By Uniform Application Of Heat, Element, Or Image Receiving Layer Therefor Patents (Class 430/203)
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Patent number: 11050024Abstract: Disclosed is a method of manufacturing a surface-modified polymer film, including forming a hydroxyl group (—OH) on the surface of a polymer film by subjecting the polymer film to light irradiation and surface treatment with a photoacid generator. The polymer film can be introduced with a hydroxyl group (—OH) group using a photoacid generator, thereby modifying the surface of the polymer film without damage to the polymer film. Also, an organic electronic device including the surface-modified polymer film can be improved in electrical characteristics and stability.Type: GrantFiled: October 24, 2018Date of Patent: June 29, 2021Assignees: CENTER FOR ADVANCED SOFT ELECTRONICS, POSTECH ACADEMY—INDUSTRY FOUNDATIONInventors: Kilwon Cho, Jinsung Kim, Boseok Kang
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Patent number: 10646772Abstract: Apparatus, systems, and methods for delivery of an automatically clearing composition in a balloon.Type: GrantFiled: May 15, 2019Date of Patent: May 12, 2020Inventor: Taylor Christopher Lowe
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Patent number: 10596087Abstract: The present invention includes an ultraviolet radiation absorbing polymer composition comprising the polymer compound of formula and compositions containing such an ultraviolet radiation absorbing polymer composition.Type: GrantFiled: August 25, 2017Date of Patent: March 24, 2020Assignee: Johnson & Johnson Consumer Inc.Inventors: Thomas Ehlis, Susan Daly
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Patent number: 10228619Abstract: Disclosed herein is an article comprising a substrate; a first region having a first brush polymer chemically bonded to the substrate; where the first brush polymer comprises repeat units of a first ethylenically unsaturated monomer and a second ethylenically unsaturated monomer; where the first ethylenically unsaturated monomer comprises a first electroactive moiety and where the second ethylenically unsaturated monomer comprises a second electroactive moiety that is different from the first electroactive moiety; where at least one of the first electroactive moiety or the second electroactive moiety is an emitter moiety and where the repeat units of the first ethylenically unsaturated monomer are covalently bonded to repeat units of the second ethylenically unsaturated monomer.Type: GrantFiled: March 31, 2017Date of Patent: March 12, 2019Assignees: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA, ROHM AND HAAS ELECTRONIC MATERIALS LLC, DOW GLOBAL TECHNOLOGIES LLCInventors: Craig J. Hawker, Zachariah Allen Page, Peter Trefonas, III, Anatoliy N. Sokolov, John Kramer, David S. Laitar, Sukrit Mukhopadhyay, Benjaporn Narupai, Christian Wilhelm Pester
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Patent number: 9818535Abstract: In the systems and methods for synthesizing a thin film with desired properties (e.g. magnetic, conductivity, photocatalyst, etc.), a metal oxide film may be deposited on a substrate. The metal oxide film may be achieved utilizing any suitable method. A reducing agent may be deposited before, after or both before and after the metal oxide layer. Oxygen may be removed or liberated from the deposited metal oxide film by low temperature local or global annealing. As a result of the annealing to remove oxygen, one or more portions of the metal oxide may be transformed into materials with desired properties. As a nonlimiting example, a metal oxide film may be treated to provide a magnetic multilayer film that is suitable for bit patterned media.Type: GrantFiled: January 8, 2015Date of Patent: November 14, 2017Assignee: UNIVERSITY OF HOUSTON SYSTEMInventors: Dmitri Litvinov, Long Chang
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Patent number: 9234081Abstract: NBT-PVA film dosimeters performance is affected due to high humidity levels. NBT-PVB film dosimeters with a relatively small effect of high humidity levels on its performance are invented. NBT-PVB film dosimeters are made by using alcoholic solution to dissolve both of NBT and PVB. The films are very useful for routine dosimeter in industrial radiation processing. A very high sensitivity NBT-PVB Radio-chromic film dosimeter is achieved due to high solubility of NBT dye in 2-methoxyethanol enabling the addition of very high concentrations of NBT dye in the film dosimeters. The dose response of conventional NBT-PVA dosimeter films are normally saturated after 50 kGy, while the invented composites of NBT-PVB dosimeter films demonstrated high dose range up to 100 kGy for high dose industrial use.Type: GrantFiled: June 8, 2010Date of Patent: January 12, 2016Assignee: KING ABDULAZIZ CITY FOR SCIENCE AND TECHNOLOGYInventors: Ahmed Ali Basfar, Khalid Ahmed Rabaeh, Akram Ahmed Al-Moussa
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Patent number: 9219126Abstract: A device, including a substrate, an electronically active component on the substrate, an interface dielectric on the semiconductor, and a relaxor dielectric on the interface dielectric. The relaxor dielectric includes a surfactant that is solid at room temperature.Type: GrantFiled: April 25, 2014Date of Patent: December 22, 2015Assignee: Palo Alto Research Center IncorporatedInventors: Gregory Whiting, Tse Nga Ng, Bing R. Hsieh
