Hardener Patents (Class 430/451)
  • Publication number: 20030215757
    Abstract: A method of processing photosensitive materials in which one or more chemical compounds are at least partially retained after processing. The chemical compounds are unique to a particular process used by a copyright owner. The absence of the unique compounds in a processed material thus indicates that the processing has been without the authorization of the copyright owner.
    Type: Application
    Filed: May 13, 2003
    Publication date: November 20, 2003
    Applicant: Eastman Kodak Company
    Inventor: John R. Fyson
  • Patent number: 6468339
    Abstract: A gelatin based photographic coating contains at least gelatin and colloidal alumina particles less than 0.2 &mgr;m. Additionally, the coating may contain any photographic addenda that may be important to the performance of a photographic product, as well as a chemical hardening agent that forms crosslinks in the coating. The alumina filled gelatin coating, when swollen with water or a photo processing solution yields an increase in wet durability in the form of an increased wet scratch resistance.
    Type: Grant
    Filed: August 23, 2001
    Date of Patent: October 22, 2002
    Assignee: Eastman Kodak Company
    Inventors: Jeffrey F. Taylor, Mridula Nair
  • Patent number: 6284426
    Abstract: The present invention provides an alkaline processing solution comprising at least one silver halide solvent other than sulfite, characterized in that said alkaline processing solution further contains aluminium ions in an amount of at least 0.3 g/l. There is further provided a method for making a lithographic printing plate according to the DTR-process using an aqueous alkaline processing solution in the presence of at least one developing agent and at least one silver halide solvent, characterized in that said alkaline processing solution contains aluminium ions in an amount of at least 0.3 g/l.
    Type: Grant
    Filed: April 22, 1996
    Date of Patent: September 4, 2001
    Assignee: Agfa-Gevaert
    Inventors: Paul Coppens, Ludo Vervloet
  • Patent number: 5968646
    Abstract: The present invention comprises a polyester film support in which the surface has been subjected to an energetic treatment with nitrogen plasma to produce amine groups on the polyester surface. The treated surface is then coated with a dilute solution of amine reactive hardener and gelatin. After drying the hardener/gelatin coated support a photographic emulsion is coated on the surface. The resulting film element has excellent adhesion of the photographic emulsion after photoprocessing, and it is safer to coat and handle than previously known methods involving grafting of hardener directly to the support.
    Type: Grant
    Filed: January 19, 1996
    Date of Patent: October 19, 1999
    Assignee: Eastman Kodak Company
    Inventors: Jeremy M. Grace, Louis J. Gerenser, Richard A. Castle, Janglin Chen, Edgar E. Riecke
  • Patent number: 5968720
    Abstract: A photographic fixer compositions comprising a silver halide solvent, an aluminum salt hardening agent, a buffering agent and ammonium ions in amount of at least 0.20 mol/l, wherein said fixer composition also contains at least an aminopolycarboxylic acid sequestering agent of formula (I-a) or (I-b) or a water-soluble salt thereof and d) at least a polyphosphonic acid sequestering agent of formula (II-a), (II-b), (II-c), (II-d') or (II-d"): ##STR1## wherein the substituents are defined in the specification. The present invention also provides a method of processing an exposed photographic silver halide element comprising the steps of developing by means of a developer comprising a silver halide developing agent and treating the developed element with a fixer composition, wherein the fixer composition is one described above.
    Type: Grant
    Filed: July 15, 1996
    Date of Patent: October 19, 1999
    Assignee: Imation Corp
    Inventors: Filippo Faranda, Franco Buriano, Carlo Marchesano
  • Patent number: 5780211
    Abstract: Disclosed is a photographic processing composition in the tablet form which comprises a first and a second ingredients, said composition being prepared by a first granulating a first powder comprising said first ingredient to form first granules, a second granulating a second powder comprising said second ingredient to form second granules, mixing said first and second granules, and compressing said mixture of granules. The tables have an apparent density of 1.0 to 2.5 g/cm.sup.3.
