By Polymerization Patents (Class 430/137.15)
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Patent number: 12209210Abstract: A method for producing a composite resin particle dispersion includes: performing polymerization A by polymerizing a styrene compound and a vinyl monomer other than the styrene compound to form a styrene-based resin; performing polymerization B by polymerizing a (meth)acrylic acid ester compound in the presence of the styrene-based resin to form intermediate resin particles containing the styrene-based resin and a (meth)acrylic acid ester-based resin; and performing polymerization C by polymerizing a styrene compound and a vinyl monomer other than the styrene compound in the presence of the intermediate resin particles to form composite resin particles. The mass ratio of the styrene-based resin to the (meth)acrylic acid ester-based resin in the composite resin particles is from 80:20 to 20:80. A difference between the lowest glass transition temperature and the highest glass transition temperature in the composite resin particles is 30° C. or more.Type: GrantFiled: August 31, 2023Date of Patent: January 28, 2025Assignee: FUJIFILM Business Innovation Corp.Inventors: Sumiaki Yamasaki, Takahiro Ishizuka, Kiyohiro Yamanaka, Yasunobu Kashima, Satoshi Inoue
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Patent number: 12195582Abstract: An electrically or thermally conductive polymer composition, includes: a polyester polymer having a backbone including at least 12 consecutive carbon atoms between ester linkages; and conductive particles dispersed in the polyester polymer. A component including an electrically or thermally conductive polymer composition is also disclosed. A method for self-regulating a temperature of a component is also disclosed.Type: GrantFiled: November 12, 2019Date of Patent: January 14, 2025Assignee: PPG Industries Ohio, Inc.Inventors: Jonathan G. Weis, Shawn R. DeBerry, W. David Polk, Paul F. Cheetham, Darin W. Laird, Kurt G. Olson, Thomas E. Decker
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Patent number: 10386739Abstract: The present invention is to provide a toner production method configured to prevent scale formation, be resistant to pipe clogging, and realize stable and efficient toner production, even in the case of long-term continuous production. Disclosed is a toner production method comprising: a dispersing step for obtaining a colorant dispersion by, in a stirring tank, (a) dispersing or dissolving a colorant and a charge control agent in a polymerizable monomer, or (b) dispersing or dissolving a binder resin, a colorant and a charge control agent in an organic solvent, and a droplets forming step by suspending the colorant dispersion in an aqueous dispersion medium, wherein, in the dispersing step, the binder resin, colorant or charge control agent is added to the polymerizable monomer or organic solvent in the stirring tank, from a hopper, through a pipe heated by a heating device.Type: GrantFiled: April 4, 2018Date of Patent: August 20, 2019Assignee: ZEON CORPORATIONInventors: Ryo Tsumura, Junichi Takashima, Fuminari Oyama
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Patent number: 9880478Abstract: Provided is a method of producing a toner including a toner particle, the method including: a granulation step of mixing a polymerizable monomer composition containing a polymerizable monomer and an aqueous medium to form a suspension of particles of the polymerizable monomer composition; and a polymerization step of polymerizing the polymerizable monomer in each of the particles of the polymerizable monomer composition in the presence of a metal phosphate containing aluminum as a metal element to provide the toner particle, the content ratio of aluminum in the metal phosphate containing aluminum being 1.0 mol % or more and 95.0 mol % or less with respect to all metal elements, the metal phosphate containing aluminum being obtained by adding an aluminum compound to the aqueous medium and/or the suspension.Type: GrantFiled: December 29, 2016Date of Patent: January 30, 2018Assignee: CANON KABUSHIKI KAISHAInventors: Tsutomu Shimano, Kunihiko Nakamura, Kenta Kamikura, Yuichi Yajima, Kenji Ookubo, Dai Nozaki, Tohru Hiramatsu
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Patent number: 9683064Abstract: A method of making a resin, includes forming an aqueous monomer droplet suspension, and colloidally stabilizing the suspension with a solid particulate material as the first stabilizer and poly(2-ethyl-2-oxazoline) as a second stabilizer. The method further includes heating the colloidally stabilized suspension to polymerize the monomer droplets, thereby forming the resin.Type: GrantFiled: September 30, 2015Date of Patent: June 20, 2017Assignee: EASTMAN KODAK COMPANYInventors: Peter David Rollinson, Peter Steven Alexandrovich, John Leonard Muehlbauer
