Plural Developer Agents Containing Patents (Class 430/478)
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Publication number: 20130288185Abstract: The present invention provides a water-based developer where the dispersibility of an image mask layer in a developer is good in a developing step of a water-developable printing original plate of a CTP system. Also, the present invention also provides a water-based developer where the scum dispersibility in the developer is good even the developing is repeatedly conducted in large quantities using the same developer in a developing step of a water-developable printing original plate of a negative system. According to the present invention, there is provided a developer composition for a printing plate containing (a) alkali metal salt of saturated fatty acid having carbon number of 12 to 18 and (b) alkali metal salt of unsaturated fatty acid having carbon number of 12 to 18 in a weight ratio of from 20:80 to 80:20 in terms of (a):(b). The developer composition may further contain an alkali agent (c).Type: ApplicationFiled: December 26, 2011Publication date: October 31, 2013Applicant: TOYOBO CO., LTD.Inventors: Yukimi Yawata, Daiki Yoshioka
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Publication number: 20130078578Abstract: The disclosed resist developer is used when developing by irradiating an energy beam onto a resist layer containing a polymer of ?-chloromethacrylate and ?-methylstyrene for rendering or exposure, and contains a fluorocarbon-containing solvent (A) and an alcohol solvent (B), the latter of which has higher solubility relative to the resist layer than the former.Type: ApplicationFiled: March 28, 2011Publication date: March 28, 2013Applicant: HOYA CORPORATIONInventors: Hiromasa Iyama, Hideo Kobayashi
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Patent number: 6479198Abstract: A silver halide light-sensitive material comprises a support and a silver halide gelatin emulsion layer. The silver halide gelatin emulsion layer or an optionally provided hydrophilic layer contains a tanning developing agent. According to the first embodiment of the present invention, the tanning developing agent has a molecular structure in which two to six benzenediol or benzenetriol rings are connected with a linking group. According to the second embodiment of the invention, the tanning developing agent consists of a polymer having side chains containing benzenediol or benzenetriol rings. According to the third embodiment of the invention, the tanning developing agent consists of a benzenediol or benzenetriol ring having an aliphatic substituent group having 5 to 40 carbon atoms or an aromatic substituent group having 7 to 40 carbon atoms. A tanning developing solution and a lithographic printing plate are also disclosed.Type: GrantFiled: February 1, 2001Date of Patent: November 12, 2002Assignee: Fuji Photo Film Co., Ltd.Inventors: Naonori Makino, Kaku Sakata
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Patent number: 6379877Abstract: According to this invention a developer has been disclosed having a low pH value between 9.6 and 11.0, preferably between 9.6 and 10.3, and comprising hydroquinone in an amount from 0 to less than 30 g per liter, an auxiliary developing agent, and as silver halide complexing agents alkali metal sulphite salts, preferably sodium salts, in an amount from 0 to less than 50 g per liter, more preferably to less than 40 g per liter, and thiocyanate salts in amounts from 0.1 to 3 g, more preferably from 0.5 to 2.Type: GrantFiled: January 31, 1996Date of Patent: April 30, 2002Assignee: Agfa-GevaertInventors: Freddy Henderickx, Ann Verbeeck, Pascal Meeus, Hieronymus Andriessen
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Patent number: 6110655Abstract: Low silver black-and-white photographic elements, such as radiographic films, can be processed quickly using black-and-white developing and fixing compositions having reduced photoprocessing activity. The entire process is fairly rapid and effective despite the lowered concentrations of photographic developing and fixing agents. The processing compositions are more environmentally friendly because the conventional hydroquinone is replaced with an ascorbic acid developing agent. In addition, the processing compositions are free of ammonium ions.Type: GrantFiled: October 26, 1999Date of Patent: August 29, 2000Assignee: Eastman Kodak CompanyInventors: Alan S. Fitterman, Robert E. Dickerson
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Patent number: 5994037Abstract: Color photographic elements, especially color photographic papers, can be more rapidly color developed (up to 25 seconds) in the presence of a color developing solution containing a selectively diffusible color development photochemical such as a development inhibitor. Despite the shortened processing time, color balance within the three color records of such elements is maintained. The selectively diffusible color development photochemical has size and structure that enables it to have sufficient solubility in the color developing composition, and to selectively diffuse into the topmost red-sensitive emulsion layers of the processed color papers only.Type: GrantFiled: October 21, 1998Date of Patent: November 30, 1999Assignee: Eastman Kodak CompanyInventors: Peter J. Twist, John D. Goddard
