Processing With Identified Silver Or Silver Salt Complexing Agent Patents (Class 430/251)
  • Patent number: 6284426
    Abstract: The present invention provides an alkaline processing solution comprising at least one silver halide solvent other than sulfite, characterized in that said alkaline processing solution further contains aluminium ions in an amount of at least 0.3 g/l. There is further provided a method for making a lithographic printing plate according to the DTR-process using an aqueous alkaline processing solution in the presence of at least one developing agent and at least one silver halide solvent, characterized in that said alkaline processing solution contains aluminium ions in an amount of at least 0.3 g/l.
    Type: Grant
    Filed: April 22, 1996
    Date of Patent: September 4, 2001
    Assignee: Agfa-Gevaert
    Inventors: Paul Coppens, Ludo Vervloet
  • Patent number: 6174643
    Abstract: It is disclosed a process for developing a lithographic printing material having physical development nuclei between an aluminum support and a silver halide emulsion layer containing 95 mole % or more of silver chloride based on the total amount of the silver halide, when development of the lithographic printing material is carried out by using a developing solution having a pH of 13.0 at a development temperature of 25° C. and a development time of 40 seconds, a decreased amount of aluminum oxide in the aluminum support is 0.8 g or more per 1 m2 of the support, the improvement wherein the process for developing a lithographic printing plate comprises subjecting to development so as to control the decreased amount of the aluminum oxide being 0.6 g or less per 1 m2 by adjusting at least one of the pH of the developing solution, the development temperature and the developing time.
    Type: Grant
    Filed: March 24, 1999
    Date of Patent: January 16, 2001
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Hideo Kiyoyama, Kimihisa Hamazoe, Toshiro Kondo
  • Patent number: 6162575
    Abstract: There is disclosed a process for making a lithographic printing plate, which comprises subjecting a lithographic printing material having physical development nuclei between an anodized aluminum support and a silver halide emulsion layer to exposure and then processing the lithographic printing material at least with a developing solution, wherein the developing solution contains an alkaline earth metal.
    Type: Grant
    Filed: October 22, 1999
    Date of Patent: December 19, 2000
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Hajime Fujioka, Toshiro Kondo
  • Patent number: 6083668
    Abstract: Disclosed is a processing element which includes a silver halide solvent represented by a general formula (1) and which has a function of efficiently fixing undeveloped silver halide remaining in a photosensitive element after developing without any harmful influence, and an image-forming method using the processing element, the general formula (1) being ##STR1## wherein R.sub.1 and R.sub.2 each represent an aliphatic hydrocarbon group.
    Type: Grant
    Filed: March 31, 1999
    Date of Patent: July 4, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazuhiko Matsumoto, Masaru Yoshikawa
  • Patent number: 6063540
    Abstract: Provided is a method for making a lithographic printing plate in which the development is carryied out by coating a developer on a photosensitive element comprising a support and at least a silver halide emulsion layer and a physical development nuclei layer, characterized in that coating amount of the developer is 60 ml or less for 1 m.sup.2 of the photosensitive element, and the developer contains at least one thioether compound and at least one alkanolamine compound as silver halide solvents. The resulting lithographic printing plate is high in printing endurance and has no stains in non-image portions. Furthermore, the running development processing can be stably carried out.
    Type: Grant
    Filed: April 6, 1998
    Date of Patent: May 16, 2000
    Inventors: Hiroyuki Kurokawa, Toshiro Kondo
  • Patent number: 6060209
    Abstract: There is disclosed a process for making a lithographic printing plate having physical development nuclei between an aluminum support and a silver halide emulsion layer to which, after exposure, a treatment using at least a developing solution, a washing solution and a finishing solution is applied in this order,the improvement wherein at least one of the above processing solutions contains at least one compound selected from the groups (A) and (B) mentioned below:(A) at least one compound selected from the group consisting of an amine compound having a propyleneoxy group and an ethyleneoxy group, an aliphatic acid amide compound having a propyleneoxy group and an ethyleneoxy group, and a quaternary ammonium compound having a propyleneoxy group and an ethyleneoxy group; and(B) at least one compound selected from the group consisting of urea and a derivative thereof.
    Type: Grant
    Filed: November 24, 1998
    Date of Patent: May 9, 2000
    Inventors: Toshiro Kondo, Hajime Fujioka, Yoshihito Ohashi
  • Patent number: 5843628
    Abstract: A color image formation method excellent in discrimination and color image stability after processing which comprises overlaying a heat developable color light-sensitive material with a complexing agent sheet in the presence of a small amount of water therebetween after or during imagewise exposure, said light-sensitive material comprising a support having provided thereon at least a light-sensitive silver halide, a binder, a coupler, a reducing agent and a slightly-water-soluble basic metal compound, said sheet comprising a support having provided thereon at least a compound forming a complex with a metal ion constituting said basic metal compound; and heat developing the light-sensitive material to obtain a color image thereon, wherein the silver chloride content of said silver halide is 80 mol % or more, said complexing agent sheet comprises a physical development nucleus and a solvent for a silver halide, and said reducing agent is at least one compound of specified phenols, hydrazines and hydrazones.
