Color Development Patents (Class 430/351)
  • Patent number: 4499172
    Abstract: A heat-developable color light-sensitive material comprising a support having thereon at least a light-sensitive silver halide, a binder, a dye releasing redox compound which is capable of reducing the light-sensitive silver halide and is capable of reacting with the light-sensitive silver halide by heating to release a hydrophilic dye and a salt of an alkylcarboxylic acid having a triple bond between the .alpha.-position carbon atom and the .beta.-position carbon atom with an organic base as a base precursor.The heat-developable color light-sensitive material containing the novel base precursor has good stability during preservation and provides a color image having a high color density and low fog in a short time by a simple procedure. A method of forming a color image using the heat-developable color light-sensitive material is also disclosed.
    Type: Grant
    Filed: March 30, 1984
    Date of Patent: February 12, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Hirai, Kozo Sato
  • Patent number: 4483914
    Abstract: A heat-developable color photographic material is disclosed. The material is comprised of a support having thereon a layer containing at least a light-sensitive silver halide, an organic silver salt oxidizing agent, a hydrophilic binder, a reducing agent for the silver halide and/or the organic silver salt oxidizing agent and a dye releasing compound which is capable of bonding to an oxidized product of the reducing agent and releasing a hydrophilic dye. The heat-developable color photographic material can easily provide a clear and stable color image by imagewise exposure to light and a heat development procedure. A method of forming a color image using the heat-developable color photographic material is also disclosed.
    Type: Grant
    Filed: November 4, 1982
    Date of Patent: November 20, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hideki Naito, Hiroshi Hara, Kozo Sato
  • Patent number: 4481284
    Abstract: A silver halide photographic light-sensitive material is disclosed, comprising a support having thereon at least one light-sensitive silver halide emulsion layer and a light-insensitive uppermost layer. The light-insensitive uppermost layer has a melting time longer than that of the light-sensitive silver halide emulsion layer and a thickness of the light-insensitive uppermost layer is from 0.3 .mu.m to 0.8 .mu.m. The silver halide photographic light-sensitive material causes a remarkably lower degree of reticulation, can reduce the amount of scum formed in the processing solution, and has an improved covering power.
    Type: Grant
    Filed: September 21, 1982
    Date of Patent: November 6, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masashi Ogawa, Kunio Ishigaki, Nobuyuki Iwasaki, Taku Nakamura
  • Patent number: 4473631
    Abstract: A heat-developable color photographic material is disclosed. The material is comprised of a support having thereon at least a light-sensitive silver halide, a hydrophilic binder, a dye releasing compound reductive and capable of releasing a hydrophilic dye and a compound represented by the following general formula (A): ##STR1## wherein A.sub.1, A.sub.2, A.sub.3, and A.sub.4, which may be the same or different, each represents a hydrogen atom or a substituent selected from an alkyl group, a substituted alkyl group, a cycloalkyl group, an aralkyl group, an aryl group, a substituted aryl group and a heterocyclic group, or A.sub.1 and A.sub.2 or A.sub.3 and A.sub.4 may combine with each other to form a ring.The heat-developable color photographic material can easily provide in a short time a clear and stable color image having a high color density and low fog by imagewise exposure and heat development procedure.
    Type: Grant
    Filed: November 4, 1983
    Date of Patent: September 25, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Hirai, Hideki Naito, Hiroshi Hara, Kozo Sato
  • Patent number: 4469773
    Abstract: A coupler containing in the coupling position a carbamoyloxy group ##STR1## upon oxidative coupling, releases a carbamic acid fragment that, in turn, is capable of thermally releasing ammonia or an amine. Such a carbamoyloxy substituted coupler and carbamic acid fragment are useful in imaging such as in photothermography and thermography. Ammonia or an amine released from the carbamic acid fragment enables imaging in imaging materials that are responsive to ammonia or an amine. The carbamoyloxy substituted coupler also generally is a dye-forming coupler that reacts with the oxidized form of a color developing agent to form a dye. An image is produced in an exposed photothermographic material comprising the carbamoyloxy substituted coupler by thermal development. An image is produced in a thermographic material comprising the carbamoyloxy substituted coupler and a color developing agent by imagewise heating the thermographic material.
