Heat Applied After Imaging Patents (Class 430/350)
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Publication number: 20030232288Abstract: Disclosed are photothermographic materials having, on a support, a layer that contains at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder, in which the mean silver iodide content of the photosensitive silver halide falls between 5 and 100 mol %, preferably between 40 and 100 mol %.Type: ApplicationFiled: November 1, 2002Publication date: December 18, 2003Inventors: Yutaka Oka, Tomoyuki Ohzeki, Katsutoshi Yamane, Seiichi Yamamoto, Sumito Yamada, Hiroyuki Mifune, Tadashi Inaba, Kohzaburoh Yamada, Katsuyuki Watanabe
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Publication number: 20030224299Abstract: A photothermographic material comprising: a support; and a photosensitive silver halide, a nonphotosensitive organic silver salt, a reducing agent and a binder, wherein the photosensitive silver halide comprises 90% by mole or more of a silver iodide and has a silver iodobromide structure having an average silver iodide content of 35% by mole or less in vicinity of a surface thereof.Type: ApplicationFiled: April 21, 2003Publication date: December 4, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventor: Fumito Nariyuki
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Publication number: 20030219684Abstract: Disclosed is a photothermographic material comprising a support, a photosensitive layer containing a silver halide having a silver iodide content of 10 mol % or more and a reducing agent and a non-photosensitive layer provided on the support, wherein at least one of the photosensitive layer and the non-photosensitive layer contains a dye showing an absorption maximum in a wavelength range of 350 nm to 430 nm. The photothermographic material exhibits high image quality, superior color tone and superior image stability after development.Type: ApplicationFiled: November 13, 2002Publication date: November 27, 2003Inventors: Yoshiharu Yabuki, Katsutoshi Yamane, Ryo Suzuki, Rikio Inoue
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Publication number: 20030219686Abstract: There is disclosed photothermographic material exhibiting superior photographic performance and having improved latitude for variation in thermal developing conditions, comprising on a support an organic silver salt, light-sensitive silver halide and a reducing agent for silver ions, wherein the reducing agent is represented by the following formula 1Type: ApplicationFiled: April 15, 2003Publication date: November 27, 2003Inventors: Norio Miura, Ryohei Iwamoto, Kazuaki Nakamura, Hiroyuki Yasukawa, Kiyoshi Fukusaka
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Publication number: 20030219674Abstract: A photothermographic film and a method for making same is taught. The film includes a support, a photothermographic imaging layer coated on the support, and a complement film generally confining the photothermographic imaging layer between the support and the complement film. The complement film is applied to the photothermographic imaging layer prior to exposure of the photothermographic imaging layer. The complement film retains any volatile materials present in the photothermographic imaging layer generated when thermal energy is applied thereto to develop a latent image exposed on the photothermographic imaging layer.Type: ApplicationFiled: May 17, 2002Publication date: November 27, 2003Inventors: Aparna V. Bhave, Karissa L. Eckert, Kenneth W. Metz, Lawrence B. Wallace, Mridula Nair, Thomas M. Smith, Barry M. Brown
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Publication number: 20030215756Abstract: A photothermographic material comprising a support and having thereon an image forming layer containing an organic silver salt, light-sensitive silver halide grains, binder and a reducing agent, wherein the reducing agent comprises: a reducing agent A containing at least a bisphenol derivative represented by following Formula (A-1); and a reducing agent B containing at least a bisphenol derivative not represented by the Formula (A-1), and the amount of reducing agent A is 5 to 45 weight % of the total weight of the reducing agent A and reducing agent B.Type: ApplicationFiled: December 27, 2002Publication date: November 20, 2003Inventors: Kiyokazu Morita, Narito Goto, Ayumu Nishijima
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Patent number: 6649329Abstract: The present application relates to a photothermographic material comprising, on a side of a support, (a) a photosensitive silver halide, (b) a reducible silver salt, (c) a phenol derivative having the specific structure as reducing compound, (d) a binder, (e) a coupler compound, and (f) a compound represented by Q1—NHNH—V6 wherein Q1 is a 5- to 7-membered unsaturated ring and V6 is a carbamoyl group, etc.Type: GrantFiled: August 3, 2001Date of Patent: November 18, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Toyohisa Oya, Kazunobu Katoh