    Type: Grant
    Filed: November 15, 1996
    Date of Patent: December 1, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiki Taguchi, Kiyoteru Miyake
  • Patent number: 5716755
    Abstract: The present invention provides a method for making a lithographic printing plate from an original containing continuous tones comprising the steps of:frequency modulation screening said original to obtain screened dataimage-wise exposing according to said screened data an imaging element comprising in the order given on a hydrophilic surface of a support (i) an image receiving layer containing physical development nuclei, (ii) a photosensitive layer containing one or more silver halide emulsions being in water permeable relationship with said image receiving layerapplying an aqueous alkaline solution to the imaging element in the presence of (a) developing agent(s) and (a) silver halide solvent(s),treating the imaging element to remove the layer(s) on top of said image receiving layer, thereby uncovering said silver image formed in said image receiving layer,characterized in that said aqueous alkaline solution is substantially free from thiosulphate ions and bromide ions and contains an aminoalcohol in an amo
    Type: Grant
    Filed: December 4, 1996
    Date of Patent: February 10, 1998
    Assignee: AGFA-Gevaert, N.V.
    Inventor: Ludo Van Rompuy
  • Patent number: 5695916
    Abstract: A thickened processing solution containing inert particles can be used in lamination processing to insure even processing.
    Type: Grant
    Filed: August 8, 1996
    Date of Patent: December 9, 1997
    Assignee: Eastman Kodak Company
    Inventor: John Richard Fyson
  • Patent number: 5693448
    Abstract: The present invention provides a method for making an offset printing plate according to the silver salt diffusion transfer process comprising the steps of:image-wise exposing an imaging element comprising in the order given on a hydrophilic surface of a support (i) an image receiving layer containing physical development nuclei and (ii) a photosensitive layer comprising a photosensitive silver halide emulsion said photosensitive layer being in water permeable relationship with said image receiving layer,applying an aqueous alkaline solution to the imaging element in the presence of (a) developing agent(s) and (a) silver halide solvent(s) to form a silver image in said image receiving layer,treating the imaging element to remove the layer(s) on top of the image receiving layer, thereby exposing the imaged surface of the support by uncovering said silver image formed in said image receiving layer,characterized in that said aqueous alkaline solution comprises less than 0.
    Type: Grant
    Filed: October 23, 1996
    Date of Patent: December 2, 1997
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Paul Coppens, Ludovicus Vervloet, Eric Hoes, Ludo Van Rompuy
  • Patent number: 5677105
    Abstract: The present invention provides a method for making a lithographic printing plate according to the silver salt diffusion transfer process comprising the steps of:image-wise exposing an imaging element comprising in the order given on a hydrophilic surface of a support (i) an image receiving layer containing physical development nuclei and (ii) a photosensitive layer comprising one or more silver halide emulsions being in water permeable relationship with said image receiving layer(b) applying an aqueous alkaline solution to the imaging element in the presence of (a) developing agent(s) and (a) silver halide solvent(s) to form a silver image in said image receiving layer, (c) treating the imaging element to remove the layer(s) on top of said image receiving layer, thereby uncovering said silver image formed in said image receiving layer,characterized in that said aqueous alkaline solution contains thiosulphate salts in an amount ranging from 0.000 mole/l to 0.
    Type: Grant
    Filed: December 16, 1996
    Date of Patent: October 14, 1997
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Ludo Van Rompuy, Paul Coppens
  • Patent number: 5677104
    Abstract: An image formation method is described, which comprises overlaying a silver halide light-sensitive material with a sheet after or during imagewise exposure, the light-sensitive material comprising a support having provided thereon at least a light-sensitive silver halide mainly comprising silver chloride, a hydrophilic binder, a reducing agent and a slightly water-soluble basic metal compound, the sheet comprising a support having provided thereon at least a compound forming a complex with a metal ion constituting said basic metal compound, a physical development nucleus, and a compound represented by the following formula (I) or a compound containing a sulfite ion; and heat-developing the material in the presence of water to form a silver image on at least one of the light-sensitive material and the sheet: ##STR1## wherein Q represents an atomic group necessary to form a 5- or 6-membered imide ring.
    Type: Grant
    Filed: December 27, 1995
    Date of Patent: October 14, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Hirai, Hiroshi Hara, Kiyoteru Miyake
  • Patent number: 5645971
    Abstract: The present invention provides a method for making a lithographic printing plate according to the silver salt diffusion transfer process comprising the steps of image-wise exposing an imaging element comprising on a support a photosensitive layer comprising a silver halide emulsion and an image receiving layer containing physical development nuclei and developing said imaging element in the presence of developing agent(s) and silver halide solvent(s) using an alkaline processing liquid characterized in that said development is carried out in the presence of a meso-ionic compound. The present invention further provides an imaging element and alkaline processing liquid for use in said method.
