Coupler With Coupling-off Ballast, Dye Or Dye Precursor Moiety Patents (Class 430/226)
-
Patent number: 5322758Abstract: In accordance with this invention a photographic color diffusion transfer element is provided wherein said element comprises a single dimensionally stable transparent support and coated thereon in reactive association and in sequence (1) a mordant layer for binding diffusible dyes, (2) a light reflecting layer, (3) imaging layers comprising a radiation sensitive layer comprising silver halide and a diffusible dye forming layer comprising a diffusible dye forming compound, and (4) a barrier layer comprising a polymer that allows the passage of solutions for processing said element when said element is contacted with an external processing bath, and wherein said barrier layer impedes the diffusion out of said element of the diffusible dye formed from said diffusible dye forming compound.Type: GrantFiled: September 28, 1992Date of Patent: June 21, 1994Assignee: Eastman Kodak CompanyInventors: John Texter, Wayne A. Bowman, Glenn T. Pearce, Douglas E. Corbin
-
Patent number: 5318879Abstract: A color photographic element is disclosed comprising a support bearing at least one photographic silver halide emulsion layer, an image dye-forming coupler, and a coupler (A) capable of forming a compound that is washed out of the photographic element upon processing and capable of releasing a bleach accelerator group, wherein the coupler (A) is represented by the formula:(SOL).sub.x --COUP--(R.sup.1).sub.y --(R.sup.2).sub.z --BLEACH.Type: GrantFiled: June 29, 1992Date of Patent: June 7, 1994Assignee: Eastman Kodak CompanyInventors: William J. Begley, Stephen P. Singer, David T. Southby, Donald Singleton, Jr.
-
Patent number: 5306603Abstract: A light-sensitive material having high light-sensitivity and high contrast and excelling in color reproduction at all light-exposed regions, yellow-image sharpness, magenta-image sharpness, and cyan-image sharpness, and having its sensitivity little deteriorated during storage. The material comprises at least one light-sensitive, silver halide emulsion layer on a support, and contains at least one specified compound which releases a photographically useful group, and a yellow-colored cyan coupler.Type: GrantFiled: June 3, 1992Date of Patent: April 26, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Keiji Mihayashi, Atsuhiro Ohkawa
-
Patent number: 5300406Abstract: A color photographic element comprises a support bearing at least one photographic silver halide emulsion layer, an image dye-forming coupler, and a combination of a development inhibitor releasing coupler and a wash-out coupler, the washout coupler (A)(i) capable of forming a compound that is washed out of the photographic element upon processing and(ii) capable of releasing a bleach accelerator group, and(iii) is represented by the formula:(SOL).sub.x --COUP--(R.sup.1).sub.y --(R.sup.2).sub.z --BLEACHThe development inhibitor releasing coupler is selected from a timed and non-timed development inhibitor releasing coupler.Type: GrantFiled: June 29, 1992Date of Patent: April 5, 1994Assignee: Eastman Kodak CompanyInventors: William J. Begley, Stephen P. Singer, David T. Southby, Donald, Jr. Singleton
-
Patent number: 5283162Abstract: There are described photographic elements containing novel release compounds which release a blocked photographically useful group, such as a blocked development inhibitor. The blocking group is removed during processing as a result of reaction with sulfite ion contained in one of the processing baths.Type: GrantFiled: May 29, 1992Date of Patent: February 1, 1994Assignee: Eastman Kodak CompanyInventors: Daniel L. Kapp, Wojciech Slusarek, David T. Southby
-
Patent number: 5270145Abstract: A process for forming a dye image including the steps of: (a) exposing a photographic element comprising a light sensitive silver halide emulsion layer containing a color coupler compound capable of forming a heat transferable dye upon development; (b) developing the exposed element resulting from step (a) with a color developer solution to form a heat transferable dye image; (c) heating the exposed, developed element resulting from step (b) to thereby transfer the dye image from the emulsion layer to a dye receiving layer which is part of the photographic element or part of a separate dye receiving element brought into contact with the photographic element; and (d) separating the emulsion layer from the dye receiving layer containing the transferred dye image; wherein the color coupler compound is of the following formula (I):COUP--B (I)wherein COUP represents a coupler moiety capable of forming a heat transferable dye upon reaction of the coupler compound with an oxidized product of the developing solutionType: GrantFiled: December 6, 1991Date of Patent: December 14, 1993Assignee: Eastman Kodak CompanyInventors: Roland G. Willis, John Texter