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Patent number: 9081283Abstract: The invention disclosed herein provides highly efficient methods and materials useful for surface patterning via polymerization reactions. In particular, by using a light-mediated radical polymerization procedure, brush formation from a surface can be regulated spatially by controlling the area of irradiation. In embodiments of the invention, polymer chain length (and/or film thickness) can be effectively controlled by either the amount of time a surface is irradiated with light (temporal control) or by the intensity of light allowed to reach the surface. Such light-mediated control allows artisans to use the disclosed processes to form complex 3-dimensional structures on a variety of surfaces. Moreover, the simplicity of the disclosed polymerization processes allows them to be adapted for use in a wide range of technologies.Type: GrantFiled: October 9, 2013Date of Patent: July 14, 2015Assignee: The Regents of the University of CaliforniaInventors: Craig J. Hawker, Brett P. Fors, Justin E. Poelma
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Patent number: 8822124Abstract: A method of forming a pattern comprises diffusing an acid formed by irradiating a portion of a photosensitive layer, into an underlayer comprising an acid sensitive copolymer having acid decomposable groups and attachment groups covalently bonded to the surface of the substrate and/or forming an interpolymer crosslink. Diffusing comprises heating the underlayer and photosensitive layer. The acid sensitive group reacts with the diffused acid to form a polar region on the underlayer, with the shape of the pattern. The photosensitive layer is removed, forming a self-assembling layer comprising a block copolymer having a first block with an affinity for the polar region, and a second block having less affinity for the polar region. The first block forms a domain aligned to the polar region, and the second block forms another domain aligned to the first. Removing either domain exposes a portion of the underlayer.Type: GrantFiled: October 4, 2011Date of Patent: September 2, 2014Assignee: Dow Global Technologies LLCInventors: Peter Trefonas, Phillip Dene Hustad, Cynthia Pierre
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Patent number: 8647740Abstract: A method for labeling fabrics, such as fabric garments, and a heat-transfer label well-suited for use in said method. In one embodiment, the heat-transfer label comprises (i) a support portion, the support portion comprising a carrier and a release layer; (ii) a wax layer, the wax layer overcoating the release layer; and (iii) a transfer portion, the transfer portion comprising an adhesive layer printed onto the wax layer and an ink design layer printed onto the adhesive layer. Preferably, at least a portion of the ink design layer is printed using a variable printing technique, such as thermal transfer printing.Type: GrantFiled: July 11, 2007Date of Patent: February 11, 2014Assignee: Avery Dennison CorporationInventors: Xiao-Ming He, Liviu Dinescu, Kuolih Tsai, Dong-Tsai Hseih, Li Shu, Yi-Hung Chiao, Alan Morgenthau, Ramin Heydarpour
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Patent number: 7585609Abstract: The present invention provides methods for forming images in positive- or negative-tone chemically amplified photoresists. The methods of the present invention rely on the vertical up-diffusion of photoacid generated by patternwise imaging of an underlayer disposed on a substrate and overcoated with a polymer containing acid labile functionality. In accordance with the present invention, the vertical up-diffusion can be the sole mechanism for imaging formation or the methods of the present invention can be used in conjunction with conventional imaging processes.Type: GrantFiled: July 25, 2006Date of Patent: September 8, 2009Assignee: International Business Machines CorporationInventors: Carl Eric Larson, Gregory Michael Wallraff
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Patent number: 7537878Abstract: A method of fabricating an OLED is provided. The method includes providing a substrate, in which a pixel electrode is formed. In addition, the method includes laminating a donor substrate attached to a frame on an entire surface of the substrate, and irradiating a laser to a predetermined region of the donor substrate to form an organic layer pattern on the pixel electrode. The present invention provides a method of fabricating the OLED capable of suppressing generation of contaminants such as particles and so on, and preventing the donor substrate from sagging or bending, as well as improving transfer efficiency since the donor substrate and the substrate are readily adhered to each other to maintain vacuum state.Type: GrantFiled: December 27, 2004Date of Patent: May 26, 2009Assignee: Samsung SDI Co., Ltd.Inventors: Myung-Won Song, Seong-Taek Lee, Mu-Hyun Kim, Byung-Doo Chin
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Publication number: 20080196626Abstract: The present invention relates to a composition comprising: (a) a polymer having at least one repeating unit of formula where R1 is a non-hydrolysable group and n is an integer ranging from 1 to 3; and (b) a crosslinking catalyst. The composition is useful in forming low k dielectric constant materials and as well as hard mask and underlayer materials with anti-reflective properties for the photolithography industry.Type: ApplicationFiled: February 20, 2007Publication date: August 21, 2008Inventors: Hengpeng Wu, WooKyu Kim, Hong Zhuang, PingHung Lu, Mark Neisser, David Abdallah, Ruzhi Zhang