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Patent number: 9557666Abstract: A toner prepared by a method comprising granulating while polymerizing a ring-opening polymerizable monomer with a catalyst under the presence of a surfactant and a colorant in a compressible fluid.Type: GrantFiled: July 10, 2014Date of Patent: January 31, 2017Assignee: Ricoh Company, Ltd.Inventors: Yoshitaka Yamauchi, Chiaki Tanaka, Taichi Nemoto
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Patent number: 9454093Abstract: Disclosed is a method for producing a polymerized toner, wherein the method comprises: a suspension step of obtaining a suspension in which droplets of a first-stage polymerizable monomer composition containing at least a first-stage polymerizable monomer and a colorant are dispersed, by suspending the first-stage polymerizable monomer composition in an aqueous dispersion medium containing a dispersion stabilizer; a first-stage polymerization step of carrying out suspension polymerization by using the suspension, in the presence of a polymerization initiator; and a second-stage polymerization step of carrying out suspension polymerization by further adding a second-stage polymerizable monomer satisfying the following formula (1), when a polymerization conversion rate in the first-stage polymerization step becomes 20 to 80%: Tg1>Tg2.Type: GrantFiled: January 24, 2014Date of Patent: September 27, 2016Assignee: ZEON CORPORATIONInventors: Hisashi Kurokawa, Akihide Hagino, Hiroyuki Taguchi
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Patent number: 9223236Abstract: The present disclosure provides processes for making inorganic or organic colorant dispersions using an acoustic mixer, where such dispersion may be used to make toner. Such processes apply low frequency, high intensity acoustic energy and a consistent shear field throughout an entire mixing vessel and provide uniform dispersion of colorants within minutes.Type: GrantFiled: March 1, 2013Date of Patent: December 29, 2015Assignee: Xerox CorporationInventors: Shigang Qiu, Santiago Faucher, Kimberly D Nosella, David R Kurceba, Yulin Wang, Karina Lopez
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Patent number: 9217941Abstract: According to one embodiment, a method of manufacturing an erasable toner includes washing toner particles including therein a coloring material that is erasable by heating and a binder resin to obtain a toner cake having the amount of water of 20% by weight to 60% by weight, and drying the toner cake at 40° C. or more and at a temperature which is lower than the complete color erasing temperature of the toner particles by 30° C. or more.Type: GrantFiled: January 10, 2014Date of Patent: December 22, 2015Assignee: Toshiba Tec Kabushiki KaishaInventors: Tsuyoshi Itou, Kazuhisa Takeda, Yasuhito Noda, Takayasu Aoki, Masahiro Ikuta, Takafumi Hara, Motonari Udo
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Patent number: 9213248Abstract: A process includes forming an emulsion comprising a monomer and a colorant, the colorant further including an anionic functional group and a lipophilic counter ion, and polymerizing the monomer to form a latex, the latex includes polymer nanoparticles having the colorant dispersed therein.Type: GrantFiled: July 23, 2013Date of Patent: December 15, 2015Assignee: XEROX CORPORATIONInventors: Valerie M. Farrugia, Maria Birau
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Patent number: 9188896Abstract: The present invention provides an electrostatic ink composition comprising a carrier liquid, a resin, a pigment and a conductive polymer. Method for producing the electrostatic ink composition and methods for printing the composition are also disclosed.Type: GrantFiled: September 30, 2011Date of Patent: November 17, 2015Assignee: Hewlett-Packard Indigo B.V.Inventors: Gil Bar-Haim, Anatoly Sobolevsky, Yaron Grinwald
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Patent number: 9023575Abstract: A toner is provided that can maintain high transferability even in long-term image output, can maintain high chargeability even in a high temperature and high humidity environment, and rarely causes fogging due to charging failure. The toner contains toner particles produced by a suspension polymerization method or a dissolution suspension method. The volume-average particle diameter (Dv) of silica particles is 50 nm or more and 800 nm or less. The mass loss rate due to heating of the silica particles from 105° C. to 200° C. is 0.60% or less. The hydrophobicity of the silica particles is 5% or more and less than 40%.Type: GrantFiled: September 10, 2013Date of Patent: May 5, 2015Assignee: Canon Kabushiki KaishaInventors: Taiji Katsura, Naotaka Ikeda, Emi Watanabe, Yuhei Terui