-
Patent number: 5262291Abstract: There are described color photographic elements containing novel release compounds which rapidly release a photographically useful group, such as a development inhibitor, from a timing group.Type: GrantFiled: July 30, 1992Date of Patent: November 16, 1993Assignee: Eastman Kodak CompanyInventors: Wojciech Slusarek, Daniel L. Kapp
-
Patent number: 5250398Abstract: A photographic silver halide material and process comprises at least one image dye-forming coupler and at least one coupler (A) represented by the formula SOL-COUP-LINK-PUG wherein SOL is a water solubilizing amide group, COUP is a naphtholic coupler moiety that, upon reaction with oxidized developer is capable of releasing LINK-PUG and capable of forming a compound that is washed out of the photographic material during photographic processing; LINK-PUG is in turn capable of releasing a photographically useful group (PUG) during photographic processing; and wherein LINK is a carbamate linking group comprising a photographic ballast group on the nitrogen atom of the carbamate group. Such a photographic silver halide material enables formation of improved images.Type: GrantFiled: June 28, 1991Date of Patent: October 5, 1993Assignee: Eastman Kodak CompanyInventors: William J. Begley, Teh-hsuan Chen
-
Patent number: 5250397Abstract: A method for processing a silver halide color photographic material is disclosed, which comprises: color developing a silver halide color photographic material with a color developer containing an aromatic primary amine color developing agent, followed by processing with a processing solution having a bleaching ability, wherein the replenishment rate of said color developer is in the range of 600 ml or less per m.sup.2 of the photographic material, and wherein said silver halide color photographic material contains at least one yellow colored cyan coupler.Type: GrantFiled: April 2, 1991Date of Patent: October 5, 1993Assignee: Fuji Photo Film Co., Ltd.Inventors: Katsushige Kamada, Keiji Mihayashi, Yoshihiro Fujita
-
Patent number: 5246820Abstract: A photographic element having improved granularity contains a dye-forming coupler containing a carbamic acid precursor capable of being converted into a carbamic acid group during processing, and wherein after processing the carbamic acid group decomposes, leaving the dye substantially non-diffusable.Type: GrantFiled: March 3, 1992Date of Patent: September 21, 1993Assignee: Eastman Kodak CompanyInventors: Jared B. Mooberry, James J. Seifert, Stephen P. Singer
-
Patent number: 5236804Abstract: A silver halide photographic light-sensitive material comprises a support having thereon photographic component layers including a silver halide emulsion layer, wherein at least one of said photographic component layers contains a compound represented by the following formula:A--(Time)n--FL--BLwherein A represents a group capable of releasing a group of --(Time)n--FL--BL upon reaction with an oxidation product of a developing agent; Time represents a timing group; FL represents a group which comes to emit fluorescence when a --BL is split off; BL represents a group capable of being split off; and n represents an integer of 0 or 1.Type: GrantFiled: February 26, 1991Date of Patent: August 17, 1993Assignee: Konica CorporationInventors: Shigeo Tanaka, Hirokazu Sato, Satoru Ikesu
-
Patent number: 5234800Abstract: A photographic naphtholic coupler comprising a ballast free naphtholic coupler moiety containing a --CONH.sub.2 group in the 2-position and a ballasted coupling-off group in the 4-position enables good wash out of dye formed upon oxidative coupling from a photographic material during processing of such a photographic material. Such a naphtholic coupler is useful in photographic silver halide materials and processes.Type: GrantFiled: July 22, 1991Date of Patent: August 10, 1993Assignee: Eastman Kodak CompanyInventors: William J. Begley, Teh-Hsuan Chen, Hans G. Ling
-
Patent number: 5204232Abstract: Disclosed is a light-sensitive silver halide photographic material having at least one silver halide emulsion layer on a support, characterized in that at least one layer of the above silver halide emulsion layers contains a compound represented by the following formula (I): ##STR1## wherein n represents 0 or 1; A represents a compound residue which cleaves a bonding to Time in the case of n=1 or a compound residue which cleaves one of bondings to FL in the case of n=0; Time represents a timing group which cleaves a bonding to FL after cleavage from A; and FL represents a compound residue which emits fluorescence by cleavage of a bonding to Time in the case of n=1 and a compound residue which emits fluorescence by cleavage of one of bondings to A in the case of n=0.Type: GrantFiled: March 11, 1991Date of Patent: April 20, 1993Assignee: Konica CorporationInventors: Hirokazu Sato, Shigeo Tanaka, Satoru Ikesu