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Patent number: 7371502Abstract: Methods of fabricating an OLED and a donor substrate are provided. The method includes: preparing a base substrate of a donor substrate; forming a light to heat conversion layer and a transfer layer on the base substrate; preparing a donor substrate including performing a dry cleaning process after forming the transfer layer; preparing a substrate, on which the transfer layer of the donor substrate is to be transferred; laminating the donor substrate and the substrate; and patterning the transfer layer by irradiating a laser to transfer the transfer layer on the substrate.Type: GrantFiled: December 22, 2004Date of Patent: May 13, 2008Assignee: Samsung SDI Co., Ltd.Inventors: Myung-Won Song, Seong-Taek Lee, Mu-Hyun Kim, Byung-Doo Chin, Tae-Min Kang, Jae-Ho Lee
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Patent number: 7160665Abstract: The present invention provides methods for forming images in positive- or negative-tone chemically amplified photoresists. The methods of the present invention rely on the vertical up-diffusion of photoacid generated by patternwise imaging of an underlayer disposed on a substrate and overcoated with a polymer containing acid labile functionality. In accordance with the present invention, the vertical up-diffusion can be the sole mechanism for imaging formation or the methods of the present invention can be used in conjunction with conventional imaging processes.Type: GrantFiled: December 30, 2002Date of Patent: January 9, 2007Assignee: International Business Machines CorporationInventors: Carl Eric Larson, Gregory Michael Wallraff
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Patent number: 7097963Abstract: Black-and-white, aqueous-based, silver halide-containing photothermographic materials have increased stability after imaging with the incorporation of at least 0.0002 mol/m2 of a halogen-substituted tetraazaindene compound.Type: GrantFiled: April 18, 2005Date of Patent: August 29, 2006Assignee: Eastman Kodak CompanyInventors: Chaofeng Zou, Kumars Sakizadeh, George J. Burgmaier, Roger L. Klaus
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Silver-free black-and-white thermographic materials containing a benzoquinone and methods of imaging
Patent number: 7022441Abstract: Silver-free, aqueous-based direct thermographic materials are designed to have image tone with near neutral density. Without the use of organic silver salts containing reducible silver ions, the image is formed using a color developing agent precursor that releases a color developing agent when heated to a temperature of at least 80° C., a combination of cyan, yellow and magenta dye-forming color couplers that provide cyan, yellow, and magenta dyes, and a substituted or unsubstituted benzoquinone as an oxidizing agent. No silver metal or silver ions are purposely added to these materials. This combination of components provides a means for controlling image tone without reliance upon conventional toning agents.Type: GrantFiled: February 25, 2004Date of Patent: April 4, 2006Assignee: Eastman Kodak CompanyInventors: Joe E. Maskasky, Victor P. Scaccia -
Patent number: 6962763Abstract: Silver-free, aqueous-based direct thermographic materials are designed to have image tone with near neutral density. Without the use of organic silver salts containing reducible silver ions, the image is formed using a color developing agent precursor that releases a color developing agent when heated to a temperature of at least 80° C., a combination of cyan, yellow and magenta dye-forming color couplers that provide cyan, yellow, and magenta dyes, and a hindered-amine N-oxyl as an oxidizing agent. No silver metal or silver ions are purposely added to these materials. This combination of components provides a means for controlling image tone without reliance upon conventional toning agents.Type: GrantFiled: February 25, 2004Date of Patent: November 8, 2005Assignee: Eastman Kodak CompanyInventors: Joe E. Maskasky, Victor P. Scaccia
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Patent number: 6946232Abstract: An image-receiving element for use in photographic and photothermographic diffusion transfer film units of the type where the image-receiving element is designed to be removed, or “peeled-apart” from a photosensitive element following exposure and photographic processing. The present image-receiving element comprises, in sequence, a support, an image-receiving layer and a strip-coat layer which serves to facilitate separation of the image-receiving element from the photosensitive element after photographic processing. The strip-coat layer comprises an anion of poly(acrylic acid), or a salt thereof, complexed with a cationic quaternary salt. In a preferred embodiment, the strip coat layer may include an ethoxylated alcohol.Type: GrantFiled: November 17, 2003Date of Patent: September 20, 2005Assignee: Polaroid CorporationInventors: Gerard Gomes, Gary S. LaPointe, James J. Manning
