During Dry Development Patents (Class 430/353)
  • Patent number: 5258281
    Abstract: A heat-developable photosensitive material which comprises an organic silver salt, a silver halide, a reducing agent and a heat development accelerator having a redox potential ranging from -1.2 V to +1.0 V on the basis of an AgCl/Ag electrode.
    Type: Grant
    Filed: November 12, 1991
    Date of Patent: November 2, 1993
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hiromi Tanaka, Tetsuro Fukui, Motokazu Kobayashi, Kenji Kagami, Masao Suzuki, Tetsuya Higuchi
  • Patent number: 5246811
    Abstract: An image forming method uses a light-sensitive material and an image receiving material. The light-sensitive material comprises a support and a light-sensitive layer provided thereon. The light-sensitive layer contains silver halide, a reducing agent, pigment particles, an ethylenically unsaturated polymerizable compound and a base precursor. The silver halide, the reducing agent, the pigment particles, the polymerizable compound and the base precursor are contained in microcapsules dispersed in the light-sensitive layer. The image forming method comprises imagewise exposing the light-sensitive material, developing the light-sensitive material to polymerize the polymerizable compound, and pressing the light-sensitive material on the image receiving material to transfer the pigment particles to the image receiving material. In the present invention, the light-sensitive material is pressed at a pressure in the range of 20 kg/cm.sup.2 to 500 kg/cm.sup.2 while heating the light-sensitive material at 30.degree. C.
    Type: Grant
    Filed: January 17, 1992
    Date of Patent: September 21, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Manabu Higuchi
  • Patent number: 5213940
    Abstract: The present invention relates to an image recording method utilizing photosensitive microcapsules. These photosensitive microcapsules have characteristics of being rendered hardenable upon exposure. Further, only the hardenable photosensitive microcapsules can be hardened. In this image recording method, an optional image pattern is initially exposed to a photosensitive recording medium having thereon the photosensitive microcapsules for rendering only the exposed photosensitive microcapsules hardenable corresponding to the image pattern. Subsequently, the exposed photosensitive recording medium is heated to harden only the hardenable photosensitive microcapsules. Further, the photosensitive recording medium is entirely exposed again with light to render the unhardened photosensitive microcapsules hardenable.
    Type: Grant
    Filed: April 3, 1992
    Date of Patent: May 25, 1993
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventors: Kouji Inaishi, Naomichi Kobayashi
  • Patent number: 5196288
    Abstract: An image forming method of imagewise exposing and heating a light-sensitive material is disclosed. The light-sensitive material comprises a support and a light-sensitive layer provided thereon. The light-sensitive layer contains silver halide, a reducing agent, an ethylenically unsaturated polymerizable compound, a color image forming substance and a base precursor. The silver halide, the reducing agent, the polymerizable compound, the color image forming substance and the base precursor are contained in microcapsules which are dispersed in the light-sensitive layer. According to the present invention, the support is made of a thin polymer film having a thickness of not more than 75 .mu.m. The light-sensitive material is heated from the side of the support for 0.1 to 5 seconds.
    Type: Grant
    Filed: September 9, 1991
    Date of Patent: March 23, 1993
    Assignees: Fuji Photo Film Co., Ltd., Seiko Epson Corp., Seiko Instruments, Inc.
    Inventor: Taku Nakamura
  • Patent number: 5192639
    Abstract: A light-sensitive material comprises a support and a light-sensitive layer provided thereon. The light-sensitive layer contains silver halide, a reducing agent and an ethylenically unsaturated polymerizable compound. According to the present invention, the light-sensitive layer further contains a chromium (VI) compound, a molybdenum (VI) compound or a tungsten (VI) compound.
    Type: Grant
    Filed: October 10, 1991
    Date of Patent: March 9, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hiroyuki Hirai
  • Patent number: 5149620
    Abstract: The addition of certain 5-mercapto-1,2,4-triazoles to silver halide photothermographic emulsions improves the post-processing image stability of those emulsions.
    Type: Grant
    Filed: July 30, 1990
    Date of Patent: September 22, 1992
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Sahron M. Simpson, John R. Boon, Marco Bucci, Massimo Bertoldi, Cristina Soncini, Kumars Sakizadeh
  • Patent number: 5147743
    Abstract: A process for the preparation of a color filter is described utilizing an exposure step of a light-sensitive material, imagewise exposing, toning and heat treating.