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Publication number: 20150118614Abstract: The present invention is to provide a toner which is able to prevent an odor generated from the toner upon fixing and which has excellent fixability. The present invention is also to provide a method for producing the toner. Disclosed is a method for producing a toner for developing electrostatic images, wherein a content of diethylbenzene in colored resin particles after a polymerization step and before a stripping step, is set to 100 to 400 ppm by the polymerization step; and wherein the diethylbenzene content in the colored resin particles after the stripping step is set to 30 to 250 ppm by the stripping step, and a content of the monovinyl monomer in the colored resin particles after the stripping step is set to 30 ppm or less by the stripping step.Type: ApplicationFiled: February 7, 2013Publication date: April 30, 2015Applicant: ZEON CORPORATIONInventor: Hiromichi Jin
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Publication number: 20150099222Abstract: The present invention provides a toner having a toner particle that contains a binder resin, wherein the binder resin contains a vinylic resin and a polyester resin, the vinylic resin contains an organic silicon polymer having a specific structure, the organic silicon polymer is contained in the surface layer of the toner particle, the proportion of a silicon atom in the organic silicon polymer having a specific structure is at least 5%, the polyester resin is a specific polymer, and the toner particle contains a specific amount of the polyester resin.Type: ApplicationFiled: October 8, 2014Publication date: April 9, 2015Inventors: Yuhei Terui, Katsuyuki Nonaka, Koji Abe, Harumi Takada
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Publication number: 20150099224Abstract: The present invention is a toner that has toner particles that have a surface layer that contains an organosilicon polymer, wherein this organosilicon polymer has a specific substructure and the ratio [ST3], in a 29Si-NMR measurement of a tetrahydrofuran-insoluble matter of the toner particles, of the peak area for this substructure to the total peak area for the organosilicon polymer satisfies the relationship ST3?0.40.Type: ApplicationFiled: October 8, 2014Publication date: April 9, 2015Inventors: Koji Abe, Yuhei Terui, Taiji Katsura, Katsuyuki Nonaka
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Publication number: 20150099227Abstract: The present invention provides a crystalline polyester resin for toner that has, when used as a resin for toner, a sharp melt property, excellent fixing performance and blocking property and a preferable charging performance. Provided is a crystalline polyester resin for toner, which is obtained by condensation polymerization of a dicarboxylic acid component containing at least one compound selected from the group consisting of terephthalic acid, 2,6-naphthalenedicarboxylic acid and derivatives thereof, and a diol component containing at least one compound selected from the group consisting of 2-methyl-1,3-propanediol, 2,2-dimethyl-1,3-propanediol and derivatives thereof, the crystalline polyester resin having a weight-average molecular weight of not less than 5000 and not more than 50000.Type: ApplicationFiled: December 15, 2014Publication date: April 9, 2015Inventors: Hayato Ida, Takashi Hirasa, Junichi Tamura, Yuya Chimoto, Takaho Shibata, Daisuke Yamashita
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Patent number: 9000101Abstract: The disclosure describes a neat, one-pot scheme for reacting a hydroxyl propagating end of a polymer with a cyclic acid anhydride to form a free acid terminus.Type: GrantFiled: July 10, 2013Date of Patent: April 7, 2015Assignee: Xerox CorporationInventors: Andrew J. Myles, Jordan H. Wosnick, Karen A. Moffat, Valerie M. Farrugia
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Patent number: 8975000Abstract: The method of producing polymerized toner, the method including: dispersing a polymerizable monomer composition containing at least a polymerizable monomer and a colorant in an aqueous medium; and polymerizing the polymerizable monomer in the aqueous medium with a polymerization initiator to produce toner particles, and is characterized in that a polymerization initiator which has a specific structure and the hydrogen bond dissociation energies of which satisfy specific relationships is used as the polymerization initiator.Type: GrantFiled: July 24, 2008Date of Patent: March 10, 2015Assignee: Canon Kabushiki KaishaInventors: Atsushi Tani, Norikazu Fujimoto, Hitoshi Itabashi
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Patent number: 8962232Abstract: A production process of a polymerized toner composed of polymer particles, including a step of polymerizing a polymerizable monomer composition containing a colorant and a polymerizable monomer in the presence of a polymerization initiator in an aqueous dispersion medium, wherein, in a stripping treatment step, the dispersion containing the polymer particles is introduced into an evaporator to conduct the stripping treatment by a method, in which a gas is blown into the dispersion within the evaporator to discharge volatile organic components including an unreacted polymerizable monomer out of the evaporator concomitantly with the gas, and both inert gas and saturated steam are used as the gas blown into the dispersion.Type: GrantFiled: November 11, 2008Date of Patent: February 24, 2015Assignee: Zeon CorporationInventor: Keita Sensui