    Type: Grant
    Filed: April 9, 1997
    Date of Patent: July 14, 1998
    Assignee: Konica Corporation
    Inventors: Yoshimasa Komatsu, Shigeharu Koboshi, Masao Ishikawa
  • Patent number: 5707787
    Abstract: A processing solution for processing an exposed silver halide photographic light-sensitive material comprises a compound represented by the following formula (A): ##STR1## wherein A.sub.1, A.sub.2, A.sub.3 and A.sub.4 each represent --COOM.sub.1, --OH, --PO.sub.3 M.sub.1 M.sub.2 or --CONH.sub.2 in which M.sub.1 and M.sub.2 each represent a hydrogen ion, an alkali metal ion or another cation; R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represent a hydrogen atom, a lower alkyl group or a hydroxyl group; n.sub.1, n.sub.2, n.sub.3 and n.sub.4 each represent an integer of 0, 1 or 2, provided that none of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are hydrogen atoms when n.sub.1 +n.sub.2 =1 and n.sub.3 +n.sub.4 =1; and X represents a substituted or unsubstituted alkylene group having 2 to 6 carbon atoms or --(B.sub.1 O)m-B.sub.2 -- in which B.sub.1 and B.sub.2 each represent a substituted or unsubstituted alkylene group having 1 to 5 carbon atoms, and m is an integer of from 1 to 4.
    Type: Grant
    Filed: August 11, 1993
    Date of Patent: January 13, 1998
    Assignee: Konica Corporation
    Inventors: Kenji Kuwae, Yutaka Ueda
  • Patent number: 5635341
    Abstract: A solution for bleaching or bleach-fixing an exposed and developed silver halide color photographic light-sensitive material contains a ferric complex salt of a compound represented by the following Formula (A-I), (A-II) or (A-III), and a compound represented by the following Formula (B): ##STR1##
    Type: Grant
    Filed: May 23, 1995
    Date of Patent: June 3, 1997
    Assignee: Konica Corporation
    Inventors: Hiroshi Yamashita, Yutaka Ueda
  • Patent number: 5591863
    Abstract: This invention is related to improved hardeners for proteinaceous materials. More specifically this invention is related to improved imidazolium hardeners for crosslinking a proteinaceous material for use in a photographic film.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: January 7, 1997
    Assignee: Sterling Diagnostic Imaging, Inc.
    Inventors: Ludovic Fodor, Timothy D. Weatherill, Rolf T. Weberg
  • Patent number: 5573895
    Abstract: A recycling method for photographic processing waste liquid is disclosed. The photographic processing waste liquid is subjected to evaporative concentration under a reduced pressure of not higher than 700 mmHg and at a temperature of not higher than 90.degree. C. The resulting distillate is used as a solvent for photographic processing agents or as an evaporation compensator for processing tanks of an automatic processing machine.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: November 12, 1996
    Assignee: Konica Corporation
    Inventors: Yoshimasa Komatsu, Masao Ishikawa, Moeko Hagiwara, Kenji Ishida, Hiroshi Yoshimoto, Shinsaku Nagaoka
  • Patent number: 5482827
    Abstract: Light-sensitive silver halide photographic elements comprising a support bearing at least one gelatin-containing silver halide emulsion layer, wherein the silver halide emulsion is chemically sensitized with sulfur and gold in the presence of a sulfinic acid compound and the gelatin is hardened with a carbamoylpyridinium salt compound.
    Type: Grant
    Filed: January 3, 1995
    Date of Patent: January 9, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Mauro Besio, Giuseppe Rocca
  • Patent number: 5470986
    Abstract: Hardeners for hydrophilic colloid defined by the formula: ##STR1## The hardeners are for crosslinking proteinaceous materials for use in photographic films.