    Type: Grant
    Filed: June 28, 1990
    Date of Patent: September 15, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Mario Grossa
  • Patent number: 5089378
    Abstract: A method for forming an image comprising heating a heat-developable light-sensitive material comprising a support having thereon at least a light-sensitive silver halide and a binder, simultaneously with or after imagewise exposure thereof in the presence of water, at least one of a base and a base precursor, and an acetylene compound represented by formula (I):R.sub.1 --C.tbd.C--R.sub.2 (I)wherein R.sub.1 and R.sub.2 each represents a hydrogen atom, a carboxyl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted alkoxycarbonyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group, or a substituted or unsubstituted carbamoyl group; provided that both R.sub.1 and R.sub.2 do not represent hydrogen atoms at the same time.
    Type: Grant
    Filed: March 20, 1991
    Date of Patent: February 18, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Ozaki, Ken Kawata, Hideki Ohmatsu
  • Patent number: 5082763
    Abstract: A heat developable photosensitive material comprising a support having thereon at least one photosensitive silver halide emulsion layer, which contains at least one compound selected from those represented by the following general formulae (I) and (II) to acquire a high S/N ratio and high sensitivity: ##STR1## wherein R represents an alkylene group, an alkenylene group, an aralkylene group or an arylene group, which each may be substituted; Y represents ##STR2## R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9 and R.sub.
    Type: Grant
    Filed: March 5, 1991
    Date of Patent: January 21, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsuro Kojima, Tomoyuki Koide
  • Patent number: 5051335
    Abstract: A novel heat developable light-sensitive material is disclosed, comprising light-sensitive silver halide emulsion layers on a paper support, wherein at least one subbing layer capable of inhibiting fog is provided interposed between the undermost layer among said light-sensitive silver halide emulsion layers and said paper support. In a preferred embodiment, the subbing layer comprises a binder and at least one material capable of inhibiting fog.
    Type: Grant
    Filed: January 26, 1989
    Date of Patent: September 24, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Masatoshi Kato
  • Patent number: 5032493
    Abstract: A method of drying a photographic light-sensitive material after development-processing in an automatic processor comprising a dry-processing portion, wherein the method comprises drying steps (a) and (b):(a) drying the photographic light-sensitive material to an extent that 65% of the moisture content of the photographic material just after squeezing is dried out; and subsequently,(b) drying the photographic light-sensitive material at a temperature which is set based on temperature and humidity conditions of an area where the automatic processor is installed.
    Type: Grant
    Filed: September 14, 1990
    Date of Patent: July 16, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Mori, Kunio Ishigaki
  • Patent number: 5030541
    Abstract: An image-forming method comprises the steps of image-wise exposing to light a light-sensitive material comprising a support and a light-sensitive layer provided thereon which contains silver halide, a reducing agent and an ethylenically unsaturated polymerizable compound, at least the silver halide and the polymerizable compound being contained in a microcapsule; simultaneously or thereafter heat-developing the light sensitive material; and pressing the light-sensitive material on an image-receiving material comprising a support and a porous image-receiving layer which contains a fluorine compound to transfer the unpolymerized polymerizable compound to the image-receiving material.
    Type: Grant
    Filed: September 5, 1989
    Date of Patent: July 9, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hiroshi Hayashi
  • Patent number: 4983502
    Abstract: A heat developing photosensitive material is disclosed, comprising silver halide, a binder, a reducing agent and a heat solvent, wherein said heat solvent is at least one selected from the group consisting of compounds represented by Formulae I, II and III: ##STR1##
    Type: Grant
    Filed: February 17, 1989
    Date of Patent: January 8, 1991
    Assignee: Konica Corporation
    Inventors: Keiji Ohbayashi, Tawara Komamura, Sohei Goto, Hidenobu Ohya
  • Patent number: 4983494
    Abstract: An image is formed in a photographic element by a process comprising a step of heating a heat-developable photosensitive material in the presence of a specific compound which typically releases a phenylmercaptotetrazole having a substituted benzene ring and serving as a development retarder.
