Heat Applied After Imaging Patents (Class 430/350)
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Publication number: 20040137382Abstract: Thermally developable compositions such thermographic and photothermographic emulsions include certain triazine-thione compounds. These emulsions can be used in thermally developable materials such as thermographic and photothermographic materials to provide increased image density and shortened development time, and to allow development at lower temperatures. Such materials can have imaging layers on one or both sides of the support.Type: ApplicationFiled: December 11, 2003Publication date: July 15, 2004Inventors: Doreen C. Lynch, Stacy M. Ulrich, Paul G. Skoug
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Publication number: 20040137380Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: 1Type: ApplicationFiled: January 9, 2003Publication date: July 15, 2004Applicant: Eastman Kodak CompanyInventors: James H. Reynolds, Douglas R. Robello, David H. Levy
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Publication number: 20040137381Abstract: An image forming method for forming an image by exposing a photothermographic material to a laser beam, the laser beam being a laser diode beam having a peak light-emission intensity at a wavelength of 350 nm to 450 nm. The photothermographic material comprises at least a non-photosensitive silver salt, a photosensitive silver halide, a binder and a reducing agent, wherein a silver iodide content of the photosensitive silver halide is 40% by mole or more.Type: ApplicationFiled: November 12, 2003Publication date: July 15, 2004Inventors: Fumito Nariyuki, Shinichi Shikii, Tetsuya Kojima
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Patent number: 6762013Abstract: Nonpolymeric fluorochemicals defined as by the following Structure I are useful in thermally developable materials. The fluorochemicals are defined as follows: Rf—R—N(R1)(R2)(R3)+X− (I) wherein Rf is a straight or branched chain perfluoroalkyl group having 4 to 18 carbon atoms, R is a divalent linking group comprising at least 4 carbon atoms and a sulfide group in the chain, R1, R2, R3 are independently hydrogen or alkyl groups or any two of R1, R2, and R3 taken together can represent the carbon and nitrogen atoms necessary to provide a 5- to 7-membered heterocyclic ring with the cationic nitrogen atom, and X− is a monovalent anion.Type: GrantFiled: October 4, 2002Date of Patent: July 13, 2004Assignee: Eastman Kodak CompanyInventors: Kumars Sakizadeh, Gary E. LaBelle, Aparna V. Bhave
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Publication number: 20040131983Abstract: The invention provides a photothermographic material including: a support and an image-forming layer including a non-photosenisitive silver salt, a photosensitive silver halide, a binder, and a reduction agent disposed on the support, wherein a silver iodide content in the photosensitive silver halide is in a range from 40 mol % to 100 mol %; and an average sphere-equivalent diameter of the photosensitive silver halide is in a range from 0.3 &mgr;m to 5.0 &mgr;m. The photothermographic material may further include a silver iodide complex forming agent as a compound which substantially reduces visible light absorption caused by the photosenisitive silver halide after thermal development. At least 50%, in terms of a projected area, of the photosensitive silver halide may be occupied by tabular silver halide grains having an aspect ratio of from 2 to 50 and being deposited with a silver salt in an epitaxial growth manner.Type: ApplicationFiled: December 17, 2003Publication date: July 8, 2004Inventors: Tomoyuki Ohzeki, Eiichi Okutsu
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Patent number: 6746830Abstract: A silver halide photosensitive material having a substrate, a heat-responsive-discolorable coloring layer and a photosensitive layer coated thereon and having a silver halide, dye-providing compound and a binder, the heat-responsive-discolorable coloring layer containing a heat-responsive-discolorable coloring composition, which is colored at a temperature lower than its discoloration initiation temperature (T) of 60 to 200° C.; which is substantially discolored at a temperature equal to or higher than T; and which does not recover its color once discolored, even when its temperature is lowered to a temperature lower than T again, and the heat-responsive-discolorable coloring composition containing a polymer having a glass transition temperature of 60 to 200° C.Type: GrantFiled: October 25, 2002Date of Patent: June 8, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Jun Arakawa, Takahiro Ishizuka
