Color Development Patents (Class 430/351)
-
Patent number: 4499172Abstract: A heat-developable color light-sensitive material comprising a support having thereon at least a light-sensitive silver halide, a binder, a dye releasing redox compound which is capable of reducing the light-sensitive silver halide and is capable of reacting with the light-sensitive silver halide by heating to release a hydrophilic dye and a salt of an alkylcarboxylic acid having a triple bond between the .alpha.-position carbon atom and the .beta.-position carbon atom with an organic base as a base precursor.The heat-developable color light-sensitive material containing the novel base precursor has good stability during preservation and provides a color image having a high color density and low fog in a short time by a simple procedure. A method of forming a color image using the heat-developable color light-sensitive material is also disclosed.Type: GrantFiled: March 30, 1984Date of Patent: February 12, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Hirai, Kozo Sato
-
Patent number: 4483914Abstract: A heat-developable color photographic material is disclosed. The material is comprised of a support having thereon a layer containing at least a light-sensitive silver halide, an organic silver salt oxidizing agent, a hydrophilic binder, a reducing agent for the silver halide and/or the organic silver salt oxidizing agent and a dye releasing compound which is capable of bonding to an oxidized product of the reducing agent and releasing a hydrophilic dye. The heat-developable color photographic material can easily provide a clear and stable color image by imagewise exposure to light and a heat development procedure. A method of forming a color image using the heat-developable color photographic material is also disclosed.Type: GrantFiled: November 4, 1982Date of Patent: November 20, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Hideki Naito, Hiroshi Hara, Kozo Sato
-
Patent number: 4481284Abstract: A silver halide photographic light-sensitive material is disclosed, comprising a support having thereon at least one light-sensitive silver halide emulsion layer and a light-insensitive uppermost layer. The light-insensitive uppermost layer has a melting time longer than that of the light-sensitive silver halide emulsion layer and a thickness of the light-insensitive uppermost layer is from 0.3 .mu.m to 0.8 .mu.m. The silver halide photographic light-sensitive material causes a remarkably lower degree of reticulation, can reduce the amount of scum formed in the processing solution, and has an improved covering power.Type: GrantFiled: September 21, 1982Date of Patent: November 6, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Masashi Ogawa, Kunio Ishigaki, Nobuyuki Iwasaki, Taku Nakamura
-
Patent number: 4473631Abstract: A heat-developable color photographic material is disclosed. The material is comprised of a support having thereon at least a light-sensitive silver halide, a hydrophilic binder, a dye releasing compound reductive and capable of releasing a hydrophilic dye and a compound represented by the following general formula (A): ##STR1## wherein A.sub.1, A.sub.2, A.sub.3, and A.sub.4, which may be the same or different, each represents a hydrogen atom or a substituent selected from an alkyl group, a substituted alkyl group, a cycloalkyl group, an aralkyl group, an aryl group, a substituted aryl group and a heterocyclic group, or A.sub.1 and A.sub.2 or A.sub.3 and A.sub.4 may combine with each other to form a ring.The heat-developable color photographic material can easily provide in a short time a clear and stable color image having a high color density and low fog by imagewise exposure and heat development procedure.Type: GrantFiled: November 4, 1983Date of Patent: September 25, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Hirai, Hideki Naito, Hiroshi Hara, Kozo Sato
-
Patent number: 4469773Abstract: A coupler containing in the coupling position a carbamoyloxy group ##STR1## upon oxidative coupling, releases a carbamic acid fragment that, in turn, is capable of thermally releasing ammonia or an amine. Such a carbamoyloxy substituted coupler and carbamic acid fragment are useful in imaging such as in photothermography and thermography. Ammonia or an amine released from the carbamic acid fragment enables imaging in imaging materials that are responsive to ammonia or an amine. The carbamoyloxy substituted coupler also generally is a dye-forming coupler that reacts with the oxidized form of a color developing agent to form a dye. An image is produced in an exposed photothermographic material comprising the carbamoyloxy substituted coupler by thermal development. An image is produced in a thermographic material comprising the carbamoyloxy substituted coupler and a color developing agent by imagewise heating the thermographic material.Type: GrantFiled: June 15, 1983Date of Patent: September 4, 1984Assignee: Eastman Kodak CompanyInventors: Anthony Adin, Csaba A. Kovacs, Delwyn E. Machiele
