Heat Applied Before Imaging Patents (Class 430/349)
  • Patent number: 6071678
    Abstract: There is disclosed a silver halide photographic light-sensitive material that contains at least one color-developing agent of formula (I) and at least one dye-forming coupler of formula (II) contained in one or more photographic constitutional layers provided on a base: ##STR1## in formula (I), Z is a carbamoyl group or the like, and Q represents a group of atoms required to form an unsaturated ring together with the C, and in formula (II), M represents a coupler component capable of causing coupling reaction at the site where G is bonded with the oxidized color-developing agent, G is a hydrogen atom or a coupling split-off group, Y.sup.1 and Y.sup.2 each represent a group having a dissociation group, whose pKa is 1 or more but 12 or less, and n and m are each an integer of 0 to 3, provided that n+m.gtoreq.1. There is also disclosed an image-forming method using the light-sensitive material.
    Type: Grant
    Filed: August 31, 1998
    Date of Patent: June 6, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kiyoshi Takeuchi
  • Patent number: 6060226
    Abstract: There is disclosed a polyester support which has a flatness index of from 0.01 to 0.07, which is defined by the following formula: Flatness index=(the average value of .DELTA.L in the transverse direction).times.(.DELTA.L range), in which .DELTA.L (%)=100.times.[(longitudinal direction size at 150.degree. C.)-(longitudinal direction size at 30.degree. C.)]/(longitudinal direction size at 30.degree. C.), and .DELTA.L range (%)=[(maximum value of .DELTA.L in the transverse direction)-(minimum value of .DELTA.L in the transverse direction). The polyester support is excellent in flatness and heat-dimensional stability.
    Type: Grant
    Filed: November 10, 1998
    Date of Patent: May 9, 2000
    Assignee: Fuji Photo Film Photo, Co., Ltd.
    Inventor: Kiyokazu Hashimoto
  • Patent number: 6040109
    Abstract: According to the present invention there is provided a method for preparing an imaging element comprising the steps of coating in the order given on a grained and anodized side of an aluminum support (i) an image receiving layer containing physical development nuclei, (ii) a photosensitive layer containing a silver halide emulsion being in water permeable relationship with said image receiving layer and (iii) optionally an antistress layer being in water permeable relationship with said image receiving layer comprising unhardened gelatin, characterized in that said aluminum support when being coated with said photosensitive layer is in contact with a guiding roller, heated at a temperature between 35 and 70.degree. C.
    Type: Grant
    Filed: February 22, 1999
    Date of Patent: March 21, 2000
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Paul Coppens, Marcus Jonckheere
  • Patent number: 6040108
    Abstract: Compositions for making structured color images comprising(a) a soluble pigment precursor which can be transformed to an insoluble pigment by means of chemical, thermal, photolytic or radiation-induced method, and(b) a binder polymer or prepolymer, or a positive or negative resist-type resin which can be structured by crosslinking, polymerization or depolymerization by applying heat or electromagnetic irradiation.The compositions can be applied to optical and thermal recording, printing, and the production of color filters for Liquid Crystal Displays, with high accuracy, high transparency and high stability.
    Type: Grant
    Filed: December 3, 1998
    Date of Patent: March 21, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Ulrich Schadeli, John S. Zambounis, Abul Iqbal, Zhimin Hao, Henri Dubas
  • Patent number: 6037108
    Abstract: A support for an imaging element is described, which support comprises a polyester polymeric film having coated thereon a subbing layer comprising gelatin and a multi-hydric organic compound having at least three hydroxyl groups, which gelatin subbing layer coated support has been subjected to a heat treatment to reduce the core-set curling tendency of the polymeric film. Imaging elements for use in an image-forming process is also described, which elements comprise a gelatin subbing layer coated polyester polymeric film support as described above, and an image-forming layer coated on the subbed support. A method for forming a heat-tempered, gelatin-subbed support for an imaging element is also described, comprising coating a subbing layer comprising gelatin and a multi-hydric organic compound having at least three hydroxyl groups on a polyester polymeric film, and subjected the coated film to heat treatment to reduce the core-set curling tendency of the polymeric film.
    Type: Grant
    Filed: April 27, 1998
    Date of Patent: March 14, 2000
    Assignee: Eastman Kodak Company
    Inventors: Janglin Chen, Richard A. Castle, Yongcai Wang
  • Patent number: 6001529
    Abstract: The speed at which a thermosensitive recording medium is scanned with a laser beam is selected to be 5 m/s or higher to increase the temperature of a thermosensitive layer of the thermosensitive recording medium for recording a gradation image thereon with high sensitivity. A sharp temperature gradient is produced along the thickness of the thermosensitive layer, so that a density gradient along the thickness of the thermosensitive layer is developed, therefore, a high-quality image can be recorded without producing any density irregularities caused by thickness irregularities of the thermosensitive layer.
