Powder Development Of Tacky Surface Patents (Class 430/144)
  • Patent number: 9623605
    Abstract: Thermally cross-linkable photo-hydrolyzable inkjet printable polymers are used to print microfluidic channels layer-by-layer on a substrate. In one embodiment, for each layer, an inkjet head deposits droplets of a mixture of hydrophobic polymer and cross-linking agent in a pattern lying outside a two-dimensional layout of the channels, and another inkjet head deposits droplets of a mixture of poly(tetrahydropyranyl methacrylate) PTHPMA (or another hydrophobic polymer which hydrolyzes to form a hydrophilic material), cross-linking agent, and a photoacid generator (PAG) in a pattern lying inside the two-dimensional layout of the channels. After all layers are printed, flood exposure of the entire substrate to UV radiation releases acid from the PAG which hydrolyzes PTHPMA to form hydrophilic poly(methacrylic acid) PMAA, thereby rendering the PTHPMA regions hydrophilic. The layers of these now-hydrophilic patterned regions together define the microfluidic channels. The cross-linking agent (e.g.
    Type: Grant
    Filed: September 12, 2012
    Date of Patent: April 18, 2017
    Assignee: International Business Machines Corporation
    Inventors: Dylan J. Boday, Joseph Kuczynski, Robert E. Meyer, III
  • Patent number: 6297058
    Abstract: A small sample of a refractory material, e.g., about 0.1 g to about 10 g, is heated to at least 1000° C., generally under a pressure of less than about 10−5 Torr. Evolved hydrogen-containing gases and/or carbon-containing gases are monitored, e.g., by mass spectrometry, and, based on the amount of the evolved gases, the concentration of hydrogen and/or carbon in the sample is calculated. It is therefore possible to accurately determine the hydrogen and carbon concentration from a small sample of a material, by a process much less burdensome than conventional techniques.
    Type: Grant
    Filed: January 14, 1999
    Date of Patent: October 2, 2001
    Assignee: Agere Systems Optoelectronics Guardian Corp.
    Inventor: William David Reents, Jr.
  • Patent number: 5750314
    Abstract: A substrate is coated with a first material which is soluble in a first solvent, whereupon a second material which is strongly adherent to the first material and insoluble in the first solvent is selectively applied by an ink jet printer. The substrate is then developed in the first solvent to establish the image. In a preferred embodiment the substrate is hydrophilic, the first material is a negative working photosensitive material, and the second material is a transparent adhesive, which permits curing the first material by exposure to actinic light after the development step. The adhesive is then removed. In an embodiment directed to a waterless plate the substrate includes a surface coating of silicone, and the first material is a primer which promotes adhesion of a second material in the form of an oleophilic adhesive which is selectively applied. The primer is then developed to expose the silicone on the non-image areas.
    Type: Grant
    Filed: December 5, 1995
    Date of Patent: May 12, 1998
    Assignee: Howard A. Fromson
    Inventors: Howard A. Fromson, Robert F. Gracia, Steven A. Rubin
  • Patent number: 5698374
    Abstract: A process for the preparation of an image is provided, which comprises exposing to light a layer of a composition which changes its stickiness when irradiated with active light, spraying a particulate image-forming material on to the layer, removing the particulate matter which has not been attached to the layer, and then heating the layer to fix the particulate image-forming to the substrate. This process is suitable for the patterning of not only a fluorescent substance for plasma display but also a light-impermeable or sparingly light-permeable material to which photolithography has heretofore been difficultly applied. Furthermore, the thickness of the image-forming material layer can be easily varied by properly selecting the grain diameter of the image-forming material.
    Type: Grant
    Filed: July 3, 1996
    Date of Patent: December 16, 1997
    Assignees: Fuji Photo Film Co., Ltd., Fuji-Hunt Electronics Technology Co., Ltd.
    Inventors: Kesanao Kobayashi, Masahide Yasui
  • Patent number: 5534380
    Abstract: A tonable, aqueous-processable, photosensitive element and process for forming a colored image from said element is described. The element comprises a support and a tonable, aqueous-processable photosensitive layer, said photosensitive layer consisting essentially of (a) an aqueous-processable, photoinsolubilizable photosensitive composition comprising a photosensitive material, and (b) a water-soluble plasticizer, wherein said photosensitive material is present in sufficient amount to insolubilize said photosensitive layer on exposure to actinic radiation, said photosensitive composition is present in sufficient amount to form a layer when said photosensitive layer is coated, and said plasticizer is present in sufficient amount to make said photosensitive layer.
