Including Developing Accelerator Patents (Class 430/469)
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Patent number: 7326527Abstract: A method of processing a photothermographic material by a thermal processor is disclosed, wherein the photothermographic material comprises on one side of a support a light-sensitive layer containing an organic silver salt, silver halide grains, a binder and a reducing agent and a light-insensitive layer and on the other side of the support a back coating layer; the thermal processor uses a transport system in which a feed roller is disposed with being in contact with a bundle of plural stacked film sheets of the photothermographic material so as to feed the uppermost film sheet of the bundle of film sheets through rotation of the feed roller to expose and develop the fed film sheet; and the back coating layer contains a matting agent of an organic resin.Type: GrantFiled: February 20, 2007Date of Patent: February 5, 2008Assignee: Konica Minolta Medical & Graphic, IncInventors: Narito Goto, Makoto Sumi
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Patent number: 6677109Abstract: A producing method of a silver halide emulsion comprising the steps of adding silver halide fine grains AgX0 having an to a silver halide seed crystal emulsion containing at least water, dispersion medium 1 and silver halide crystal, and growing the seed crystal by dissolving the added AgX0, wherein AgX0 are formed in dispersion medium solution 2 containing dispersion medium 2, the pH of dispersion medium solution 2 of the time when AgX0 are formed is from 7.3 to 12.2, the average equivalent-circle projected area diameter of AgX0 is from 0.001 to 0.2 &mgr;m, and AgX0 are non-twin crystal grains not substantially having twin planes.Type: GrantFiled: January 27, 2003Date of Patent: January 13, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Mitsuo Saitou, Masaaki Miki, Katsuhisa Ohzeki
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Patent number: 6593073Abstract: A silver halide photographic element comprises at least one silver halide emulsion layer comprising a silver halide emulsion comprising core/shell silver halide grains wherein the core region comprises silver bromide with from about 5 to about 20% silver iodide and the shell region comprises silver bromide with about 0.1 to about 10% silver iodide and said layer contains a fragmentable electron donor compound of the formula X—Y′ or a compound which contains a moiety of the formula —X—Y′; wherein X is an electron donor moiety, Y′ is a leaving proton H or a leaving group Y, with the proviso that if Y′ is a proton, a base, &bgr;−, is covalently linked directly or indirectly to X, and wherein: 1) X—Y′ has an oxidation potential between 0 and about 1.Type: GrantFiled: December 20, 1999Date of Patent: July 15, 2003Assignee: Eastman Kodak CompanyInventors: Jon N. Eikenberry, Yun C. Chang
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Patent number: 5994037Abstract: Color photographic elements, especially color photographic papers, can be more rapidly color developed (up to 25 seconds) in the presence of a color developing solution containing a selectively diffusible color development photochemical such as a development inhibitor. Despite the shortened processing time, color balance within the three color records of such elements is maintained. The selectively diffusible color development photochemical has size and structure that enables it to have sufficient solubility in the color developing composition, and to selectively diffuse into the topmost red-sensitive emulsion layers of the processed color papers only.Type: GrantFiled: October 21, 1998Date of Patent: November 30, 1999Assignee: Eastman Kodak CompanyInventors: Peter J. Twist, John D. Goddard
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Patent number: 5882847Abstract: A color light-sensitive material advantageous in that a ratio of .gamma. in a short time processing using a color developer containing a silver halide solvent to .gamma. in a standard time processing using a color developer containing no silver halide solvent is from 0.8 to 1.2 in any case of yellow, magenta and cyan and an image formation method using the same.Type: GrantFiled: March 10, 1997Date of Patent: March 16, 1999Assignee: Fuji Photo Film Co., Ltd.Inventors: Akimitsu Haijima, Toshihiro Nishikawa
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Patent number: 5843630Abstract: A photographic concentrate for preparing a color developer comprises benzyl alcohol, water and organic solvents. This concentrate can be part of a kit for preparing a color developer along with 2 other concentrated solutions.The noted concentrated solution comprises benzyl alcohol at between 25 and 35%, water at between 3 and 8%, ethylene glycol at between 10 and 20% and diethylene glycol at between 35 and 60%.Type: GrantFiled: August 9, 1996Date of Patent: December 1, 1998Assignee: Eastman Kodak CompanyInventor: Jean Pierre Masson