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Patent number: 5994040Abstract: A processing composition for silver halide photographic light-sensitive material, which comprises at least one compound represented by the following formula (A), (A-I) or (A-II) and at least one compound represented by the following formula (B): ##STR1## Also disclosed are a developer prepared from the processing composition, and a processing method using the developer.Type: GrantFiled: March 4, 1997Date of Patent: November 30, 1999Assignee: Fuji Photo Film Co., Ltd.Inventors: Shinnichi Morishima, Kohzaburoh Yamada, Seiji Yamashita, Minoru Sakai, Kouta Fukui, Eiichi Okutsu
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Patent number: 5792599Abstract: Provided is a color photographic material excellent in discrimination and color reproducibility, which has a support and at least a light-sensitive silver halide, a binder, a coupler and a coupling developing agent provided thereon, and at least three light-sensitive emulsion layers having spectral sensitivities in different wavelength regions, respectively, in which at least two different coupling development agents are contained in different light-sensitive emulsion layers.Type: GrantFiled: September 20, 1996Date of Patent: August 11, 1998Assignee: Fuji Photo Film Co., Ltd.Inventor: Toshiki Taguchi
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Patent number: 5770351Abstract: There is described a method of processing silver halide photographic material in a processing machine using a developing solution which comprises either a hydroquinone type developing agent or a reductone type developing agent, together with an electron transfer agent as an auxiliary developing agent, and with at least one basic compound the anion of which is carbonate, sulphite or hydroxide, where in the presence of a compound of formula (I), Ar is an aromatic ring or heterocyclic aromatic ring which is optionally substituted.Type: GrantFiled: August 15, 1997Date of Patent: June 23, 1998Assignee: Ilford LimitedInventors: William Edward Long, Michael John Parker
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Patent number: 5554492Abstract: The invention provides a color photographic material comprising at least one silver halide emulsion layer having associated therewith a dye image-forming coupler and which contains in a layer thereof an ETA (electron transfer agent) releasing compound of the general formula: ##STR1## wherein R.sup.1 is an alkyl group,R.sup.2 to R.sup.6 are individually H or an alkyl group with the proviso that when one or both of R.sup.5 or R.sup.6 are H, R.sup.3 and R.sup.4 must not be H,R.sup.7 to R.sup.11 are individually H, or an alkyl or alkoxy group,A is H or an alkyl group and B is an alkyl group or, together with the atoms to which they are attached, A and B complete a carbocyclic or heterocyclic ring group,or,when A and B are not linked together, A and R.sup.2 may together complete an aromatic or nonaromatic carbocyclic group or an aromatic or nonaromatic heterocyclic group,with the proviso that if R.sup.7 to R.sup.11 are all hydrogen then neither R.sub.3 nor R.sub.4 are methyl or hydroxymethyl.Type: GrantFiled: April 7, 1995Date of Patent: September 10, 1996Assignee: Eastman Kodak CompanyInventor: Siu C. Tsoi
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Photographic silver halide developer compositions and process for forming photographic silver images
Patent number: 5545508Abstract: A process for forming a black-and-white high contrast negative photographic silver image by development of a silver halide photographic element with an aqueous alkaline photographic developer composition comprising a dihydroxybenzene developing agent, an auxiliary superadditive developing agent, an antifogging agent, an antioxidant compound, a combination of buffering agents and a sequestering agent, characterized by the fact that: a) the auxiliary developing agent is an aminophenol compound, b) the combination of buffering agents comprises at least a first buffering agent represented by carbonate compounds and at least a second buffering agent represented by phosphate compounds, the total amount of said first buffering agent and said second buffering agent being at least 35 grams per liter, band c) the pH of said aqueous alkaline photographic developer composition is in the range 9.0 to 11.0.Type: GrantFiled: February 13, 1996Date of Patent: August 13, 1996Assignee: Minnesota Mining and ManufacturingInventors: Carlo Marchesano, Elda Moizo, Filippo Faranda -
