By Coating Patents (Class 430/137.11)
  • Publication number: 20090042122
    Abstract: Toner compositions, methods for making toner compositions, and methods for coating toner particles. A method for coating toner particles may include mixing dry toner particles and a dispersion including shell particles to coat at least a portion of an exterior surface of the toner particles with an essentially continuous layer of the shell particles. The toner particles may comprise a first resin and a coloring agent. The shell particles may comprise a second resin.
    Type: Application
    Filed: August 7, 2008
    Publication date: February 12, 2009
    Applicant: KATUN CORPORATION
    Inventors: JEAN GUAY, MARK CUMMINGS
  • Patent number: 7476481
    Abstract: An electrostatic charge image developing toner comprises core particles formed by flocculating and fusion-bonding at least polyester resin particles containing wax and colorant particles, and a coating layer containing a resin formed over the core particles.
    Type: Grant
    Filed: November 5, 2004
    Date of Patent: January 13, 2009
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Yasumitsu Fujino, Hideaki Ueda, Seishi Ojima, Fumie Motoori
  • Patent number: 7452652
    Abstract: Liquid toners suitable for use in the electrostatic printing of functional materials to produce microstructures such as ribs, electrodes, spacers or filters, and methods of producing the liquid toners. The functional materials, which may include metals, glass and phosphors, are suspended as particles in a dilutent, which may be a non-polar liquid. The surface, or portions of the surface, of the functional material particles are given an appropriate acidic or hydroxyl functionality necessary for their use in electrostatic imaging either by etching or by coating with a material having the appropriate surface functionality.
    Type: Grant
    Filed: December 22, 2004
    Date of Patent: November 18, 2008
    Inventor: Robert H. Detig
  • Publication number: 20080241724
    Abstract: Toner compositions of toner particles including additive particles upon an external surface of the toner particles, wherein the additive particles include crosslinked styrene containing polymer particles, exhibit reduced sensitivity to relative humidity. The crosslinked styrene containing polymer particles have an average particle size of from about 30 nm to about 300 nm, and may include styrene homopolymer particles, styrene copolymer particles or mixtures thereof. A process of reducing the relative humidity sensitivity of toner using such external surface additive is also described.
    Type: Application
    Filed: June 11, 2008
    Publication date: October 2, 2008
    Applicant: XEROX CORPORATION
    Inventors: Maria N.V. MCDOUGALL, Daryl Vanbesien, Allan K. Chen, Richard P.N. Veregin, Vladislav Skorokhod
  • Patent number: 7419753
    Abstract: A toner composition that includes a resin substantially free of cross linking, a cross linked resin, a polyester resin as a crystalline polyester resin, and a colorant.
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: September 2, 2008
    Assignee: Xerox Corporation
    Inventors: Daryl W. Vanbesien, Raj D. Patel, Karen A. Moffat, Edward G. Zwartz, Cuong Vong
  • Patent number: 7416827
    Abstract: Ultra low melt toner compositions with improved non-additive heat cohesion are disclosed. These toner compositions include toner particles comprising amorphous resins containing at least one unsaturated moiety, and when the toner particles are surface treated with a peroxy compound and optionally with a peroxy promoter compound, the surface of the toner particles is cross-linked to form a thin, robust shell. Processes for preparing the toner compositions are also described.
    Type: Grant
    Filed: June 30, 2005
    Date of Patent: August 26, 2008
    Assignee: Xerox Corporation
    Inventors: Valerie M. Farrugia, Guerino G. Sacripante, Michael S. Hawkins, Ke Zhou
  • Patent number: 7374846
    Abstract: The present invention relates to a non-magnetic monocomponent color toner composition and a method for preparing the same, and more particularly to a non-magnetic monocomponent color toner composition having a narrow charge distribution, good charging characteristics, good environmental independence, superior image characteristics, high transfer efficiency and long-term stability caused by significantly improved charge maintenance capability, and a method for preparing the same. The non-magnetic monocomponent color toner composition of the present invention is prepared by coating organic particles having an average particle size of 0.3 to 2.0 ?m, organic particles having an average particle size of 0.05 to 0.25 ?m, and silica on toner mother particles.
    Type: Grant
    Filed: October 21, 2005
    Date of Patent: May 20, 2008
    Assignee: LG Chem, Ltd.
