And Bleach Patents (Class 430/460)
  • Patent number: 7351522
    Abstract: An object of the present invention is to provide a method of processing silver halide color paper that ensures (a) promptness such that finished prints can be handed at shop to customers, (b) small installation area for mini-labs, (c) processing solution stability capable of withstanding slack seasons, (d) normal image quality, (e) small replenishment solution amount and (f) inhibition of tar generation and sulfuration phenomenon occurrence. This object can be attained by a concentrated processing composition for color paper which has a concentrated processing composition for bleach replenishment of 3.0 or less in pH containing 0.3 mol/L or more of EDTA.Fe(III) ammonium, 0.3 mol/L or more of a sulfinic acid compound of specified structure and 0.5 mol/L or more of ammonium bromide and a concentrated processing composition for fixative replenishment of 4.0 or more in pH containing 0.7 mol/L of ammonium thiosulfate and 0.
    Type: Grant
    Filed: August 15, 2005
    Date of Patent: April 1, 2008
    Assignee: Fujifilm Corporation
    Inventor: Kazuaki Yoshida
  • Patent number: 7160674
    Abstract: A bundle for simultaneous refilling of chemicals for processing color photography silver halide materials in an automatic processing apparatus, wherein the bundle comprises at least one bottle with the refilling solution for a color developer and at least two bottles with refilling solutions for a bleach-fixing bath, characterized in that the bottle with the refilling solution for the color developer comprises more than 60 g of color developer substance per 1 L of bottle volume, is distinguished in that the capacity of the bundle is increased.
    Type: Grant
    Filed: July 29, 2004
    Date of Patent: January 9, 2007
    Assignee: A&O Imagining Solutions GmbH
    Inventor: Ralf Wichmann
  • Patent number: 7135275
    Abstract: A solid bleach-fixing composition for a silver halide color photographic light-sensitive material, comprising at least one specific 5-membered heterocyclic azoliumthiolate compound, particularly, a solid bleach-fixing composition wherein the specific thiolate compound is a diazolium-thiolate compound substituted by a water-soluble group. A method for processing a silver halide color photographic light-sensitive material, comprising using a bleach-fixing solution containing a specific 5-membered heterocyclic azoliumthiolate compound, and regenerating at least 50 mass % of the used bleach-fixing solution as a bleach-fixing processing agent for replenishment; and a method for processing a silver halide color photographic light-sensitive material, comprising regenerating at least 30 mass % of the used processing solution further containing used rinsing solution as a bleach-fixing processing agent for replenishment.
    Type: Grant
    Filed: August 18, 2004
    Date of Patent: November 14, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kazuaki Yoshida
  • Patent number: 7108962
    Abstract: A photographic processing composition, containing at least one compound of formula (I) or (II): A1-X-L-Y-A2??(I) wherein A1 and A2 each are a specific aryl or aromatic heterocyclic group; L is a specific arylene or divalent aromatic heterocyclic group; X and Y each are a specific divalent group; the compound of (I) contains at least two of —SO3M or —CO2M, but not contains —N?N— or —SH; M is a hydrogen, alkali or alkali earth metal, ammonium, or pyridinium; wherein A11 is a specific tri- or tetra-valent aromatic hydrocarbon or aromatic heterocyclic group; A12 is an aryl or aromatic heterocyclic group; X1 is a divalent group; M1 is a hydrogen, alkali or alkali earth metal, ammonium, or pyridinium; the molecule of (II) does not contain —N?N— or —SH; n is 3 or 4; r and s each are 0 to 10, (r+s) is 2 or more.
    Type: Grant
    Filed: January 24, 2003
    Date of Patent: September 19, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Makoto Suzuki, Yasufimi Nakai
  • Patent number: 6927019
    Abstract: A concentrated blix solution composition, which can remarkably reduce the replenishing amount of the blix solution and/or remarkably reduce the blix time, comprises: 1) a concentrated composition part containing a bleaching agent; and 2) a concentrated composition part containing a fixing agent, wherein the part concentrated composition 1) satisfies all the following conditions: (1) pH is from 2.0 to 3.5, (2) a specific gravity is 1.130 or more, (3) the bleaching agent comprises an iron(III) complex salt of an aminopolycarboxylic acid, (4) a concentration of the bleaching agent is from 0.5 to 1.0 mole/L, and (5) a content of an aminopolycarboxylic acid having not been complexed is from 0.1 to 3% by mole based on the bleaching agent, and a processing process using the same.