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Patent number: 6746807Abstract: This invention relates to a photothermographic element comprising a support, at least one photothermographic imaging layer, and at least one filter layer, wherein the filer layer comprises a heat-bleachable composition comprising a benzothiazine arylidiene filter dye, which filter dye is in the presence of an effective amount of a base precursor.Type: GrantFiled: November 20, 2002Date of Patent: June 8, 2004Assignee: Eastman Kodak CompanyInventors: Ramanuj Goswami, Margaret J. Helber, Teresa J. Hosmer, David H. Levy
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Patent number: 6746829Abstract: In a thermal developing method for continuously and thermally developing thermal developing sheets which have a latent image formed thereon by exposure and various sizes, a minimum temperature recovery time required for thermally developing a next thermal developing sheet is determined from physical information about a thermally developed sheet, and the next thermal developing sheet is started to be developed after the minimum temperature recovery time passes.Type: GrantFiled: February 19, 2002Date of Patent: June 8, 2004Assignee: Fuji Photo Film Co., Ltd.Inventor: Akihiro Hashiguchi
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Patent number: 6746831Abstract: Thermographic and photothermographic materials comprise a barrier layer to provide physical protection and to prevent migration of diffusible imaging components and by-products resulting from high temperature imaging and/or development The barrier layer comprises 15 to 100 weight % of a film-forming cellulose ether polymer. This barrier layer is capable of retarding diffusion of mobile chemicals such as fatty carboxylic acids, developers, and toners. This barrier layer can also include other film-forming polymers to provide a clear and scratch-resistant surface.Type: GrantFiled: January 27, 2003Date of Patent: June 8, 2004Assignee: Eastman Kodak CompanyInventor: Bryan V. Hunt
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Publication number: 20040106074Abstract: A silver salt photothermographic dry imaging material including non-photosensitive aliphatic carboxylic acid silver salts; a photosensitive emulsion containing photosensitive silver halide grains; a silver ion reducing agent; a binder; and a cyan coloring leuco dye. A percentage of the photosensitive silver halide grains having a mean particle size of 0.01 or more &mgr;m and 0.04 &mgr;m or less is 5% or more by mass and 50% or less by mass of total photosensitive silver halide grains by conversion into a silver amount.Type: ApplicationFiled: November 20, 2003Publication date: June 3, 2004Applicant: Konica Minolta Holdings, Inc.Inventors: Hiroshi Kashiwagi, Narito Goto
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Publication number: 20040101789Abstract: A reversible multicolor recording medium includes a supporting substrate and a recording layer including reversible thermal coloring compositions having different colors on the supporting substrate. The reversible thermal coloring compositions are included within a separated and independent minute gap structure, and respectively have light-to-heat transforming materials which respectively absorb infrared rays having different wavelength ranges to generate heat.Type: ApplicationFiled: August 7, 2003Publication date: May 27, 2004Inventors: Kenichi Kurihara, Noriyuki Kishii, Hisanori Tsuboi
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Publication number: 20040096784Abstract: Aqueous-based thermally developable emulsions and photothermographic imaging materials include photosensitive silver halide core-shell grains that comprise at least 20 mol % iodide based on total silver, an amount of iodide in the core of the grains that can be up to the iodide saturation limit in silver iodobromide, and an amount of iodide in the shell of the grains that is at least 2 mol % less than the amount of iodide present in the core, and further provided that the total amount of silver in the shell is from about 10 to about 80 mol % of total silver in the grains. These materials provide desired Dmax and reduced image “print out”.Type: ApplicationFiled: November 15, 2002Publication date: May 20, 2004Applicant: Eastman Kodak CompanyInventors: Joe E. Maskasky, Victor P. Scaccia, David A. Dickinson
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Publication number: 20040096785Abstract: A photothermographic material containing, on a substrate, at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder in which the total silver iodide content of the photosensitive silver halide is 40 mol % or more and 100 mol % or less, and the coating amount of the photosensitive silver halide, in terms of an amount of silver, is 0.0005 g/m2 or more and 0.4 g/m2 or less, as well as an image forming method for the photothermographic material which comprises exposing the photothermographic material by using a semiconductor laser having an emission peak intensity at a wavelength of from 350 nm to 450 nm as a light source.Type: ApplicationFiled: November 7, 2003Publication date: May 20, 2004Inventor: Fumito Nariyuki