Patent number: 5508152Abstract: A processing method is disclosed, comprising development-processing a photographic material comprising a support having thereon a silver halide emulsion layer or a constituent layer adjacent to the emulsion layer which contains (i) a silver halide composition comprising at least one of silver bromochloride, silver chloroiodide, or silver bromochloroiodide each having a silver chloride content of 90 mole % or more, or silver chloride, and (ii) a compound represented by the following Formula (I) ##STR1## wherein R.sub.1 represents a hydrogen atom, an ammonium group or an alkali metal atom; and R.sub.2 represents a hydrogen atom, an alkyl group or an aryl group, with a developing solution containing (1) a dihydroxybenzene compound, and (2) an ascorbic acid or a derivative thereof in an amount of at least 5 mole % based on the amount of the dihydroxybenzene compound.Type: GrantFiled: February 27, 1995Date of Patent: April 16, 1996Assignee: Fuji Photo Film Co., Ltd.Inventors: Harumi Toyoda, deceased, Eiichi Okutsu, Tadashi Ito, Kiyoshi Morimoto
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Patent number: 5478706Abstract: The present invention relates to an alkaline aqueous black-and-white photographic developer composition comprising:(1) at least one black-and-white developing agent,(2) at least one black-and-white auxiliary developing agent,(3) at least one antifoggant,(4) at least one sequestering agent,(5) a sulfite antioxidant,(6) at least one buffering agent,(7) a tone agent, and(8) at least one tone promoting agent,wherein said tone agent is a primary organic amine compound and said tone promoting agent is a silver halide solvent.Type: GrantFiled: March 3, 1994Date of Patent: December 26, 1995Assignee: Minnesota Mining And Manufacturing CompanyInventors: Carlo Marchesano, Filippo Faranda, Franco Buriano
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Patent number: 5460919Abstract: A process of forming a super high-contrast negative image is disclosed, which comprises the steps of imagewise exposing a negative-working silver halide photographic material comprising a support having thereon one or more hydrophilic colloidal layers, at least one of the one or more hydrophilic colloidal layers being a negative-working silver halide emulsion layer, and then developing the photographic material with a developer containing an aminophenol derivative developing agent and a reductone compound in the existence of an organic compound having a negative reduction potential. A negative-working silver halide photographic material and a photographic developer being used for the image-forming process are also disclosed.Type: GrantFiled: July 22, 1994Date of Patent: October 24, 1995Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Naoki Obi, Yasuhiko Kojima, Yasuo Shigemitsu, Jun Takeuchi, Kiyoshi Suematsu
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Patent number: 5372911Abstract: A process of forming a super high-contrast negative image is disclosed, which comprises the steps of imagewise exposing a negative-working silver halide photographic material comprising a support having thereon one or more hydrophilic colloidal layers, at least one of the one or more hydrophilic colloidal layers being a negative-working silver halide emulsion layer, and then developing the photographic material with a developer containing an aminophenol derivative developing agent and a reductone compound in the existence of an organic compound having a negative reduction potential. A negative-working silver halide photographic material and a photographic developer being used for the image-forming process are also disclosed.Type: GrantFiled: June 11, 1992Date of Patent: December 13, 1994Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Naoki Obi, Yasuhiko Kojima, Yasuo Shigemitsu, Jun Takeuchi, Kiyoshi Suematsu
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Patent number: 5344741Abstract: The present invention provides a developer for silver halide photographic light-sensitive materials which provides super-high contrast and is improved in stability with time. This developer contains at least (1) a developing agent, (2) 10 g/l or more of a hydroquinonemonosulfonate, (3) 0.3 mol/l or more of a sulfite and (4) an amino compound in an amount necessary to accelerate enhancement of contrast and has a pH of 10.5-12.3.Type: GrantFiled: November 29, 1993Date of Patent: September 6, 1994Assignee: Mitsubishi Paper Mills LimitedInventors: Tamotu Iwata, Seiichi Sumi