    Type: Grant
    Filed: June 20, 1996
    Date of Patent: July 8, 1997
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Ludo Van Rompuy, Rene De Keyzer, Jean-Marie Dewanckele, Marcel Monbaliu, Jos Vaes
  • Patent number: 5620829
    Abstract: The present invention provides a method for making a lithographic printing plate according to the silver salt diffusion transfer process comprising the steps of image-wise exposing an imaging element comprising on a support a photosensitive layer comprising silver halide emulsion(s) wherein less than 1 mole % of the silver halide is silver bromide and an image receiving layer containing physical development nuclei and developing said imaging element using an alkaline processing liquid with a pH lower than 11.5 in the presence of developing agent(s) and a meso-ionic compound.
    Type: Grant
    Filed: June 27, 1995
    Date of Patent: April 15, 1997
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Lode Deprez
  • Patent number: 5607811
    Abstract: The present invention provides a method for making a lithographic printing plate according to the silver salt diffusion transfer process comprising the steps of:image-wise exposing an imaging element comprising on a support in the order given a photosensitive layer comprising a silver halide emulsion and an image receiving layer containing physical development nuclei in water permeable relationship with said emulsion layer,developing said imaging element by means of an alkaline developing solution comprising at least 0.1 mole/l of ascorbic acid as the main developer and at least 0.015 mole/l of an auxiliary developer of the class of the 1-phenyl-3-pyrazolidones in the presence of silver halide solvent(s) characterized in that said developing solution comprises at least 0.003 mole/l of thiosulfate.
    Type: Grant
    Filed: December 8, 1995
    Date of Patent: March 4, 1997
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Jos Vaes, Luc Wabbes
  • Patent number: 5536618
    Abstract: The present invention provides a method for making a lithographic printing plate according to the silver salt diffusion transfer process comprising the steps of exposing and developing an imaging element comprising on a support a silver halide emulsion layer and an image-receiving layer in the presence of a silver halide solvents corresponding to the following formula:Z.sup.1 --(R.sup.1 --X.sup.1).sub.n --(R.sup.2 --X.sup.2)--L--(X.sup.3 --R.sup.3)--(X.sup.4 --R.sup.4).sub.m --Z.sup.2 (I)wherein X.sup.1, X.sup.2, X.sup.3 and X.sup.4 each independently represents --S--, --NH-- or --N(R.sup.5 --Z.sup.3)--, R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 each independently represents an alkylene, an alkenylene or an alkynylene, n and m each independently represents an integer from 0 to 4, Z.sup.1, Z.sup.2 and Z.sup.
    Type: Grant
    Filed: February 27, 1995
    Date of Patent: July 16, 1996
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Rene De Keyzer, Paul Callant, Jean-Marie Dewanckele, Marcel Monbaliu
  • Patent number: 5472822
    Abstract: A lithographic printing plate is prepared from a silver halide photosensitive material in accordance with a silver complex diffusion transfer process. The photosensitive material is exposed and developed with a diffusion transfer processing solution containing a mesoionic compound as a silver halide complexing agent. The printing plate has good ink receptivity and minimized plate wear. The processing solution is free from the problems of corrosion and waste solution disposal.
    Type: Grant
    Filed: October 1, 1992
    Date of Patent: December 5, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Katsumi Hayashi
  • Patent number: 5449585
    Abstract: The present invention provides a method for making an offset printing plate according to the silver salt diffusion transfer process having improved printing properties comprising the step of developing an imaging element comprising in the order given (i) a hydrophilic base, (ii) an image receiving layer containing physical development nuclei and (iii) a photosensitive layer containing a silver halide emulsion in the presence of a 1-phenyl-5-mercapto-tetrazole, being substituted by one or two substituents from the group consisting of:(i) a --COOM group with M representing hydrogen, a metal cation, or an ammonium group,(ii) a --SO.sub.3 M.sup.1 group, M.sup.1 representing hydrogen, a metal cation, or an ammonium group,(iii) an acylamido group,(iv) and a substituent containing at least one of the aforementioned substituents (i)-(iv).
    Type: Grant
    Filed: June 29, 1994
    Date of Patent: September 12, 1995
    Assignee: Agfa-Gevaert
    Inventors: Paul Coppens, Ludovicus Vervloet, Eric Hoes
  • Patent number: 5432042
    Abstract: The present invention provides a method for making a lithographic printing plate according to the silver salt diffusion transfer process using a photographic material comprising on a support a silver halide emulsion layer and a layer containing physical development nuclei comprising the steps of:image-wise exposing said photographic material anddeveloping a thus obtained image-wise exposed photographic material by guiding said image-wise exposed photographic material through an alkaline processing liquid in 15 s or less; characterized in that said alkaline processing liquid comprises a hydrophobizing compound having a mercapto group that has a pK.sub.a of 4.5 or less.
    Type: Grant
    Filed: May 25, 1994
    Date of Patent: July 11, 1995
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Lode Deprez, Jos Vaes, Paul Gestels
  • Patent number: 5391457
    Abstract: A lithographic printing plate is prepared from a photosensitive material comprising a silver halide emulsion layer and a physical development nucleus layer on a support in accordance with a silver complex diffusion transfer process. The photosensitive material is diffusion transfer processed in the presence of both a triazole, oxadiazole or similar compound and an organic thioether compound. The printing plate has good ink receptivity and minimized plate wear. The processing solution is free from the problems of corrosion and waste solution disposal.
