And Bleach Patents (Class 430/460)
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Patent number: 12054842Abstract: An aqueous composition comprising (a) metal ions comprising tin ions and silver ions and (b) at least one complexing agent of formula (C1) R1—X1—S—X21[D1-X22—]n—S—X3—R2, (C2) R1—X1—S—X31-D2-[X32—S—]nX3—R2, (C3) R3—X1—S—X41-[D3-X42—]nS—X3—R4 wherein X1, X3 are independently selected from a linear or branched C1-C12 alkanediyl, which may be unsubstituted or substituted by OH; X21, X22 are independently selected from X1, which may be further substituted by —X5—COOR12, —X5—SO2—O—R12, a C2 to C6 polyoxyalkylene group of formula —(O—CH2—CHR11)z—OH, or a combination thereof, and —X1—NH—CO—X6—CO—NH—X1—; X31, X32 are independently selected from a chemical bond and X1; X41, X42 are independently selected from X1; X5 is a linear or branched Ci to C10 alkyl; X6 is selected from X1 and a divalent 5 or 6 membered aromatic group; R1, R2 are independently selected from a monovalent 5 or 6 membered aromatic N-heterocyclic group comprising one N atom or two N atoms which are separated by at least one C atom, and its derivativeType: GrantFiled: March 22, 2019Date of Patent: August 6, 2024Assignee: BASF SEInventors: Katharina Fritzsche, Doris Kremzow-Graw, Marco Arnold, Alexander Fluegel
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Patent number: 7351522Abstract: An object of the present invention is to provide a method of processing silver halide color paper that ensures (a) promptness such that finished prints can be handed at shop to customers, (b) small installation area for mini-labs, (c) processing solution stability capable of withstanding slack seasons, (d) normal image quality, (e) small replenishment solution amount and (f) inhibition of tar generation and sulfuration phenomenon occurrence. This object can be attained by a concentrated processing composition for color paper which has a concentrated processing composition for bleach replenishment of 3.0 or less in pH containing 0.3 mol/L or more of EDTA.Fe(III) ammonium, 0.3 mol/L or more of a sulfinic acid compound of specified structure and 0.5 mol/L or more of ammonium bromide and a concentrated processing composition for fixative replenishment of 4.0 or more in pH containing 0.7 mol/L of ammonium thiosulfate and 0.Type: GrantFiled: August 15, 2005Date of Patent: April 1, 2008Assignee: Fujifilm CorporationInventor: Kazuaki Yoshida
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Patent number: 7160674Abstract: A bundle for simultaneous refilling of chemicals for processing color photography silver halide materials in an automatic processing apparatus, wherein the bundle comprises at least one bottle with the refilling solution for a color developer and at least two bottles with refilling solutions for a bleach-fixing bath, characterized in that the bottle with the refilling solution for the color developer comprises more than 60 g of color developer substance per 1 L of bottle volume, is distinguished in that the capacity of the bundle is increased.Type: GrantFiled: July 29, 2004Date of Patent: January 9, 2007Assignee: A&O Imagining Solutions GmbHInventor: Ralf Wichmann
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Patent number: 7135275Abstract: A solid bleach-fixing composition for a silver halide color photographic light-sensitive material, comprising at least one specific 5-membered heterocyclic azoliumthiolate compound, particularly, a solid bleach-fixing composition wherein the specific thiolate compound is a diazolium-thiolate compound substituted by a water-soluble group. A method for processing a silver halide color photographic light-sensitive material, comprising using a bleach-fixing solution containing a specific 5-membered heterocyclic azoliumthiolate compound, and regenerating at least 50 mass % of the used bleach-fixing solution as a bleach-fixing processing agent for replenishment; and a method for processing a silver halide color photographic light-sensitive material, comprising regenerating at least 30 mass % of the used processing solution further containing used rinsing solution as a bleach-fixing processing agent for replenishment.Type: GrantFiled: August 18, 2004Date of Patent: November 14, 2006Assignee: Fuji Photo Film Co., Ltd.Inventor: Kazuaki Yoshida
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Patent number: 7108962Abstract: A photographic processing composition, containing at least one compound of formula (I) or (II): A1-X-L-Y-A2??(I) wherein A1 and A2 each are a specific aryl or aromatic heterocyclic group; L is a specific arylene or divalent aromatic heterocyclic group; X and Y each are a specific divalent group; the compound of (I) contains at least two of —SO3M or —CO2M, but not contains —N?N— or —SH; M is a hydrogen, alkali or alkali earth metal, ammonium, or pyridinium; wherein A11 is a specific tri- or tetra-valent aromatic hydrocarbon or aromatic heterocyclic group; A12 is an aryl or aromatic heterocyclic group; X1 is a divalent group; M1 is a hydrogen, alkali or alkali earth metal, ammonium, or pyridinium; the molecule of (II) does not contain —N?N— or —SH; n is 3 or 4; r and s each are 0 to 10, (r+s) is 2 or more.Type: GrantFiled: January 24, 2003Date of Patent: September 19, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Makoto Suzuki, Yasufimi Nakai
