And Bleach Patents (Class 430/460)
  • Patent number: 5679501
    Abstract: A novel process and processing composition for processing a silver halide photographic material is disclosed. The processing composition is an aqueous solution of a ferric (III) complex salt of an ?S,S! optical isomer of a compound represented by formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 each represents a hydrogen atom, an aliphatic group, an aromatic group or a hydroxyl group; W represents a divalent linking group containing carbon atoms; and M.sub.1, M.sub.2, M.sub.3 and M.sub.4 each represents a hydrogen atom or a cation. The processing composition is useful for bleaching a silver halide color photographic material. A process for processing a silver halide color photographic material is further disclosed, employing the above described process composition containing a ferric (III) complex salt of the compound of formula (I) as a bleaching agent.
    Type: Grant
    Filed: January 3, 1995
    Date of Patent: October 21, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Seki, Hisashi Okada
  • Patent number: 5677115
    Abstract: A silver halide color photographic material having at least one silver halide emulsion layer on a support is color developed after imagewise exposure, followed by desilverization, wherein the photographic material has a total dry film thickness of 8 to 22 .mu.m, the concentration of ammonium ions contained in a processing solution having fixing ability used in desilverization is 0 to 50 mol % based on the total cations, and the processing solution having fixing ability contains at least one kind of thioether compound, thereby improving desilverization performance in continuous processing and preventing yellow stains from increasing.
    Type: Grant
    Filed: July 30, 1996
    Date of Patent: October 14, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Masatoshi Goto
  • Patent number: 5670305
    Abstract: A composition for bleach-fixing a silver halide photographic element comprising a fixing agent and a ternary ferric-complex salt formed by a tetradentate ligand and a tridentate ligand and a method of bleach-fixing using said composition.
    Type: Grant
    Filed: March 22, 1996
    Date of Patent: September 23, 1997
    Assignee: Eastman Kodak Company
    Inventors: Stuart Terrance Gordon, Keith Henry Stephen, Eric Richard Brown, Celia Ann DeAndrea, Mary Morris Podhorecki, William George Henry
  • Patent number: 5635341
    Abstract: A solution for bleaching or bleach-fixing an exposed and developed silver halide color photographic light-sensitive material contains a ferric complex salt of a compound represented by the following Formula (A-I), (A-II) or (A-III), and a compound represented by the following Formula (B): ##STR1##
    Type: Grant
    Filed: May 23, 1995
    Date of Patent: June 3, 1997
    Assignee: Konica Corporation
    Inventors: Hiroshi Yamashita, Yutaka Ueda
  • Patent number: 5633124
    Abstract: This invention provides a process for removal of silver halide from a silver halide photographic recording material by a processing solution with fixing ability (a fixer) containing thiosulfate as a fixing agent conducted in the presence of a thioether compound incorporated within a fixer formulation. It further provides a fixer formulation for use in said process. The fixer contains a maximum ammonium ion concentration of 0.9M.
    Type: Grant
    Filed: October 20, 1994
    Date of Patent: May 27, 1997
    Assignee: Eastman Kodak Company
    Inventors: Eric R. Schmittou, Jacob J. Hastreiter, Jr., Stuart T. Gordon
  • Patent number: 5627015
    Abstract: To achieve superior desilvering property and reduced stains even with the use of a biodegradable bleaching agent in a dilute concentration, the processing is conducted with a processing solution comprising a ferric complex salt of the compound of formula (I) or (II) and, for example, a 2-carboxypyridyl and having bleaching ability. (In the formulae, R.sub.1 to R.sub.5 represent, for example, a hydrogen atom or a carboxyl group, L.sub.1 to L.sub.5 represent, for example, an alkylene group, G.sub.1 and G.sub.2 represent, for example, a carboxyl group or an aryl group and X represents, for example, a hydrogen atom).
    Type: Grant
    Filed: December 7, 1994
    Date of Patent: May 6, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okada, Yoshihiro Fujita
  • Patent number: 5618658
    Abstract: A substantially sulfur-free ammonium thiosulfate containing product can be produced by spray drying an aqueous solution containing ammonium thiosulfate and effective stabilizing amounts of both a carbonate component and a sulfite component under effective conditions to provide a substantially sulfur-free product. The carbonate component is selected from among ammonium carbonate or bicarbonate, an alkali metal carbonate or bicarbonate, or an alkaline metal carbonate or bicarbonate while the sulfite component is an ammonium sulfite or bisulfite, alkali metal sulfite or bisulfite, or an alkaline metal sulfite or bisulfite.
    Type: Grant
    Filed: August 28, 1995
    Date of Patent: April 8, 1997
    Assignee: Fuji Hunt Photographic Chemicals, Inc.