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Patent number: 5318881Abstract: This invention relates to a method of processing an image-wise exposed silver halide photographic material wherein said method comprises the following steps:(a) developing the photographic material for 5 to 15 seconds in an aqueous developing solution,(b) fixing the photographic material for 5 to 15 seconds in an aqueous fixing solution, and(c) washing the photographic material for 5 to 20 seconds,wherein both said developing and fixing solutions are free of gelatin hardeners.The method is particularly intended for use in processing radiographic films which:comprise a support and silver halide emulsion layer or layers, at least one of said silver halide emulsion layers containing tabular silver halide grains having an average diameter to thickness ratio of at least 3:1 and highly deionized gelatin, andshow a swelling index lower than 140% and a melting time of from 45 to 120 minutes.The method shows the advantages of lower environmental pollution and shorter processing times.Type: GrantFiled: February 22, 1993Date of Patent: June 7, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventors: Marco Bucci, Carlo Marchesano, Dino Ferrari, Carlo Illuminati
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Non-toxic photographic developer composition for processing x-ray films in automatic film processors
Patent number: 5278035Abstract: A non-hydroquinone and non-alkali metal hydroxide containing developer composition for radiographic materials and a method of use thereof are provided. The developer composition comprises a developer selected from the group consisting of ascorbic acid and sugar-type derivatives thereof, stereoisomers and diastereoisomers of ascorbic acid and its sugar-type derivatives, their salts and mixtures thereof, together with a sulfite, a 3-pyrazolidone compound, and an anti-swelling agent selected from the group consisting of sodium sulfate, glutaraldehyde or mixtures thereof, said composition having a pH of from 9.5 to 10.6, and said developer being present in an amount of at least about 15 grams, said sulfite being present in an amount of from 2 to 50 grams, said swelling control agent being present in an amount of from 35 to 90 grams, and water to 1.0 liter.Type: GrantFiled: April 12, 1991Date of Patent: January 11, 1994Inventor: Audenried W. Knapp -
Patent number: 5266442Abstract: A method for the production of a silver image with improved contrast by the development of an image-wise exposed photographic silver halide emulsion layer material with a developer liquid containing a hydroquinone in the presence of an auxiliary developing agent, wherein said developer liquid is applied to said photographic material containing silver halide grains that have been chemically sensitized with organic thiosulphonic acid anions in combination with a gold sensitizer in the absence of thiosulphate ions.Type: GrantFiled: December 17, 1991Date of Patent: November 30, 1993Assignee: Agfa-Gevaert N.V.Inventor: Richard A. Ooms
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Patent number: 5264323Abstract: An improved photographic developing solution is free of dihydroxybenzene developing agents such as hydroquinone, has a pH in the range of from 9.5 to 11.5 and comprises (1) an ascorbic acid developing agent, (2) an auxiliary super-additive developing agent and (3) a carbonate buffering agent in a concentration of at least 0.5 molar. The developing solution is broadly useful in black-and-white development but is most advantageously employed in a process for forming a high-contrast image utilizing a silver halide photographic element comprising a hydrazine compound which functions as a nucleating agent and an amino compound which functions as an incorporated booster. The developing solution is ecologically advantageous, exhibits excellent stability with respect to seasoning effects, and provides high speed and good upper scale contrast combined with a low level of pepper fog and a moderate degree of chemical spread.Type: GrantFiled: December 14, 1992Date of Patent: November 23, 1993Assignee: Eastman Kodak CompanyInventors: Michael D. Purol, Paul A. Zielinski, Donald L. Kerr
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Patent number: 5236816Abstract: An improved photographic developing solution is free of dihydroxybenzene developing agents such as hydroquinone, has a pH in the range of from 9.5 to 11.5 and comprises (1) an ascorbic acid developing agent, (2) an auxiliary super-additive developing agent and (3) a carbonate buffering agent in a concentration of at least 0.5 molar. The developing solution is broadly useful in black-and-white development but is most advantageously employed in a process for forming a high-contrast image utilizing a silver halide photographic element comprising a hydrazine compound which functions as a nucleating agent and an amino compound which functions as an incorporated booster. The developing solution is ecologically advantageous, exhibits excellent stability with respect to seasoning effects, and provides high speed and good upper scale contrast combined with a low level of pepper fog and a moderate degree of chemical spread.Type: GrantFiled: April 10, 1992Date of Patent: August 17, 1993Assignee: Eastman Kodak CompanyInventors: Michael D. Purol, Paul A. Zielinski, Donald L. Kerr