    Inventors: Hyeung-Jin Lee, Tae-Hee Yoon, Joo-Yong Park, Chang-Soon Lee
  • Patent number: 7371498
    Abstract: The present invention relates to methods of drying and recovering toner particles from a liquid carrier. The methods are very effective to generate discrete, substantially non-agglomerated dry toner particles in a manner that preserves the particle size and particle distribution of the wet particles. The resultant dried toner particles free-flowing with a relatively narrow particle size distribution. The present invention uses extrusion techniques to coat wet toner particles onto a substrate surface. Because the resultant coating has a relatively large drying surface area per gram of particle incorporated into the coating, drying may occur relatively quickly under moderate temperature and pressure conditions. After drying, the dried toner particles are readily recovered and may then be used in dry or even wet toners for electrophotographic applications.
    Type: Grant
    Filed: June 30, 2004
    Date of Patent: May 13, 2008
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Ronald J. Moudry, Hsin Hsin Chou
  • Patent number: 7354690
    Abstract: A toner producing method is provided, which comprises preparing toner base particles in an aqueous medium, wherein the toner base particles comprise resin fine particles, and forming a coating layer on the surface of the toner base particles, wherein the coating layer is formed by attaching or coating a toner functional substance onto the surface of the toner base particles using at least one of supercritical fluids and sub-supercritical fluids.
    Type: Grant
    Filed: September 19, 2006
    Date of Patent: April 8, 2008
    Assignee: Ricoh Company, Ltd.
    Inventors: Masayuki Ishii, Chiaki Tanaka, Nahiro Watanabe, Kei Naitoh, Takuya Saito
  • Publication number: 20080070144
    Abstract: A toner including toner particles including a binder resin, and a modified layered inorganic material in which at least part of interlayer ions is replaced with an organic ion, and a fatty acid metal compound located on a surface of the toner particles; and an external additive located on the fatty acid metal compound, wherein the external additive is a material different from the fatty acid metal compound. An image forming apparatus including an image bearing member; a developing device configured to develop the electrostatic latent image with a developer including the toner; a transfer device; and a fixing device. A method for preparing the toner including dispersing or emulsifying a toner composition including a modified layered inorganic material to prepare toner particles; mixing a fatty acid metal compound with the toner particles; and second mixing the toner particles with an external additive.
    Type: Application
    Filed: September 10, 2007
    Publication date: March 20, 2008
    Inventors: Tsuneyasu Nagatomo, Naohiro Watanabe, Osamu Uchinokura, Satoshi Kojima
  • Patent number: 7344817
    Abstract: The present invention relates to methods of drying and recovering toner particles from a liquid carrier. The methods are very effective to generate discrete, substantially non-agglomerated dry toner particles in a manner that preserves the particle size and particle distribution of the wet particles. The resultant dried toner particles free-flowing with a relatively narrow particle size distribution. The present invention uses electrical phenomena to help transfer charged toner particles from a liquid carrier onto a substrate surface. In practical effect, the particles are electrically plated onto the surface. Because the resultant coating has a relatively large drying surface area per gram of particle incorporated into the coating, drying may occur relatively quickly under moderate temperature and pressure conditions. After drying, the dried toner particles are readily recovered and may then be used in dry or even wet toners for electrophotographic applications.
    Type: Grant
    Filed: June 30, 2004
    Date of Patent: March 18, 2008
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Hsin Hsin Chou, Ronald J. Moudry
  • Publication number: 20080057431
    Abstract: A toner having a core with a first latex having a specific glass transition temperature, and further having a shell surrounding the core with a second latex having a specific glass transition temperature and possessing functional groups, and processes for producing the same.
    Type: Application
    Filed: September 5, 2006
    Publication date: March 6, 2008
    Inventors: Zhen Lai, Yuhua Tong, Chieh-Min Cheng, Peter V. Nguyen, Jon T. Owens
  • Publication number: 20080044755
    Abstract: Toner compositions, in embodiments, having excellent charging characteristics and excellent dispensing performance are provided.
    Type: Application
    Filed: August 15, 2006
    Publication date: February 21, 2008
    Inventors: Vincenzo G. Marcello, Dennis A. Mattison, Steven A. VanScott, Kevin F. Marcell, Timothy L. Lincoln, Angela Schnuerch
  • Patent number: 7323281
    Abstract: A toner comprising toner particles comprising a first binder resin; a second binder resin different from said first binder resin and having a glass transition temperature of from 40 to 55° C.; a colorant; and a release agent, and a particulate resin material which is located on surface of the toner particles with a coverage of from 50 to 100%, and which has a glass transition temperature of from 50 to 90° C., wherein a weight ratio (W2/W1) between the second binder resin (W2) and the first binder resin (W1) is from 5/95 to 40/60, and wherein a ratio (G?80/G?180) between a storage modulus of the toner at 80° C. (G?80) and a storage modulus at 180° C. (G?180) is from 100 to 1,000.