    Inventors: Malcolm S. Penman, Edward C. Saunders, Peter R. Wardle
  • Patent number: 5607820
    Abstract: A method for desilvering an imagewise exposed and color development processed silver halide color light-sensitive material comprising processing the imagewise exposed and color developed silver halide color light-sensitive material with a processing solution exhibiting bleaching ability which contains at least one of hydrogen peroxide and a compound capable of releasing hydrogen peroxide, wherein the silver halide color light-sensitive material has an emulsion layer comprising a light-sensitive silver halide with at least 90 mol % silver chloride and substantially no silver iodide, the processing solution exhibiting a bleaching ability contains at least one water-soluble chloride, the color developed silver halide color light-sensitive material contains 1 mmol/m.sup.2 or less of a color developing agent in the light-sensitive material when introduced into the processing solution exhibiting a bleaching ability and the desilvering is completed within 30 seconds.
    Type: Grant
    Filed: April 26, 1995
    Date of Patent: March 4, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Koichi Nakamura
  • Patent number: 5593816
    Abstract: A silver halide color photographic material which comprises a support having thereon at least one layer containing at least one compound represented by the following general formulaR.sup.1 --SO.sub.2 NH.sub.2wherein R.sup.1 represents an unsubstituted aliphatic group having 6 or more carbon atoms, an unsubstituted aryl group or an aryl group substituted by at least one substituent selected from the group consisting of an aliphatic group, an aryloxy group, a carbamoyl group, an acylamino group, an aliphatic oxycarbonyl group, an arylcarbonyl group and a halogen atom, provided that R.sup.1 does not contain any coupler residue.
    Type: Grant
    Filed: January 7, 1994
    Date of Patent: January 14, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroo Takizawa, Toshiyuki Makuta
  • Patent number: 5587277
    Abstract: A solid photographic processing composition in tablet form for a silver halide photographic light sensitive material is provided, wherein at least a part of the surface of said solid processing composition is covere-coated with a compound selected from (i) a polyalkylene glycol having an average molecular weight of 2000 to 20000, (ii) a monosaccharide or disaccharide and (iii) a vinyl polymer having a betaine structure. The tablets of the processing composition are enclosed in a package, and introduced into a processing tank.
    Type: Grant
    Filed: July 11, 1995
    Date of Patent: December 24, 1996
    Assignee: Konica Corporation
    Inventors: Hiroshi Yamashita, Yutaka Ueda
  • Patent number: 5582958
    Abstract: A photographic bleaching or bleach/fixing composition contains a water-soluble ternary complex of an iron ion, a polycarboxylate ligand, and a second ligand which has at least one carboxyl group on an aromatic nitrogen heterocycle, such as a pyridinecarboxylic acid. Preferred materials are biodegradable, but all of the ternary complexes can be used in a variety of bleach or bleach/fix processes to good advantage as bleaching agents. They are particularly suitable for use in rehalogenating ferric chelate bleaches.
    Type: Grant
    Filed: January 10, 1995
    Date of Patent: December 10, 1996
    Assignee: Eastman Kodak Company
    Inventors: John M. Buchanan, Eric R. Brown, Stuart T. Gordon
  • Patent number: 5578428
    Abstract: A process for the bleaching of an exposed photographic material utilizes a peroxide bleach solution to remove metallic silver from the exposed photographic material. The silver from the photographic material passes into the bleach solution such that at least part of the excess silver over that required to catalyze the bleaching action is removed from the bleach solution by forming an insoluble silver compound, for example, by the addition of a halide. The invention provides an apparatus for use in the bleaching method.
    Type: Grant
    Filed: December 14, 1995
    Date of Patent: November 26, 1996
    Assignee: Eastman Kodak Company
    Inventor: John R. Fyson
  • Patent number: 5573893
    Abstract: There is disclosed a method for processing a silver halide color photographic material. The method comprises processing a silver halide color photographic material having a photographic layer, the degree of swelling of which is 1.2 to 3.0, by a color developer containing at least one compound represented by formula (I) in an amount of 0.01 to 10 g per liter of said color developer. ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 each represent a hydrogen atom, or an alkyl group, an alkoxy group, or an alkenyl group, which may be substituted, n is an integer of 1 to 3, and M represents a hydrogen atom or a counter cation.
    Type: Grant
    Filed: August 24, 1994
    Date of Patent: November 12, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Fujimoto, Takatoshi Ishikawa, Kazuaki Yoshida
  • Patent number: 5550010
    Abstract: The present invention relates to a color photographic processing method, and a product for color photography comprising, in addition to the conventional layers of light-sensitive silver halides, a non light-sensitive top layer.The method and photographic product enable sensitivity to be controlled during photographic processing.The invention also makes it possible to prevent deterioration of the processing baths.