    Type: Grant
    Filed: July 18, 2003
    Date of Patent: August 9, 2005
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kazuaki Yoshida
  • Patent number: 6852477
    Abstract: A composition for photographic bleaching contains a peracid bleaching agent such as a peroxide, persulfate, or periodate, and a cyclicaminomethanediphosphonic acid or a salt thereof as a stabilizing compound. This bleaching composition can also include a fixing agent, and can be used to provide color photographic images in various color photographic materials.
    Type: Grant
    Filed: October 22, 2003
    Date of Patent: February 8, 2005
    Assignee: Eastman Kodak Company
    Inventors: Shirleyanne E. Haye, Janet M. Huston
  • Patent number: 6838233
    Abstract: A method of processing photographic color papers is carried out using a photographic bleach-fixing composition in a bleach-fixing step that is carried out for less than 60 seconds. The bleach-fixing composition comprises certain aliphatic or aromatic sulfur-containing compounds that include a —N?C(SH)— group. The bleach-fixing composition can be prepared from a two-part bleach-fixing kit having two solutions that can be added directly to a processing chamber or premixed to form a replenisher solution.
    Type: Grant
    Filed: March 3, 2004
    Date of Patent: January 4, 2005
    Assignee: Eastman Kodak Company
    Inventors: Paul A. Schwartz, Valerie L. Kuykendall, Eric R. Schmittou, Leif P. Olson, Susan M. Flavin
  • Publication number: 20040266139
    Abstract: A semiconductor device having a semiconductor substrate, at least one of a protruding electrode and wiring formed on one surface of the semiconductor substrate, and a first resin film formed on this surface. The first resin film has elasticity low enough to reduce stress induced by a difference in thermal expansion coefficient between the semiconductor substrate and the first resin film. A second resin film, having higher elasticity or higher strength than the first resin film, may be formed on the other surface of the semiconductor substrate.
    Type: Application
    Filed: July 29, 2004
    Publication date: December 30, 2004
    Inventor: Kazutaka Shibata
  • Publication number: 20040185390
    Abstract: Stable, single-part photographic bleach-fixing “precursor” compositions comprise one or more iron-ligand complexes, one or more thiosulfates as the sole fixing agents, and optionally, a sulfite preservative. At least 50 mol % of the iron in the composition is in the form of Fe(II). This composition can be used directly in photoprocessing, or used as a regenerator when mixed with bleach-fixing overflow to provide a replenishing solution. Because the Fe(II) compounds are precursor bleaching agents, they must be oxidized to Fe(III) for active bleaching prior to or during the photographic processing operations.
    Type: Application
    Filed: January 28, 2004
    Publication date: September 23, 2004
    Inventors: Sheridan E. Vincent, Valerie L. Kuykendall, Jean M. Buongiorne
  • Publication number: 20040180303
    Abstract: A method of processing photographic color papers is carried out using a photographic bleach-fixing composition in a bleach-fixing step that is carried out for less than 60 seconds. The bleach-fixing composition comprises certain aliphatic or aromatic sulfur-containing compounds that include a —N═C(SH)— group. The bleach-fixing composition can be prepared from a two-part bleach-fixing kit having two solutions that can be added directly to a processing chamber or premixed to form a replenisher solution.
    Type: Application
    Filed: March 3, 2004
    Publication date: September 16, 2004
    Inventors: Paul A. Schwartz, Valerie L. Kuykendall, Eric R. Schmittou, Leif P. Olson, Susan M. Flavin
  • Publication number: 20040110102
    Abstract: A concentrated bleach-fixer composition for a silver halide color photographic material is disclosed, comprising an aminopolycarboxylic acid iron complex and a thiosulfate, wherein the bleach-fixer composition further comprises at least one compound selected from a phosphate salt, polyphosphate salt, an imidazole compound and a diaminotriazine compound; and the aminopolycarboxylic acid iron complex having a Fe(II) ratio of not less than 50 mol %.
    Type: Application
    Filed: December 1, 2003
    Publication date: June 10, 2004
    Applicant: Konica Minolta Holdings, Inc.
    Inventors: Satoshi Okano, Kouki Kawashima
  • Patent number: 6727051
    Abstract: A photographic bleach-fixing composition has reduced odor and acceptable storage stability. It comprises an iron-ligand complex bleaching agent, thiosulfate fixing agent, sulfite ions, and a phthalic acid or salt thereof. This bleach-fixing composition can be used in various photographic processing protocols to provide color images from color photographic silver halide materials.