    Type: Grant
    Filed: September 29, 2006
    Date of Patent: January 29, 2008
    Assignee: Ricoh Company, Ltd.
    Inventors: Shigeru Emoto, Shinichiro Yagi, Naohito Shimota, Maiko Kondo, Fumihiro Sasaki, Toshiki Nanya, Hiroto Higuchi, Masami Tomita, Tomoyuki Ichikawa
  • Publication number: 20080003515
    Abstract: A method of preparing toner, is provided by preparing a stabilizer dispersion solution using distilled water and a dispersing agent; forming droplets by discharging the toner composition including at least one polymerizable monomer, a colorant, wax, and an initiator into the stabilizer dispersion solution through a syringe needle; forming core particles by warming the droplets dispersed in the stabilizer dispersion solution; and forming shells by adding a polymerizable monomer, a cross-linking agent, and an initiator to the core particles. The diameter of particles of the toner can be efficiently adjusted by changing the manufacturing process of the polymerization toner. The distribution of the toner particle diameter is improved and thus no additional sorting process is required. Also, the transferring performance of the toner can be improved, and various colors can be realized by a simple process.
    Type: Application
    Filed: December 11, 2006
    Publication date: January 3, 2008
    Inventors: Yo-da Shin, Kyung-yol Yon, Chang-kook Hong, Min-young Cheong, Sang-soon Lim, Su-bum Park
  • Patent number: 7297459
    Abstract: A process for manufacturing a toner having improved relative humidity sensitivity is described. The process comprises forming polyester toner particles by emulsion/aggratation, fluidizing the toner particles with a stream of inert gas while spraying the toner particles with a solution containing an additive affecting relative humidity sensitivity, and wherein the additive contacts a surface of the toner particles and the additive remains on the surface of the toner particles.
    Type: Grant
    Filed: November 1, 2004
    Date of Patent: November 20, 2007
    Assignee: Xerox Corporation
    Inventors: Milan Maric, Alan E. J. Toth, Marko D. Saban
  • Patent number: 7285367
    Abstract: A method of manufacturing a toner for developing static charges in an aqueous system is provided which includes preparation step for a resin kneaded product, preparation step for the aqueous dispersion of a less water-soluble alkaline earth metal salt, preparation step for synthetic resin particles, removal step for the less water-soluble alkaline earth metal salt, and separation-cleaning-drying step. At preparation step S3 for synthetic resin, an ionic material for decomposing the less water-soluble alkaline earth metal salt is admixed with a mixture of the resin kneaded product and the aqueous dispersion of the less water-soluble alkaline earth metal salt.
    Type: Grant
    Filed: March 7, 2005
    Date of Patent: October 23, 2007
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Yoshitaka Kawase, Takanori Kamoto, Satoru Ariyoshi
  • Publication number: 20070218393
    Abstract: A toner including a core including at least a colorant, a release agent and a first binder resin; and a shell located overlying the core and including at least a second binder resin, wherein the first binder resin includes a polyester resin including a unit obtained from a diol selected from the group consisting of aliphatic diols and alicyclic diols, and the second binder resin includes a vinyl copolymer, and wherein a weight ratio (S/C) of the shell (S) to the core (C) is from 0.05 to 0.5 and the toner has a volume average particle diameter of from 3 to 8 ?m.
    Type: Application
    Filed: March 13, 2007
    Publication date: September 20, 2007
    Inventors: Tsuyoshi Nozaki, Chiyoshi Nozaki, Minoru Nakamura, Atsushi Yamamoto
  • Publication number: 20070207402
    Abstract: The invention provides a toner for electrostatic latent image development comprising a first component and a second component which are isolated from each other and capable of forming a color when the first component and the second component are brought into reaction with each other, and a photo-curable composition containing either the first component or the second component, the photo-curable composition not being capable of forming a color when the photo-curable composition is not cured, that is irreversibly controlled to a state of being capable of forming a color by irradiating light having a specific wavelength at which the photo-curable composition is cured.
    Type: Application
    Filed: August 16, 2006
    Publication date: September 6, 2007
    Applicant: FUJI XEROX CO., LTD.
    Inventors: Seiichi Takagi, Takashi Imai, Susumu Yoshino, Katsumi Daimon, Emi Takahashi, Toyofumi Inoue, Yasushige Nakamura, Isao Ito
  • Publication number: 20070202427
    Abstract: A method for preparing a toner including providing toner particles including at least a binder resin; and contacting a coating fluid including a silicone resin and at least one of a super critical fluid and a sub-critical fluid with a surface of the toner particles to form thereon a layer including the silicone resin. A toner prepared by the method. A developer including the toner and an optional carrier. An image forming method, and image forming apparatus, and a process cartridge using the developer.