    Type: Grant
    Filed: October 18, 1989
    Date of Patent: January 8, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Kitaguchi, Masatoshi Kato
  • Patent number: 4956260
    Abstract: A light-sensitive material comprising a light-sensitive layer provided on a support wherein the light-sensitive layer contains silver halide, a reducing agent, a polymerizable compound, and an additive compound selected from the group consisting of a 5- or 6-membered nitrogen containing heterocyclic compound, thiourea, a thiourea derivative, a thioether compound, polyethylene glycol and a polyethylene glycol derivative. Thermal image-forming methods utilizing the light-sensitive materials are also disclosed.
    Type: Grant
    Filed: December 29, 1986
    Date of Patent: September 11, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Koichi Nakamura
  • Patent number: 4927730
    Abstract: A light-sensitive material comprising a light-sensitive layer containing silver halide, a reducing agent, a polymerizable compound and a color image forming substance provided on a support, characterized in that the color image forming substance is a triazene compound having the following formula: ##STR1## in which Ar is an aryl group or a heterocyclic group, each of which may have one or more substituent groups; each of R.sup.1 and R.sup.2 independently is a group selected from the group consisting of hydrogen, an alkyl group, a cycloalkyl group, an aralkyl group, an alkenyl group, an aryl group and a heterocyclic group, each of which may have one or more substituent groups, or R.sup.1 and R.sup.2 form, together with the neighboring nitrogen, a heterocyclic group which may have one or more substituent groups; and n is 1, 2 or 3. An image forming method utilizing the light-sensitive material is also disclosed.
    Type: Grant
    Filed: April 27, 1987
    Date of Patent: May 22, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kazo Sato
  • Patent number: 4916047
    Abstract: A silver halide light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, and containing a compound containing a repeating unit, said compound containing a repeating unit being connected at the repeating unit to a compound represented by formula (I) at the position of the PWR or Time moiety:PWR--Time.sub.t PUG (I)wherein PWR represents a moiety capable of releasing (Time.sub.t PUG upon reduction, and PUG represents a group which can fulfil a photographically useful function after the release; Time represents a moiety capable of releasing PUG through a reaction subsequent to the release from PWR in the form of --Time.sub.t PUG; and t represents 0 or 1.
    Type: Grant
    Filed: April 29, 1988
    Date of Patent: April 10, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keizo Koya, Junichi Yamanouchi, Masaharu Toriuchi, Yoshisada Nakamura
  • Patent number: 4904573
    Abstract: A method for forming an image by the steps of:(a) imagewise exposing a heat-developable color light-sensitive material;(b) uniformly exposing at least a portion of the heat-developable light-sensitive material; and(c) heat developing the imagewise exposed and uniformly exposed heat-developable light-sensitive material to form a color image.
    Type: Grant
    Filed: November 10, 1988
    Date of Patent: February 27, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hiroshi Hara
  • Patent number: 4893148
    Abstract: A dry silver salt roll film for use in the rotary type microphotography is stored in the form of a roll within a range of hardness from 70 of durometer A to 80 of durometer D, so that an unexposed film can be stored stably for a long period of time.
    Type: Grant
    Filed: May 3, 1988
    Date of Patent: January 9, 1990
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Masahiko Sanada, Yoshio Hayashi, Akira Ohnuma, Shuichiro Ogawa
  • Patent number: 4886739
    Abstract: In a thermally processable imaging element and process an imaging layer comprising a photothermographic or thermographic imaging composition and 2.5 to 20% by weight of the layer of at least one hydrolyzed polyalkoxysilane (hydrolyzed Si(OR.sub.1).sub.4 or hydrolyzed R.sub.2 --Si(OR.sub.3).sub.3) enables increased maximum image density. Such a hydrolyzed polyalkoxysilane in a hydrophobic imaging layer of such an element enables increased adhesion of the imaging layer to a contiguous hydrophobic hydrophilio layer, particularly a hydrophilic overcoat layer.
    Type: Grant
    Filed: August 10, 1988
    Date of Patent: December 12, 1989
    Assignee: Eastman Kodak Company
    Inventor: Wojciech M. Przezdziecki
  • Patent number: 4880725
    Abstract: A color image is formed by imagewise exposing a color photosensitive material comprising at least a silver halide and a coupler and subjecting the material to intensified development with a processing solution containing a reducing agent and an intensifier. A substantially water-insoluble basic metal compound is previously contained in the silver halide based color photosensitive material, while the processing solution contains a compound capable of complexing reaction with the metal ion of the substantially water-insoluble basic metal compound to release a base.