-
Patent number: 4463079Abstract: A diffusion transfer heat-developable color photographic material. The material comprises a support, a photosensitive silver halide, an organic silver salt, a hydrophobic binder, a dye releasing activator, and a dye releasing redox compound which releases a diffusible dye. Color images are obtained with the material by transferring a dye released by heat development. The material makes it possible to obtain clear color images by a simple procedure and the images obtained are stable over a long period of time.Type: GrantFiled: April 30, 1982Date of Patent: July 31, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Hideki Naito, Hiroshi Hara, Kozo Sato
-
Patent number: 4460681Abstract: Color photothermographic articles are prepared by having the various color-forming layers separated by organic solvent soluble barrier layers insoluble in the organic solvent used to coat at least one of the adjacent color-forming layers.Type: GrantFiled: March 15, 1983Date of Patent: July 17, 1984Assignee: Minnesota Mining and Manufacturing CompanyInventor: Robert A. Frenchik
-
Patent number: 4452883Abstract: A photothermographic color construction is disclosed, the construction having at least two color-forming layers comprising:a. a first, spectrally-sensitized, color-forming layer coated out of a solvent system selected from lower alkyl alcohols (up to 4 carbon atoms) ketones (up to 6 carbon atoms), aromatic hydrocarbons (up to 10 carbon atoms), or mixtures thereof,b. an upper, second, different, spectrally-sensitized color-forming layer coated out of a toluene or acetone solvent system, andc.Type: GrantFiled: May 17, 1983Date of Patent: June 5, 1984Assignee: Minnesota Mining and Manufacturing CompanyInventors: Robert A. Frenchik, Kristen A. Hoff
-
Patent number: 4430415Abstract: A heat-developable color photographic material is disclosed. The material is comprised of a support having thereon a layer containing fine droplets of complex coacervate containing a light-sensitive silver halide, an organic silver salt oxidizing agent and a color image forming substance which are prepared by complex coacervation and hardened with a hardening agent. Color fog does not occur with the material and it can be easily prepared to provide a color image having good color balance by imagewise exposure to light and a heat development procedure. A process for forming a color image using the heat-developable color photographic material is also disclosed.Type: GrantFiled: September 2, 1982Date of Patent: February 7, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiaki Aono, Hiroshi Hara, Hideki Naito, Kozo Sato
-
Patent number: 4430420Abstract: In a photothermographic silver halide material and process for preparing an enhanced silver image, an aminosulfonylhydrazone that is capable of developing an image in the photothermographic material and that is capable, upon oxidation, of releasing an aminosulfinic acid, which, in turn, thermally releases ammonia or amine provides a silver image in the photothermographic material and provides ammonia or amine for activation of an ammonia or amine responsive imaging material. After imagewise exposure of the photothermographic material, a silver image enhanced by an image in the ammonia or amine responsive imaging material is produced by heating the photothermographic material.Type: GrantFiled: August 27, 1982Date of Patent: February 7, 1984Assignee: Eastman Kodak CompanyInventor: Anthony Adin
-
Patent number: 4426441Abstract: In a dye-forming imaging material comprising (a) a dye-forming coupler, and (b) an organic reducing agent that is capable in its oxidized form of reacting with the dye-forming coupler to form a dye, improvements are provided by a reducing agent that is a ureidoaniline silver halide developing agent free of strong electron withdrawing groups. Such an imaging material can be a photographic silver halide material. The imaging material can be a photothermographic material for producing a dye image comprising, in reactive association, (a) photographic silver halide, (b) a dye-forming coupler, and (c) an oxidation-reduction image forming combination comprising (1) an organic silver salt oxidizing agent, and (2) an organic reducing agent for the organic silver salt oxidizing agent, wherein the reducing agent is a ureidoaniline which is capable in its oxidized form of reacting with the dye-forming coupler to form a dye.Type: GrantFiled: December 3, 1982Date of Patent: January 17, 1984Assignee: Eastman Kodak CompanyInventors: Anthony Adin, Roy C. DeSelms