-
Patent number: 5169749Abstract: The improved silver halide photographic material has a substantially colorless coupler that has a leaving group with a protected formyl group at the active site, said protected formyl group being such that subsequent to the elimination of the leaving group upon coupling reaction, the protective group for a formyl group undergoes cleavage, causing reaction with an aromatic primary amine to form a ballasted Schiff type dye. The novel substantially colorless coupler is capable of highly efficient dye formation.Type: GrantFiled: April 17, 1991Date of Patent: December 8, 1992Assignee: Konica CorporationInventors: Eisaku Katoh, Shuji Kida, Shuichi Sugita
-
Patent number: 5155004Abstract: A chitosan or chitin compound having a photographically useful residue. There is also disclosed a method for processing a silver halide photographic material which comprises processing a silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer in the presence of said chitosan or chitin compound represented by the following general formula (I) ##STR1## wherein the substituents are defined in the instant specification.Type: GrantFiled: March 13, 1991Date of Patent: October 13, 1992Assignee: Fuji Photo Film Co., Ltd.Inventor: Tetsuro Kojima
-
Patent number: 5151343Abstract: A photographic naphtholic coupler comprising a ballast free naphtholic coupler moiety containing a --CONH.sub.2 group in the 2- position and a ballasted coupling-off group in the 4- position enables good wash out of dye formed upon oxidative coupling from a photographic material during processing of such a photographic material. Such a naphtholic coupler is useful in photographic silver halide materials and processes.Type: GrantFiled: August 22, 1991Date of Patent: September 29, 1992Assignee: Eastman Kodak CompanyInventors: William J. Begley, Teh-hsuan Chen, Hans G. Ling, John W. Harder, Arlyce T. Bowne
-
Patent number: 5151356Abstract: A silver halide color photographic material comprising a support having provided thereon at least one water-soluble yellow dye-forming polymer coupler containing a repeating unit derived from at least one monomer in which the polymerization moiety is only in a coupling-off group.Type: GrantFiled: March 8, 1990Date of Patent: September 29, 1992Assignee: Fuji Photo Film Co., Ltd.Inventors: Kei Sakanoue, Tsumoru Hirano
-
Patent number: 5116717Abstract: A silver halide photographic material composed of a support having thereon at least one silver halide photosensitive emulsion layer, at least one layer of the material containing a blocked photographic reagent precursor represented by formula (I): ##STR1## wherein X.sub.1 represents a divalent linking group containing a hetero atom bonded to the carbon atom, provided that X.sub.1 is linked to the carbon atom by a group other than ##STR2## PUG represents a photographically useful group containing a hetero atom bonded to X.sub.1 ; W represents .dbd.N-- or ##STR3## Y.sub.1 represents hydrogen or a group capable of being substituted; Z represents an atomic group necessary for forming a heterocyclic ring, provided that when W represents a ##STR4## the group adjacent to W in the heterocyclic ring is a group other than ##STR5## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.Type: GrantFiled: February 25, 1991Date of Patent: May 26, 1992Assignee: Fuji Photo Film Co., Ltd.Inventors: Tetsunori Matsushita, Morio Yagihara
-
Patent number: 5112730Abstract: A silver halide color photographic material comprises a support having thereon at least one silver halide emulsion layer and at least one cyan coupler which can release a water-soluble compound residual group which contains a 2-acyaminophenylazo group or 2-sulfonamidophenylazo group via a coupling reaction with an oxidation product of a primary aromatic amine developing agent.Type: GrantFiled: December 5, 1990Date of Patent: May 12, 1992Assignee: Fuji Photo Film Co., Ltd.Inventors: Atsuhiro Ohkawa, Takayoshi Kamio, Masuzi Motoki, Keiji Mihayashi
-
Patent number: 5091291Abstract: A coupler having as a coupling-off group an alkyl group substituted with an electron source capable of stabilizing carbonium ion.Type: GrantFiled: October 25, 1990Date of Patent: February 25, 1992Assignee: Eastman Kodak CompanyInventors: Philip T. S. Lau, Danny R. Thompson
-
Patent number: 5064742Abstract: A dry image-forming process is disclosed which comprises transferring a mobile hydrophilic dye formed imagewise at exposure areas of a heat developable light-sensitive material comprising a support having thereon at least a light-sensitive silver halide, a hydrophilic binder, a reducing agent for the silver halide, and a non-diffusible 2-equivalent coupler by heating the light-sensitive material after imagewise exposure or simultaneously with imagewise exposure in the presence of a hydrophilic thermal solvent at a high temperature at which the hydrophilic thermal solvent is in a molten state without supplying a solvent from the outside, and fixing the dye in a dye-fixing layer.Type: GrantFiled: March 29, 1990Date of Patent: November 12, 1991Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiaki Aono, Koichi Nakamura