    Type: Grant
    Filed: June 15, 1983
    Date of Patent: September 4, 1984
    Assignee: Eastman Kodak Company
    Inventors: Anthony Adin, Csaba A. Kovacs, Delwyn E. Machiele
  • Patent number: 4463079
    Abstract: A diffusion transfer heat-developable color photographic material. The material comprises a support, a photosensitive silver halide, an organic silver salt, a hydrophobic binder, a dye releasing activator, and a dye releasing redox compound which releases a diffusible dye. Color images are obtained with the material by transferring a dye released by heat development. The material makes it possible to obtain clear color images by a simple procedure and the images obtained are stable over a long period of time.
    Type: Grant
    Filed: April 30, 1982
    Date of Patent: July 31, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hideki Naito, Hiroshi Hara, Kozo Sato
  • Patent number: 4460681
    Abstract: Color photothermographic articles are prepared by having the various color-forming layers separated by organic solvent soluble barrier layers insoluble in the organic solvent used to coat at least one of the adjacent color-forming layers.
    Type: Grant
    Filed: March 15, 1983
    Date of Patent: July 17, 1984
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Robert A. Frenchik
  • Patent number: 4452883
    Abstract: A photothermographic color construction is disclosed, the construction having at least two color-forming layers comprising:a. a first, spectrally-sensitized, color-forming layer coated out of a solvent system selected from lower alkyl alcohols (up to 4 carbon atoms) ketones (up to 6 carbon atoms), aromatic hydrocarbons (up to 10 carbon atoms), or mixtures thereof,b. an upper, second, different, spectrally-sensitized color-forming layer coated out of a toluene or acetone solvent system, andc.
    Type: Grant
    Filed: May 17, 1983
    Date of Patent: June 5, 1984
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Robert A. Frenchik, Kristen A. Hoff
  • Patent number: 4430415
    Abstract: A heat-developable color photographic material is disclosed. The material is comprised of a support having thereon a layer containing fine droplets of complex coacervate containing a light-sensitive silver halide, an organic silver salt oxidizing agent and a color image forming substance which are prepared by complex coacervation and hardened with a hardening agent. Color fog does not occur with the material and it can be easily prepared to provide a color image having good color balance by imagewise exposure to light and a heat development procedure. A process for forming a color image using the heat-developable color photographic material is also disclosed.
    Type: Grant
    Filed: September 2, 1982
    Date of Patent: February 7, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiaki Aono, Hiroshi Hara, Hideki Naito, Kozo Sato
  • Patent number: 4430420
    Abstract: In a photothermographic silver halide material and process for preparing an enhanced silver image, an aminosulfonylhydrazone that is capable of developing an image in the photothermographic material and that is capable, upon oxidation, of releasing an aminosulfinic acid, which, in turn, thermally releases ammonia or amine provides a silver image in the photothermographic material and provides ammonia or amine for activation of an ammonia or amine responsive imaging material. After imagewise exposure of the photothermographic material, a silver image enhanced by an image in the ammonia or amine responsive imaging material is produced by heating the photothermographic material.
    Type: Grant
    Filed: August 27, 1982
    Date of Patent: February 7, 1984
    Assignee: Eastman Kodak Company
    Inventor: Anthony Adin
  • Patent number: 4426441
    Abstract: In a dye-forming imaging material comprising (a) a dye-forming coupler, and (b) an organic reducing agent that is capable in its oxidized form of reacting with the dye-forming coupler to form a dye, improvements are provided by a reducing agent that is a ureidoaniline silver halide developing agent free of strong electron withdrawing groups. Such an imaging material can be a photographic silver halide material. The imaging material can be a photothermographic material for producing a dye image comprising, in reactive association, (a) photographic silver halide, (b) a dye-forming coupler, and (c) an oxidation-reduction image forming combination comprising (1) an organic silver salt oxidizing agent, and (2) an organic reducing agent for the organic silver salt oxidizing agent, wherein the reducing agent is a ureidoaniline which is capable in its oxidized form of reacting with the dye-forming coupler to form a dye.