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Patent number: 6649338Abstract: A silver salt photohermographic material is disclosed, comprising a support having provided thereon a light-sensitive layer containing light-sensitive silver halide, a light-insensitive organic silver salt and a binder, wherein the photohermographic material exhibits a gradation of 2.0 to 5.0 within the density region of 0.5 and 2.0 on a photographic characteristic curve obtained when the photothermographic material is subjected to exposure of 50 &mgr;J/cm2 and thermal development at 124° C. for 16 sec.; the light-sensitive layer comprises lower and upper layers and a glass transition temperature of a binder contained in the lower layer being higher than that of a binder contained in the upper layer.Type: GrantFiled: June 5, 2002Date of Patent: November 18, 2003Assignee: Konica CorporationInventor: Tsuyoshi Mitsuhashi
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Publication number: 20030211428Abstract: A mono-sheet heat-developable photosensitive material, which comprises a layer containing a light-sensitive silver halide, a light-insensitive organic fatty acid silver salt, a thermal developer and a binder on a support, and exhibits substantially no sensitivity after being subjected to heat-development.Type: ApplicationFiled: April 25, 2003Publication date: November 13, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Katsutoshi Yamane, Masatoshi Nakanishi, Fumito Nariyuki
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Patent number: 6645704Abstract: The present invention is related to a method of making a color photothermographic element such as a capture film intended to be developed to yield an image by the application of heat, preferably without the addition of processing solutions. In particular, this invention relates to the annealing of a photothermographic imaging element prior to storage and use. It has been found that the use of such an annealing process improves raw stock storage and hence, the performance of color photothermographic systems.Type: GrantFiled: November 26, 2002Date of Patent: November 11, 2003Assignee: Eastman Kodak CompanyInventor: David H. Levy
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Patent number: 6645706Abstract: Thermally developable materials include a reducing agent composition that can reduce silver ions and provide high contrast images. The reducing agent composition includes a) a hindered phenol reducing agent, an aromatic di- or tri-hydroxy compound, or mixtures thereof, and b) a thermally-releasable p-phenylenediamine co-developer that is represented by the following Structure I: R—NH-BLOCK (I) wherein R—NH— is a p-phenylenediamine group and BLOCK is a blocking group that is cleaved upon exposure to at least 120° C. for at least 5 seconds and comprises one or more of the following thermally cleavable groups: —CONH—, —COO—, —CONHSO2—, —PO3—, —SO2—, —COCH2NHCO—, or —COS—, and BLOCK is directly linked to R—NH— through one of the thermally cleavable groups.Type: GrantFiled: September 17, 2002Date of Patent: November 11, 2003Assignee: Eastman Kodak CompanyInventors: Sharon M. Simpson, Takuzo Ishida
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Patent number: 6645705Abstract: The present invention is a photographic element which includes a support, at least one silver-halide emulsion layer superposed on the support and a processing-solution-permeable overcoat overlying the silver-halide emulsion layer that becomes water-resistant in the final product, without requiring lamination or fusing. The presence, in the coating composition, of a compound comprising a blocked copolymer of ethylene oxide and propylene oxide has been found to improve wet durability, prevent the retention of iron, and improve the conversion of the overcoat to a water-resistant layer during processing. The present invention is also directed to a method of making a photographic print involving developing the photographic element.Type: GrantFiled: November 5, 2001Date of Patent: November 11, 2003Assignee: Eastman Kodak CompanyInventors: Hwei-Ling Yau, Kevin M. O'Connor, Elmer C. Flood, David E. Decker
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Publication number: 20030207216Abstract: The present invention provides a photothermographic material comprising a support and an image forming layer provided thereon, the image forming layer including at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder, the photothermographic material meets at least one of the following conditions of (i) and (ii):Type: ApplicationFiled: April 1, 2003Publication date: November 6, 2003Inventors: Kouta Fukui, Eiichi Okutsu, Fumito Nariyuki