-
Patent number: 5051343Abstract: This invention relates to novel photographic dye-forming coupler compounds which are non-diffusible as incorporated in a photographic element, but which, during processing, are converted to a form which is removable from the element if the coupler compound has not reacted with oxidized silver halide color developing agent.Type: GrantFiled: June 16, 1989Date of Patent: September 24, 1991Assignee: Eastman Kodak CompanyInventors: Gregory J. Lestina, Jon D. Bass, John W. Harder, Stephen P. Singer
-
Patent number: 5026628Abstract: Photographic compound (A) capable of releasing a photographically useful group is represented by the formula: SOL-CAR-LINK-PUG wherein SOL is a water-solubilizing group; CAR is a carrier moiety that, upon reaction with oxidized developing agent, is capable of releasing LINK-PUG and capable of forming a compound that is washed out of the photographic element during photographic processing; LINK-PUG is in turn capable of releasing a photographically useful group (PUG) during photographic processing and LINK-PUG is represented by the formula: ##STR1## wherein X, R.sub.1, R.sub.2, R.sub.3, R.sub.4 and PUG are as defined in the application. The photographic compound (A) enables formation of easily removable compounds in photographic elements and processes that provide images having improved acutance.Type: GrantFiled: February 22, 1990Date of Patent: June 25, 1991Assignee: Eastman Kodak CompanyInventors: William J. Begley, Teh-Hsuan Chen, Kenneth N. Kilminster, Jerrold N. Poslusny, Wojciech Slusarek
-
Patent number: 4985336Abstract: A silver halide color photographic light-sensitive material is disclosed, comprising a support having provided thereon at least one red-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer and at least one blue-sensitive silver halide emulsion layer, wherein at least one red-sensitive silver halide emulsion layer and at least one green-sensitive silver halide emulsion layer each contains a precursor compound capable of releasing a compound upon reacting with an oxidation product of a developing agent, and said released compound is capable of releasing a development inhibitor upon further reacting with another molecule of the oxidation product of the developing agent. The material has improved sharpness and color reproducibility.Type: GrantFiled: January 6, 1989Date of Patent: January 15, 1991Assignee: Fuji Photo Film Co., Ltd.Inventors: Seiji Ichijima, Keiji Mihayashi
-
Patent number: 4975361Abstract: A color photographic light-sensitive material comprising a support having thereon at least one layer containing light-sensitive silver salt, wherein the color photographic a light-sensitive material contains at least one image forming compound represented by the following general formula (I):(Dye-X).sub.q -Y (I)wherein Dye, X, q and Y are described in detail below.Type: GrantFiled: December 21, 1988Date of Patent: December 4, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Kozo Sato, Hiroshi Hara
-
Patent number: 4948698Abstract: A heat-processible color photographic material having on a base support at least a light-sensitive silver halide, a reducing agent, a binder and a dye-providing material represented by the following general formula (1) in disclosed. where A is a coupler site capable of dye formation by entering into a coupling reaction with the oxidized product of the reducing agent; L is a divalent linkage grop binding to A at the active point of the coupler site represented by A; B is a ballast group having a sufficient molecular size or shape to render the dye-providing material of the general formula (1) substantially immobile during thermal development; Dye is a dye site, n is 1, 2 or 3, part of the coupler site A optionally serving as part of the dye site Dye.Type: GrantFiled: October 10, 1989Date of Patent: August 14, 1990Assignee: Konica CorporationInventor: Tawara Komamura
-
Patent number: 4857440Abstract: Photographic compound (A) capable of releasing a photographically useful group by means of intramolecular nucleophilic displacement exhibits increased resistance to hydrolysis when the compound contains in a coupling position a coupling-off group represented by the formula: ##STR1## wherein Q, R.sub.q, R.sub.1, R.sub.2, R.sub.3, n and PUG are as defined in the application. Such a compound (A) is useful in a photographic silver halide material and process.Type: GrantFiled: June 30, 1988Date of Patent: August 15, 1989Assignee: Eastman Kodak CompanyInventors: William J. Begley, Michael J. Carmody, John M. Buchanan