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Patent number: 6927019Abstract: A concentrated blix solution composition, which can remarkably reduce the replenishing amount of the blix solution and/or remarkably reduce the blix time, comprises: 1) a concentrated composition part containing a bleaching agent; and 2) a concentrated composition part containing a fixing agent, wherein the part concentrated composition 1) satisfies all the following conditions: (1) pH is from 2.0 to 3.5, (2) a specific gravity is 1.130 or more, (3) the bleaching agent comprises an iron(III) complex salt of an aminopolycarboxylic acid, (4) a concentration of the bleaching agent is from 0.5 to 1.0 mole/L, and (5) a content of an aminopolycarboxylic acid having not been complexed is from 0.1 to 3% by mole based on the bleaching agent, and a processing process using the same.Type: GrantFiled: July 18, 2003Date of Patent: August 9, 2005Assignee: Fuji Photo Film Co., Ltd.Inventor: Kazuaki Yoshida
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Patent number: 6852477Abstract: A composition for photographic bleaching contains a peracid bleaching agent such as a peroxide, persulfate, or periodate, and a cyclicaminomethanediphosphonic acid or a salt thereof as a stabilizing compound. This bleaching composition can also include a fixing agent, and can be used to provide color photographic images in various color photographic materials.Type: GrantFiled: October 22, 2003Date of Patent: February 8, 2005Assignee: Eastman Kodak CompanyInventors: Shirleyanne E. Haye, Janet M. Huston
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Patent number: 6838233Abstract: A method of processing photographic color papers is carried out using a photographic bleach-fixing composition in a bleach-fixing step that is carried out for less than 60 seconds. The bleach-fixing composition comprises certain aliphatic or aromatic sulfur-containing compounds that include a —N?C(SH)— group. The bleach-fixing composition can be prepared from a two-part bleach-fixing kit having two solutions that can be added directly to a processing chamber or premixed to form a replenisher solution.Type: GrantFiled: March 3, 2004Date of Patent: January 4, 2005Assignee: Eastman Kodak CompanyInventors: Paul A. Schwartz, Valerie L. Kuykendall, Eric R. Schmittou, Leif P. Olson, Susan M. Flavin
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Publication number: 20040266139Abstract: A semiconductor device having a semiconductor substrate, at least one of a protruding electrode and wiring formed on one surface of the semiconductor substrate, and a first resin film formed on this surface. The first resin film has elasticity low enough to reduce stress induced by a difference in thermal expansion coefficient between the semiconductor substrate and the first resin film. A second resin film, having higher elasticity or higher strength than the first resin film, may be formed on the other surface of the semiconductor substrate.Type: ApplicationFiled: July 29, 2004Publication date: December 30, 2004Inventor: Kazutaka Shibata
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Publication number: 20040185390Abstract: Stable, single-part photographic bleach-fixing “precursor” compositions comprise one or more iron-ligand complexes, one or more thiosulfates as the sole fixing agents, and optionally, a sulfite preservative. At least 50 mol % of the iron in the composition is in the form of Fe(II). This composition can be used directly in photoprocessing, or used as a regenerator when mixed with bleach-fixing overflow to provide a replenishing solution. Because the Fe(II) compounds are precursor bleaching agents, they must be oxidized to Fe(III) for active bleaching prior to or during the photographic processing operations.Type: ApplicationFiled: January 28, 2004Publication date: September 23, 2004Inventors: Sheridan E. Vincent, Valerie L. Kuykendall, Jean M. Buongiorne
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Publication number: 20040180303Abstract: A method of processing photographic color papers is carried out using a photographic bleach-fixing composition in a bleach-fixing step that is carried out for less than 60 seconds. The bleach-fixing composition comprises certain aliphatic or aromatic sulfur-containing compounds that include a —N═C(SH)— group. The bleach-fixing composition can be prepared from a two-part bleach-fixing kit having two solutions that can be added directly to a processing chamber or premixed to form a replenisher solution.Type: ApplicationFiled: March 3, 2004Publication date: September 16, 2004Inventors: Paul A. Schwartz, Valerie L. Kuykendall, Eric R. Schmittou, Leif P. Olson, Susan M. Flavin