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Publication number: 20030207218Abstract: A photothermographic imaging material comprising a support having thereon a sublayer and a photosensitive layer in the order, the photosensitive layer comprising photosensitive silver halide grains, light-insensitive organic silver salt grains, a binder, and a reducing agent for silver ions, wherein the sublayer comprises: (i) a first polymer selected from the group consisting of a polyester and a polyester derivative; and (ii) a second polymer selected from the group consisting of a vinyl polymer latex, a water-soluble polymer containing a vinyl polymer component, a styrene-diolefin copolymer and a polyurethane.Type: ApplicationFiled: April 17, 2003Publication date: November 6, 2003Inventors: Takayuki Sasaki, Tadashi Arimoto, Kenji Ohnuma
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Publication number: 20030203323Abstract: A photothermographic imaging material comprising a support having thereon a photosensitive layer comprising photosensitive silver halide grains, light-insensitive organic silver salt grains, a binder, and a reducing agent for silver ions, wherein the silver halide grains are capable of: (a) forming surface latent images when exposed prior to heating development; and (b) forming internal latent images when exposed after heating development.Type: ApplicationFiled: March 5, 2003Publication date: October 30, 2003Inventors: Hideki Takiguchi, Soc Man Ho Kimura
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Publication number: 20030203322Abstract: The present invention provides a spectrally sensitized photothermographic silver halide element support having a first surface and a second surface, a photothermographic composition that is to be exposed to a laser being disposed on the first surface of the support. The element has at least one back layer disposed on the second surface of the support. The photothermographic composition comprises silver halide emulsion grains having a number average grain size of less than 0.1 &mgr;m and that are spectrally sensitized with a sensitizing dye having a spectral sensitivity that corresponds to the spectral properties of the laser. The photothermographic composition further comprises an organic silver salt, a reducing agent for silver ions, and at least one dye. In addition, the photothermographic composition has a transmission optical density greater than 0.1 at the exposure wavelength, and the back layer has a transmission optical density greater than 0.1 at the exposure wavelength.Type: ApplicationFiled: December 23, 2002Publication date: October 30, 2003Applicant: Eastman Kodak CompanyInventors: Thomas C. Geisler, Thomas J. Kub, Darlene F. Stewart, Mark C. Skinner, Bryan V. Hunt
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Patent number: 6638682Abstract: A method for applying an image to a receptor element, which comprises the steps of (i) providing a transfer sheet comprising a support having a first surface and a second surface, and a coating capable of receiving an image on the first surface of the support, (ii) imaging the coating, (iii) dry peeling the coating from the support in the absence of wet release prior to hand ironing, (iv) positioning the dry peeled coating on a receptor element having valleys or pores, (v) positioning a non-stick sheet on the dry peeled coating which is positioned on the receptor element having valleys or pores, and (vi) heating the non-stick sheet to drive the dry peeled coating into the receptor element having valleys or pores.Type: GrantFiled: November 29, 2001Date of Patent: October 28, 2003Assignee: Foto-Wear!, Inc.Inventors: Donald S. Hare, Scott A. Williams
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Publication number: 20030198901Abstract: Antistatic compositions include a fluorochemical that is a reaction product of Rf—CH2CH2—SO3H with an amine wherein Rf comprises 4 or more fully fluorinated carbon atoms. These antistatic compositions can be formulated in organic solvent-based conductive coating compositions, with or without hydrophobic binders, that can be used to form conductive layers in thermally developable materials including thermographic and photothermographic materials.Type: ApplicationFiled: March 27, 2002Publication date: October 23, 2003Applicant: Eastman Kodak CompanyInventors: Kumars Sakizadeh, Gary E. LaBelle, Michael W. Orem, Aparna V. Bhave
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Publication number: 20030194658Abstract: A photothermographic imaging material comprising a support having thereon a photosensitive layer comprising a photosensitive silver halide, a light-insensitive organic silver salt, a binder, and a reducing agent for silver ions,Type: ApplicationFiled: July 11, 2002Publication date: October 16, 2003Applicant: KONICA CORPORATIONInventors: Ayumu Nishijima, Kiyokazu Morita, Norio Miura, Kazuaki Nakamura, Ryohei Iwamoto, Kiyoshi Fukusaka