    Type: Grant
    Filed: November 3, 1992
    Date of Patent: February 21, 1995
    Assignee: Fuji Photo Film Co., Ltd
    Inventor: Katsumi Hayashi
  • Patent number: 5387483
    Abstract: Lithographic printing material is processed with a developer at pH 10.0 to 11.8 containing 30 to 80 gram/liter of hydroquinone in accordance with a diffusion transfer process. The developer is capable and stable. The resulting transfer silver image has improved printing endurance and ink receptivity.
    Type: Grant
    Filed: December 3, 1993
    Date of Patent: February 7, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yoshihiro Takagi
  • Patent number: 5348836
    Abstract: The present invention provides a photographic material comprising on a support photosensitive silver halide particles, and substantially light insensitive silver salt particles having a speed at least a factor 10 less under the same conditions of exposure and development of said photosensitive silver halide particles than said photosensitive silver halide particles and a releasing compound of formula (I) or (II) as specified in the claims capable of image-wise releasing sulphide or a sulphide under conditions for image-wise development of said photosensitive silver halide particles to silver. The present invention further provides a method for obtaining an image and a lithographic printing plate with said photographic material.
    Type: Grant
    Filed: April 22, 1993
    Date of Patent: September 20, 1994
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Ludo Van Rompuy, Jean-Marie Dewanckele
  • Patent number: 5340705
    Abstract: An aqueous alkaline processing liquid for use in silver halide photography, wherein said liquid comprises one or more alkanolamines, the said alkanolamines consisting of one or more tertiary alkanolamines in a total amount in the range from 0.3 mol/l to 1.5 mol/l, and one or more secondary alkanolamines in an amount from 0 mol % to 30 mol % with respect to the amount of tertiary alkanolamine(s), and said liquid also contains sulphite ions in an amount in the range of 16 g/l to 30 g/l.
    Type: Grant
    Filed: March 2, 1993
    Date of Patent: August 23, 1994
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Rene De Keyzer, Raymond L. Odeurs, Luc A. De Brabandere
  • Patent number: 5340690
    Abstract: According to the present invention there is provided a method for making a lithographic printing plate according to the DTR-process comprising the steps of:information-wise exposing an imaging element comprising on a support a silver halide emulsion layer and an image-receiving layer containing physical development nuclei anddeveloping said information-wise exposed imaging element with an alkaline processing liquid in the presence of developing agent(s) and silver halide solvent(s) characterized in that said silver halide solvents comprise a combination of (an) alkanolamine(s) and a thiosulfate wherein said thiosulfate is used in a total amount between 0.01% and 1% by weight in said alkaline processing liquid.
    Type: Grant
    Filed: March 15, 1993
    Date of Patent: August 23, 1994
    Assignee: Agfa-Gavaert, N.V.
    Inventors: Rene M. De Keyzer, Jean-Marie O. Dewanckele, Ludo L. Van Rompuy, Jos A. Vaes
  • Patent number: 5324622
    Abstract: The present invention provides a photographic material comprising on a support (i) photosensitive silver halide particles, (ii) substantially light insensitive silver salt particles having a speed at least a factor 10 less than said photosensitive silver halide particles under the same conditions of exposure and development of said photosensitive silver halide particles and (iii) a releasing compound capable of image-wise releasing under the conditions for image-wise development of said photosensitive silver halide to silver a chemical sensitizer, said chemical sensitizer rendering said substantially light insensitive silver salt particles developable. The present invention also provides a method for making an image therewith and a method for making a lithographic printing plate.
    Type: Grant
    Filed: July 29, 1992
    Date of Patent: June 28, 1994
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Ludo L. Van Rompuy, Jean-Marie O. Dewanckele, Jos A. Vaes, Marcel J. Monbaliu
  • Patent number: 5283156
    Abstract: The present invention provides a method for making a lithographic printing plate according to the silver salt diffusion transfer process comprising the steps of image-wise exposing an imaging element comprising on a support a photosensitive layer comprising a silver halide emulsion and an image receiving layer containing physical development nuclei and developing said imaging element in the presence of developing agent(s) and silver halide solvent(s) using an alkaline processing liquid characterized in that said development is carried out in the presence of a regulator according to one of the formulas as specified in the claims. The present invention further provides an imaging element and alkaline processing liquid for use in said method.
    Type: Grant
    Filed: December 4, 1992
    Date of Patent: February 1, 1994
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Marcel Monbaliu, Rene De Keyzer, Jean-Marie Dewanckele, Jos Vaes, Ludo Van Rompuy
  • Patent number: 5283157
    Abstract: A method for making a lithographic printing plate which comprises the steps of A) imagewise exposing a light sensitive material which comprises a support, a negative working silver halide emulsion layer and a surface physical development nucleating layer on said support, and B) processing the exposed material in a silver complex diffusion transfer developer containing a water soluble iodide to produce a non-black oleophilic silver image on the surface of said printing plate.