-
Patent number: 4418140Abstract: A process for the development of color photographic light-sensitive material is described. The process comprises color developing an exposed light-sensitive material in the presence of a compound of the general formula: ##STR1## wherein M is a hydrogen atom, an alkali metal atom, NH.sub.4 or a protective group for the mercapto group which undergoes cleavage by the action of an alkali; R is a hydrogen atom or an alkyl group containing 1 to 3 carbon atoms; and R' is a hydrogen atom or an alkyl group containing 1 to 3 carbon atoms. This process prevents the formation of color development fog without seriously reducing sensitivity.Type: GrantFiled: April 8, 1982Date of Patent: November 29, 1983Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Mifune, Shoji Ishiguro, Tadao Shishido, Tatsuo Nishimura
-
Patent number: 4411984Abstract: A diphenylamine compound that is a precursor for a phenazine dye comprises, in an ortho position to the amine of the diphenylamine, a sulfonyldiamido group (--NHSO.sub.2 NHR) that is capable of releasing a sulfonylamine fragment upon oxidation. The diphenylamine compound upon oxidation intramolecularly cyclizes to a phenazine dye. The sulfonylamine fragment is capable of thermally releasing ammonia or an amine. The diphenylamine compound and sulfonylamine fragment are useful in imaging such as in photothermography. Ammonia or an amine thermally released from the sulfonylamine fragment enables imaging in imaging materials that are responsive to ammonia or an amine. The diphenylamine compound also generally is a silver halide developing agent.Type: GrantFiled: May 3, 1982Date of Patent: October 25, 1983Assignee: Eastman Kodak CompanyInventor: Rolf S. Gabrielsen
-
Patent number: 4390617Abstract: The present invention is directed towards a silver halide photographic material which has a reducing agent for silver halide or a precursor thereof and a compound M.sub.1 H.sub.m (PO.sub.n).sub.i.jH.sub.2 O which generates base when heat is applied. M is a metal from the Groups IA and IIA of the Periodic Table, 1 and i are individually integers from 1 to 3, m is an integer from 0 to 4, n is 3 or 4, and j is an integer from 0 to 12.Type: GrantFiled: March 5, 1981Date of Patent: June 28, 1983Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Kenichiro Okaniwa, Toyoaki Masukawa, Kiyoshi Yamashita, Wataru Ishikawa
-
Patent number: 4379835Abstract: A thermographic imaging system comprising a single layer and capable of providing a stable dark to black image upon localized heating is disclosed. The single layer comprises a polymeric binder, a combination of at least two leuco dyes, and a nitrate salt.Type: GrantFiled: December 22, 1980Date of Patent: April 12, 1983Assignee: Minnesota Mining and Manufacturing CompanyInventors: Robert D. Lowrey, Howard D. Nelson, George Van Dyke Tiers
-
Patent number: 4374916Abstract: In an electrically activatable recording element improvements are provided by an electrically conductive interlayer (ECI layer) separating (a) an electrically activatable recording layer from (b) a photoconductive layer or electrical activating means. The ECI layer comprises electrically conductive particles uniformly dispersed in an electrically insulating binder. The interlayer enables imaging with a minimized air gap between (a) and (b). The recording element is room light handleable. The element provides an image by dry development processing or by means of processing solutions.Type: GrantFiled: November 27, 1981Date of Patent: February 22, 1983Assignee: Eastman Kodak CompanyInventors: Mark Lelental, Gary M. Goncher
-
Patent number: 4368255Abstract: A method of processing monochrome silver halide material which contains in at least one silver halide layer in addition to the normal image-forming color coupler or couplers a development inhibitor releasing compound which method comprises developing the exposed material in a color developing solution which comprises not more than 2.5 g/liter of a paraphenylene diamine color developing agent which is able to couple with the color coupler or couplers and D.I.R. compound present, the process further comprising silver halide fixing, silver image bleaching and washing steps. The developed photographic images exhibit a remarkable increase in sharpness.Type: GrantFiled: July 15, 1981Date of Patent: January 11, 1983Assignee: Ciba-Geigy AGInventor: Thomas G. Borg