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Patent number: 5789143Abstract: This invention relates to a silver halide color photographic element comprising a support, a silver halide emulsion and poly(thioether)s wherein greater than 50 percent of the poly(thioether)s have acidic functional end groups with an aqueous pKa.ltoreq.10, or end groups which will react to form acidic functional end groups with an aqueous pKa.ltoreq.10 during development, on both termini and wherein the poly(thioether)s have a molecular weight greater than 800.Type: GrantFiled: April 30, 1997Date of Patent: August 4, 1998Assignee: Eastman Kodak CompanyInventors: George J. Burgmaier, David A. Dickinson, Robert A. Guistina
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Patent number: 5702873Abstract: A redox-amplification solution comprising hydrogen peroxide, or a substance capable of releasing hydrogen peroxide, or reducing agent, such as a color developing agent, and in combination three or more sequestering agents for complexing with a transition metal ion to inhibit catalysis of impurities emanating from a photographic film coating and enhance the stability of the solution; a method of photographic color processing including a step using the redox-amplification solution and its use therefor.Type: GrantFiled: April 10, 1996Date of Patent: December 30, 1997Assignee: Eastman Kodak CompanyInventor: Peter Jeffery Twist
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Patent number: 5691130Abstract: A color recording photographic element is disclosed containing a support and, superimposed on the support, blue, green and red recording layer units. The layer unit nearest the support contains a high chloride tabular grain emulsion and an optionally esterified glycolic ether having a molecular weight of at least 300 and containing at least one thioether moiety. The layer unit farthest from the support is free of the optionally esterified glycol compound. The advantages realized are an increased imaging density range, increased sensitivity, and increased contrast.Type: GrantFiled: November 28, 1995Date of Patent: November 25, 1997Assignee: Eastman Kodak CompanyInventors: Lois Ann Buitano, Richard Peter Szajewski
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Patent number: 5595860Abstract: A process for processing a silver halide color photographic material, which comprises developing in a color developer substantially free of sulfite ion and containing an aromatic primary amine color developing agent and at least one phosphorus compound selected from the group consisting of compounds represented by formula (I), formula (I-a) and formula (I-b) and internal salts thereof: ##STR1## wherein R, R' and R" each represents an aliphatic hydrocarbon group or an aryl group; A represents a divalent or trivalent linking group; M, M' and M" each represents a hydrogen atom, an alkali metal atom, an alkaline earth metal atom, an ammonium or a quaternary ammonium; and m represents 2 when M, M' or M" is monovalent and m is 1 when M, M' and M" is divalent.Type: GrantFiled: April 27, 1995Date of Patent: January 21, 1997Assignee: Fuji Photo Film Co., Ltd.Inventors: Takatoshi Ishikawa, Masakazu Yoneyama
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Patent number: 5508155Abstract: Substituted hydroxylamine antioxidants can be prepared by reacting hydroxylamine or a mono-substituted hydroxylamine with an epoxide. The antioxidant reaction product is not removed from the reaction mixture, but is used without separation after combination with a color developer to provide a photographic color developer composition. The antioxidants are highly water soluble and thus exhibit no objectionable odor.Type: GrantFiled: December 22, 1994Date of Patent: April 16, 1996Assignee: Eastman Kodak CompanyInventors: Carl A. Marrese, Paul A. Zielinski
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Patent number: 5466562Abstract: A method of processing an imagewise exposed photographic silver halide colour material by a redox amplification method in which the colour material is treated with a colour developing agent in the presence of an oxidantin which a processor is used which comprises means for applying a relatively small volume of processing solution to an imagewise exposed silver halide material and in which the relatively small volume of solution is supplied from a reservoir of relatively large volume and, while processing, the processing solution being used is isolatable from said reservoir and,wherein either a colour developer solution without oxidant or an oxidant solution without colour developing agent is held in the reservoir andwherein the additional oxidant (or colour developing agent) respectively needed for amplification is introduced into the processing solution while it is isolated from said reservoir andwherein the used developer/amplifier so-formed is discarded into said reservoir after use where any unused introdType: GrantFiled: July 15, 1994Date of Patent: November 14, 1995Assignee: Eastman Kodak CompanyInventor: Peter D. Marsden
