Hardener Patents (Class 430/451)
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Publication number: 20030215757Abstract: A method of processing photosensitive materials in which one or more chemical compounds are at least partially retained after processing. The chemical compounds are unique to a particular process used by a copyright owner. The absence of the unique compounds in a processed material thus indicates that the processing has been without the authorization of the copyright owner.Type: ApplicationFiled: May 13, 2003Publication date: November 20, 2003Applicant: Eastman Kodak CompanyInventor: John R. Fyson
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Patent number: 6468339Abstract: A gelatin based photographic coating contains at least gelatin and colloidal alumina particles less than 0.2 &mgr;m. Additionally, the coating may contain any photographic addenda that may be important to the performance of a photographic product, as well as a chemical hardening agent that forms crosslinks in the coating. The alumina filled gelatin coating, when swollen with water or a photo processing solution yields an increase in wet durability in the form of an increased wet scratch resistance.Type: GrantFiled: August 23, 2001Date of Patent: October 22, 2002Assignee: Eastman Kodak CompanyInventors: Jeffrey F. Taylor, Mridula Nair
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Patent number: 6284426Abstract: The present invention provides an alkaline processing solution comprising at least one silver halide solvent other than sulfite, characterized in that said alkaline processing solution further contains aluminium ions in an amount of at least 0.3 g/l. There is further provided a method for making a lithographic printing plate according to the DTR-process using an aqueous alkaline processing solution in the presence of at least one developing agent and at least one silver halide solvent, characterized in that said alkaline processing solution contains aluminium ions in an amount of at least 0.3 g/l.Type: GrantFiled: April 22, 1996Date of Patent: September 4, 2001Assignee: Agfa-GevaertInventors: Paul Coppens, Ludo Vervloet
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Patent number: 5968646Abstract: The present invention comprises a polyester film support in which the surface has been subjected to an energetic treatment with nitrogen plasma to produce amine groups on the polyester surface. The treated surface is then coated with a dilute solution of amine reactive hardener and gelatin. After drying the hardener/gelatin coated support a photographic emulsion is coated on the surface. The resulting film element has excellent adhesion of the photographic emulsion after photoprocessing, and it is safer to coat and handle than previously known methods involving grafting of hardener directly to the support.Type: GrantFiled: January 19, 1996Date of Patent: October 19, 1999Assignee: Eastman Kodak CompanyInventors: Jeremy M. Grace, Louis J. Gerenser, Richard A. Castle, Janglin Chen, Edgar E. Riecke
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Patent number: 5968720Abstract: A photographic fixer compositions comprising a silver halide solvent, an aluminum salt hardening agent, a buffering agent and ammonium ions in amount of at least 0.20 mol/l, wherein said fixer composition also contains at least an aminopolycarboxylic acid sequestering agent of formula (I-a) or (I-b) or a water-soluble salt thereof and d) at least a polyphosphonic acid sequestering agent of formula (II-a), (II-b), (II-c), (II-d') or (II-d"): ##STR1## wherein the substituents are defined in the specification. The present invention also provides a method of processing an exposed photographic silver halide element comprising the steps of developing by means of a developer comprising a silver halide developing agent and treating the developed element with a fixer composition, wherein the fixer composition is one described above.Type: GrantFiled: July 15, 1996Date of Patent: October 19, 1999Assignee: Imation CorpInventors: Filippo Faranda, Franco Buriano, Carlo Marchesano
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Patent number: 5780211Abstract: Disclosed is a photographic processing composition in the tablet form which comprises a first and a second ingredients, said composition being prepared by a first granulating a first powder comprising said first ingredient to form first granules, a second granulating a second powder comprising said second ingredient to form second granules, mixing said first and second granules, and compressing said mixture of granules. The tables have an apparent density of 1.0 to 2.5 g/cm.sup.3.Type: GrantFiled: April 9, 1997Date of Patent: July 14, 1998Assignee: Konica CorporationInventors: Yoshimasa Komatsu, Shigeharu Koboshi, Masao Ishikawa
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Patent number: 5707787Abstract: A processing solution for processing an exposed silver halide photographic light-sensitive material comprises a compound represented by the following formula (A): ##STR1## wherein A.sub.1, A.sub.2, A.sub.3 and A.sub.4 each represent --COOM.sub.1, --OH, --PO.sub.3 M.sub.1 M.sub.2 or --CONH.sub.2 in which M.sub.1 and M.sub.2 each represent a hydrogen ion, an alkali metal ion or another cation; R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represent a hydrogen atom, a lower alkyl group or a hydroxyl group; n.sub.1, n.sub.2, n.sub.3 and n.sub.4 each represent an integer of 0, 1 or 2, provided that none of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are hydrogen atoms when n.sub.1 +n.sub.2 =1 and n.sub.3 +n.sub.4 =1; and X represents a substituted or unsubstituted alkylene group having 2 to 6 carbon atoms or --(B.sub.1 O)m-B.sub.2 -- in which B.sub.1 and B.sub.2 each represent a substituted or unsubstituted alkylene group having 1 to 5 carbon atoms, and m is an integer of from 1 to 4.Type: GrantFiled: August 11, 1993Date of Patent: January 13, 1998Assignee: Konica CorporationInventors: Kenji Kuwae, Yutaka Ueda