-
Patent number: 4857447Abstract: A silver halide color photographic light-sensitive material is disclosed, comprising (1) a coupler having a dye moiety, the maximum absorption wavelength of which is shifted to the shorter wavelength by a bond cleaving, directly or through a timing group, due to a coupling reaction with an oxidized product of an aromatic primary amine-based developing agent, and, as a result of the reaction, forming a compound having a dye portion which has the original maximum absorption wavelength before shifting; and (2) a compound releasing a development inhibitor directly or through a timing group upon reacting with the oxidized aromatic primary amine-based developing agent.Type: GrantFiled: May 28, 1986Date of Patent: August 15, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Koji Tamoto, Mitsunori Ono
-
Patent number: 4847188Abstract: A thermally developable light-sensitive material having at least a light-sensitive silver halide, a reducing agent, a binder and a dye-providing material on a support is disclosed. The dye-providing material is a compound that releases or forms a diffusible dye as a function of development and which has a group capable of reacting with the nucleophilic agent.Type: GrantFiled: February 1, 1988Date of Patent: July 11, 1989Assignee: Konica CorporationInventors: Tawara Komamura, Hidenobu Ohya
-
Patent number: 4847185Abstract: Photographic compounds capable of releasing a photographically useful group (PUG) by means of an intramolecular nucleophilic displacement provide increased image acutance when a coupling-off group in the coupling position of the compound is a group of the formula: ##STR1## wherein PUG is a photographically useful group; Q is N or C--R where R is hydrogen or a substituent that does not adversely affect imaging; and Z represents atoms completing a non-aromatic, heterocyclic ring. The photographic compounds are useful in photographic materials and processes.Type: GrantFiled: June 30, 1988Date of Patent: July 11, 1989Assignee: Eastman Kodak CompanyInventors: William J. Begley, Michael J. Carmody, John M. Buchanan
-
Patent number: 4842985Abstract: A conventional silver halide color photographic material is described, containing a coupler having a dye moiety having the maximum absorption wave length shifted to a short wave length by a linkage which is cleaved directly or through a timing group by a coupling reaction with the oxidation product of a developing agent and forming a compound or the precursor thereof (compound A) having a dye moiety having the maximum absorption wave length before shifting as the result of the above-described reaction and a compound capable of fixing the hue of the compound A at a long wave length and/or capable of immobilizing the compound A in the photographic layer.Type: GrantFiled: December 8, 1987Date of Patent: June 27, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Mitsunori Ono, Koji Tamoto, Keiji Mihayashi, Seiji Ichijima, Isamu Itoh, Yoshisada Nakamura
-
Patent number: 4842994Abstract: A silver halide photographic material is described, comprising a support having provided thereon at least one silver halide photographic emulsion layer and comprising a bleach accelerator-releasing coupler, wherein said bleach accelerator-releasing coupler is represented by formula (I)A--(TIME).sub.n --S--X--(Y).sub.m --(Z)l]a (I)wherein A represents a coupler residual group; TIME represents a timing group; n represents 0 or 1; X represents a cyclic aliphatic group or a saturated heterocyclic group; Y represents an aliphatic group having from 1 to 8 carbon atoms which may contain a group of --O--, a group of --S--, a group of --COO--, a group of --CO--, a group of ##STR1## a group of ##STR2## a group of --SO.sub.2 --or a group of ##STR3## in its chain; m represents an integer of from 0 to 3, and when m represents 2 or more, the two or more Y groups may be the same or different; Z represents a group of --OH, a group of --COOM, a group of --SO.sub.Type: GrantFiled: November 12, 1987Date of Patent: June 27, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Kei Sakanoue, Seiji Ichijima
-
Patent number: 4830957Abstract: A color light-sensitive material is disclosed. The material is comprised of a support having provided thereon at least one image-forming compound represented by formula (I)(Dye--X).sub.q Y (I)wherein X, Y, q, and Dye are as defined herein. The light-sensitive material shows excellent yellow dye-transferring properties and provides a yellow dye having excellent light fastness.Type: GrantFiled: October 7, 1987Date of Patent: May 16, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Kozo Sato, Masashi Takeuchi, Takeshi Shibata
-