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Patent number: 6737227Abstract: Thermally developable compositions such thermographic and photothermographic emulsions include certain heterocyclic disulfide compounds and ascorbic acid or reductone reducing agents. These compositions can be used in thermally developable materials such as thermographic and photothermographic materials to provide increased image density and shortened development time, and to allow development at lower temperatures. Such materials can have imaging layers on one or both sides of the support.Type: GrantFiled: March 7, 2003Date of Patent: May 18, 2004Assignee: Eastman Kodak CompanyInventors: Doreen C. Lynch, Stacy M. Ulrich
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Publication number: 20040091823Abstract: In a heat development method for performing heat development by applying light or heat onto a heat-developable recording material including a photothermographic material or a light-sensitive heat-sensitive recording material, it has been configured such that the target temperature of a heater is increased than normal immediately after the start-up of the heat development apparatus, and subsequently, the increase range is reduced with time.Type: ApplicationFiled: September 2, 2003Publication date: May 13, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventor: Tetsuya Kojima
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Patent number: 6733959Abstract: Photothermographic materials prepared using aqueous formulations include silver halides that are chemically sensitized using certain tellurium-containing compounds. Such tellurium-containing chemical sensitizing compounds are generally provided in aqueous solution or in an aqueous solid particulate dispersion and can be represented by the following Structure I, II, or III: Te(L)m(X1)n (II) Pd(X2)2[Te(R′)2]2 (III) wherein X represents the same or different COR, CSR, CNRRa, CR, PRRa, or P(OR)2 groups, R and Ra are independently alkyl, alkenyl, or aryl groups, L is a ligand derived from a neutral Lewis base, X1 and X2 independently represent a halo, OCN, SCN, S2CNRRa, S2COR, S2CSR S2P(OR)2, S2PRRa, SeCN, TeCN, CN, SR, OR, alkyl, aryl, N3, or O2CR group, R′ is an alkyl or aryl group, p is 2 or 4, m is 0, 1, 2, or 4, and n is 2 or 4 provided that when m is 0 or 2, n is 2 or 4, and when m is 1 or 4, n is 2.Type: GrantFiled: August 6, 2001Date of Patent: May 11, 2004Assignee: Eastman Kodak CompanyInventors: Henry J. Gysling, David A. Dickinson, Mark Lelental, John W. Boettcher
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Patent number: 6730461Abstract: A photothermographic material that comprises a support having thereon one or more thermally-developable imaging layers comprising a binder and in reactive association, a photosensitive silver halide, a non-photosensitive source of reducible silver ions, and a reducing composition for the non-photosensitive source reducible silver ions. The thermally-developable layers further comprises one or more radiation absorbing compounds that provide a total absorbance of greater than 0.6 and up to and including 3 in the thermally-developable imaging layer(s). These photothermographic materials are independently coated and dried while the material is conveyed at a rate of at least 5 meters per minute.Type: GrantFiled: October 26, 2001Date of Patent: May 4, 2004Assignee: Eastman Kodak CompanyInventors: Bryan V. Hunt, Steven H. Kong, William D. Ramsden, Gary E. Labelle
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Patent number: 6730462Abstract: This invention relates to a photothermographic element comprising a support, at least one photothermographic imaging layer, and at least one filter layer, wherein the filer layer comprises a heat-bleachable composition comprising a barbituric acid arylidene filter dye is in the presence of an effective amount of a base precursor.Type: GrantFiled: November 20, 2002Date of Patent: May 4, 2004Assignee: Eastman Kodak CompanyInventors: Ramanuj Goswami, Margaret J. Helber, Cynthia A. MacMillan, Mary C. Brick
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Publication number: 20040081925Abstract: The present invention relates to a photothermographic material, having at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder on at least one surface of a support. The photosensitive silver halide contains at least two kinds of photosensitive silver halides having respective sensitivities different from each other for a light with the same exposure wavelength and a silver iodide content of the photosensitive silver halide is 5% by mole or more.Type: ApplicationFiled: October 16, 2003Publication date: April 29, 2004Inventors: Yutaka Oka, Tomoyuki Ohzeki