    Type: Grant
    Filed: December 27, 1988
    Date of Patent: November 14, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Hirai, Haruhiko Iwano
  • Patent number: 4853743
    Abstract: An image recording apparatus in which a latent image formed on a photo-sensitive material by optical exposure is thermally developed. The photo-sensitive material is piled on an image receiving material so that the image developed on the photo-sensitive material is transferred onto the image receiving material. A moisture detecting sensor directly or indirectly detects the moisture content of the photo-sensitive material to output a control signal. In response to the control signal, a preheating roller preheats the photo-sensitive material or a humidifying nozzle is operated to humidify the photo-sensitive material, whereby the moisture content of the photo-sensitive material is maintained at a desired value.
    Type: Grant
    Filed: April 14, 1988
    Date of Patent: August 1, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akihiko Nagumo, Shigeru Yoshino
  • Patent number: 4845018
    Abstract: An image-forming process involving a heating step is disclosed, which comprises conducting the heating in the presence of a compound represented by the following general formula (I): ##STR1## wherein: R.sup.1 and R.sup.2, which may be the same or different, each represents a group selected from an aryl group, a substituted aryl group, a heterocyclic group, and a substituted heterocyclic group;R.sup.3 represents a hydrogen atom, an alkyl group, a substituted alkyl group, a cycloalkyl group, a substituted cycloalkyl group, an aralkyl group, a substituted aralkyl group, or a group selected from those which are referred to with respect to R.sup.1 and R.sup.2 ;R.sup.1, R.sup.2, and R.sup.3 may form a ring structure via a hydrocarbon chain, a hetero atom-containing hydrocarbon chain or a hetero atom, or may be directly bound to each other to form a ring structure; andPUG represents a photographically useful group.
    Type: Grant
    Filed: February 18, 1986
    Date of Patent: July 4, 1989
    Assignee: Fuji Photo Film, Co., Ltd.
    Inventors: Kozo Sato, Hiroshi Kitaguchi, Masashi Takeuchi, Masaaki Tsukase, Masatoshi Kato
  • Patent number: 4824759
    Abstract: A method for forming an image, which comprises heating a light-sensitive material in the presence of a compound capable of forming a 2-mercaptobenzazole ring by a ring closing reaction when heated.In accordance with the method of the present invention, development is stopped at an appropriate time of development whereby an image having a high maximum density and low fog is obtained.A heat-developable light-sensitive material containing the compound is also disclosed.
    Type: Grant
    Filed: February 7, 1986
    Date of Patent: April 25, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kozo Sato, Hiroshi Kitaguchi, Masashi Takeuchi, Masaaki Tsukase, Masatoshi Kato
  • Patent number: 4824756
    Abstract: An image-forming method which comprises:imagewise exposing a light-sensitive material comprising a light-sensitive layer provided on a support wherein the light-sensitive layer contains silver halide, a reducing agent and a mixture of at least two polymerizable compounds to form a latent image of the silver halide;simultaneously or thereafter developing the light-sensitive material to polymerize the mixture of the polymerizable compounds within the area where the latent image of the silver halide has been formed; andpressing the light-sensitive material on an image-receiving material to transfer the unpolymerized mixture of the polymerizable compounds to the image-receiving material.
    Type: Grant
    Filed: March 11, 1987
    Date of Patent: April 25, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Taku Nakamura
  • Patent number: 4820617
    Abstract: A heat-developable photosensitive material of which thermal fogging is markedly suppressed without detriment to image characteristics such as sensitivity, which is prepared by forming a single layer or multiple layers of a heat-developable photosensitive element comprising at least (a) an oxidation-reduction image-forming component comprising a long-chain fatty acid silver salt and a reducing agent, (b) a photosensitive silver halide or/and a photosensitive slilver halide-forming component, (c) a binder, and (d) at least one member selected from the compounds represented by the following general formula:HOOC--R--COOHwherein R represents an alkylene or alkenylene group of at least 4 carbon atoms which may be linear or branched, on a support.
    Type: Grant
    Filed: December 30, 1987
    Date of Patent: April 11, 1989
    Assignee: Oriental Photo Industrial Co., Ltd.
