By Polymerization Patents (Class 430/137.15)
  • Patent number: 7282313
    Abstract: Disclosed is a production method of an electrophotographic toner, which comprises toner particles comprising a resin and a colorant. The method comprises a step of forming toner particles in an aqueous medium, and processing an aqueous medium containing the toner particles or a component of the toner particles by gas bubbles.
    Type: Grant
    Filed: August 23, 2004
    Date of Patent: October 16, 2007
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Akira Ohira, Junji Ujihara, Shoichiro Ishibashi, Kentarou Yamawaki
  • Patent number: 7258959
    Abstract: The object of the present invention is to provide a developer having a sharp charge amount distribution and bringing out high-quality image without substantially smearing a charging unit, developing units, a photoconductor, and an intermediate transferring member by the developer, namely, a developer capable of providing an appropriate image density and exhibiting extremely little background smear even when used over a long period of time and repeatedly used for a number of sheets of paper as well as to provide an image forming apparatus for electrophotography using the developer.
    Type: Grant
    Filed: September 26, 2005
    Date of Patent: August 21, 2007
    Assignee: Ricoh Company, Ltd.
    Inventors: Shinya Nakayama, Satoshi Mochizuki, Yasuaki Iwamoto, Yasuo Asahina, Kazuhiko Umemura, Hideki Sugiura, Hisashi Nakajima, Tomoyuki Ichikawa, Tomoko Utsumi, Koichi Sakata, Akihiro Kotsugai, Osamu Uchinokura, Masayuki Ishii
  • Patent number: 7252920
    Abstract: A method for manufacturing a polymerized toner comprising a process for forming fine droplets of a polymerizable monomer composition in an aqueous dispersion medium, and a process for polymerizing the polymerizable monomer composition after the process for forming fine droplets; wherein the process for forming fine droplets has the steps of: preparing an agitating apparatus having an agitator equipped with an agitating blade or rotor and a dispersion supply tank; providing a polymerizable monomer composition and an aqueous dispersion medium into the dispersion supply tank; then, mixing the polymerizable monomer composition and the aqueous dispersion medium by the agitator to obtain a dispersion of fine droplets; and the relationship between the peripheral velocity of the agitating blade or rotor of the agitator and the number of circulations of the dispersion is controlled.
    Type: Grant
    Filed: March 19, 2004
    Date of Patent: August 7, 2007
    Assignee: Zeon Corporation
    Inventors: Hisashi Kurokawa, Makoto Watanabe
  • Patent number: 7252917
    Abstract: The toner having a significantly improved dispersibility of a colorant in toner particles is provided. The present invention provides a dry toner comprising: (i) a binder resin; (ii) a colorant; (iii) at least one of metallophthalocyanine and a metallophthalocyanine derivative having a central metal selected from the group consisting of Cr, Fe, C o, Ni, Zn, Mn, Mg, and Al; and (iv) a polymer containing 0.5 to 20% by mass of a base unit derived from a specific polymerizable monomer having an amide group.
    Type: Grant
    Filed: March 10, 2004
    Date of Patent: August 7, 2007
    Assignee: Canon Kabushiki Kaisha
    Inventors: Manabu Ohno, Motoya Fukushima, Hitoshi Itabashi, Yasushi Katsuta, Emi Tosaka, Norikazu Fujimoto
  • Publication number: 20070178401
    Abstract: The present invention provides a method of producing a polymerized toner which is capable of dispersing a colorant in a polymerizable monomer finely and uniformly and is excellent in production efficiency, wherein a step of preparing a polymerizable monomer composition containing the polymerizable monomer and the colorant includes a dispersing process in which a polymerizable monomer mixture containing the polymerizable monomer and the colorant is supplied to a media type dispersing machine equipped with a media particle and a screen for media separation and the colorant is dispersed in the polymerizable monomer mixture to obtain a polymerizable monomer dispersion, wherein a media diameter of the media particle and an aperture ratio of the screen for media separation satisfy the following formulas 1 and 2: Formula ? ? 1 ? : 0.01 ? ? mm ? ( media ? ? diameter ) ? 0.
    Type: Application
    Filed: January 30, 2007
    Publication date: August 2, 2007
    Applicant: ZEON CORPORATION
    Inventor: Hisashi Kurokawa
  • Patent number: 7247414
    Abstract: A method for producing resin particles mainly made of a resin material using a dispersion liquid in which a dispersoid containing the resin material is finely dispersed in a dispersion medium, the method comprising a dispersion medium removing step which comprises ejecting the dispersion liquid from a head portion in the form of droplets into a solidifying portion, conveying the droplets in the solidifying portion to remove the dispersion medium, and obtaining agglomerates each of which is composed of two ore more fine particles derived from the dispersoid, and a bonding step for welding and bonding the fine particles which constitute each of the agglomerates, thereby obtaining resin particles. The resin particles can be used for manufacturing a toner.