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Patent number: 8951708Abstract: The present embodiments relate to methods of making a toner composition. More specifically, the present embodiments relate to methods of including a functional material into a toner composition.Type: GrantFiled: June 5, 2013Date of Patent: February 10, 2015Assignee: Xerox CorporationInventors: Yu Liu, Cuong Vong, Sarah Vella, Gregory McGuire, Richard Klenkler, Nan-xing Hu, Paul Gerroir
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Publication number: 20150037725Abstract: A yellow toner is provided which is superior in dispersibility of C. I. pigment yellow 185, has a high color development property, and is superior in light resistance. The yellow toner has toner particles containing at least a binder resin, a wax, and a colorant, wherein the yellow toner contains C.I.Type: ApplicationFiled: March 6, 2013Publication date: February 5, 2015Inventors: Shosei Mori, Takeshi Sekiguchi, Taichi Shintou, Yuko Katsumoto, Takayuki Ujifusa, Takeshi Miyazaki
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Publication number: 20150037730Abstract: A liquid developer contains an electrically insulating liquid carrier and toner particles dispersed in the liquid carrier. Each toner particle includes a core and a shell layer that is formed on a surface of the core and contains a thermosetting resin.Type: ApplicationFiled: July 25, 2014Publication date: February 5, 2015Applicant: KYOCERA DOCUMENT SOLUTIONS INC.Inventors: Hidetoshi MIYAMOTO, Katsuki OSANISHI, Yoshio OZAWA
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Publication number: 20150030977Abstract: A process includes forming an emulsion comprising a monomer and a colorant, the colorant further including an anionic functional group and a lipophilic counter ion, and polymerizing the monomer to form a latex, the latex includes polymer nanoparticles having the colorant dispersed therein.Type: ApplicationFiled: July 23, 2013Publication date: January 29, 2015Applicant: Xerox CorporationInventors: Valerie M. Farrugia, Maria Birau
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Publication number: 20150024324Abstract: To provide an emulsion polymerized agglomerated toner for electrostatic charge image which is excellent in the fixing property even at a high temperature without deteriorating other properties and which does not emit an odor offensive to people, and a process for its production. An emulsion polymerized agglomerated toner characterized in that the odor index of aliphatic aldehydes measured by gas chromatography is at most 300, and an emulsion polymerized agglomerated toner which is an emulsion polymerized agglomerated toner obtainable via a polymerization step, a flocculation step and an aging step, characterized in that an emulsion polymerized latex before the flocculation step is a latex having a peroxide value of at most 30.Type: ApplicationFiled: October 7, 2014Publication date: January 22, 2015Applicant: MITSUBISHI CHEMICAL CORPORATIONInventors: Masaya OTA, Tomohiko Tokunaga, Kazuo Mitsuhashi
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Patent number: 8927185Abstract: The present invention provides a toner having superior color development property and a method of producing a toner having favorable particle size distribution and color development property, in which the toner containing a binder resin and a colorant that contains a phthalocyanine pigment represented by general formula (1), and the method for producing the toner.Type: GrantFiled: August 20, 2013Date of Patent: January 6, 2015Assignee: Canon Kabushiki KaishaInventors: Ryuji Higashi, Akiko Kitao, Taichi Shintou, Takeshi Miyazaki
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Publication number: 20140377698Abstract: This disclosure relates to a polymerized toner prepared by suspension polymerization. Particularly, this disclosure relates to a polymerized toner that further comprises a specific functional macro monomer, a polymer thereof, or a mixture thereof, in addition to a binder resin, and a pigment, a pigment stabilizer, a charge control agent and wax, which are dispersed in the binder resin, and thus can be fixed at low temperature in a development process, and exhibit high glossiness and excellent transfer efficiency.Type: ApplicationFiled: December 4, 2012Publication date: December 25, 2014Applicant: LG CHEM, LTD.Inventors: Wook Jang, Chang-Soon Lee, Woo-Cheul Jung, Jung Woo Kim
