Thermographic Process Patents (Class 430/348)
  • Patent number: 4405994
    Abstract: Thermo-optic writing on an information support in which an organic sublayer covered by a metal layer is deposited on a substrate. A plastic deformation due to the thrust exerted by the localized swelling of the sub-layer is created in the metal layer to produce a relief impression without piercing of the metal layer.
    Type: Grant
    Filed: January 21, 1981
    Date of Patent: September 20, 1983
    Assignee: Thomson-CSF
    Inventors: Jean Cornet, Jean-Claude Lehureau, Henriette Magna
  • Patent number: 4388400
    Abstract: A heat-mode recording material is disclosed. The material comprises a base which is overlaid with a recording layer made of a metal, semimetal or semiconductor containing at least hydrogen.
    Type: Grant
    Filed: October 6, 1981
    Date of Patent: June 14, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masatoshi Tabei, Minoru Wada, Yonosuke Takahashi, Satoshi Yoshida
  • Patent number: 4349218
    Abstract: Fluoran compounds of the formula ##STR1## wherein one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represents n-alkyl having 6 to 12 carbon atoms and the other R's, independently of each other, represent hydrogen, alkyl having 1 to 12 carbon atoms, alkoxyalkyl having 2 to 8 carbon atoms or benzyl optionally substituted in the ring by nitro, halogen or alkyl having 1 to 6 carbon atoms.The fluoran compounds are particularly useful as color formers which give intense dark green color when they are brought into contact with an electron-accepting co-reactant.
    Type: Grant
    Filed: October 3, 1979
    Date of Patent: September 14, 1982
    Inventors: Robert Garner, Jean C. Petitpierre
  • Patent number: 4340655
    Abstract: Improved thermal and mechanical barrier layers coated on the recording layer of an optical recording element are disclosed. The improved layers comprise water-soluble polymers having a glass transition temperature when dry of at least 100.degree. C. and preferably at least 150.degree. C. These barrier layers are easily coated and do not significantly degrade the performance of the element. Optional layers such as spacer layers and topcoat layers coated on the barrier layers are also disclosed.
    Type: Grant
    Filed: June 18, 1980
    Date of Patent: July 20, 1982
    Assignee: Eastman Kodak Company
    Inventors: Kenneth R. Hollister, Harold T. Thomas
  • Patent number: 4335198
    Abstract: A recording member includes a recording layer capable of recording in response to applied heat. The heat is produced by absorption of high intensity radiation which defines recording information. The recording layer has a radiation absorption layer and an anti-reflection layer capable of preventing the reflection of radiation at the radiation absorption layer.
    Type: Grant
    Filed: May 14, 1979
    Date of Patent: June 15, 1982
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hiroshi Hanada, Masanao Kasai, Hitoshi Hanadate, Yoko Oikawa
  • Patent number: 4321309
    Abstract: A heat-sensitive recording material having a heat-sensitive layer composed mainly of a leuco dye and a phenolic compound used as a developer, said heat-sensitive layer containing as a binding agent any one or combinations of polyvinyl alcohol, oxidized starch and etherized starch, and methyl cellulose in a ratio by weight between 98:2 and 90:10.
    Type: Grant
    Filed: May 27, 1980
    Date of Patent: March 23, 1982
    Assignee: Sanyo-Kokusaku Pulp Co., Ltd.
    Inventors: Hisashi Mino, Masao Matsukawa, Minematsu Nagashima
  • Patent number: 4312522
    Abstract: This invention discloses a heat sensitive recording sheet which contains, as a developer, at least one of the compounds represented by the general formula ##STR1## where R represents hydrogen, an alkyl radical of from 1 to 12 carbon atoms, a cycloalkyl radical of from 3 to 10 carbon atoms, an aralkyl radical of from 7 to 10 carbon atoms, and a phenyl radical, and may be identical to or different from each other, n is zero, or an integer of 1 or 2.The heat sensitive recording sheet of this invention has a sharper rise in developed color density and is advantageous for its handling and storage as well as gives a developed color image having an excellent fastness to light and water resistance in addition to very little decrease in density of the developed color image with time.