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Publication number: 20040110102Abstract: A concentrated bleach-fixer composition for a silver halide color photographic material is disclosed, comprising an aminopolycarboxylic acid iron complex and a thiosulfate, wherein the bleach-fixer composition further comprises at least one compound selected from a phosphate salt, polyphosphate salt, an imidazole compound and a diaminotriazine compound; and the aminopolycarboxylic acid iron complex having a Fe(II) ratio of not less than 50 mol %.Type: ApplicationFiled: December 1, 2003Publication date: June 10, 2004Applicant: Konica Minolta Holdings, Inc.Inventors: Satoshi Okano, Kouki Kawashima
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Patent number: 6727051Abstract: A photographic bleach-fixing composition has reduced odor and acceptable storage stability. It comprises an iron-ligand complex bleaching agent, thiosulfate fixing agent, sulfite ions, and a phthalic acid or salt thereof. This bleach-fixing composition can be used in various photographic processing protocols to provide color images from color photographic silver halide materials.Type: GrantFiled: March 27, 2003Date of Patent: April 27, 2004Assignee: Eastman Kodak CompanyInventors: Shirleyanne E. Haye, Janet M. Huston, Eric R. Schmittou, Therese M. Feller
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Publication number: 20040058283Abstract: A one-part photographic bleach-fixing concentrate containing an iron(III) complex salt, a thiosulphate and a sulphite, a disulphite or a sulphinic acid, remains stable if a phosphate, polyphosphate or polyphosphonate, or a nitrate or bromide is added thereto.Type: ApplicationFiled: September 23, 2003Publication date: March 25, 2004Inventors: Gustav Tappe, Wolfgang Korner
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Publication number: 20040023167Abstract: A concentrated blix solution composition, which can remarkably reduce the replenishing amount of the blix solution and/or remarkably reduce the blix time, comprises: 1) a concentrated composition part containing a bleaching agent; and 2) a concentrated composition part containing a fixing agent, wherein the part concentrated composition 1) satisfies all the following conditions: (1) pH is from 2.0 to 3.5, (2) a specific gravity is 1.130 or more, (3) the bleaching agent comprises an iron(III) complex salt of an aminopolycarboxylic acid, (4) a concentration of the bleaching agent is from 0.5 to 1.0 mole/L, and (5) a content of an aminopolycarboxylic acid having not been complexed is from 0.1 to 3% by mole based on the bleaching agent, and a processing process using the same.Type: ApplicationFiled: July 18, 2003Publication date: February 5, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventor: Kazuaki Yoshida
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Patent number: 6656669Abstract: A photographic bleach-fixing composition for a color photographic processing system in which bleach-fixing is carried out in a bleach-fixing bath that is replenished with a replenishing solution, wherein the photographic bleach-fixing composition comprises: (a) a Fe(III) complex of a compound represented by Formula (I); , wherein each A1, A2, A3 and A4 represents independently —CH2OH, —PO3M2 or —COOM, in which M represents a hydrogen atom or a monovalent cation; and X represents an alkylene group with 2 to 6 carbon atoms or —(B1O)n—B2—, in which each B1 and B2 represents independently an alkylene group with 1 to 8 carbon atoms, and n represents an integer of 1 to 8, and (b) Fe(III) complex of ethylenediaminetetraacetic acid or Fe(III) complex of diethylenetriaminepentaacetic acid, provided that the mol concentration of (a) and (b) being A and B respectively satisfy the following formula: 0.9<A/B<5.0.Type: GrantFiled: September 5, 2002Date of Patent: December 2, 2003Assignee: Konica CorporationInventor: Kenji Ishida
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Publication number: 20030203324Abstract: A color image forming method is disclosed, comprising exposing a silver halide color photographic material and developing the exposed photographic material at 43 to 180° C. to form a color image, wherein when the photographic material is exposed so that the light-sensitive layer has a transmission density of a minimum density plus 0.1, the light-sensitive layer comprises dye-clouds having an average diameter of 3.0 to 20.0 &mgr;m. There is also disclosed a digital image forming process, wherein image recording information of the photographic material which was formed by use of the color image forming method is converted to digital image information through an image sensor.Type: ApplicationFiled: March 26, 2003Publication date: October 30, 2003Inventors: Noriyuki Kokeguchi, Hiroyuki Hoshino, Hiromoto Ii