    Type: Grant
    Filed: March 22, 1993
    Date of Patent: February 1, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Paul Davies
  • Patent number: 5268253
    Abstract: The present invention provides a method for making a lithographic printing plate according to the DTR-process comprising the steps of:information-wise exposing an imaging element comprising on a support in the order given a photosensitive layer containing a silver halide emulsion and a layer containing physical development nuclei;developing said information-wise exposed imaging element in the presence of developing agent(s) and silver halide solvent(s)characterized in that said silver halide emulsion comprises said silver halide in an amount of at least 2 g/m.sup.2 (expressed as AgNO.sub.3), said development is carried out in the presence of a physical development restraining compound and wherein imaging elements comprising a positive working silver halide emulsion of the internal latent image type are excluded. Lithographic printing plates with substantially improved printing endurance are obtained.
    Type: Grant
    Filed: January 27, 1993
    Date of Patent: December 7, 1993
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Ludo Van Rompuy
  • Patent number: 5258258
    Abstract: Disclosed is a processing solution used for making lithographic printing plates by silver complex diffusion transfer process which contains at least one thioether derivative represented by the following formulas (I), (II) and (III): ##STR1## wherein n.sub.1 and n.sub.2 each represents 0, 1 or 2 and R.sub.1 and R.sub.2 each represents an alkylene group of 1-5 carbon atoms, ##STR2## wherein R.sub.1 represents an alkylene group of 1-5 carbon atoms, X represents a hydrogen atom, a carboxy group, an alkoxycarbonyl group, a carbamoyl group, a hydroxy group, or --OR.sup.2 in which R.sup.2 has the same meaning as --R.sub.1 --S).sub.n CH.sub.2 CH.sub.2 OH above, and n represents 0, 1 or 2, ##STR3## wherein X' represents an aromatic or heterocyclic group which has a carboxy group, R.sub.1 and R.sub.2 each represents an alkylene group of 1-5 carbon atoms and n represents 0, 1, 2 or 3.
    Type: Grant
    Filed: October 10, 1991
    Date of Patent: November 2, 1993
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Eiji Matsubara, Hidetoshi Miura, Takimi Hashimoto
  • Patent number: 5204212
    Abstract: An aqueous alkaline processing liquid suitable for use in the silver complex diffusion transfer reversal (DTR-) process, wherein said liquid contains 3-(N,N-diethylamino)propane-1,2-diol and contains phosphate ions in a concentration of not more than 0.03 mol/l.
    Type: Grant
    Filed: December 27, 1991
    Date of Patent: April 20, 1993
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Jean-Pierre D. Tahon
  • Patent number: 5200295
    Abstract: A method for the production of a silver image by the silver complex diffusion transfer reversal process, said method comprising the following steps:(I) image-wise photo-exposing a silver halide emulsion layer of a photographic silver halide emulsion having in waterpermeable relationship with the silver halide at least one developing agent,(II) wetting with a practically neutral aqueous liquid the said photo-exposed silver halide emulsion layer and/or wetting with said liquid a development nuclei containing layer of an image-receiving material as defined hereinafter and contacting said materials thereby bringing said layers into waterpermeable relationship with each other, and(III) separating the contacted materials after formation in the image-receiving material of a silver image,wherein said image-receiving material contains in co-operable relationship: (i) physical development nuclei, (ii) a silver halide solvent being a silver complexing agent or precursor thereof, (iii) a watersoluble sulfite or sulfite p
    Type: Grant
    Filed: December 10, 1991
    Date of Patent: April 6, 1993
    Assignee: AGFA-Gevaert N.V.
    Inventors: Leon L. Vermeulen, Robert S. Pauwels, Jean-Marie O. Dewanckele
  • Patent number: 5200294
    Abstract: According to the present invention there is provided a method for making a lithographic printing plate according to the DTR-process comprising the steps of:information-wise exposing an imaging element comprising on a support a silver halide emulsion layer and an image-receiving layer containing physical development nuclei anddeveloping said information-wise exposed imaging element with an alkaline processing liquid in the presence of developing agent(s), silver halide solvent(s) and hydrophobizing agent(s) characterized in that said hydrophobizing agent(s) are present in said alkaline processing liquid in a total amount of at least 0.1 g/l and wherein at least one of said silver halide solvents is a compound corresponding to the following formula:Z--(R.sup.1 --S).sub.t --R.sup.2 --S--R.sup.3 --Y (I)wherein Z and Y each independently represents hydrogen, an alkyl group, an amino group, and ammonium group, a hydroxyl, a sulfo group, a carboxyl, an amino carbonyl or an aminosulfonyl, R.sup.1, R.sup.2 and R.sup.