    Type: Grant
    Filed: June 27, 1994
    Date of Patent: November 28, 1995
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Ludovic Fodor, Timothy D. Weatherill, Rolf T. Weberg
  • Patent number: 5441852
    Abstract: A method of processing a silver halide color photographic material by exposing the material to light, color developing, processing with a solution having a fixing function and thereafter, stabilizing the material. The stabilizing processing solution is one in for replacing formaldehyde in known processing solutions. The compound that replaces the formaldehyde is a meta substituted benzaldehyde. A method of using the processing solution is also disclosed.
    Type: Grant
    Filed: May 4, 1994
    Date of Patent: August 15, 1995
    Assignee: Konica Corporation
    Inventors: Moeko Hagiwara, Hiroaki Kobayashi
  • Patent number: 5424177
    Abstract: Disclosed is a stabilizer for silver halide color photographic light-sensitive materials comprising-at least one compound represented by Formula (I) and at least one compound selected from the group consisting of Formula (II-A), Formula (II-B) and Formula (II-C); ##STR1## wherein Z represents a group of atoms necessary to form a substituted or unsubstituted homocycle or a substituted or unsubstituted heterocycle, X represents an aldehyde group, ##STR2## wherein R.sub.1 and R.sub.2 each represents a lower alkyl group; 1 represents an integer of 1 to 4, ##STR3## wherein R.sub.1 and R.sub.2 each represent a hydrogen atom or a lower alkyl group, X.sub.1 and X.sub.2 each represent an alkyleneoxy group or a branched alkyleneoxy group, m and n each represents 0 or an integer of 1 to 100, provided that m+n.ltoreq.100 is satisfied, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 each represents a hydrogen atom, a hydroxyl group, a lower alkyl group, an alkoxyl group, a halogen atom or a hydroxyalkyl group.
    Type: Grant
    Filed: June 26, 1992
    Date of Patent: June 13, 1995
    Assignee: Konica Corporation
    Inventors: Hiroaki Kobayashi, Kenji Kuwae, Moeko Hagiwara
  • Patent number: 5316898
    Abstract: A solid composition for bleaching an exposed and developed silver halide color photographic light-sensitive material and processing method thereof. The composition contains at least one kind of ferric complex salt and is in the form of a tablet having a bulk density of 1.0 to 2.5 g/cm.sup.3. The composition provides excellent solubility and preservability.
    Type: Grant
    Filed: February 24, 1993
    Date of Patent: May 31, 1994
    Assignee: Konica Corporation
    Inventors: Yutaka Ueda, Hiroshi Yamashita
  • Patent number: 5278035
    Abstract: A non-hydroquinone and non-alkali metal hydroxide containing developer composition for radiographic materials and a method of use thereof are provided. The developer composition comprises a developer selected from the group consisting of ascorbic acid and sugar-type derivatives thereof, stereoisomers and diastereoisomers of ascorbic acid and its sugar-type derivatives, their salts and mixtures thereof, together with a sulfite, a 3-pyrazolidone compound, and an anti-swelling agent selected from the group consisting of sodium sulfate, glutaraldehyde or mixtures thereof, said composition having a pH of from 9.5 to 10.6, and said developer being present in an amount of at least about 15 grams, said sulfite being present in an amount of from 2 to 50 grams, said swelling control agent being present in an amount of from 35 to 90 grams, and water to 1.0 liter.
    Type: Grant
    Filed: April 12, 1991
    Date of Patent: January 11, 1994
    Inventor: Audenried W. Knapp
  • Patent number: 5217853
    Abstract: A method for development processing of a silver halide photosensitive material using an automatic processor including at least the functions of development, fixing, washing and drying is disclosed, comprising using an alkaline developer containing a dialdehyde film hardening agent and carrying out the processing under conditions such that the running equilibrium pH of the fixer is at least 4.6.
    Type: Grant
    Filed: August 3, 1992
    Date of Patent: June 8, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Minoru Yamada, Takashi Toyoda
  • Patent number: 5155004
    Abstract: A chitosan or chitin compound having a photographically useful residue. There is also disclosed a method for processing a silver halide photographic material which comprises processing a silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer in the presence of said chitosan or chitin compound represented by the following general formula (I) ##STR1## wherein the substituents are defined in the instant specification.