    Type: Application
    Filed: February 20, 2007
    Publication date: August 30, 2007
    Inventor: Chiaki TANAKA
  • Patent number: 7252920
    Abstract: A method for manufacturing a polymerized toner comprising a process for forming fine droplets of a polymerizable monomer composition in an aqueous dispersion medium, and a process for polymerizing the polymerizable monomer composition after the process for forming fine droplets; wherein the process for forming fine droplets has the steps of: preparing an agitating apparatus having an agitator equipped with an agitating blade or rotor and a dispersion supply tank; providing a polymerizable monomer composition and an aqueous dispersion medium into the dispersion supply tank; then, mixing the polymerizable monomer composition and the aqueous dispersion medium by the agitator to obtain a dispersion of fine droplets; and the relationship between the peripheral velocity of the agitating blade or rotor of the agitator and the number of circulations of the dispersion is controlled.
    Type: Grant
    Filed: March 19, 2004
    Date of Patent: August 7, 2007
    Assignee: Zeon Corporation
    Inventors: Hisashi Kurokawa, Makoto Watanabe
  • Publication number: 20070154832
    Abstract: A method of preparing a toner, includes: preparing a high molecular weight latex particle by polymerizing a toner composition including a macromonomer having a hydrophilic group, a hydrophobic group and at least one reactive functional group, and at least one polymerizable monomer; forming a core particle by aggregating the high molecular weight latex particle; forming a shell layer by coating the core particle using a polymer having a higher glass transition temperature than a glass transition temperature of the core particle. Also, provided are a toner prepared using the method, an image forming method using the toner, and an image forming apparatus using the toner. Using the toner, an image can be fused at a low temperature. Also, durability of the toner is improved.
    Type: Application
    Filed: November 8, 2006
    Publication date: July 5, 2007
    Inventors: Chang-kook Hong, Kyung-yol Yon, Min-young Cheong
  • Publication number: 20070154831
    Abstract: A method of preparing a toner is provided, including: preparing a core by mixing a polyester resin and a colorant with a macromonomer including a hydrophilic group, a hydrophobic group, and one or more reactive functional groups, and a nonionic reactive emulsifier; and preparing a shell by polymerizing the exterior surface of the core using one or more polymerizable monomers and an initiator, wherein the macromonomer and the nonionic reactive emulsifier participate in the polymerization. A toner is prepared using the method. An image forming method and an image forming apparatus are provided that use the toner. Using the method, the image forming apparatus can print high quality images at high speed at a low temperature since the core of toner has superior fixability at a low temperature and superior image properties and the shell of toner has superior durability and superior charging properties. Also, using the nonionic reactive emulsifier, stable toner particles having desired sizes are prepared.
    Type: Application
    Filed: November 8, 2006
    Publication date: July 5, 2007
    Inventors: Min-young Cheong, Kyung-yol Yon, Chang-kook Hong, Jun-young Lee
  • Patent number: 7208255
    Abstract: A color toner composition for developing latent electrostatic images includes nanopowder-coated toner particles, the powder-coated toner particles being characterized in that each comprises a core toner particle having a volume average diameter, Dp, and the core toner particles have affixed to their surfaces a plurality of discrete colorant powder particles having a volume average diameter, dp, wherein the ratio of Dp/dp is at least about 5 and the weight fraction of colorant powder particles is at least about 0.01 based on the combined weight of core toner particles and colorant powder particles. Preferably, the weight fraction of colorant powder particles is from about 0.3 to about 3 times the product, (?p/?r) (d/r) (1+d/r)2, where ?p is the density of the colorant powder particles, ?r the density of the core resin particles, d, the volumetric mean diameter of the colorant powder particles and r the volumetric mean radius of the toner core resin particles.
    Type: Grant
    Filed: April 22, 2004
    Date of Patent: April 24, 2007
    Assignee: DPI Solutions, Incorporated
    Inventors: Chul-Hwan Kim, Kyung Hee Kim, Eui Joon Choi, Hyun-Nam Yoon
  • Patent number: 7179576
    Abstract: A toner includes core particles containing a resin and a colorant, and a coating layer formed over the core particles. The coating layer includes at least one type of coating particles selected from the group consisting of wax-containing resin microparticles containing a resin and a wax, and colorant-containing resin microparticles containing a resin and a colorant, the coating particles fusion-bonded to the surface of the core particles.
    Type: Grant
    Filed: March 4, 2004
    Date of Patent: February 20, 2007
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Hideaki Ueda, Mitsutoshi Nakamura, Noboru Ueda, Yasumitsu Fujino
  • Patent number: 7169527
    Abstract: A developing agent includes a toner particle having a plurality of resin particles containing a binder resin and coloring agent, and a continuous releasant phase which is present between the plurality of resin particles, and coats the plurality of resin particles.