    Type: Grant
    Filed: March 27, 2003
    Date of Patent: April 27, 2004
    Assignee: Eastman Kodak Company
    Inventors: Shirleyanne E. Haye, Janet M. Huston, Eric R. Schmittou, Therese M. Feller
  • Publication number: 20040058283
    Abstract: A one-part photographic bleach-fixing concentrate containing an iron(III) complex salt, a thiosulphate and a sulphite, a disulphite or a sulphinic acid, remains stable if a phosphate, polyphosphate or polyphosphonate, or a nitrate or bromide is added thereto.
    Type: Application
    Filed: September 23, 2003
    Publication date: March 25, 2004
    Inventors: Gustav Tappe, Wolfgang Korner
  • Publication number: 20040023167
    Abstract: A concentrated blix solution composition, which can remarkably reduce the replenishing amount of the blix solution and/or remarkably reduce the blix time, comprises: 1) a concentrated composition part containing a bleaching agent; and 2) a concentrated composition part containing a fixing agent, wherein the part concentrated composition 1) satisfies all the following conditions: (1) pH is from 2.0 to 3.5, (2) a specific gravity is 1.130 or more, (3) the bleaching agent comprises an iron(III) complex salt of an aminopolycarboxylic acid, (4) a concentration of the bleaching agent is from 0.5 to 1.0 mole/L, and (5) a content of an aminopolycarboxylic acid having not been complexed is from 0.1 to 3% by mole based on the bleaching agent, and a processing process using the same.
    Type: Application
    Filed: July 18, 2003
    Publication date: February 5, 2004
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventor: Kazuaki Yoshida
  • Patent number: 6656669
    Abstract: A photographic bleach-fixing composition for a color photographic processing system in which bleach-fixing is carried out in a bleach-fixing bath that is replenished with a replenishing solution, wherein the photographic bleach-fixing composition comprises: (a) a Fe(III) complex of a compound represented by Formula (I);  , wherein each A1, A2, A3 and A4 represents independently —CH2OH, —PO3M2 or —COOM, in which M represents a hydrogen atom or a monovalent cation; and X represents an alkylene group with 2 to 6 carbon atoms or —(B1O)n—B2—, in which each B1 and B2 represents independently an alkylene group with 1 to 8 carbon atoms, and n represents an integer of 1 to 8, and (b) Fe(III) complex of ethylenediaminetetraacetic acid or Fe(III) complex of diethylenetriaminepentaacetic acid, provided that the mol concentration of (a) and (b) being A and B respectively satisfy the following formula: 0.9<A/B<5.0.
    Type: Grant
    Filed: September 5, 2002
    Date of Patent: December 2, 2003
    Assignee: Konica Corporation
    Inventor: Kenji Ishida
  • Publication number: 20030203324
    Abstract: A color image forming method is disclosed, comprising exposing a silver halide color photographic material and developing the exposed photographic material at 43 to 180° C. to form a color image, wherein when the photographic material is exposed so that the light-sensitive layer has a transmission density of a minimum density plus 0.1, the light-sensitive layer comprises dye-clouds having an average diameter of 3.0 to 20.0 &mgr;m. There is also disclosed a digital image forming process, wherein image recording information of the photographic material which was formed by use of the color image forming method is converted to digital image information through an image sensor.
    Type: Application
    Filed: March 26, 2003
    Publication date: October 30, 2003
    Inventors: Noriyuki Kokeguchi, Hiroyuki Hoshino, Hiromoto Ii
  • Patent number: 6638697
    Abstract: A method of processing a silver halide color photographic material comprises the steps of color-developing an image-wise exposed silver halide color photographic material and subjecting the developed material to desilvering in a processing bath having a fixing function and containing a thiosulfate compound and the following compound or analogue thereof in a molar ratio of 1/0.05 to 1/0.30. In this process, the fixing speed is extremely high even when the replenishing rate is low and the processed photosensitive material has an excellent resistance to fading by light.
    Type: Grant
    Filed: November 9, 1995
    Date of Patent: October 28, 2003
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takatoshi Ishikawa, Tetsuro Kojima, Masaru Yoshikawa
  • Publication number: 20030198902
    Abstract: A photographic processing composition, containing at least one compound of formula (I) or (II):
    Type: Application
    Filed: January 24, 2003
    Publication date: October 23, 2003
    Inventors: Makoto Suzuki, Yasufimi Nakai
  • Publication number: 20030190560
    Abstract: A photographic bleach-fixing composition has reduced odor and acceptable storage stability. It comprises an iron-ligand complex bleaching agent, thiosulfate fixing agent, sulfite ions, and a phthalic acid or salt thereof. This bleach-fixing composition can be used in various photographic processing protocols to provide color images from color photographic silver halide materials.