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Patent number: 6638697Abstract: A method of processing a silver halide color photographic material comprises the steps of color-developing an image-wise exposed silver halide color photographic material and subjecting the developed material to desilvering in a processing bath having a fixing function and containing a thiosulfate compound and the following compound or analogue thereof in a molar ratio of 1/0.05 to 1/0.30. In this process, the fixing speed is extremely high even when the replenishing rate is low and the processed photosensitive material has an excellent resistance to fading by light.Type: GrantFiled: November 9, 1995Date of Patent: October 28, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Takatoshi Ishikawa, Tetsuro Kojima, Masaru Yoshikawa
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Publication number: 20030198902Abstract: A photographic processing composition, containing at least one compound of formula (I) or (II):Type: ApplicationFiled: January 24, 2003Publication date: October 23, 2003Inventors: Makoto Suzuki, Yasufimi Nakai
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Publication number: 20030190560Abstract: A photographic bleach-fixing composition has reduced odor and acceptable storage stability. It comprises an iron-ligand complex bleaching agent, thiosulfate fixing agent, sulfite ions, and a phthalic acid or salt thereof. This bleach-fixing composition can be used in various photographic processing protocols to provide color images from color photographic silver halide materials.Type: ApplicationFiled: March 27, 2003Publication date: October 9, 2003Inventors: Shirleyanne E. Haye, Janet M. Huston, Eric R. Schmittou, Therese M. Feller
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Publication number: 20030118956Abstract: A photographic bleach-fixing composition for a color photographic processing system in which bleach-fixing is carried out in a bleach-fixing bath that is replenished with a replenishing solution, wherein the photographic bleach-fixing composition comprises:Type: ApplicationFiled: September 5, 2002Publication date: June 26, 2003Applicant: KONICA CORPORATIONInventor: Kenji Ishida
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Patent number: 6582893Abstract: Stable, single-part photographic bleach-fixing “precursor” compositions comprise one or more iron-ligand complexes, one or more thiosulfates as the sole fixing agents, and optionally, a sulfite preservative. At least 50 mol % of the iron in the composition is in the form of Fe(II). This composition can be used directly in photoprocessing, or used as a regenerator when mixed with bleach-fixing overflow to provide a replenishing solution. Because the Fe(II) compounds are precursor bleaching agents, they must be oxidized to Fe(III) for active bleaching prior to or during the photographic processing operations.Type: GrantFiled: April 3, 2002Date of Patent: June 24, 2003Assignee: Eastman Kodak CompanyInventors: Sheridan E. Vincent, Valerie L. Kuykendall, Jean M. Buongiorne
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Publication number: 20030087207Abstract: A method for preparing a kit part of a bleach-fixing solution or a kit of a bleaching solution for use in silver halide color photographic materials is disclosed, comprising (a) adding a [S,S]-alkylenediamine-N,N′-disuccinic acid or its salt into a mixing tank to form a solution, and then, (b) adding thereto at least one iron(III) salt selected from the group consisting of iron(III) nitrate, iron(III) chloride, iron(III) bromide, (M1)3Fe(III) (SO4)3 and M1Fe(III) (SO4)2.Type: ApplicationFiled: April 3, 2002Publication date: May 8, 2003Applicant: KONICA CORPORATIONInventor: Satoru Kuse
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Publication number: 20030054298Abstract: A photographic processing composition for silver halide color photographic lightsensitive material, comprising at least one compound represented by the formula (I):Type: ApplicationFiled: March 29, 2002Publication date: March 20, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Makoto Suzuki, Yasufumi Nakai, Yoshiharu Yabuki
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Publication number: 20020192604Abstract: A method of processing a silver halide color photographic material comprises the steps of color-developing an image-wise exposed silver halide color photographic material and subjecting the developed material to desilvering in a processing bath having a fixing function and containing a thiosulfate compound and the following compound or analogue thereof in a molar ratio of 1/0.05 to 1/0.30. In this process, the fixing speed is extremely high even when the replenishing rate is low and the processed photosensitive material has an excellent resistance to fading by light.Type: ApplicationFiled: November 9, 1995Publication date: December 19, 2002Inventors: TAKATOSHI ISHIKAWA, TETSURO KOJIMA, MASARU YOSHIKAWA