    Type: Grant
    Filed: November 28, 1994
    Date of Patent: July 9, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Gregory A. Bodager, Bruce M. Monroe
  • Patent number: 5401603
    Abstract: A tonable, aqueous-processable, photosensitive element and process for forming a colored image from said element is described. The element comprises a support and a tonable, aqueous-processable photosensitive layer, said photosensitive layer consisting essentially of (a) an aqueous-processable, photoinsolubilizable photosensitive composition comprising a photosensitive material, and (b) a water-soluble plasticizer, wherein said photosensitive material is present in sufficient amount to insolubilize said photosensitive layer on exposure to actinic radiation, said photosensitive composition is present in sufficient amount to form a layer when said photosensitive layer is coated, and said plasticizer is present in sufficient amount to make said photosensitive layer.
    Type: Grant
    Filed: February 15, 1994
    Date of Patent: March 28, 1995
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Gregory A. Bodager, Bruce M. Monroe
  • Patent number: 5356751
    Abstract: The process and product are disclosed for mounting free-flowing particles, which employ a support having a support surface with an array of tacky areas which have a size and bonding strength suitable for adhesion of either one or two of said particles. In the process the particles flow across the support surface to allow particles to contact the tacky areas and adhere thereto. An array of mounted particles may thus be provided which has at least 50% singly or doubly mounted particles.
    Type: Grant
    Filed: December 27, 1993
    Date of Patent: October 18, 1994
    Assignee: E. I. Du Pont de Nemours & Company
    Inventors: Allan Cairncross, Ulrich Klabunde
  • Patent number: 5286595
    Abstract: The present invention concerns a phototackifiable composition useful as a coating on a substrate consisting of an optically clear blend of two or more polymers and a photosensitive compound that forms a strong acid on exposure to actinic radiation. The invention also relates to a process for coating such a composition on a support and toning the image-wise exposed composition on the support.
    Type: Grant
    Filed: March 30, 1993
    Date of Patent: February 15, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Walter R. Hertler, Howard E. Simmons, III, Mario Grossa
  • Patent number: 5229244
    Abstract: The present invention concerns a phototackifiable composition useful as a coating on a substrate consisting of an optically clear blend of two or more polymers and a photosensitive compound that forms a strong acid on exposure to actinic radiation. The invention also relates to a process for coating such a composition on a support and toning the image-wise exposed composition on the support.
    Type: Grant
    Filed: June 29, 1992
    Date of Patent: July 20, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Walter R. Hertler, Howard E. Simmons, III
  • Patent number: 5213920
    Abstract: The present disclosure relates to an electrophotographic method of obtaining a lithographic printing plate comprising the step of transferring a toner image from a toner image bearing member to a toner receiving plate, said toner receiving plate comprising a thermoplastic film support and a crosslinked hydrophilic layer thereon, characterized in that said crosslinked hydrophilic layer either carries on top thereof or incorporates spacing particles forming protuberances on said layer.According to a preferred embodiment, the average particle diameter by volume of the spacing particles is at least twice the average particle diameter by volume of the electrophotographic toner.
    Type: Grant
    Filed: November 26, 1991
    Date of Patent: May 25, 1993
    Assignee: Agfa-GEVAERT N.V.
    Inventors: Paul J. Coppens, Ludovicus H. Vervloet, Serge M. Tavernier, Paul F. Sterckx
  • Patent number: 5028512
    Abstract: Printing plates having a photosensitive layer coated on a support wherein said photosensitive layer contains a powdered solid adhered to the surface of said plate by means of powdering followed by the application of heat or solvent before exposure. Said powders are capable of being removed from said surface during the developing process.
    Type: Grant
    Filed: November 3, 1989
    Date of Patent: July 2, 1991
    Assignee: Konica Corporation and Mitsubishi Kasei Corporation
    Inventors: Toshio Nagatani, Minoru Seino, Toru Okamoto, Chihiro Eguchi
  • Patent number: 4857429
    Abstract: An optical contact of a patternwise powdery coating layer is improved by permeating a substantially transparent inorganic material having a refractive index of 1.2 to 2.0 into a paternwise powdery coating layer formed on a substrate, thereby forming a mixture layer of the transparent inorganic material and the powdery coating layer between the patternwise powdery coating layer and the substrate.
    Type: Grant
    Filed: December 3, 1986
    Date of Patent: August 15, 1989
    Assignee: Hitachi, Ltd.