    Type: Application
    Filed: March 27, 2003
    Publication date: October 9, 2003
    Inventors: Shirleyanne E. Haye, Janet M. Huston, Eric R. Schmittou, Therese M. Feller
  • Publication number: 20030118956
    Abstract: A photographic bleach-fixing composition for a color photographic processing system in which bleach-fixing is carried out in a bleach-fixing bath that is replenished with a replenishing solution, wherein the photographic bleach-fixing composition comprises:
    Type: Application
    Filed: September 5, 2002
    Publication date: June 26, 2003
    Applicant: KONICA CORPORATION
    Inventor: Kenji Ishida
  • Patent number: 6582893
    Abstract: Stable, single-part photographic bleach-fixing “precursor” compositions comprise one or more iron-ligand complexes, one or more thiosulfates as the sole fixing agents, and optionally, a sulfite preservative. At least 50 mol % of the iron in the composition is in the form of Fe(II). This composition can be used directly in photoprocessing, or used as a regenerator when mixed with bleach-fixing overflow to provide a replenishing solution. Because the Fe(II) compounds are precursor bleaching agents, they must be oxidized to Fe(III) for active bleaching prior to or during the photographic processing operations.
    Type: Grant
    Filed: April 3, 2002
    Date of Patent: June 24, 2003
    Assignee: Eastman Kodak Company
    Inventors: Sheridan E. Vincent, Valerie L. Kuykendall, Jean M. Buongiorne
  • Publication number: 20030087207
    Abstract: A method for preparing a kit part of a bleach-fixing solution or a kit of a bleaching solution for use in silver halide color photographic materials is disclosed, comprising (a) adding a [S,S]-alkylenediamine-N,N′-disuccinic acid or its salt into a mixing tank to form a solution, and then, (b) adding thereto at least one iron(III) salt selected from the group consisting of iron(III) nitrate, iron(III) chloride, iron(III) bromide, (M1)3Fe(III) (SO4)3 and M1Fe(III) (SO4)2.
    Type: Application
    Filed: April 3, 2002
    Publication date: May 8, 2003
    Applicant: KONICA CORPORATION
    Inventor: Satoru Kuse
  • Publication number: 20030054298
    Abstract: A photographic processing composition for silver halide color photographic lightsensitive material, comprising at least one compound represented by the formula (I):
    Type: Application
    Filed: March 29, 2002
    Publication date: March 20, 2003
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Makoto Suzuki, Yasufumi Nakai, Yoshiharu Yabuki
  • Publication number: 20020192604
    Abstract: A method of processing a silver halide color photographic material comprises the steps of color-developing an image-wise exposed silver halide color photographic material and subjecting the developed material to desilvering in a processing bath having a fixing function and containing a thiosulfate compound and the following compound or analogue thereof in a molar ratio of 1/0.05 to 1/0.30. In this process, the fixing speed is extremely high even when the replenishing rate is low and the processed photosensitive material has an excellent resistance to fading by light.
    Type: Application
    Filed: November 9, 1995
    Publication date: December 19, 2002
    Inventors: TAKATOSHI ISHIKAWA, TETSURO KOJIMA, MASARU YOSHIKAWA
  • Publication number: 20020187441
    Abstract: Concentrated aqueous photographic fixing compositions include a photographic fixing agent and a compound represented by Structure I 1
    Type: Application
    Filed: June 5, 2002
    Publication date: December 12, 2002
    Inventors: Jean M. Buongiorne, Mary E. Craver, Ramanuj Goswami
  • Publication number: 20020182548
    Abstract: A photographic prebleaching or conditioning composition is useful for providing color positive images in color reversal photographic materials. This composition includes at least 0.0001 mol/l of a cyclic mercapto bleach accelerating agent and at least 0.0001 mol/l of a water-soluble or water-dispersible 2,6-diarylaminotriazine or diaminostilbene dye stain reducing agent.
    Type: Application
    Filed: February 13, 2001
    Publication date: December 5, 2002
    Applicant: Eastman Kodak Company
    Inventors: Harry J. Price, Michael P. Youngblood, Ramanuj Goswami
  • Publication number: 20020164551
    Abstract: Stable, single-part photographic bleach-fixing “precursor” compositions comprise one or more iron-ligand complexes, one or more thiosulfates as the sole fixing agents, and optionally, a sulfite preservative. At least 50 mol % of the iron in the composition is in the form of Fe(II). This composition can be used directly in photoprocessing, or used as a regenerator when mixed with bleach-fixing overflow to provide a replenishing solution. Because the Fe(II) compounds are precursor bleaching agents, they must be oxidized to Fe(III) for active bleaching prior to or during the photographic processing operations.