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Patent number: 5354646Abstract: A method of colour-developing a silver halide colour light-sensitive material having plural silver halide emulsion layers each containing substantially silver chlorobromide. At least one of the layers has a silver chloride content of not less than 20 mol %, and a colour developer being used in the colour developing method contains the compounds each represented by the following formula [I]: ##STR1## According to the processing method, a colour photographic image having a satisfactory colour density can be obtained by a rapid development process and the excellent preservability for a long standing of the colour developer can be displayed.Type: GrantFiled: March 7, 1994Date of Patent: October 11, 1994Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Kazuhiro Kobayashi, Shigeharu Koboshi, Masao Ishikawa, Masayuki Kurematsu, Yoko Matsushima
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Patent number: 5344750Abstract: A color development process for processing an imagewise exposed silver halide color photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer comprising a color coupler and a silver iodobromide emulsion containing silver iodide in an amount of from 2 to 20 mol %, comprising the step of processing the color photographic material in a color developing solution containing a color developing agent and bromide ion for 40 seconds to 90 seconds, wherein the color developing agent is represented by formula (D'): ##STR1## wherein R.sub.1d, and R.sub.2d, each represents an alkyl group having 1 to 4 carbon atoms; and L.sub.1 represents a straight-chain or branched alkylene group having 3 or 4 carbon atoms, the concentration {Br.sup.- } of bromide ion in the color developing solution is from 30 to 60 mmol/l, the relationship between the concentration {R} of the color developing agent in the color developing solution and the concentration {Br.sup.Type: GrantFiled: May 11, 1993Date of Patent: September 6, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroshi Fujimoto, Masato Taniguchi
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Patent number: 5264330Abstract: There is disclosed a method for processing a silver halide color photographic material containing a yellow coupler represented by formula (Y) with a color developer containing an aromatic primary amine color developing agent and a polymer of vinyl alcohol or vinyl pyrrolidone series. The disclosure described provides a method for development processing wherein yellow stain and processing nonuniformity in a running processing can be prevented effectively.Type: GrantFiled: March 13, 1991Date of Patent: November 23, 1993Assignee: Fuji Photo Film Co. Ltd.Inventors: Kazuaki Yoshida, Takatoshi Ishikawa
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Patent number: 5118593Abstract: A method of color image formation is disclosed, comprising imagewise exposing a color photographic light-sensitive material comprising a reflective support having provided thereon at least one light-sensitive layer containing a color coupler capable of forming a color image upon coupling with an oxidation product of an aromatic primary amine developing agent and a silver halide emulsion, and processing the exposed light-sensitive material with a color developing solution containing substantially no benzyl alcohol within a development time of 2 minutes and 30 seconds, wherein said processing is carried out in the pressence of at least one compound represented by formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 each represents a hydrogen atom, a hydroxyl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, an acyl group, or a sulfonyl group; or R.sup.1 and R.sup.2, or R.sup.3 and R.sup.Type: GrantFiled: September 19, 1991Date of Patent: June 2, 1992Assignee: Fuji Photo Film Co., Ltd.Inventors: Kokichi Waki, Shigeo Hirano