    Inventors: Nobuaki Hayashi, Shoichi Uchino, Yoshifumi Tomita, Saburo Nonogaki, Masahiro Nishizawa
  • Patent number: 4855200
    Abstract: A high contrast and brightness fluorescent screen of a color picture tube has a light absorbing layer in the form of fine dots or stripes provided for the inner surface of a panel of the tube on which the phosphor layer is formed, and a light reflection layer provided at an interface between the light absorbing layer and the phosphor layer. To manufacture the fluorescent screen, a photosensitive resin layer coated on an inner surface of the panel is exposed to light through a photomask mounted on outside of the panel to form a pattern. Nonluminous light absorbing substance is applied on the pattern to form the light absorbing layers.
    Type: Grant
    Filed: December 28, 1987
    Date of Patent: August 8, 1989
    Assignee: Hitachi, Ltd.
    Inventors: Yoshifumi Tomita, Masahiro Nishizawa, Saburo Nonogaki
  • Patent number: 4735880
    Abstract: A photosensitive composition comprising (1) at least one diazonium compound selected from among salts and double salts of diazonium ions represented by the general formulas: ##STR1## wherein A stands for a substituent selected from among ##STR2## wherein R.sub.1 and R.sub.2 each stand for an alkyl or benzyl group with the proviso that the total number of carbon atoms of R.sub.1 and R.sub.2 is 8 to 16, and (2) at least one nitrate selected from the group consisting of calcium nitrate and magnesium nitrate and a pattern forming process using such a composition.This composition gets sticky upon exposure to light.
    Type: Grant
    Filed: April 16, 1986
    Date of Patent: April 5, 1988
    Assignee: Hitachi, Ltd.
    Inventors: Hajime Morishita, Saburo Nonogaki, Nobuaki Hayashi, Shoichi Uchino, Masahiro Nishizawa, Kiyoshi Miura, Osamu Sasaya, Yoshifumi Tomita
  • Patent number: 4729935
    Abstract: A process for the production of photographic images utilizing a photographic element comprising a transparent support and a coating on the support comprising a diazonium composition having a light absorbency of about 45% or less, and a colorant composition, said coating having a light transmission of not more than about 0.1%.
    Type: Grant
    Filed: October 18, 1985
    Date of Patent: March 8, 1988
    Assignee: Hoechst Celanese Corporation
    Inventors: John E. Walls, Major S. Dhillon
  • Patent number: 4681824
    Abstract: A fluorescent screen of a color picture tube is manufactured by the steps of forming a film of substance which becomes sticky when exposed to light on an inner surface of a panel of the tube, exposing predetermined portion of the film through a shadow mask to render sticky the exposed portions, repeatedly applying powders of phosphors of respective colors onto the portions which became sticky so as to form phosphor picture elements of respective colors, exposing portions of the film other than the predetermined portions to render them sticky, and applying a powder of graphite to the portions other than the predetermined portions to form a black matrix film.
    Type: Grant
    Filed: April 16, 1982
    Date of Patent: July 21, 1987
    Assignee: Hitachi, Ltd.
    Inventor: Yoshifumi Tomita
  • Patent number: 4612268
    Abstract: A method of forming a color picture tube fluorescent screen by so-called dry process. After a photosticky substance mainly containing a diazonium compound is coated on a panel inner face, phosphor is adhered to portions of the compound which have been exposed to light through a color selection electrode and rendered sticky, and surplus phosphor applied on unexposed portions of the compound is removed, the above steps being consecutively repeated for phosphors of three colors to form picture elements of triads of three color phosphors on the panel inner face. The panel inner face is then treated with an aqueous solution containing at least polymer coagulant.
    Type: Grant
    Filed: July 8, 1985
    Date of Patent: September 16, 1986
    Assignee: Hitachi, Ltd.
    Inventors: Kiyoshi Miura, Hiroshi Yokomizo, Osamu Sasaya, Hajime Morishita, Yoshifumi Tomita
  • Patent number: 4537851
    Abstract: A water-soluble, positive-working photoresist composition is disclosed which comprises water-soluble aromatic diazonium salt, water-soluble phenolic compound, and water-soluble polymeric compound. When the film of this composition is irradiated with a pattern of actinic ray and then brought into contact with an alkaline gas or solution, the coating of unexposed areas hardens to become water-insoluble. Preferably, when the film is brought into contact with a suspension of powder or dry powder after being hardened, a positive pattern of powder is obtained by the development with water.
    Type: Grant
    Filed: September 12, 1983
    Date of Patent: August 27, 1985
    Assignee: Hitachi, Ltd.
    Inventors: Saburo Nonogaki, Nobuaki Hayashi, Yoshifumi Tomita
  • Patent number: 4520094
    Abstract: A photosensitive composition turning shicky by light exposure, which comprises a salt or p-aminobenzenediazonium compound and at least one of salts of o- and m-aminobenzenediazonium compounds, has a distinguished effect in forming a phosphor screen of a color picture tube.