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Publication number: 20020187441Abstract: Concentrated aqueous photographic fixing compositions include a photographic fixing agent and a compound represented by Structure I 1Type: ApplicationFiled: June 5, 2002Publication date: December 12, 2002Inventors: Jean M. Buongiorne, Mary E. Craver, Ramanuj Goswami
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Publication number: 20020182548Abstract: A photographic prebleaching or conditioning composition is useful for providing color positive images in color reversal photographic materials. This composition includes at least 0.0001 mol/l of a cyclic mercapto bleach accelerating agent and at least 0.0001 mol/l of a water-soluble or water-dispersible 2,6-diarylaminotriazine or diaminostilbene dye stain reducing agent.Type: ApplicationFiled: February 13, 2001Publication date: December 5, 2002Applicant: Eastman Kodak CompanyInventors: Harry J. Price, Michael P. Youngblood, Ramanuj Goswami
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Publication number: 20020164551Abstract: Stable, single-part photographic bleach-fixing “precursor” compositions comprise one or more iron-ligand complexes, one or more thiosulfates as the sole fixing agents, and optionally, a sulfite preservative. At least 50 mol % of the iron in the composition is in the form of Fe(II). This composition can be used directly in photoprocessing, or used as a regenerator when mixed with bleach-fixing overflow to provide a replenishing solution. Because the Fe(II) compounds are precursor bleaching agents, they must be oxidized to Fe(III) for active bleaching prior to or during the photographic processing operations.Type: ApplicationFiled: April 3, 2002Publication date: November 7, 2002Inventors: Sheridan E. Vincent, Valerie L. Kuykendall, Jean M. Buongiorne
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Patent number: 6406838Abstract: The present invention provides an overcoat for a photographic element that allows for appropriate diffusion of photographic processing solutions. The overcoat comprises 10 to 50% by weight of a enzyme-degradable biopolymer and 50 to 90% by weight of hydrophobic particles (by weight of dry laydown of the entire overcoat). An enzyme is applied to the element before, during, or after conventional photoprocessing. According to one embodiment of the invention, the photographic element can be exposed and processed using normal photofinishing equipment, with no modifications, to provide an imaged element together with a protective, water-resistant layer.Type: GrantFiled: July 3, 2001Date of Patent: June 18, 2002Assignee: Eastman Kodak CompanyInventors: Thomas H. Whitesides, Amy Jasek, Hwei-Ling Yau, Jill E. Fornalik
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Patent number: 6395461Abstract: Specific aromatic compounds having an extended planar &pgr; system are useful as spectral sensitizing dye stain reducing agents in photographic processing compositions and methods for providing color or black-and-white images in various photographic silver halide materials. These compounds are devoid of diaminostilbene fragments or fused triazole nuclei. They are particularly useful in fixing and bleaching compositions in the processing of color photographic silver halide materials, but can also be used in various other processing compositions.Type: GrantFiled: February 1, 2001Date of Patent: May 28, 2002Assignee: Eastman Kodak CompanyInventors: Ramanuj Goswami, Mary E. Craver, Harry J. Price
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Publication number: 20020037482Abstract: A bleach or bleach/fixing solution for processing photographic silver halide materials which, relative to the silver halide content of the unprocessed material, exhibit prior to the bleaching step a content of silver arising from development of at least 65 mol %, in particular for processing color reversal materials, characterized in that the solution contains at least one iron complex of propylenediaminetetraacetic acid or of &bgr;-alaninediacetic acid or a mixture of these complexes and the total concentration of the stated iron complexes in the solution is at least 0.045 and at most 0.25 mol/l and a process for processing, in which such a solution is used, is characterized by a small introduced quantity of iron complexes, a low residual silver content, a low bleaching fog value, elevated resistance to precipitation and in that the bleach solution may be rejuvenated.Type: ApplicationFiled: August 1, 2001Publication date: March 28, 2002Inventors: Ralf Wichmann, Thomas Hubsch, Thomas Stetzer
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Publication number: 20010004514Abstract: Specific aromatic compounds having an extended planar &pgr; system are useful as spectral sensitizing dye stain reducing agents in photographic processing compositions and methods for providing color or black-and-white images in various photographic silver halide materials. These compounds are devoid of diaminostilbene fragments or fused triazole nuclei. They are particularly useful in fixing and bleaching compositions in the processing of color photographic silver halide materials, but can also be used in various other processing compositions.Type: ApplicationFiled: February 1, 2001Publication date: June 21, 2001Inventors: Ramanuj Goswami, Mary E. Craver, Harry J. Price