    Type: Grant
    Filed: March 22, 2004
    Date of Patent: January 30, 2007
    Assignees: Kabushiki Kaisha Toshiba, Toshiba Tec Kabushiki Kaisha
    Inventors: Tsuyoshi Ito, Toshiaki Yamauchi
  • Patent number: 7169526
    Abstract: A toner for the development of an electrostatic image is provided wherein at least one layer of a particulate resin is coated onto a substantial portion of the surface of an agglomerate of particles made from at least primary polymer particles and primary colorant particles, wherein at least one of the primary polymer particles and the particulate resin contains a wax, and the particulate resin of the outermost layer is substantially free of wax and a process for producing the toner.
    Type: Grant
    Filed: December 18, 2000
    Date of Patent: January 30, 2007
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Tomoko Ishikawa, Yuqing Xu, Katsuo Koizumi, Noriaki Takahashi, Osamu Ando
  • Patent number: 7157199
    Abstract: A toner comprising toner particles comprising a first binder resin; a second binder resin different from said first binder resin and having a glass transition temperature of from 40 to 55° C.; a colorant; and a release agent, and a particulate resin material which is located on surface of the toner particles with a coverage of from 50 to 100%, and which has a glass transition temperature of from 50 to 90° C., wherein a weight ratio (W2/W1) between the second binder resin (W2) and the first binder resin (W1) is from 5/95 to 40/60, and wherein a ratio (G?80/G?180) between a storage modulus of the toner at 80° C. (G?80) and a storage modulus at 180° C. (G?180) is from 100 to 1,000.
    Type: Grant
    Filed: December 1, 2003
    Date of Patent: January 2, 2007
    Assignee: Ricoh Company, Ltd.
    Inventors: Shigeru Emoto, Shinichiro Yagi, Naohito Shimota, Maiko Kondo, Fumihiro Sasaki, Toshiki Nanya, Hiroto Higuchi, Masami Tomita, Tomoyuki Ichikawa
  • Patent number: 7083890
    Abstract: A toner is used in an image forming process employing a toner recycling system and contains at least a modified polyester resin, a coloring agent, and a releasing agent. The toner has a volume-average particle diameter Dv, a number-average particle diameter Dn and a shape factor SF-1, wherein Dv is in a range from 4.0 ?m to 6.0 ?m, the ratio Dv/Dn of Dv to Dn is in a range from 1.00 to 1.30, and the shape factor SF-1 is in a range from 140 to 200.
    Type: Grant
    Filed: January 20, 2004
    Date of Patent: August 1, 2006
    Assignee: Ricoh Company, Ltd.
    Inventors: Shigeru Emoto, Toshiki Nanya, Naohito Shimota, Maiko Kondo, Shinichiro Yagi, Hiroto Higuchi, Fumihiro Sasaki, Takahiro Honda, Junichi Awamura
  • Patent number: 7049039
    Abstract: A coloring agent for use in toners which comprises coloring particles modified with a surface modifier having in one molecule a hydrophilic moiety, a hydrophobic moiety, and a reactive moiety between the hydrophilic moiety and the hydrophobic moiety. Also disclosed is a toner comprising toner particles containing at least a binder resin and a coloring agent comprising the above surface-modified coloring particles.
    Type: Grant
    Filed: May 21, 2002
    Date of Patent: May 23, 2006
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yayoi Tazawa, Yasukazu Ayaki
  • Patent number: 7005224
    Abstract: The present invention relates to the use of polyolefin waxes which have been prepared by means of metallocene catalysts and have been modified to make them polar in photocopier toners and also to photocopier toners comprising such polyolefin waxes modified to make them polar.
    Type: Grant
    Filed: November 25, 2002
    Date of Patent: February 28, 2006
    Assignee: Clariant GmbH
    Inventors: Gerd Hohner, Michael Bayer
  • Patent number: 6887638
    Abstract: A toner for developing an electrostatic latent image is provided that is excellent in releasing property upon fixing and shape controllability upon production of the toner. The toner for developing electrostatic latent image has a number average molecular weight in a range of from 10,000 to 30,000 and a ratio of a Z average molecular weight and a weight average molecular weight in a range of from 3.0 to 6.0.
    Type: Grant
    Filed: April 16, 2003
    Date of Patent: May 3, 2005
    Assignee: Fuji Xoerox Co., Ltd.