    Type: Grant
    Filed: October 19, 1982
    Date of Patent: May 28, 1985
    Assignee: Hitachi, Ltd.
    Inventors: Hajime Morishita, Motoo Akagi, Nobuaki Hayashi, Saburo Nonogaki, Shoichi Uchino, Takahiro Kohashi
  • Patent number: 4510226
    Abstract: A photosensitive composition becoming sticky upon exposure to light which comprises (a) a salt of a diazonium compound represented by the formula ##STR1## wherein R.sub.1 and R.sub.2 are independently --H, --CH.sub.3, --OCH.sub.3 or ##STR2## but R.sub.1 and R.sub.2 cannot be ##STR3## at the same time; and R.sub.3 and R.sub.4 are independently a straight-chain lower alkyl group, and (b) a salt of an aromatic diazonium compound having no --OH group directly bonding to a benzene ring, has an improved sensitivity because it contains the salt of the compound represented by the above formula. By using said photosensitive composition, there is provided a process for forming a pattern of powder coated layer excellent in light sensitivity.
    Type: Grant
    Filed: July 19, 1983
    Date of Patent: April 9, 1985
    Assignee: Hitachi, Ltd.
    Inventors: Hajime Morishita, Motoo Akagi, Saburo Nonogaki, Nobuaki Hayashi, Shoichi Uchino
  • Patent number: 4501810
    Abstract: The lithographic printing plate of the invention comprises a substrate having a hydrophilic surface, a coating on said surface of a light sensitive material (e.g., a water soluble diazo) and a top coating of discrete, oleophilic resin particles (e.g., an emulsion polymer), the resin particle coating being:(a) transparent to actinic light;(b) sufficiently permeable to allow a developer for the light sensitive material to penetrate through to the underlying light sensitive coating;(c) insoluble in said developer;(d) capable of being coalesced in situ after the plate is imaged and developed.
    Type: Grant
    Filed: March 3, 1983
    Date of Patent: February 26, 1985
    Assignee: Howard A. Fromson
    Inventors: Howard A. Fromson, Robert F. Gracia
  • Patent number: 4469766
    Abstract: For formation of a cathode-ray tube phosphor screen by causing a fluorescent material to adhere to a particle-accepting sticky surface formed uniformly on the inner surface of a face plate, phosphor particles are placed on the inner surface of the face plate and caused to slide physically over the particle-accepting sticky surface so as to be stuck thereto.
    Type: Grant
    Filed: November 18, 1982
    Date of Patent: September 4, 1984
    Assignee: Hitachi, Ltd.
    Inventors: Masahiro Nishizawa, Kiyoshi Miura, Hiroshi Yokomizo, Osamu Sasaya, Yoshifumi Tomita
  • Patent number: 4409313
    Abstract: A photosensitive composition improved in sensitivity by adding a salt of a compound represented by the general formula: ##STR1## (wherein R.sub.1 and R.sub.2 each represents a straight chain alkyl group, and X, Y and Z each represents H, a straight chain alkyl group or an alkoxy group, but two or more of X, Y and Z can not be H at the same time) to an aromatic diazonium salt which gets sticky upon exposure to light.
    Type: Grant
    Filed: September 29, 1982
    Date of Patent: October 11, 1983
    Assignee: Hitachi, Ltd.
    Inventors: Hajime Morishita, Takahiro Kohashi, Saburo Nonogaki, Motoo Akagi, Nobuaki Hayashi, Shoichi Uchino
  • Patent number: 4407916
    Abstract: A process for forming a fluorescent screen, where polychroic patterns are successively formed from at least two kinds of phosphors having different color emission or black powder by means of a photosensitive substance capable of turning tacky by light irradiation, which comprises bringing a finer particulate filling material than particles of the phosphors in contact with tackified parts when or after the particles of the phosphors are applied to the tackified parts in the individual steps of forming patterns each of the individual phosphors. The filling material saturates the tackiness of the phosphor pattern in question in advance to formation of a phosphor pattern in the successive step, and a cause for contamination of the pattern of the preceding step with the phosphor of the successive step can be eliminated thereby.
    Type: Grant
    Filed: March 15, 1982
    Date of Patent: October 4, 1983
    Assignee: Hitachi, Ltd.
    Inventors: Motoo Akagi, Shoichi Uchino, Saburo Nonogaki
  • Patent number: 4377630
    Abstract: A photosensitive composition improved in sensitivity by adding a salt of a compound represented by the general formula: ##STR1## (wherein R.sub.1 and R.sub.2 each represents a straight chain alkyl group, and X, Y and Z each represents H, a straight chain alkyl group or an alkoxy group, but two or more of X, Y and Z can not be H at the same time) to an aromatic diazonium salt which gets sticky upon exposure to light.