    Type: Grant
    Filed: March 13, 1991
    Date of Patent: October 13, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tetsuro Kojima
  • Patent number: 5135840
    Abstract: Photographic processing chemicals in the form of granulates having an average particle diameter of from 150 to 3000 .mu.m containing a polymer having a molar mass of from 6,000,000 to 14,000,000 in a quantity from 1 to 1,000 mg/kg of granulate consisting of at least 80 mol % of one or more of the monomers, acrylamide, acrylic acid and cationic monomer or mixtures of acrylamide and cationic or anionic monomer are distinguished by being easy to prepare, dust free and freely pourable.
    Type: Grant
    Filed: March 8, 1991
    Date of Patent: August 4, 1992
    Assignee: Agfa Gevaert Aktiengesellschaft
    Inventors: Karl-Heinz Reuter, Heinz Meckl
  • Patent number: 5034249
    Abstract: Layers containing proteinaceous binders, in particular gelatin layers of the kind used, for example, in photographic recording materials, are hardened by means of an instant hardener by casting a hardening system composed of at least two layers over the layer of binder, the lower of these two layers containing the instant hardener while the upper layer, which may be applied together with or immediately after the lower layer, contains a protein-containing binder but no hardener. The hardened layers have improved surface properties (wet scratch resistance, antifriction properties).
    Type: Grant
    Filed: August 19, 1987
    Date of Patent: July 23, 1991
    Assignee: Agfa Gevaert Aktiengesellschaft
    Inventors: Heinz Reif, Prem Lalvani, Hans Buschmann
  • Patent number: 4978607
    Abstract: A photographic recording material which comprises at least one gelatin-containing silver halide emulsion layer and at least one protective layer containing a gelatin derivative, the protective layer being further away from the layer support than each silver halide emulsion layer and 30 to 90% of the amino groups of the gelatin in the gelatin derivative being reacted with a monofunctional acid derivative, and which is hardened with an instant hardener can be produced at high speed and, hence, at high drying temperatures without any reticulation grain occurring during processing.
    Type: Grant
    Filed: September 1, 1988
    Date of Patent: December 18, 1990
    Assignee: AGFA-Gevaert Aktiengessellschaft
    Inventors: Edouard Roche, Wolfgang Himmelmann, Hans-Theo Buschmann, Heinz Quambusch
  • Patent number: 4908300
    Abstract: A method of a processing of a silver halide color photographic material is disclosed. The process comprises a step of developing the exposed color photographic material and a step of treating the developed color photographic material with a bleach-fixing solution. The bleach-fixing solution contains an organic acid ferric complex. At least one layer of the emulsion layers of the photographic material contains silver halide grains containing from 0.5 to 25 mol % of silver iodide. The total dry-thickness of the photographic component layers contained in the photographic material is from 8 to 25 .mu.m and the swelling rate T1/2 of the photographic component layers is not more than 25 sec. The method is suitable for rapid processing of the fine grain-type high-speed silver iodide-containing color photographic material. The method uses a bleach-fixing bath enabling the rapid processing of the high-speed color photographic material.
    Type: Grant
    Filed: October 14, 1988
    Date of Patent: March 13, 1990
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Shigeharu Koboshi, Moeko Higuchi, Shinji Kadota
  • Patent number: 4904554
    Abstract: A process for hardening gelatin holograms after dehydration involving subjecting the hologram to an atmosphere containing aldehyde vapor and water vapor. The process provides hardening of the gelatin hologram to increase resistance to moisture and heat without adversely affecting diffraction efficiency. Monitoring of the diffraction efficiency during the aldehyde-water vapor treatment allows fine tuning of the hologram efficiency and evenness.