    Type: Grant
    Filed: August 31, 1994
    Date of Patent: August 27, 1996
    Assignee: Eastman Kodak Company
    Inventors: Fran.cedilla.ois J. Bredoux, Yannick Begel, Henri Freisz
  • Patent number: 5543272
    Abstract: There is disclosed a photographic composition having fixing capacity and a method for processing a silver halide photographic material using the same. The photographic composition having fixing capacity comprises a photographic composition having fixing capacity, which comprises at least one compound represented by the following formula (I) and at least one compound represented by the following formula (II):RSO.sub.2 SM formula (I)wherein R represents an aliphatic group, an aromatic group, or a heterocyclic group, and M represents a hydrogen atom or a cationic group,R.sup.1 SO.sub.2 M.sup.1 formula (II)wherein R.sup.1 represents an aliphatic group, an aromatic group, or a heterocyclic group, and M.sup.1 represents a hydrogen atom or a cationic group.
    Type: Grant
    Filed: February 10, 1994
    Date of Patent: August 6, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsuro Kojima, Masaru Yoshikawa, Yoshihiro Fujita
  • Patent number: 5534394
    Abstract: A method for processing a silver halide color photographic material with which edge staining and the occurrence of staining on aging after processing can be prevented, and with which the stability of the bleach-fixer can be improved, comprising color developing and bleach-fixing the photographic material, wherein the bleach-fixer contains (1) thiosulfate, (2) at least one type of compound selected from among the group of compounds represented by formulae (I) and (II): ##STR1## wherein Ra, Rb, R.sup.1 through R.sup.4, X.sup.1 and n are as defined in the specification, and (3) an adduct of bisulfite with at least one type of compound selected from among the group of compounds represented by formulae (A), (B), (C) and (D): ##STR2## wherein R.sub.1 through R.sub.11, X, Y, Z, m and n are as defined in the specification.
    Type: Grant
    Filed: November 1, 1994
    Date of Patent: July 9, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takatoshi Ishikawa, Shinji Ueda, Hirotomo Sasaki, Tetsuro Kojima
  • Patent number: 5484691
    Abstract: A solid processing composition for providing fixer or bleach-fixer of a silver halide photographic light-sensitive material is disclosed, wherein the composition comprises a sugar alcohol and at least one of a thiosulfate salt and a thiocyanate salt.
    Type: Grant
    Filed: August 15, 1994
    Date of Patent: January 16, 1996
    Assignee: Konica Corporation
    Inventors: Kenji Ishida, Takashi Deguchi
  • Patent number: 5460923
    Abstract: A processing method for silver halide photographic material is disclosed, in which at least one hydrophilic colloidal layer containing a dye of a solid fine grain dispersion. The processing method is carried out by processing the photographic material with a solution having a fixing ability containing at least one compound represented by formula (A):RSO.sub.2 SM (A)wherein R represents an aliphatic group, an aryl group or a heterocyclic group, and M represents a hydrogen atom or a cation group.
    Type: Grant
    Filed: December 23, 1994
    Date of Patent: October 24, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masatoshi Goto, Yoshihiro Fujita
  • Patent number: 5451491
    Abstract: A method of desilvering an imagewise and developed color silver halide element, said method comprising bleaching the photographic element with a peracid bleach and subsequently contacting the photographic element with a fixer solution comprising thiosulfate anion and sodium cation;wherein the Molar-minute fixing Time is less than about 0.2 Molar-minutes.times.m.sup.2 /g Ag.times.the grams of incorporated silver per square meter of the photographic element.
    Type: Grant
    Filed: February 22, 1994
    Date of Patent: September 19, 1995
    Assignee: Eastman Kodak Company
    Inventors: Richard P. Szajewski, John M. Buchanan
  • Patent number: 5429914
    Abstract: A composition having a fixing ability for photography which is used as a bath having a fixing ability, for processing an exposed silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer, said compositian being substantially free of thiosulfate ion and comprising as a fixing agent at least one thioether comcompound having at least one group selected from the group consisting of ##STR1## and a heterocyclic group, wherein M.sub.1, M.sub.2 and M.sub.3 may be the same or different, each represents a hydrogen atom or a counter cation; R.sub.1 to R.sub.19, which may be the same or different, each represents a hydrogen atom, an alkyl group, an aryl group, an aralkyl group or an alkenyl group; and X.sup..crclbar. represents a counter anion.
    Type: Grant
    Filed: August 4, 1993
    Date of Patent: July 4, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsuro Kojima, Nobuo Watanabe
  • Patent number: 5427896
    Abstract: A method for processing a color photographic material comprising a support having on at least one surface thereof at least one layer containing a light-sensitive silver halide emulsion and a non-diffusing oil-soluble coupler capable of forming a dye by coupling with the oxidation product of an aromatic primary amine developing agent, wherein the oil-soluble dye is a pyrrolotriazole cyan coupler and the color photographic material is processed after color development with a bath containing, as a fixing agent, at least one of nitrogen-containing heterocyclic compounds having a sulfide group, meso-ionic compounds and thioether compounds.