    Type: Grant
    Filed: November 5, 1997
    Date of Patent: December 14, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Shinji Imai
  • Patent number: 5968714
    Abstract: A recording process comprising the steps of: information-wise exposing to radiation a photosensitive thermally developable photographic material, thereby producing a latent image; and heating the photosensitive thermally developable photographic material, characterized in that the photosensitive thermally developable photographic material is on one and the same holding or guiding means during both the information-wise exposure step and the heating step; and the information-wise exposure step is carried out during the heating step; and a method of increasing the photosensitivity of a photosensitive thermally developable photographic material.
    Type: Grant
    Filed: September 5, 1997
    Date of Patent: October 19, 1999
    Assignee: Agfa-Gevaert
    Inventors: Luc Leenders, Jacobus Bosschaerts, Robert Overmeer, Eddie Daems, Leo Oelbrandt, Hans Strijckers, Thomas Zehetmaier, Jurgen Muller, Friedrich Stumpf, Gerald Halbedl
  • Patent number: 5914220
    Abstract: A polyester support in which a difference between orientation angles in both the side edges and that in the center thereof is from 0.degree. to 40.degree., whereby a photographic film having excellent flatness after heat treatment is provided.
    Type: Grant
    Filed: May 19, 1997
    Date of Patent: June 22, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Masahiko Murayama
  • Patent number: 5851749
    Abstract: There is disclosed novel color-developing agents of the formula (I). There is also disclosed silver halide photographic light-sensitive materials and image-forming methods, using the color-developing agent. The color-developing agent is excellent in color-forming property, and the image obtained from the color-developing agent is good in stability of hue and image. ##STR1## wherein Z.sup.1 represents an acyl group, a carbamoyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonyl group, or a carbonimidoyl group, Q.sup.1 represents a group of atoms required to form a 5- or 6-membered aromatic ring together with the C, Q.sup.2 represents a heterocyclic residue, Y.sup.1 represents a group capable of substitution onto the aromatic ring, m is 1 or 2, and n is an integer of 0 to 3.
    Type: Grant
    Filed: November 26, 1996
    Date of Patent: December 22, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Atsuhiro Okawa, Toshiyuki Makuta, Toshiki Taguchi
  • Patent number: 5804355
    Abstract: Thermal recording or producing of a contone image comprises an imagewise and scanwise exposing a thermographic recording material with a set (s) of radiation beams (b), wherein at any given moment (t) during the exposure at least two radiation beams impinge on different dots (m) of a scanline (l), so that by completion of the exposure each effective dot of the scanline has been impinged. Photo-thermographic recording or producing comprises a developing of the exposed photo-thermographic recording material with a set (s) of radiation beams (b), wherein at any given moment (t) during the development at least two radiation beams impinge on different dots (m) of a scanline (l), so that by completion of the development step each dot of the scanline has been impinged by all radiation beams.
    Type: Grant
    Filed: March 6, 1997
    Date of Patent: September 8, 1998
    Assignee: Agfa-Gevaert N.V.
    Inventors: Jacobus Herman Bosschaerts, Robert Theodoor Overmeer, Leo Oelbrandt, Hans Louis Strijckers, Eddie Roza Daems
  • Patent number: 5773189
    Abstract: An image formation process comprising image exposing a photosensitive element which contains at least a photosensitive silver halide, a binder and a dye donating compound which forms or releases a diffusive dye corresponding or inversely corresponding to an exposure amount, and transferring the diffusive dye formed or released to a dye fixing element by heat development in the presence of a base and/or a precursor thereof, wherein the process further comprises the step of feeding water to said photosensitive element after image exposure, and the photosensitive element is maintained at a temperature of 40.degree. to 90.degree. on undergoing exposure, whereby photographic performance of the heat development photosensitive material exhibits good stability to changes in ambient temperature on undergoing exposure.
    Type: Grant
    Filed: November 14, 1997
    Date of Patent: June 30, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Takeshi Shibata
  • Patent number: 5747226
    Abstract: Provided are a processing material used for forming images on a heat-developable photosensitive material by heating the processing material and the photosensitive material in a condition that they are brought into face-to-face contact, with the processing material comprising a long web support, preferably having a thickness of from 4 to 40 .mu.m, provided thereon a processing layer, preferably comprising a base or a precursor of bases; and a method of forming images on a heat-developable photosensitive material, which comprises a step of supplying a fountain water to the photosensitive material, a step of bringing the dampened photosensitive material into face-to-face contact with the aforesaid processing material and a step of applying heat thereto.