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Patent number: 6221570Abstract: The present invention provides compositions and methods of making one-part bleach-fix liquid concentrates, packaged in a single unit, wherein the bleaching agent is a polyvalent metal oxidizing agent that is protected from reduction for an extended period of time by incorporating a thiocyanate salt as at least one fixing agent. The thiocyanate salt in added in an amount sufficient to provide one-part bleach-fix liquid concentrates that are homogeneous, essentially free of crystallized components and which retain effective oxidizing potential during extended storage.Type: GrantFiled: January 6, 2000Date of Patent: April 24, 2001Assignee: Trebla Chemical CompanyInventor: Laszlo Papai
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Patent number: 6174653Abstract: A method of forming a color photographic image comprises: contacting an imagewise exposed color photographic material with a color developing composition to provide a developed material, and contacting the developed material with a bleach-fix composition. This composition is a bleaching agent comprising of a complex of ferric ion and an aminopolycarboxylic acid, a fixing agent; and sulphite ion in an amount up to 0.1 mol/l; said bleach-fix composition having a pH from about 4 to about 8 and said contacting being for a period from about 5 to about 20 seconds.Type: GrantFiled: October 12, 1999Date of Patent: January 16, 2001Assignee: Eastman Kodak CompanyInventor: Nigel R. Wildman
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Patent number: 6153364Abstract: Specific aromatic compounds having an extended planar .pi. system are useful as spectral sensitizing dye stain reducing agents in photographic processing compositions and methods for providing color or black-and-white images in various photographic silver halide materials. These compounds are devoid of diaminostilbene fragments or fused triazole nuclei. They are particularly useful in fixing and bleaching compositions in the processing of color photographic silver halide materials, but can be used in various other processing compositions.Type: GrantFiled: December 16, 1999Date of Patent: November 28, 2000Assignee: Eastman Kodak CompanyInventors: Ramanuj Goswami, Harry J. Price, Mary E. Craver
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Patent number: 6103458Abstract: There is disclosed a method for processing a silver halide color photographic light-sensitive material, which comprises processing a silver halide color photographic light-sensitive material that contains a color-forming reducing agent, with an alkaline solution that is substantially free from any color-developing agent, and then processing the light-sensitive material with a bleach-fix solution that contains a ferric complex salt of a compound represented by formula (I) or (II): ##STR1## wherein, in formula (I), R.sub.1 represents a hydrogen atom, or an aliphatic hydrocarbon, aryl, or heterocyclic group; L.sub.1 and L.sub.2 each represent an alkylene group; and M.sub.1 and M.sub.2 each represent a hydrogen atom or a cation; and wherein, in formula (II), R.sub.21, R.sub.22, R.sub.23, and R.sub.24 each represent a hydrogen atom, or an aliphatic hydrocarbon, aryl, heterocyclic, hydroxyl, or carboxyl group; t and u are each 0 or 1; W represents a divalent carbon-containing linking group; and M.sub.21, M.sub.Type: GrantFiled: July 31, 1997Date of Patent: August 15, 2000Assignee: Fuji Photo Film Co., Ltd.Inventor: Hiroyuki Seki
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Patent number: 5976772Abstract: A bleach/fixing bath, characterized in that it contains, apart from the active and auxiliary substances necessary for bleach/fixing, a phosphonocarboxylic acid having at least two carboxylic acid groups per molecule, is lower in odor and more stable than conventional bleaching baths.Type: GrantFiled: September 30, 1997Date of Patent: November 2, 1999Assignee: Agfa Gevaert AGInventors: Thomas Hubsch, Ralf Weimann, Angelika Scholkmann, Erika Spriewald
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Patent number: 5972583Abstract: Color photographic elements can be processed with an acidic periodate bleaching composition that also includes chloride ions as a rehalogenating agent.Type: GrantFiled: December 7, 1998Date of Patent: October 26, 1999Assignee: Eastman Kodak CompanyInventors: Sidney J. Bertucci, Eric R. Schmittou