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Patent number: 5110713Abstract: A method for continuously processing silver halide color photographic material with a color developer containing at least one aromatic primary amine color-developing agent is disclosed. In the method a silver halide color photographic material at least one of the layers of which contains a silver halide emulsion of a high chloride comprising 80 mol % or over of silver chloride is processed in the presence of a specific heterocyclic compound, after exposure to light, with a color developer that is substantially free from sulfite ions and whose replenishing amount is 120 ml or below per m.sup.2 of the silver halide photographic material, to attain desired photographic characteristics.Type: GrantFiled: March 27, 1991Date of Patent: May 5, 1992Assignee: Fuji Photo Film Co., Ltd.Inventors: Kazuaki Yoshida, Takatoshi Ishikawa
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Patent number: 5079133Abstract: A silver halide color photographic material is provided that contains at least one pyrazoloazole type coupler represented by formula (I) ##STR1## wherein Za and Zb each represents ##STR2## or .tbd.N--, R.sub.1 and R.sub.Type: GrantFiled: July 16, 1990Date of Patent: January 7, 1992Assignee: Fuji Photo Film Co., Ltd.Inventors: Akio Mitsui, Takashi Ozawa
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Patent number: 5077180Abstract: A method for continuously processing silver halide color photographic material with a color developer containing at least one aromatic primary amine color-developing agent is disclosed. In the method a silver halide color photographic material at least one of the layers of which contains a silver halide emulsion of a high chloride comprising 80 mol % or over of silver chloride is processed, after exposure to light, with a color developer that is substantially free from sulfite ions and whose replenishing amount is 120 ml or below per m.sup.2 of the silver halide photographic material, to attain desired photographic characteristics.Type: GrantFiled: March 4, 1991Date of Patent: December 31, 1991Assignee: Fuji Photo Film Co., Ltd.Inventors: Kazuaki Yoshida, Takatoshi Ishikawa
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Patent number: 4968588Abstract: A method for processing a silver halide color photographic material is described, which comprises processing a silver halide color photographic material comprising a reflective support having thereon at least one silver halide emulsion layer for a period of 2 minutes and 30 seconds or less with a color devleoping solution which does not substantially contain benzyl alcohol and which contains at least one of compounds selected from the group consisting of a compound represented by formula (I), a compound represented by formula (II), hydantoic acid, allylamine, aminoguanidine, o-aminobenzoic acid, L-(+)-cysteine, benzylamine, DL-serine, morpholine, N-hydroxyethyl morpholine, o-aminobenzyl alcohol, quinuclidine, or salts thereof, tetramethylammonium acetate, choline, or choline chloride, ##STR1## wherein R.sup.1 represents a hydroxyalkyl group having from 2 to 10 carbon atoms; and R.sup.2 and R.sup.Type: GrantFiled: September 8, 1989Date of Patent: November 6, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Takatoshi Ishikawa, Morio Yagihara
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Patent number: 4954425Abstract: A method for forming an intensified color image by subjecting a silver halide color photographic material exposed imagewise to light, to color-development processing that uses a monobath development-intensifying solution containing hydrogen peroxide or a compound that releases hydrogen peroixide and a color-developing agent is disclosed. According to the color-intensifying method silver-saving can be attained using a greatly reduced amount of a processing solution.Type: GrantFiled: August 15, 1988Date of Patent: September 4, 1990Assignee: Fuji Photo Film Co., Ltd.Inventor: Haruhiko Iwano
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Patent number: 4880725Abstract: A color image is formed by imagewise exposing a color photosensitive material comprising at least a silver halide and a coupler and subjecting the material to intensified development with a processing solution containing a reducing agent and an intensifier. A substantially water-insoluble basic metal compound is previously contained in the silver halide based color photosensitive material, while the processing solution contains a compound capable of complexing reaction with the metal ion of the substantially water-insoluble basic metal compound to release a base.Type: GrantFiled: December 27, 1988Date of Patent: November 14, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Hirai, Haruhiko Iwano
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Patent number: 4853318Abstract: A process for processing color photographic papers using a color developer substantially free from benzyl alcohol and containing a compound represented by formula (I) ##STR1## wherein Z represents an atomic group forming an aromatic nucleus is disclosed. In the process, the formation of color stains is greatly reduced even in the case of shortening the processing times for the blix step and the wash and/or stabilization step after color development.Type: GrantFiled: February 17, 1987Date of Patent: August 1, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshihiro Fujita, Hiroshi Fujimoto, Takatoshi Ishikawa, Shinzo Kishimoto