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Publication number: 20030194660Abstract: The present invention provides a heat developable light sensitive material comprising a support and a constituent layer disposed on one surface of the support and including a light sensitive layer, wherein the constituent layer includes a binder, an organic silver salt, a reducing agent for silver ion, light sensitive silver halide grains, and at least one polymer binder selected from a group consisting of polyvinyl butyral, cellulose acetate, cellulose butyrate and derivatives thereof, and a mercury content of the constituent layer is no more than 1 mg/m2, and a logarithmic value of the cross sectional resistance value (&OHgr;) of the light sensitive material is no more than 12, and a coated amount of silver is no more than 1.9 g/m2, and image forming methods using the above-described heat developable light sensitive material.Type: ApplicationFiled: February 25, 2003Publication date: October 16, 2003Inventor: Senzou Sasaoka
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Publication number: 20030194659Abstract: A heat-developable photosensitive material includes at least a photosensitive silver halide particle, a nonphotonsensitive organic silver salt, a developing accelerator, a reducing agent and a binder on a support, wherein the photosensitive silver halide includes silver iodide at 5 mol % to 100 mol % and the average particle size of the photosensitive silver halide is 5 nm to 80 nm. A heat developing method for the heat-developable photosensitive material is also disclosed.Type: ApplicationFiled: September 11, 2002Publication date: October 16, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Tomoyuki Ohzeki, Katsutoshi Yamane
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Publication number: 20030194667Abstract: A heat-developable photosensitive material comprising on a support light-sensitive silver halide, a light-insensitive organic silver salt, a reducing agent and a binder, wherein at least 30 mole % of the total light-sensitive silver halide is silver halide of high silver iodide content having an average &ggr;-phase proportion of from 5 to 70 mole %, and a method of forming images on the heat-developable photosensitive material with a semiconductor laser.Type: ApplicationFiled: February 27, 2003Publication date: October 16, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventor: Fumito Nariyuki
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Patent number: 6632625Abstract: Mutant ob receptors have been made which a) lack a functional first CK-F3 domain; b) lack a functional second CK-F3 domain or c) lack a functional intracellular domain. These receptors may be used in various assays, such as a transactivation assay to identify novel ligands.Type: GrantFiled: December 2, 1997Date of Patent: October 14, 2003Assignee: Merck & Co., Inc.Inventors: Tung M. Fong, Ruey-Ruey C. Huang, Leonardus Van Der Ploeg
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Publication number: 20030190568Abstract: The thermally developable photosensitive material of the present invention has a support and including on at least one surface of the support a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent for thermal development, a binder and a compound represented by the following general formula (1): 1Type: ApplicationFiled: March 25, 2003Publication date: October 9, 2003Inventors: Yasuhiro Yoshioka, Keiichi Suzuki
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Publication number: 20030190558Abstract: There is described a thermal development apparatus, which makes it possible to prevent generation of density variations caused by changes of the processing temperature during the thermal developing operation when the thermal developing photosensitive material is continuously processed, without increasing the cost of the apparatus so much. The thermal development apparatus includes a thermal developing processor to apply a thermal development processing to the thermal developing photosensitive material, a detector to detect the thermal developing photosensitive material to be conveyed into the thermal developing processor and a controller to control the thermal developing processor in a feed forward controlling mode based on a processing condition of the thermal developing processor. The processing condition is established in advance, corresponding to a load of processing the thermal developing photosensitive material detected in advance by the detector.Type: ApplicationFiled: April 2, 2003Publication date: October 9, 2003Applicant: KONICA CORPORATIONInventors: Takehiro Shiraishi, Makoto Sumi, Makoto Horiuchi
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Patent number: 6630291Abstract: Aqueous-based thermally sensitive emulsions and photothermographic imaging materials include phthalazine N-oxide or a derivative thereof to improve raw stock keeping and to extend the useful range of processing temperatures without interfering with spectral sensitization. The emulsions and photothermographic materials may also include a cyclic imide, phthalazinone, benzoxazine dione, benzthiazine dione, or quinazoline dione as a development promoter.Type: GrantFiled: August 21, 2002Date of Patent: October 7, 2003Assignee: Eastman Kodak CompanyInventors: Joe E. Maskasky, Victor P. Scaccia, David A. Dickinson