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Patent number: 5635341Abstract: A solution for bleaching or bleach-fixing an exposed and developed silver halide color photographic light-sensitive material contains a ferric complex salt of a compound represented by the following Formula (A-I), (A-II) or (A-III), and a compound represented by the following Formula (B): ##STR1##Type: GrantFiled: May 23, 1995Date of Patent: June 3, 1997Assignee: Konica CorporationInventors: Hiroshi Yamashita, Yutaka Ueda
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Patent number: 5591863Abstract: This invention is related to improved hardeners for proteinaceous materials. More specifically this invention is related to improved imidazolium hardeners for crosslinking a proteinaceous material for use in a photographic film.Type: GrantFiled: June 5, 1995Date of Patent: January 7, 1997Assignee: Sterling Diagnostic Imaging, Inc.Inventors: Ludovic Fodor, Timothy D. Weatherill, Rolf T. Weberg
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Patent number: 5573895Abstract: A recycling method for photographic processing waste liquid is disclosed. The photographic processing waste liquid is subjected to evaporative concentration under a reduced pressure of not higher than 700 mmHg and at a temperature of not higher than 90.degree. C. The resulting distillate is used as a solvent for photographic processing agents or as an evaporation compensator for processing tanks of an automatic processing machine.Type: GrantFiled: June 7, 1995Date of Patent: November 12, 1996Assignee: Konica CorporationInventors: Yoshimasa Komatsu, Masao Ishikawa, Moeko Hagiwara, Kenji Ishida, Hiroshi Yoshimoto, Shinsaku Nagaoka
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Patent number: 5482827Abstract: Light-sensitive silver halide photographic elements comprising a support bearing at least one gelatin-containing silver halide emulsion layer, wherein the silver halide emulsion is chemically sensitized with sulfur and gold in the presence of a sulfinic acid compound and the gelatin is hardened with a carbamoylpyridinium salt compound.Type: GrantFiled: January 3, 1995Date of Patent: January 9, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: Mauro Besio, Giuseppe Rocca
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Patent number: 5470986Abstract: Hardeners for hydrophilic colloid defined by the formula: ##STR1## The hardeners are for crosslinking proteinaceous materials for use in photographic films.Type: GrantFiled: June 27, 1994Date of Patent: November 28, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventors: Ludovic Fodor, Timothy D. Weatherill, Rolf T. Weberg
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Patent number: 5441852Abstract: A method of processing a silver halide color photographic material by exposing the material to light, color developing, processing with a solution having a fixing function and thereafter, stabilizing the material. The stabilizing processing solution is one in for replacing formaldehyde in known processing solutions. The compound that replaces the formaldehyde is a meta substituted benzaldehyde. A method of using the processing solution is also disclosed.Type: GrantFiled: May 4, 1994Date of Patent: August 15, 1995Assignee: Konica CorporationInventors: Moeko Hagiwara, Hiroaki Kobayashi
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Patent number: 5424177Abstract: Disclosed is a stabilizer for silver halide color photographic light-sensitive materials comprising-at least one compound represented by Formula (I) and at least one compound selected from the group consisting of Formula (II-A), Formula (II-B) and Formula (II-C); ##STR1## wherein Z represents a group of atoms necessary to form a substituted or unsubstituted homocycle or a substituted or unsubstituted heterocycle, X represents an aldehyde group, ##STR2## wherein R.sub.1 and R.sub.2 each represents a lower alkyl group; 1 represents an integer of 1 to 4, ##STR3## wherein R.sub.1 and R.sub.2 each represent a hydrogen atom or a lower alkyl group, X.sub.1 and X.sub.2 each represent an alkyleneoxy group or a branched alkyleneoxy group, m and n each represents 0 or an integer of 1 to 100, provided that m+n.ltoreq.100 is satisfied, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 each represents a hydrogen atom, a hydroxyl group, a lower alkyl group, an alkoxyl group, a halogen atom or a hydroxyalkyl group.Type: GrantFiled: June 26, 1992Date of Patent: June 13, 1995Assignee: Konica CorporationInventors: Hiroaki Kobayashi, Kenji Kuwae, Moeko Hagiwara
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Patent number: 5316898Abstract: A solid composition for bleaching an exposed and developed silver halide color photographic light-sensitive material and processing method thereof. The composition contains at least one kind of ferric complex salt and is in the form of a tablet having a bulk density of 1.0 to 2.5 g/cm.sup.3. The composition provides excellent solubility and preservability.Type: GrantFiled: February 24, 1993Date of Patent: May 31, 1994Assignee: Konica CorporationInventors: Yutaka Ueda, Hiroshi Yamashita