    Type: Grant
    Filed: August 27, 1996
    Date of Patent: May 5, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshisada Nakamura, Shun-ichi Ishikawa, Kazuhiko Matsumoto
  • Patent number: 5743006
    Abstract: A hybrid thermal imaging system (20, 120) often includes a focal plane array (30, 130), a thermal isolation structure (50, 150) and an integrated circuit substrate (60, 160). The focal plane array (30, 130) includes thermal sensitive elements (42, 142) formed from a pyroelectric film layer (82), such as barium strontium titanate (BST). One side of the thermal sensitive elements (42, 142) may be coupled to a contact pad (62, 162) disposed on the integrated circuit substrate (60, 160) through a mesa strip conductor (56, 150) of the thermal isolation structure (50, 150). The other side of the thermal sensitive elements (42, 142) may be coupled to an electrode (36, 136). The various components of the focal plane array (30, 130) may be fabricated from multiple heterogeneous layers (74, 34, 36, 82, 84) formed on a carrier substrate (70).
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: April 28, 1998
    Assignee: Texas Instruments Incorporated
    Inventor: Howard R. Beratan
  • Patent number: 5693455
    Abstract: A stepped pattern is formed in a photoresist film (10) by heating the photoresist at a first temperature to soft bake it, and then applying a mask (10) that allows only a selected portion (15) of the photoresist to be heated. That portion of the photoresist film is then heated at a temperature sufficient to partially degrade the photoresist, and the mask is removed. Another portion (22) of the photoresist film is then exposed to ultraviolet light to degrade it more fully than in the earlier step. The photoresist film is then developed under conditions sufficient to completely remove the portion exposed to ultraviolet light, and to partially remove the portion heated using the mask, thereby creating a stepped feature in the photoresist film.
    Type: Grant
    Filed: July 6, 1995
    Date of Patent: December 2, 1997
    Assignee: Motorola, Inc.
    Inventors: Thomas J. Swirbel, Dale W. Dorinski
  • Patent number: 5670292
    Abstract: A dry type image formation process which comprises imagewise exposing a heat-developable photosensitive material to light, and then heat-developing the heat-developable photosensitive material, wherein the heat-developable photosensitive material further comprises a component isolated by microcapsules and the heat-developable photosensitive material is pressed before or after heat development so that the microcapsules are ruptured to release the internal phase and cause the component to be diffused into the photosensitive layer, allowing its function to be fulfilled, and an image formation process which comprises heat-developing a heat-developable photosensitive material after or simultaneously with imagewise exposing, the heat-developable photosensitive material comprising a photosensitive silver halide, a reducing agent, a basic precursor, a dye-providing substance which undergoes heat development to release or produce a dye, and a silver halide fixing agent which is a compound capable of fixing and stabili
    Type: Grant
    Filed: August 31, 1995
    Date of Patent: September 23, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazuhiko Matsumoto, Masaki Noro, Hisashi Okamura, Shun-ichi Ishikawa
  • Patent number: 5631120
    Abstract: A stepped pattern is formed in a photoresist film (10) by heating the photoresist at a first temperature to soft bake it, and then heating only a selected portion (15) of the photoresist. That portion of the photoresist film is then heated at a temperature sufficient to partially degrade the photoresist. Another portion (22) of the photoresist film is then exposed to ultraviolet light to degrade it more fully than in the earlier step. The photoresist film is then developed under conditions sufficient to completely remove the portion exposed to ultraviolet light, and to partially remove the portion heated in the first step, thereby creating a stepped feature in the photoresist film.
    Type: Grant
    Filed: March 20, 1996
    Date of Patent: May 20, 1997
    Assignee: Motorola, Inc.
    Inventors: Thomas J. Swirbel, Dale W. Dorinski
  • Patent number: 5536622
    Abstract: Trityl hydrazides and formyl-phenyl hydrazines are useful as co-developers with hindered phenols in phothothermographic and thermographic elements. These co-developers have the formula:R.sup.1 --(C.dbd.O).sub.n --NHNH--R.sup.2R.sup.1 represents hydrogen and R.sup.2 represents an aryl or substituted aryl group; or,R.sup.1 represents hydrogen, alkyl and alkenyl groups of up to 20 carbon atoms; alkoxy, thioalkoxy, or amido groups of up to 20 carbon atoms; aryl, alkaryl, or aralkyl groups of up to 20 carbon atoms; aryloxy, thioaryloxy, or anilino groups of up to 20 carbon atoms; aliphatic or aromatic heterocyclic ring groups containing up to 6 ring atoms; carbocyclic ring groups comprising up to 6 ring carbon atoms; or fused ring or bridging groups comprising up to 14 ring atoms; and R.sup.2 represents a trityl group.
