A process including: forming a first chlorogallium phthalocyanine (ClGaPc) in N-methyl-2-pyrrolidone (NMP) to form a ClGaPc (NMP) Type-I product; forming a second chlorogallium phthalocyanine in dimethyl sulfoxide (DMSO) to form a ClGaPc (DMSO) Type-I product; separately dry milling and then wet treating the Type-I products to form respective Type-II products; blending the Type-II products together along with a resin to form a coating mixture; and coating the mixture to form a charge generator layer in an electrostatographic imaging article.Type: GrantFiled: March 23, 2001Date of Patent: December 10, 2002Assignee: Xerox CorporationInventors: Richard A. Burt, George Liebermann, Cheng-Kuo Hsiao, Ah-Mee Hor
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Patent number: 6489072Abstract: An electrophotographic photoconductor includes a conductive substrate and a photosensitive layer formed on a substrate. The photosensitive layer includes a phthalocyanine compound as a charge generation substance. An embodiment of the photosensitive layer contains a first phthalocyanine compound as a main component and a second phthalocyanine compound as a secondary component and as a result, has greater ability to generate negative charges than the ability of the first phthalocyanine compound.Type: GrantFiled: May 31, 2001Date of Patent: December 3, 2002Assignee: Fuji Electric Imaging Device Co., Ltd.Inventors: Teruo Sasaki, Yoichi Nakamura, Shinjirou Suzuki
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Patent number: 6447965Abstract: An electrophotographic photoreceptor highly sensitive to laser light, which is capable of forming an image without forming an interference fringe and a coating liquid for a charge generating layer for forming the same are provided, and the photoreceptor is produced with excellent coating properties and high electric characteristics at a low cost. The electrophotographic photoreceptor comprises an electroconductive support and a photosensitive layer thereon having a charge generating layer containing TiOPc as a charge generating material and having a Y value by a color measuring apparatus of 37 or less, and particularly 35 or less, and a charge transporting layer, accumulated thereon, containing a charge transporting material. In an X-ray diffraction spectrum, the TiOPc has major diffraction peaks at Bragg angles (2&thgr;±0.2°) of 7.3°, 9.4°, 9.6°, 11.6°, 13.3°, 17.9°, 24.1° and 27.2°, and in particular, the diffraction peaks at the Bragg angles (2&thgr;±0.Type: GrantFiled: August 31, 2000Date of Patent: September 10, 2002Assignee: Sharp Kabushiki KaishaInventors: Tomomi Nakamura, Masato Miyauchi
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Publication number: 20020119388Abstract: A method for manufacturing an electrophotography photosensitive body coats a charge generating layer on a conductive substrate and a charge transport layer on the charge generating layer. The charge generating layer is formed using a coating solution includes a charge generating substance, a binding resin and a solvent. The charge transport layer is formed using a second coating solution including a charge transport substance, a binding resin and a solvent.Type: ApplicationFiled: December 4, 2001Publication date: August 29, 2002Inventor: Hirotaka Kobayashi
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Publication number: 20020094487Abstract: A photoreceptor including an electroconductive substrate; a charge generation layer formed overlying the electroconductive substrate and including as a charge generation material a titanyl phthalocyanine crystal having an X-ray diffraction spectrum such that a maximum diffraction peak is observed at a Bragg (2&thgr;) angle of 27.2°±0.2° when a specific X-ray of Cu-K&agr; having wavelength of 1.514 Å irradiates the titanyl phthalocyanine crystal; and a charge transport layer formed on the charge generation layer and including a binder resin, a charge transport material, water and tetrahydrofuran, wherein a weight ratio of the water to the tetrahydrofuran in the charge transport layer is from 1/50 to 1/0.5.Type: ApplicationFiled: May 9, 2001Publication date: July 18, 2002Applicant: Ricoh Company, Ltd.Inventor: Yoshiaki Kawasaki
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Publication number: 20020051919Abstract: An apparatus for forming an image on a recording sheet having low toner pile height. A photoconductive member is provided, said photoconductive member includes a charge generation pattern for directing developed toner; means for recording a latent image of one color separation on said photoconductive member; means for developing said latent image on said photoconductive member; and means for transferring said developed said latent image on said photoconductive member to the recording sheet.Type: ApplicationFiled: June 28, 2001Publication date: May 2, 2002Applicant: Xerox CorporationInventor: John S. Berkes
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Patent number: 6352809Abstract: A process for producing an electrophotographic photoreceptor, which includes contacting a solution containing at least one of optically functional organosilicon compounds represented by formula (I) F—[D—A]b (I) with a solid catalyst for reaction, then separating the solid catalyst to form an optically functional coating solution, and coating and curing the optically functional coating solution to form a cured film, an electrophotographic photoreceptor having at least one layer made of the cured film produced by this process, and an image-forming apparatus having the same.Type: GrantFiled: August 9, 2000Date of Patent: March 5, 2002Assignee: Fuji Xerox Co., Ltd.Inventors: Katsumi Nukada, Wataru Yamada, Kazuhiro Koseki, Tomozumi Uesaka
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Publication number: 20010038960Abstract: The present invention relates to an electrophotosensitive material wherein a layer containing a binder resin and a pigment among a photosensitive layer is formed by applying and drying a coating solution prepared by dispersing the binder resin and the pigment in a dispersion medium containing alcohol represented by the formula (1): 1Type: ApplicationFiled: March 15, 2001Publication date: November 8, 2001Inventors: Jun Azuma, Mitsuo Ihara, Maki Uchida, Daisuke Kuboshima, Yukikatsu Imanaka, Hiromi Nakatsu, Teruyo Taguchi