    Type: Grant
    Filed: August 14, 1980
    Date of Patent: January 26, 1982
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Akihiro Yamaguchi, Keizaburo Yamaguchi, Hisamichi Murakami
  • Patent number: 4311750
    Abstract: A multi-color thermo-sensitive recording material comprises two thermo-sensitive coloring layers capable of forming different colors respectively at different temperatures, which are formed one over the other on a support member, and a discoloring layer comprising a cross-linking type resin, which is disposed between the two thermo-sensitive coloring layers, and which is cross-linked in the course of the coating of the thermo-sensitive layers, without being dissolved into any of the two thermo-sensitive coloring layers.
    Type: Grant
    Filed: December 4, 1979
    Date of Patent: January 19, 1982
    Assignee: Ricoh Company Limited
    Inventors: Keishi Kubo, Tetsuo Tanaka
  • Patent number: 4312009
    Abstract: A device for projecting ink droplets through a set of projection holes to print a pattern under selective electrical or light pulse control.A first plate formed with a large number of holes is placed in close proximity to the surface of the printing medium. A second plate a small distance from the first defines therewith a chamber in which the ink is locally heated by electrical current controlled by light selectively impinging on a photoconductive part of said second plate in register with each hole or each group of holes so as to form a pattern with constant or variable parts.
    Type: Grant
    Filed: February 5, 1980
    Date of Patent: January 19, 1982
    Assignee: Smh-Adrex
    Inventor: Francois Lange
  • Patent number: 4307898
    Abstract: 3-[(Alkoxy)(aryl or heteroaryl)methyl]-1H-indoles which are useful as color formers in pressure-sensitive carbonless duplicating systems and thermal marking systems are prepared by reacting 3-[(arylsulfonyl)(aryl or heteroaryl)methyl]-1H-indoles with alcohols in the presence of a base.
    Type: Grant
    Filed: March 6, 1980
    Date of Patent: December 29, 1981
    Assignee: Sterling Drug Inc.
    Inventors: Paul J. Schmidt, William M. Hung
  • Patent number: 4293634
    Abstract: A method of recording images on a radiation sensitive material comprising forming a layer of a radiation sensitive material comprised of a heterogeneous mixture of substances. At least one of the substances of the heterogeneous mixture serves as a binder capable of converting its states of aggregation in the mixture under the action of the intrinsic or reflected radiation obtainable from the object being recorded. Another substance of the heterogeneous mixture, in the form of particles, is capable of interacting with a force field. The layer is introduced in a force field and an image of the object being recorded is projeced on that layer. The produced image is fixed by converting the state of aggregation of the heterogeneous mixture. The proposed method makes it possible to record images in any spectral range of the intrinsic and reflected radiation of the object. Images of any objects can be recorded on that layer containing no silver halides.
    Type: Grant
    Filed: April 10, 1980
    Date of Patent: October 6, 1981
    Inventor: Yakov A. Monosov
  • Patent number: 4291119
    Abstract: A recording material comprising a support having thereon a layer containing (i) at least one metal and (ii) a layer containing one or more metal sulfides other than GeS, metal fluorides or metal oxides. A mono-layer mixture of (i) and (ii) may also be used.
    Type: Grant
    Filed: January 23, 1980
    Date of Patent: September 22, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keishiro Kido, Satoshi Yoshida, Tomoaki Ikeda
  • Patent number: 4289071
    Abstract: A shallow relief non-bottoming printing plate is disclosed having a polymerized layer of less than about 0.020 inch and which includes a plurality of dispersed particles sufficient to create small protuberances in non-image or background areas to prevent bottoming. Photopolymerizable elements, as well as processing techniques, are also disclosed for making such printing plates.
    Type: Grant
    Filed: September 12, 1979
    Date of Patent: September 15, 1981
    Assignee: Napp Systems (USA), Inc.
    Inventors: Robert W. Hallman, Koichi Kimoto, Sakuo Okai
  • Patent number: 4288509
    Abstract: A recording material comprising a transparent support having formed thereon a recording layer containing a thermally coagulatable proteinaceous compound, the recording layer having an average optical density throughout the wavelength region of about 350 mm to 450 nm of at least about 1.5 is disclosed, which is suitable for preparing a reprographic material such as a photmask by flash exposure in heat conducting relation with an original.