    Inventors: Tetuya Higuchi, Akira Tsukada, Yukio Takegawa
  • Patent number: 4814254
    Abstract: In a photographic element amenable to heat development or mobile dye heat transfer, an electroconductive layer is formed from a composition containing an electroconductive substance, typically carbon black and a high molecular weight compound having a glass transition temperature of not higher than 40.degree. C. at a relative humidity of 20% or a melting point of not higher than 180.degree. C., for example, polyethylene glycol, such that the conductive layer undergoes a minimized change in electric resistance when folded.
    Type: Grant
    Filed: March 7, 1986
    Date of Patent: March 21, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hideki Naito, Hiroyuki Ozaki
  • Patent number: 4788134
    Abstract: The present invention provides a heat-developable photographic light-sensitive material comprising, on a support, at least containing a light-sensitive silver halide, a binder, a reducing agent, and an organic silver salt, wherein said organic silver salt is a silver salt of a pyrazolazole-type compound represented by formula (I) ##STR1## wherein R.sup.1 and R.sup.2 each represents a hydrogen atom or a substituent; Za, Zb, and Zc each represents a methine group, a substituted methine group, .dbd.N-- or --NH--; and one of the Za-Zb bond and Zb-Zc bond is a double bond and the other is a single bond.The present heat-developable photographic light-sensitive materials are capable of forming images of high density, with low fog, in a short period of time.
    Type: Grant
    Filed: October 23, 1986
    Date of Patent: November 29, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Ozaki, Ken Kawada
  • Patent number: 4783396
    Abstract: The present invention provides silver halide photographic materials containing a havel compound, which when reduced, releases a photographically useful group as triggered off by the cleavage of the nitrogen-oxygen single bond in the compound and which is represented by the following general formula (I): ##STR1## wherein EAG represents a group which accepts an electron from a reducing substance; N and O each represents nitrogen atom and an oxygen atom, respectively; R.sup.1 and R.sup.2 each represents a substituent other than a hydrogen atom, and when R.sup.1 or R.sup.2 is bonded to --(Time).sub.t PUG, R.sup.1 or R.sup.2 is a mere bond or a substituent other than a hydrogen atom, and R.sup.1 and R.sup.
    Type: Grant
    Filed: October 30, 1986
    Date of Patent: November 8, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koki Nakamura, Sahigeru Nakamura
  • Patent number: 4775613
    Abstract: A heat-developable light-sensitive material comprising a support having thereon at least one layer containing a light-sensitive silver halide, a reducing agent, a binder and an acetylene silver compound.The heat-developable light-sensitive material which contains the novel organic silver compound can provide images having high density and low fog when subjected to a short period of developing time even when a small amount of a base processor is used.
    Type: Grant
    Filed: March 31, 1986
    Date of Patent: October 4, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Hirai, Hiroshi Hara, Ken Kawata
  • Patent number: 4772544
    Abstract: A heat-developable photographic material is disclosed wherein the photographic material comprising at least one of an acid or a salt thereof having an acid dissociation constant pKa of 7 or less.
    Type: Grant
    Filed: August 7, 1985
    Date of Patent: September 20, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hiroyuki Hirai
  • Patent number: 4764458
    Abstract: A heat developable light-sensitive material is disclosed. The material comprises a support having provided thereon at least a light-sensitive silver halide, a reducing agent, a binder and an organic silver salt of the formula: ##STR1## wherein R.sub.1 represents a hydrogen atom or a substituted or unsubstituted alkyl, cycloalkyl, alkenyl, alkynyl, aralkyl, aryl or heterocyclic group; R.sub.2 represents a hydrogen atom or a substituted or unsubstituted alkyl group; R.sub.3 represents a halogen atom, a substituted or unsubstituted alkyl, alkoxy, amino, alkylsulfonyl, arylsulfonyl, carbamoyl, sulfamoyl or alkoxycarbonyl group or a cyano group; X represents ##STR2## wherein R.sub.4 represents a hydrogen atom or a substituted or unsubstituted alkyl group, --SO.sub.2 --, ##STR3## wherein R.sub.5 represents a substituted or unsubstituted alkyl group, and ##STR4## and l represents 0 or an integer of from 1 to 3; and when l is 2 or 3, the groups R.sub.3 may be the same or different.