Patent number: 4810615Abstract: Dye releasing compounds which release dyes corresponding to formula I ##STR1## wherein R.sup.1 denotes alkyl, aryl, arylamino, alkoxy or aryloxy,R.sup.2 denotes H or halogen,R.sup.3 denotes alkyl with 2-4 carbon atoms,R.sup.4 denotes H or one or more substituents such as alkyl, alkoxy, acylamino or halogen, including a substituent in the ortho-position to the group ##STR2## which together with R.sup.5 completes a cyclic amino group, R.sup.5 denotes alkyl with up to 4 carbon atoms or a group which together with a subsituent denoted by R.sup.4 or together with R.sup.6 completes a cyclic amino group, andR.sup.6 denotes alkyl with up to 4 carbon atoms or a group which together with R.sup.5 completes a cyclic amino groupare suitable for the production of light-stable cyan colour images.Type: GrantFiled: June 8, 1987Date of Patent: March 7, 1989Assignee: Agfa-Gevaert AktiengesellschaftInventors: Immo Boie, Hans Vetter, Kaspar Wingender
-
Patent number: 4804619Abstract: A silver halide color photographic material improved in image quality such as sharpness and graininess is disclosed. The silver halide color photographic material is comprises support having thereon photographic component layers comprising at least two silver halide emulsion layers, adjacently arranged to each other, having the same color sensitivity and different speed from each other. In this photographic material the highest speed layer among these emulsion layers contains a DIR compound capable of releasing a diffusible development inhibitor or a diffusible compound capable of releasing a development inhibitor, and the total thickness of the silver halide emulsion layers is within the range of from 1.5 .mu.m to 5 .mu.m, and the silver halide emulsion layers are allowed to have the interposition of a non-light-sensitive intermediate layer.Type: GrantFiled: October 23, 1987Date of Patent: February 14, 1989Assignee: Konica CorporationInventors: Yoshitaka Yamada, Masao Iwamura
-
Patent number: 4801520Abstract: A direct positive color light-sensitive material comprising a support having provided thereon at least one photographic emulsion layer containing unfogged internal latent image type silver halide particles and a color image forming coupler, wherein said color image forming coupler itself is substantially nondiffusible and produces or releases a dye upon oxidation coupling with a color developing agent, and said light-sensitive material contains at least one development inhibitor-releasing type coupler selected from the group consisting of compounds represented by formulae (D-I) and (D-II)Coup--Z (D-I)Coup--TIME--Z (D-II)wherein Coup represents a coupler residual group; Z represents a diffusible development inhibitor or a precursor thereof; and TIME represents a timing group.Type: GrantFiled: July 17, 1987Date of Patent: January 31, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Noriyuki Inoue, Tatsuo Heki
-
Patent number: 4777120Abstract: A photographic masking coupler containing in the coupling position a coupling-off group that is capable of reacting with oxidized color developing agent to form a water-insoluble dye in non-image areas and a water-soluble compound in image areas of a color photographic element enables formation of a colored integral mask for color correction upon exposure and processing of the element. The masking couplers are essentially colorless in a color photographic element. Such a photographic masking coupler is advantageous in a color photographic element and process.Type: GrantFiled: May 18, 1987Date of Patent: October 11, 1988Assignee: Eastman Kodak CompanyInventor: Philip T. S. Lau
-
Patent number: 4774181Abstract: An imaging element is described which comprises a dye image-forming coupler compound and a compound capable of releasing a fluorescent dye as a function of silver halide development. The released dye is capable of fluorescence which optically compensates for unwanted absorption of an image dye thereby resulting in color correction of the image.Type: GrantFiled: June 25, 1987Date of Patent: September 27, 1988Assignee: Eastman Kodak CompanyInventors: Nair N. Ravindran, Ramanuj Goswami
-
Patent number: 4772542Abstract: A silver halide photographic material is disclosed. The material has at least one silver halide emulsion layer on a support, said silver halide emulsion layer containing a coupler which forms a mobile dye by coupling reaction with the oxidized product of a color developing agent, and said silver halide emulsion layer having in association therewith a non-light sensitive layer containing substantially non-light sensitive fine silver halide grains.Type: GrantFiled: September 11, 1987Date of Patent: September 20, 1988Assignee: Konishiroku Photo Industry Co., Ltd.Inventor: Yoshihiro Haga
-