    Type: Grant
    Filed: August 28, 1995
    Date of Patent: July 16, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Sharon M. Simpson, Lori S. Harring
  • Patent number: 5496687
    Abstract: A photographic film-incorporated camera which comprises a supply room in which an unexposed photographic film drawn from a cylindrical cartridge has been wound up and a wind-up room with which the cylindrical cartridge is enclosed, and which is designed to feed one exposure of the photographic film drawn from the supply room per a shooting to wind up in the cylindrical cartridge. The photographic film comprises a photographic layer on a composite of a support and a subbing layer. The composite is obtained by subjecting the support which comprises an aromatic polyester having a glass transition temperature of 50.degree. to 200.degree. C. to heat treatment at a temperature of 40.degree. C. to the glass transition temperature for 0.1 to 1,500 hours before or after forming the subbing layer on the support.
    Type: Grant
    Filed: March 2, 1995
    Date of Patent: March 5, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Fumio Kawamoto
  • Patent number: 5478705
    Abstract: Particles of compound useful in imaging elements are milled using a milling media comprising a polymeric resin. The use of polymeric milling media permits the production of particles having an average particle size less than 1 micron. Further, the resulting particles are free from the contamination resulting from conventional milling media of, for example, glass, ceramic or steel.
    Type: Grant
    Filed: May 25, 1994
    Date of Patent: December 26, 1995
    Assignee: Eastman Kodak Company
    Inventors: David A. Czekai, Dennis E. Smith, John F. Bishop, Paul E. Woodgate, James R. Bennett
  • Patent number: 5462824
    Abstract: Disclosed is a silver halide photographic material provided with at least one silver halide emulsion layer on a support and wound in a roll form, wherein the above support is subjected to a heat treatment until a heat amount in an endothermic peak which appears including a glass transition temperature becomes 100 to 1,000 mcal/g, and the support is of biaxially oriented polyester having a loss elastic modulus of 0.01 to 0.1, the glass transition temperature of 50.degree. to 200.degree. C., a Young's modulus of 530 to 2,000 kg/mm.sup.2, a breaking elongation of 60 to 200%, and a ratio of the refraction indexes in a film face direction and a thickness direction of 1.10 to 1.22.
    Type: Grant
    Filed: December 2, 1993
    Date of Patent: October 31, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Fumio Kawamoto, Yoshiki Sakaino, Shohei Yoshida
  • Patent number: 5422235
    Abstract: In a photographic paper production method, a photographic paper support is coated with one or more photographic silver halide emulsion layers and one or more other hydrophilic colloid layers, at least one of the layers including a hardener. The coated support is then dried and conditioned to a temperature of from 24.degree. C. to 33.degree. C. The photographic and other layers on the support are conditioned to an equilibrium relative humidity of from 55% to 70%. The coated support is then stored at the conditioned temperature until the photographic and other layers have achieved a predetermined hardness. The new photographic paper production method reduces the post-production storage time required for photographic paper to achieve an acceptable level of abrasion resistance.
    Type: Grant
    Filed: August 17, 1993
    Date of Patent: June 6, 1995
    Assignee: Eastman Kodak Company
    Inventors: John W. Chapman, Andrew F. Sierakowski, Robyn A. Whittle
  • Patent number: 5409797
    Abstract: A heat-sensitive recording material for laser recording is provided including a support having thereon a heat-sensitive layer including at least a first substantially colorless coloring component, a second substantially colorless coloring component which reacts with the first substantially colorless coloring component to develop a color, and an infrared-absorbing dye.
    Type: Grant
    Filed: September 7, 1993
    Date of Patent: April 25, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Noriyuki Hosoi, Masao Yabe, Naoto Yanagihara
  • Patent number: 5374496
    Abstract: An image forming method is conducted by subjecting a dry silver salt image forming medium to imagewise exposure and heating to form a light-absorbing organic compound. Thereafter, the medium is subjected to polymerization exposure to imagewise polymerize the medium based on the formation pattern of the light-absorbing compound. The light-absorbing organic compound has specific sensitivities to light in order to maximize contrast.
    Type: Grant
    Filed: September 10, 1993
    Date of Patent: December 20, 1994
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kenji Kagami, Akihiro Mouri, Masato Katayama, Kazuo Isaka, Tetsuro Fukui, Susumu Nakamura, Masao Suzuki
  • Patent number: 5326689
    Abstract: A photographic material which exhibits excellent dynamic properties and little curl is provided. The silver halide photographic material comprises at least one light-sensitive layer on a polyester support, wherein the polyester support is a polyester support having a glass transition temperature of 90.degree. C. to 200 .degree. C. and is subject to glow discharge treatment. The polyester support is preferably subjected to post heat treatment at a temperature ranging from 50 .degree. C. to lower than the glass transition temperature of said polyester support after the glow discharge treatment.
    Type: Grant
    Filed: August 18, 1993
    Date of Patent: July 5, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Masahiko Murayama
  • Patent number: 5298360
    Abstract: A layer transfer material which comprises a temporary support, a light-sensitive resin layer and a separation layer interposed between the temporary support and the light-sensitive resin layer, wherein the separation layer has a low oxygen permeability and a softening point of 80.degree. C. or below and is easily separable from the temporary support and a method of its use.