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Patent number: 5945262Abstract: The present invention provides a correcting liquid for silver imaged lithographic printing plates being an aqueous solution having a pH in the range between 5.5 and 8.5 and comprising a iron (III) complex salt of an organic acid, a sulphite or a metabisulphite, a silver halide solvent and an accelerator, said accelerator being an organic heterocyclic compound having a mercapto- or thione group and not having a hydrophilic substituent besides the said mercapto or thione group characterized in that said accelerator is present in an amount ranging from 0.04 to 0.4 mole per liter of correcting liquid.Type: GrantFiled: December 4, 1996Date of Patent: August 31, 1999Assignee: Agfa-Gevaert, N.B.Inventor: Lode Deprez
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Patent number: 5922519Abstract: A method for processing a silver halide color photographic photosensitive material comprises the steps of desilverizing a photosensitive silver halide material having at least one red-sensitive layer, green-sensitive layer and blue-sensitive layer respectively on one side of a transparent support and a magnetic recording layer containing magnetic grains on the other side after the color development and then washing it with water and/or stabilizing it, wherein a bath having fixing function used in the desilverization step contains the following compound or analogue thereof. ##STR1## This method does not impair the S/N ratio of the magnetically recorded information and excellent desilverization effect can be obtained.Type: GrantFiled: May 24, 1996Date of Patent: July 13, 1999Assignee: Fuji Photo Film Co., Ltd.Inventors: Takatoshi Ishikawa, Masaru Yoshikawa, Tetsuro Kojima
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Patent number: 5856074Abstract: This invention relates to a fixing bath containing a biologically degradable complexing agent of formula I ##STR1## wherein R.sup.1-4 represents hydrogen, C.sub.1 -C.sub.10 -alkyl, hydroxy-C.sub.1 -C.sub.10 -alkyl, C.sub.1 -C.sub.10 -alkoxy-C.sub.1 -C.sub.10 -alkyl, carboxy-C.sub.2 -C.sub.10 -alkyl, dicarboxy-C.sub.1 -C.sub.10 -alkyl, carboxy-hydroxy-C.sub.1 -C.sub.10 -alkyl, hydroxy-C.sub.1 -C.sub.5 -alkyl-(oxy-C.sub.1 -C.sub.5 -alkyl).sub.n, or C.sub.1 -C.sub.5 -alkoxy-C.sub.1 -C.sub.5 -alkyl-(oxy-C.sub.1 -C.sub.5 -alkyl).sub.n,M represents hydrogen, lithium, sodium, potassium or ammonium, andn represents 1, 2, 3 or 4,the iron(III) complex salt of which does not impede electrolytic desilverisation during the regeneration of spent fixing bath.Type: GrantFiled: October 17, 1997Date of Patent: January 5, 1999Assignee: Agfa-Gevaert AGInventors: Gustav Tappe, Norman Klaunzer
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Patent number: 5814435Abstract: There is disclosed a photographic composition having fixing capacity and a method for processing a silver halide photographic material using the same. The photographic composition having fixing capacity comprises at least one compound represented by the following formula (I):RSO.sub.2 M formula (I)wherein R represents a lower alkyl group having 1 to 3 carbon atoms, and M represents a hydrogen atom or a cationic group.Type: GrantFiled: August 5, 1996Date of Patent: September 29, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Tetsuro Kojima, Masaru Yoshikawa, Yoshihiro Fujita
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Patent number: 5814437Abstract: A method for processing a silver halide photographic light-sensitive material is by an automatic processor having a processing chamber with a small volume.Type: GrantFiled: October 27, 1997Date of Patent: September 29, 1998Assignee: Konica CorporationInventors: Manabu Nakahanada, Yutaka Ueda
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Patent number: 5795703Abstract: A method for processing silver halide photosensitive photographic material comprises the steps of developing an image-exposed silver halide photosensitive material and desilvering it with a processing solution having fixing function which contains a thiosulfate radical and a specified meso-ionic compound or a specified thiourea, an amount of ammonium ion in the solution being 0 to 50% based on the total counter cations in the solution. This method can provide processed silver halide photosensitive photographic material having excellent photographic properties while keeping a low stain concentration with even a small amount of a replenisher.Type: GrantFiled: December 10, 1996Date of Patent: August 18, 1998Assignee: Fuji Photo Film Co., Ltd.Inventor: Takatoshi Ishikawa
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Patent number: 5783376Abstract: A composition for bleaching or bleach-fixing a silver halide photographic material has a pH of from 2 to 9. The composition comprises a bleaching agent which is either a persulfate or polyvalent metal complex of an aminopolycarboxylic acid, and from 0.01 to 2M of a sulfo-substituted carboxylate represented by Formula I(MO.sub.3 S).sub.n --R--(COOM).sub.m (I)wherein R is a benzene ring or a straight, branched or cyclic saturated aliphatic group having 2 to 8 carbon atoms;M is hydrogen or an organic or inorganic cation; andn is 1 to 7;with the proviso that if R is an aliphatic group, m is 2 to 4 and m and n combined cannot equal more than the number of carbon atoms in R plus two, and if R is a benzene ring, m is 2 to 5 and m and n combined cannot equal more than six.Type: GrantFiled: May 14, 1997Date of Patent: July 21, 1998Assignee: Eastman Kodak CompanyInventors: Stuart Terrance Gordon, John Michael Buchanan, Sidney Joseph Bertucci