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Patent number: 6911294Abstract: A multicolor image forming material comprising: an image receiving sheet comprising an image receiving layer; and at least five heat transfer sheets different in color each comprising a substrate, a light-heat conversion layer and an image forming layer, each of the heat transfer sheets being adapted to be superposed on the image receiving sheet with the image forming layer facing the image receiving layer and irradiated with laser light to transfer the irradiated area of the image forming layer to the image receiving layer to record an image on the image receiving sheet, wherein the area of the recording has a size of 515 mm by 728 mm or larger, and at least one of the heat transfer sheets comprises titanium oxide as a colorant in the image forming layer thereof.Type: GrantFiled: August 29, 2003Date of Patent: June 28, 2005Assignee: Fuji Photo Film Co., Ltd.Inventor: Shinichi Yoshinari
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Patent number: 6824961Abstract: A heat developing method having the steps of: initially making the overall surface of a heat developing photosensitive material or a photosensitive and thermosensitive recording material (hereinafter called a “heat developing recording material”) to a predetermined temperature not lower than a glass transition temperature and not higher than heat development start temperature; and performing heat development.Type: GrantFiled: May 16, 2002Date of Patent: November 30, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Masaharu Ogawa, Toshitaka Agano
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Patent number: 6790569Abstract: A color photothermographic element comprising at least three light-sensitive units which have their individual sensitivities in different wavelength regions, each of the units comprising at least one light-sensitive silver-halide emulsion, binder, and dye-providing coupler, and a blocked developer in the presence of a thermal solvent represented by the following structure: wherein the groups are as defined in the specification to promote the thermal development of the photothermographic element.Type: GrantFiled: May 16, 2001Date of Patent: September 14, 2004Assignee: Eastman Kodak CompanyInventors: Xiqiang Yang, Zbyslaw R. Owczarczyk, David T. Southby, Mark E. Irving, Paul B. Merkel, Lyn M. Irving, David H. Levy
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Patent number: 6750894Abstract: The present invention relates to a method of recording an image of a given object onto a substrate. In the method, the object is first defined as the numerical image values at its coordinate locations and then, using these numerical values for control, the final image is recorded with the help of reactive agents capable of undergoing a change of state. Each one of the state-changing reactive agents is applied onto each point of the substrate in an amount located and controlled by the numerical value of the respective point in the object image, whereupon each one of the amounts of the applied agents is subjected to a reaction causing a change of state. The invention can be implemented to record photographic images, for instance. Other applications are in the manufacture of printed-circuit boards, printing plates and the like.Type: GrantFiled: July 1, 2002Date of Patent: June 15, 2004Inventor: Urho A. Pietilä
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Publication number: 20040053157Abstract: A multicolor image forming material comprising: an image receiving sheet comprising an image receiving layer; and at least five heat transfer sheets different in color each comprising a substrate, a light-heat conversion layer and an image forming layer, each of the heat transfer sheets being adapted to be superposed on the image receiving sheet with the image forming layer facing the image receiving layer and irradiated with laser light to transfer the irradiated area of the image forming layer to the image receiving layer to record an image on the image receiving sheet, wherein the area of the recording has a size of 515 mm by 728 mm or larger, and at least one of the heat transfer sheets comprises titanium oxide as a colorant in the image forming layer thereof.Type: ApplicationFiled: August 29, 2003Publication date: March 18, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventor: Shinichi Yoshinari
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Publication number: 20040029033Abstract: An ink transfer sheet and method for using the same. The transfer sheet includes a backing layer, a release layer on the backing layer, and an ink receiving layer on the release layer. The ink receiving layer contains a quaternary ammonium salt thereon or impregnated therein. To use the transfer sheet, an ink containing an anionic coloring agent is applied to the ink receiving layer, preferably using thermal inkjet methods. Thereafter, the transfer sheet is positioned on a fabric substrate. Heat is applied to the sheet which causes the release layer and ink receiving layer to adhere to the substrate. The backing layer is then detached from the release layer leaving the release and ink receiving layers (with the printed image thereon) on the substrate. This process transfers the image to the fabric substrate, with the image being stabilized by interactions between the quaternary ammonium salt and anionic coloring agent.Type: ApplicationFiled: August 6, 2003Publication date: February 12, 2004Inventors: Melissa D. Boyd, Mark H. Kowaiski