    Type: Grant
    Filed: July 20, 1979
    Date of Patent: September 8, 1981
    Assignee: Process Shizai Co., Ltd.
    Inventor: Takashi Kashiwagi
  • Patent number: 4283077
    Abstract: Aldehyde or ketone 0-[(3-indolyl)(aryl or heteroaryl)methyl]oximes which are useful as color-formers in pressure-sensitive carbonless duplicating systems and thermal marking systems are prepared by reacting 3-[(arylsulfonyl)(aryl or heteroaryl)methyl]-1H-indoles with aldehyde or ketone oximes in the presence of a base.
    Type: Grant
    Filed: March 6, 1980
    Date of Patent: August 11, 1981
    Assignee: Sterling Drug Inc.
    Inventors: Paul J. Schmidt, William M. Hung
  • Patent number: 4282534
    Abstract: A thermal recording element comprising a support having formed thereon a recording layer, a first protective layer of a halogenated polyolefin, polystyrene, polystyrene derivative, halogenated rubber or styrene-vinyltoluene copolymer formed on the recording layer; and a second protective layer of a polymer having strong film strength formed on the first protective layer.
    Type: Grant
    Filed: June 26, 1979
    Date of Patent: August 4, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Fumiaki Shinozaki, Tomizo Namiki, Masao Kitajima, Tomoaki Ikeda, Yuzo Mizobuchi
  • Patent number: 4273860
    Abstract: There is disclosed a cobalt(III) complex-containing photographic composition, element and process which can be made negative-working or positive-working. Featured are an exposure activatible image precursor composition and a photoinhibitor composition capable of inhibiting image formation in the image precursor composition.
    Type: Grant
    Filed: December 20, 1978
    Date of Patent: June 16, 1981
    Assignee: Eastman Kodak Company
    Inventor: Anthony Adin
  • Patent number: 4266009
    Abstract: A novel imaging material comprising a substrate; a lead layer thereon including at least 20% by weight of lead and having a substantially dome shaped grain structure; and a stabilizing layer formed on said lead layer and comprising a specific metallic element or an organic polymer. The imaging material has a gradation, an excellent resolution and an improved storage stability. The imaging material can form an image thereon by a dry process even in a light room without the conventional development step.
    Type: Grant
    Filed: November 2, 1978
    Date of Patent: May 5, 1981
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Takeshi Ueda, Kiichiro Sasaguri, Hidehiko Kobayashi
  • Patent number: 4259424
    Abstract: An improved heat-developable photosensitive material is disclosed which comprises an infrared rays-absorbing layer provided in contact with or adjacent to a layer comprising a reducible organic silver salt.
    Type: Grant
    Filed: February 5, 1979
    Date of Patent: March 31, 1981
    Assignee: Canon Kabushiki Kaisha
    Inventors: Ichiro Endo, Hajime Kobayashi, Toshiyuki Komatsu, Shigeru Ohno
  • Patent number: 4252890
    Abstract: An imaging system wherein a migration-type imaging member comprising a softenable layer containing agglomerable migration marking material is provided, and the member is exposed to an image pattern of electromagnetic radiation of sufficient energy to cause a simultaneous imagewise migration at least in depth in the softenable layer and agglomeration of the agglomerable migration marking material in the imagewise exposed areas of the imaging member. In another embodiment, a microscopically discontinuous layer of imaging material on a stable substrate is agglomeration or evaporation imaged by the inventive system.
    Type: Grant
    Filed: October 26, 1977
    Date of Patent: February 24, 1981
    Assignee: Xerox Corporation
    Inventors: Werner E. L. Haas, James E. Adams, Bela Mechlowitz
  • Patent number: 4251564
    Abstract: The imaging layer coated side of a heat-responsive recording medium is selectively heat-sinked by the raised portions of live skin tissue contacting the same so that only the unheat-sinked portions of the recording medium will reach an imaging temperature. The source of heat for the film may be a flash lamp directed against the opposite substrate side of the film where the electromagnetic energy thereof is converted into heat when absorbed by the substrate, or may be a source of externally applied heat transmitted through the substrate to the imaging layer of the film. In the latter case, the recording medium is preferably initially in spaced relationship with a heat contact plate which is to be contacted by a heat source, which may be the end face of a piston either pre-heated to a given temperature or having a current heatable resistance thereon to be pulsed with current. In the former case the plunger end face preferably has a low heat conductivity coating thereon.