    Type: Grant
    Filed: December 13, 2004
    Date of Patent: July 24, 2007
    Assignee: Seiko Epson Corporation
    Inventors: Satoru Miura, Koji Akioka, Ken Ikuma
  • Publication number: 20070166635
    Abstract: A toner is provided including a binder resin, a colorant, and a release agent, which has a volume average particle diameter (Dv) of from 3 to 9 ?m, and wherein the binder resin and the release agent form a sea-island structure in which the island formed of the release agent is dispersed in the sea formed of the binder resin in a cross-sectional image of the toner obtained by a transmission electron microscope (TEM), and the following relationships are satisfied: IB>IA and IB>IC, wherein each of IA, IB, and IC represents an area ratio (%) of the island in an outermost region (A) of the cross-sectional image of the toner, an intermediate region (B) thereof located under the outermost region (A), and an innermost region (C) thereof located under the intermediate region (B); and a method of preparing the toner.
    Type: Application
    Filed: January 18, 2007
    Publication date: July 19, 2007
    Inventors: Atsushi Yamamoto, Chiyoshi Nozaki, Tsuyoshi Nozaki, Minoru Nakamura, Yoshimichi Ishikawa
  • Publication number: 20070166638
    Abstract: A toner is manufactured by way of a coarse particle preparing step, a slurry preparing step, a pulverizing step, a cooling step, and a depressurizing step. Slurry of toner coarse particles obtained by way of the coarse particle preparing step and the slurry preparing step is made to pass under heat and pressure through a pressure-resistant nozzle whereby toner coarse particles are pulverized into diameter-reduced toner particles. By providing the cooling step immediately after the pulverizing step, dispersion of wax component into the toner particles is promoted. And by further providing the depressurizing step, bubbling and coarsening of the toner particles due to the bubbling are prevented. By so doing, there is obtained a diameter-reduced toner particle in which wax is evenly dispersed and which does not cause bleeding out.
    Type: Application
    Filed: January 12, 2007
    Publication date: July 19, 2007
    Applicant: Sharp Kabushiki Kaisha
    Inventors: Katsuru Matsumoto, Yasuhiro Shibai
  • Patent number: 7241548
    Abstract: A method for preparing a toner including toner particles, including granulating a toner constituent mixture to prepare toner constituent particles having a polar group with a first polarity on a surface thereof; and mixing a surfactant having a second polarity different from the first polarity and a particulate material with the toner constituent particles to prepare the toner particles. A toner prepared by the method mentioned above. An image forming method including developing a latent image with the toner; transferring the toner image on a receiving material optionally via an intermediate transfer medium, and fixing the toner image on the receiving material. A process cartridge including a developer container containing a developer including the toner mentioned above, and at least one of an image bearing member; a charger; a developing device; and a cleaner.
    Type: Grant
    Filed: June 28, 2004
    Date of Patent: July 10, 2007
    Assignee: Ricoh Company Limited
    Inventors: Tsunemi Sugiyama, Hiroshi Yamashita, Yohichiroh Watanabe, Shinji Ohtani, Takuya Saito
  • Patent number: 7235338
    Abstract: A toner prepared by a method of dissolving or dispersing toner constituents comprising a modified resin capable of reacting with an active hydrogen and a colorant which is a black metallic material to prepare a solution or a dispersion; and reacting the solution or dispersion with at least one of a crosslinking agent and an elongation agent in an aqueous medium including a resin particulate material.
    Type: Grant
    Filed: June 30, 2004
    Date of Patent: June 26, 2007
    Assignee: Ricoh Company, Ltd.
    Inventors: Takeshi Takada, Masahiro Ohki, Toyoshi Sawada, Keiko Shiraishi, Masashi Nagayama
  • Patent number: 7226714
    Abstract: A process for producing a polymerized toner, comprising a step 1 of preparing a polymerizable monomer composition comprising at least a polymerizable monomer and a colorant, and a step 2 of polymerizing the polymerizable monomer composition in an aqueous medium to form a colored polymer particles, wherein the step 1 comprises a dispersing step of dispersing the colorant finely in a mixed solution comprising at least a polymerizable monomer and a colorant with a media dispersing machine which comprises a rotor and a media particle separation screen mounted on a driving shaft and is operable to rotate simultaneously in association with rotation of the driving shaft.
    Type: Grant
    Filed: August 27, 2004
    Date of Patent: June 5, 2007
    Assignee: Zeon Corporation
    Inventor: Nobuyasu Ota
  • Patent number: 7202003
    Abstract: Dry electrophotographic toner compositions are provided comprising an amphipathic copolymer comprising basic functionalities covalently bonded to the amphipathic copolymer. Methods of making the toner compositions are also provided. The present toner compositions exhibit unique charge characteristics and unique chemical and charge interaction properties.