    Inventors: Takao Ishiyama, Shuji Sato, Hiroshi Kamada, Masakazu Iijima
  • Patent number: 6887637
    Abstract: A toner for electrostatic image development, which comprises a binder resin, a colorant and a charge control resin, wherein the charge control resin is a copolymer composed a vinyl monomer unit and a quaternary ammonium salt group-containing (meth)acrylate monomer unit and has a glass transition temperature of 40 to 75° C., and a production process thereof.
    Type: Grant
    Filed: February 13, 2001
    Date of Patent: May 3, 2005
    Assignee: Zeon Corporation
    Inventor: Kazu Niwa
  • Patent number: 6875550
    Abstract: A non-magnetic single-component toner 8 of the present invention has toner mother particles 8a, and external additives 12 comprising: two hydrophobic silicas 13, 14 of which particle diameters are different from each other, i.e. a mean primary particle diameter of 7 nm to 12 nm and a mean primary particle diameter of 40 nm to 50 nm, and a hydrophobic rutile/anatase type titanium oxide 15 having a spindle shape of which major axial diameter is in a range from 0.02 nm to 0.10 nm and the ratio of the major axial diameter to the minor axial diameter is set to be 2 to 8, wherein the external additives 12 adhere to the toner mother particles 8a. By the hydrophobic silicas 13, 14 having work function smaller than the work function of the toner mother particles 8a, the negative charging property is imparted to the toner mother particles 8a and the fluidity is also insured.
    Type: Grant
    Filed: July 10, 2002
    Date of Patent: April 5, 2005
    Assignee: Seiko Epson Corporation
    Inventors: Nobuhiro Miyakawa, Takuya Kadota, Hidehiro Takano, Shinji Yasukawa, Masanao Kunugi
  • Patent number: 6858369
    Abstract: According to a toner and a manufacturing method of the present invention, the toner, which is composed of a binding resin component precipitated in particle shapes with a coloring agent component dispersed in the binding resin component, is produced by dissolving the binding resin component in a supercritical fluid (a SCF), blending the coloring agent component in the SCF, and lowering solubility of the binding resin component for precipitating the binding resin component in the particle shapes. Even when the coloring agent content is increased, by the SCF, the toner can maintain dispersibility of the coloring agent component in the binding resin component precipitated in the particle shapes, meanwhile coloring power is also maintained thereby. Therefore, the toner can promote miniaturization of an image forming apparatus using the toner.
    Type: Grant
    Filed: May 9, 2003
    Date of Patent: February 22, 2005
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Katsumi Adachi, Masamitsu Sakuma, Kiyoshi Toizumi, Taisuke Kamimura, Tadashi Iwamatsu, Kenji Mishima
  • Patent number: 6808855
    Abstract: A toner production process comprising the step of polymerizing a polymerizable monomer in the presence of (i) base particles containing at least a binder resin and (ii) a polymerization initiator. The polymerization initiator has in one molecule a hydrophilic moiety and a hydrophobic moiety and a reactive moiety between them, and the base particles are enlarged and/or surface-modified upon polymerization of the polymerizable monomer. Also disclosed is a toner having a circularity of from 0.92 to 1.0, which is produced by this process.
    Type: Grant
    Filed: May 23, 2002
    Date of Patent: October 26, 2004
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yasukazu Ayaki, Hitoshi Itabashi, Yayoi Tazawa
  • Patent number: 6806011
    Abstract: The present invention provides an electrophotographic dry toner comprising colored resin particles with releasing agent particles dispersed in a binder resin or an electrophotographic dry toner wherein a resin coating layer obtained by the fixation and fusion of encapsulating resin particles is provided on the surface of colored resin particles with releasing agent particles dispersed in a binder. The releasing agent particles dispersed in each colored resin particle have a particle diameter distribution such that the particle diameter of releasing agent particles dispersed in the vicinity of the surface of each colored resin particle is larger than the particle diameter of releasing agent particles at a central site of the colored resin particle. Alternatively, the colored resin particle is coated with the releasing coating layer with a releasing agent layer interposed between them.
    Type: Grant
    Filed: November 20, 2003
    Date of Patent: October 19, 2004
    Assignee: Seio Epson Corporation
    Inventors: Takashi Teshima, Masaki Kato, Takatomo Fukumoto
  • Publication number: 20040146795
    Abstract: A toner is used in an image forming process employing a toner recycling system and contains at least a modified polyester resin, a coloring agent, and a releasing agent. The toner has a volume-average particle diameter Dv, a number-average particle diameter Dn and a shape factor SF-1, wherein Dv is in a range from 4.0 &mgr;m to 6.0 &mgr;m, the ratio Dv/Dn of Dv to Dn is in a range from 1.00 to 1.30, and the shape factor SF-1 is in a range from 140 to 200.