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Publication number: 20030186176Abstract: A silver halide photosensitive material having a substrate, a heat-responsive-discolorable coloring layer and a photosensitive layer coated thereon and having a silver halide, dye-providing compound and a binder, the heat-responsive-discolorable coloring layer containing a heat-responsive-discolorable coloring composition, which is colored at a temperature lower than its discoloration initiation temperature (T) of 60 to 200° C.; which is substantially discolored at a temperature equal to or higher than T; and which does not recover its color once discolored, even when its temperature is lowered to a temperature lower than T again, and the heat-responsive-discolorable coloring composition containing a polymer having a glass transition temperature of 60 to 200° C.Type: ApplicationFiled: October 25, 2002Publication date: October 2, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Jun Arakawa, Takahiro Ishizuka
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Patent number: 6620577Abstract: Photothermographic imaging materials having increased photospeed are provided by certain selenium chemical sensitizers that are added during the formulation of a photothermographic emulsion. These selenium chemical sensitizers can be used alone or in combination with other sulfur, tellurium, or gold chemical sensitizers as well as with oxidatively decomposed sulfur-containing compounds.Type: GrantFiled: February 25, 2002Date of Patent: September 16, 2003Assignee: Eastman Kodak CompanyInventors: Doreen C. Lynch, Andrea L. Opatz, Henry J. Gysling, Sharon M. Simpson
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Patent number: 6620562Abstract: The present invention is directed to a method of scanning silver-halide-containing color photographic and photothermographic film. In particular, the present invention comprises a photographic element comprising at least one infrared imaging dye-forming agent in a blue-sensitive color layer of the element, thereby forming at least one image record in the infrared region of the imagewise exposed and developed element. This expedient leads to the formation of high quality images when scanning photographic elements in which the silver halide, metallic silver, and/or any organic silver salts have not been removed.Type: GrantFiled: August 13, 2001Date of Patent: September 16, 2003Assignee: Eastman Kodak CompanyInventors: James H. Reynolds, David H. Levy, Robert W. Kulpinski, Leif P. Olson, Wojciech K. Slusarek
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Publication number: 20030170573Abstract: Disclosed is a photothermographic material comprising a support having disposed on a surface thereof, a non-photosensitive silver source, a photosensitive silver halide, and a reducing agent, and having disposed another surface thereof at least one non-photosensitive layer, wherein at least one of the non-photosensitive layers contains at least one type of gelatin having an isoelectric point of from 5.0 to 9.5; and a method for processing the photothermographic material.Type: ApplicationFiled: December 23, 2002Publication date: September 11, 2003Inventor: Rikio Inoue
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Publication number: 20030170576Abstract: A heat-developable photosensitive material comprising a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder contained in one side of a support, wherein chloride ion concentration in the entire layer positioned on the photosensitive silver halide-containing side of the support is 600 ppm or less based on the weight of the organic silver salt, and the heat-developable photosensitive material contains a compound represented by formula (I) defined in the specification.Type: ApplicationFiled: December 16, 2002Publication date: September 11, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventor: Kouta Fukui
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Publication number: 20030162140Abstract: A heat-developable image recording material comprises a support; a photosensitive silver halide; a reducing agent for a silver ion; a hinder; and a non-photosensitive organic silver salt grain, wherein the non-photosensitive organic silver salt grain has: 1) a silver stearate content of 1 mol % or less; 2) a length/width ratio of 1 to 9; 3) an aspect ratio of 1.1 to 30; and 4) an equivalent-sphere diameter of 0.05 to 1 &mgr;m.Type: ApplicationFiled: December 26, 2001Publication date: August 28, 2003Inventors: Takayoshi Oyamada, Itsuo Fujiwara
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Publication number: 20030162134Abstract: A photothermographic material that comprises a support having thereon one or more thermally-developable imaging layers comprising a binder and in reactive association, a photosensitive silver halide, a non-photosensitive source of reducible silver ions, and a reducing composition for the non-photosensitive source reducible silver ions. The thermally-developable layers further comprises one or more radiation absorbing compounds that provide a total absorbance of greater than 0.6 and up to and including 3 in the thermally-developable imaging layer(s). These photothermographic materials exhibit reduced mottle without significant loss in sensitivity.Type: ApplicationFiled: December 5, 2001Publication date: August 28, 2003Applicant: Eastman Kodak CompanyInventors: Bryan V. Hunt, Steven H. Kong, William D. Ramsden, Gary E. Labelle