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Patent number: 4837132Abstract: A method is described for processing a silver halide color photographic material after imagewise exposure, comprising color developing, desilvering, and at least one of washing and stabilizing a silver halide color photographic material, wherein a color developer which does not substantially contain benzyl alcohol but comprises at least one compound represented by formula (I) ##STR1## wherein M.sup.1, M.sup.2, M.sup.3 and M.sup.4 each represents a hydrogen atom, an alkali metal ion, an ammonium ion, or 1/n of an n-valent cation is used for the color development.Type: GrantFiled: May 26, 1987Date of Patent: June 6, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroshi Fujimoto, Takatoshi Ishikawa
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Patent number: 4596765Abstract: A photographic color forming agent composition comprising an aromatic primary amine color developing agent and materials (A), (B), and (C). Material A is a compound having an aromatic ring bearing two hydroxy groups in the ortho positions thereof. Material B is a hydroxyalkylidene-diphosphonic acid metal ion chelating agent. Material C is at least one metal salt selected from the group consisting of the water-soluble metal salts of magnesium, bismuth, aluminum, zinc, barium, or zirconium. The metal salt is present in an amount in mols equivalent to or more than the amount in mols of metal ion chelating agents of B.Type: GrantFiled: December 4, 1984Date of Patent: June 24, 1986Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Masayuki Kurematsu, Shigeharu Koboshi
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Patent number: 4546068Abstract: There is disclosed a method for processing of a light sensitive silver halide color photographic material characterized by carrying out, after an image exposure of the material, a development processing of the material in the presence of the following components (A), (B), and (C) and/or (D):(A) an aromatic primary amine color developing agent compound;(B) a manganese salt and/or a cerium salt;(C) a diphosphonic acid sequestering agent and a magnesium salt and/or a lithium salt; and(D) at least one of the sequestering agent selected from the group consisting of the compounds represented by the formulas (I), (II), (III), (IV) and (V) found in the specification.Type: GrantFiled: May 29, 1984Date of Patent: October 8, 1985Assignee: Konishiroku Photo Industry Co., Ltd.Inventor: Satoru Kuse
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Patent number: 4465762Abstract: A method for forming a color image comprising color developing a color photographic silver halide light-sensitive material containing at least one compound represented by formula (I) ##STR1## wherein X is a hydrogen atom or an acetyl group, R is an aryl group, and each of R.sub.1, R.sub.2, R.sub.3, and R.sub.4 is a hydrogen atom, an alkyl group, or an aryl group,using a color developer containing a p-phenylenediamine-based and/or p-aminophenol-based color developing agent and without performing black-and-white development.Type: GrantFiled: March 3, 1982Date of Patent: August 14, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Takatoshi Ishikawa, Takashi Nakamura, Kotaro Nakamura
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Patent number: 4414305Abstract: An image-forming method is disclosed. The method includes providing a silver halide color photographic material and imagewise exposing that material. The exposed material is color developed in the presence of a compound capable of reacting with or adsorbing a silver halide. The material is developed within a mono-bath intensifying developing solution which includes hydrogen peroxide or a compound capable of releasing hydrogen peroxide and a color developing agent. The solution substantially excludes the presence of bromide ions and iodide ions. The compound capable of reacting with or being absorbed into silver halide is a nitrogen-containing heterocyclic compound which has been found to be very useful in the image-forming method to obtain high color density with materials containing a small amount of silver halide.Type: GrantFiled: July 28, 1982Date of Patent: November 8, 1983Assignee: Fuji Photo Film Co., Ltd.Inventors: Koichi Nakamura, Hiroyuki Hirai