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Publication number: 20040081926Abstract: A photothermographic material, comprising at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder, wherein a total silver iodide content of the photosensitive silver halide is 40% by mole or more and thermal development is started within 60 sec after exposure.Type: ApplicationFiled: October 17, 2003Publication date: April 29, 2004Inventor: Fumito Nariyuki
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Publication number: 20040067454Abstract: Nonpolymeric fluorochemicals defined as by the following Structure I are useful in thermally developable materials.Type: ApplicationFiled: October 4, 2002Publication date: April 8, 2004Applicant: Eastman Kodak CompanyInventors: Kumars Sakizadeh, Gary E. LaBelle, Aparna V. Bhave
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Patent number: 6713240Abstract: Aqueous-based photothermographic materials comprise a hydrophilic binder, preformed silver halides, an organic silver salt other than a silver carboxylate, a reducing agent composition, and one or more mercaptotriazoles as toners in one or more thermally developable imaging layers. These layers have a pH less than 7. These photothermographic materials can be used in combination with phosphor intensifying screens for radiographic imaging.Type: GrantFiled: July 11, 2002Date of Patent: March 30, 2004Assignee: Eastman Kodak CompanyInventors: Doreen C. Lynch, Chaofeng Zou, Stacy M. Ulrich
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Patent number: 6713241Abstract: Aqueous-based thermally sensitive emulsions and imaging materials include a mixture of binders in at least one imaging layer. These binder mixtures include from 70 to about 99 weight % of hydrophilic binders such as gelatin and gelatin derivatives, and the remainder of the total binder weight is composed of one or more hydrophobic binders or water-dispersible polymer latexes. These binder mixtures are particularly useful in imaging layers of thermographic and photothermographic materials and provide long term keeping and reduced crystallization of fatty acids.Type: GrantFiled: August 9, 2002Date of Patent: March 30, 2004Assignee: Eastman Kodak CompanyInventors: Kathleen M. Vaeth, Charles L. Bauer, Jon A. Hammerschmidt, David M. Teegarden
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Publication number: 20040058281Abstract: An image forming method using a photothermographic material comprising, on at least one side of a support, at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder, wherein the photothermographic material: 1) having a gamma value of 2.0 to 4.0 is developed in a thermal development device configured such that a distance between an exposing section and a developing section is not more than 50 cm; 2) having a silver salt of fatty acid at an application amount of 5 mmol/m2 to 18 mmol/m2 is developed in a thermal development device configured such that a distance between an exposing section and a developing section is not more than 50 cm; 3) is discharged from a thermal development device within 35 seconds after heating for thermal development is ceased.Type: ApplicationFiled: August 21, 2003Publication date: March 25, 2004Inventors: Katsutoshi Yamane, Sumito Yamada, Eiichi Okutsu, Tomoyuki Ohzeki, Yutaka Oka
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Patent number: 6709809Abstract: A silver salt photothermographic material is disclosed, comprising at least a light sensitive layer and at least a light insensitive layer, the light sensitive layer comprising organic silver salt grains, a light sensitive emulsion containing light sensitive silver halide grains and medium, a reducing agent and a binder, wherein at least one of the light sensitive layer and the light insensitive layer contains a silver-saving agent and the photothermographic material which has been subjected to thermal development at 123° C. for 13.5 sec. exhibits an average contrast of 2.0 to 6.0 within the density range of 0.25 to 2.0 on a characteristic curve of the photothermographic material.Type: GrantFiled: June 21, 2001Date of Patent: March 23, 2004Assignee: Konica CorporationInventors: Hiroyuki Yanagisawa, Socman Ho Kimura
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Publication number: 20040053173Abstract: Aqueous-based thermally sensitive emulsions and photothermographic imaging materials include photosensitive silver halide grains that are predominantly homogeneous and comprise at least 20 mol % iodide based on total silver in the grains. These materials provide desired Dmax and reduced image “print out”.Type: ApplicationFiled: September 18, 2002Publication date: March 18, 2004Applicant: Eastman Kodak CompanyInventors: Joe E. Maskasky, Victor P. Scaccia