    Type: Grant
    Filed: February 12, 1993
    Date of Patent: June 27, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hiroshi Hayashi
  • Patent number: 5415983
    Abstract: A method for processing a silver halide photographic material is disclosed, comprising a support having thereon at least one light-sensitive silver halide emulsion layer, which comprises the steps of developing and fixing the image-wise exposed silver halide photographic material, wherein the fixing bath used in the fixing step contains at least one meso-ionic compound other than meso-ionic 1,2,4-triazolium-3-thiolate compounds, wherein said meso-ionic compound is a compound represented by formula (I): ##STR1## wherein M and A.theta. are as defined in the specification as a fixing agent. The fixing bath and subsequent baths have excellent stability against precipitation, and the processed photographic material having improved image stability can be obtained.
    Type: Grant
    Filed: July 28, 1993
    Date of Patent: May 16, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsuro Kojima, Nobuo Watanabe
  • Patent number: 5409805
    Abstract: A solid processing agent for a silver halide photographic light-sensitive material is disclosed, which comprises a compound represented by the following Formula (I): ##STR1## wherein R.sub.1 represents a halogen atom, an alkyl group or an alkenyl group, provided that a plural of R.sub.1 's may be the same or different; R.sub.2 represents a halogen atom, an alkyl group, an alkenyl group or an alkoxy group; R.sub.3 represents a lower alkyl group, provided that R.sub.1, R.sub.2 and R.sub.3 may be the same or different, m and n each represent an integer of 0 to 5; and X represents an anion.
    Type: Grant
    Filed: July 14, 1994
    Date of Patent: April 25, 1995
    Assignee: Konica Corporation
    Inventors: Tsuyoshi Haraguchi, Hiroaki Kobayashi
  • Patent number: 5409804
    Abstract: A Photographic processing composition and a processing method using the same, wherein the composition contains a compound represented by formula (I) or a chelating compound of Fe(III) , M.sub.n (III), Co(III), Rh(II), Rh(III), Au(II), Au(III) or Ce(IV) and a compound represented by formula (I); ##STR1## wherein X.sub.1, X.sub.2, and X.sub.3 each represents a hydrogen atom, --L--COOM, or ##STR2## at least one of X.sub.1, X.sub.2, and X.sub.3 represents ##STR3## represents a carbon atomic group necessary for forming an aryl group; R.sub.1 represents a hydrogen atom or a substituent group; R.sub.2 represents an alkyl group, an alkoxy group, an acrylamino group, an alkylsulfonylamino group, an arylsulfonylamino group, a ureido group, an alkoxycarbonylamino group, an aryloxycarbonylamino group, a sulfamoyl group, a carbamoyl group, an alkylthio group, an alkylsulfonyl group, an arylsulfonyl group, an alkylsulfinyl group, an arylsulfinyl group, a hydroxy group, a halogen atom, a cyano group, --SO.sub.3 M.sup.
    Type: Grant
    Filed: January 24, 1994
    Date of Patent: April 25, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadashi Inaba, Hisashi Okada, Hiroyuki Seki
  • Patent number: 5401621
    Abstract: A process for processing an imagewise exposed silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer, comprising the steps of developing in a developing bath and processing in a bath having a fixing ability, wherein the bath having the fixing ability contains at least one mesoionic compound represented by formula (I): ##STR1## In a second embodiment, a process is disclosed for processing an imagewise exposed silver halide color photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer, comprising the steps of subjecting the material to color development, and then subjecting the material to blix in a blix bath, wherein the blix bath contains at least one mesoionic compound represented formula (III) or (IV): ##STR2##
    Type: Grant
    Filed: August 2, 1991
    Date of Patent: March 28, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsuro Kojima, Nobuo Watanabe
  • Patent number: 5395742
    Abstract: There is disclosed a novel diaminostilbene series compound, a method for forming an image using the same, and a composition comprising the same. The diaminostilbene compound is represented by the following formula (I): ##STR1## wherein L.sup.1 and L.sup.2, which are the same or different, each represent --OR.sup.1 or --N--R.sup.2 (R.sup.3), wherein the four substituents L.sup.1 and L.sup.2 have four or more substituents in total selected from substituents represented by the following formula (II);R.sup.1 and R.sup.2 each represent a hydrogen atom, an alkyl group, or an alkyl group having a substituent selected from substituents represented by the formula (II);R.sup.3 represents an alkyl group or an alkyl group having a substituent selected from substituents represented by the formula (II); andM represents a hydrogen atom, an alkali metal, an ammonium, or a pyridinium:formula (II)--SO.sub.3 M, --OSO.sub.3 M, --COOM, and --NR.sub.
    Type: Grant
    Filed: May 16, 1994
    Date of Patent: March 7, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasuaki Deguchi, Toshiaki Kubo
  • Patent number: 5391466
    Abstract: A method and chemical composition for bleaching or bleach fixing exposed and developed silver halide photographic light-sensitive material using a ferric complex salt of a compound represented by the following Formula I, II, III, IV, V, VI or VII: ##STR1##(R.sub.1)(R.sub.2)N--X.sub.1 --(Z--X.sub.2).sub.n --N(R.sub.3)(R.sub.4)(III)(R.sub.1)HN--X.sub.1 --(Z--X.sub.2).sub.n --NH(R.sub.