    Type: Grant
    Filed: November 29, 1991
    Date of Patent: March 29, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morimasa Sato, Masayuki Iwasaki, Fumiaki Shinozaki
  • Patent number: 5296343
    Abstract: Disclosed is a silver halide photographic emulsion spectrally sensitized in the wavelength range longer than 730 nm, and full-color recording materials containing such a photographic emulsion. The photographic emulsion has undergone J-band sensitization by containing at least one compound represented by the following general formula (I) in an amount of from 0.3 to 0.9 based on the specific addition amount defined in the disclosure, at a temperature ranging from 60.degree. C. to 85.degree. C. to gain a spectral sensitivity maximum at a wavelength from 730 nm to 900 nm: ##STR1## wherein Z.sub.1 and Z.sub.2 each represents a sulfur or selenium atom; Q.sub.1 and Q.sub.2 each represents a methylene group; R.sub.1 and R.sub.2 each represents an alkyl group; R.sub.3 represents an alkyl group, an aryl group or a heterocyclyl group; L.sub.1, L.sub.2 and L.sub.3 each represents a methine group; A.sub.1 and A.sub.2 each represents the atoms necessary for completing a benzene ring; R.sub.1 and R.sub.2 may combine with L.
    Type: Grant
    Filed: October 7, 1991
    Date of Patent: March 22, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takanori Hioki, Takashi Kato, Tadashi Ikeda
  • Patent number: 5292613
    Abstract: A photosensitive transfer material is described, comprising a temporary support having formed thereon in sequence a thermoplastic resin layer, a separating layer having only slight permeability to oxygen, and a photosensitive resin layer, wherein the adhesion between the thermoplastic resin layer and the separating layer is weakest. The photosensitive transfer material is useful, for example, for an image-forming process.
    Type: Grant
    Filed: January 29, 1992
    Date of Patent: March 8, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morimasa Sato, Masayuki Iwasaki, Fumiaki Shinozaki
  • Patent number: 5272045
    Abstract: Solid anti-fogging agents such as 5-nitroindazole which are otherwise poorly soluble in water are converted to readily water soluble compositions that are solids at room temperature when they are first dissolved in water soluble polymers or other organic compounds that have a melting point above room temperature and do not chemically react with the anti-fogging agent. The anti-foggants are preferably dissolved in the polymer or organic compound at or near the compounds' melting point below 175.degree.C.
    Type: Grant
    Filed: November 13, 1992
    Date of Patent: December 21, 1993
    Assignee: Sun Chemical Corporation
    Inventors: Dinesh P. Patel, John L. Adkins
  • Patent number: 5238801
    Abstract: A silver halide photographic material which has at least one silver halide emulsion layer on a support, wherein there is incorporated at least one electrically conductive layer of which the surface resistance is not more than 10.sup.12 .OMEGA. under conditions of 25.degree. C., 25% RH, which photographic material has been dried out at a relative humidity of not more than 50% when the water content is not more than 300 wt% with respect to the total dry weight of the binder included in the silver halide emulsion layers and other hydrophilic layers on the support, which was subjected, after drying, to a heat treatment of duration at least 6 hours at a temperature of at least 30.degree. C. in an atmosphere of absolute humidity not more than 0.01, and which has been stored under conditions of absolute humidity not more than 0.01.
    Type: Grant
    Filed: October 22, 1992
    Date of Patent: August 24, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kunio Ishigaki, Ken-ichi Kuwabara, Akira Hatakeyama
  • Patent number: 5171657
    Abstract: An image forming method comprising;subjecting an image forming medium containing at least a photosensitive silver halide, an organic silver salt, a reducing agent, a polymerizable polymer precursor and a photopolymerization initiator, to imagewise exposure, followed by heating to produce a light-absorbing organic compound in said image forming medium; and subjecting said image forming medium in which said light-absorbing organic compound has been produced, to polymerization exposure to cause said polymerizable polymer precursor to polymerize; where the light-absorbing characteristics of said light-absorbing organic compound are utilized to suppress the polymerization of said polymerizable polymer precursor at the area at which said light-absorbing organic compound has been produced.
    Type: Grant
    Filed: October 15, 1991
    Date of Patent: December 15, 1992
    Assignees: Canon Kabushiki Kaisha, Oriental Photo Industrial Co., Ltd.
    Inventors: Kenji Kagami, Akihiro Mouri, Masato Katayama, Kazuo Isaka, Tetsuro Fukui, Susumu Nakamura, Masao Suzuki
  • Patent number: 5128236
    Abstract: A photographic, silver halide element that can be dried under rapid conditions during coating without deleterious effects on fog, kinks and other surface conditions, is described. This process can function with the addition of a small amount of a high boiling, aromatic alcohol to the emulsion prior to coating. Further improvements are noted with the addition of small amounts of a humectant and a plasticizer. The films resulting from this novel process can be handled without problems in the modern, automatic changing devices, for example.