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Publication number: 20040053174Abstract: The present invention provides a photothermographic material comprising a substrate and a composition provided thereon. The composition includes a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent for thermal development and a binder. Each of organic compounds comprised in an amount of approximately 0.05 g/m2 or more in the composition has a volatilization remaining ratio of 50% or more at 160° C. The photothermographic material preferably comprises, as a color tone adjuster, a combination of a phthalazine acid and a phthalic acid compound each having a specific structure. The invention further provides a method for producing the imaged photothermographic material. In the production of this material, a thermal developing device having a filter for collecting volatilized material is used.Type: ApplicationFiled: September 10, 2003Publication date: March 18, 2004Inventor: Kouta Fukui
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Publication number: 20040048186Abstract: Disclosed is a thermally sensitive imagable article and compositions therefor. The imagable article comprises a coating on a substrate, the coating comprising an amino acid or amide, and a compound capable of generating an acid upon heating. The coating optionally comprises a radiation absorbing compound. When imagewise exposed the coating has the property that exposed regions become relatively insoluble in a developer liquid whereas regions that have not been exposed remain relatively soluble in the developer and dissolve in the developer, leaving the exposed substrate in those regions.Type: ApplicationFiled: December 10, 2001Publication date: March 11, 2004Applicant: Kodak Polychrome Graphics LLC.Inventors: Gregory Turner, Denise Howard
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Patent number: 6703191Abstract: Thermally developable compositions such thermographic and photothermographic emulsions include certain triazine-thione compounds. These emulsions can be used in thermally developable materials such as thermographic and photothermographic materials to provide increased image density and shortened development time, and to allow development at lower temperatures. Such materials can have imaging layers on one or both sides of the support.Type: GrantFiled: January 14, 2003Date of Patent: March 9, 2004Assignee: Eastman Kodak CompanyInventors: Doreen C. Lynch, Stacy M. Ulrich, Paul G. Skoug
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Publication number: 20040043338Abstract: A thermally developable light-sensitive material comprising a support having thereon light-sensitive silver halide grains, an organic silver halide salt and a reducing agent, wherein when a regression line is obtained by plotting color coordinates (u*, v*) of the thermally developable light-sensitive material at optical densities of 0.5, 1.0, 1.5 and the minimum density on a two dimensional coordinates of CIE 1976 (L* u* v*) color space, in which the abscissa is u* and the ordinate is v*, a coefficient of determination R2 of the regression line is from 0.998 to 1.000.Type: ApplicationFiled: July 31, 2003Publication date: March 4, 2004Applicant: Konica CorporationInventor: Hiroyuki Yanagisawa
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Patent number: 6699648Abstract: Antistatic compositions include a fluorochemical that is a reaction product of Rf—CH2CH2—SO3H with an amine wherein Rf comprises 4 or more fully fluorinated carbon atoms. These antistatic compositions can be formulated in organic solvent-based conductive coating compositions, with or without hydrophobic binders, that can be used to form conductive layers in thermally developable materials including thermographic and photothermographic materials.Type: GrantFiled: March 27, 2002Date of Patent: March 2, 2004Assignee: Eastman Kodak CompanyInventors: Kumars Sakizadeh, Gary E. LaBelle, Michael W. Orem, Aparna V. Bhave
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Patent number: 6699647Abstract: Photothermographic imaging materials having increased photospeed are provided by certain tellurium chemical sensitizers that are added during the formulation of a photothermographic emulsion.Type: GrantFiled: October 11, 2001Date of Patent: March 2, 2004Assignee: Eastman Kodak CompanyInventors: Doreen C. Lynch, Andrea L. Opatz, Steven M. Shor, Sharon M. Simpson, Brian C. Willett, Henry J. Gysling
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Publication number: 20040038156Abstract: An image forming method using a photothermographic material including, on at least one surface of a support, at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent for silver ions, and a binder, in which (1) the photothermographic material is exposed and thermally developed during transportation at a transportation speed of 23 mm/sec or faster, (2) the non-photosensitive organic silver salt contains 30 mol % to 85 mol % of silver behenate and an amount of the time untill a leading end of the photothermographic material reaches a thermal development station after a power source for ae thermal developing apparatus is turned on is 15 minutes or less, or (3) a coating amount of silver inf the photothermographic material is 1.9 g/m2 or less and a thermal development time is 12 sec or less.Type: ApplicationFiled: May 30, 2003Publication date: February 26, 2004Inventors: Takayoshi Oyamada, Senzo Sasaoka, Katsutoshi Yamane