Patent number: 4764454Abstract: A novel silver halide color photographic material is provided comprising a compound of the general formula (I):LIG-A-LVG (I)wherein A represents a group which reacts with an oxidation product of a developing agent to cleave the bond to LVG; LVG represents a coupling-off group; and LIG represents a group which reacts with metal ions to form a complex compound.A novel method of processing the instant silver halide color photographic material is provided including a processing step using a processing solution of an iron (II) ion concentration of 1.times.10.sup.-6 to 1 mol/l. In the processing step, the potential of a bath having a bleaching capacity containing an aminopolycarboxylic acid-iron (III) complex salt is 150 mV or less.Type: GrantFiled: December 18, 1986Date of Patent: August 16, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Seiji Ichijima, Kei Sakanoue
-
Patent number: 4749641Abstract: An imaging element is described which comprises a colorless coupler compound which contains an oxidizable lueco dye moiety and optionally a colorless dye image-forming coupler compound. Following color development a masking dye is obtained by oxidation of the leuco dye moiety in areas where no photographic development occurs.Type: GrantFiled: September 15, 1986Date of Patent: June 7, 1988Assignee: Eastman Kodak CompanyInventors: John E. Kaufman, Max H. Stern
-
Patent number: 4725531Abstract: A photographic light-sensitive material comprising a support having thereon at least one light-sensitive silver halide emulsion layer having associated therewith a compound represented by formula (I) ##STR1## wherein Q represents a cyano group, a trifluoromethyl group, or a carbamoyl group represented by the formula --CONR.sup.1 R.sup.2 (wherein R.sup.1 represents a hydrogen atom, an alkyl group, or a substituted alkyl group, and R.sup.2 represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aralkyl group, or an aryl group, or R.sup.1 and R.sup.2 may combine directly or through an oxygen atom to form a ring); M represents an alkyl group, a substituted alkyl group, an alkoxy group, a substituted alkoxy group, or a halogen atom; E.sup.Type: GrantFiled: May 2, 1986Date of Patent: February 16, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Toru Harada, Masaharu Toriuchi
-
Patent number: 4724198Abstract: There is disclosed a light-sensitive silver halide color photographic material having red-sensitive, green-sensitive and blue-sensitive emulsion layers, each layer consisting of two or more layers with different sensitivities on a support, wherein the layers are constituted so as to satisfy the following requirements (A), (B), (C) and (D):(A) of the respective emulsion layers having the highest sensitivities among the the red-sensitive, green-sensitive and blue-sensitive emulsion layers, the highest sensitivity blue-sensitive emulsion layer is provided on the side farthest from the support;(B) at least the the highest sensitivity red-sensitive emulsion layer and the highest sensitivity green-sensitive emulsion layer are provided between the the highest blue-sensitive emulsion layer and a blue-sensitive emulsion layer with lower sensitivity;(C) none of the respective red-sensitive, green-sensitive and blue-sensitive emulsion layers having the lowest sensitivities exists on the side farther than the low sensitiType: GrantFiled: December 15, 1986Date of Patent: February 9, 1988Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Yoshitaka Yamada, Toshifumi Iijima, Kenji Kumashiro, Takashi Kamio, Shinya Shimura
-
Patent number: 4698297Abstract: A silver halide color photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, the color photographic light-sensitive material containing a compound capable of releasing a group represented by the general formula (I) described below upon the reaction with the oxidation product of a developing agent: ##STR1## wherein W and Z each represents an oxygen atom, a sulfur atom or a group of ##STR2## X.sub.1, X.sub.2, X.sub.3, X.sub.4 and X.sub.5 each represents a hydrogen atom or an organic residue; PUG represents a photographically useful group; n represents 1 or 2; any two of X.sub.1, X.sub.2, X.sub.3, X.sub.4, X.sub.5 and PUG each represents a divalent group and may be connected to each other to form a cyclic structure; and when n represents 2, two Z's, two X.sub.3 's and two X.sub.4 's may be the same or different.Type: GrantFiled: May 28, 1985Date of Patent: October 6, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Seiji Ichijima, Noboru Sasaki
-
Patent number: 4650748Abstract: A heat-developable color photo-sensitive material having a support. On the support, there is a photographic component layer containing at least a photo-sensitive silver halide, a reducing agent, a binder and a dye-providing material. At least one of the dye-providing materials in the photo-sensitive material is a polymer having a unit derived from a monomer represented by Formula I.Type: GrantFiled: December 23, 1985Date of Patent: March 17, 1987Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Tawara Komamura, Hidenobu Ohya