    Type: Grant
    Filed: April 4, 1986
    Date of Patent: August 16, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Hirai, Hiroshi Hara, Ken Kawata
  • Patent number: 4761360
    Abstract: A light-sensitive material comprising a light-sensitive layer which contains silver halide, a reducing agent and a polymerizable compound provided on a support, characterized in that the light-sensitive layer further contains a silver diazotate having the following formula:Ar--N.dbd.N--O--Ag(L).sub.nin which Ar is an aryl group or a heterocyclic group, each of which may have one or more substituent groups; L is a ligand; and n is 0, 1 or 2. Image-forming methods utilizing the light-sensitive materials are also disclosed.
    Type: Grant
    Filed: February 24, 1987
    Date of Patent: August 2, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kozo Sato, Soichiro Yamamoto
  • Patent number: 4756999
    Abstract: A photothermographic element comprising a substrate having coated thereon a photothermographic medium comprising a binder having dispersed therein an organic silver salt or complex, a photocatalyst and a reducing agent, characterized in that the photothermographic medium contains as an antifoggant, in the absence of mercury compounds, an effective antifogging amount of a compound of the general formula: ##STR1## characterized in that: X.sup.1 and X.sup.2 independently represent halogen atoms,X.sup.3 represents a halogen atom or an electron withdrawing substituent, andZ represents the necessary atoms to complete a ring system which may comprise a single ring or a fused ring system which rings may bear substituents.
    Type: Grant
    Filed: November 3, 1986
    Date of Patent: July 12, 1988
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Steven Swain, Ronald E. Watts
  • Patent number: 4753862
    Abstract: A light-sensitive material comprising a light-sensitive layer which contains silver halide, a reducing agent and a polymerizable compound provided on a support, characterized in that the light-sensitive layer further contains a triazenesilver having the following formula: ##STR1## in which Ar is an aryl group or a heterocyclic group, each of which may have one or more substituent groups; R is a monovalent group selected from the group consisting of an alkyl group, a cycloalkyl group, an aralkyl group, an aryl group and a heterocyclic group, each of which may have one or more substituent groups; L is a ligand; and n is 0, 1 or 2. Image-forming methods utilizing the light-sensitive materials are also disclosed.
    Type: Grant
    Filed: February 24, 1987
    Date of Patent: June 28, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kozo Sato, Soichiro Yamamoto
  • Patent number: 4752547
    Abstract: A dye-forming electrothermographic element comprises an electrically activatable recording layer comprising (a) a reducing agent or reducing agent precursor capable of being activated by a Lewis base; (b) a cobalt(III) Lewis base complex; and (c) at least one of (i) a reducible dye-forming compound that has an oxidation state above that of the conjugate dye, (ii) a dye capable of changing its wavelength of absorption by reaction with a Lewis base, and (iii) a dye-forming coupler capable of reacting with the oxidized form of the reducing agent in (a) to form a dye. A negative or positive dye image is formed in such a dye-forming electrothermographic element by applying an electrical potential imagewise to the element of a magnitude and for a time sufficient to produce in the image areas a charge density sufficient to produce a latent image; and, then, heating the element to a temperature and for a time sufficient to form a dye image in the element.
    Type: Grant
    Filed: June 4, 1986
    Date of Patent: June 21, 1988
    Assignee: Eastman Kodak Company
    Inventors: Stanley W. Cowen, James C. Fleming, Mark Lelental
  • Patent number: 4743534
    Abstract: Method for preparing photosensitive silver halide crystals. A binder resin, a source of halide ions, and a source of silver ions are dissolved in an organic solvent, e.g., ethanol. Silver halide nuclei will then form. Additional source of halide ions and additional source of silver ions can be added to the solution in incremental additions, so that the initially-formed silver halide nuclei will grow. Upon removal of the solvent, the silver halide crystals will exist in a dry state, entrapped in the binder resin. Silver halide crystals formed and grown in this manner can be used to prepare photothermographic imaging compositions, which compositions will exhibit higher speed than photothermographic imaging compositions containing silver halide crystals grown according to conventional methods.
    Type: Grant
    Filed: November 8, 1985
    Date of Patent: May 10, 1988
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Oanh V. Pham
  • Patent number: 4740445
    Abstract: A color image is formed in an image forming reaction system comprising a photographic heat-developable silver halide light-sensitive material by reacting a difficultly soluble metal compound, for example, calcium carbonate with a compound capable of water-mediated complexing reaction with the metal ion of the difficultly soluble metal compound and having an organic base, for example, guanidine oxalate in the presence of water to increase the pH of the system.