    Type: Grant
    Filed: December 19, 1991
    Date of Patent: April 6, 1993
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Rene M. De Keyzer, Jean-Marie O. Dewanckele, Ludo L. Van Rompuy, Jos A. Vaes
  • Patent number: 5162192
    Abstract: An aqueous alkaline processing liquid suitable for use in the silver complex diffusion transfer reversal (DTR-) process, wherein wherein said liquid contains a mixture of alkanolamines, the said mixture consisting of (I) N-methyl-diethanolamine and of (II) N,N-dimethyl-ethanolamine in a total amount in the range from 0.3 mol/l to 1.5 mol/l, and in a molar ratio of (I) to (II) from 1/20 to 20/1.
    Type: Grant
    Filed: September 9, 1991
    Date of Patent: November 10, 1992
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Rene M. De Keyzer, Raymond L. Odeurs, Luc A. De brabandere
  • Patent number: 5124229
    Abstract: An aqueous alkaline processing liquid suitable for use in the silver complex diffusion transfer reversal (DTR-) process, wherein said liquid contains one or more alkanolamines, the said alkanolamine(s) consisting of one or more tertiary alkanolamines in an amount in the range from 0.3 mol to 1.5 mol/l, and one or more secondary alkanolamines in an amount from 0 mol % to 5 mol % with respect to the amount of tertiary alkanolamine(s), and said liquid also contains a mixture of a silver image toning agent A being 1-phenyl-1H-tetrazole-5-thiol or a tautomer thereof and at least one other silver image toning agent B being a 1-phenyl-1H-tetrazole-5-thiol or a tautomer thereof, wherein the phenyl nucleus is substituted with halogen, the toning agent A and toning agent(s) B being present in said liquid in a molar ratio from 1/15 to 15/1.
    Type: Grant
    Filed: May 17, 1990
    Date of Patent: June 23, 1992
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Rene M. De Keyzer, Raymond L. Odeurs, Luc A. De Brabandere
  • Patent number: 5073473
    Abstract: A method for forming an image by silver salt diffusion transfer is described, comprises processing an imagewise exposed photosensitive element provided with a layer of photosensitive silver halide emulsion on a support, and an image-receiving element provided with an image-receiving layer containing a silver-precipitating agent on a support, with an alkali processing composition in the presence of a silver halide solvent, to convert at least part of the unexposed silver halide in the emulsion layer into a transferable silver complex salt, to transfer at least part of said complex salt into the image-receiving layer, and to form an image in the image-receiving layer; the processing being carried out in the presence of at least one compound as described.
    Type: Grant
    Filed: January 16, 1990
    Date of Patent: December 17, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keizo Koya, Yoshio Idota
  • Patent number: 5068164
    Abstract: The present invention provides a developer for making a lithographic printing plate by silver complex diffusion transfer process which contains a hydroxyaryl fatty acid. This hydroxyaryl fatty acid preferably has the formula: ##STR1## wherein R.sub.1 represents a straight chain alkyl group of 1-19 carbon atoms and R.sub.2 represents a straight chain alkylene group of 1-19 carbon atoms with a proviso that sum of carbon atoms of R.sub.1 and R.sub.2 is 10-20 and R.sub.3 and R.sub.4 each represents a hydrogen atom, a hydroxyl group or an alkyl or alkoxy group of 1-9 carbon atoms.
    Type: Grant
    Filed: March 27, 1990
    Date of Patent: November 26, 1991
    Assignee: Mitsubishi Paper Mills, Limited
    Inventors: Toshiro Kondo, Hidetoshi Miura
  • Patent number: 5063136
    Abstract: An aqueous alkaline processing liquid suitable for use in the silver complex diffusion transfer (DTR-) process, wherein said liquid contains one or more alkanolamines, the said alkanolamine(s) consisting of one or more tertiary alkanolamines in an amount in the range from 0.15 mol to 1.5 mol/l, and one or more secondary alkanolamines in an amount higher than 5 mol % but not higher than 100 mol % with respect to the amount of tertiary alkanolamine(s), and said liquid also contains a mixture of a silver image toning agent A being 1-phenyl-1H-tetrazole-5-thiol or a tautomer thereof and at least one other silver image toning agent B being a 1-phenyl-1H-tetrazole-5-thiol or a tautomer thereof, wherein the phenyl nucleus is substituted with halogen, the toning agent A and toning agent(s) B being present in said liquid in a molar ratio from 1/15 to 15/1.
    Type: Grant
    Filed: May 17, 1990
    Date of Patent: November 5, 1991
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Rene M. De Keyzer, Raymond L. Odeurs, Luc A. De brabandere
  • Patent number: 5057395
    Abstract: Disclosed is a silver complex diffusion transfer process which comprises processing a photosensitve material comprising a support and at least a silver halide emulsion layer provided thereon and an image receiving material comprising a support and at least an image receiving layer provided thereon which are brought into close contact with each other in a developing processing solution. This process is characterized in that said image receiving layer has 1-3 g/m.sup.2 of a hydrophilic colloid at least 80% by weight of which is gelatin; total amount of hydrophilic colloid present on the emulsion layer side of the photosensitive material is 5-8 g/m.sup.2 ; when the materials are immersed in a 0.1N aqueous sodium hydroxide solution at 20.degree. C. for 1 minute, amount of absorbed solution per 1 g of hydrophilic colloid is 3.