    Type: Grant
    Filed: December 3, 1982
    Date of Patent: January 17, 1984
    Assignee: Eastman Kodak Company
    Inventors: Anthony Adin, Roy C. DeSelms
  • Patent number: 4418140
    Abstract: A process for the development of color photographic light-sensitive material is described. The process comprises color developing an exposed light-sensitive material in the presence of a compound of the general formula: ##STR1## wherein M is a hydrogen atom, an alkali metal atom, NH.sub.4 or a protective group for the mercapto group which undergoes cleavage by the action of an alkali; R is a hydrogen atom or an alkyl group containing 1 to 3 carbon atoms; and R' is a hydrogen atom or an alkyl group containing 1 to 3 carbon atoms. This process prevents the formation of color development fog without seriously reducing sensitivity.
    Type: Grant
    Filed: April 8, 1982
    Date of Patent: November 29, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Mifune, Shoji Ishiguro, Tadao Shishido, Tatsuo Nishimura
  • Patent number: 4411984
    Abstract: A diphenylamine compound that is a precursor for a phenazine dye comprises, in an ortho position to the amine of the diphenylamine, a sulfonyldiamido group (--NHSO.sub.2 NHR) that is capable of releasing a sulfonylamine fragment upon oxidation. The diphenylamine compound upon oxidation intramolecularly cyclizes to a phenazine dye. The sulfonylamine fragment is capable of thermally releasing ammonia or an amine. The diphenylamine compound and sulfonylamine fragment are useful in imaging such as in photothermography. Ammonia or an amine thermally released from the sulfonylamine fragment enables imaging in imaging materials that are responsive to ammonia or an amine. The diphenylamine compound also generally is a silver halide developing agent.
    Type: Grant
    Filed: May 3, 1982
    Date of Patent: October 25, 1983
    Assignee: Eastman Kodak Company
    Inventor: Rolf S. Gabrielsen
  • Patent number: 4390617
    Abstract: The present invention is directed towards a silver halide photographic material which has a reducing agent for silver halide or a precursor thereof and a compound M.sub.1 H.sub.m (PO.sub.n).sub.i.jH.sub.2 O which generates base when heat is applied. M is a metal from the Groups IA and IIA of the Periodic Table, 1 and i are individually integers from 1 to 3, m is an integer from 0 to 4, n is 3 or 4, and j is an integer from 0 to 12.
    Type: Grant
    Filed: March 5, 1981
    Date of Patent: June 28, 1983
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Kenichiro Okaniwa, Toyoaki Masukawa, Kiyoshi Yamashita, Wataru Ishikawa
  • Patent number: 4379835
    Abstract: A thermographic imaging system comprising a single layer and capable of providing a stable dark to black image upon localized heating is disclosed. The single layer comprises a polymeric binder, a combination of at least two leuco dyes, and a nitrate salt.
    Type: Grant
    Filed: December 22, 1980
    Date of Patent: April 12, 1983
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Robert D. Lowrey, Howard D. Nelson, George Van Dyke Tiers
  • Patent number: 4374916
    Abstract: In an electrically activatable recording element improvements are provided by an electrically conductive interlayer (ECI layer) separating (a) an electrically activatable recording layer from (b) a photoconductive layer or electrical activating means. The ECI layer comprises electrically conductive particles uniformly dispersed in an electrically insulating binder. The interlayer enables imaging with a minimized air gap between (a) and (b). The recording element is room light handleable. The element provides an image by dry development processing or by means of processing solutions.
    Type: Grant
    Filed: November 27, 1981
    Date of Patent: February 22, 1983
    Assignee: Eastman Kodak Company
    Inventors: Mark Lelental, Gary M. Goncher
  • Patent number: 4368255
    Abstract: A method of processing monochrome silver halide material which contains in at least one silver halide layer in addition to the normal image-forming color coupler or couplers a development inhibitor releasing compound which method comprises developing the exposed material in a color developing solution which comprises not more than 2.5 g/liter of a paraphenylene diamine color developing agent which is able to couple with the color coupler or couplers and D.I.R. compound present, the process further comprising silver halide fixing, silver image bleaching and washing steps. The developed photographic images exhibit a remarkable increase in sharpness.