    Type: Application
    Filed: April 3, 2002
    Publication date: November 7, 2002
    Inventors: Sheridan E. Vincent, Valerie L. Kuykendall, Jean M. Buongiorne
  • Patent number: 6406838
    Abstract: The present invention provides an overcoat for a photographic element that allows for appropriate diffusion of photographic processing solutions. The overcoat comprises 10 to 50% by weight of a enzyme-degradable biopolymer and 50 to 90% by weight of hydrophobic particles (by weight of dry laydown of the entire overcoat). An enzyme is applied to the element before, during, or after conventional photoprocessing. According to one embodiment of the invention, the photographic element can be exposed and processed using normal photofinishing equipment, with no modifications, to provide an imaged element together with a protective, water-resistant layer.
    Type: Grant
    Filed: July 3, 2001
    Date of Patent: June 18, 2002
    Assignee: Eastman Kodak Company
    Inventors: Thomas H. Whitesides, Amy Jasek, Hwei-Ling Yau, Jill E. Fornalik
  • Patent number: 6395461
    Abstract: Specific aromatic compounds having an extended planar &pgr; system are useful as spectral sensitizing dye stain reducing agents in photographic processing compositions and methods for providing color or black-and-white images in various photographic silver halide materials. These compounds are devoid of diaminostilbene fragments or fused triazole nuclei. They are particularly useful in fixing and bleaching compositions in the processing of color photographic silver halide materials, but can also be used in various other processing compositions.
    Type: Grant
    Filed: February 1, 2001
    Date of Patent: May 28, 2002
    Assignee: Eastman Kodak Company
    Inventors: Ramanuj Goswami, Mary E. Craver, Harry J. Price
  • Publication number: 20020037482
    Abstract: A bleach or bleach/fixing solution for processing photographic silver halide materials which, relative to the silver halide content of the unprocessed material, exhibit prior to the bleaching step a content of silver arising from development of at least 65 mol %, in particular for processing color reversal materials, characterized in that the solution contains at least one iron complex of propylenediaminetetraacetic acid or of &bgr;-alaninediacetic acid or a mixture of these complexes and the total concentration of the stated iron complexes in the solution is at least 0.045 and at most 0.25 mol/l and a process for processing, in which such a solution is used, is characterized by a small introduced quantity of iron complexes, a low residual silver content, a low bleaching fog value, elevated resistance to precipitation and in that the bleach solution may be rejuvenated.
    Type: Application
    Filed: August 1, 2001
    Publication date: March 28, 2002
    Inventors: Ralf Wichmann, Thomas Hubsch, Thomas Stetzer
  • Publication number: 20010004514
    Abstract: Specific aromatic compounds having an extended planar &pgr; system are useful as spectral sensitizing dye stain reducing agents in photographic processing compositions and methods for providing color or black-and-white images in various photographic silver halide materials. These compounds are devoid of diaminostilbene fragments or fused triazole nuclei. They are particularly useful in fixing and bleaching compositions in the processing of color photographic silver halide materials, but can also be used in various other processing compositions.
    Type: Application
    Filed: February 1, 2001
    Publication date: June 21, 2001
    Inventors: Ramanuj Goswami, Mary E. Craver, Harry J. Price
  • Patent number: 6221570
    Abstract: The present invention provides compositions and methods of making one-part bleach-fix liquid concentrates, packaged in a single unit, wherein the bleaching agent is a polyvalent metal oxidizing agent that is protected from reduction for an extended period of time by incorporating a thiocyanate salt as at least one fixing agent. The thiocyanate salt in added in an amount sufficient to provide one-part bleach-fix liquid concentrates that are homogeneous, essentially free of crystallized components and which retain effective oxidizing potential during extended storage.
    Type: Grant
    Filed: January 6, 2000
    Date of Patent: April 24, 2001
    Assignee: Trebla Chemical Company
    Inventor: Laszlo Papai
  • Patent number: 6174653
    Abstract: A method of forming a color photographic image comprises: contacting an imagewise exposed color photographic material with a color developing composition to provide a developed material, and contacting the developed material with a bleach-fix composition. This composition is a bleaching agent comprising of a complex of ferric ion and an aminopolycarboxylic acid, a fixing agent; and sulphite ion in an amount up to 0.1 mol/l; said bleach-fix composition having a pH from about 4 to about 8 and said contacting being for a period from about 5 to about 20 seconds.