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Publication number: 20140363765Abstract: A method for producing a toner for electrostatic image development, including the steps of (1) polycondensing an alcohol component, a carboxylic acid component, and polyethylene terephthalate to provide an amorphous polyester; and (2) subjecting the amorphous polyester obtained in the step (1) and components containing a crystalline polyester in an amount of from 0.3 to 2.5 times the mass of the components derived from the polyethylene terephthalate in the amorphous polyester to a process for producing a toner. The toner for electrostatic image development obtained by the method of the present invention is suitably used in development or the like of latent images formed in, for example, an electrophotographic method, an electrostatic recording method, an electrostatic printing method, or the like.Type: ApplicationFiled: April 30, 2014Publication date: December 11, 2014Applicant: Kao CorporationInventors: Norihiro FUKURI, Eiji SHIRAI
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Patent number: 8900787Abstract: A process includes forming particles in a latex by emulsion polymerization of a mixture including one or more monomers in an emulsion, and about 4 percent or less by weight of the mixture of a non-surfactant-based charge control agent, the non-surfactant-based charge control agent is distributed within a matrix of the particles, and forming toner particles from the particles in the latex, the toner particles supporting a sufficient triboelectric charge for use under A-zone environmental conditions in a single-component development system.Type: GrantFiled: May 16, 2013Date of Patent: December 2, 2014Assignee: Xerox CorporationInventors: Robert D. Bayley, Grazyna E. Kmiecik-Lawrynowicz, Maura A. Sweeney, Susan J. LaFica
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Publication number: 20140342286Abstract: A toner prepared by a method comprising granulating while polymerizing a ring-opening polymerizable monomer with a catalyst under the presence of a surfactant and a colorant in a compressible fluid.Type: ApplicationFiled: July 10, 2014Publication date: November 20, 2014Inventors: Yoshitaka YAMAUCHI, Chiaki TANAKA, Taichi NEMOTO
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Publication number: 20140308610Abstract: The present invention provides a toner that contains an azo pigment well-dispersed in a binder resin and has a satisfactory color tone. The toner contains toner particles each containing a binder resin and a colorant. Each of the toner particles contains a compound having a polyester moiety and a bisazo structure moiety. The colorant is the azo pigment.Type: ApplicationFiled: November 8, 2012Publication date: October 16, 2014Applicant: CANON KABUSHIKI KAISHAInventors: Yuki Hasegawa, Yasuaki Murai, Masatake Tanaka, Takayuki Toyoda, Masashi Kawamura, Waka Hasegawa, Masashi Hirose
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Publication number: 20140302437Abstract: A method for producing toner particles that contain a binder resin having a styrene-acrylic resin as a main component, a colorant, and a block polymer that has polyester segments and vinyl polymer segments, has a step of producing resin particles in accordance with a suspension polymerization method or a dissolution suspension method, and thereafter, holding the temperature of the aqueous medium in which the resin particles are dispersed, for 60 minutes or more, between a glass transition point TgA (° C.) of the resin particles and an onset temperature TmA (° C.) of an endothermic peak derived from the block polymer in the resin particles, in such a manner that a temperature fluctuation rate not greater than 0.35° C./minute, and a temperature fluctuation range is not greater than 20° C.Type: ApplicationFiled: April 1, 2014Publication date: October 9, 2014Applicant: CANON KABUSHIKI KAISHAInventors: Tsutomu Shimano, Masatake Tanaka, Naoya Isono, Shintaro Noji, Yu Yoshida
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Patent number: 8841057Abstract: A resin binder for use in a toner for electrophotography, containing a polycondensation resin obtainable by polycondensing an alcohol component containing an aliphatic polyhydric alcohol having two or more secondary carbon atoms with a hydroxyl group bound thereto (an alcohol A), and a carboxylic acid component, wherein the alcohol A is contained in an amount of from 10 to 100% by mol, of the alcohol component; and a toner for electrophotography containing the resin binder. The toner for electrophotography of the present invention is suitably used in developing latent images formed in electrophotography, electrostatic recording method, electrostatic printing method or the like.Type: GrantFiled: October 29, 2008Date of Patent: September 23, 2014Assignee: Kao CorporationInventors: Katsutoshi Aoki, Norihiro Fukuri, Takashi Kubo, Yoshitomo Kimura, Yasunori Inagaki, Yoshihiro Ueno, Hidenori Tachi