-
Patent number: 4343880Abstract: A dye-forming electrically activatable recording element comprises an electrically conductive support having thereon (a) an electrically activatable recording layer comprising in an electrically conductive polymeric binder, an organic silver salt and a reducing agent, (b) a photoconductive layer separated from (a) by an air gap of up to 20 microns, and (c) an electrically conductive layer on (b), wherein the recording layer (a) comprises in reactive association, (A) a dye-forming coupler, and (B) an oxidation-reduction combination comprising (i) an organic silver salt oxidizing agent, with (ii) a reducing agent which in its oxidized form forms a dye with the dye-forming coupler. The recording element can be room light handleable and can provide a dye image and silver image by dry development processing.Type: GrantFiled: June 20, 1980Date of Patent: August 10, 1982Assignee: Eastman Kodak CompanyInventor: Mark Lelental
-
Patent number: 4328305Abstract: This invention is directed to a method for treating the surface of photothermally crystallizable chemically-machinable glass-ceramic articles to render them non-sticking when brought into contact with certain organic materials. More particularly, the invention is drawn to the treatment of photothermally crystallizable, chemically-machinable glass-ceramic head pads for use in conjunction with information storage discs with SO.sub.2 vapors to render them non-sticking with respect to those discs.Type: GrantFiled: January 9, 1981Date of Patent: May 4, 1982Assignee: Corning Glass WorksInventor: Herbert E. Rauscher
-
Patent number: 4328299Abstract: Polychromatic glass articles and methods of producing such articles are disclosed in which the glass is activated by exposure to ultraviolet radiation and contains as a sensitizing agent an oxide of copper, samarium, terbium, praeseodymium, or europium.Type: GrantFiled: July 23, 1980Date of Patent: May 4, 1982Assignee: Corning Glass WorksInventors: George H. Beall, Syed N. Hoda, Richard W. Waldron
-
Patent number: 4323640Abstract: A photosensitive medium suitable for storing positive images and a method of using it are provided, the medium being a multilayer film comprising SnO.sub.2 and doped silver chloride and the method comprising an exposure step for negative imaging and a heating step for image reversal.Type: GrantFiled: November 5, 1980Date of Patent: April 6, 1982Assignee: Corning Glass WorksInventors: Nicholas F. Borrelli, Peter L. Young
-
Patent number: 4284704Abstract: Imaging means, such as a tetrazolium salt, capable of reduction to form a visible image is present in a radiation-sensitive layer in combination with a photoreductant incorporating one or more labile hydrogen atoms and capable of producing a reducing agent precursor in radiation-struck areas of the layer. An image is produced in the layer by processing the layer after imagewise exposure to actinic radiation.Type: GrantFiled: September 29, 1978Date of Patent: August 18, 1981Assignee: Eastman Kodak CompanyInventors: James C. Fleming, Joseph W. Manthey, Ralph T. Brongo
-
Patent number: 4283477Abstract: In a photothermographic element comprising (A) at least one photosensitive layer comprising a photosensitive component, such as photosensitive silver halide or a diazotype photosensitive material, (B) at least one layer comprising a processing agent for the photosensitive component and (C) a separation polymer between (A) and (B), increased preexposure storage stability is provided by a polysulfonamide as separation polymer (C). After imagewise exposure of the photothermographic element, an image can be developed by merely heating the element to moderately elevated temperatures.Type: GrantFiled: November 2, 1978Date of Patent: August 11, 1981Assignee: Eastman Kodak CompanyInventors: George L. Fletcher, Jr., Richard A. deMauriac, Stewart H. Merrill
-
Patent number: 4273860Abstract: There is disclosed a cobalt(III) complex-containing photographic composition, element and process which can be made negative-working or positive-working. Featured are an exposure activatible image precursor composition and a photoinhibitor composition capable of inhibiting image formation in the image precursor composition.Type: GrantFiled: December 20, 1978Date of Patent: June 16, 1981Assignee: Eastman Kodak CompanyInventor: Anthony Adin