    Type: Grant
    Filed: November 22, 1993
    Date of Patent: February 21, 1995
    Assignee: Konica Corporation
    Inventors: Yutaka Ueda, Kenji Kuwae
  • Patent number: 5354647
    Abstract: The invention provides a bleach fix agent comprising a dilute solution of an alkaline metal or ammonium thiosulphite or a mixture thereof and iron (III) EDTA together with a soluble sulphite. The invention is characterized in that the soluble sulphite is present in an excess of the amount required for stabilization whereby the sulphite can be sacrificially destroyed by oxidizing agents in use thereby to neutralize the oxidizing effects upon the thiosulphate. The invention is particularly suitable for "RX" processes and results in the possibility of eliminating the stop-bath without allowing staining of the photographic material to occur.
    Type: Grant
    Filed: July 22, 1992
    Date of Patent: October 11, 1994
    Assignee: Eastman Kodak Company
    Inventor: John R. Fyson
  • Patent number: 5352567
    Abstract: A novel method for processing a silver halide color photographic material which comprises color developing an imagewise exposed silver halide color photographic material and then processing the material with a having a bleaching ability containing at least one bleaching agent a ferric complex of a compound represented by at least one of formula (I) and formula (II): ##STR1## wherein W.sup.1 represents an alkylene group containing 3 or less carbon atoms in total; L.sup.1, L.sup.2, L.sup.3 and L.sup.4 each represents an alkylene or arylene group; and M.sub.1 to M.sub.6 each represents a hydrogen atom or a cation; ##STR2## wherein W.sup.2 represents an alkylene group having 2 to 8 carbon atoms, an arylene group having 6 to 10 carbon atoms, cyclohexane group, ##STR3## (in which W.sup.21 and W.sup.22 each represents an alkylene group, and m represents an integer of 1 to 3, and A represents a hydrogen atom, hydrocarbon group, --L.sub.A --COOM, --L.sub.A --PO.sub.3 M.sub.2, --L.sub.A --OH or --L.sub.A --SO.sub.
    Type: Grant
    Filed: September 22, 1992
    Date of Patent: October 4, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okada, Tadashi Inaba, Morio Yagihara
  • Patent number: 5350668
    Abstract: A method for processing a silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer which comprises subjecting the silver halide color photographic material to imagewise exposure and color development, and then processing with a processing solution having bleaching ability, wherein the silver halide emulsion layer contains silver halide grains having a composition such that tabular silver iodobromide grains having an aspect ratio of not higher than 3 account for at least 50% of the entire projected area of the silver halide grains, and the processing solution having bleaching ability contains as a bleaching agent an iron (III) complex salt of a compound having the described structural formula, used in a concentration of 0.01 to 0.17 mol/liter.
    Type: Grant
    Filed: April 28, 1993
    Date of Patent: September 27, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akira Abe, Hiroyuki Seki, Hisashi Okada, Tadashi Inaba
  • Patent number: 5338649
    Abstract: A process for bleaching or bleach-fixing an imagewise exposed silver halide photographic material is provided, comprising developing in a color developing solution and bleaching or bleach-fixing in a processing composition having a bleaching capacity containing as a bleaching agent a metal chelate compound of a chelate-forming compound or salt thereof and a metal ion selected from the group consisting of Fe(III), Mn(III), Co(III), Rh(II), Rh(III), Au(II), Au(III) and Ce(IV), the chelate-forming compound or salt thereof is represented by formula (I): ##STR1## wherein G.sub.1 and G.sub.2 each represents a carboxyl group, a phosphono group, a sulfo group, a hydroxyl group, a mercapto group, an aryl group, a heterocyclic group, an alkylthio group, an amidino group, a guanidino group or a carbamoyl group; L.sub.1, L.sub.2 and L.sub.
    Type: Grant
    Filed: September 14, 1993
    Date of Patent: August 16, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadashi Inaba, Hisashi Okada, Ryo Suzuki, Yasuhiro Katsuoka, Hiroyuki Seki
  • Patent number: 5338648
    Abstract: A process and composition for processing a silver halide photographic material. The photographic material mat be a black and white photographic material or a color photographic material.
    Type: Grant
    Filed: September 27, 1993
    Date of Patent: August 16, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsuro Kojima, Nobuo Watanabe
  • Patent number: 5310633
    Abstract: Disclosed is a powdery bleach-fixing composition which is substantially not caked during storage. The bleach-fixing composition for color photographic materials comprises a thiosulfate, an iron (III) complex compound or a salt thereof, and a sulfite, bisulfite or pyrosulfite, at least 50 molar % (in terms of sulfite ion equivalent) thereof being potassium salt.