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Patent number: 8835589Abstract: An improved polycondensation method for bio-based polyesters synthesized from pre-formed macromers and the corresponding compositions, which are useful for producing binder polymers for imaging applications such as emulsion-aggregation (EA) toner.Type: GrantFiled: January 26, 2012Date of Patent: September 16, 2014Assignee: Xerox CorporationInventors: Valerie M. Farrugia, Guerino G. Sacripante, Ke Zhou
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Patent number: 8808958Abstract: The present invention relates to a process for preparing a polymerized toner, and in particular to a process for preparing a polymerized toner and a polymerized toner prepared therefrom, wherein a certain block copolymer and copper phthalocyanine are used within a predetermined range of the amounts for a carbon black dispersant during a suspension polymerization, thereby making it possible to realize a narrow particle sizes distribution, high transcription efficiency, and an enhanced image concentration.Type: GrantFiled: September 23, 2011Date of Patent: August 19, 2014Assignee: LG Chem, Ltd.Inventors: Wook Jang, Chang-Soon Lee, Dong-Jin Park, Jung-Woo Kim
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Patent number: 8802342Abstract: The present invention relates to a crystalline resin for toners which includes a composite resin including a polycondensation-based resin component obtained by polycondensing an alcohol component containing an aliphatic diol having 2 to 10 carbon atoms with a carboxylic acid component containing an aromatic dicarboxylic acid, and a styrene-based resin component; a resin binder containing the crystalline resin and a non-crystalline resin; and a toner for electrophotography which contains the resin binder. According to the present invention, there are provided a crystalline resin for toners which is capable of producing a toner that is excellent in not only low-temperature fixing ability but also gloss of images and anti-filming property, a resin binder, and a toner for electrophotography.Type: GrantFiled: December 9, 2009Date of Patent: August 12, 2014Assignee: Kao CorporationInventors: Eiji Shirai, Tetsuya Ueno
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Patent number: 8765349Abstract: A method of manufacturing toner is provided. In the method, toner constituents are dissolved or dispersed in an organic solvent to prepare a toner constituents liquid. The toner constituents liquid is degassed so that the toner constituents liquid includes dissolved oxygen in an amount of 3 mg/L or less. The toner constituents liquid is vibrated in a chamber having at least one nozzle to form a liquid column resonance standing wave in the toner constituents liquid. The toner constituents liquid is discharged from the nozzle disposed within an area including an antinode of the liquid column resonance standing wave to form the toner constituents liquid into liquid droplets. The liquid droplets are dried to solidify the liquid droplets into solid particles.Type: GrantFiled: July 25, 2012Date of Patent: July 1, 2014Assignee: Ricoh Company, Ltd.Inventors: Yoshihiro Norikane, Andrew Mwaniki Mulwa, Kiyotada Katoh, Yasutada Shitara
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Publication number: 20140162182Abstract: An object of the present invention is to provide a magenta toner having high lightness and saturation and having spectral reflection properties having a wider color range. A magenta toner including magenta toner particles each including a binder resin and a colorant, wherein the colorant includes a compound represented by a formula (1): (wherein R1 and R2 represent an alkyl group or an alkoxyalkyl group, and at least one of R1 and R2 has not less than 7 carbon atoms.Type: ApplicationFiled: July 24, 2012Publication date: June 12, 2014Applicant: CANON KABUSHIKI KAISHAInventors: Masao Nakano, Taichi Shintou, Yutaka Tani, Takayuki Ujifusa, Kaoru Takahashi, Satoshi Saito, Takeshi Miyazaki, Masashi Hirose
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Patent number: 8741531Abstract: A method of manufacturing toner includes forming liquid droplets. The forming liquid droplets includes vibrating a toner constituents liquid in a liquid column resonance liquid chamber having a plurality of nozzles to form a liquid column resonance pressure standing wave therein, and discharging the toner constituents liquid from the nozzles. The method further includes solidifying the liquid droplets. The toner constituents liquid includes an organic solvent and toner constituents dissolved or dispersed in the organic solvent. The toner constituents include a resin, a colorant, and a release agent. The nozzles are disposed within an area including an antinode of the liquid column resonance pressure standing wave. One of the nozzles disposed closer to a node of the liquid column resonance pressure standing wave has a smaller outlet diameter than that disposed farther from the node. The toner constituents liquid is applied with a uniform pressure at a vicinity of each nozzle.Type: GrantFiled: April 12, 2012Date of Patent: June 3, 2014Assignee: Ricoh Company, Ltd.Inventors: Yoshihiro Norikane, Masaru Ohgaki