    Type: Grant
    Filed: July 30, 1986
    Date of Patent: April 26, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Hirai, Yoshiharu Yabuki, Kozo Sato
  • Patent number: 4740455
    Abstract: A novel heat developable light-sensitive material is provided comprising a silver halide spectrally sensitized by a polymethine containing at least one basic nucleus wherein the dye contains, as a group for substituting nitrogen atoms in said basic nucleus, at least one of the groups represented by general formulae (A) and (B): ##STR1##--(CH.sub.2 --.sub.2 NHSO.sub.2 Rwherein m represents an integer of 1 or 2; Y represents an atomic group necessary for the formation of a cyclic imide group; and R represents a C.sub.1-4 alkyl group.In a preferred embodiment, the atomic group represented by Y is selected from the group consisting of a succinic acid imido group, a phthalic acid imido group, an orthobenzosulfimido group, and a maleimido group. The atomic group may be optionally substituted by a halogen atom, a nitro group, a carboxyl group, an acylamino group such as an acetylamino group, or an alkoxycarbonyl amino group such as an ethoxycarbonyl group.
    Type: Grant
    Filed: August 6, 1986
    Date of Patent: April 26, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiiti Kubodera, Masaki Okazaki
  • Patent number: 4740363
    Abstract: Alkali is generated from two neutral parts by reacting a complexing agent such as sodium picolinate in one part with a slightly water-soluble metal compound such as zinc oxide in the other part in the presence of water.
    Type: Grant
    Filed: July 30, 1986
    Date of Patent: April 26, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Hirai, Yoshiharu Yabuki, Kozo Sato
  • Patent number: 4735884
    Abstract: A light-sensitive material comprising a light-sensitive layer which contains silver halide, a reducing agent and a polymerizable compound provided on a support, characterized in that the reducing agent is a hydrazine derivative having the following formula (I): ##STR1## in which R.sup.1 is a monovalent group selected from the group consisting of hydrogen, an alkyl group, a cycloalkyl group, an alkenyl group, an aryl group, an aralkyl group, an alkynyl group and a heterocyclic group, each of which may have one or more substituent groups; each of R.sup.2 and R.sup.3 independently is an aryl group which may have one or more substituent group, or R.sup.2 and R.sup.3 form, together with the neighboring carbon, a condensed aromatic ring; R.sup.4 is a monovalent group selected from the group consisting of an aryl group, a heterocyclic group, hydrogen, an alkyl group, an alkoxycarbonyl group and carbamoyl, each of which may have one or more substituent groups.
    Type: Grant
    Filed: February 24, 1987
    Date of Patent: April 5, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Jiro Tsukahara, Taku Nakamura
  • Patent number: 4732846
    Abstract: A heat-developable light-sensitive material is described, comprising a support having provided thereon at least(a) a binder;(b) a light-sensitive silver halide;(c) at least one silver salt of a compound represented by formula (I) or (II) ##STR1## wherein Z represents a non-metallic atomic group forming a heterocyclic ring together with the nitrogen atom,A--C.tbd.
    Type: Grant
    Filed: April 30, 1986
    Date of Patent: March 22, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiaki Aono, Masatoshi Kato, Hiroshi Hara
  • Patent number: 4731321
    Abstract: A heat developable light-sensitive material comprising a support having thereon at least one light-sensitive layer wherein at least one layer comprises a compound represented by the following general formula (I): ##STR1## wherein R.sub.1 and R.sub.2, which may be the same or different, each represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group, a heterocyclic group each of which may be substituted or unsubstituted; a carboxy group or a salt thereof; R.sub.3 and R.sub.
    Type: Grant
    Filed: December 16, 1986
    Date of Patent: March 15, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kozo Sato, Yoshiharu Yabuki, Hiroyuki Hirai, Ken Kawata
  • Patent number: 4728600
    Abstract: A heat-developable light-sensitive material is described, comprising a support having thereon at least (1) a light-sensitive silver halide, (2) a silver salt oxidizing agent, (3) silver salt particles having adsorbed thereon at least one compound selected from a cyclic imino compound represented by formula (I) described below and a mercapto compound represented by formula (II) described below, (4) a reducing agent, and (5) a binder.Formula (I) is represented by ##STR1## wherein Z represents a non-metallic atomic group forming a heterocyclic ring containing an imino group together with the nitrogen atom of formula (I).Formula (II) is represented byR--S--M (II)wherein M represents a hydrogen atom or an alkali metal atom; and R represents a substituted or unsubstituted aliphatic hydrocarbon group, a substituted or unsubstituted aromatic hydrocarbon group, or a substituted or unsubstituted heterocyclic group.