    Type: Grant
    Filed: February 12, 1979
    Date of Patent: February 17, 1981
    Inventors: Vincent D. Cannella, Mark H. McCormick-Goodhart
  • Patent number: 4243746
    Abstract: A novel dispersion imaging material comprising a substrate, a sublayer thereon comprising at least 70% by weight of a member selected from palladium, gold, germanium and combinations thereof and having a thickness of 5 A to 200 A, and a main imaging layer on said sublayer comprising at least 50% by weight of tin, and optionally as the outermost layer a protective layer comprising an organic polymer. The sublayer modifies the layer structure of the tin-based main imaging layer. The imaging material has a high safety in respect of toxicity as well as an excellent gradation and a high sensitivity. The imaging material can form thereon an image by a dry process even in a light room without the conventional development and fixation steps.
    Type: Grant
    Filed: March 5, 1979
    Date of Patent: January 6, 1981
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Takeshi Ueda, Shozo Kinoshita, Kiichiro Sasaguri, Hidehiko Kobayashi
  • Patent number: 4242439
    Abstract: A dry process high sensitivity imaging film includes a solid, high optical density and substantially opaque film of dispersion imaging material deposited on a substrate. The film of dispersion imaging material comprises a plurality of separate layers of different and substantially mutually insoluble metal components having relatively high melting points and relatively low melting point eutectics, and interfaces between said layers having relatively low melting points.
    Type: Grant
    Filed: September 27, 1979
    Date of Patent: December 30, 1980
    Assignee: Energy Conversion Devices, Inc.
    Inventors: Masatsugu Izu, Vincent D. Cannella
  • Patent number: 4242440
    Abstract: Certain polyacetylenes exhibit reversible color changes at transition temperatures in the range -180.degree. to 220.degree. C., wherein the thermochromic cycles can be repeated many times with no apparent degradation and little change in spectroscopic properties.These thermochromic polyacetylenes are useful in temperature-indicator and indicia-display device applications.A process for laser-beam recording of images is described employing a thermochromic polyacetylene, in which the hysteresis properties of the polyacetylene can be suitably altered allowing for selectively storing or erasing the formed image.
    Type: Grant
    Filed: April 30, 1979
    Date of Patent: December 30, 1980
    Assignee: Allied Chemical Corporation
    Inventors: Kwok C. Yee, Anthony F. Preziosi, Gordhanbhai N. Patel, Ronald R. Chance, Granville G. Miller, Ray H. Baughman
  • Patent number: 4208478
    Abstract: A Te(II) complex represented by the formula: RTeM(R').sub.3 wherein M is lead, tin, germanium or silicon; R and R' are alkyl or aryl is useful in an imaging material to provide a non-silver image. The imaging material can be a photographic material, especially a heat-developable photographic material containing, for example, a photosensitive metal salt other than the Te(II) material or other sources of developable nuclei.
    Type: Grant
    Filed: October 13, 1977
    Date of Patent: June 17, 1980
    Assignee: Eastman Kodak Company
    Inventors: Sylvia A. Gardner, Henry J. Gysling
  • Patent number: 4199615
    Abstract: A dry-process imaging film which is sensitive to, and substantially simultaneously imaged and developed by, electromagnetic radiation above a threshold value applied thereto through an imaging mask. The film, in its preferred form, comprises a thin solid continuous, non-particulate film of a dispersion imaging material provided with a thin, flexible, protective overlayer of a polymeric resin. The film of dispersion imaging material is carried or supported on a flexible plastic substrate which may be transparent or light reflective.
    Type: Grant
    Filed: February 18, 1977
    Date of Patent: April 22, 1980
    Assignee: Energy Conversion Devices, Inc.
    Inventors: Harvey H. Wacks, Donald J. Sarrach