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Patent number: 5206123Abstract: A method for high contrast development of an image-wise exposed photographic element comprising a support and at least one silver halide emulsion layer, which method comprises contacting said exposed element in the presence of a hydrazine compound with an aqueous alkaline developing solution which has a pH between 10 and 13 and contains a dihydroxybenzene developing agent a 3-pyrazolidinone or an aminophenol developing agent sulphite ions and a contrast promoting amount of an amino compound characterized in that said developing solution further contains an aprotic solvent corresponding to general formula (I) or (II) : ##STR1## wherein R.sub.1 represents alkyl, substituted alkyl, alkylamino or substituted alkylamino, andR.sub.2 and R.sub.3 each independently represent alkyl substituted alkyl orwherein R.sub.1 together with R.sub.2 represent the necessary atoms to form together with the carbon and the nitrogen atom respectively to which they are attached, a heterocyclic ring, and R.sub.Type: GrantFiled: February 18, 1992Date of Patent: April 27, 1993Assignee: Agfa-Gevaert, N.V.Inventors: Richard A. Ooms, Piet Kok
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Patent number: 5098819Abstract: An environmentally-safe, non-toxic non-hydroquinone and non-alkali metal hydroxide containing photographic developer composition is provided comprising a developer selected from the group consisting of ascorbic acid and sugar-type derivatives thereof, stereoisomers and diastereoisomers of ascorbic acid and its sugar-type derivatives, their salts and mixtures thereof, together with a sulfite, an alkali metal carbonate, and a 3-pyrazolidone developer compound.Type: GrantFiled: January 28, 1991Date of Patent: March 24, 1992Inventor: Audenried W. Knapp
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Patent number: 5034302Abstract: A developer sheet useful in forming images having a high density comprising a support having front and back surfaces; anda developer layer coated from a solution on said front surface, said developer layer comprising a particulate reactive material being capable of reacting with a substantially colorless chromogenic material upon contact and generating an image, a binder material, and a viscosity increasing additive is provided. The developer sheet is particularly useful in photosensitive microencapsulated imaging systems for forming overhead transparencies.Type: GrantFiled: January 10, 1991Date of Patent: July 23, 1991Assignee: The Mead CorporationInventors: Paul C. Adair, Cheryl L. Moore
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Patent number: 5028515Abstract: In a color print containing cyan, magenta and yellow colored dyes, the color print where the spectral absorption peak wave lengths of the respective colored dyes lie in the range represented by the following formula:1/2(.lambda.y+.lambda.c).gtoreq..lambda.m.gtoreq.1/2(.lambda.y+.lambda.c)-1 0.lambda.c=Spectral absorption peak wave length (nm) of the colored cyan dye.lambda.m=Spectral absorption peak wave length (nm) of the colored magenta dye.lambda.y=Spectral absorption peak wave length (nm) of the colored yellow dyeIn the color print, improvement of the color reproduction and improvement of the observation light source dependency, which hitherto tend to conflict with each other, can be attained at the same time.Type: GrantFiled: October 15, 1990Date of Patent: July 2, 1991Assignee: Fuji Photo Film Co., Ltd.Inventors: Kazunori Hasebe, Koji Takahashi
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Patent number: 4851326Abstract: A silver halide color photographic material having at least one silver halide emulsion layer on a reflective support is, after having been imagewise exposed, subjected to color development with a color developer which does not substantially contain benzyl alcohol and which contains a bromide ion in an amount of 4.times.10.sup.-3 mol/liter or less, for a period of time of 2 minutes or less, to obtain a color images with a high colored density. The silver halide color photographic material specifically has at least one silver chlorobromide emulsion layer which does not substantially contain silver iodide and which contains silver chloride in an amount of 50 mol % or more.In the color images thus formed by the present process, the colored density is high and the fog is less.Type: GrantFiled: February 24, 1987Date of Patent: July 25, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Takatoshi Ishikawa, Junya Nakajima
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Patent number: 4801516Abstract: There is provided a method of processing a silver halide color photographic material which comprises processing the silver halide color photographic material with a color developer containing an aromatic primary amine color developing agent and a specific hydroxylamine compound. According to this method the stability of a color developer is improved so that the increased fogging problem in continuous processing is lessened and the processing time is shortened.Type: GrantFiled: June 24, 1987Date of Patent: January 31, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Takatoshi Ishikawa, Morio Yagihara