    Type: Grant
    Filed: June 30, 2004
    Date of Patent: April 10, 2007
    Assignee: Samsung Electronics Company
    Inventors: Ronald J. Moudry, James A. Baker, Zbigniew Tokarski, Julie Y. Qian
  • Patent number: 7198874
    Abstract: The present invention relates to a toner useful, for example, for visualizing an electrostatic latent image formed on an image bearing member by a method such as electrophotography and electrostatic recording methods.
    Type: Grant
    Filed: April 4, 2006
    Date of Patent: April 3, 2007
    Assignee: Ricoh Company, Ltd.,
    Inventors: Takuya Saito, Hiroshi Yamashita, Yohichiroh Watanabe, Tsunemi Sugiyama
  • Patent number: 7195852
    Abstract: The invention provides liquid toner compositions in which the polymeric binder is chemically grown in the form of copolymeric binder particles dispersed in a liquid carrier. The polymeric binder includes one amphipathic copolymer comprising one or more S material portions and one or more D material portions, wherein the amphipathic copolymer comprises a polysiloxane moiety having molecular weight of at least about 500. Methods of making the liquid toner compositions are also provided.
    Type: Grant
    Filed: June 30, 2004
    Date of Patent: March 27, 2007
    Assignee: Samsung Electronics Company
    Inventors: Ronald J. Moudry, James A. Baker
  • Patent number: 7163775
    Abstract: A toner for developing an electrostatic image having a good combination of hot offset resistance and low temperature fixability. The toner includes (1) a resin having at least one group that can react with a compound having an active hydrogen in an amount of 2 pieces per molecule of the resin, and a colorant. The toner satisfies the following relationship: 3?G=R?Rideal?20, where G represents a ratio of a weight of components other than the colorant and the resin that are insoluble in the organic solvent to total weight of the toner, R represents a weight ratio of components included in the toner that are insoluble in the organic solvent to the total weight of the toner, and Rideal represents an ideal weight ratio of the colorant and the resin, which is calculated from a formula of the toner.
    Type: Grant
    Filed: March 19, 2004
    Date of Patent: January 16, 2007
    Assignee: Ricoh Company Limited
    Inventors: Takeshi Takada, Chiaki Tanaka, Naohiro Watanabe
  • Patent number: 7153625
    Abstract: In a process for producing toner particles by dispersing in an aqueous medium a polymerizable monomer composition containing at least a polymerizable monomer and a colorant and carrying out polymerization by the use of a polymerization initiator, the concentration of alcohol having 4 to 6 carbon atoms in the aqueous medium is so adjusted as to be from 500 ppm to 2,000 ppm when the polymerization conversion of the polymerizable monomer composition is 30%, and to be from 2,300 ppm to 10,000 ppm when the polymerization conversion of the polymerizable monomer composition is 97%.
    Type: Grant
    Filed: April 11, 2005
    Date of Patent: December 26, 2006
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takeshi Kaburagi, Yushi Mikuriya, Keiji Komoto, Yasushi Katsuta, Kenichi Nakayama
  • Patent number: 7141342
    Abstract: This invention provides a magenta toner obtaining a sharp color and having a high coloring power and superior transparency and light-fastness.
    Type: Grant
    Filed: August 19, 2005
    Date of Patent: November 28, 2006
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takayuki Toyoda, Yasuaki Murai, Takeshi Miyazaki, Norikazu Fujimoto
  • Patent number: 7105263
    Abstract: Dry electrographic toner particles are provided that comprise at least one visual enhancement additive encapsulated within an amphipathic copolymer. The amphipathic copolymer comprises one or more S portions and one or more D portions. Methods of making and methods of using these toner particles are also provided.
    Type: Grant
    Filed: December 30, 2003
    Date of Patent: September 12, 2006
    Assignee: Samsung Electronics Company
    Inventors: Ronald J. Moudry, Julie Y. Qian, James A. Baker
  • Patent number: 7083890
    Abstract: A toner is used in an image forming process employing a toner recycling system and contains at least a modified polyester resin, a coloring agent, and a releasing agent. The toner has a volume-average particle diameter Dv, a number-average particle diameter Dn and a shape factor SF-1, wherein Dv is in a range from 4.0 ?m to 6.0 ?m, the ratio Dv/Dn of Dv to Dn is in a range from 1.00 to 1.30, and the shape factor SF-1 is in a range from 140 to 200.
    Type: Grant
    Filed: January 20, 2004
    Date of Patent: August 1, 2006
    Assignee: Ricoh Company, Ltd.