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Non-toxic photographic developer composition for processing x-ray films in automatic film processors
Patent number: 5278035Abstract: A non-hydroquinone and non-alkali metal hydroxide containing developer composition for radiographic materials and a method of use thereof are provided. The developer composition comprises a developer selected from the group consisting of ascorbic acid and sugar-type derivatives thereof, stereoisomers and diastereoisomers of ascorbic acid and its sugar-type derivatives, their salts and mixtures thereof, together with a sulfite, a 3-pyrazolidone compound, and an anti-swelling agent selected from the group consisting of sodium sulfate, glutaraldehyde or mixtures thereof, said composition having a pH of from 9.5 to 10.6, and said developer being present in an amount of at least about 15 grams, said sulfite being present in an amount of from 2 to 50 grams, said swelling control agent being present in an amount of from 35 to 90 grams, and water to 1.0 liter.Type: GrantFiled: April 12, 1991Date of Patent: January 11, 1994Inventor: Audenried W. Knapp -
Patent number: 5217853Abstract: A method for development processing of a silver halide photosensitive material using an automatic processor including at least the functions of development, fixing, washing and drying is disclosed, comprising using an alkaline developer containing a dialdehyde film hardening agent and carrying out the processing under conditions such that the running equilibrium pH of the fixer is at least 4.6.Type: GrantFiled: August 3, 1992Date of Patent: June 8, 1993Assignee: Fuji Photo Film Co., Ltd.Inventors: Minoru Yamada, Takashi Toyoda
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Patent number: 5155004Abstract: A chitosan or chitin compound having a photographically useful residue. There is also disclosed a method for processing a silver halide photographic material which comprises processing a silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer in the presence of said chitosan or chitin compound represented by the following general formula (I) ##STR1## wherein the substituents are defined in the instant specification.Type: GrantFiled: March 13, 1991Date of Patent: October 13, 1992Assignee: Fuji Photo Film Co., Ltd.Inventor: Tetsuro Kojima
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Patent number: 5135840Abstract: Photographic processing chemicals in the form of granulates having an average particle diameter of from 150 to 3000 .mu.m containing a polymer having a molar mass of from 6,000,000 to 14,000,000 in a quantity from 1 to 1,000 mg/kg of granulate consisting of at least 80 mol % of one or more of the monomers, acrylamide, acrylic acid and cationic monomer or mixtures of acrylamide and cationic or anionic monomer are distinguished by being easy to prepare, dust free and freely pourable.Type: GrantFiled: March 8, 1991Date of Patent: August 4, 1992Assignee: Agfa Gevaert AktiengesellschaftInventors: Karl-Heinz Reuter, Heinz Meckl
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Patent number: 5034249Abstract: Layers containing proteinaceous binders, in particular gelatin layers of the kind used, for example, in photographic recording materials, are hardened by means of an instant hardener by casting a hardening system composed of at least two layers over the layer of binder, the lower of these two layers containing the instant hardener while the upper layer, which may be applied together with or immediately after the lower layer, contains a protein-containing binder but no hardener. The hardened layers have improved surface properties (wet scratch resistance, antifriction properties).Type: GrantFiled: August 19, 1987Date of Patent: July 23, 1991Assignee: Agfa Gevaert AktiengesellschaftInventors: Heinz Reif, Prem Lalvani, Hans Buschmann
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Patent number: 4978607Abstract: A photographic recording material which comprises at least one gelatin-containing silver halide emulsion layer and at least one protective layer containing a gelatin derivative, the protective layer being further away from the layer support than each silver halide emulsion layer and 30 to 90% of the amino groups of the gelatin in the gelatin derivative being reacted with a monofunctional acid derivative, and which is hardened with an instant hardener can be produced at high speed and, hence, at high drying temperatures without any reticulation grain occurring during processing.Type: GrantFiled: September 1, 1988Date of Patent: December 18, 1990Assignee: AGFA-Gevaert AktiengessellschaftInventors: Edouard Roche, Wolfgang Himmelmann, Hans-Theo Buschmann, Heinz Quambusch
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Patent number: 4908300Abstract: A method of a processing of a silver halide color photographic material is disclosed. The process comprises a step of developing the exposed color photographic material and a step of treating the developed color photographic material with a bleach-fixing solution. The bleach-fixing solution contains an organic acid ferric complex. At least one layer of the emulsion layers of the photographic material contains silver halide grains containing from 0.5 to 25 mol % of silver iodide. The total dry-thickness of the photographic component layers contained in the photographic material is from 8 to 25 .mu.m and the swelling rate T1/2 of the photographic component layers is not more than 25 sec. The method is suitable for rapid processing of the fine grain-type high-speed silver iodide-containing color photographic material. The method uses a bleach-fixing bath enabling the rapid processing of the high-speed color photographic material.Type: GrantFiled: October 14, 1988Date of Patent: March 13, 1990Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Shigeharu Koboshi, Moeko Higuchi, Shinji Kadota