    Type: Grant
    Filed: October 12, 1999
    Date of Patent: January 16, 2001
    Assignee: Eastman Kodak Company
    Inventor: Nigel R. Wildman
  • Patent number: 6153364
    Abstract: Specific aromatic compounds having an extended planar .pi. system are useful as spectral sensitizing dye stain reducing agents in photographic processing compositions and methods for providing color or black-and-white images in various photographic silver halide materials. These compounds are devoid of diaminostilbene fragments or fused triazole nuclei. They are particularly useful in fixing and bleaching compositions in the processing of color photographic silver halide materials, but can be used in various other processing compositions.
    Type: Grant
    Filed: December 16, 1999
    Date of Patent: November 28, 2000
    Assignee: Eastman Kodak Company
    Inventors: Ramanuj Goswami, Harry J. Price, Mary E. Craver
  • Patent number: 6103458
    Abstract: There is disclosed a method for processing a silver halide color photographic light-sensitive material, which comprises processing a silver halide color photographic light-sensitive material that contains a color-forming reducing agent, with an alkaline solution that is substantially free from any color-developing agent, and then processing the light-sensitive material with a bleach-fix solution that contains a ferric complex salt of a compound represented by formula (I) or (II): ##STR1## wherein, in formula (I), R.sub.1 represents a hydrogen atom, or an aliphatic hydrocarbon, aryl, or heterocyclic group; L.sub.1 and L.sub.2 each represent an alkylene group; and M.sub.1 and M.sub.2 each represent a hydrogen atom or a cation; and wherein, in formula (II), R.sub.21, R.sub.22, R.sub.23, and R.sub.24 each represent a hydrogen atom, or an aliphatic hydrocarbon, aryl, heterocyclic, hydroxyl, or carboxyl group; t and u are each 0 or 1; W represents a divalent carbon-containing linking group; and M.sub.21, M.sub.
    Type: Grant
    Filed: July 31, 1997
    Date of Patent: August 15, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hiroyuki Seki
  • Patent number: 5976772
    Abstract: A bleach/fixing bath, characterized in that it contains, apart from the active and auxiliary substances necessary for bleach/fixing, a phosphonocarboxylic acid having at least two carboxylic acid groups per molecule, is lower in odor and more stable than conventional bleaching baths.
    Type: Grant
    Filed: September 30, 1997
    Date of Patent: November 2, 1999
    Assignee: Agfa Gevaert AG
    Inventors: Thomas Hubsch, Ralf Weimann, Angelika Scholkmann, Erika Spriewald
  • Patent number: 5972583
    Abstract: Color photographic elements can be processed with an acidic periodate bleaching composition that also includes chloride ions as a rehalogenating agent.
    Type: Grant
    Filed: December 7, 1998
    Date of Patent: October 26, 1999
    Assignee: Eastman Kodak Company
    Inventors: Sidney J. Bertucci, Eric R. Schmittou
  • Patent number: 5945262
    Abstract: The present invention provides a correcting liquid for silver imaged lithographic printing plates being an aqueous solution having a pH in the range between 5.5 and 8.5 and comprising a iron (III) complex salt of an organic acid, a sulphite or a metabisulphite, a silver halide solvent and an accelerator, said accelerator being an organic heterocyclic compound having a mercapto- or thione group and not having a hydrophilic substituent besides the said mercapto or thione group characterized in that said accelerator is present in an amount ranging from 0.04 to 0.4 mole per liter of correcting liquid.
    Type: Grant
    Filed: December 4, 1996
    Date of Patent: August 31, 1999
    Assignee: Agfa-Gevaert, N.B.
    Inventor: Lode Deprez
  • Patent number: 5922519
    Abstract: A method for processing a silver halide color photographic photosensitive material comprises the steps of desilverizing a photosensitive silver halide material having at least one red-sensitive layer, green-sensitive layer and blue-sensitive layer respectively on one side of a transparent support and a magnetic recording layer containing magnetic grains on the other side after the color development and then washing it with water and/or stabilizing it, wherein a bath having fixing function used in the desilverization step contains the following compound or analogue thereof. ##STR1## This method does not impair the S/N ratio of the magnetically recorded information and excellent desilverization effect can be obtained.