    Inventors: Shigeru Emoto, Toshiki Nanya, Naohito Shimota, Maiko Kondo, Shinichiro Yagi, Hiroto Higuchi, Fumihiro Sasaki, Takahiro Honda, Junichi Awamura
  • Patent number: 7078144
    Abstract: The present invention relates to a method for manufacturing a toner with adjusted particle size distribution having a step of preparing colored particles that contain a binder resin and a colorant, and a step of classifying the colored particles. In the classification step, a classifier that has a plurality of vane-wheel classifying rotors coaxially in a casing, enables the rotating speed of each classifying rotor to be set to be the same as or different from each other, and can simultaneously perform a plurality of stages of classification corresponding to each classifying rotor is used; and the powder material comprising colored particles to which a fluidizing agent is added is fed to the classifier to perform classification.
    Type: Grant
    Filed: December 17, 2003
    Date of Patent: July 18, 2006
    Assignee: Zeon Corporation
    Inventors: Nobuyasu Ota, Toshihiko Yamato
  • Patent number: 7074535
    Abstract: The present invention relates to a toner useful, for example, for visualizing an electrostatic latent image formed on an image bearing member by a method such as electrophotography and electrostatic recording methods. In addition, the present invention also relates, without limitation, to a developer including a toner, a developing method using a toner and a method of preparing the toner.
    Type: Grant
    Filed: March 18, 2004
    Date of Patent: July 11, 2006
    Assignee: Ricoh Company, Ltd.
    Inventors: Takuya Saito, Hiroshi Yamashita, Yohichiroh Watanabe, Tsunemi Sugiyama
  • Patent number: 7070896
    Abstract: A toner containing a binder resin, a colorant, a charge control agent, and a thiazolyl disulfide compound or a thiuram disulfide compound. A process for producing a toner comprising polymerization of a polymerizable monomer composition that contains a polymerizable monomer and a colorant in an aqueous medium in the presence of a compound selected from a group consisting of (1) a thiazol thio compound, (2) a thiuram compound and (3) a dithiocarbamate compound.
    Type: Grant
    Filed: March 22, 2002
    Date of Patent: July 4, 2006
    Assignee: Zeon Corporation
    Inventors: Takuji Kishimoto, Rieko Takahara
  • Patent number: 7070898
    Abstract: A toner having a favorable fixability, excelling in charge stability, and capable of forming a image of retaining a high image density and a high resolution in long-term use is provided. That is, the toner of the present invention is a toner obtained by polymerizing a polymerizable monomer composition comprising a polymerizable monomer and a colorant, in which the polymerizable monomer composition is polymerized using a polymerization initiator comprising a redox initiator which includes an organic peroxide with a 10-hour half-life temperature of 86° C. or higher and an reducing agent; the toner has a ratio of a weight-average particle diameter to a number-average particle diameter of 1.40 or less; and the toner has top of a main-peak in a molecular weight range of 5,000 to 50,000 in a molecular weight distribution measured using GPC of the THF-soluble part thereof, including t-butanol with a content of 0.1 to 1,000 ppm.
    Type: Grant
    Filed: December 4, 2003
    Date of Patent: July 4, 2006
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tatsuya Nakamura, Kenji Okado, Akira Hashimoto, Keiji Komoto
  • Patent number: 7029818
    Abstract: The present invention relates to the use of wax-coated pigment granules as colorants in electrophotographic toners and developers, powder coating materials, inkjet inks, electret fibers, and color filters, wherein the coated pigment granules have a particle size of between 0.05 and 5 mm and a wax content of from 1 to 50% by weight, based on the overall weight of the coated pigment granules.
    Type: Grant
    Filed: November 1, 2001
    Date of Patent: April 18, 2006
    Assignee: Clariant GmbH
    Inventors: Ulrike Rohr, Ruediger Baur, Hans-Joachim Metz, Andreas Stohr
  • Patent number: 7018768
    Abstract: Amphipathic copolymers are provided comprising one or more S portions and one or more D portions. The copolymers have a chromophore covalently bonded thereto via a urethane, urea or amide linkage. These copolymers provide exceptionally useful components in toner compositions, because they provide easily prepared color-imparting particles that provide excellent color rendition.
    Type: Grant
    Filed: June 30, 2003
    Date of Patent: March 28, 2006
    Assignee: Samsung Electronics Company
    Inventors: Leonard J. Stulc, Julie Y. Qian, James A. Baker
  • Patent number: 7014969
    Abstract: The present invention provides a silica fine particle capable of preventing a charging member or an image bearing member from being contaminated with toner when the toner contains the particle and also capable of providing the toner with a stable developing property. The silica fine particle of the present invention has been hydrophobic treated. Furthermore, the particle has a peak in a range of 0.04 ?m to 1 ?m and a peak in the range of 1 ?m to 100 ?m in a volume-basis particle diameter distribution. The particle has a frequency ratio of 10 to 80% for the particles with a particle diameter of 0.04 ?m to 1 ?m to a total of all the peaks, and the particles has the frequency ratio of less than 16% for the particles with a particle diameters of 20 ?m to 2000 ?m to the total of all the peaks.