    Type: Grant
    Filed: June 27, 1990
    Date of Patent: July 7, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Patricia J. Beighle, Carl P. Beitelshees, Daniel E. Jacober, Herbert W. Lim
  • Patent number: 5104767
    Abstract: A method of forming an image is disclosed comprising irradiating a heat-sensitive recording material with a laser beam, wherein the heat-sensitive recording material includes a support having provided thereon a light-absorbing layer containing microcapsules which encapsulate a core substance containing carbon black and a binder, and tranferring a latent image thus formed on the light-absorbing layer, in accordance with the pattern and amount of the laser beam irradiation, to an image-receiving film under pressure to thereby obtain a visible image on the image-receiving film.
    Type: Grant
    Filed: September 27, 1990
    Date of Patent: April 14, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kotaro Nakamura
  • Patent number: 5096803
    Abstract: A method for producing a silver halide photographic material which comprises the steps of:(a) coating hydrophilic colloid coating liquid on a polyester support;(b) forming a hydrophilic colloid layer by drying said hydrophilic coating liquid, when A is not more than 300, in an atmosphere having a relative humidity of not more than 50% and such that the ratio A/B is at least 18whereinA is determined by the following formula:A=(M/S).times.100wherein M represents the moisture content by weight of said hydrophilic colloid layer on said support and S represents the solid weight of said hydrophilic colloid layer on said support, andB is the drying time until A is not more than 8 expressed in seconds; and(C) heat treating said coated supported from step (b) at a temperature of at least 30.degree. C. in a atmosphere having an absolute humidity of not more than 1%.The method of the present invention provides silver halide photographic materials which have improved dimensional stability.
    Type: Grant
    Filed: April 18, 1990
    Date of Patent: March 17, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Satoshi Kanetake, Shinichi Hashimoto
  • Patent number: 5061611
    Abstract: A method of preparing a light sensitive silver halide phtographic material is disclosed. The photographic material comprises a polyester support having a hydrophobic polymer layer containing a vinylidene chloride copolymer and at least one hydrophilic polymer layer. The method comprises steps of coating a hydrophilic polymer layer onto the polyester support, drying the layer until a water content of the layer reaches 60 wt %, and contacting the layer with air having a relative humidity of 5 to 25% for a period 5 seconds to 10 minutes. The photographic material according to the method has such a physical characteristics as dimensional stability for long time storage or anti-cracking of the photographic layer at the preparation period. It is suitable for printing use.
    Type: Grant
    Filed: May 1, 1990
    Date of Patent: October 29, 1991
    Assignee: Konica Corporation
    Inventors: Hideaki Sakata, Toshiharu Nagashima, Akira Kobayashi
  • Patent number: 4963458
    Abstract: A light-sensitive image forming method using a recording element which comprises a recording layer on a support is disclosed. The recording layer contains at least two active components of a photopolymerizable composition such as a polymerizable compound and a polymerization initiator, both of which are essential for a photopolymerization reaction. The components are separated from each other by the shell of microcapsules in such manner that at least one component is contained in the microcapsules which are dispersed in the recording layer and the other component is arranged outside of the microcapsule. The image forming method comprises the steps of: heating the recording element to form the photopolymerizable composition in the recording layer; and imagewise exposing to light the recording element to imagewise polymerize the photopolymerizable composition.
    Type: Grant
    Filed: September 6, 1988
    Date of Patent: October 16, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shunichi Ishikawa, Fumiaki Shinozaki
  • Patent number: 4960679
    Abstract: An image forming device is provided which comprises an image forming layer containing molecules of an organic compound capable of phase transition, and functional molecules such as those of a photochromic compound. An image forming process is also provided which employs the above-mentioned device.
    Type: Grant
    Filed: January 11, 1990
    Date of Patent: October 2, 1990
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takashi Nakagiri, Yukuo Nishimura, Kunihiro Sakai, Yoshinori Tomida, Ken Eguchi, Kenji Saito
  • Patent number: 4946769
    Abstract: A silver halide photographic light-sensitive material, and a method of preparing the same and a method of image forming using the same photographic material. The photographic material comprises a support bearing, on one side thereof, a layer containing a light-sensitive silver halide emulsion comprised of silver halide grains having an average size of from 0.05 .mu.m to 0.3 .mu.m and gelatin and, on the other side thereof, a non-light-sensitive layer containing gelatin and at least one of the emulsion layer and the non-light-sensitive layer is brought into contact with air having a temperature of from 35.degree. C. to 80.degree. C. or relative humidity of from 5% to 25% for a period not shorter than 5 seconds to not longer than one minute, within 5 minutes from the point of time when the average surface temperature of said layer is raised up to a temperature 1.degree. C.