    Type: Grant
    Filed: May 5, 1993
    Date of Patent: May 10, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazuaki Yoshida, Takatoshi Ishikawa
  • Patent number: 5300408
    Abstract: A method for processing a silver halide color photographic material, which comprises processing an imagewise exposed silver halide color photographic material with a processing solution containing at least one chelate compound of a metal salt selected from the group consisting of salts of Fe(III), Mn(III), Co(III), Rh(II), Rh(III), Au(II), Au(III) and Ce(IV) with an organic acid represented by following general formula (I): ##STR1## wherein Z represents a nonmetallic atom group required to form a heterocyclic group; R represents a substituent; n represents 0 or an integer of from 1 to 10; Q.sub.1, Q.sub.2 and Q.sub.3 each represents a hydrogen atom, an aliphatic hydrocarbon group substituted by a carboxyl group, an aromatic hydrocarbon group substituted by a carboxyl group or a heterocyclic group substituted by a carboxyl group; and W represents a divalent linkage group containing at least one of an alkylene group or an arylene group.
    Type: Grant
    Filed: December 14, 1992
    Date of Patent: April 5, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okada, Tadashi Inaba
  • Patent number: 5298370
    Abstract: A method of processing a silver halide color photographic material using a carbamoyl or imidazole type organic metal complex bleaching agent of any of compounds of formulae (I), (II), (III), (IV), and (V) and a mercapto, mesoionic or thioether fixing agent of compounds of formulae (A), (B) and (C). A bleach-fixing composition containing the bleaching agent and fixing agent is also disclosed. The processing method provides good desilvering with little bleach fogging of the processed photographic material, and the processing composition has good stability. W in formula (III) below represents a divalent linking group.
    Type: Grant
    Filed: May 13, 1992
    Date of Patent: March 29, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsuro Kojima, Hisashi Okada, Nobuo Watanabe
  • Patent number: 5298371
    Abstract: There is disclosed a method for processing a silver halide light-sensitive material in which processing can be carried out while maintaining and controlling the processing performance of a bleach-fixing solution. This results in making it possible to reduce the amount of the bleach-fixing solution used. The method comprises subjecting an image-wise exposed silver halide light-sensitive material to bleach-fixing processing in a bleach-fixing solution after a color development processing, wherein a bath containing the bleach-fixing solution is divided into plural parts by at least one anion exchange membrane wherein an anode and a cathode are disposed in different parts so that electrification can be carried out between the anode part and the cathode part.
    Type: Grant
    Filed: August 20, 1992
    Date of Patent: March 29, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Takashi Nakamura
  • Patent number: 5288595
    Abstract: A method for processing a silver halide photosensitive material comprises the steps of developing an exposed silver halide photosensitive material and treating it with a bath having a fixing function containing an N-oxide compound having a mercapto group in the molecule. When the bath having a fixing function is used, a stable fixing power and excellent desilverization effect can be obtained by processing a color photosensitive material with only a small amount of replenisher.
    Type: Grant
    Filed: May 10, 1993
    Date of Patent: February 22, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Harumi Watanabe, Tetsuro Kojima, Nobuo Watanabe
  • Patent number: 5256531
    Abstract: A photographic processing composition containing at least one compound represented by formula (I) ##STR1## wherein R, R.sub.1 and R.sub.2 each represent a hydrogen atom, an alkyl group or an aryl group; and L.sub.1 represents an alkylene group or an arylene group. Also disclosed a processing composition for a silver halide color photographic material containing a metal chelate compound formed from a compound represented by formula (I) and a metal salt selected from salts of Fe(III), Mn(III), Co(III), Rh(II), Rh(III), Au(III), Au(II) and Ce(IV). A method is also disclosed for processing a silver halide photographic material with the processing compositions.
    Type: Grant
    Filed: June 25, 1992
    Date of Patent: October 26, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okada, Shigeru Nakamura
  • Patent number: 5250401
    Abstract: Disclosed is a method for processing a silver halide color photographic material, which comprises the steps of:image-wise exposing a silver halide color photographic material,color developing the image-wise exposed silver halide photographic material, andprocessing the color developed silver halide photographic material, in the presence of a processing composition containing a metal chelating compound formed by a compound represented by following formula (I) and a salt of a metal belonging to group Ib, IIb, IIIb,IVb, Vb, VIb, VIIb, or VIII of the Periodic Table: ##STR1## wherein Z represents a heterocyclic group; L represents a divalent linkage group; R.sub.11 and R.sub.12 each represents a hydrogen atom, an aliphatic group, an aromatic group, or a heterocyclic group; and n represents 0 or 1. Also disclosed is the processing composition used in the above method.