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Patent number: 6245475Abstract: A method of forming one or more polymer containing layers on a substrate using ink jet nozzles. The method is particularly suited to forming one or more polymer containing layers of a photoreceptor. The polymer containing layers may be formed by moving a substrate, in particular a cylindrical substrate, past the ink jet nozzles, by moving the ink jet nozzles over the substrate, or both. The ink jet nozzles are capable of being independently controlled in order to permit precise location of the coating on the substrate.Type: GrantFiled: December 16, 1999Date of Patent: June 12, 2001Assignee: Xerox CorporationInventors: Merlin E. Scharfe, John M. Hammond, Robert F. Dunham, Jian Cai, Kenny Tuan Dinh, Roger T. Janezic
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Patent number: 6225016Abstract: A photoconductor for electrophotography includes a photosensitive film containing a bisazo charge generation agent described by structural formula (I) and from 100 nmol to 40 mmol, preferably from 500 nmol to 20 mmol, of a compound described by a structural formula (II) with respect to 1 mol of the bisazo charge generation agent. Such a photoconductor for electrophotography minimizes visual defects and image nonuniformity.Type: GrantFiled: August 25, 2000Date of Patent: May 1, 2001Assignee: Fuji Electric Imaging Device Co., Ltd.Inventors: Teruo Sasaki, Yoichi Nakamura
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Patent number: 6214513Abstract: A coating process for the fabrication of organic photoreceptors employs an electrically conductive single slot die biased to allow an electric field between the die and the ground plane on the photoreceptor substrate. The homogenous coating dispersion is fed through the die at a predetermined gap and rate to control coating thickness at the same time that an electric field is applied. The formulation, rheology, particle mobility, coating speed, electric field and the like are controlled so that the photogenerator particles migrate to the substrate in the dwell time defined by the coating die region.Type: GrantFiled: November 24, 1999Date of Patent: April 10, 2001Assignee: Xerox CorporationInventors: Jian Cai, Robert F. Dunham, Merle Emil Scharfe, Ian D. Morrison
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Patent number: 6190812Abstract: The present invention provides a single-layer type electrophotosensitive material comprising a conductive substrate and a photosensitive layer formed on the conductive substrate, wherein the photosensitive layer contains a phthalocyanine compound as an electric charge generating material, a hole transferring material and an electron transferring material in a binder resin, and that a difference in absolute value between a plus polarity sensitivity and a minus polarity sensitivity measured under the conditions of an exposure wavelength of 780 nm and an exposure energy of 1.0 &mgr;J/cm2 is not more than 500 V, and a reversal development type digital image forming apparatus using the electrophotosensitive material, which does not include a charge neutralizing step.Type: GrantFiled: June 20, 2000Date of Patent: February 20, 2001Assignee: Kyocera Mita CorporationInventors: Yukikatsu Imanaka, Hiroaki Iwasaki, Yuji Tanaka, Masakatsu Hayashi
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Patent number: 6180309Abstract: A process for preparing an imaging member includes applying a first organic layer to an imaging member substrate, treating the first organic layer with one of corona discharge or plasma discharge; and applying a second organic layer to the first organic layer.Type: GrantFiled: November 26, 1999Date of Patent: January 30, 2001Assignee: Xerox CorporationInventors: David J Maty, Robert L Flanagan
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Patent number: RE39516Abstract: The present invention provides a single-layer type electrophotosensitive material comprising a conductive substrate and a photosensitive layer formed on the conductive substrate, wherein the photosensitive layer contains a phthalocyanine compound as an electric charge generating material, a hole transferring material and an electron transferring material in a binder resin, and that a difference in absolute value between a plus polarity sensitivity and a minus polarity sensitivity measured under the conditions of an exposure wavelength of 780 nm and an exposure energy of 1.0 ?J/cm2 is not more than 500 V, and a reversal development type digital image forming apparatus using the electrophotosensitive material, which does not include a charge neutralizing step.Type: GrantFiled: October 14, 2004Date of Patent: March 13, 2007Assignee: Kyocera Mita CorporationInventors: Yukikatsu Imanaka, Hiroaki Iwasaki, Yuji Tanaka, Masakatsu Hayashi
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Patent number: RE42189Abstract: The present invention provides a single-layer type electrophotosensitive material comprising a conductive substrate and a photosensitive layer formed on the conductive substrate, wherein the photosensitive layer contains a phthalocyanine compound as an electric charge generating material, a hole transferring material and an electron transferring material in a binder resin, and that a difference in absolute value between a plus polarity sensitivity and a minus polarity sensitivity measured under the conditions of an exposure wavelength of 780 nm and an exposure energy of 1.0 ?J/cm2 is not more than 500 312 V, and a reversal development type digital image forming apparatus using the electrophotosensitive material, which does not include a charge neutralizing step.Type: GrantFiled: September 15, 2009Date of Patent: March 1, 2011Assignee: Kyocera Mita CorporationInventors: Yukikatsu Imanaka, Hiroaki Iwasaki, Yuji Tanaka, Masakatsu Hayashi