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Patent number: 6610450Abstract: This invention comprises an imaging element comprising an imaging layer having associated therewith a phenolic activating agent in combination with a blocked color-forming agent of Structure I: wherein PUG is a photographically useful color-forming agent, LINK 1 and LINK 2 are linking groups; TIME is a timing group; HET is a heterocyclic group, and the other groups are as defined in the specification.Type: GrantFiled: June 1, 2001Date of Patent: August 26, 2003Assignee: Eastman Kodak CompanyInventors: Xiqiang Yang, Zbyslaw R. Owczarczyk, David T. Southby
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Publication number: 20030157442Abstract: Disclosed is a photothermographic material containing a photosensitive silver halide, a non-photosensitive silver salt of an organic acid, a reducing agent for silver ions and a binder on one surface of a support, wherein a ratio of twin crystal grains of the photosensitive silver halide is 1.0% or less with respect to the total grain number of the photosensitive silver halide. This photothermographic material shows high sensitivity, low fog, high Dmax (maximum density) and little increase of fog during storage.Type: ApplicationFiled: June 7, 2002Publication date: August 21, 2003Inventor: Tokuju Oikawa
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Patent number: 6607872Abstract: A photothermographic recording material comprising a photo-addressable thermally developable element coatable from aqueous media comprising a substantially light-insensitive organic silver salt, photosensitive silver halide in catalytic association with the substantially light-insensitive organic silver salt and a reducing agent in thermal working relationship with the substantially light-insensitive organic silver salt and a binder, characterized in that the binder comprises a water-soluble polymer, a water-dispersible polymer or a mixture of a water-soluble polymer and a water-dispersible polymer and particles of the photosensitive silver halide are non-aggregating in the photo-addressable thermally developable element and are uniformly distributed over and between particles of the substantially light-insensitive organic silver salt, at least 80% by number of the particles having a diameter, determined by transmission electron microscopy, of ≦40 nm; and a recording process therefor.Type: GrantFiled: June 14, 1999Date of Patent: August 19, 2003Assignee: Agfa-GevaertInventors: Herman Uytterhoeven, Yvan Gilliams, Johan Loccufier, Sabine Emmers, Ronny De Clercq
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Patent number: 6605418Abstract: Thermally developable compositions such thermographic and photothermographic emulsions include certain quaternary phthalazine compounds. These emulsions can be used in thermally developable materials such as thermographic and photothermographic materials to provide improved sensitometric and post processing properties. Such materials can have imaging layers on one or both sides of the support.Type: GrantFiled: October 28, 2002Date of Patent: August 12, 2003Assignee: Eastman Kodak CompanyInventors: William D. Ramsden, Chaofeng Zou
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Publication number: 20030143500Abstract: A heat-developable photosensitive material comprises: a support; a light-sensitive silver halide; a reducing agent for a silver ion; a binder; and a light-insensitive organic silver salt grain, wherein the light-insensitive organic silver salt grain contains a silver behenate in an specific amount.Type: ApplicationFiled: June 27, 2002Publication date: July 31, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Takayoshi Oyamada, Kouta Fukui, Toyohisa Oya, Eiichi Okutsu, Yasuhiro Yoshioka
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Thermally developable imaging materials having improved shelf stability and stabilizing compositions
Patent number: 6599685Abstract: Thermally developable photothermographic materials comprise a backside layer that includes a toner as a backside stabilizer. Useful backside stabilizers include pyridazine, phthalazine, phthalazinone, benzoxazine dione, benzthiazine dione, or quinazoline dione compounds, or derivatives of any of these compounds to provide improved shelf stability. These backside stabilizers can be provided particularly in non-photosensitive compositions that include an antihalation composition.Type: GrantFiled: January 8, 2002Date of Patent: July 29, 2003Assignee: Eastman Kodak CompanyInventor: Steven H. Kong -