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Publication number: 20040033447Abstract: Aqueous-based photothermographic materials comprise a hydrophilic binder, preformed silver halides, an organic silver salt, a reducing agent composition, and one or more benzothiazolium, benzoselenazolium, or benzotellurazolium salts as antifoggants. These photothermographic materials can be used in combination with phosphor intensifying screens for radiographic imaging.Type: ApplicationFiled: August 14, 2003Publication date: February 19, 2004Applicant: Eastman Kodak CompanyInventors: Chaofeng Zou, Roger L. Klaus
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Publication number: 20040029054Abstract: Aqueous-based thermally sensitive emulsions and imaging materials include a mixture of binders in at least one imaging layer. These binder mixtures include from 70 to about 99 weight % of hydrophilic binders such as gelatin and gelatin derivatives, and the remainder of the total binder weight is composed of one or more hydrophobic binders or water-dispersible polymer latexes. These binder mixtures are particularly useful in imaging layers of thermographic and photothermographic materials and provide long term keeping and reduced crystallization of fatty acids.Type: ApplicationFiled: August 9, 2002Publication date: February 12, 2004Applicant: Eastman Kodak CompanyInventors: Kathleen M. Vaeth, Charles L. Bauer, Jon A. Hammerschmidt, David M. Teegarden
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Patent number: 6689547Abstract: A photothermographic material that comprises a support having thereon one or more thermally-developable imaging layers comprising a binder and in reactive association, a photosensitive silver halide, a non-photosensitive source of reducible silver ions, and a reducing composition for the non-photosensitive source reducible silver ions. The thermally-developable layers further comprises one or more radiation absorbing compounds that provide a total absorbance of greater than 0.6 and up to and including 3 in the thermally-developable imaging layer(s). These photothermographic materials exhibit reduced mottle without significant loss in sensitivity.Type: GrantFiled: December 5, 2001Date of Patent: February 10, 2004Assignee: Eastman Kodak CompanyInventors: Bryan V. Hunt, Steven H. Kong, William D. Ramsden, Gary E. Labelle
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Patent number: 6689548Abstract: A photothermographic imaging material comprising a support having thereon a photosensitive layer, wherein the photosensitive layer has a silver coverage of 0.8 to 2.5 g/m2 and comprises a compound represented by Formula (A) or Formula (B): wherein each R3, R4 and R5 is independently an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heterocyclic group, provided that R5 includes a silyl containing group, wherein Z2 represents OR22, X2, or OH; n2 is an integer of 1 to 3; each R21 and R22 is independently an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heterocyclic group, provided that R21 contains at least one primary amino group or at least two selected from the group consisting of primary and secondary amino groups; and X is a chlorine atom or a bromine atom.Type: GrantFiled: August 12, 2002Date of Patent: February 10, 2004Assignee: Konica CorporationInventors: Hirobumi Yamashita, Toshihisa Takeyama
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Publication number: 20040023164Abstract: Novel silver compounds can include a primary core of a photosensitive silver halide and a shell covering the primary core. This shell includes one or more non-photosensitive silver salts, each silver salt including an organic silver coordinating ligand. Other novel silver compounds are homogeneous silver salts of organic silver coordinating ligands throughout (non-core-shell). Still other silver compounds can include a primary core of a non-photosensitive metal salt and a shell covering the primary core. This shell includes one or more non-photosensitive silver salts, each silver salt including an organic silver coordinating ligand. These types of silver compounds can be used as sources of reducible silver ions in thermally developable imaging materials including thermographic and photothermographic materials.Type: ApplicationFiled: July 30, 2002Publication date: February 5, 2004Applicant: Eastman Kodak CompanyInventors: Boris B. Bokhonov, Lilia P. Burleva, David R. Whitcomb, Nepal C. Howlader, Louis M. Leichter