    Type: Application
    Filed: January 20, 2004
    Publication date: July 29, 2004
    Inventors: Shigeru Emoto, Toshiki Nanya, Naohito Shimota, Maiko Kondo, Shinichiro Yagi, Hiroto Higuchi, Fumihiro Sasaki, Takahiro Honda, Junichi Awamura
  • Publication number: 20040146794
    Abstract: A toner is provided for the development of an electrostatic image which includes an agglomerate of particles obtained by agglomerating at least primary polymer particles and primary colorant particles, wherein the toner has a THF insoluble content of from 15% to 80% and the toner further includes a wax having a melting point of 30 to 100° C., and the method for producing the same.
    Type: Application
    Filed: December 2, 2003
    Publication date: July 29, 2004
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Kazuo Mitsuhashi, Osamu Ando, Noriaki Takahashi, Tomoko Ishikawa, Yuqing Xu
  • Publication number: 20040110078
    Abstract: The present invention provides an electrophotographic dry toner comprising colored resin particles with releasing agent particles dispersed in a binder resin or an electrophotographic dry toner wherein a resin coating layer obtained by the fixation and fusion of encapsulating resin particles is provided on the surface of colored resin particles with releasing agent particles dispersed in a binder. The releasing agent particles dispersed in each colored resin particle have a particle diameter distribution such that the particle diameter of releasing agent particles dispersed in the vicinity of the surface of each colored resin particle is larger than the particle diameter of releasing agent particles at a central site of the colored resin particle. Alternatively, the colored resin particle is coated with the releasing coating layer with a releasing agent layer interposed between them.
    Type: Application
    Filed: November 20, 2003
    Publication date: June 10, 2004
    Applicant: SEIKO EPSON CORPORATION
    Inventors: Takashi Teshima, Masaki Kato, Takatomo Fukumoto
  • Patent number: 6743559
    Abstract: Disclosed is a toner comprising particles of a polyester resin, an optional colorant, and polypyrrole, wherein said toner particles are prepared by an emulsion aggregation process. Another embodiment of the present invention is directed to a process which comprises (a) generating an electrostatic latent image on an imaging member, and (b) developing the latent image by contacting the imaging member with charged toner particles comprising a polyester resin, an optional colorant, and polypyrrole, wherein said toner particles are prepared by an emulsion aggregation process.
    Type: Grant
    Filed: January 23, 2003
    Date of Patent: June 1, 2004
    Assignee: Xerox Corporation
    Inventors: James R. Combes, Karen A. Moffat, Maria N. V. McDougall
  • Patent number: 6730450
    Abstract: Disclosed is a toner comprising particles of a polyester resin, an optional colorant, and poly(3,4-ethylenedioxythiophene), wherein said toner particles are prepared by an emulsion aggregation process. Another embodiment of the present invention is directed to a process which comprises (a) generating an electrostatic latent image on an imaging member, and (b) developing the latent image by contacting the imaging member with charged toner particles comprising a polyester resin, an optional colorant, and poly(3,4-ethylenedioxythiophene), wherein said toner particles are prepared by an emulsion aggregation process.
    Type: Grant
    Filed: November 28, 2000
    Date of Patent: May 4, 2004
    Assignee: Xerox Corporation
    Inventors: Karen A. Moffat, Rina Carlini, Maria N. V. McDougall, Dan A. Hays, Jack T. LeStrange
  • Patent number: 6720122
    Abstract: A toner for development of electrostatic images, comprising colored particles containing at least a binder resin, a colorant and a softening agent, wherein the softening agent is an organic compound having a molecular weight of at least 1,000, a solubility of at least 5 g in 100 g of styrene as measured at 25° C., and an acid value of at most 10 mg KOH/g. The toner is excellent in fixing ability, shelf stability and flowability and permits forming images having high image quality. A production process thereof is also provided.
    Type: Grant
    Filed: April 1, 2002
    Date of Patent: April 13, 2004
    Assignee: Zeon Corp.
    Inventor: Tokudai Ogawa
  • Publication number: 20040058267
    Abstract: A toner for developing an electrostatic latent image is provided that is excellent in releasing property upon fixing and shape controllability upon production of the toner. The toner for developing electrostatic latent image has a number average molecular weight in a range of from 10,000 to 30,000 and a ratio of a Z average molecular weight and a weight average molecular weight in a range of from 3.0 to 6.0.
    Type: Application
    Filed: April 16, 2003
    Publication date: March 25, 2004
    Applicant: Fuji Xerox Co., Ltd.