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Patent number: 4409324Abstract: A multilayer color photographic sensitive material is disclosed. The material is comprised of a support base and a silver halide emulsion layer. The material contains at least one layer containing a high boiling solvent and an oil-soluble coupler, wherein the volume ratio of solvent to coupler is 1/2 or less, and a compound represented by the general formula (I): ##STR1## wherein X is a hydrogen atom or an acetyl group, R is an aryl group, and R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents a hydrogen atom, an alkyl group or an aryl group. The material produces sharp images even though it contains a low oil/coupler ratio. Furthermore, there is no retardation of development.Type: GrantFiled: September 21, 1982Date of Patent: October 11, 1983Assignee: Fuji Photo Film Co., Ltd.Inventors: Takatoshi Ishikawa, Akio Mitsui, Masakazu Morigaki, Takashi Nakamura
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Patent number: 4292400Abstract: Photographic elements containing image-wise developable silver halide are developed in the presence of an oxathioether development activator according to the formula:R.sup.1 --A--(OCH.sub.2 CH.sub.2).sub.n --S--A'--(X--A").sub.m --Y--R.sup.2wherein:R.sup.1 is H, alkyl, hydroxyalkyl, or R.sup.2 --Y--(A"--X).sub.m --A'--S--,A, A', and A" is alkylene, with the proviso that A is a monovalent bond when R.sup.1 is hydrogen or alkyl or hydroxyalkyl,X is --OCO--, --SO.sub.2 --, --CONH--, or Y,Y is ligand or complexing function of the type of --S-- and --N(Q)-- (Q=H or alkyl),R.sup.2 is alkyl, which may be substituted by OH, or when Y is --N(Q)--, R.sup.2 together with Q may represent the atoms needed to complete a nitrogen-containing saturated ring,n is at least 2, and m is 0 or 1.The development activators can be used in black-and-white development or in color development. They can be incorporated in the photographic material or in the developing solution.Type: GrantFiled: September 10, 1980Date of Patent: September 29, 1981Assignee: Agfa-Gevaert, N.V.Inventors: Robert J. Pollet, Francis J. Sels, Karel A. Brems, Maurice A. de Ramaix
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Patent number: 4282306Abstract: Diffusion transfer color processes employing dye developers have been found to give improved results by the inclusion in the processing composition of a 5- or 6-membered aromatic unsaturated diazole free of imino nitrogen atoms.Type: GrantFiled: April 24, 1980Date of Patent: August 4, 1981Assignee: Polaroid CorporationInventor: Ronald F. Lambert
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Patent number: 4273863Abstract: A process of forming color images comprises imagewise exposing a silver halide photographic color image-transfer product comprising an image dye-providing compound in the presence of a silver halide developer, and treating the exposed photographic product with an alkaline processing composition in the presence of an amino acid or a combination of an acid and an amine. Color images are achieved having excellent image discrimination (Dmax-Dmin).Type: GrantFiled: July 27, 1979Date of Patent: June 16, 1981Assignee: Eastman Kodak CompanyInventors: Jean Deabriges, Yves Ferre, Claude Goumont
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Patent number: 4272613Abstract: A color photographic process is described for a silver halide photographic material having at least a silver halide emulsion layer containing a dye-forming coupler, comprising developing in a color developer solution containing components (1) an aromatic primary amino color developing agent, (2) a 1-aryl-3-pyrazolidone compound having two substituents at the 4-position, and (3) at least one compound selected from compounds represented by formulae (I) and (II): ##STR1## wherein X represents a hydrocarbon group having 1 to 6 carbon atoms; R represents a carboxylic acid group, a water-soluble carboxylic acid salt group, a water-soluble carboxylic acid ester group, or a water-soluble carboxylic acid amide group; m is 1 or 2; and n is 0 or 1; and then fixing by an acid hardening fix solution.Type: GrantFiled: May 19, 1980Date of Patent: June 9, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Haruo Shibaoka, Junkichi Ogawa
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Patent number: 4267263Abstract: .beta.-Aminoethyl carbamic acid is useful in photographic baths and developer compositions in order to accelerate the development.Type: GrantFiled: December 12, 1979Date of Patent: May 12, 1981Assignee: AGFA-Gevaert, A.G.Inventors: Friedrich-Wilhelm Kunitz, Erich Wolff, Karl Frank
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Patent number: 4264717Abstract: Compounds of the formula ##STR1## are useful in photographic materials and processes for the color development.Type: GrantFiled: October 17, 1979Date of Patent: April 28, 1981Assignee: AGFA-Gevaert, A.G.Inventors: Helmut Haseler, Fritz Nittel