    Type: Grant
    Filed: November 15, 1988
    Date of Patent: August 7, 1990
    Assignee: Konica Corporation
    Inventors: Takeo Arai, Toshiharu Nagashima
  • Patent number: 4933267
    Abstract: A silver halide photographic material is disclosed, having at least one hydrophilic colloid layer comprising a polyester support and having a polymer latex on at least one side of said polyester support, wherein both surfaces of said support are coated with a polymer layer comprising a copolymer containing from 50 to 99.5% by weight vinylidene chloride and wherein both polymer layers have a thickness of at least 0.3 .mu.m. A method for treating the silver halide photographic material is also disclosed.
    Type: Grant
    Filed: November 17, 1989
    Date of Patent: June 12, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kunio Ishigaki, Takashi Naoi
  • Patent number: 4873168
    Abstract: A method for treating an imaging sheet is disclosed. The method includes the steps of providing an imaging sheet having coated on one of its surfaces a layer of microcapsules, the microcapsules containing a radiation curable composition and having an image-forming agent associated therewith, heating the sheet; and image-wise exposing the layer of microcapsules to actinic radiation; wherein the heating step is performed prior to or after the image-wise exposing step. The method reduces or removes damage defects on the imaging sheet and, in some instances, extends the dynamic range of the image-forming agents.
    Type: Grant
    Filed: March 7, 1988
    Date of Patent: October 10, 1989
    Assignee: The Mead Corporation
    Inventors: Donna L. Ruder, Lyudmila Feldman, James A. Dowler
  • Patent number: 4857439
    Abstract: A method of making a photothermographic silver halide element comprises the combination of (I) adding an alkyl carboxylic acid containing 8 to 22 carbon atoms to a layer of the element comprising photosensitive silver halide and (II) after preparation of the layer comprising silver halide and before exposure of the element to light heating the element uniformly at a temperature and for a time sufficient to enable the photothermographic element to exhibit increased latent image stability upon imagewise exposure to light. The photothermographic element includes photosensitive silver halide and an oxidation-reduction image forming combination in a polmeric binder. A developed visible image is provided in such a photothermographic element after exposure to light by uniformly heating the exposed photothermographic element to moderately elevated temperatures.
    Type: Grant
    Filed: April 4, 1988
    Date of Patent: August 15, 1989
    Assignee: Eastman Kodak Company
    Inventors: Edward L. Dedio, John W. Reeves
  • Patent number: 4788124
    Abstract: An imaging process which comprises image-wise simultaneously exposing to heat and light or ultraviolet radiation an imaging material comprising a support having a layer of photosensitive microcapsules on the surface thereof, said microcapsules containing an internal phase including an image-forming agent and a photosensitve composition which undergoes a change in viscosity, melting point, softening point to heat and light or ultraviolet radiation but which remains essentially unchanged in the presence of either heat or light or ultraviolet radiation alone; assembling said imaging material with an image-receiving sheet and subjecting the assembly to a uniform transfer force such that said image-forming agent is image-wise transferred to said imaging material; wherein said photohardenable composition includes a free radical addition polymerizable or crosslinkable compound and an ionic dye-reactive counter ion compound, said ionic dye-reactive counter ion compound, said ionic dye-reactive counter ion compound be
    Type: Grant
    Filed: August 19, 1987
    Date of Patent: November 29, 1988
    Assignee: The Mead Corporation
    Inventor: Richard F. Wright
  • Patent number: 4606994
    Abstract: Photocured layers possessing a defined controllable hardness are produced by exposing a layer of a photopolymerizable or photocrosslinkable mixture, which contains a partially crystalline polymeric binder possessing olefinic double bonds capable of undergoing polymerization, to actinic light, by a method in which the photocurable layer, prior to exposure to actinic light, is subjected to a heat treatment in which the partially crystalline parts of the polymeric binder are partially or completely fused.
    Type: Grant
    Filed: April 23, 1985
    Date of Patent: August 19, 1986
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl H. Illers, Mong-Jon Jun, Gunnar Schornick
  • Patent number: 4602263
    Abstract: A thermal imaging method for forming color images is provided which relies upon the irreversible unimolecular fragmentation of one or more thermally unstable carbamate moieties of an organic compound to effect a visually discernible color shift from colorless to colored, from colored to colorless or from one color to another.
    Type: Grant
    Filed: September 4, 1984
    Date of Patent: July 22, 1986
    Assignee: Polaroid Corporation
    Inventors: Alan L. Borror, Ernest W. Ellis, Donald A. McGowan
  • Patent number: 4576906
    Abstract: A color diffusion transfer photographic element which comprises a support having provided thereon at least one silver halide emulsion layer containing a non-diffusible redox compound capable of releasing a diffusible dye or a precursor thereof by processing with an alkaline processing solution containing 3-pyrazolidinone type developing agent in the presence of a silver halide developing agent after exposure to light, wherein said alkaline processing solution is subjected to a heat treatment before use under a substantially oxygen-free condition for at least T days, wherein T is represented by the formula ##EQU1## wherein X represents the maximum temperature at which the heated alkaline processing solution is held, provided that X is about 40.degree. C. or more.