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Patent number: 6689533Abstract: A dye-fixing element for color diffusion transfer process, having an ultraviolet-absorbing layer that contains an ultraviolet absorber in a coating amount of 0.2 g/m2 or more, over a mordant layer; and containing, as at least one dispersion medium for the ultraviolet absorber, a compound represented by formula (1), in a ratio (mass ratio) of 25 to 200% of the ultraviolet absorber; with the sum of coating amounts of the ultraviolet absorber and total dispersion medium for the ultraviolet absorber being 1.0 g/m2 or less; wherein x and y each represent a molar fraction of each recurring unit, the total of x and y is 1, and y ranges from 0.85 to 0.95.Type: GrantFiled: October 31, 2002Date of Patent: February 10, 2004Assignee: Fuji Photo Film Co., Ltd.Inventor: Kiyoshi Irita
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Patent number: 6673508Abstract: A planographic printing plate material and a method of preparing a planographic printing plate are disclosed, the planographic printing plate material comprising a support and provided thereon, one or more structural layers containing light sensitive silver halide grains, organic silver salt grains, a reducing agent, a contrast-increasing agent and a physical developing nucleus.Type: GrantFiled: March 12, 2002Date of Patent: January 6, 2004Assignee: Konica CorporationInventor: Takeshi Sampei
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Patent number: 6645711Abstract: A silver halide color photographic light-sensitive material containing a compound of the formula: wherein R1, R2 and R3 each represent a hydrogen atom or a substituent; R4 represents an alkyl, aryl or heterocyclic group; R1 and R2, or/and R2 and R4 may combine with each other to form a 5-membered, 6-membered or 7-membered ring; Z represents a group of non-metallic atoms that form a 5-membered, 6-membered or 7-membered ring together with the nitrogen atom and two carbon atoms in the benzene ring; R5 represents an alkyl, aryl or heterocyclic group, in which the compound of the formula contains none of a hydroxyl group, a carboxyl group and a sulfo group in each of R1, R2, R3 and R4.Type: GrantFiled: July 18, 2002Date of Patent: November 11, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Osamu Uchida, Toshio Kawagishi, Masaaki Tsukase, Kazuhiko Matsumoto
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Publication number: 20030194637Abstract: A dye-fixing element for color diffusion transfer process, having an ultraviolet-absorbing layer that contains an ultraviolet absorber in a coating amount of 0.2 g/m2 or more, over a mordant layer; and containing, as at least one dispersion medium for the ultraviolet absorber, a compound represented by formula (1), in a ratio (mass ratio) of 25 to 200% of the ultraviolet absorber; with the sum of coating amounts of the ultraviolet absorber and total dispersion medium for the ultraviolet absorber being 1.Type: ApplicationFiled: October 31, 2002Publication date: October 16, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventor: Kiyoshi Irita
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Publication number: 20030124451Abstract: A method and apparatus for producing identification (ID) cards using a photosensitive imaging system employing microcapsules is described. In accordance with one aspect of the invention, ID cards are produced by translating an image containing identifying indicia into a latent image on an appropriate photosensitive donor sheet, pressure developing the latent image, forming a full color print of the image on a developer sheet, laminating an ID card substrate in registration with the image to the developer sheet and die cutting the laminated article to produce an ID card. Self-contained imaging systems can also be used to produce identification cards. The image preferably includes unique information useful in identifying the card holder such as a photograph, fingerprint, signature, description, name, etc. The identifying indicia may be combined with non-variable information including background printing, card issuer data, logos, security features, etc.Type: ApplicationFiled: November 7, 2002Publication date: July 3, 2003Inventors: Joseph C. Camillus, Alexander Y. Polykarpov, Ibrahim Katampe
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Publication number: 20030096188Abstract: A planographic printing plate material and a method of preparing a planographic printing plate are disclosed, the planographic printing plate material comprising a support and provided thereon, one or more structural layers containing light sensitive silver halide grains, organic silver salt grains, a reducing agent, a contrast-increasing agent and a physical developing nucleus.Type: ApplicationFiled: March 12, 2002Publication date: May 22, 2003Inventor: Takeshi Sampei
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Color-developing agent, silver halide photographic light-sensitive material and image-forming method
Patent number: 6495304Abstract: There is disclosed a novel color-developing agent of a 1,2,4-thiadiazol-5-yl hydrazine type. There is also disclosed a silver halide photographic light-sensitive material which gives sufficient color formation by development and forms an image excellent in image quality and image storability, by using the color-developing agent. Further, there is disclosed an image-forming method using the light-sensitive material.Type: GrantFiled: June 25, 2001Date of Patent: December 17, 2002Assignee: Fuji Photo Film Co., Ltd.Inventors: Osamu Uchida, Yasuhiro Ishiwata, Kiyoshi Takeuchi, Taiji Katsumata, Takashi Nakamura -