    Type: Grant
    Filed: October 2, 2003
    Date of Patent: March 21, 2006
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shinya Yachi, Yushi Mikuriya, Katsuyuki Nonaka, Shuntaro Watanabe
  • Patent number: 7008747
    Abstract: An electrophotographic developer comprising at least one element selected from the group consisting of boron and phosphorus in a content of 0.1 to 100 ppm, which the developer is excellent in flowability and shelf stability, does not give image defects such as occurrence of white stripes and attains almost constant image quality even when the ambient conditions including temperature and humidity fluctuate. A production process of a polymerized toner used in the developer, a production process of the developer, and an image forming process.
    Type: Grant
    Filed: October 5, 2004
    Date of Patent: March 7, 2006
    Assignee: Zeon Corporation
    Inventors: Takashi Iga, Kojiro Masuo, Kazuhiro Sato
  • Patent number: 6953648
    Abstract: A process for producing toner particles, in which toner particles are produced by polymerizing a polymerizable monomer composition containing at least a polymerizable monomer in an aqueous medium in a vessel, is provided. In this process, a resin composition containing a THF-insoluble resin component, which is a resin component generated in the process for producing toner particles, is kneaded. Then, the kneaded material and the polymerizable monomer are mixed together, and the resulting polymerizable monomer is polymerized to produce toner particles. For the resin composition, toner particles different from those having desired property, deposits on the vessel where the polymerization reaction occurred, or the like is used.
    Type: Grant
    Filed: April 24, 2003
    Date of Patent: October 11, 2005
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takeshi Tsujino, Hitosi Kanda, Ryoichi Fujita, Yoshinori Tsuji
  • Patent number: 6951702
    Abstract: A toner for developing a static image is disclosed. The toner has carboxyl group in an amount of from 0.1×10?5 to 2.0×10?5 moles/g in a condition that the toner particle is dispersed in water, and an amount of a metal element contained in the toner is from 10 to 5,000 ppm by weight based on the toner.
    Type: Grant
    Filed: May 23, 2003
    Date of Patent: October 4, 2005
    Assignee: Konica Corporation
    Inventors: Asao Matsushima, Hiroyuki Kozuru, Tomoe Kitani, Tomoko Tanma
  • Patent number: 6946229
    Abstract: A color toner which gives a suitable image gloss and has an excellent color reproducibility, which has sufficient anti-offset properties even when a release oil is not coated on a fixing roller or is coated in only a small amount, and which has excellent transfer properties, durability, and charge stability relative to humidity is disclosed. Also, an image-forming apparatus using the color toner and a toner container filled with the color toner are disclosed. The color toner comprises a continuous phase of a resin containing a urea-modified polyester resin; and a modified resin dispersed in the continuous phase, wherein the modified resin contains a release polymer portion containing a release polymer; and a modified portion containing a plurality of vinyl monomer units, the modified portion having an average ester group concentration of 8% by weight to 30% by weight.
    Type: Grant
    Filed: August 26, 2003
    Date of Patent: September 20, 2005
    Assignee: Ricoh Company, Ltd.
    Inventors: Masanori Suzuki, Takuya Saito, Hiroshi Yamashita, Yohichiroh Watanabe, Takeshi Takada, Tsunemi Sugiyama, Satoshi Mochizuki, Yasuaki Iwamoto, Takayuki Koike
  • Patent number: 6939656
    Abstract: Methods for producing a polymerized toners are provided, where, a dispersion including colored polymer particles obtained by polymerizing a polymerizable composition is treated stably in the process of reducing the remaining monomer, the resultant polymerized toners include a sufficiently low content of remaining monomer, and the resultant polymerized toners have excellent properties and are useful as developers for printing and copying. In the process of reducing the remaining monomer, the dispersion of the colored polymer particles is treated by stripping in the presence of a specific antifoaming agent.
    Type: Grant
    Filed: July 31, 2003
    Date of Patent: September 6, 2005
    Assignee: Zeon Corporation
    Inventors: Katsutomo Tanaka, Makoto Watanabe, Keita Sensui
  • Patent number: 6939657
    Abstract: A method of manufacturing polymer particles for use in a toner capable of incorporating fine wax particle in a polymer resin particle also in a case of adopting a dispersion polymerization method used generally so far, thereby enabling to prevent offset in a heat fixing device provided to copying machines or printers thereby improving the fixing property of the toner and capable of forming images at fine fineness when the polymer resin particles are used as the toner. The fine wax particle is dispersed by using the polymeric dispersant into an organic solvent and one or more of monomers for forming the polymer is dissolved and the polymerizing reaction of the monomer is proceeded while depositing the fine polymer particles on the surface of the fine wax particle upon deposition of the polymer into the organic solvent in the initial stage of the polymerizing reaction of the monomer, thereby incorporating the fine wax particles into the formed polymer particle.