    Type: Grant
    Filed: July 15, 1981
    Date of Patent: January 11, 1983
    Assignee: Ciba-Geigy AG
    Inventor: Thomas G. Borg
  • Patent number: 4343880
    Abstract: A dye-forming electrically activatable recording element comprises an electrically conductive support having thereon (a) an electrically activatable recording layer comprising in an electrically conductive polymeric binder, an organic silver salt and a reducing agent, (b) a photoconductive layer separated from (a) by an air gap of up to 20 microns, and (c) an electrically conductive layer on (b), wherein the recording layer (a) comprises in reactive association, (A) a dye-forming coupler, and (B) an oxidation-reduction combination comprising (i) an organic silver salt oxidizing agent, with (ii) a reducing agent which in its oxidized form forms a dye with the dye-forming coupler. The recording element can be room light handleable and can provide a dye image and silver image by dry development processing.
    Type: Grant
    Filed: June 20, 1980
    Date of Patent: August 10, 1982
    Assignee: Eastman Kodak Company
    Inventor: Mark Lelental
  • Patent number: 4328305
    Abstract: This invention is directed to a method for treating the surface of photothermally crystallizable chemically-machinable glass-ceramic articles to render them non-sticking when brought into contact with certain organic materials. More particularly, the invention is drawn to the treatment of photothermally crystallizable, chemically-machinable glass-ceramic head pads for use in conjunction with information storage discs with SO.sub.2 vapors to render them non-sticking with respect to those discs.
    Type: Grant
    Filed: January 9, 1981
    Date of Patent: May 4, 1982
    Assignee: Corning Glass Works
    Inventor: Herbert E. Rauscher
  • Patent number: 4328299
    Abstract: Polychromatic glass articles and methods of producing such articles are disclosed in which the glass is activated by exposure to ultraviolet radiation and contains as a sensitizing agent an oxide of copper, samarium, terbium, praeseodymium, or europium.
    Type: Grant
    Filed: July 23, 1980
    Date of Patent: May 4, 1982
    Assignee: Corning Glass Works
    Inventors: George H. Beall, Syed N. Hoda, Richard W. Waldron
  • Patent number: 4323640
    Abstract: A photosensitive medium suitable for storing positive images and a method of using it are provided, the medium being a multilayer film comprising SnO.sub.2 and doped silver chloride and the method comprising an exposure step for negative imaging and a heating step for image reversal.
    Type: Grant
    Filed: November 5, 1980
    Date of Patent: April 6, 1982
    Assignee: Corning Glass Works
    Inventors: Nicholas F. Borrelli, Peter L. Young
  • Patent number: 4284704
    Abstract: Imaging means, such as a tetrazolium salt, capable of reduction to form a visible image is present in a radiation-sensitive layer in combination with a photoreductant incorporating one or more labile hydrogen atoms and capable of producing a reducing agent precursor in radiation-struck areas of the layer. An image is produced in the layer by processing the layer after imagewise exposure to actinic radiation.
    Type: Grant
    Filed: September 29, 1978
    Date of Patent: August 18, 1981
    Assignee: Eastman Kodak Company
    Inventors: James C. Fleming, Joseph W. Manthey, Ralph T. Brongo
  • Patent number: 4283477
    Abstract: In a photothermographic element comprising (A) at least one photosensitive layer comprising a photosensitive component, such as photosensitive silver halide or a diazotype photosensitive material, (B) at least one layer comprising a processing agent for the photosensitive component and (C) a separation polymer between (A) and (B), increased preexposure storage stability is provided by a polysulfonamide as separation polymer (C). After imagewise exposure of the photothermographic element, an image can be developed by merely heating the element to moderately elevated temperatures.
    Type: Grant
    Filed: November 2, 1978
    Date of Patent: August 11, 1981
    Assignee: Eastman Kodak Company
    Inventors: George L. Fletcher, Jr., Richard A. deMauriac, Stewart H. Merrill
  • Patent number: 4273860
    Abstract: There is disclosed a cobalt(III) complex-containing photographic composition, element and process which can be made negative-working or positive-working. Featured are an exposure activatible image precursor composition and a photoinhibitor composition capable of inhibiting image formation in the image precursor composition.