    Type: Grant
    Filed: November 17, 1989
    Date of Patent: October 15, 1991
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Yasuo Tsubai, Susumu Baba, Akio Yoshida
  • Patent number: 5043246
    Abstract: A non-light-sensitive image-receiving element useful in a silver complex diffusion transfer process includes at least one layer containing certain S-thiuronium alkyl sulfonates which act as tone controlling agents that accelerate the physical development of silver.
    Type: Grant
    Filed: March 12, 1990
    Date of Patent: August 27, 1991
    Assignee: Eastman Kodak Company
    Inventors: Anthony M. Barnett, Colin J. Gray, Julie Baker
  • Patent number: 5035978
    Abstract: A non-light-sensitive image-receiving element useful in a silver complex diffusion transfer process includes at least one layer containing certain tone controlling agents that accelerate the physical development of silver. Compounds useful for this purpose are alkyl disulfides substituted by a water solubilizing group, thiazolidine carboxylic acids, .gamma.-thiobutyrolactones, higher alkyl thioglycolates, and carboxy-substituted rhodanines.
    Type: Grant
    Filed: July 12, 1990
    Date of Patent: July 30, 1991
    Assignee: Eastman Kodak Company
    Inventors: Anthony M. Barnett, Colin J. Gray, Julie Baker
  • Patent number: 4912015
    Abstract: A method of forming an image by silver salt diffusion transfer comprising (a) developing a light-sensitive element including an imagewise exposed light-sensitive silver halide emulsion layer with an alkali processing solution comprising a silver halide solvent to convert at least a portion of unexposed silver halide in the emulsion layer into a transferable silver complex salt, and (b) transferring at least a portion of the silver complex salt to an image-receiving element containing a silver precipitating agent to form an image on the image-receiving layer, wherein the processing is carried out in the presence of an organic phosphonic acid compound.
    Type: Grant
    Filed: September 16, 1988
    Date of Patent: March 27, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yoshio Idota
  • Patent number: 4892811
    Abstract: A silver halide photographic material which comprises a support having coated thereon a light-sensitive silver halide emulsion layer, wherein the photographic material contains a blocked photographic agent represented by the following general formula (I): ##STR1## wherein A represents a photographic agent moiety which is bonded to a blocking moiety through a hetero atom, or a precursor thereof; R.sup.1 represents a hydrogen atom or a substituent group; and Z represents atoms necessary to form a carboxylic ring or a heterocyclic ring. The blocked photographic agent is completely stable upon storage of the photographic material, and releases a photographic agent at a desired time upon processing of the photographic material. The blocked photographic agent also exhibits its function to a substantial degree over a wide range.
    Type: Grant
    Filed: November 16, 1987
    Date of Patent: January 9, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Mitsunori Ono, Akihiko Ikegawa
  • Patent number: 4891304
    Abstract: A silver halide photographic material comprising a support having provided thereon at least one silver halide emulsion layer containing a compound represented by formula (I): ##STR1## wherein EAG represents an aromatic group bonding to N.sub.A and capable of accepting an electron;N.sub.A and N.sub.B each represents a nitrogen atom;R.sup.1 represents a lone pair, a .pi.-bond, a .sigma.-bond, or a substituent other than a hyudrogen atom;n represents 2 or 3;m represents 0 when n represents 2, or m represents 1 and N.sub.B has a positive charge when n represents 3;X.sup..crclbar. represents an anion;the groups or bonds represented by R.sup.1 may be combined with each other or may be combined with EAG to form a ring;R.sup.2 represents R.sup.3 --CO--, R.sup.3 --SO.sub.2 --, R.sup.3 --CO--N.dbd.CH--, or R.sup.3 --SO.sub.2 --N.dbd.CH--, wherein R.sup.3 represents an alkyl group, an aryl group, or a heterocyclic group;the group represented by R.sup.2 may be combined with at least one of R.sup.
    Type: Grant
    Filed: March 30, 1989
    Date of Patent: January 2, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Koki Nakamura
  • Patent number: 4888267
    Abstract: An ecologically clean method for processing an imagewise exposed photographic material having a silver halide emulsion layer which method comprises the steps of:(A) developing the image-wise exposed photographic material by means of at least one diffusible developing agent in the absence of such an amount of silver halide solvent that would reduce the coverage of developed silver metal (Ag/m2) by more than 20% using an aqueous alkaline liquid.
    Type: Grant
    Filed: April 29, 1988
    Date of Patent: December 19, 1989
    Assignee: AGFA-Gevaert N.V.
    Inventor: Gino L. De Rycke
  • Patent number: 4876171
    Abstract: A photographic image is formed on an image-receiving material by imagewise exposing a silver halide photosensitive material, placing the exposed material on an image-receiving material, and subjecting the assembly to silver salt diffusion transfer in the presence of a reducing agent, a physical development nucleus, a complexing compound capable of complexing reaction with a silver ion in the presence of water and/or a hydrophilic thermal solvent as a medium, and optionally, a substantially water-insoluble basic metal compound.