Patent number: 6599686Abstract: The present invention provides a spectrally sensitized photothermographic silver halide element comprising a support layer having on at least one surface thereof a photothermographic composition which displays uniform image density across its surface when exposed to floodlight or uniform incandescent light exposure at radiation wavelengths to which the element is sensitive, said element comprising at least two layers, including a top layer and a photothermographic emulsion layer, said photothermographic emulsion layer comprising a binder, a light insensitive silver source, a reducing agent for silver ion and infrared radiation sensitive silver halide grains, wherein the coherent radiation is rendered more diffuse in its passage through the element than when it strikes the top layer. This may be accomplished at least in part by 1) the top layer of the element having haze induced therein of 0.Type: GrantFiled: June 5, 2002Date of Patent: July 29, 2003Assignee: Eastman Kodak CompanyInventors: Thomas C. Geisler, Thomas J. Kub, Darlene F. Stewart, Paul C. Schubert, James C. Vanous, Mark C. Skinner
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Patent number: 6599676Abstract: A process for making thermally imageable negative working compositions comprising the steps of: (1) providing a patterning composition layer on a substrate, said patterning composition comprising: (a) at least one thermal-generator acid generator, (b) at least one cross-linking resin or compound; (c) at least one binder resin comprising a polymer containing at least one reactive pendent group selected from the group, consisting of hydroxyl, carboxylic acid, sulfonamide, alkoxymethylamide and mixtures thereof; and (d) at least one infrared absorber; (2) subjecting the patterning composition layer to a two-stage radiation exposure; (a) one stage being a flood UV-exposure; and (b) the other stage being a imagewise infrared exposure stage; (3) treating the exposed patterning composition with heat energy; and (4) developing the heat treated, exposed patterning composition with an aqueous alkaline developer to remove the non-imaged areas of the patterning composition and leaving the imaged areas substantiType: GrantFiled: January 3, 2002Date of Patent: July 29, 2003Assignee: Kodak Polychrome Graphics LLCInventors: Celin Savariar-Hauck, Hans-Joachim Timpe
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Patent number: 6599684Abstract: The present invention is directed to a photothermographic element comprising at least one imaging layer with a pyrrolotriazole coupler and a developing agent, or precursor thereof, the combination of which is capable of forming an image record in the infrared region of the light spectrum in response to a selected hue of visible light. This expedient leads to the formation of high quality images, especially when scanning photothermographic elements in which the silver halide, metallic silver, and/or any organic silver salts have not been removed. Also disclosed is a method for photothermographically forming a developed image comprising an infrared image record.Type: GrantFiled: August 13, 2001Date of Patent: July 29, 2003Assignee: Eastman Kodak CompanyInventors: James H. Reynolds, Leif P. Olson, Wojciech K. Slusarek, David H. Levy
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Publication number: 20030138739Abstract: A photothermographic material comprises: a support; a binder; an organic silver salt; a reducing agent for silver ion; and a photosensitive silver halide grain, wherein said photothermographic material contains a solvent in an amount of from 5 to 1,000 mg/m2 and the intensity of an odor generated from said photothermographic material is from −3 to 1 at 120° C.Type: ApplicationFiled: September 10, 2002Publication date: July 24, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Senzo Sasaoka, Yutaka Tamura
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Publication number: 20030138738Abstract: A photothermographic material that comprises a support having thereon one or more thermally-developable imaging layers comprising a binder and in reactive association, a photosensitive silver halide, a non-photosensitive source of reducible silver ions, and a reducing composition for the non-photosensitive source reducible silver ions. The thermally-developable layers further comprises one or more radiation absorbing compounds that provide a total absorbance of greater than 0.6 and up to and including 3 in the thermally-developable imaging layer(s). These photothermographic materials are independently coated and dried while the material is conveyed at a rate of at least meters per minute.Type: ApplicationFiled: December 5, 2001Publication date: July 24, 2003Applicant: Eastman Kodak CompanyInventors: Bryan V. Hunt, Steven H. Kong, William D. Ramsden, Gary E. Labelle