    Type: Grant
    Filed: June 26, 2003
    Date of Patent: September 6, 2005
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventors: Naomichi Kobayashi, Masato Tanaka
  • Patent number: 6858369
    Abstract: According to a toner and a manufacturing method of the present invention, the toner, which is composed of a binding resin component precipitated in particle shapes with a coloring agent component dispersed in the binding resin component, is produced by dissolving the binding resin component in a supercritical fluid (a SCF), blending the coloring agent component in the SCF, and lowering solubility of the binding resin component for precipitating the binding resin component in the particle shapes. Even when the coloring agent content is increased, by the SCF, the toner can maintain dispersibility of the coloring agent component in the binding resin component precipitated in the particle shapes, meanwhile coloring power is also maintained thereby. Therefore, the toner can promote miniaturization of an image forming apparatus using the toner.
    Type: Grant
    Filed: May 9, 2003
    Date of Patent: February 22, 2005
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Katsumi Adachi, Masamitsu Sakuma, Kiyoshi Toizumi, Taisuke Kamimura, Tadashi Iwamatsu, Kenji Mishima
  • Patent number: 6846604
    Abstract: A toner composition including toner particles including mother toner particles, which include a binder resin, a colorant and a release agent, and a charge controlling agent which is located on a surface of the mother toner particles and fixed thereon, wherein the toner particles have a spherical degree of from 0.960 to 1.000 and a specific surface area of from 0.70 to 2.5 m2/g. The toner composition optionally includes an external additive which is present on the surface of the toner particles.
    Type: Grant
    Filed: September 19, 2002
    Date of Patent: January 25, 2005
    Assignee: Ricoh Company Limited
    Inventors: Shigeru Emoto, Hiroshi Yamashita, Naohiro Watanabe, Tsunemi Sugiyama, Hiroshi Yamada, Masami Tomita
  • Patent number: 6841329
    Abstract: A toner process comprising mixing a colorant dispersion with a latex, a wax dispersion, and a coagulant, and wherein the polymer present in the latex possesses a gel content of from about 0.5 to about 4.5 weight percent, a polymer melt flow index (MFI) of from about 20 to about 45 grams/10 minutes at about from about 115° C. to about 145° C., the crosslinking molecular weight Mc of the polymer being from about 12,000 to about 200,000, and the crosslinking density Me of the polymer being from about 1.2×10?9 to about 2×10?7/Kmole.
    Type: Grant
    Filed: April 14, 2003
    Date of Patent: January 11, 2005
    Assignee: Xerox Corporation
    Inventors: Peter V. Nguyen, Amy A. Albright, Donald Riley, Chieh-Min Cheng
  • Patent number: 6841325
    Abstract: The present invention relates to an electrostatic-latent-image developing toner which contains at least a binder resin, a coloring agent and a wax that does not exhibit a clear peak on a low-temperature side of a main fusing peak in a DSC curve, the wax being represented by the formula; R1—(OCO—R2)n in which R1 and R2 independently represent a hydrocarbon group having 1 to 40 carbon atoms that may have a substituent, and n is an integer of 1 to 4.
    Type: Grant
    Filed: January 29, 2003
    Date of Patent: January 11, 2005
    Assignee: Minolta Co., Ltd.
    Inventors: Hideaki Ueda, Shino Hirao, Masahiro Anno
  • Publication number: 20040265723
    Abstract: The invention provides liquid toner compositions in which the polymeric binder is chemically grown in the form of copolymeric binder particles dispersed in a liquid carrier. The polymeric binder includes one amphipathic copolymer comprising one or more S material portions and one or more D material portions, wherein the S material portion of the copolymer has molecular weight and solubility properties selected to provide a three dimensional gel of controlled rigidity which can be reversibly reduced to a fluid state by application of energy. The toners as described herein surprisingly provide compositions that are particularly suitable for electrophotographic processes wherein the transfer of the image from the surface of a photoconductor to an intermediate transfer material or directly to a print medium is carried out without film formation on the photoconductor.
    Type: Application
    Filed: June 30, 2003
    Publication date: December 30, 2004
    Inventors: Julie Y. Qian, James A. Baker
  • Publication number: 20040265722
    Abstract: The invention provides liquid toner compositions in which the polymeric binder is chemically grown in the form of copolymeric binder particles dispersed in a liquid carrier. The polymeric binder includes one amphipathic copolymer comprising one or more S material portions and one or more D material portions, wherein the components of the composition comprise sufficient acid and base functionality to provide a three dimensional gel of controlled rigidity which can be reversibly reduced to a fluid state by application of energy. The toners as described herein surprisingly provide compositions that are particularly suitable for electrophotographic processes wherein the transfer of the image from the surface of a photoconductor to an intermediate transfer material or directly to a print medium is carried out without film formation on the photoconductor.