    Inventors: Takao Ishiyama, Shuji Sato, Hiroshi Kamada, Masakazu Iijima
  • Publication number: 20040048182
    Abstract: A multi-layered toner comprises a core and a covering layer. The binder resin in the core has an acid value differing from the acid value of the binder resin in the covering layer.
    Type: Application
    Filed: September 6, 2002
    Publication date: March 11, 2004
    Applicant: TOSHIBA TEC KABUSHIKI KAISHA
    Inventor: Takashi Urabe
  • Patent number: 6686112
    Abstract: The present invention provides an electrophotographic dry toner comprising colored resin particles with releasing agent particles dispersed in a binder resin or an electrophotographic dry toner wherein a resin coating layer obtained by the fixation and fusion of encapsulating resin particles is provided on the surface of colored resin particles with releasing agent particles dispersed in a binder. The releasing agent particles dispersed in each colored resin particle have a particle diameter distribution such that the particle diameter of releasing agent particles dispersed in the vicinity of the surface of each colored resin particle is larger than the particle diameter of releasing agent particles at a central site of the colored resin particle. Alternatively, the colored resin particle is coated with the releasing coating layer with a releasing agent layer interposed between them.
    Type: Grant
    Filed: November 13, 2001
    Date of Patent: February 3, 2004
    Assignee: Seiko Epson Corporation
    Inventors: Takashi Teshima, Masaki Kato, Takatomo Fukumoto
  • Patent number: 6686111
    Abstract: Disclosed is a toner comprising particles of a vinyl resin, an optional colorant, and poly(3,4-ethylenedioxythiophene), wherein said toner particles are prepared by an emulsion aggregation process. Another embodiment of the present invention is directed to a process which comprises (a) generating an electrostatic latent image on an imaging member, and (b) developing the latent image by contacting the imaging member with charged toner particles comprising a vinyl resin, an optional colorant, and poly(3,4-ethylenedioxythiophene), wherein said toner particles are prepared by an emulsion aggregation process.
    Type: Grant
    Filed: November 28, 2000
    Date of Patent: February 3, 2004
    Assignee: Xerox Corporation
    Inventors: Karen A. Moffat, Maria N. V. McDougall, Rina Carlini, Dan A. Hays, Jack T. LeStrange, Paul J. Gerroir
  • Patent number: 6677092
    Abstract: A magnetic toner for MICR printers is provided with a binder resin, magnetic powder, and metal oxide particles which are in the outer surface of each toner base particle made from the binder resin and the magnetic powder, the metal oxide particles having a volume resistivity of 1×105 to 1×1011 &OHgr;·cm. A developer containing this MICR toner makes it possible to provide superior image density and reading precision, even after 150,000 to 300,000 sheets of A-4 paper have been continuously printed.
    Type: Grant
    Filed: April 23, 2001
    Date of Patent: January 13, 2004
    Assignee: Kyocera Corporation
    Inventor: Takaaki Arai
  • Patent number: 6673501
    Abstract: Disclosed is a toner comprising particles of a polyester resin, an optional colorant, and polypyrrole, wherein said toner particles are prepared by an emulsion aggregation process. Another embodiment of the present invention is directed to a process which comprises (a) generating an electrostatic latent image on an imaging member, and (b) developing the latent image by contacting the imaging member with charged toner particles comprising a polyester resin, an optional colorant, and polypyrrole, wherein said toner particles are prepared by an emulsion aggregation process.
    Type: Grant
    Filed: November 28, 2000
    Date of Patent: January 6, 2004
    Assignee: Xerox Corporation
    Inventors: James R. Combes, Karen A. Moffat, Maria N. V. McDougall
  • Patent number: 6664018
    Abstract: A method of forming an aqueous dispersion of particles of zinc stearate includes the steps of forming a mixture of at least one surfactant and water, heating the mixture to a temperature of from about 40° C. to less than a melting temperature of zinc stearate, adding a metal-containing stearate to the mixture under agitation, adding to the mixture a solution of a zinc salt in water, whereby upon inclusion of both the metal-containing stearate and the zinc salt in the mixture, the zinc salt reacts with the metal-containing stearate to form the particles of zinc stearate, continuing the heating and agitation following completion of the latter of the adding of the solution of zinc salt or the adding of the metal-containing stearate to continue the reaction, and cooling to obtain the aqueous dispersion of particles of zinc stearate. The method forms a stable aqueous dispersion of nanometer sized zinc stearate particles particularly useful in coating toner particles.
    Type: Grant
    Filed: April 23, 2002
    Date of Patent: December 16, 2003
    Assignee: Xerox Corporation
    Inventors: Allan K. Chen, Tie Hwee Ng, Lu Jiang, Kimberly D. Nosella, Paul J. Gerroir, Michael Damato