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Publication number: 20030138740Abstract: A photothermographic material comprising: a transparent support; and a photosensitive layer comprising a photosensitive silver halide, a non-photosensitive organic silver salt, a thermal developer and a binder, wherein the photosensitive silver halide comprises silver iodide in a ratio of 5% by mole or more, the non-photosensitive organic silver salt comprises silver behenate in a ratio of 30% by mole or more and less than 80% by mole, and the binder has a glass transition temperature of 45° C. or more.Type: ApplicationFiled: October 4, 2002Publication date: July 24, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventor: Sumito Yamada
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Publication number: 20030139292Abstract: A black and white thermographic recording material comprising a thermosensitive element and a support, the thermosensitive element containing at least one substantially light-insensitive organic silver salt, a binder and optionally photosensitive silver halide, characterized in that the thermosensitive element further contains deliberately added metal nano-particles in a molar ratio with respect to the total molar concentration of the at least one substantially light-insensitive organic silver salt in the range of 0.05:1 to 10−6:1; and the use for the purpose of increasing the ratio of Dmax to the quantity of said substantially light-insensitive organic silver salts per unit area of the above-mentioned thermographic recording material.Type: ApplicationFiled: November 27, 2002Publication date: July 24, 2003Applicant: AGFA-GEVAERTInventors: Ingrid Geuens, Luc Verberckt, Ivan Hoogmartens, Frank De Voeght, Iris Vanwelkenhuysen
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Patent number: 6596470Abstract: A heat-developable light-sensitive material, which at least contains: (a) a photosensitive silver halide; (b) a reducible silver salt; (c) a dispersion of fine crystalline particles of a color-developing agent; (d) a dispersion of fine crystalline particles of a coupler capable of reacting with an oxidized product of the color-developing agent, to form a dye; (e) a dispersion of fine crystalline particles of a thermal solvent; and (f) a binder, each of which is contained on the same side of a support. An image-forming method, which utilizes the heat-developable light-sensitive material.Type: GrantFiled: November 27, 2001Date of Patent: July 22, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Kazuhiko Matsumoto, Toshio Kawagishi
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Publication number: 20030124473Abstract: A silver salt photothermographic material is disclosed, comprising a support having provided thereon a light-sensitive layer containing light-sensitive silver halide, a light-insensitive organic silver salt and a binder, wherein the photothermographic material exhibits a gradation of 2.0 to 5.0 within the density region of 0.5 and 2.0 on a photographic characteristic curve obtained when the photothermographic material is subjected to exposure of 50 &mgr;J/cm2 and thermal development at 124° C. for 16 sec.; the light-sensitive layer comprises lower and upper layers and a glass transition temperature of a binder contained in the lower layer being higher than that of a binder contained in the upper layer.Type: ApplicationFiled: June 5, 2002Publication date: July 3, 2003Inventor: Tsuyoshi Mitsuhashi
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Patent number: 6586165Abstract: The present invention is a photographic element which includes, in order, a transparent support, at least one silver halide emulsion layer superposed on the support, optionally a white or diffuse reflective layer, and a processing-solution-permeable protective layer on the backside, which protective layer becomes water-resistant in the final product without lamination or fusing. The present invention is also directed to a method of making a photographic print involving developing the photographic element. The resulting print is viewed through the support, which provides protection against scratches and stains, while the polymeric overcoat provides water and stain protection to the reverse of the print where minor scratches or damage are not critical, since the image is not viewed from this side. Thus, this invention provides for a tough, stain resistant and transparent viewing surface and a stain resistant back side, which is permeable to processing solutions.Type: GrantFiled: April 27, 2001Date of Patent: July 1, 2003Assignee: Eastman Kodak CompanyInventors: Kevin M. Donovan, Glenn M. Brown, Lloyd A. Lobo
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Patent number: 6586166Abstract: This invention involves use of ionic liquids as addenda in a photothermographic system. The presence of an ionic liquid was found to increase image density. A preferred ionic liquid comprises an organic cation associated with a suitable anion, which ionic liquid melts at a temperature of 50° C. or less.Type: GrantFiled: November 21, 2001Date of Patent: July 1, 2003Assignee: Eastman Kodak CompanyInventors: Leif P. Olson, James H. Reynolds