    Type: Grant
    Filed: December 20, 1978
    Date of Patent: June 16, 1981
    Assignee: Eastman Kodak Company
    Inventor: Anthony Adin
  • Patent number: 4264721
    Abstract: A color photographic material comprising, on a support, a silver halide emulsion layer which contains a 2-equivalent .alpha.-acylacetamide yellow coupler carrying a nitrogen-containing heterocyclic coupling off group, joined to a nitrogen atom, as being releasable upon the reaction with an oxidation product of a color developing agent and a compound of the following formula (I) or its tautomer: ##STR1## wherein X and Y are as herein defined, is described.
    Type: Grant
    Filed: October 29, 1979
    Date of Patent: April 28, 1981
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Shinji Shimano, Tsuneo Wada, Katsuo Mogaki, Shinichi Nakamura, Kouji Tokitou
  • Patent number: 4245027
    Abstract: A light-sensitive image recording material comprising, as a self-supporting film or in one or more layers on a support, at least(a) a heat sensitive coloring element comprising at least one polyvinyl pyridine and at least one polyvinylidene halide, and(b) a light sensitizing element comprising at least one of(1) a compound which, on exposure to actinic radiation, is capable of complexing the polyvinyl pyridine of element (a) or is capable of forming a quaternary salt with the polyvinyl pyridine of element (a), or(2) a compound which, on exposure to actinic radiation, is capable of releasing a precursor which is capable of complexing the polyvinyl pyridine of element (a) or is capable of forming a quaternary salt with the polyvinyl pyridine of element (a) under heating,and a dry process for recording a light image comprising(1) imagewise exposing to actinic radiation the light-sensitive image recording material described above, and(2) uniformly heating the imagewise exposed light-sensitive image recording mate
    Type: Grant
    Filed: July 11, 1978
    Date of Patent: January 13, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keiji Takeda, Masayoshi Nagata, Kenji Matsumoto
  • Patent number: 4221860
    Abstract: A process for forming color photographic images having improved granularity, sharpness, and gradation by applying, after image exposure, a color reversal process including a step of performing color development in the presence of a competing coupler. The element processed is a multilayer reversal color photographic material comprising a support having coated thereon at least three differently sensitive photographic silver halide emulsion layers, the outermost layer of the color photographic material being blue-sensitive and containing a nondiffusible coupler forming a yellow dye by a coupling reaction with an oxidized primary aromatic amino color developing agent and represented by the following general formula (I) ##STR1## wherein R.sub.1 represents an alkyl group or an aryl group; R.sub.
    Type: Grant
    Filed: May 20, 1977
    Date of Patent: September 9, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takeshi Hirose, Akia Okumura
  • Patent number: 4219615
    Abstract: A multilayer color photographic material suitable for optically recording sound images on a sound track area formed thereon is composed of a support having coated thereon at least one silver halide emulsion layer containing a color coupler in at least a 40 mol% excess of the stoichiometric amount of the coupler to the silver halide contained in the emulsion layer and at least one silver halide emulsion layer containing a color coupler in an amount less than 40 mol% excess of the stoichiometric amount of the coupler to the silver halide in the emulsion layer.The color photographic material is suitably processed by a color intensification development process.
    Type: Grant
    Filed: February 24, 1978
    Date of Patent: August 26, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tadao Sakai
  • Patent number: 4201582
    Abstract: Certain mercapto heterocyclic compounds in certain photothermographic and thermographic elements and compositions containing silver salts of certain heterocyclic thione compounds and an organic reducing agent for the silver salts provide improved developed image tone. In the photothermographic element comprising photographic silver halide in association with the silver salt of heterocyclic thione, a developed and stabilized image, in the absence of a separate stabilizer or stabilizer precursor, with improved tone, is provided by heating the element. The photothermographic element and composition can contain a binder.
    Type: Grant
    Filed: December 22, 1975
    Date of Patent: May 6, 1980
    Assignee: Eastman Kodak Company
    Inventor: Richard L. White