    Type: Grant
    Filed: July 30, 1991
    Date of Patent: October 5, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okada, Morio Yagihara, Tadashi Inaba, Hiroyuki Seki
  • Patent number: 5250402
    Abstract: A photographic processing composition for processing a silver halide photographic light-sensitive material. The composition contains at least one metal chelating compound formed from a metal salt of Fe(III) and a monoamine compound or salt thereof represented by formula (I-a') or (I-b'): ##STR1## wherein R represents a substituent; Q represents a group of non-metal atoms necessary to form a heterocyclic ring; X and Y each represents a carbon atom or a nitrogen atom; L.sub.1 ' and L.sub.2 ' each represents an alkylene group; M.sub.1, M.sub.2, M.sub.3 each represents a hydrogen atom or a cation; and u represents 0, 1, 2, 3, or 4.
    Type: Grant
    Filed: June 25, 1992
    Date of Patent: October 5, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okada, Tadashi Inaba, Morio Yagihara
  • Patent number: 5236814
    Abstract: A method for processing a silver halide color photographic light-sensitive material comprising a support having thereon a silver halide emulsion layer, comprising steps ofdeveloping said light-sensitive material with a color developerbleaching, after said developing step, said light-sensitive material with a bleaching solution, andtreating, after said bleaching step, said light-sensitive material with a solution having fixing capability, whereinsaid light-sensitive material has a coating weight of silver of not more than 1 g/m.sup.
    Type: Grant
    Filed: September 10, 1991
    Date of Patent: August 17, 1993
    Assignee: Konica Corporation
    Inventors: Satoru Kuse, Shigeharu Koboshi
  • Patent number: 5234801
    Abstract: A method for continuously processing an image-wise exposed silver halide color photographic material comprising the steps of color developing, bleach-fixing and at least one of washing with water and stabilizing. A replenisher is supplied to the bleach-fix bath to result in an overflow of from 30 to 500 ml/m.sup.2 of the photographic material processed. The bleach-fixing step further comprises collecting the bleach-fix overflow, regenerating the collected bleach-fix bath overflow by adding thereto a regenerant to produce a regenerated bleach-fix bath, and reusing the regenerated bleach-fix bath as a replenisher to the bleach-fix bath. The regeneration rate defined as the amount of bleach-fix overflow used for regeneration divided by the total amount of overflow multiplied by 100% is more than 80%. The photographic layers of the silver halide color photographic material have a degree of swelling of from about 2.5 to 4.0.
    Type: Grant
    Filed: February 26, 1992
    Date of Patent: August 10, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Takatoshi Ishikawa
  • Patent number: 5232822
    Abstract: A method for processing a light-sensitive silver halide color photographic material including color developing processing, and fixing. The bleaching is with a bleaching solution containing at least one of ferric complexes of the compounds represented by the formula (A) or (b) shown below and has a pH of 2.0 to 5.5. The fixing is with a processing solution having fixing ability and which contains at least one mole/liter of a thiosulfate. Said processing solution having fixing ability contains a compound selected from the group (FB). ##STR1## wherein A.sub.1 to A.sub.4 may be either the same or different, and each represent --CH.sub.2 OH, --COOM or --PO.sub.3 M.sub.1 M.sub.2 ; M, M.sub.1 and M.sub.2 each represent hydrogen atom, sodium atom, potassium atom or ammonium group; X represents a substituted or unsubstituted alkylene group having 3 to 6 carbon atoms, ##STR2## wherein A.sub.1 to A.sub.4 may be either the same or different and each represent --CH.sub.2 OH, --COOM or --PO.sub.3 M.sub.1 M.sub.2 ; M, M.
    Type: Grant
    Filed: July 17, 1991
    Date of Patent: August 3, 1993
    Assignee: Konica Corporation
    Inventors: Masao Ishikawa, Shigeharu Koboshi
  • Patent number: 5230991
    Abstract: A method for processing a silver halide color photographic light-sensitive material is discloseed. The method comprises the steps ofdeveloping a silver halide color photographic light-senaitive material which comprises silver halide grains substantially consisting of silver chloride, whith acolor developer, andbleach-fixing said deveoped light-sensitive material with a bleach-fixer containing a water soluble bromide salt in an amount of from 0.01 mol/l to 1.0 mol/l and having a pH value of from 6.5 to 8.5 in a tank in whic said bleach fixer has a surface area opening to air of from 8 cm.sup.2 /l to 100 cm.sup.2 /l.
    Type: Grant
    Filed: October 18, 1991
    Date of Patent: July 27, 1993
    Assignee: Konica Corporation
    Inventors: Shinsaku Nagaoka, Shigeharu Koboshi
  • Patent number: 5223379
    Abstract: A processing composition having a bleaching ability which is used for processing silver halide color photographic materials, and containing a metal chelate compound formed fromthe salt of a metal selected from the group consisting of Fe(III), Mn(III), Co(III), Rh(II), Rh(III), Au(II), Au(III) and Ce(IV), andat least one of a compound represented by formula (I) and a compound represented by formula (II): ##STR1## wherein L.sub.1 and L.sub.2 each represents ##STR2## X.sub.1 and X.sub.2 each represents an oxygen atom or a sulfur atom, R, R.sub.1, R.sub.2 and R.sub.3 each represents a hydrogen atom or an aryl or alkyl group which may be substituted, R.sub.4 represents an aryl or alkyl group which may be substituted, ##STR3## or --OR.sub.7, R.sub.5 and R.sub.6 each has the same meaning as R.sub.1, R.sub.7 represents an aryl or alkyl group which may be substituted, Y.sub.1 and Y.sub.2 each represents an arylene or alkylene group which may be substituted, R, L.sub.1 and L.sub.