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Publication number: 20040023151Abstract: A negative resist material, which comprises at least a high polymer containing repeating units represented by the following general formula (1) and having a weight average molecular weight of 1,000 to 500,000. There is provided a negative resist material, in particular, a negative resist material of chemical amplification type, which shows high sensitivity, resolution, exposure latitude and process adaptability as well as good pattern shape after light exposure, and further shows superior etching resistance.Type: ApplicationFiled: January 23, 2003Publication date: February 5, 2004Applicant: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Takanobu Takeda, Osamu Watanabe, Wataru Kusaki, Ryuji Koitabashi
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Patent number: 6686133Abstract: A photothermographic recording material comprising a support and a photo-addressable thermally developable element, the photo-addressable thermally developable element containing a mixture of a substantially light-insensitive silver salt of a monocarboxylic acid and a substantially light-insensitive compound exclusive of silver succinate represented by formula (I): AgOOC—R1—COOAg wherein R1 is a straight chain saturated or unsaturated hydrocarbon group with two or three carbon atoms, optionally substituted with one or more of ═O, ═S, ═CR2R3, an alkyl group, an aryl group, an amino group, a substituted amino group, a cycloalkyl group, a hydroxy group, a thiol group, an alkyl sulphone group, an aryl sulphone group, an alkoxy group, an acyloxy group, a thioalkyl group, a thioaryl, a carbamic ester group, a halogen atom or a —(C═O)R4 group; wherein if R1 is substituted with two substituents selected from the group consisting of alkyl, thioalkyl, substituted amino and alkoxType: GrantFiled: March 19, 2002Date of Patent: February 3, 2004Assignee: Agfa-GevaertInventor: Horst Friedel
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Patent number: 6682878Abstract: A thermal development photosensitive material suitable for medical diagnoses, industrial photography, printing and COM. The material contains at least one photosensitive silver halide, a non-photosensitive organic silver salt, a binder, at least one of compounds represented by the following formula (I) and at least one of compounds represented by the following formula (II) on one surface of a substrate. The material has high sensitivity and provides an image with a tone close to a pure black tone.Type: GrantFiled: December 5, 2001Date of Patent: January 27, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Kouta Fukui, Yasuhiro Yoshioka
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Publication number: 20040013985Abstract: Aqueous-based photothermographic materials comprise a hydrophilic binder, preformed silver halides, an organic silver salt other than a silver carboxylate, a reducing agent composition, and one or more mercaptotriazoles as toners in one or more thermally developable imaging layers. These layers have a pH less than 7. These photothermographic materials can be used in combination with phosphor intensifying screens for radiographic imaging.Type: ApplicationFiled: July 11, 2002Publication date: January 22, 2004Applicant: Eastman Kodak CompanyInventors: Doreen Lynch, Chaofeng Zou, Stacy M. Ulrich
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Publication number: 20040013984Abstract: Organic solvent-based photothermographic materials comprise one or more mercaptotriazoles represented by the following Structure I as toner(s): 1Type: ApplicationFiled: July 11, 2002Publication date: January 22, 2004Applicant: Eastman Kodak CompanyInventors: Doreen C. Lynch, Stacy M. Ulrich, Chaofeng Zou
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Publication number: 20040009438Abstract: High-speed black-and-white photothermographic materials can be imaged in any suitable fashion using ultraviolet, visible, infrared, or X-radiation. They can have one or more thermally developable imaging layers on either or both sides of the support and can be imaged with or without a phosphor intensifying screen in an imaging assembly. The photothermographic emulsions and materials have a net Dmin less than 0.25, and require less than 1 erg/cm2 to achieve a density of 1.00 above net Dmin.Type: ApplicationFiled: April 16, 2003Publication date: January 15, 2004Applicant: Eastman Kodak CompanyInventors: Chaofeng Zou, Doreen C. Lynch