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Patent number: 4797350Abstract: A process for forming a dye image is disclosed, in which a silver halide photographic light-sensitive material having a silver halide emulsion layer is developed by a color developer comprising an aromatic primary amine and an N,N- dialkylhydroxylamine. The silver halide emulsion layer contains a hydrophobic dye-forming coupler and a compound selected from the group consisting of compounds having a sterically hindered phenol group and polyalkylpiperidine compounds or the water soluble acid salt thereof. The dye image having a high maximum density and a high light-fastness can be obtained when the color developer without benzyl alcohol is used.Type: GrantFiled: April 6, 1987Date of Patent: January 10, 1989Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Keiji Ohbayashi, Shigeo Chino, Mitsuhiro Okumura, Kaoru Onodera
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Patent number: 4783394Abstract: A color image forming process is described, which comprises developing an imagewise exposed silver halide color photographic material with a color developer containing an aromatic primary amine developing agent and being substantially free of benzyl alcohol for a period of up to about 2 minutes and 30 seconds, wherein the silver halide color photographic material comprises a reflective support having thereon a blue-sensitive silver halide emulsion layer containing a yellow color-forming coupler, a green-sensitive silver halide emulsion layer contaning a magenta color-forming coupler, and a red-sensitive silver halide emulsion layer containing a cyan color-forming coupler in this order, the material further containing light-insensitive hydrophilic colloid layers between the blue-sensitive silver halide emulsion layer and the green-sensitive silver halide emulsion layer and between the green-sensitive silver halide emulsion layer and the red-sensitive silver halide emulsion layer and at least one light-insensitType: GrantFiled: April 10, 1987Date of Patent: November 8, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Takeshi Hirose, Kiyoshi Nakazyo, Hideaki Naruse
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Patent number: 4774167Abstract: A method for processing a silver halide color photographic material is provided, which comprises subjecting an imagewise exposed silver halide color photographic material having at least one silver halide emulsion layer on a reflective support to color development for a period not exceeding 2 minutes and 30 seconds using a color-developing solution containing substantially no benzyl alcohol, a sulfite in a concentration of 8.times.10.sup.-3 mol/liter or less, and a hydroxylamine in a concentration of 1.5.times.10.sup.-2 mol/liter or less, thereby achieving high color densities of the developed images and reduced fog. The effects of this method are particularly significant in photographic paper containing a pyrazoloazole type magenta coupler.Type: GrantFiled: February 24, 1987Date of Patent: September 27, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshio Koshimizu, Takatoshi Ishikawa, Shinji Ueda
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Photographic silver halide developer compositions and process for forming photographic silver images
Patent number: 4756997Abstract: An aqueous alkaline photographic silver halide developer composition comprising a dihydroxy benzene developing agent, an auxiliary superadditive developing agent, an antifogging agent, an antioxidant and a buffering agent, characterized by the fact that the composition further comprises a stabilizing amount of an .alpha.-ketocarboxylic acid.The developer composition has a better resistance against air oxidation and can be left in continuous transport automatic processors for several days without undergoing any substantial decrease of its developing properties.The developer composition is particularly useful in a process for the formation of a high contrast silver image by developing silver halide photographic elements including at least a negative acting surface latent image type silver halide emulsion in the presence of a hydrazine compound, preferably in the additional presence of an effective amount of a contrast promoting agent.Type: GrantFiled: July 21, 1987Date of Patent: July 12, 1988Assignee: Minnesota Mining and Manufacturing CompanyInventor: Carlo Marchesano -
Patent number: 4740452Abstract: The present invention provides a process for preparing a negative image of high contrast comprising developing an exposed silver halide photographic material which is substantially a surface latent image-type material in the presence of a hydrazine derivative, wherein said material is processed with a water-soluble alkaline developer having a pH value of from 10.5 to 12.3 and at least comprising the following components (1) through (3):(1) a dihydroxybenzene-type developing agent;(2) 0.3 mole/liter (developer) or more of a sulfite preservative; and(3) from 0.01 to 0.30 mole/liter (developer) of a compound of formula (A) ##STR1## in which R.sub.2 represents an alkyl group having from 3 to 6 carbon atoms; R.sub.3 and R.sub.4 each represents an alkyl or hydroxyalkyl group having from 1 to 10 carbon atoms.The formed negative images are of high contrast and are almost free from silver stain. The sensitivity is high and the dot image quality is good.Type: GrantFiled: May 22, 1986Date of Patent: April 26, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Eiichi Okutsu, Mitsunori Hirano