Publication number: 20020172899Abstract: A heat developing method having the steps of: initially making the overall surface of a heat developing photosensitive material or a photosensitive and thermosensitive recording material (hereinafter called a “heat developing recording material”) to a predetermined temperature not lower than a glass transition temperature and not higher than heat development start temperature; and performing heat development.Type: ApplicationFiled: May 16, 2002Publication date: November 21, 2002Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Masaharu Ogawa, Toshitaka Agano
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Color-developing agent, silver halide photographic light-sensitive material and image-forming method
Publication number: 20020102489Abstract: There is disclosed a novel color-developing agent of a 1,2,4-thiadiazol-5-yl hydrazine type. There is also disclosed a silver halide photographic light-sensitive material which gives sufficient color formation by development and forms an image excellent in image quality and image storability, by using the color-developing agent. Further, there is disclosed an image-forming method using the light-sensitive material.Type: ApplicationFiled: June 25, 2001Publication date: August 1, 2002Inventors: Osamu Uchida, Yasuhiro Ishiwata, Kiyoshi Takeuchi, Taiji Katsumata, Takashi Nakamura -
Patent number: 6423465Abstract: A method is disclosed for preparing a patterned continuous polymeric brush on a substrate surface. The method generally involves functionalization of the substrate surface followed by surface-initiated polymerization at the initiation sites so provided, e.g., using a living free radical polymerization technique or the like, whereby a covalently bound continuous polymeric brush results, with acid-labile groups present throughout. An acid is then applied to the continuous polymer brush in a predetermined pattern, under conditions that result in removal of the acid-labile groups in at least one first region of the continuous polymer brush but not in at least one second region of the continuous polymer brush. In a preferred embodiment, the acid is a photogenerated acid resulting from imagewise irradiation of a photoacid generator applied as a film or coating to the surface-bound polymer brush.Type: GrantFiled: January 28, 2000Date of Patent: July 23, 2002Assignees: International Business Machines Corporation, The Board of Trustees of the Leland Stanford Junior UniversityInventors: Craig Jon Hawker, James Lupton Hedrick, William Dinan Hinsberg, III, Marc Husemann, Michael Morrison
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Patent number: 6410217Abstract: A heat-developable color light-sensitive material which contains at least, on a support, a light-sensitive silver halide emulsion, a binder, and a dye-providing compound, wherein the light-sensitive material contains at least one compound represented by formula (I) in, for example, a protective layer: formula (I) wherein R1 is a chlorine atom or an alkoxy group, R2 is an acylamino group or an alkoxycarbonyl group, R11 is a hydrogen atom or an alkyl group; R12 and R13, which are the same or different from, each are a hydrogen atom, an alkyl group or an alkoxy group.Type: GrantFiled: March 1, 2001Date of Patent: June 25, 2002Assignee: Fuji Photo Film Co., Ltd.Inventors: Kazuki Uehara, Nobuhiro Nishita
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Patent number: 6403278Abstract: An image-receiving element for use in photographic and photothermographic dirrufsion transfer film units of the type where the image-receiving element is designed to be removed, or “peeled-apart” from a photosensitive element following exposure and photographic processing. The present image-receiving element comprises, in sequence, a support, an image-receiving layer and a strip-coat layer which serves to facilitate separation of the image-receiving element from the photosensitive element after photographic processing. The strip-coat layer comprises a cationic homopolymer or a copolymer of an acrylate with a quarternary salt functional group. The strip coat provides a glossy image after photographic processing.Type: GrantFiled: December 15, 2000Date of Patent: June 11, 2002Assignee: Polaroid CorporationInventors: Agota F. Fehervari, James J. Manning
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Patent number: 6340561Abstract: Disclosed is a heat developable color photosensitive material, said material comprising a support having disposed thereon a photosensitive layer including at least two layers, any one of the layers containing a photosensitive silver halide, a binder, and an incorporated color developing agent, one layer containing a substantially colorless coupler which forms a diffusive dye by coupling with the oxidized form of the incorporated developing agent, another layer containing a compound represented by the general formula (1). In the color photosensitive material for heat development, the hue of the diffusive dye, which is formed by the coupling reaction between the substantially colorless compound and the oxidized form of the incorporated color developing agent, and the hue of the diffusive dye residue, which is represented by Dye in the general formula (1), differ from each other.Type: GrantFiled: September 29, 2000Date of Patent: January 22, 2002Assignee: Fuji Photo Film Co., Ltd.Inventors: Hideaki Naruse, Yuki Mizukawa