    Type: Grant
    Filed: July 2, 1981
    Date of Patent: March 22, 1983
    Assignee: Hitachi, Ltd.
    Inventors: Hajime Morishita, Takahiro Kohashi, Saburo Nonogaki, Motoo Akagi, Nobuaki Hayashi, Shoichi Uchino
  • Patent number: 4324850
    Abstract: In forming a fluorescent screen for a color picture tube having triads of phosphor materials of the three primary colors arranged in a predetermined pattern on the inner surface of a panel, a photosensitive film which exhibits stickiness when exposed to a threshold amount of light is formed on the inner surface of the panel. Locations of the photosensitive film where the three color phosphor materials respectively occupy are exposed to light from a light source through a shadow mask mounted to the panel. The amount of exposure light for a first color phosphor material is the threshold or above and that for second and third phosphor materials is below the threshold. After completion of the light exposures for the first to third color phosphor materials through the shadow mask, the shadow mask is dismounted from the panel and the first color phosphor material is deposited onto the photosensitive film.
    Type: Grant
    Filed: February 28, 1980
    Date of Patent: April 13, 1982
    Assignee: Hitaci, Ltd.
    Inventors: Yoshifumi Tomita, Masahiro Nishizawa, Hiroshi Yokomizo, Hiromitu Nakai
  • Patent number: 4276363
    Abstract: A process for forming a phosphor screen of a color picture tube comprising forming a thin layer using a photosensitive composition which contains an aromatic diazonium salt as a photosensitive component and produces tackiness by exposure to actinic light on the surface of the substrate and contacting the tackified thin layer after exposure to light with phosphor particles to form each phosphor layer for emitting color is improved by using as the phosphor particles those coated with at least one surface coating material selected from the group consisting of Zn(OH).sub.2, Zn.sub.3 (PO.sub.4).sub.2 and AlPO.sub.4 in shortening the contact time between the thin layer and the phosphor particles.
    Type: Grant
    Filed: October 19, 1979
    Date of Patent: June 30, 1981
    Assignees: Hitachi, Ltd., Kasei Optonix, Ltd.
    Inventors: Toshikatsu Manabe, Saburo Nonogaki, Hajime Morishita, Shoichi Uchino, Yoshifumi Tomita, Masahiro Nishizawa, Hiroshi Yokomizo, Susumu Ohmatoi
  • Patent number: 4269918
    Abstract: A strongly fixed patternwise coated powder layer is formed on a substrate by subjecting a thin layer of photo-sensitive composition containing an aromatic diazonium salt as a photo-sensitive component capable of becoming sticky due to the formation of a photolytic reaction product of the salt by a patternwise light exposure, thereby making the light-exposed part of the thin layer sticky, bringing the thin layer in contact with powdery grains, thereby forming a powder-containing coating layer, and contacting the powder-containing coating layer with a powdery material that reacts with the photolytic product, thereby forming a water-insoluble or slightly water-soluble solid material to fix the powdery grains to the substrate.
    Type: Grant
    Filed: August 3, 1979
    Date of Patent: May 26, 1981
    Assignee: Hitachi, Ltd.
    Inventors: Saburo Nonogaki, Hajime Morishita, Shoichi Uchino, Toshikatsu Manabe
  • Patent number: 4254210
    Abstract: To reduce silver coating weight in photographic silver halide elements (e.g., medical X-ray films) the density of the silver image is increased by forming a black-toned, direct positive image in a photopolymer layer on the reverse side from the silver image.
    Type: Grant
    Filed: May 11, 1978
    Date of Patent: March 3, 1981
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Albert L. Van Stappen
  • Patent number: 4247612
    Abstract: In a method of forming a fluorescent screen on the inner surface of a face plate of a color picture tube wherein a film of photosensitive composition consisting essentially of a diazonium salt, the portions of the films to be deposited with phosphors are exposed to light through a color selection electrode so as to impart sticky property to the portions by a photoreaction and moisture in atmosphere and then a powder of phosphors is deposited by utilizing the sticky property, a photosensitive binder is incorporated into photosensitive film which undergoes a cross-linkage reaction with the photosensitive composition, thus rendering the mixture insoluble in water.
    Type: Grant
    Filed: August 8, 1979
    Date of Patent: January 27, 1981
    Assignee: Hitachi, Ltd.
    Inventors: Masahiro Nishizawa, Hiroshi Yokomizo, Yoshifumi Tomito, Saburo Nonogaki, Toshikatsu Manabe