-
Patent number: 4264721Abstract: A color photographic material comprising, on a support, a silver halide emulsion layer which contains a 2-equivalent .alpha.-acylacetamide yellow coupler carrying a nitrogen-containing heterocyclic coupling off group, joined to a nitrogen atom, as being releasable upon the reaction with an oxidation product of a color developing agent and a compound of the following formula (I) or its tautomer: ##STR1## wherein X and Y are as herein defined, is described.Type: GrantFiled: October 29, 1979Date of Patent: April 28, 1981Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Shinji Shimano, Tsuneo Wada, Katsuo Mogaki, Shinichi Nakamura, Kouji Tokitou
-
Patent number: 4245027Abstract: A light-sensitive image recording material comprising, as a self-supporting film or in one or more layers on a support, at least(a) a heat sensitive coloring element comprising at least one polyvinyl pyridine and at least one polyvinylidene halide, and(b) a light sensitizing element comprising at least one of(1) a compound which, on exposure to actinic radiation, is capable of complexing the polyvinyl pyridine of element (a) or is capable of forming a quaternary salt with the polyvinyl pyridine of element (a), or(2) a compound which, on exposure to actinic radiation, is capable of releasing a precursor which is capable of complexing the polyvinyl pyridine of element (a) or is capable of forming a quaternary salt with the polyvinyl pyridine of element (a) under heating,and a dry process for recording a light image comprising(1) imagewise exposing to actinic radiation the light-sensitive image recording material described above, and(2) uniformly heating the imagewise exposed light-sensitive image recording mateType: GrantFiled: July 11, 1978Date of Patent: January 13, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Keiji Takeda, Masayoshi Nagata, Kenji Matsumoto
-
Patent number: 4221860Abstract: A process for forming color photographic images having improved granularity, sharpness, and gradation by applying, after image exposure, a color reversal process including a step of performing color development in the presence of a competing coupler. The element processed is a multilayer reversal color photographic material comprising a support having coated thereon at least three differently sensitive photographic silver halide emulsion layers, the outermost layer of the color photographic material being blue-sensitive and containing a nondiffusible coupler forming a yellow dye by a coupling reaction with an oxidized primary aromatic amino color developing agent and represented by the following general formula (I) ##STR1## wherein R.sub.1 represents an alkyl group or an aryl group; R.sub.Type: GrantFiled: May 20, 1977Date of Patent: September 9, 1980Assignee: Fuji Photo Film Co., Ltd.Inventors: Takeshi Hirose, Akia Okumura
-
Patent number: 4219615Abstract: A multilayer color photographic material suitable for optically recording sound images on a sound track area formed thereon is composed of a support having coated thereon at least one silver halide emulsion layer containing a color coupler in at least a 40 mol% excess of the stoichiometric amount of the coupler to the silver halide contained in the emulsion layer and at least one silver halide emulsion layer containing a color coupler in an amount less than 40 mol% excess of the stoichiometric amount of the coupler to the silver halide in the emulsion layer.The color photographic material is suitably processed by a color intensification development process.Type: GrantFiled: February 24, 1978Date of Patent: August 26, 1980Assignee: Fuji Photo Film Co., Ltd.Inventor: Tadao Sakai
-
Patent number: 4201582Abstract: Certain mercapto heterocyclic compounds in certain photothermographic and thermographic elements and compositions containing silver salts of certain heterocyclic thione compounds and an organic reducing agent for the silver salts provide improved developed image tone. In the photothermographic element comprising photographic silver halide in association with the silver salt of heterocyclic thione, a developed and stabilized image, in the absence of a separate stabilizer or stabilizer precursor, with improved tone, is provided by heating the element. The photothermographic element and composition can contain a binder.Type: GrantFiled: December 22, 1975Date of Patent: May 6, 1980Assignee: Eastman Kodak CompanyInventor: Richard L. White