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Patent number: 6337170Abstract: This invention provides a color diffusion transfer image forming material comprising a light-sensitive material containing a compound which forms or releases a diffusible dye upon reaction with a developing agent derived from a light-sensitive silver halide, aminopheno derivative or phenylenediamine derivative and an oxidation product of the developing agent supported on a first support, and a dye-fixing material containing a discoloration preventing agent having a specific structure supported on a second support which may be the same as or different from the first support, wherein the light-sensitive material and the dye-fixing material are located so that the diffusible dye formed or released by developing is at least transferred from the light-sensitive material to the dye-fixing material in developing the light-sensitive material, thereby providing the image forming material with excellent properties in terms of dye concentration, image fastness and the like.Type: GrantFiled: June 3, 1998Date of Patent: January 8, 2002Assignee: Fuji Photo Film Co., Ltd.Inventor: Hideaki Naruse
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Patent number: 6333143Abstract: There is disclosed a method for forming an image on a light-sensitive material having on a base at least a light-sensitive silver halide emulsion and a binder, which comprises, subjecting at least one light-sensitive layer to exposure to light, by using an exposure head that has a plurality of different light sources for emitting lights in respective specific wavelength regions correspondingly to adjacent exposure picture elements, to form an image, wherein, in the specific wavelength regions from the shortest wavelength to the longest wavelength for the respective plurality of light sources to be used, the change in sensitivity of the light-sensitive material in the spectral sensitivity curve obtained by plotting the sensitivities of the light-sensitive material in terms of the specific wavelength regions including the wavelengths in centers of gravity of respective light sources is 0.01 log E/nm or less.Type: GrantFiled: August 12, 1999Date of Patent: December 25, 2001Assignee: Fuji Photo Film Co., Ltd.Inventors: Takeshi Shibata, Yuji Mihara
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Patent number: 6329129Abstract: A heat-developable color light-sensitive material comprising a support having thereon at least a light-sensitive silver halide emulsion, a hydrophilic binder and a dye-donating compound capable of releasing a diffusible dye in correspondence or counter-correspondence to the silver development, wherein at least two light-insensitive layers are provided between the support and a light-sensitive layer closest to the support and the light-insensitive layer not adjacent to the light-sensitive layer contains at least one compound represented by the following formula (I) or (II): wherein R1 to R6 are defined herein wherein R7, R8 and R9 are defined herein and Y represents —CO— or —SO2—.Type: GrantFiled: November 22, 2000Date of Patent: December 11, 2001Assignee: Fuji Photo Film Co., Ltd.Inventor: Takayasu Yamazaki
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Publication number: 20010038982Abstract: A heat-developable color light-sensitive material which contains at least, on a support, a light-sensitive silver halide emulsion, a binder, and a dye-providing compound, wherein the light-sensitive material contains at least one compound represented by formula (I) in, for example, a protective layer: formula (I) 1Type: ApplicationFiled: March 1, 2001Publication date: November 8, 2001Inventors: Kazuki Uehara, Nobuhiro Nishita
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Patent number: 6303261Abstract: Disclosed are a silver halide color photographic material having on a support a photographic element in which silver halide grains, a developing agent and a coupler capable of forming a dye by reaction with an oxidation product of the developing agent are incorporated, the photographic element further comprising at least one color stain inhibitive compound represented by the following formula (SC-1) or (SC-2) and at least one photographically useful group-releasing compound represented by the following formula (II); and a method of forming color images by the use of the foregoing material: A—[(L1)a—(B)m]p—(L2)n—PUG (II)Type: GrantFiled: March 15, 2000Date of Patent: October 16, 2001Assignee: Fuji Photo Film Co., Ltd.Inventors: Jun Arakawa, Toshio Kawagishi
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Patent number: 6303282Abstract: The present invention discloses a color photographic photosensitive material for heat development, which material is characterized in that the color photographic photosensitive material produces superior discrimination with reduced color muddiness in rapid processing. The color photographic photosensitive material for heat development of the present invention comprises a support having thereon a photosensitive silver halide, a binder, a dye-releasable compound, a compound represented by the general formula (I) or (II), and a compound represented by the general formula (III) or (IV).Type: GrantFiled: December 15, 1999Date of Patent: October 16, 2001Assignee: Fuji Photo Film Co., Ltd.Inventors: Hideaki Naruse, Toshio Kawagishi, Takeshi Shibata