    Type: Grant
    Filed: May 24, 1996
    Date of Patent: July 13, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takatoshi Ishikawa, Masaru Yoshikawa, Tetsuro Kojima
  • Patent number: 5856074
    Abstract: This invention relates to a fixing bath containing a biologically degradable complexing agent of formula I ##STR1## wherein R.sup.1-4 represents hydrogen, C.sub.1 -C.sub.10 -alkyl, hydroxy-C.sub.1 -C.sub.10 -alkyl, C.sub.1 -C.sub.10 -alkoxy-C.sub.1 -C.sub.10 -alkyl, carboxy-C.sub.2 -C.sub.10 -alkyl, dicarboxy-C.sub.1 -C.sub.10 -alkyl, carboxy-hydroxy-C.sub.1 -C.sub.10 -alkyl, hydroxy-C.sub.1 -C.sub.5 -alkyl-(oxy-C.sub.1 -C.sub.5 -alkyl).sub.n, or C.sub.1 -C.sub.5 -alkoxy-C.sub.1 -C.sub.5 -alkyl-(oxy-C.sub.1 -C.sub.5 -alkyl).sub.n,M represents hydrogen, lithium, sodium, potassium or ammonium, andn represents 1, 2, 3 or 4,the iron(III) complex salt of which does not impede electrolytic desilverisation during the regeneration of spent fixing bath.
    Type: Grant
    Filed: October 17, 1997
    Date of Patent: January 5, 1999
    Assignee: Agfa-Gevaert AG
    Inventors: Gustav Tappe, Norman Klaunzer
  • Patent number: 5814435
    Abstract: There is disclosed a photographic composition having fixing capacity and a method for processing a silver halide photographic material using the same. The photographic composition having fixing capacity comprises at least one compound represented by the following formula (I):RSO.sub.2 M formula (I)wherein R represents a lower alkyl group having 1 to 3 carbon atoms, and M represents a hydrogen atom or a cationic group.
    Type: Grant
    Filed: August 5, 1996
    Date of Patent: September 29, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsuro Kojima, Masaru Yoshikawa, Yoshihiro Fujita
  • Patent number: 5814437
    Abstract: A method for processing a silver halide photographic light-sensitive material is by an automatic processor having a processing chamber with a small volume.
    Type: Grant
    Filed: October 27, 1997
    Date of Patent: September 29, 1998
    Assignee: Konica Corporation
    Inventors: Manabu Nakahanada, Yutaka Ueda
  • Patent number: 5795703
    Abstract: A method for processing silver halide photosensitive photographic material comprises the steps of developing an image-exposed silver halide photosensitive material and desilvering it with a processing solution having fixing function which contains a thiosulfate radical and a specified meso-ionic compound or a specified thiourea, an amount of ammonium ion in the solution being 0 to 50% based on the total counter cations in the solution. This method can provide processed silver halide photosensitive photographic material having excellent photographic properties while keeping a low stain concentration with even a small amount of a replenisher.
    Type: Grant
    Filed: December 10, 1996
    Date of Patent: August 18, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Takatoshi Ishikawa
  • Patent number: 5783376
    Abstract: A composition for bleaching or bleach-fixing a silver halide photographic material has a pH of from 2 to 9. The composition comprises a bleaching agent which is either a persulfate or polyvalent metal complex of an aminopolycarboxylic acid, and from 0.01 to 2M of a sulfo-substituted carboxylate represented by Formula I(MO.sub.3 S).sub.n --R--(COOM).sub.m (I)wherein R is a benzene ring or a straight, branched or cyclic saturated aliphatic group having 2 to 8 carbon atoms;M is hydrogen or an organic or inorganic cation; andn is 1 to 7;with the proviso that if R is an aliphatic group, m is 2 to 4 and m and n combined cannot equal more than the number of carbon atoms in R plus two, and if R is a benzene ring, m is 2 to 5 and m and n combined cannot equal more than six.
    Type: Grant
    Filed: May 14, 1997
    Date of Patent: July 21, 1998
    Assignee: Eastman Kodak Company
    Inventors: Stuart Terrance Gordon, John Michael Buchanan, Sidney Joseph Bertucci
  • Patent number: 5783375
    Abstract: A redox amplification process with minimal steps includes processing a silver halide with an amplifier/bleach/fix solution that includes a redox oxidant capable of bleaching a silver image and a fixing agent that does not react with the redox oxidant.