    Type: Grant
    Filed: July 2, 1985
    Date of Patent: March 18, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Osamu Takahashi, Minoru Sakai
  • Patent number: 4433037
    Abstract: A heat erasable photographic material comprises, in reactive association, in a suitable binder:(a) photographic silver halide;(b) a mild oxidizing agent which consists essentially of a cobalt(III) amine salt which, upon heating of the photographic material, will oxidize any latent image silver present in the photographic material; and(c) a weak complexing agent for the oxidized silver.Any latent image silver in the photographic material is erased upon brief uniform heating of the photographic material. The photographic material is light handleable prior to uniform heating. After uniform heating, the photographic material is capable of being imagewise exposed and processed to produce a developed silver image. The photographic material may comprise a selected silver halide developing agent.
    Type: Grant
    Filed: July 15, 1982
    Date of Patent: February 21, 1984
    Assignee: Eastman Kodak Company
    Inventor: Thap DoMinh
  • Patent number: 4361645
    Abstract: A photographic element comprising a plurality of layers (e.g., three) of light sensitive emulsions arranged one on top of the other and based on a support, each of the emulsions comprising a coupler, a silver halide compound and a sensitization promoter which is transformed into a sensitizer by thermal, photo- or electro-sensitization. Novel processes of color photography and spectral sensitization of color photography emulsions are also disclosed. Furthermore, cameras having means to activate the sensitization promoters in the emulsions are provided.
    Type: Grant
    Filed: February 3, 1981
    Date of Patent: November 30, 1982
    Inventor: Jean J. Robillard
  • Patent number: 4335957
    Abstract: A method and apparatus for forming an image using an image forming sheet that is normally non-photosensitive but can be rendered photosensitive by preheating and is exposed at the preheated area to a light image to form therein a latent image and then heat-developed to form a visible image. After preheating, the preheated area is cooled by cooling means prior to exposure.
    Type: Grant
    Filed: May 22, 1981
    Date of Patent: June 22, 1982
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Kohei Nonaka, Masahiro Koyama, Makoto Gonmori, Takeo Kimura, Tetsuo Shiga
  • Patent number: 4332889
    Abstract: A novel heat-activatable and heat-developable dry image forming material comprising (a) a silver salt of long chain fatty acid with at least 16 carbon atoms, (b) a reducing agent for silver ions, (c) a silver halide component including silver iodide or a silver halide-forming component including silver iodide-forming compound, (d) an oxidizing agent for free silver, (e) a photoreactive halogeno oxidizing agent, (f) a binder, and (g) a specific spectral sensitizing dye has been found to have improved spectral sensitivity as well as excellent storage stability.
    Type: Grant
    Filed: May 19, 1981
    Date of Patent: June 1, 1982
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Tetsuo Siga, Shozo Kinoshita, Yoshinobu Ito, Minoru Akiyama
  • Patent number: 4293634
    Abstract: A method of recording images on a radiation sensitive material comprising forming a layer of a radiation sensitive material comprised of a heterogeneous mixture of substances. At least one of the substances of the heterogeneous mixture serves as a binder capable of converting its states of aggregation in the mixture under the action of the intrinsic or reflected radiation obtainable from the object being recorded. Another substance of the heterogeneous mixture, in the form of particles, is capable of interacting with a force field. The layer is introduced in a force field and an image of the object being recorded is projeced on that layer. The produced image is fixed by converting the state of aggregation of the heterogeneous mixture. The proposed method makes it possible to record images in any spectral range of the intrinsic and reflected radiation of the object. Images of any objects can be recorded on that layer containing no silver halides.
    Type: Grant
    Filed: April 10, 1980
    Date of Patent: October 6, 1981
    Inventor: Yakov A. Monosov
  • Patent number: 4292389
    Abstract: There is provided a process for preparing a photosensitive plate for printing which comprises providing a heat-depositable fine powder having a constant directional size of 0.5-40.mu. onto the surface of a photosensitive plate for printing at a ratio of 0.005-0.5 g. of the said powder per m.sup.2 of the said plate to uniformly disperse and adhere the said powder onto the said surface, while preheating the right side (side on which powder adheres) and/or the reverse side of the said plate upon providing said powder or before or after providing, and subsequently contacting the right side of the said plate with a heating roll having a high releasing surface, whereby the said fine powder is fused and fixed on onto the surface of the said plate.
    Type: Grant
    Filed: January 24, 1980
    Date of Patent: September 29, 1981
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Hiroshi Kojima, Kunio Ito, Masami Akiyama, Takeshi Tanaka