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Patent number: 6277537Abstract: A photographic chrogenic and substantially dry dye-diffusion-transfer element is disclosed, wherein said element is activated by heat and comprises contacting dye-receiver and dye-donor layers and further comprises a layer which contains a thermal solvent according to formula (I) wherein Z1, Z2, Z3, Z4, and Z5 are substituents, the Hammet sigma paameters of Z2, Z3, and Z4 sum to at least −0.28 and less than 1.53; the calculated logP for I is greater than 3 and less than 10.Type: GrantFiled: December 6, 1991Date of Patent: August 21, 2001Assignee: Eastman Kodak CompanyInventors: David Scott Bailey, Ronald Henry White, John Texter
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Color-developing agent, silver halide photographic light-sensitive material and image-forming method
Patent number: 6277994Abstract: There is disclosed a novel color-developing agent of a 1,2,4-thiadiazol-5-yl hydrazine type. There is also disclosed a silver halide photographic light-sensitive material which gives sufficient color formation by development and forms an image excellent in image quality and image storability, by using the color-developing agent. Further, there is disclosed an image-forming method using the light-sensitive material.Type: GrantFiled: March 31, 2000Date of Patent: August 21, 2001Assignee: Fuji Photo Film Co., Ltd.Inventors: Osamu Uchida, Yasuhiro Ishiwata, Kiyoshi Takeuchi, Taiji Katsumata, Takashi Nakamura -
Patent number: 6268105Abstract: There is disclosed a dye-fixing element utilizable to form an image by releasing or producing an image-forming dye or a precursor thereof in proportion or contraproportion to developed silver formed by development after imagewise exposing of a photosensitive silver halide and thereafter by diffusion or diffusive-transfer of the dye, which element comprises a polymeric dye mordant containing a recurring unit of the formula (A) and/or (B): wherein R12 and R22 each are H or an alkyl group, Y1 and Y2 each are ←CONR4—, ←COO— or ←CH(OH)CH2O—, X is Cl, Br, I or OH, Z is an atomic group necessary to form a 5- to 7-membered heteroring together with the N, R13 and R23 each are H, CH3, C2H5, or a halogen atom, and R4 is H or an alkyl group having 1-4 carbon atoms, and the symbol ← is a bond on the side of the main chain of the polymer. There is also disclosed a method for forming a color image excellent in fastness to light without causing any color-mixing.Type: GrantFiled: May 24, 2000Date of Patent: July 31, 2001Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroshi Arakatsu, Nobuo Seto, Toshiki Taguchi
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Patent number: 6265118Abstract: There is disclosed an image element wherein a dye, formed or released by reaction with an oxidized product of specific a compound, and specific a fixed compound, coexist in a binder on a support. The image element can have high color density in image, and it can be excellent in light fastness. Furthermore, there is also disclosed an image formation method to provide the image element.Type: GrantFiled: January 28, 2000Date of Patent: July 24, 2001Assignee: Fuji Photo Film Co., Ltd.Inventor: Keiichi Taguchi
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Patent number: 6265117Abstract: A color imaging element comprising a dye formed upon a reaction of an oxidation product of a compound represented by formula (I) shown below together with at least one water-soluble compound represented by formula (II) shown below on a support: wherein Z represents a carbamoyl group, an acyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonyl group or a sulfamoyl group; and Q represents an atomic group necessary for forming an unsaturated ring together with the carbon atom; wherein X represents a hydrogen atom, a hydroxy group, an aliphatic group, an acyl group, an aliphatic oxy group, an aliphatic oxycarbonyl group or an aryloxycarbonyl group; Y1 and Y2, which may be the same or different, each represents a hydrogen atom or a substituent, or Y1 and Y2 may be combined with each other to form a 5-membered or 6-membered ring; Z1 represents a simple bond, a methylene group which may be substituted or an ethylene group which may be substituted; Z2 represents aType: GrantFiled: September 20, 1999Date of Patent: July 24, 2001Assignee: Fuji Photo Film Co., Ltd.Inventor: Keiichi Taguchi
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Patent number: 6261746Abstract: Disclosed is an image-forming method which comprises exposing a photographic material comprising a support having thereon at least a photosensitive silver halide emulsion and a binder, the silver halide emulsion containing at least one compound selected from metal ions and metal complex ions which are electron traps of 0.2 eV or less in depth, with an exposing head having at least three kinds of exposure light sources having different specific light emitting wavelength regions corresponding to at least three different color sensitivities of the photographic material, each of the at least three kinds of exposure light sources having different center-of-gravity wavelengths in each of the specific light emitting wavelength regions, wherein each of the specific light emitting wavelength regions is from the shortest wavelength to the longest wavelength among the exposure light sources having different center-of-gravity wavelengths, and the photographic material has a sensitivity variation of 0.Type: GrantFiled: January 19, 2000Date of Patent: July 17, 2001Assignee: Fuji Photo Film Co., Ltd.Inventor: Takuji Kosugi