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Patent number: 4560637Abstract: A process for forming a polymeric image in a silver halide sensor type polymerizable light-sensitive material having a silver halide photographic emulsion layer is disclosed. The process is comprised of reducing a development nucleus-containing silver halide using at least one phenol compound and at least one hydrazine compound in the presence of at least one non-gaseous ethylenically unsaturated compound capable of undergoing addition polymerization to selectively polymerize the non-gaseous ethylenically unsaturated compound in an area where the development nucleus-containing silver halide is present. The phenol compound is represented by the following general formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.2 ', R.sub.3 and R.sub.3 ' are defined within the disclosure. The hydrazine compound is represented by the following general formula (II): ##STR2## wherein R.sub.4, R.sub.5 and R.sub.6 are defined within the disclosure.Type: GrantFiled: December 21, 1982Date of Patent: December 24, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Minoru Maeda, Noriyuki Inoue, Mikio Totsuka
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Patent number: 4427762Abstract: An image-forming method wherein a photosensitive material comprising a support having a photosensitive copper (I) halide emulsion that contains silver halide and which has grains of copper (I) halide crystal dispersed in a binder is subjected to imagewise exposure and development with an alkaline solution is disclosed. The imagewise exposure is effected either in a dry or wet state. The alkaline solution contains compounds selected from at least two of the following three groups: (A) a group consisting of .alpha.-amino acids, .alpha.Type: GrantFiled: December 15, 1982Date of Patent: January 24, 1984Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Toshiaki Takahashi, Noboru Itoh
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Patent number: 4298673Abstract: A lithographic type diffusion transfer developing composition which provides high contrast images having sharp toe-gradation for developing silver halide light-sensitive materials contains at least one amine represented by one of the following general formulae (I), (II) or (III):H.sub.2 N-C.sub.n H.sub.2n -X (I) ##STR1## X, X', R.sub.1, n and m are defined in the specification. The process of developing using such a composition is also disclosed.Type: GrantFiled: March 6, 1978Date of Patent: November 3, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Kikuo Kubotera, Eiichi Mizuki, Masato Satomura, Haruhiko Iwano, Tadahiro Fujiwara
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Patent number: H2048Abstract: A non-hydroquinone photographic developer composition comprising: (a) a developer selected from the group consisting of ascorbic acid and sugar-type derivatives thereof, or alkali metal salts and mixtures thereof, in an amount of 0.1 to 0.4 mol/liter (mol/l); (b) an effective amount of an auxiliary developing agent comprising a 3-pyrazolidone compound, an aminophenol or a mixture thereof; (c) an alkali metal sulfite in an amount less than or equal to 0.32 mol/l; (d) an alkali metal carbonate in an amount of 0.1 to 0.4 mol/l; (e) an alkali metal hydroxide in an amount of from 0.08 to 2.0 mols/l; (f) with the developer composition having a pH of 11.8 or higher at 25° C.Type: GrantFiled: February 14, 1995Date of Patent: September 3, 2002Assignee: Fuji Hunt Photographic Chemicals, Inc.Inventors: Haixing Wan, Diane Zhang, David Carlson, Alan A. Bornstein
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Patent number: H1112Abstract: A silver halide color photographic light-sensitive material improved in graininess, comprising a support having thereon a red-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a blue-sensitive silver halide emulsion layer, wherein at least one of the red-sensitive emulsion layer and the green-sensitive emulsion layer has the three-layered structure, in which the low speed silver halide emulsion layer, medium speed silver halide emulsion layer and high speed silver halide emulsion layer are coated on the support in this order; and the coating amount of silver in the layer increases in the order of the medium speed layer, low speed layer and high speed layer.Type: GrantFiled: October 16, 1990Date of Patent: November 3, 1992Assignee: Konica CorporationInventors: Atsuo Ezaki, Keisuke Tobita, Hiroshi Ikeda, Hideaki Haraga