    Type: Grant
    Filed: April 17, 1986
    Date of Patent: March 1, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Hara, Toshiaki Aono
  • Patent number: 4725534
    Abstract: A process for producing a heat-developable photosensitive material containing fine photosensitive silver halide particles having a uniform particle form and particle size, said silver halide being prepared by reacting a silver salt of an organic fatty acid stoichiometrically with an inorganic or organic halogen compound.
    Type: Grant
    Filed: February 26, 1985
    Date of Patent: February 16, 1988
    Assignee: Oriental Photo Industrial Co., Ltd.
    Inventors: Kenji Kagami, Kenichi Nishio, Yukio Takegawa, Kazunori Shigemori
  • Patent number: 4716100
    Abstract: A heat developable light-sensitive material containing a novel base precursor (I), which is stable during storage and rapidly decomposes to release a basic component upon heating higher than a certain temperature, has excellent storability and provides an image having a good image quality, i.e., a low fog density and a high image density within a short period of developing time.
    Type: Grant
    Filed: August 26, 1985
    Date of Patent: December 29, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshiharu Yabuki, Kozo Sato, Ken Kawata, Hiroyuki Hirai
  • Patent number: 4713316
    Abstract: A heat-developable photographic material having improved preservability, which comprises a support having thereon at least one heat-developable photographic layer, said photographic material containing a dye represented by formula (I) ##STR1## wherein n and m each represents 0, 1, 2 or 3;p and q each represents 0 or 1;L represents a methine group or a substituted methine group;R.sub.1 and R.sub.2 are same or different and each represents an unsubstituted or substituted alkyl group;R.sub.3 and R.sub.4 are same or different and each represents a hydrogen atom, an alkyl group, an alkoxy group, a hydroxyl group, an unsubstituted or substituted amino group or a halogen atom; or said R.sub.3 and R.sub.4 form a condensed 6-membered ring;Z and Z' are same or different and each represents a non-metallic atomic group necessary for forming a substituted or unsubstituted 5-membered or 6-membered ring, or substituted or unsubstituted 5-membered or 6-membered ring which is condensed with another ring;X.sup..crclbar.
    Type: Grant
    Filed: December 4, 1985
    Date of Patent: December 15, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiiti Kubodera, Toshinao Ukai, Hisashi Okada
  • Patent number: 4710450
    Abstract: A photographic element comprising photosensitive and image-receiving layers on a support further includes a primary exothermic electroconductive layer serving as a heating element and an auxiliary exothermic electroconductive layer thereon, wherein the primary conductive layer containing conductive substance like carbon black so that it is heated upon electric conduction, contributing to heat development.
    Type: Grant
    Filed: February 13, 1986
    Date of Patent: December 1, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hideki Naito
  • Patent number: 4708928
    Abstract: Photothermographic imaging chemistry, and particularly color chemistry, can be contained within solid particles. Photothermographic media can then be made by dispersing these particles within a binder in the concentrations and proportions desired.
    Type: Grant
    Filed: August 29, 1986
    Date of Patent: November 24, 1987
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Thomas C. Geisler
  • Patent number: 4696887
    Abstract: A novel method for formation of an image comprising a heating step, comprising the heating carried out in the presence of a compound of general formula (I):X--SO.sub.2 (DI) (I)wherein X represents a reducing group capable of reducing a silver salt and capable of being oxidized by heating and in its oxidized state capable of releasing a compound represented by (DI)--SO.sub.2 NH.sub.2 by reaction with a nucleophilic agent; and (DI) represents a development inhibiting group capable of inhibiting the oxidation reduction reaction of the silver salt and a reducing aent.The compound of the formula (I) functions to inhibit development after a certain period of time from the beginning of heat development.The present method provides a stable image with reduced fog and image mottle.
    Type: Grant
    Filed: February 13, 1986
    Date of Patent: September 29, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kozo Sato, Hiroshi Kitaguchi, Masashi Takeuchi, Masaaki Tsukase, Masatoshi Kato