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Patent number: 4904554Abstract: A process for hardening gelatin holograms after dehydration involving subjecting the hologram to an atmosphere containing aldehyde vapor and water vapor. The process provides hardening of the gelatin hologram to increase resistance to moisture and heat without adversely affecting diffraction efficiency. Monitoring of the diffraction efficiency during the aldehyde-water vapor treatment allows fine tuning of the hologram efficiency and evenness.Type: GrantFiled: March 21, 1988Date of Patent: February 27, 1990Assignee: Hughes Aircraft CompanyInventor: John E. Wreede
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Patent number: 4874687Abstract: A method for forming an image comprising the steps of:(a) imagewise exposing a light-sensitive silver halide photographic material comprising a support having provided on at least one surface thereof a light-sensitive silver halide emulsion, at least one of an active halogen hardening agent and a bisvinylsulfone hardening agent, and a slightly water-soluble basic metallic compound; and(b) developing said exposed material with a developer solution containing a compound capable of reacting with said basic metallic compound to release a base.Type: GrantFiled: November 18, 1987Date of Patent: October 17, 1989Assignee: Fuji Photo Film Co., Ltd.Inventor: Masamichi Itabashi
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Patent number: 4751173Abstract: A process for hardening gelatin, which comprises incorporating in a gelatin-containing material at least one hardening compound represented by formula (I) ##STR1## wherein R.sup.1 represents a substituted or unsubstituted aryl group, Z represents non-metallic atoms necessary for the formation of a nitrogen-containing heteroaromatic ring which may optionally be substituted, X.sup..crclbar. represents an anion, and n represents 0 or 1 provided that when n represents 0, the compound forms an inner salt. The gelatin hardeners can rapidly harden gelatin with little or no post-hardening and react with reactive groups of gelatin with high selectivity.Type: GrantFiled: December 29, 1986Date of Patent: June 14, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Hisashi Okamura, Hiroshi Kawamoto
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Patent number: 4690884Abstract: A scavenger-spreader element adapted for use with a photosensitive element to form a negative image is disclosed as well as methods for processing said photosensitive element to produce the negative image. The scavenger-spreader element comprises a support carrying a hydrophilic layer, a cross-linking agent for the polymeric thickener of the photographic processing composition, a barrier layer to control diffusion of said cross-linking agent and a layer adapted to possess substantial adhesion for the cross-linked polymeric thickening agent.Type: GrantFiled: February 11, 1986Date of Patent: September 1, 1987Assignee: Polaroid CorporationInventors: Frank E. DeBruyn, Jr., Lucretia J. Weed
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Patent number: 4256826Abstract: A bleach-fix sheet for use in color photographic processes comprises a support having thereon a bleaching agent, a fixing agent and a hardened hydrophilic binder. In a preferred embodiment, the bleach-fix sheet is useful to bleach and fix a retained image in a color image diffusion transfer unit.Type: GrantFiled: August 14, 1978Date of Patent: March 17, 1981Assignee: Eastman Kodak CompanyInventors: Gerhard Popp, Patrick H. Saturno, Keith H. Stephen
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Patent number: 4216108Abstract: A proteinaceous material such as gelatin is hardened by treatment with an aqueous solution of a partial hydrolysis product of cyanuric chloride that has been buffered with a water-soluble borate, e.g. sodium metaborate, potassium metaborate or ammonium metaborate.The proteinaceous material can be a proteinaceous coating such as a photographic silver halide emulsion layer, a backing layer, a protective layer, a filter layer or any other photographic auxiliary layer.Type: GrantFiled: March 27, 1979Date of Patent: August 5, 1980Assignee: AGFA-GEVAERT N.V.Inventors: Francis J. Sels, Hendrik E. Kokelenberg, George F. van Veelen
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Patent number: 4181529Abstract: A proteinaceous material such as gelatin is hardened by treatment with an aqueous solution of a partial hydrolysis product of cyanuric chloride that has been buffered with a water-soluble borate, e.g. sodium metaborate, potassium metaborate or ammonium metaborate.The proteinaceous material can be a proteinaceous coating such as a photographic silver halide emulsion layer, a backing layer, a protective layer, a filter layer or any other photographic auxiliary layer.Type: GrantFiled: May 9, 1978Date of Patent: January 1, 1980Assignee: AGFA-GEVAERT N.V.Inventors: Francis J. Sels, Hendrik E. Kokelenberg, George F. Van Veelen