    Type: Application
    Filed: June 30, 2003
    Publication date: December 30, 2004
    Inventors: Julie Y. Qian, James A. Baker
  • Publication number: 20040265724
    Abstract: Amphipathic copolymers are provided comprising one or more S portions and one or more D portions. The copolymers have a chromophore covalently bonded thereto via a urethane, urea or amide linkage. These copolymers provide exceptionally useful components in toner compositions, because they provide easily prepared color-imparting particles that provide excellent color rendition.
    Type: Application
    Filed: June 30, 2003
    Publication date: December 30, 2004
    Inventors: Leonard J. Stulc, Julie Y. Qian, James A. Baker
  • Publication number: 20040265725
    Abstract: The invention provides liquid toner compositions in which the polymeric binder is chemically grown in the form of copolymeric binder particles dispersed in a liquid carrier. The polymeric binder includes one amphipathic copolymer comprising one or more S material portions and one or more D material portions, wherein the components of the composition comprise sufficient crosslinking functionality to provide a three dimensional gel of controlled rigidity which can be reversibly reduced to a fluid state by application of energy. The toners as described herein surprisingly provide compositions that are particularly suitable for electrophotographic processes wherein the transfer of the image from the surface of a photoconductor to an intermediate transfer material or directly to a print medium is carried out without film formation on the photoconductor.
    Type: Application
    Filed: June 30, 2003
    Publication date: December 30, 2004
    Inventors: Julie Y. Qian, James A. Baker
  • Patent number: 6835521
    Abstract: To provide a process for producing toner particles in a good efficiency which have less residue of monomers and less other organic volatile components, the process has a polymerization step of polymerizing a polymerizable monomer composition containing at least a polymerizable monomer, in a vessel holding therein an aqueous medium, wherein a high-temperature saturated steam with a temperature higher than 100° C. is introduced into the aqueous medium held in the vessel, at the latter half of polymerization or after the polymerization has been completed, to remove at least organic volatile components from toner particles having at least a binder resin and a colorant.
    Type: Grant
    Filed: January 24, 2003
    Date of Patent: December 28, 2004
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yoshinori Tsuji, Toshiyuki Ugai, Akira Hashimoto, Hidekazu Fumita
  • Publication number: 20040259018
    Abstract: To provide a process for producing toner particles in a good efficiency which have less residue of monomers and less other organic volatile components, the process has a polymerization step of polymerizing a polymetizable monomer composition containing at least a polymerizable monomer, in a vessel holding therein an aqueous medium, wherein a high-temperature saturated steam with a temperature higher than 100° C. is introduced into the aqueous medium held in the vessel, at the latter half of polymerization or after the polymerization has been completed, to remove at least organic volatile components from toner particles having at least a binder resin and a colorant.
    Type: Application
    Filed: July 13, 2004
    Publication date: December 23, 2004
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Yoshinori Tsuji, Toshiyuki Ugai, Akira Hashimoto, Hidekazu Fumita
  • Publication number: 20040253531
    Abstract: The present invention relates to a method for manufacturing a toner with adjusted particle size distribution having a step of preparing colored particles that contain a binder resin and a colorant, and a step of classifying the colored particles. In the classification step, a classifier that has a plurality of vane-wheel classifying rotors coaxially in a casing, enables the rotating speed of each classifying rotor to be set to be the same as or different from each other, and can simultaneously perform a plurality of stages of classification corresponding to each classifying rotor is used; and the powder material comprising colored particles to which a fluidizing agent is added is fed to the classifier to perform classification.
    Type: Application
    Filed: December 17, 2003
    Publication date: December 16, 2004
    Applicant: ZEON CORPORATION
    Inventors: Nobuyasu Ota, Toshihiko Yamato
  • Patent number: 6824945
    Abstract: Disclosed is an electrophotographic toner using a polyester resin as a binder and a highly dispersed pigment colorant. The toner gives a high quality image excellent in transparency and chroma (brightness, gloss) and exhibits excellent powder fluidity, anti-offset property, charge stability and transferability.
    Type: Grant
    Filed: July 7, 2003
    Date of Patent: November 30, 2004
    Assignee: Ricoh Company, Ltd.