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Patent number: 8741518Abstract: A toner includes toner particles each containing a binder resin, a colorant, and a carboxy-containing styrene-based resin, in which the toner particles are produced in an aqueous medium, each of the toner particles has a styrene-acrylic-based resin component content of 50.0% by mass or more, cyclohexane-insoluble matter A obtained by subjecting the toner to Soxhlet extraction with cyclohexane for 4 hours is 70.0% by mass or more, and cyclohexane-insoluble matter B obtained by subjecting the toner to Soxhlet extraction with cyclohexane for 24 hours is 40.0% by mass or less, and wherein when the z-average molecular weight and the weight-average molecular weight of tetrahydrofuran-soluble matter of the carboxy-containing styrene-based resin determined by gel permeation chromatography measurement are represented by Mz and Mw, respectively, Mz and Mw satisfy the following expressions: 10,000?Mw?30,000, and 1.62?Mz/Mw?5.00.Type: GrantFiled: April 12, 2011Date of Patent: June 3, 2014Assignee: Canon Kabushiki KaishaInventors: Hideki Kaneko, Shinya Yachi, Kenichi Nakayama, Takeshi Kaburagi, Shiro Kuroki
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Publication number: 20140141366Abstract: In a toner including toner particles obtained by performing suspension polymerization using a monomer composition containing a polymerizable monomer and a polar resin and in a method for manufacturing the above toner, the polar resin satisfies the following conditions (1) to (4). (1) The polar resin is a styrene-based resin. (2) A main peak molecular weight Mp is 5,000 to 100,000. (3) When the acid value of a low molecular weight component is represented by A and the acid value of a high molecular weight component is represented by B, 0.80?A/B?1.20 is satisfied. (4) The acid value is 5.0 to 40.0 mgKOH/g.Type: ApplicationFiled: July 10, 2012Publication date: May 22, 2014Applicant: CANON KABUSHIKI KAISHAInventors: Yasushi Katsuta, Shinya Yachi, Takeshi Shimura, Nobuhisa Abe, Kenta Kamikura
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Patent number: 8728702Abstract: A polyester resin toner binder which gives a toner with good anti-blocking property at high temperature and high humidity and good low-temperature fixing ability. The present invention is directed to a toner binder for developing electrostatic charge images, which binder comprises a condensation-polymerization polyester resin, the polyester resin being a product formed in the presence of a catalyst (a) represented by the following general formula (I): Ti(—X)m(—OR)n??(I) wherein R, X, m and n are as defined herein.Type: GrantFiled: May 24, 2012Date of Patent: May 20, 2014Assignee: Sanyo Chemical Industries, Ltd.Inventors: Takashi Ono, Yoko Sakurai
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Patent number: 8728703Abstract: An electrophotographic toner obtained from a dispersion or emulsion liquid of an oil phase containing a toner material in an aqueous medium, the toner including: a binder resin, wherein the toner material includes: (A) an epoxy resin prepolymer; (B) an adduct of a dihydric phenol with a polyalkylene oxide; (C) a phenolic compound, or an alcohol compound, or both thereof; and (D) a carboxylic acid compound, and wherein the binder resin includes a resin obtained by allowing the (A), the (B), the (C) and the (D) to react with each other.Type: GrantFiled: July 2, 2012Date of Patent: May 20, 2014Assignee: Ricoh Company, Ltd.Inventors: Hiroshi Yamashita, Satoyuki Sekiguchi, Daisuke Asahina, Tsuyoshi Sugimoto, Masaki Watanabe, Rintaro Takahashi
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Publication number: 20140134531Abstract: A yellow toner is provided which is much more improved in color development and chroma, and much more improved in light resistance. The yellow toner contains, at least, a binder resin, a wax, and a coloring agent. The coloring agent is a compound represented by the following general formula (1).Type: ApplicationFiled: January 23, 2014Publication date: May 15, 2014Applicant: CANON KABUSHIKI KAISHAInventors: Shosei Mori, Takeshi Sekiguchi, Taichi Shintou, Takeshi Miyazaki
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Patent number: 8715897Abstract: The present disclosure provides polyesters suitable for use in forming toners. In embodiments, a polyester may be subjected to phase inversion emulsification, in which charge control agents are added so that the polyester emulsion includes charge control agents therein. The resulting polyester emulsion with charge control agents may then be utilized to form toner particles.Type: GrantFiled: November 16, 2009Date of Patent: May 6, 2014Assignee: Xerox CorporationInventors: Robert D. Bayley, Yuhua Tong, Timothy L. Lincoln, Grazyna Kmiecik-Lawrynowicz, Maura A. Sweeney