    Type: Grant
    Filed: May 16, 1991
    Date of Patent: June 29, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okada, Tadashi Inaba, Toshihiko Maekawa, Tsukasa Yamada, Hiroyuki Seki
  • Patent number: 5221597
    Abstract: Disclosed is a method of processing a silver halide color photographic material where an imagewise exposed silver halide color photographic material is, after color-developed, processed with a bleaching solution contains (1,3-diamino-propanetetraacetato)iron (III) complex and that, when the material is processed with the said processing solution having a fixing ability, a jet stream of the said processing solution is run against the emulsion surface of the said photographic material. By the method, rapid desilvering is possible, and the material processed is not stained.
    Type: Grant
    Filed: December 13, 1991
    Date of Patent: June 22, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshihiro Fujita, Shinji Ueda, Takatoshi Ishikawa, Akira Abe, Shigeru Nakamura
  • Patent number: 5202228
    Abstract: Silver sulfide is reversed in a process for regenerating a dissolved silver-containing spent bleach fixer solution. The process is particularly suited for treating the bleach fixer solution in a manner which enables recycling of the solution giving rise to considerable reduction in cost of bleach fixer solution and reduced environmental pollution. The process comprises introducing a hydrosulfide reagent into the bleach fixer solution, which contains silver, to precipitate silver sulfide while maintaining pH and thiosulfate levels in the bleach fixer to allow for reuse. The precipitate is isolated from the bleach fixer solution to remove silver thereby and hence enable recycling of the bleach fixer solution. It is preferred to adjust the pH and sulfite levels following silver removal to complete the regeneration process.
    Type: Grant
    Filed: August 9, 1991
    Date of Patent: April 13, 1993
    Assignee: Technology Transfer Barbados Inc.
    Inventors: Michael E. Dutka, Paul H. Whitney, Keith E. Malcolm
  • Patent number: 5194368
    Abstract: The present invention relates to a method for processing a silver halide photographic light-sensitive material having at least one silver halide emulsion layer containing silver iodide with a processing solution having fixing ability after developing the light-sensitive material. The object of the present invention is to speed up the fixing process in the foregoing method and to reduce the amount of waste liquor from the fixing process. The present invention is characterized in that the processing with the processing solution having fixing ability is performed while the processing solution is brought into contact with an anion-exchange resin and that 20 to 2,000 l of the processing solution per liter of the anion-exchange resin is brought into contact with the resin.
    Type: Grant
    Filed: September 6, 1989
    Date of Patent: March 16, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinji Ueda, Tetsuro Kojima, Tohru Kitahara, Tomokazu Yasuda, Yoshihiro Fujita, Takatoshi Ishikawa
  • Patent number: 5188927
    Abstract: A composition for the processing of a silver halide color photographic material, which comprises at least one metal chelate compound formed of a salt of metal selected from the group consisting of Fe(III), Mn(III), Co(III), Rh(II), Rh(III), Au(III), Au(II) and Ce(IV) and a compound represented by the general formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.a, R.sub.b, and R.sub.c each represent a hydrogen atom, an aliphatic group or an aromatic group; R.sub.5 and R.sub.6 each represents a hydrogen atom, an aliphatic group, an aromatic group, a halogen atom, a cyano group, a nitro group, an acyl group a sulfamoyl group, a carbamoyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonyl group or a sulfinyl group, or R.sub.5 and R.sub.6 together may form a 5- or 6-membered ring; L.sub.1 represents a divalent aliphatic or aromatic group or a divalent linking group containing at least one of them; A.sub.
    Type: Grant
    Filed: June 14, 1991
    Date of Patent: February 23, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okada, Seki Hiroyuki
  • Patent number: 5187050
    Abstract: A method for processing a silver halide photographic material is described, comprising the steps of:(a) developing a silver halide photographic material comprising a support having thereon at least one hydrophilic colloidal layer, including at least one light-sensitive emulsion layer containing tabular silver halide grains having an aspect ratio of at least about 4, the total number of hydrophilic colloidal layers having a degree of swelling of about 250% or less; and(b) after developing a predetermined amount of said silver halide photographic material, adding a single replenisher of the developer comprising a 3-pyrazolidone developing agent represented by formula (I): ##STR1## wherein R.sub.o represents a substituted or unsubstituted aryl group; and R.sub.1, R.sub.2, R.sub.3 and R.sub.
    Type: Grant
    Filed: February 4, 1992
    Date of Patent: February 16, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Minoru Yamada, Takashi Toyoda, Sumito Yamada