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Patent number: 6677106Abstract: A method for imaging patterning compositions comprising the steps of: (1) providing at least one patterning composition layer on a substrate; said patterning composition comprising: (a) at least one acid generator; (b) at least one cross linking resin or compound; (c) at least one binder resin comprising a polymer containing reactive pendant group selected from group consisting of hydroxyl, carboxylic acid, sulfonamide, active imide, alkoxymethylamides and mixtures thereof; and (d) at least one infrared absorber; (2) imagewise exposing the patterning composition layer to actinic radiation; (3) treating the imaged patterning composition layer with heat energy to treat the imaged portions of the composition layer; (4) flood exposing the heat-treated, imaged patterning composition layer with UV light for a predetermined time, said time being sufficient to promote the effective clear-out of non-imaged portions during the developing step without causing substantial deterioration of the imaged portions; andType: GrantFiled: January 3, 2002Date of Patent: January 13, 2004Assignee: Kodak Polychrome Graphics LLCInventors: Oliver Richard Blum, William Paul Heideman, Dean Ginther, Jeffrey James Collins
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Publication number: 20040002021Abstract: A heat-developable photosensitive material, which comprises a light-sensitive layer containing a light-sensitive silver halide, a light-insensitive organic silver salt, a thermal developer and a binder and a protective layer containing a fluorine compound having at least one fluorinated alkyl group, having not less than 2 carbon atoms and not more than 13 fluorine atoms and at least one anionic or nonionic hydrophilic group, and is subjected to processing by a heat-developing machine having a stock tray for heat-developable photosensitive materials placed at the height of not more than 55 cm above the floor.Type: ApplicationFiled: June 3, 2003Publication date: January 1, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventor: Katsutoshi Yamane
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Patent number: 6670978Abstract: A recording apparatus for recording on a recording medium in a heated mode includes a first emitting portion and a second emitting portion. The first emitting portion emits writing light for providing recording spots on the recording medium. The second emitting portion emits sub-heating light for providing heating spots on the recording medium. A distance between the heating spot and the recording spot is substantially constant in a main scanning direction. The recording spots are arranged in a two-dimensional pattern including columns in the main scanning direction and rows in an auxiliary scanning direction. The recording spots aligned in the columns are inclined at a predetermined angle with respect to the main scanning direction. The same number of heating spots as the columns of the recording spots is provided in parallel to the columns and inclined at the predetermined angle with respect to the main scanning direction.Type: GrantFiled: January 12, 2001Date of Patent: December 30, 2003Assignee: Fuji Photo Film Co., Ltd.Inventor: Yoshiharu Sasaki
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Publication number: 20030235791Abstract: An object of the present invention is to provide a novel heat-developable photosensitive material which hardly exerts an influence on the image color tone and exhibits high sensitivity.Type: ApplicationFiled: August 1, 2002Publication date: December 25, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Toyohisa Oya, Hirokazu Kyota, Kouta Fukui
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Patent number: 6667148Abstract: Thermally developable materials include an imaging layer containing a non-photosensitive source of reducible silver ions. Disposed over the imaging layer is a barrier layer that comprises inorganic filler particles that are intercalated or exfoliated with a hydrophilic or water-dispersible polymer. The particles have a length to thickness ratio of from about 10 to about 1000. The barrier layer can prevent migration of diffusible imaging components and by-products resulting from high temperature imaging and/or development. These thermally developable materials include both thermographic and photothermographic materials.Type: GrantFiled: January 14, 2003Date of Patent: December 23, 2003Assignee: Eastman Kodak CompanyInventors: YuanQiao Rao, Jon A. Hammerschmidt, Charles L. Bauer, Robert J. Kress, Anne M. Miller
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Publication number: 20030232288Abstract: Disclosed are photothermographic materials having, on a support, a layer that contains at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder, in which the mean silver iodide content of the photosensitive silver halide falls between 5 and 100 mol %, preferably between 40 and 100 mol %.Type: ApplicationFiled: November 1, 2002Publication date: December 18, 2003Inventors: Yutaka Oka, Tomoyuki Ohzeki, Katsutoshi Yamane, Seiichi Yamamoto, Sumito Yamada, Hiroyuki Mifune, Tadashi Inaba, Kohzaburoh Yamada, Katsuyuki Watanabe