    Type: Grant
    Filed: March 21, 1988
    Date of Patent: February 27, 1990
    Assignee: Hughes Aircraft Company
    Inventor: John E. Wreede
  • Patent number: 4874687
    Abstract: A method for forming an image comprising the steps of:(a) imagewise exposing a light-sensitive silver halide photographic material comprising a support having provided on at least one surface thereof a light-sensitive silver halide emulsion, at least one of an active halogen hardening agent and a bisvinylsulfone hardening agent, and a slightly water-soluble basic metallic compound; and(b) developing said exposed material with a developer solution containing a compound capable of reacting with said basic metallic compound to release a base.
    Type: Grant
    Filed: November 18, 1987
    Date of Patent: October 17, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Masamichi Itabashi
  • Patent number: 4751173
    Abstract: A process for hardening gelatin, which comprises incorporating in a gelatin-containing material at least one hardening compound represented by formula (I) ##STR1## wherein R.sup.1 represents a substituted or unsubstituted aryl group, Z represents non-metallic atoms necessary for the formation of a nitrogen-containing heteroaromatic ring which may optionally be substituted, X.sup..crclbar. represents an anion, and n represents 0 or 1 provided that when n represents 0, the compound forms an inner salt. The gelatin hardeners can rapidly harden gelatin with little or no post-hardening and react with reactive groups of gelatin with high selectivity.
    Type: Grant
    Filed: December 29, 1986
    Date of Patent: June 14, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okamura, Hiroshi Kawamoto
  • Patent number: 4690884
    Abstract: A scavenger-spreader element adapted for use with a photosensitive element to form a negative image is disclosed as well as methods for processing said photosensitive element to produce the negative image. The scavenger-spreader element comprises a support carrying a hydrophilic layer, a cross-linking agent for the polymeric thickener of the photographic processing composition, a barrier layer to control diffusion of said cross-linking agent and a layer adapted to possess substantial adhesion for the cross-linked polymeric thickening agent.
    Type: Grant
    Filed: February 11, 1986
    Date of Patent: September 1, 1987
    Assignee: Polaroid Corporation
    Inventors: Frank E. DeBruyn, Jr., Lucretia J. Weed
  • Patent number: 4256826
    Abstract: A bleach-fix sheet for use in color photographic processes comprises a support having thereon a bleaching agent, a fixing agent and a hardened hydrophilic binder. In a preferred embodiment, the bleach-fix sheet is useful to bleach and fix a retained image in a color image diffusion transfer unit.
    Type: Grant
    Filed: August 14, 1978
    Date of Patent: March 17, 1981
    Assignee: Eastman Kodak Company
    Inventors: Gerhard Popp, Patrick H. Saturno, Keith H. Stephen
  • Patent number: 4216108
    Abstract: A proteinaceous material such as gelatin is hardened by treatment with an aqueous solution of a partial hydrolysis product of cyanuric chloride that has been buffered with a water-soluble borate, e.g. sodium metaborate, potassium metaborate or ammonium metaborate.The proteinaceous material can be a proteinaceous coating such as a photographic silver halide emulsion layer, a backing layer, a protective layer, a filter layer or any other photographic auxiliary layer.
    Type: Grant
    Filed: March 27, 1979
    Date of Patent: August 5, 1980
    Assignee: AGFA-GEVAERT N.V.
    Inventors: Francis J. Sels, Hendrik E. Kokelenberg, George F. van Veelen
  • Patent number: 4181529
    Abstract: A proteinaceous material such as gelatin is hardened by treatment with an aqueous solution of a partial hydrolysis product of cyanuric chloride that has been buffered with a water-soluble borate, e.g. sodium metaborate, potassium metaborate or ammonium metaborate.The proteinaceous material can be a proteinaceous coating such as a photographic silver halide emulsion layer, a backing layer, a protective layer, a filter layer or any other photographic auxiliary layer.
    Type: Grant
    Filed: May 9, 1978
    Date of Patent: January 1, 1980
    Assignee: AGFA-GEVAERT N.V.
    Inventors: Francis J. Sels, Hendrik E. Kokelenberg, George F. Van Veelen