    Inventors: Shigeru Emoto, Masami Tomita, Hiroshi Yamashita, Tsunemi Sugiyama
  • Patent number: 6808853
    Abstract: An electrostatic image developing toner comprising a resin and a colorant is disclosed. The resin comprises a polymerization component of a polymerizable monomer having a polar group in an amount of 1.0 to 10.0 percent by weight, and a polymerization component of a polyfunctional polymerizable monomer in an amount of 0.1 to 10.0 percent by weight; ratio (A/B) is from 0.5 to 20.0 percent; and either a peak or a shoulder is positioned in the molecular weight region of 5,000 to 20,000, wherein A is an area of a chromatograph curve in the molecular weight region of 60,000 to 1,000,000, based on GCP measurement of a THF soluble component of toner and B is an entire area of the chromatograph curve.
    Type: Grant
    Filed: December 2, 2002
    Date of Patent: October 26, 2004
    Assignee: Konica Corporation
    Inventors: Tomoe Kitani, Takao Yamanouchi, Naohiro Hirose, Ken Ohmura
  • Patent number: 6808855
    Abstract: A toner production process comprising the step of polymerizing a polymerizable monomer in the presence of (i) base particles containing at least a binder resin and (ii) a polymerization initiator. The polymerization initiator has in one molecule a hydrophilic moiety and a hydrophobic moiety and a reactive moiety between them, and the base particles are enlarged and/or surface-modified upon polymerization of the polymerizable monomer. Also disclosed is a toner having a circularity of from 0.92 to 1.0, which is produced by this process.
    Type: Grant
    Filed: May 23, 2002
    Date of Patent: October 26, 2004
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yasukazu Ayaki, Hitoshi Itabashi, Yayoi Tazawa
  • Publication number: 20040191659
    Abstract: A toner having a favorable fixability, excelling in charge stability, and capable of forming a image of retaining a high image density and a high resolution in long-term use is provided. That is, the toner of the present invention is a toner obtained by polymerizing a polymerizable monomer composition comprising a polymerizable monomer and a colorant, in which the polymerizable monomer composition is polymerized using a polymerization initiator comprising a redox initiator which includes an organic peroxide with a 10-hour half-life temperature of 86° C. or higher and an reducing agent; the toner has a ratio of a weight-average particle diameter to a number-average particle diameter of 1.40 or less; and the toner has top of a main-peak in a molecular weight range of 5,000 to 50,000 in a molecular weight distribution measured using GPC of the THF-soluble part thereof, including t-butanol with a content of 0.1 to 1,000 ppm.
    Type: Application
    Filed: December 4, 2003
    Publication date: September 30, 2004
    Inventors: Tatsuya Nakamura, Kenji Okado, Akira Hashimoto, Keiji Komoto
  • Publication number: 20040191661
    Abstract: The toner having a significantly improved dispersibility of a colorant in toner particles is provided. The present invention provides a dry toner comprising: (i) a binder resin; (ii) a colorant; (iii) at least one of metallophthalocyanine and a metallophthalocyanine derivative having a central metal selected from the group consisting of Cr, Fe, Co, Ni, Zn, Mn, Mg, and Al; and (iv) a polymer containing 0.5 to 20% by mass of a base unit derived from a specific polymerizable monomer having an amide group.
    Type: Application
    Filed: March 10, 2004
    Publication date: September 30, 2004
    Inventors: Manabu Ohno, Motoya Fukushima, Hitoshi Itabashi, Yasushi Katsuta, Emi Tosaka, Norikazu Fujimoto
  • Publication number: 20040180282
    Abstract: In a method for manufacturing a polymerized toner, in a washing step after polymerization, colored polymer particles are washed using a continuous pressurizing filter in a circulation washing manner, in which a dispersion containing colored polymer particles obtained in the polymerization step is supplied by pressure to the inlet of the continuous pressurizing filter from a slurry tank that stores the dispersion; the dispersion is filtered in the filter while stirring; the concentrated dispersion is fed back to the slurry tank from the outlet; a washing solution in a quantity equivalent to the quantity of the filtrate filtered by filtration is added to the slurry tank to dilute the filtrate; and the dispersion diluted by the washing solution is circulated in the filter.
    Type: Application
    Filed: March 5, 2004
    Publication date: September 16, 2004
    Applicant: ZEON CORPORATION
    Inventor: Nobuyasu Ota
  • Patent number: 6790576
    Abstract: It is an object of the present invention to provide a dispersing agent for a pigment capable of finely dispersing a pigment in a dispersion medium. The present invention provides a dispersing agent for a pigment comprising at least a metallic compound having a specific structure with a central metal capable of taking a penta-coordinated structure, and n-electron-donating compound having affinity for the dispersion medium and capable of being coordinated with the central metal of the metallic compound.
    Type: Grant
    Filed: January 10, 2003
    Date of Patent: September 14, 2004
    Assignee: Canon Kabushiki Kaisha
    Inventors: Norikazu Fujimoto, Hitoshi Itabashi