-
Patent number: 4631251Abstract: In a heat-developable color photo-sensitive material comprising a support bearing thereon a photographic component layer containing at least a photo-sensitive silver halide, a reducing agent, a binder and a dye-providing material; said heat-developable photo-sensitive material characterized in that at least one of said dye-providing materials is a polymer having a repetition unit being derived from a monomer Formula [I] below: ##STR1## wherein , Q represents an ethylene unsaturated group or a group having an ethylene unsaturated group; Z represents a group of atoms required for forming a nitrogen-containing heterocyclic residual group in which a polymerizable ethylene unsaturated bonding may also be incorporated into the heterocyclic ring, together with a nitrogen atom; R.sub.1 represents an alkyl, aryl, alkylamino, anilino, acylamino or ureido group; Ar represents an aryl group or a heterocyclic residual group; and n is an integer of zero or one.Type: GrantFiled: August 30, 1985Date of Patent: December 23, 1986Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Tawara Komamura, Shunji Suginaka, Kimie Tachibana
-
Patent number: 4563412Abstract: Diffusion transfer photographic color products and processes are described in which there are utilized novel chrome complexed neutral tone black image dye-providing materials which include either a 1-naphthol-2'-naphthol-1', 2-azo dye moiety or a 2-naphthol-2'naphthol-1, 1'-azo dye moiety, a parasubstituted phenyl azo-pyrazolone dye moiety and a cation. The image dye-providing material includes a diffusion control moiety such as a hydroquinonyl group or a precursor thereof and may be diffusible or nondiffusible as a function of the diffusion control moiety.Type: GrantFiled: September 26, 1984Date of Patent: January 7, 1986Assignee: Polaroid CorporationInventors: Patrick F. King, Stephen G. Stroud
-
Patent number: 4557998Abstract: Essentially colorless, hydrophilic ligand-releasing polymers are prepared from ethylenically unsaturated polymerizable monomers represented by the structure: ##STR1## wherein R' is hydrogen or lower alkyl, COUP is a photographic color coupling moiety, LINK is a coupling-off group which can be cleaved by an oxidized developer composition, and LIG is a ligand capable of complexing with metal ions, while joined to the polymer, to form a dye. These polymers also have recurring units which impart hydrophilicity to the polymer. These polymers form metal complex dyes in unexposed areas of photographic elements only, while the ligand is cleaved from the polymer in the exposed areas and washed out of the element.Type: GrantFiled: January 2, 1985Date of Patent: December 10, 1985Assignee: Eastman Kodak CompanyInventors: William N. Washburn, Kenneth R. Hollister
-
Patent number: 4555478Abstract: A process of obtaining highly stable color images comprises use of an element which has a support having thereon at least one silver halide emulsion layer having associated therewith an essentially colorless, immobile, ligand-releasing compound of the structure LIG-X. In this structure, LIG is a ligand which is capable of complexing with metal ions (e.g. ferrous ions) to form a metal complex dye, and X is a group which, as a function of silver halide development, is cleaved from LIG. A color image is formed by developing the described element after imagewise exposure with a developing agent to imagewise cleave the bond between the LIG and X, and treating the developed element with metal ions (e.g. ferrous ions) to form a metal complex dye image.Type: GrantFiled: January 2, 1985Date of Patent: November 26, 1985Assignee: Eastman Kodak CompanyInventors: James A. Reczek, Janice M. Palumbo
-
Patent number: 4548888Abstract: Photographic elements, diffusion transfer assemblages, coordination complexes and processes are described which employ a novel nondiffusible hydrazone compound capable of releasing at least one diffusible yellow dye or dye precursor thereof having the formula: ##STR1## wherein: (a) Z.sup.1 and Z.sup.2 each independently represents the atoms necessary to complete a 5- or 6-membered aromatic heterocyclic ring;(b) CAR represents a ballasted carrier moiety capable of releasing the diffusible yellow dye moiety or precursor thereof as a function of development;(c) R represents hydrogen, an alkyl or substituted alkyl group of from 1 to about 12 carbon atoms, an aryl or substituted aryl group of from about 6 to about 12 carbon atoms, a substituted or unsubstituted 5- or 6-membered aromatic heterocyclic ring, or CAR, and(d) n is 0, 1 or 2, with the proviso that when n is 0, then R is CAR.Type: GrantFiled: November 7, 1984Date of Patent: October 22, 1985Assignee: Eastman Kodak CompanyInventor: Michael W. Crawley