    Type: Grant
    Filed: August 29, 1996
    Date of Patent: July 21, 1998
    Assignee: Eastman Kodak Company
    Inventor: Peter Jeffery Twist
  • Patent number: 5776666
    Abstract: A method of accelerating black and white development comprising contacting a negative-type silver halide photographic element during processing with a developer prebath or a developer bath comprising an accelerator compound of the formula: ##STR1## is disclosed, wherein R.sub.1, R.sub.2, and R.sub.3 are substituents; said R.sub.1, R.sub.2, and R.sub.3 may further combine with each other to form a 5-, 6-, or 7-membered ring; and wherein said developer prebath and developer bath do not contain any iron(III) ion complex salt having bleaching activity.A bath selected from the group consisting of developer prebaths and developer baths for black and white development of a negative-type silver halide photographic element comprising an aqueous solution of accelerator compound of the formula: ##STR2## is also disclosed, wherein R.sub.1, R.sub.2, and R.sub.3 are substituents; said R.sub.1, R.sub.2, and R.sub.
    Type: Grant
    Filed: March 3, 1993
    Date of Patent: July 7, 1998
    Assignee: Eastman Kodak Company
    Inventors: John Texter, Arthur Herman Herz, Henry Wolf Altland
  • Patent number: 5753423
    Abstract: A ready-to-use bleaching or bleach-fixing solution can be prepared by mixing an aqueous solution of succinic acid, maleic acid or malic acid, and an aminopolycarboxylic acid ligand, adding a ferric salt to form a ferric ligand chelate, and adding a chemical base, such as ammonia, to provide a final pH of from 2.5 to 5.5. optionally, a portion of the chemical base can be added before the addition of the ferric salt.
    Type: Grant
    Filed: April 29, 1996
    Date of Patent: May 19, 1998
    Assignee: Eastman Kodak Company
    Inventors: Jean Marie Buongiorne, Stephen Joseph Waffle, Richard Thomas Clark
  • Patent number: 5707787
    Abstract: A processing solution for processing an exposed silver halide photographic light-sensitive material comprises a compound represented by the following formula (A): ##STR1## wherein A.sub.1, A.sub.2, A.sub.3 and A.sub.4 each represent --COOM.sub.1, --OH, --PO.sub.3 M.sub.1 M.sub.2 or --CONH.sub.2 in which M.sub.1 and M.sub.2 each represent a hydrogen ion, an alkali metal ion or another cation; R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represent a hydrogen atom, a lower alkyl group or a hydroxyl group; n.sub.1, n.sub.2, n.sub.3 and n.sub.4 each represent an integer of 0, 1 or 2, provided that none of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are hydrogen atoms when n.sub.1 +n.sub.2 =1 and n.sub.3 +n.sub.4 =1; and X represents a substituted or unsubstituted alkylene group having 2 to 6 carbon atoms or --(B.sub.1 O)m-B.sub.2 -- in which B.sub.1 and B.sub.2 each represent a substituted or unsubstituted alkylene group having 1 to 5 carbon atoms, and m is an integer of from 1 to 4.
    Type: Grant
    Filed: August 11, 1993
    Date of Patent: January 13, 1998
    Assignee: Konica Corporation
    Inventors: Kenji Kuwae, Yutaka Ueda
  • Patent number: 5695915
    Abstract: A method used for processing a silver halide photographic light sensitive material including steps of developing and treating with a solution having bleaching capability. The solution having bleaching capability comprises a ferric complex salt of a compound represented by the following formula A: ##STR1## wherein A.sub.1, A.sub.2, A.sub.3 and A.sub.4 are independently a --CH.sub.2 OH group, a --PO.sub.3 M.sub.2 group or a --COOM group, which may be the same or different; M is a cation: and X is an alkylene group having 2 to 6 carbon atoms or a --(B.sub.1 O).sub.n --B.sub.2 -- group, in which is an integer of 1 to 8, B.sub.1 and B.sub.2 are independently an alkylene group having 1 to 5 carbon atoms, which may be the same or different. The solution can be used as a bleaching solution or bleach-fixing solution for color photographic material. The solution may further be used as a reducing solution for reducing an image formed on a photographic light-sensitive material.
    Type: Grant
    Filed: December 17, 1993
    Date of Patent: December 9, 1997
    Assignee: Konica Corporation
    Inventors: Yutaka Ueda, Kenji Kuwae
  • Patent number: 5691120
    Abstract: Aminosuccinic acid chelants are disclosed which have been found to be applicable in photographic processes. The aminosuccinic acids can be used in a method of bleaching or bleach-fixing a silver halide photographic material comprising contacting the photographic material with a bleaching solution containing at least one metal complex of a polyamino disuccinic acid and one or more metal complexes of a polyamino monosuccinic acid or a monoamino monosuccinic acid.
    Type: Grant
    Filed: January 14, 1997
    Date of Patent: November 25, 1997
    Assignee: Eastman Kodak Company
    Inventors: David A. Wilson, Druce K. Crump, Eric R. Brown