    Type: Grant
    Filed: February 12, 1988
    Date of Patent: October 24, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hiroyuki Hirai
  • Patent number: 4859565
    Abstract: Method for making images by image-wise exposing a silver halide emulsion layer, developing it with an alkaline processing solution in the presence of a silver halide solvent, development nuclei, and a density- and tone-controlling compound, transferring silver complexes from the emulsion layer to a non-light-sensitive image-receiving layer and forming an image therein, said density- and tone-controlling compound being contained in said image-receiving layer and/or in said processing solution and corresponding to the general formula: ##STR1## wherein R.sup.1, R.sup.2, and R.sup.3 (same or different) represent hydrogen, C.sub.1 -C.sub.8 alkyl, or Alk.sub.1 --X--Alk.sub.2 --Y--; Alk.sub.1 is (substituted) C.sub.1 -C.sub.8 alkyl; X is --O-- or --S--; Alk.sub.2 is (substituted) C.sub.1 -C.sub.8 alkylene; Y is a single bond, --O--, --S--, --CONH--, --SO.sub.2 NH--, or --NHCONH--; R.sup.3 can alternatively represent (substituted) C.sub.1 -C.sub.8 alkylthio; at least one of R.sup.1, R.sup.2, and R.sup.
    Type: Grant
    Filed: April 26, 1988
    Date of Patent: August 22, 1989
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Rene M. De Keyzer, Robert J. Pollet, Leon L. Vermeulen
  • Patent number: 4830949
    Abstract: An ecologically advantageous method for processing an exposed photographic silver halide emulsion layer-bearing material involves the steps of:(A) developing in an aqueous alkaline liquid an image-wise exposed silver halide emulsion layer of said material by means of at least one diffusible developing agent in the absence of such an amount of silver halide solvent that would reduce the coverage of developed silver metal (Ag/m2) by more than 20%,(B) bringing the emulsion layer side of said developed photographic material while still wet by the liquid from step (A) into contact with a water-absorbing processing layer of a receptor element that contains in an organic hydrophilic colloid binder a silver halide reducing agent and silver halide complexing agent and in waterpermeable relationship therewith physical development nuclei,(C) maintaining said photographic material and receptor compound into said receptor element until removal of undeveloped silver halide from the exposed silver halide emulsion layer is s
    Type: Grant
    Filed: April 29, 1988
    Date of Patent: May 16, 1989
    Assignee: AGFA-Gevaert N.V.
    Inventor: Gino L. De Rycke
  • Patent number: 4824760
    Abstract: A lithographic printing plate made by silver complex diffusion transfer process from a lithographic printing plate material which contains a compound represented by the general formula [I] in photographic constituting layer is markedly improved in its printing endurance: ##STR1## wherein M represents hydrogen, an alkali metal or ammonium ion and R.sup.1 -R.sup.4 each represents hydrogen atom, alkyl group, alkenyl group, aralkyl group, aryl group, halogen atom, alkoxy group, hydroxyl group, amino group, carboxyl group, sulfone group, alkoxycarbonyl group, acylamide group or sulfonamide group and two of R.sup.1 -R.sup.4 may jointly form a ring.
    Type: Grant
    Filed: April 7, 1987
    Date of Patent: April 25, 1989
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Kazuyoshi Yamamoto, Masahiko Saikawa, Eiji Kanada
  • Patent number: 4820610
    Abstract: A light-sensitive liquid composition in which droplets of a silver halide emulsion are dispersed in a polymerizable compound, characterized in that a polymer having a principal chain consisting essentially of a hydrocarbon chain substituted in part with hydrophilic groups which contain, in their terminal groups, -OH or nitrogen having a lone electron-pair is dissolved in the polymerizable compound. Process for the preparation thereof is also disclosed.
    Type: Grant
    Filed: May 25, 1988
    Date of Patent: April 11, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Taku Nakamura, Tsumoru Hirano, Eiji Funatsu
  • Patent number: 4784933
    Abstract: Lithographic printing plates which have such a high sensitivity as permitting use of semiconductor laser beam of low output, a high resolving power and a high printing endurance and are free from occurrence of scumming are made by a method which comprises imagewise exposing a light sensitive material which comprises a support and at least a silver halide emulsion layer and a surface physical development nuclei layer provided on the support, said emulsion layer comprising silver halide grains which contain at least silver bromide and containing at least one sensitizing dye having a maximum spectral sensitivity in the region of longer than 700 .mu.m and then developing the exposed light sensitive material with a silver complex diffusion transfer developer containing at least a thiocyanate. Further improvement can be obtained by providing an antihalation means to keep the reflectance of a light of longer than 700 .mu.m at 13-40%.
    Type: Grant
    Filed: November 12, 1986
    Date of Patent: November 15, 1988
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Eiji Kanada, Yasuo Tsubai, Akira Tanaka, Toshiro Kondo, Yoshikazu Takaya, Masahiko Saikawa, Hiroshi Nishinoiri