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Patent number: 5783375Abstract: A redox amplification process with minimal steps includes processing a silver halide with an amplifier/bleach/fix solution that includes a redox oxidant capable of bleaching a silver image and a fixing agent that does not react with the redox oxidant.Type: GrantFiled: August 29, 1996Date of Patent: July 21, 1998Assignee: Eastman Kodak CompanyInventor: Peter Jeffery Twist
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Patent number: 5776666Abstract: A method of accelerating black and white development comprising contacting a negative-type silver halide photographic element during processing with a developer prebath or a developer bath comprising an accelerator compound of the formula: ##STR1## is disclosed, wherein R.sub.1, R.sub.2, and R.sub.3 are substituents; said R.sub.1, R.sub.2, and R.sub.3 may further combine with each other to form a 5-, 6-, or 7-membered ring; and wherein said developer prebath and developer bath do not contain any iron(III) ion complex salt having bleaching activity.A bath selected from the group consisting of developer prebaths and developer baths for black and white development of a negative-type silver halide photographic element comprising an aqueous solution of accelerator compound of the formula: ##STR2## is also disclosed, wherein R.sub.1, R.sub.2, and R.sub.3 are substituents; said R.sub.1, R.sub.2, and R.sub.Type: GrantFiled: March 3, 1993Date of Patent: July 7, 1998Assignee: Eastman Kodak CompanyInventors: John Texter, Arthur Herman Herz, Henry Wolf Altland
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Patent number: 5753423Abstract: A ready-to-use bleaching or bleach-fixing solution can be prepared by mixing an aqueous solution of succinic acid, maleic acid or malic acid, and an aminopolycarboxylic acid ligand, adding a ferric salt to form a ferric ligand chelate, and adding a chemical base, such as ammonia, to provide a final pH of from 2.5 to 5.5. optionally, a portion of the chemical base can be added before the addition of the ferric salt.Type: GrantFiled: April 29, 1996Date of Patent: May 19, 1998Assignee: Eastman Kodak CompanyInventors: Jean Marie Buongiorne, Stephen Joseph Waffle, Richard Thomas Clark
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Patent number: 5707787Abstract: A processing solution for processing an exposed silver halide photographic light-sensitive material comprises a compound represented by the following formula (A): ##STR1## wherein A.sub.1, A.sub.2, A.sub.3 and A.sub.4 each represent --COOM.sub.1, --OH, --PO.sub.3 M.sub.1 M.sub.2 or --CONH.sub.2 in which M.sub.1 and M.sub.2 each represent a hydrogen ion, an alkali metal ion or another cation; R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represent a hydrogen atom, a lower alkyl group or a hydroxyl group; n.sub.1, n.sub.2, n.sub.3 and n.sub.4 each represent an integer of 0, 1 or 2, provided that none of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are hydrogen atoms when n.sub.1 +n.sub.2 =1 and n.sub.3 +n.sub.4 =1; and X represents a substituted or unsubstituted alkylene group having 2 to 6 carbon atoms or --(B.sub.1 O)m-B.sub.2 -- in which B.sub.1 and B.sub.2 each represent a substituted or unsubstituted alkylene group having 1 to 5 carbon atoms, and m is an integer of from 1 to 4.Type: GrantFiled: August 11, 1993Date of Patent: January 13, 1998Assignee: Konica CorporationInventors: Kenji Kuwae, Yutaka Ueda
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Patent number: 5695915Abstract: A method used for processing a silver halide photographic light sensitive material including steps of developing and treating with a solution having bleaching capability. The solution having bleaching capability comprises a ferric complex salt of a compound represented by the following formula A: ##STR1## wherein A.sub.1, A.sub.2, A.sub.3 and A.sub.4 are independently a --CH.sub.2 OH group, a --PO.sub.3 M.sub.2 group or a --COOM group, which may be the same or different; M is a cation: and X is an alkylene group having 2 to 6 carbon atoms or a --(B.sub.1 O).sub.n --B.sub.2 -- group, in which is an integer of 1 to 8, B.sub.1 and B.sub.2 are independently an alkylene group having 1 to 5 carbon atoms, which may be the same or different. The solution can be used as a bleaching solution or bleach-fixing solution for color photographic material. The solution may further be used as a reducing solution for reducing an image formed on a photographic light-sensitive material.Type: GrantFiled: December 17, 1993Date of Patent: December 9, 1997Assignee: Konica CorporationInventors: Yutaka Ueda, Kenji Kuwae