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Publication number: 20140113229Abstract: An object of the present invention is to provide a magenta toner having high dispersibility of a colorant and good spectral characteristics. A magenta toner includes a magenta toner particle including at least a binder resin, a compound represented by the formula (1), and a colorant, wherein the colorant includes a pigment having a quinacridone skeleton: (wherein R1 and R2 each independently represent a hydrogen atom, an alkyl group, an aryl group, or an aralkyl group.Type: ApplicationFiled: July 24, 2012Publication date: April 24, 2014Applicant: CANON KABUSHIKI KAISHAInventors: Yutaka Tani, Masao Nakano, Takayuki Ujifusa, Taichi Shintou, Kaoru Takahashi, Satoshi Saito, Takayuki Toyoda, Takeshi Miyazaki, Masashi Hirose
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Patent number: 8703379Abstract: Methods for making toner particles comprising a polyester-wax resin, wherein the polyester-wax resin includes a bio-based oil that is chemically incorporated into the main chain of the polyester resin. The toner particles may be formed using emulsion aggregation methods. A toner formed from the toner particles may be used in low-oil or oil-less fusing systems.Type: GrantFiled: July 27, 2012Date of Patent: April 22, 2014Assignee: Xerox CorporationInventor: Valerie M. Farrugia
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Patent number: 8685613Abstract: A method of producing an electrostatic latent image developing toner that includes the steps of producing a resin particle dispersion by polymerizing, in a water-based solvent, a polymerizable monomer that includes a polymerizable monomer having a vinyl-based double bond, and washing the resin particle dispersion through contact with an organic solvent, wherein the washed resin particle dispersion, a colorant particle dispersion produced by dispersing a colorant, and a release agent particle dispersion produced by dispersing a release agent are mixed together, and following formation of aggregate particles by aggregation of the resin particles, the colorant particles and the release agent particles, heating is conducted to fuse the aggregate particles and produce the electrostatic latent image developing toner.Type: GrantFiled: June 24, 2013Date of Patent: April 1, 2014Assignee: Fuji Xerox Co., Ltd.Inventor: Masaaki Suwabe
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Publication number: 20140080048Abstract: A toner is provided that can maintain high transferability even in long-term image output, can maintain high chargeability even in a high temperature and high humidity environment, and rarely causes fogging due to charging failure. The toner contains toner particles produced by a suspension polymerization method or a dissolution suspension method. The volume-average particle diameter (Dv) of silica particles is 50 nm or more and 800 nm or less. The mass loss rate due to heating of the silica particles from 105° C. to 200° C. is 0.60% or less. The hydrophobicity of the silica particles is 5% or more and less than 40%.Type: ApplicationFiled: September 10, 2013Publication date: March 20, 2014Inventors: Taiji Katsura, Naotaka Ikeda, Emi Watanabe, Yuhei Terui
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Publication number: 20140072912Abstract: Processes for preparing polyester resins as toner production components. The processes include reacting an organic diol and a cyclic alkylene carbonate to produce carbon dioxide (CO2) and a polyalkoxy diol. The carbon dioxide is reacted with an alkylene glycol or alkylene oxide to produce additional cyclic alkylene carbonate having the same chemical structure as the cyclic alkylene carbonate used to produce the polyalkoxy diol. The additional cyclic alkylene carbonate is added with the cyclic alkylene carbonate used to produce the polyalkoxy diol. The polyalkoxy diol can be reacted with an organic diacid or diester in preparing a polyester resin. To prepare a toner, the polyester resin can be contacted with at least one toner production component.Type: ApplicationFiled: September 12, 2012Publication date: March 13, 2014Applicant: XEROX CORPORATIONInventor: Guerino G. Sacripante
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Patent number: 8669035Abstract: A method for producing toner according to one example embodiment includes combining and agglomerating a first polymer emulsion with a colorant dispersion and a release agent dispersion to form toner cores. A borax coupling agent is added to the toner cores. A second polymer emulsion is combined and agglomerated with the toner cores having the borax coupling agent to form toner shells around the toner cores. The aggregated toner cores and toner shells are fused to form toner particles.Type: GrantFiled: December 29, 2011Date of Patent: March 11, 2014Assignee: Lexmark International, Inc.Inventors: Jing X. Sun, Kofi Opare Diggs